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Year 12
December 2019
Vacation Work
Approximate Time: 2 hours
Total marks available: 100
Due: Your first chemistry lesson in January.
Topic 1 Questions 1 – 15
Topic 2 Questions 16 – 40
Topic 3 Questions 41 – 45
Topic 5 Questions 46 – 75
Topic 8/13A Questions 76 – 86
Mixed Bag Questions 87 – 100
Topic 1: Atomic Structure
Q1.
The diagrams show the shape and relative size of four of the atomic orbitals occupied in a magnesium
atom.
A E
B F
C G
D H
(Total for question = 1 mark)
Q2.
The electronic configuration of a metal ion with a charge of +3 could be
2 2 6
A 1s 2s 2p
2 2 6 1
B 1s 2s 2p 3s
2 2 6 2 1
C 1s 2s 2p 3s 3p
2 2 6 2 3
D 1s 2s 2p 3s 3p
(Total for question = 1 mark)
Q3.
Which of the following graphs, not drawn to scale, best represents the trend in the melting temperatures
of the elements across Period 3, from sodium to argon?
(Total for question = 1 mark)
Q4.
–1
The first six ionization energies, in kJ mol , of an element are
A 2
B 3
C 4
D 5
(Total for question = 1 marks)
Q5.
The graph shows the variation of first ionisation energy with atomic number for successive elements in
the Periodic Table.
(Total for question = 1 mark)
Q6.
The first six successive ionisation energies of an element X are given in the table.
B XO3
C X2O
D X2O3
Q7.
Which of these statements is correct?
A The ionic radii of the alkali metals increase down the group.
+ + +
B The ionic radii for the ions Na , Mg2 , Al3 increase across this series.
C The first ionisation energies of the alkali metals increase down the group.
D The melting temperatures of successive elements in Period 3 always increase across the period.
Q8.
What is the sequence of the orbitals from which electrons are removed in the first four ionisations of
boron?
(Total for question = 1 mark)
Q9.
+
The smallest ion which is isoelectronic with the sodium ion, Na , is
–
A hydride ion, H .
3–
B nitride ion, N .
2–
C oxide ion, O .
–
D fluoride ion, F .
Q10.
Identify the atom with two unpaired electrons in its lowest energy state (ground state).
A Be
B C
C Cl
D Ca
(Total for question = 1 mark)
Q11.
Which of the following series shows the elements in order of increasing melting temperature?
D S, Cl, Ar
(Total for question = 1 mark)
Q12.
Which of the following equations shows the process occurring when the second ionisation energy of
magnesium is measured?
– 2+
A Mg(s) – 2e → Mg (g)
– 2+
B Mg(g) – 2e → Mg (g)
+ –
C Mg (g) + e → Mg(s)
+ – 2+
D Mg (g) – e → Mg (g)
Q13.
3−
The electronic configuration of the nitride ion, N , is
2 2
A 1s 2s
2 2 1
B 1s 2s 2p
2 2 3
C 1s 2s 2p
2 2 6
D 1s 2s 2p
(Total for question = 1 mark)
Q14.
The Avogadro constant is equal to the number of
A atoms in one mole of any element.
B atoms in one mole of any monatomic element.
C atoms in one mole of any compound.
D ions in one mole of an ionic compound.
(Total for question = 1 mark)
Q15.
Which ion has the smallest ionic radius?
−
A Cl
2+
B Ca
+
C K
2−
D S
(Total for question = 1 mark)
Q16.
Which molecule contains three atoms in a straight line?
A BF3
B CH4
C H2O
D SF6
(Total for question = 1 mark)
Q17.
Consider the following equation.
A 4
B 5
C 6
D 7
(Total for question = 1 mark)
Q18.
Which bond angles are present in a molecule of methanol?
A 90° and 104.5°
B 104.5° and 109.5°
C 109.5° and 180°
D 90° and 180°
(Total for question = 1 mark)
Q19.
Which compound contains a bond with the greatest polarity?
Q20.
In which pair are the ions isoelectronic?
+ 2−
A Li and O
+ −
B Na and Cl
2+ 2−
C Mg and S
3+ −
D Al and F
(Total for question = 1 mark)
Q21.
In what states do sodium and sodium chloride conduct electricity?
(Total for question = 1 mark)
Q22.
(Total for question = 1 mark)
Q23.
