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Quality
1
National University of Science & Technology (NUST)
Introduction to Air Quality Impacts
An air pollutant is a gas, liquid droplet, or solid particle which, if
dispersed in the air with sufficient concentration, poses a hazard to
flora, fauna, property, and climate
Air pollution, a visible environmental side effect of transportation,
has become a public health concern for millions of urban residents
worldwide
Transportation or “mobile” sources of air pollution, particularly
motor vehicles, are a primary source of local carbon monoxide
problems and are considered the main cause of excess regional
photochemical oxidant concentrations (Air pollutants formed by
the action of sunlight on oxides of nitrogen and hydrocarbons)
Transportation vehicles typically emit carbon monoxide, nitrogen
oxides, small particulate matter, and other toxic substances that
can cause health problems when inhaled
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Introduction to Air Quality Impacts
Air pollution also has adverse effects on forests, lakes, and rivers
The contribution of transportation vehicle use to global warming
remains a cause for much concern as anthropogenic (human)
impacts on the upper atmosphere become increasingly evident
In this chapter we discuss:
Air pollution sources
Adverse impacts of air pollution
Factors that affect pollutant emissions and concentrations
Estimation of pollutant emissions and concentrations
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Air Pollutants – Types, Sources, and Trends
CO -- Carbon Monoxide
HC -- Hydrocarbons
SOx – Sulfur oxides
NOx – Nitrous Oxides
Particulate matters -- include dust & smoke
Heavy metals - Pb, Cd, Zn, and Cu
CO2 -- Carbon Dioxide (a single tank produces 300-400 pounds of
CO2)
CFC -- Chlorofluorocarbons
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Air Pollutants – Types, Sources, and Trends
Benzene (motor vehicles emit about 15% of world’s
benzene)
Aldehydes
Asbestos
Ozone (03)
Acidic Depositions
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Air Pollutants – Types, Sources, and Trends
SOURCES
- Natural sources: volcanoes, forest fires, etc.
- Man-made (anthropogenic) sources
Stationary sources: Industrial plants, etc.
Mobile sources: transportation, etc.
Power generation
Fuel use
Slash & burn agricultural practices
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Air Pollutants – Types, Sources, and Trends
Primary vs. Secondary
Primary air pollutant: are those emitted directly into the
atmosphere and include carbon monoxide, hydrocarbons
sulfur oxides, nitrogen oxides, and particulate matter
Secondary air pollutants: such as ozone and acidic
depositions, are those formed in the atmosphere as a
result of physical and chemical processes (such as
hydrolysis, oxidation, and photochemistry) on primary
pollutants
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Air Pollutants – Types, Sources, and Trends
Criteria vs. Greenhouse
Criteria air pollutants: are a set of air pollutants that cause
smog, acid rain, and other health hazards. Are typically
emitted from many sources in industry, mining,
transportation, electricity generation and agriculture. In most
cases they are the products of the combustion of fossil fuels or
industrial processes (CO, SOX, NOX, etc)
Greenhouse gases (GHG): A greenhouse gas (GHG), is that
gas in atmosphere that absorbs and emits radiation within the
thermal infrared range. This process is the fundamental cause
of the greenhouse effect.
Water vapor , Carbon dioxide , Methane, Nitrous oxide, Ozone ,
CFCs 8
Air Pollutants – Types, Sources, and Trends
o The ground is heated by visible and
(some) infrared light from the Sun.
o The heated surface emits infrared light.
o The primary components of Earth’s
atmosphere, N2 and O2 do not have
absorption in the IR wavelength range,
therefore, do not have a significant role
in setting the surface temperature of the
planet…
o Greenhouse gas are efficient in
absorbing IR light(H2O, CO2).
o Greenhouse gases trap (absorb and re-
emit) the infrared radiation, increasing
the temperature of the atmosphere…
Air Pollutants – Types, Sources, and Trends
20
18
16 Carbon Monoxide
Emission(millions of short tons)
14 (*10)
Volatile Organic
12
Compounds
10 Nitrogen Oxides
8
6 Sulphur Dioxide
4
Particulate
2 Matter
0
1970 1980 1990 1995 2000 2001 2002
Year
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Air Pollutants – Types, Sources, and Trends
CO
Non
Transpor
tation
44%
Transpor NOx
tation
56%
Transpor
tation
Non 44%
VOCs Transpor
tation
56%
Transpor
tation
37%
Non
Transpor
tation
63% 11
The Process of Air Pollution
Emission Dispersion
Concentration
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Emissions
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Emissions
• Emission. The overall magnitude of emissions depends on the
number of emitting sources, the diversity of source types, the nature
and scale of activity at the polluting source, and the emission
characteristics. For instance, more pollutants are emitted by motor
vehicles at higher altitudes, due to inefficient combustion caused by
air thinness.
• Mobile emission. A mobile source of air pollution is one that is
capable of moving from one place to another under its own power,
such as a motorized vehicle. The total air quality in an area is
measured in terms of the ambient concentration of pollutants that
are emitted by mobile and stationary sources.
• Emission factors. An emission factor is an average estimate of the
rate at which a pollutant is released into the atmosphere as a result
of some activity (such as motor vehicle operation) in terms of
activity level such as VMT (vehicle-miles of travel) or VHT (vehicle-
hours traveled) for motor vehicles.
Air Quality Estimation
Total Emissions
= Emissions per vehicle per mile * number of vehicles * nr. of miles
Total Emissions
= Emissions per vehicle per mile * number of vehicles * nr. of miles
BUT …
Total Emissions
= Emissions per vehicle per mile * number of vehicles * nr. of miles
Pollutant Dispersion
Factors Affecting Pollutant Dispersion & Concentration
• Magnitude of Emissions
• Meteorological Conditions
– Wind Speed, Wind Direction, Mixing Speed
– Temperature
• Topography & Urban Spatial Form
• Altitude
• Physical Mixing, Deposition & Chemical Reactions
Dispersion Models
– Box Model
– Gaussian Plume Model
– Numerical Model
The Box Model for Predicting Pollutant Dispersion
a 2 b2 H 2
V
Average Time Taken to be
Transported =
a 2 b2 H 2
2V
The Box Model - Assumptions
(c) From (b), all pollutant emissions would have completely dispersed out of the
mixing box in 1.21 hours That is, residual concentration after 1.21 hrs is zero.
Thus, if 1,000g of pollutant are released in bursts every two hours, the maximum
concentration will simply be:
Calculating Concentration
Spatial
Dimension
Global
National
Regional Temporal
Local Dimension
– ROW
– Corridor
– Community/Local System
– Region
– Global
Spatial Dimensions
of Air Quality Impacts of Transportation Projects and Policies