INORGANIC CHEMISTRY

Daily Practice Problems

Target JEE 2018
CLASS : XIII MARKS : 36 DATE :25-26/09/2017 TIME : 35 MIN. DPP. NO.-19
Single correct :
Q.1 Choose the correct order of Melting point? [3]
(A) ZnCl2 < HgCl2 (B) CdCl2 < ZnCl2 (C) BeO < BeF2 (D) SiO2 > NaCl

Q.2 Which of the following compound has tetrahedral geometry and have d3s hybridisation? [3]
(A) PH3 (B) SiCl4 (C) MnO4¯ (D) Ni(CO)4

Q.3 How many molecules are linear in following compounds but does not have anylone pair on central atom.
ICl2¯, CO2, XeF2, [I(CN)2]¯, BrF2¯ , [ I2(CN)]+, I3¯, C2H2, SnCl2, OF2, HgCl2 [3]
(A) 4 (B) 2 (C) 5 (D) 3

Q.4 The correct order of boiling point is : [3]

(A) He > Ne > Ar (B) HF < NH3 < H2O < H2O2
(C) CCl4 > Cl2 (D) ICl  Br2

More than one correct :

Q.5 About the following structure : [4]
F F O O 2– O O
Z B B X C C Y N N
F F O P O O Q O
choose the correct options :
(A) Y > X (B) X > Z (C) P > Q (D) X > Y

Q.6 Which of the following species have bond order of 2 as well as diamagnetic? [4]
(A) CN+ (B) BN (C) SiF+ (D) I2+

Q.7 Select the correct statement according to MOT - [4]

(A) If bond order is zero or negative then molecule cannot exist.
(B) S2 molecule is paramagnetic due to presence of two unpaired electrons.
(C) In O2 molecule * 2p y orbital have unpaired electron.
(D) If sp mixing is present then B2 molecule is paramagnetic.

Q.8 Which of the following inert gas species are non planar having at least four atom in a plane ? [4]
(A) XeF6 (B) XeF5 (C) XeF5 (D) SF6

Q.9 Select the correct statement(s): [4]

(A) CH3 – C–CH3 angle in (CH3)2C = CH2 is smaller and the CH3 – C = CH2 angle is larger than the
trigonal 120°.
(B) O – I – F angle is less than 90° (89°) in IOF4–.
(C) In SeOCl2, Cl – Se – Cl angle is less than the Cl – Se – O angle
(D) POCl3 is tetrahedral with a double bond between P and O. There is no lone pair on central atom.

Q.10 Which of the following species are octahedral? [4]

(A) PF6– (B) Sb(OH)6– (C) SbBr6– (D) BrF5