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Innovative Food Science and Emerging Technologies 34 (2016) 86–99

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Innovative Food Science and Emerging Technologies

journal homepage: www.elsevier.com/locate/ifset

Thermal energy storage based solar drying systems: A review


Karunesh Kant a,⁎, A. Shukla a, Atul Sharma a, Anil Kumar b,c, Anand Jain c
a
Non-Conventional Energy Laboratory, Rajiv Gandhi Institute of Petroleum Technology, Raebareli, U.P., India
b
Energy Technology Research Center, Dept. of Mech. Engineering, Faculty of Engineering, Prince of Songkla University, 15 Karnjanavanich Rd., Hat Yai, Songkhla 90110, Thailand
c
Energy Centre, Maulana Azad National Institute of Technology, Bhopal, Madhya Pradesh, India

a r t i c l e i n f o a b s t r a c t

Article history: Solar dryer based on thermal energy storage materials is quite effective for continuously drying agriculture
Received 7 October 2015 and food products at steady state in the temperature range (40 °C–60 °C). Such dryers have globally become a
Received in revised form 22 December 2015 potential viable substitute to the solar dryers based on fossil fuel, due to the utilization of clean energy resources
Accepted 13 January 2016
and cost-effectiveness. Storage materials utilized in these dryers can store energy during the sunshine hour and
Available online 27 January 2016
deliver the stored energy during off-sunshine. It reduces the existing load on the gap between energy demand
Keywords:
and supply, hence plays a vital role in energy sustainability. A number of studies have been done in last few
Solar dryer decades for drying agriculture and food products with a solar dryer based on thermal energy storage concept.
Thermal energy storage This paper mainly presents a review on the important contributions made so far in the field of solar drying
Solar energy systems based on the thermal energy storage medium, with a focus on recent updates in thermal energy storage
Phase change materials technology available in terms of materials capable of storing heat as sensible and latent heat.
Industrial relevance:

1. Solar energy defuses in the nature and provides low grade heat. This characteristic of solar energy is good for
drying at low temperature, high flow rate with low temperature rise.
2. Worldwide, there is huge demand of efficient solar dryers utilized by various food and agricultural products.
3. Solar energy based solar dryers are not only cost efficient but also can be used across the globe, specially
contributing to cleaner energy resources.
4. Novel system designs and techniques related to solar dryers are being explored to increase the efficiency and
performance of solar dryers, which could in turn be much more commercially utilized by the end user.
5. Phase change materials can store energy during sunshine hours and retrieve during off-sunshine hours for
drying purpose, hence solar dryers embedded with such materials could be quite useful.

© 2016 Elsevier Ltd. All rights reserved.

Contents

1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87
2. Thermal energy storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88
2.1. Sensible heat storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88
2.2. Latent heat storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89
2.3. Thermochemical energy storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89
3. Phase change materials for thermal energy storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89
4. Solar dryer systems embedded with thermal energy storage materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89
4.1. Solar dryer systems with sensible heat storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90
4.1.1. Indirect solar dryers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90
4.1.2. Greenhouse dryers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90
4.2. Solar dryer with latent heat storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90
4.2.1. Indirect solar dryer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90
4.2.2. Greenhouse dryer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96
4.2.3. Hybrid solar dryer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 97

⁎ Corresponding author at: Non-Conventional Energy Laboratory, Rajiv Gandhi Institute of Petroleum Technology, Raebareli 229316, U.P., India.
E-mail address: k1091kant@gmail.com (K. Kant).

http://dx.doi.org/10.1016/j.ifset.2016.01.007
1466-8564/© 2016 Elsevier Ltd. All rights reserved.
K. Kant et al. / Innovative Food Science and Emerging Technologies 34 (2016) 86–99 87

5. Use of software in solar drying systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 97


6. Summary and conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 97
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98

