CRC HANDBOOK

of
THERMOPHYSICAL
and
THERMOCHEMICAL
DATA

David R. Lide
Former Director, Standard Reference Data
National Institute of Standards and Technology

Henry Kehiaian
Research Director
University of Paris 7-CNRS
Institute of Topology and System Dynamics

CRC Press
Boca Raton New York
 TABLE OF CONTENTS

Introduction vii
Instructions on Using the Diskette ix

1. SYMBOLS, UNITS, AND TERMINOLOGY

1.1. Names and Symbols for Thermodynamic and Transport Properties 3
Table 1.1.1. Recommended Names and Symbols 5

1.2. SI Units and Conversion Factors 9

Table 1.2.1. Names and Symbols for the SI Base Units 11
Table 1.2.2. SI Derived Units with Special Names and Symbols 11
Table 1.2.3. SI Prefixes 12
Table 1.2.4. Conversion Factors 12

1.3. International Temperature Scale of 1990 17

Table 1.3.1. Defining Fixed Points of the ITS-90 19
Table 1.3.2. Values of Coefficients in the Vapor Pressure Equations for Helium 19

2. THERMODYNAMIC PROPERTIES OF PURE SUBSTANCES

2.1. Physical Constants and Phase Behavior 23
Table 2.1.1. Summary of Physical Constants of Important Substances 25
Table 2.1.2. Solid-Liquid-Gas Triple Point of Pure Substances 45
Table 2.1.3. Vapor Pressure and Boiling Temperature of Liquids 49
Table 2.1.4. Sublimation Pressure of Solids 61
Table 2.1.5. Influence of Pressure on Melting Temperature 63

2.2. Volumetric Properties 67

Table 2.2.1. Virial Coefficients of Gases 69
Table 2.2.2. Saturated Densities and Molar Volumes of Liquids 81

2.3. Calorimetric Properties of Non-Reacting Systems 87

Table 2.3.1. Ideal Gas Heat Capacity 89
Table 2.3.2. Heat Capacity of Liquids 93
Table 2.3.3. Heat Capacity of Solids 97
Table 2.3.4. Enthalpy of Fusion 99
Table 2.3.5. Enthalpy of Vaporization 109

2.4. Calorimetric Properties Associated with Chemical Reactions 123

Table 2.4.1. Standard State Thermochemical Properties at 298.15 K 125
Table 2.4.2. Thermochemical Properties at High Temperatures 171
Table 2.4.3. CODATA Key Values 197

2.5. Surface Tension 201

Table 2.5.1. Surface Tension of Common Liquids 203

3. THERMODYNAMIC PROPERTIES OF MIXTURES

3.1. Phase Equilibria and Related Topics 209
Table 3.1.1. Isothermal Vapor-Liquid Equilibria and Excess Gibbs Energies of Binary Mixtures 211
Table 3.1.2. Azeotropic Data for Binary Mixtures 331
Table 3.1.3. Liquid-Gas Critical Properties of Binary Mixtures 339
Table 3.1.4. Liquid-Liquid Equilibria in Binary Liquid Mixtures 351

3.2. Volumetric Properties 361

Table 3.2.1. Densities and Excess Volumes of Binary Liquid Mixtures 363
 3.3. Calorimetric Properties 373
Table 3.3.1. Excess Enthalpies of Binary Liquid Mixtures 375
Table 3.3.2. Isobaric Excess Heat Capacities of Binary Liquid Mixtures 393
Table 3.3.3. Activity Coefficients and Partial Molar Excess Enthalpies at Infinite Dilution 399

4. TRANSPORT PROPERTIES
4.1. Viscosity 405
Table 4.1.1. Viscosity of Gases 407
Table 4.1.2. Viscosity of Liquids 409

4.2. Thermal Conductivity 413

Table 4.2.1. Thermal Conductivity of Gases 415
Table 4.2.2. Thermal Conductivity of Liquids 417
Table 4.2.3. Thermal Conductivity of Solids 419

4.3. Diffusion Coefficients 421

Table 4.3.1. Diffusion Coefficients in Gases at a Pressure of 101325 Pa (1 atm) 423
Table 4.3.2. Diffusion Coefficients in Liquids at Infinite Dilution 425
Table 4.3.3. Diffusion Coefficients of Ions in Water at Infinite Dilution 427

5. TABLES OF PROPERTIES OF INDIVIDUAL SUBSTANCES

Table 5.1. Thermophysical Properties of Some Common Fluids 431
Table 5.2. Thermodynamic Properties of Air 441
Table 5.3. Properties of Liquid Water 443
Table 5.4. Density of Standard Mean Ocean Water 445
Table 5.5. Steam Tables 447

INDEXES
Substance List 451
Index 517