Which is the shortest covalent bond?
A H–H
B H–N
C H–S
D H–Br
(Total for question = 1 mark)
Q24.
Which of the following compounds has the highest boiling temperature?
Q25.
Sulfur can combine with fluorine to form a number of different compounds, some of which are shown
below. From the diagrams given, which compound will not be polar?
(Total for question = 1 mark)
Q26.
Four dot-and-cross electron diagrams are shown.
Q27.
Which diagram best represents the electron densities in lithium iodide?
(Total for question = 1 mark)
Q28.
Which of these statements is the best evidence for the existence of ions in sodium chloride?
A Solid sodium chloride conducts electricity.
B When an electric current is passed through a solution of sodium chloride, the movement of the
coloured ions is observed.
C Sodium chloride crystals have a regular shape.
D There is good agreement between theoretical and experimental lattice energies for sodium
chloride.
(Total for question = 1 mark)
Q29.
Which of the following bonds is likely to be the most polar?
A H—F
B P—O
C N—Cl
D C—S
Q30.
A CO2
B NH3
C CCl4
D CH4
Q31.
(Total for question = 1 mark)
Q34.
Which molecule has the shortest distance between the atoms?
(Total for question = 1 mark)
Q35.
What is the trend in boiling temperatures for the hydrogen halides from HF to HI?
A decreases
C increases
(Total for question = 1 mark)
Q36.
What are the approximate bond angles in the and ions?
(Total for question = 1 mark)
Q37.
Which of the following has the smallest ionic radius?
2–
A O
–
B F
+
C Na
2+
D Mg
(Total for question = 1 mark)
Q38.
What is the equation for the lattice energy of magnesium chloride?
2+ –
B Mg (s) + 2Cl (g) → MgCl2(s)
2+ –
C Mg (g) + 2Cl (g) → MgCl2(s)
2+ –
D Mg (g) + 2Cl (g) → MgCl2(g)
Q40.
Which of the following elements has the greatest attraction for bond pairs of electrons in a covalent bond?
Topic 3: Redox
Q41.
In which reaction is calcium oxidised?
(1)
A Ca + 2HCl → CaCl2 + H2
Q42.
3+ –
Al → Al + 3e
+ –
2H + 2e → H2
When these ionic half-equations are combined, the full ionic equation is
(1)
+ 3+
A Al + 2H → Al + H2
+ – 3+ –
B Al + 2H + 2e → Al + H2 + 3e
+ 3+
C Al + 6H → Al + 3H2
+ 3+
D 2Al + 6H → 2Al + 3H2
A −1
B +3
C +5
D +7
(Total for question = 1 mark)
Q45.
The oxidation number of sulfur in potassium aluminium sulfate (potash alum), KAl(SO4)2.12H2O, is
A –2
B +2
C +6
D +8
(Total for question = 1 mark)
Q46.
A compound has the composition by mass of 54.5% C, 9.1% H and 36.4% O. What is its empirical
formula?
A C2H2O
B C2H4O
C C4H9O
D C6HO4
(Total for question = 1 mark)
Q47.
Sodium hydrogencarbonate decomposes on heating.
3
What is the maximum volume of carbon dioxide, in dm , which could be obtained by heating 0.25 mol
sodium hydrogencarbonate?
The gas volume is measured at room temperature and pressure when the molar volume of a gas = 24
3 –1
dm mol .
A 3
B 6
C 12
D 24
(Total for question = 1 mark)
Q48.
3 3
50 cm of hydrogen is mixed with 25 cm of chlorine. The gases react as shown in the equation below.
What is the total volume of gas present at the end of the reaction?
[All gas volumes are measured at the same temperature and pressure.]
3
A 75 cm
3
B 100 cm
3
C 125 cm
3
D 150 cm
(Total for question = 1 mark)
Q49.
Which of the following gas samples has the same volume as 7.0 g of carbon monoxide?
All volumes are measured at the same temperature and pressure.
A 1.0 g of hydrogen
B 3.5 g of nitrogen
C 10.0 g of argon
D 35.5 g of chlorine
(Total for question = 1 mark)
Q50.
3 –3
How many moles of ions are present in 30 cm of 0.025 mol dm barium hydroxide solution,
Ba(OH)2(aq)?
A 0.00075
B 0.00150
C 0.00225
D 0.00450
(Total for question = 1 mark)
Q51.