1. Introduction pressure on very many fields related to energy production as well as en-
ergy transmission. Solar energy is the most abundant energy resource
The drying is the basic process to reduce moisture from a product, available on the regular basis (during day time) which can become
which is one of the oldest techniques used for food or agricultural the most efficient and feasible way out to deal with the increasing
products storage (Augustus Leon, Kumar, & Bhattacharya, 2002). Food energy demand and supply gap. Particularly, to facilitate the drying of
products, particularly fruits and vegetables require hot air in the food and agriculture products, the solar energy is most suitable but
temperature range of 45–60 °C for safe drying i.e., drying the products intermittent in nature due to non-availability of solar radiation in the
so as to keep their edible and nutritious properties intact. Requisite night. Therefore thermal energy storage facility is required to store
moisture content and superior quality of the product can be achieved solar energy to be used in off sunshine hours (Saxena & El-Sebaii,
under controlled conditions of temperature and humidity (Sharma, 2015; Shalaby, Bek, & El-Sebaii, 2014).
Colangelo, & Spagna, 1995). In the case of vegetables, which is the Solar drying technique facilitates domestic as well as industrial
main nutrients product, 50% of wet (Wahidi & Rohani, 1996) (Wahidi sector for number of food and agricultural products, so as;
& Rohani, 1996) (Wahidi & Rohani, 1996) (Wahidi & Rohani, 1996)
(Wahidi & Rohani, 1996) (Wahidi & Rohani, 1996) vegetables — to make the preservation process much easier,
(i.e., peels) are removed as unwanted items while cooking due to its — to develop a certain product much more usable,
higher moisture content (Wahidi & Rohani, 1996). Dried peels of — to increase storage capacity and cost-effective transportation, and
vegetables can be further used for the feeding of the animals. Moreover, — to harness direct or indirect ecological benefits.
the transportation cost of vegetables is also reduced due to reduction Hence, an efficient solar dryer system could be of much use for the
in the weight and size of such dried product. It has been studied that larger benefit of the mankind. This certainly requires the challenging
lack of appropriate technology, inappropriate farming, fertilization, the task of developing novel solar dryers with efficient energy consumption
non-existence of marketing channels, inappropriate transportation, for the specific product. Solar energy is considered quite effective for
high post-harvest losses etc., cause a food loss in the range of 10 to food drying, due to the following reasons:
40% (Esper & Mühlbauer, 1998). Hence, food preservation is the need
of the hour to reduce the food loss and drying is widely accepted as an • Solar energy diffuses in nature easily and provides low-grade heat.
important tool in this direction, since a long time. Therefore, efficient These characteristics of solar energy are good for drying food products
drying technologies are required to reduce moisture content from at low temperature, high flow rate with the gradual and low-
food and vegetables for preservation. Well-designed solar dryers may temperature rise.
provide a much-needed suitable substitute for drying of some of the • The irregular nature of solar radiation will not affect the drying perfor-
agricultural crops in developing countries (Mahapatra & Imre, 1990; mance at low temperature. Even the energy stored in the product
Sodha & Chandra, 1994; Ekechukwu & Norton, 1999; Hossain, Woods, itself will help in removing excess moisture during the period of no
& Bala, 2005; Zhiqiang, 2005). Application of solar energy in the agricul- sunshine.
tural area has enlarged due to fluctuation in the price of fossil fuels, • Solar energy is available at most of the required sites of drying food
environmental concerns and expected running down of conventional products.
fossil fuels. Fig. 1 shows the drastic increase in energy consumption • The solar dryer for food products could also be put to other multiple
being experienced in the food and related sector. This is putting a usages, such as space heating.

Source: Central Electricity Authority 2015

Fig. 1. Sector wise electricity consumption growth in India (GWh).


