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Hebei Zetian Chemical Co., Ltd.

Phenolic Resin Material Safety Data Sheet


Part I: Chemical Names
Chemical Chinese name: 酚醛树脂 Technical specification
code:
Chemical name in English: phenolic resin CAS No.: 9003-35-4
Chinese name 2: Formula:
English name 2: Molecular weight:

Part II: Composition/Composition Information


Harmful ingredients content CAS No.

Part III: Risk Overview


Risk categories:
Invasion route:
Health hazards: Exposure to dust generated during processing or use of this product can cause headaches, drowsiness, general
weakness, respiratory irritation, asthmatic bronchitis, and skin disorders, as well as kidney damage. Air environment
analysis found phenol, formaldehyde and ammonia. In the polycondensation process, formaldehyde, phenol, and
carbon monoxide poisoning can occur.
Environmental hazard:
Explosion hazard: This product is not explosive. This product is not a flammable solid.
Part IV: First Aid Measures
skin contact: Remove contaminated clothing and thoroughly wash skin with soap and water.
eye contact: Raise eyelids and rinse with running water or saline. Get medical attention.
Inhalation: Quickly leave the scene to the fresh air. Keep the airway open. If breathing is difficult, give oxygen. If breathing stops,
give artificial respiration immediately. Medical treatment。
Ingestion: Drink plenty of warm water and induce vomiting. Get medical attention.
Part V: Fire Fighting Measures
Dangerous characteristics: The toxic gases are liberated by high heat. Powder and air can form an explosive mixture. When it reaches a certain
concentration, it will explode in the event of Mars.
Hazardous combustion Carbon monoxide, carbon dioxide.
products:
Fire fighting methods: Water cooling containers, if possible, move the containers from the fire to an open space. Extinguishing agents: water
spray, foam, carbon dioxide, dry powder, sand.
Part VI: Emergency Response to Leakage
Emergency treatment: Rapidly evacuated personnel from leaking contaminated areas to safe areas, and isolated and strictly restricted access.
Cut off the fire. It is recommended that emergency personnel wear self-contained positive pressure breathing apparatus
and wear anti-static overalls. If it is a liquid. Cut off the leak as much as possible. Prevent restricted space such as
sewers and flood drains. Small leak: Absorb with dry sand or similar material. A lot of leaks: constructing
embankments or digging pits for containment. Cover with foam to reduce vapor disasters. Use explosion-proof pump
to transfer to tanker or special collector, recycle or transport to waste disposal site for disposal. If it is a solid, collect it
in a dry, clean, covered container and ship it to a waste disposal site for disposal.
Part VII: Handling and Storage
Operational notes: Closed operation. Closed operation provides good natural ventilation. Operators must be specially trained to strictly
observe the operating procedures. It is recommended that operators wear self-priming filter-type dust masks, chemical
safety glasses, and anti-static overalls. Keep away from fire and heat sources and smoking is prohibited in the
workplace. Use explosion-proof ventilation systems and equipment. Prevent vapors from leaking into the workplace
air. Avoid contact with oxidants. It should be lightly loaded and unloaded during handling to prevent damage to the
packaging and containers. Equipped with the appropriate types and quantities of fire-fighting equipment and
emergency response equipment. Empty containers may be harmful residues.
Storage note: Store in a cool, ventilated warehouse. Keep away from fire and heat sources. Keep the container sealed. should be kept
away from oxidizer, do not store together. Equipped with the appropriate variety and quantity of fire equipment.
Storage areas should be equipped with spill emergency treatment equipment and suitable containment materials.

Part VIII: Contact Control/Personal Protection


Occupational exposure
limits
China MAC (mg/m3): 6 (phenol-based plastic), 0.1 (based on phenol), 0.05 (formaldehyde)
Former Soviet Union MAC 0.1 (by phenol), 0.05 (by formaldehyde)
(mg/m3):
TLVTN: No standard established
TLVWN: No standard established
Monitoring method:
engineering control: Closed operation. Provides good natural ventilation.
Respiratory protection: Generally do not need special protection, high-consistency contact can wear self-absorption filter dust masks.
Eye protection: Wear chemical safety goggles when necessary.
Physical protection: Wear anti-static overalls.
Hand protection: Wear general work protective gloves.
Other protection: Smoking is strictly prohibited on the job site. Maintain good hygiene habits.
Part 9: Physical and Chemical Properties
The main ingredients: Phenolic Resin Heat of combustion no data
(kJ/mol):
Appearance and traits: According to the chemical structure and Critical temperature no data
molecular weight, there are liquids and solids. (°C):
pH: Critical pressure (MPa): no data
Melting point (°C): no data Octanol/water partition no data
coefficient logarithm:
Boiling point (°C): no data Flash point (°C): no data
Relative density (water = no data Ignition temperature 420 (powder )
1): (°C):
Relative vapor density (air no data Explosion limit% (V/V): no data
= 1):
Saturated vapor pressure no data Lower explosion limit%
(kPa): (V/V):
The main purpose: Used as laminating plastics, pressed plastic Solubility: Soluble in ethanol。
powders, glass fiber reinforced plastics and
adhesives for the bonding industry, coating
industry, etc.
Other physical and
chemical properties:
Part 10: Stability and Reactivity
stability: stable。
Incompatible materials: Strong oxidants。
Avoid contact conditions: High fever
Polymerization hazards:
Decomposition products:
Part 11: Toxicology Information
Acute toxicity: LD50: No data Mutagenicity:
Subacute and chronic Teratogenicity:
toxicity:
Irritability: Carcinogenicity:
Sensitization:
Part 12: Ecological Information
Ecotoxicological toxicity: This product is not a poison product. Bioaccumulation or
bioaccumulation:
Biodegradability: Other harmful effects: No data
Non-biodegradability:

Part 13: Disposal


Nature of waste:
Disposal methods: Before disposal, refer to national and local regulations. It is recommended that it be disposed of by incineration.
Disposal considerations:
Part 14: Transport Information
Dangerous goods number: ——
UN number: ——
Packaging logo: ——
Packing category: ——
method of packing: ——
Transportation The transport vehicles shall be equipped with fire extinguishers and emergency response treatment equipment of
considerations: corresponding types and quantities during transport. It is best to transport in the morning and evening in summer. The
tank (tank) used for transportation shall have a grounding chain, and a hole partition may be arranged in the tank to
reduce the static electricity generated by the vibration. It is strictly prohibited to mix and transport with oxidants, edible
chemicals, etc. Avoid exposure, rain, and high temperature during transportation. Stopovers should stay away from fire,
heat, and high temperature areas. The exhaust pipe of the vehicle carrying this item must be equipped with a
fire-retardant device, which prohibits the use of mechanical equipment and tools that generate sparks. It is forbidden to
let slip on railway transportation. It is strictly forbidden to use wooden boats and cement ships for bulk transportation.
Part 15: Regulatory Information
Regulatory Information This product is not in the Catalogue of Hazardous Chemicals (2015 Edition) and it is not a dangerous chemical; this
product is not subject to the United Nations “Rules for the Recommendations on the Transport of Dangerous Goods”
(19th revised edition) and is not classified as hazardous. Products.
Part 16: Other Information
references:
Form filling department:
Data review unit:
Modify the description:
other information:

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