Which of the following aqueous solutions contains the greatest number of negative ions?
3 −3
A 500 cm of 0.10 mol dm Na2SO4(aq)
3 −3
B 250 cm of 0.12 mol dm BaCl2(aq)
3 −3
C 250 cm of 0.15 mol dm KI(aq)
3 −3
D 500 cm of 0.10 mol dm Zn(NO3)2(aq)
(Total for question = 1 mark)
Q52.
In the synthesis of ammonia, 56.0 g nitrogen was reacted with excess hydrogen.
A 5.66
B 8.82
C 9.10
D 10.7
(Total for question = 1 mark)
Q53.
Calculate the empirical formula of the compound with the percentage composition by mass:
Li = 17.9%; P = 26.8%; O = 55.3%
–1
Molar masses / g mol Li = 6.9, P = 31.0, O = 16.0
(1)
A Li2P3O6
B Li3PO3
C LiPO3
D Li3PO4
Q54.
3
In an experiment carried out at 200°C and 1 atm pressure, 20 cm of ammonia gas reacted with an
excess of heated copper(II) oxide.
3
If all measurements were made at 200°C and 1 atm pressure, what would be the total volume, in cm , of
gaseous products?
A 10
B 20
C 30
D 40
(Total for question = 1 mark)
Q55.
–3 3
What is the concentration, in mol dm , of a solution of 10.6 g of sodium carbonate, Na2CO3, in 250 cm
of solution?
(Total for question = 1 mark)
Q57.
When 1.270 g of copper (Ar = 63.5) is added to excess silver nitrate solution, 4.316 g of silver (Ar =
107.9) forms.
Q58.
–3
B 2.7 × 10
C 2.7
3
D 2.7 × 10
(Total for question = 1 mark)
Q59.
What is the empirical formula of the oxide formed when 2.6 g of chromium produces 3.8 g of chromium
oxide?
–1
Molar masses / g mol Cr = 52.0, O = 16.0
(1)
A CrO
B CrO2
C Cr2O3
D Cr3O4
A CH
B CH2
C C2H4
D CnH2n
(Total for question = 1 mark)
Q61.
3
How many atoms are there in 120 cm of ammonia gas at room temperature and pressure (r.t.p.)?
3 –1 23 –1
[Molar volume of gas at r.t.p. = 24 000 cm mol Avogadro constant = 6.0 × 10 mol ]
21
A 3.0 × 10
22
B 1.2 × 10
22
C 1.5 × 10
25
D 1.2 × 10
(Total for question = 1 mark)
Q62.
Hydrogen is manufactured using the reaction
The mass of hydrogen, in tonnes, which can be produced from 160 tonnes of methane is
A 27
B 54
C 60
D 67
(Total for question = 1 mark)
Q63.
When 0.127 g of copper is added to excess silver nitrate solution, the following reaction occurs.
–1
[Molar masses / g mol : Cu = 63.5 Ag = 107.9]
A 0.216 g
B 0.254 g
C 0.432 g
D 0.863 g
(Total for question = 1 mark)
Q64.
Aluminium reacts with hydrochloric acid.
What is the maximum volume of hydrogen at room temperature and pressure (r.t.p.)
that can be formed from 0.135 g of aluminium?
3 –1 –1
[Molar volume of gas at r.t.p. = 24 000 cm mol Molar mass Al = 27.0 g mol ]
3
A 60 cm
3
B 80 cm
3
C 120 cm
3
D 180 cm
(Total for question = 1 mark)
Q65.
23 −1
The Avogadro constant is 6.0 × 10 mol .
23
A 3.0 × 10
23
B 6.0 × 10
24
C 2.4 × 10
24
D 9.0 × 10
(Total for question = 1 mark)
Q66.
Phosphoric(V) acid, H3PO4, can be made from phosphorus in two stages.
P4 + 5O2 → P4O10
Data
The percentage atom economy, by mass, for the production of phosphoric(V) acid from phosphorus is
A 58.0
B 69.0
C 72.4
D 100
(Total for question = 1 mark)
Q67.
The molecular formula of phosphorus(V) oxide is P4O10.
What is the percentage by mass of phosphorus in this oxide?
–1
[Molar masses / g mol : O = 16.0 P = 31.0]
A 28.6%
B 42.9%
C 43.7%
D 56.3%
(Total for question = 1 mark)
Q68.