88 K. Kant et al. / Innovative Food Science and Emerging Technologies 34 (2016) 86–99

Table 1 there is no sun in the night hours. Available solar energy also depends
Initial and final moisture content of the product (Garg, 2000). on the metrological condition of location and climate. Reliability of
Product Moisture content % Maximum temperature solar energy can be improved by storing its share when it is in excess
Initial Final
allowable for drying (°C) to the requirement, and using the same stored energy, whenever
needed. Solar energy can be stored by thermal, electrical, chemical,
Potatoes 75 13 75
and mechanical methods (Mahlia, Saktisahdan, Jannifar, Hasan, &
Chilies 80 5 65
Apples 80 24 70 Matseelar, 2014; Hasnain, 1998; Zalba, Marı́n, Cabeza, & Mehling,
Apricot 85 18 65 2003). System operability and utility of solar dryer can be enhanced
Grapes 80 15–20 70 by storing solar energy in the form of thermal energy in thermal energy
Bananas 80 15 70 storage materials. The initial moisture content and final moisture
Guavas 80 7 65
Opra 80 20 65
content along with the maximum temperature at which product may
Pineapple 80 10 65 be dried are very crucial for safe drying, depending on the specific
Tomatoes 96 10 60 product, which is given in Table 1.
Brinjal 95 6 60
Millet 21 14 NA
2. Thermal energy storage
Spinach 80 10 NA
Cassava 62 17 NA
Cassava leaves 80 10 NA Thermal energy can be stored in well-insulated materials as a
Fish raw 75 15 30 change in internal energy of the material, as sensible heat, latent
Fish water 75 15 50 heat and thermochemical or combination of these. Fig. 2 displays an
Onion ring 80 10 55
Prunes 85 15 55
overview of the major techniques involved for solar thermal energy
Peaches 85 18 65 storage.
Mulberries 80 10 65
Figs 80 24 NA 2.1. Sensible heat storage
Yams 80 10 65
Nutmeg 80 20 65
Sorrel 80 20 65 In the sensible heat storage, thermal energy is stored by increasing
Coffee 50 11 NA the temperature of a liquid or solid, using the heat capacity and change
Coffee beans 55 12 NA in temperature of the material during the process of charging and
Cocoa beans 50 7 NA discharging. The amount of heat stored depends on the specific heat of
Cotton 50 9 75
Cotton seeds 50 8 75
the medium, the temperature change and the amount of storage
Copra 30 5 NA material. Generally, water appears to be the best SHS materials due to
Ground nuts 40 9 50 its high specific heat and inexpensive. The amount of energy stored is
Silk cocoons 68–70 10–12− 80 determined by the temperature change of the material and can be
Timber
stated in the form of
Foliage trees 25–35 17–20 50
Conifers 30–40 010–015 50 Z T2
Soaked trees 60 12 50
E¼m C p dT ð1Þ
Mahogany 35 11 NA T1
Leather 50 18 35
Fabrics 50 8 75
¼ mC p ðT 2 −T 1 Þ ð2Þ

Solar energy is abundantly and freely available, environmentally where, m is the mass and Cp is the specific heat at constant pressure. T1
clean so it is recognized as one of the most promising alternative energy and T2 signify the lower and upper temperature levels in the middle of
resource options. However, solar energy is intermittent in nature, as which the storage operates. The difference (T2–T1) is denoted as the

Fig. 2. Different types of thermal storage of solar energy (Bal, Satya, & Naik, 2010).
K. Kant et al. / Innovative Food Science and Emerging Technologies 34 (2016) 86–99 89

temperature swing (Gogus, 2009). Table 2 gives a list of selected solid–


liquid materials which can be used for sensible heat storage based
applications.

2.2. Latent heat storage

Latent heat storage (LHS) stores thermal energy at the time of phase
transition from solid to liquid or liquid to vapor in the form of latent heat
of fusion and vaporization respectively. Phase change materials (PCMs)
have been widely studied and used for wide range of applications
(Sharma, Tyagi, Chen, & Buddhi, 2009) due to its property of heat
absorption and discharging during melting and solidification process
respectively. Fig. 3 shows the temperature variation with the amount
of stored heat. The temperature of storage materials is increased in the
sensible heating and it became constant during the transition phase
and stores large amount of energy at this time. Heating a material causes
a phase change (usually melting), storing energy in the form of latent
Fig. 3. Sensible and latent heat storage.
heat, commonly referred as latent heat storage process. The amount of
energy stored E, in this case, hangs on the mass (m) and latent heat of
fusion (λ) of the material. 3. Phase change materials for thermal energy storage

E ¼ mλ ð3Þ Amongst above thermal heat storage techniques, latent heat thermal
energy storage is particularly more attractive to other due to its ability
to provide high-energy storage density per unit mass and per unit
The storage functions isothermally at the melting point of the mate-
volume in a more or less isothermal process, i.e., store heat at a constant
rial. If isothermal operation at the phase change temperature is difficult,
temperature corresponding to the phase-transition temperature of
the system operates over a range of temperatures T1 to T2 that includes
PCM. Thus, PCMs release large amounts of energy upon freezing in the
the melting point. The sensible heat contributions have to be considered
form of latent heat and absorb equal amounts of energy from the imme-
and the amount of energy stored is given by
diate environment upon melting. Number of PCMs were investigated by
28 9 8T 93 different investigators for different applications (Sharma, Tyagi, Chen, &
>
<ZT >
= <Z2 = Buddhi, 2009; Sharma, Dong, Buddhi, & Un, 2005; Sharma, Shukla, Chen,
6 7
E ¼ m4 C ps dT þ λ þ C pl dT 5 ð4Þ & Dwivedi, 2013; Sharma, Shukla, Chen, & Wu, 2014; Abhat, 1983;
>
: >
; : ;
T1 T Baetens, Jelle, & Gustavsen, 2010). A classification of PCMs is shown in
Fig. 4. Various types of PCMs studied and used for different applications
with their operating temperature ranges are tabulated in Table 4 which
where, Cps and Cpl denote the specific heats of the solid and liquid phases
can be used for integrating PCM with the solar dryer in the appropriate
and T ⁎ represents the melting temperature of PCM. Comparison of var-
temperature range. During sunshine hours, the maximum temperature
ious heat storage media has been given in Table 3.
within the drying chamber varies from 40 °C to 54 °C (Devahastin &
Pitaksuriyarat, 2006a, 2006b).
2.3. Thermochemical energy storage

4. Solar dryer systems embedded with thermal energy storage


Thermochemical systems rely on the energy absorbed and released
materials
in breaking and reforming molecular bonds in a completely reversible
chemical reaction. In this case, the heat stored depends on the amount
The entire review for solar drying with thermal energy storage can
of storage material, the endothermic heat of reaction, and the extent
be discussed in two subsections. In the first section, authors have
of conversion.
reviewed, solar drying systems using sensible heat storage methods
and discussion related to solar dryers based on latent heat storage
Q ¼ ar mΔhr ð5Þ
methods has been given in the subsequent section.

Table 3
Table 2 Comparison of various heat storage media (stored energy = 106 kJ = 300 kWh; ΔT = 15 K)
A list of selected solid–liquid materials for sensible heat storage (Sharma, Tyagi, Chen, & (www.eolss.net/ebooks/sample%20chapters/c08/e3-14-02-00.pdf).
Buddhi, 2009).
Heat storage material
Medium Fluid type Temperature Density Specific
Sensible heat Phase change
range (°C) (kg/m3) heat (J/kg K)
storage materials
Rock 20 2560 879
Property Rock Water Organic Inorganic
Brick 20 1600 840
a a
Concrete 20 1900–2300 880 Latent heat of fusion (kJ/kg) 190 230
Water 0–100 1000 4190 Specific heat (kJ/kg) 1.0 4.2 2.0 2.0
Caloriea HT43 Oil 12–260 867 2200 Density (kg/m3) 2240 1000 800 1600
Engine oil Oil Up to 160 888 1880 Storage mass for storing 106 kJ (kg) 67,000 16,000 5300 4350
Ethanol Organic liquid Up to 78 790 2400 Relative massb 15 4 1.25 1.0
Proponal Organic liquid Up to 97 800 2500 Storage volume for storing 106 kJ (m3) 30 16 6.6 2.7
Butanol Organic liquid Up to 118 809 2400 Relative volumeb 11 6 2.5 1.0
Isotunaol Organic liquid Up to 100 808 3000 a
The latent heat of fusion is not of interest for sensible heat storage.
Isopentanol Organic liquid Up to 148 831 2200 b
Relative mass and volume are based on latent heat storage in inorganic phase change
Octane Organic liquid Up to 126 704 2400
materials.
90 K. Kant et al. / Innovative Food Science and Emerging Technologies 34 (2016) 86–99

Fig. 4. Classification of phase change materials.