The solution containing the greatest number of chloride ions is
3 −2 −3
A 10 cm of 1.00 × 10 mol dm AlCl3
3 −2 −3
B 20 cm of 1.50 × 10 mol dm MgCl2
3 −2 −3
C 30 cm of 1.50 × 10 mol dm HCl
3 −2 −3
D 10 cm of 2.50 × 10 mol dm CaCl2
For safety reasons, the concentration of lead in paint should not exceed 600 parts per million (ppm) by
mass. (1 ppm by mass = 1 mg in 1 kg)
Therefore, the mass of lead in one kilogram of paint should not exceed
A 0.06 g
B 0.60 g
C 6.0 g
D 60 g
Q70.
3 −3
10 g of magnesium is added to 1 dm of 1 mol dm copper(II) sulfate solution and the mixture is stirred
until no further reaction occurs.
Q71.
The ionic equation for the reaction between hydrochloric acid and aqueous sodium hydroxide is
+ −
A H (aq) + OH (aq) → H2O(l)
− +
B Cl (aq) + Na (aq) → NaCl(aq)
+ − + − − +
C H (aq) + Cl (aq) + Na (aq) + OH (aq) → Cl (aq) + Na (aq) + H2O(l)
+ − + −
D H (aq) + Cl (aq) + Na (aq) + OH (aq) → NaCl(aq) + H2O(l)
(Total for question = 1 mark)
Q72.
0.05 mol of calcium carbonate was added to a solution containing 0.08 mol of nitric acid.
A CH3
B C2H6
C C2H5
D C4H10
(Total for question = 1 mark)
Q74.
The Avogadro constant is numerically equal to the number of
A ions in 1 mol of sodium chloride, NaCl
B atoms in 1 mol of hydrogen gas, H2
C electrons in 1 mol of helium gas, He
D molecules in 1 mol of oxygen gas, O2
(Total for question = 1 mark)
Q75.
Consider the reaction
–1
H2(g) + I2(g) → 2HI (g) ΔH = –9.0 kJ mol
–1
The bond energy of H—H = 436 kJ mol
–1
The bond energy of H—I = 298 kJ mol
–1
It can be deduced that the bond energy of I—I, in kJ mol , is
(1)
A 75.5
B 84.5
C 151
D 169
Q76.
3 –3 3 –3
When 10 cm of 1 mol dm nitric acid is mixed with 20 cm of 1 mol dm sodium hydroxide solution,
there is a temperature rise of ΔT.
3 –3 3 –3
If the reaction is repeated with 20 cm of nitric acid of 1 mol dm and 20 cm of 1 mol dm sodium
hydroxide solution, the temperature rise is
A 2 Δ T
B 1.5 Δ T
C Δ T
D 0.75 Δ T
(Total for question = 1 mark)
Q77.
Consider the following data.
Q78.
An excess of zinc powder is added to a solution of copper(II) sulfate and the maximum change in
temperature of the solution is measured.
A mass is equal to the mass of zinc added to the mass of copper(II) sulfate solution.
C specific heat capacity is the average of the specific heat capacities of the solution and zinc.
(Total for question = 1 mark)
Q79.
The enthalpy change of combustion of ethanol was determined by using a spirit burner containing ethanol
3
to heat 250 cm of water in a copper calorimeter.
The experimental value obtained was less exothermic than a value found looking up literature.
Which is the least likely reason for this difference in the enthalpy values?
A Heat loss from the copper calorimeter
B Incomplete combustion of the ethanol
C Use of non-standard conditions
D Loss of ethanol by evaporation
(Total for question = 1 mark)
Q80.
The enthalpy changes of two reactions are
(Total for question = 1 mark)
Q82.
3 −3 3 –3
When 100 cm of 2.0 mol dm sodium hydroxide solution is added to 100 cm of 2.0 mol dm sulfuric
acid (an excess) to form sodium sulfate, the temperature rise is 12.5 °C.
–1
What is the enthalpy change of the reaction in kJ mol ?
(Total for question = 1 mark)
Q83.
For reactions with the ionic equation
+ –
H (aq) + OH (aq) → H2O(l)
the type of enthalpy change is
A ΔHatomisation
B ΔHcombustion
C ΔHformation
D ΔHneutralisation
(Total for question = 1 mark)
Q84.