4.1. Solar dryer systems with sensible heat storage 4.1.2. Greenhouse dryers
Ayyappan and Mayilsamy (2012) developed a natural convection
4.1.1. Indirect solar dryers solar tunnel dryer integrated with rock bed as sensible heat storage ma-
Jain (2007) carried out a study on solar crop drying with reversed terial to test its performance for copra drying. The experiments were
absorber plate type collector having natural air flow. Thermal storage carried out with and without the integration of heat storage material.
materials affect natural mass flow rate in the drying system. The ther- The temperature gradient inside the tunnel dryer is about 10–25 °C
mal model was developed based on energy equation. The reversed during the clear day and 7–12 °C during off-sunshine hours, which is
absorber, packed bed, inclined absorber and dryer are shown in Fig. 5. quite sufficient to dry agricultural commodities. The dryer reduces the
The absorber plate with built-in thermal storage (Aboul-Enein, El- moisture content of copra from 52% (w.b.) to 7.1% (w.b.) in 54 h and
Sebaii, Ramadan, & El-Gohary, 2000) is inclined at 30°. 1 m length and 60 h respectively with and without the heat storage material. It
1 m breadth reversed absorber plate having 0.15 m packed bed could produces 85% milling copra grade 1 (MCG1). In open sun drying,
dry 95 kg of onion from a moisture content of 6.14–0.27 kg water/kg moisture content reduces from 52.3% (w.b.) to about 7.1% in 153 h
of dry substance in a 24 h drying period. In this type of solar dryer, no with an average of 53% MCG1. The average solar tunnel dryer thermal
external power was required to operate dryer. Air flow takes place nat- efficiency estimated to be about 15%. The use of heat storage material
urally due to the thermosyphon effect. Mohanraj and Chandrasekar increases the dryer efficiency by 2% to 3%. Ayyappan, Mayilsamy, and
(2009) carried out an experimental study of chili drying on indirect Sreenarayanan (2015) conducted an experiment with natural convec-
forced convection solar dryer integrated with different sensible heat tion solar greenhouse dryer using different sensible heat storage
storage materials as shown in Fig. 6. Solar air heater consists of the materials (concrete, sand and rock-bed) in order to study their thermal
glass cover, copper absorber plate painted with black paint. The performance. For both sand and rock-bed, 4″ thickness was found to be
gap between absorber plate and insulation is filled with sand optimum as it provides better drying environment both during day and
mixed with aluminum scraps to store the heat during sunshine night. The dryer reduced the moisture content of coconuts from 52
hours and to obtain hot air during off-sunshine hours. The dryer is (w.b.) to 7% (w.b.) using concrete as heat storage material in 78 h saving
capable of holding about 50 kg of chili per batch. The drying chamber 55% of drying time compared to open sun drying which takes 174 h for
was isolated with glass wool of 10 mm width. The solar air heater reducing the moisture content to the same level. The sand took 66 h
was tilted to an angle about 25° with respect to horizontal surface saving 62% of drying time whereas rock-bed took only 53 h thereby
(Shariah, Al-Akhras, & Al-Omari, 2002). Integration of storage mate- saving 69% of drying time compared to open sun drying. The efficiency
rials increases the drying time by about 4 h per day and maintain of the dryer was found to be 9.5, 11 and 11.65% using concrete, sand
consistent air temperature. The chili was dried from initial moisture and rock-bed respectively.
content 72.8% to the final moisture content about 9.2% and 9.7% (wet
basis) in the bottom and top trays respectively. Jain and Jain (2004) 4.2. Solar dryer with latent heat storage
presented a transient analytical model for inclined multi-pass solar
air heater with inbuilt thermal storage and attached with the deep 4.2.1. Indirect solar dryer
bed solar dryer as shown in Fig. 7. Dryer was evaluated for drying Devahastin and Pitaksuriyarat (2006a), (2006b) investigated the
paddy crop in the month of October for climate condition of Delhi feasibility of latent heat storage (LHS) with paraffin wax as a PCM to
(India). Jain (2005) presented an analysis of multi-tray crop drying store surplus solar energy and discharge it when the energy availability
attached to an inclined multi-pass solar air heater with inbuilt ther- is inadequate or not available. Heat transfer characteristics, temperature
mal storage. Multi-tray dryer attached with solar air heater (Jain & profiles as well as the effects of the inlet air temperature and velocity on
Jain, 2004). The grain temperature increased with the increase in the charge and discharge periods were investigated. A schematic
the collector area and tilt angle of solar air heater up to its certain diagram of the experimental set-up is shown in Fig. 8(a). PCMs are
critical value. The thermal energy storage gets affected during the stored in LHS tank, the detailed sketch of LHS tank is shown in
off-sunshine hour and proposed mathematical model is useful Fig. 8(b). PCM solidifies from outer surface to inner due to heat loss
for evaluating the performance of solar air heater and predicting from surrounding. The amount of extractable energy per unit mass
moisture content, grain temperature, humidity of drying air and flow rate of inlet ambient air was 1920 and 1386 kJ min kg−1 when
drying rate in the grain bed. Hawlader, Chou, Jahangeer, Rahman, using inlet air velocity of 1 and 2 ms−1, correspondingly. PCMs could
and Lau (2003) carried out a study on solar-assisted heat pump save energy during drying of sweet potato up to 34–40%, when using
dryer and water heater. The performance indices considered to inlet air velocity of 2 and 1 ms−1, correspondingly.
evaluate the performance of the system are solar fraction (SF) and Shanmugam and Natarajan (2007) investigated the performance of
coefficient of performance (COP) with and without a water heater. an indirect forced convection and desiccant integrated solar dryer
The values of COP, obtained from the simulation and experiment [shown in Fig. 9(a, b)] for drying of green peas and pineapple slices
are 7.0, and 5.0, respectively, whereas the solar fraction (SF) values with and without the reflective mirror. The system is operated in two
of 0.65 and 0.61 are obtained from simulation and experiment, modes, sunshine hours and off-sunshine hours. During sunshine
correspondingly. hours, the hot air from the flat plate collector is forced to the drying
Table 4
PCMs and their properties which can be used for drying purpose.

Compound Tm (°C) Hf (kJ/kg) Cp (kJ/kg K) k (W/m K) ρ (kg/m3) Ref.

Eicosane 36.6 247 – – 788 Paris, Falardeau, and Villeneuve (1993)


Paraffin C20–C33 48–50 189 2.1 0.21 769 (l) Abhat (1983)
912 (s)
1-Tetradecanol 38 205 – – 825 Hawes et al. (1993)
Paraffin wax 64 173.6 – 0.167 (l) 790 (l) Lane (1980)

K. Kant et al. / Innovative Food Science and Emerging Technologies 34 (2016) 86–99
266.0 0.346 (s) 916 (s) Dincer and Rosen (2002)
Tridecylic 41.8 157 – – – Solé, Neumann, Niedermaier, Martorell, Schossig, and Cabeza (2014)
Methyl-12 hydroxy-stearate 42–43 120–126 – – – Feldman, Shapiro, and Banu (1986)
Elaidic 47 218 – – 851 (l) Hale, Hoover, and Neill (1971)
Galactitolhexa laurate 40.21 157.60 – – – Sarı and Biçer (2012)
Stearyl laurate 42.21 201.03–201.53 1.97 (s) – – Alper Aydın (2013)
2.31 (l)
Methyl eicosanoate 45 230 – – – (Hale, Hoover, and Neill (1971)
Sorbitol 55 166 – – – Barone, Gatta, Ferro, and Piacente (1990)
Stearyl palmitate 57.34 219.74–219.88 1.55 (s) – – Alper Aydın (2013)
1,4 Butanediol stearic acid 58 186 – – – Cabus, Bogaerts, Van Mechelen, Smet, and Goderis (2013)
Glycerol tripalmitate 58.50 185.9 – – – Sarı, Biçer, Karaipekli, Alkan, and Karadag (2010)
Methyl oxalate 54.3 178 – – – Sharma, Tyagi, Chen, and Buddhi (2009)
Palmitic 63 187 – 0.165 (l) 874 (l) Abhat (1983)
61 203.4 – 0.159 (l) 847 (l) Kaygusuz Kamil (2001)
64 185.4 – 0.162 (l) 850 (l) Sari and Kaygusuz (2002)
Stearic 70 203 2.35 (l) 0.172 (l) 941 (l) Abhat (1983)
69 202.5 – – 848 (l) Kaygusuz Kamil (2001)
60–61 186.5 – – – Sari and Kaygusuz (2001)
69.4 199 – – – Hale, Hoover, and Neill (1971)
Nonadecylic 67 192 – – – Sarier and Onder (2012)
Arachidic 74 227 – – – Bailey (1950)
Heneicosylic 73–74 193 – – – Sarier and Onder (2012)
Phenylacetic 16.7 102 – – – Sharma, Tyagi, Chen, and Buddhi (2009)
Acetamide 81 241 – – – Hale, Hoover, and Neill (1971)
Cd(NO3)2·4H2O 59.5 – – – – Naumann and Emons (1989)
Fe(NO3)2·6H2O 60 – – – – Belton and Ajami (1973)
Ba(OH)2·8H2O 78 265.7 – 0.653 (l, 85.7 °C) (Dincer & Rosen, 2002); 1937 (l, 84 °C) (Dincer & Rosen, 2002); Abhat (1983), Dincer and Rosen (2002), Heckenkamp and Baumann (1997),
(Lane, 1980) (Lane, 1980) Naumann and Emons (1989), Lane (1980), and Lindner (1996)
267 (Abhat, – 0.678 (l, 98.2 °C) (Lane, 1980) 2070 (s, 24 °C) (Dincer & Rosen, 2002);
1983) (Naumann & Emons, 1989); (Lane, 1980)
280 – 1.255 (s, 23 °C) (Dincer & Rosen, 2002); 2180 (s) (Abhat, 1983)
(Lane, 1980)