In which of the following does X represent the mean bond enthalpy for the O−H bond in water?
(Total for question = 1 mark)
Q85.
The following statements give information about the thermodynamic stability of magnesium chlorides.
Which signs of the standard enthalpy changes of formation of MgCl and MgCl3 are correct?
(Total for question = 1 mark)
Q86.
The table shows the mean bond enthalpies for some covalent bonds.
–1
What is the approximate enthalpy change, in kJ mol , for the reaction shown?
(Total for question = 1 marks)
Q87.
Answer the question with a cross in the box you think is correct (). If you change your mind about
an answer, put a line through the box () and then mark your new answer with a cross ().
3 −2 −3 −4
10 cm of a 1.00 × 10 mol dm solution needs to be diluted to make the concentration 5.00 × 10
−3
mol dm .
3
What volume of water, in cm , should be added?
A 20
B 40
C 190
D 200
(Total for question = 1 mark)
Q88.
Solutions of barium chloride and silver nitrate are mixed together. The reaction that takes place is an
example of
A displacement.
B neutralization.
C oxidation.
D precipitation.
(Total for question = 1 mark)
Q89.
–3 –3 –3
The concentration of potassium ions in human blood is in the range 3.5 × 10 to 5.0 × 10 mol dm .
3
An average person has 5 dm of blood.
What is the minimum mass of potassium ions in the blood of an average person?
–1
[Molar mass of potassium = 39.1 g mol ]
A 0.137 g
B 0.684 g
C 0.978 g
D 684.0 g
Q90.
3 3
What is the maximum volume, in dm , of sulfur trioxide that could be obtained when 0.5 dm of sulfur
3
dioxide is mixed with 1 dm of oxygen, under suitable conditions?
B 1.5
C 2.0
D 2.5
(Total for question = 1 mark)
Q91.
3
What is the number of atoms present in 3.06 dm of carbon dioxide, at 373 K?
3 –1 23 –1
[Molar volume of a gas at 373 K is 30.6 dm mol , Avogadro constant = 6.0 × 10 mol ]
22
A 1.8 × 10
22
B 6.0 × 10
23
C 1.8 × 10
23
D 6.0 × 10
(Total for question = 1 mark)
Q92.
Phosphorus reacts with iodine to produce phosphorus(III) iodide:
P4 + 6I2 → 4PI3
What is the minimum mass of iodine required to produce 1 kg of phosphorus(III) iodide when the
phosphorus is in excess?
−1
Data: molar mass of phosphorus(III) iodide = 411.7 g mol
A 0.616 kg
B 0.925 kg
C 2.466 kg
D 3.700 kg
(Total for question = 1 mark)
Q93.
Ammonia is manufactured from hydrogen and nitrogen in the Haber process.
If 60 tonnes of hydrogen produces 80 tonnes of ammonia, what is the percentage yield in the reaction?
A × 100%
B × 100%
C × 100%
D × 100%
(Total for question = 1 mark)
Q94.
55 2+ 2+
Which statement is true about the ions Mn and 56Fe ?
55 2+ 56 2+
A Mn is deflected less in a mass spectrometer than Fe .
55 2+ 56 2+
C Mn has more protons than Fe .
Q95.
−
An ion, X , contains 36 electrons.
A s
B p
C d
D f
(Total for question = 1 mark)
Q96.
16 17 18
A sample of oxygen contains the isotopes O, O, O.
How many peaks would there be for the O ions in the mass spectrum of this sample of oxygen?
A 3
B 5
C 6
D 9
(Total for question = 1 marks)
Q97.
Which of these Period 2 elements has the highest melting temperature?
A Lithium
B Boron
C Nitrogen
D Neon
(Total for question = 1 mark)
Q98.
Which of the following contains one mole of neutrons?
A 1 g of H
B 1 g of C
C 2 g of Mg
D 2 g of Ne
(Total for question = 1 mark)
Q99.
The total number of occupied orbitals in the third quantum shell of a silicon atom in its ground state is
A 2
B 3
C 4
D 5
Q100.
– + 2 2 6
Which of the species, Ne, F and Na , have the electronic structure 1s 2s 2p ?
A Ne only
–
B Ne and F only
+
C Ne and Na only
– +
D Ne, F and Na
(Total for question = 1 mark)