(l) stands for liquid and (s) stands for solid.

91
92
Table 5
Summary of research work carried out by different authors.

Author/Ref. Type of study Type of dryer used for study Crop of drying Thermal energy storage materials Findings
experimental/numerical

K. Kant et al. / Innovative Food Science and Emerging Technologies 34 (2016) 86–99
Jain (2007) Transient analytical model Reversed absorber plate type collector Onions Granite grits Packed bed could dry 95 kg of onion from a moisture
content of 6.14–0.27 kg water/kg of dry substance in a
24 h drying period
Mohanraj and Chandrasekar (2009) Experimental study Indirect forced convection solar dryer Chili Gravel The chili was dried from initial moisture content 72.8%
to the final moisture content about 9.2% and 9.7% (wet
basis) in the bottom and top trays respectively.
Jain and Jain (2004) Transient analytical model Indirect forced convection solar dryer Paddy crop Granite grits The thermal storage effect during the off-sunshine hour.
Jain (2005) Parametric study Indirect forced convection solar dryer Paddy crop Granite grits _
Ayyappan, Mayilsamy, and Sreenarayanan Experimental study Solar tunnel dryer Copra Rock bed _
(2015)
Ayyappan, Mayilsamy, and Sreenarayanan Experimental study solar greenhouse dryer Concrete, sand and rock-bed The efficiency of the dryer was found to be 9.5, 11 and
(2015) 11.65% using concrete, sand and rock-bed respectively
Devahastin and Pitaksuriyarat (2006a), Experimental study Indirect forced convection Sweet potato Latent heat storage (paraffin wax) Energy savings 40% and 34% with air flow rate 1 and 2
(2006b) m/s respectively
Berroug, Lakhal, El Omari, Faraji, and El Numerical modeling Greenhouse dryer Plants Latent heat storage at the north The rise of air temperature 6–12 °C and 10–15% reduced
Qarnia (2011) wall relative humidity.
Shalaby and Bek (2014) Experimental study Indirect solar dryer OcimumBasilicum and Latent heat storage (paraffin wax) The temperature of drying air is higher 2.5–7.5 °C up to
ThevetiaNeriifolia 5 h after sunset with PCM.
Shringi, Kothari, and Panwar (2014) Thermodynamic analysis Indirect solar dryer Garlic cloves _ The initial and final moisture content of garlic cloves are
55.5 (w.b.) % and 6.5% (w.b.) respectively for 8 h
Jain and Tewari (2015) Experimental study Indirect solar dryer Thermal efficiency 28.2% and Payback period is 1.5 year
Reyes, Mahn, and Vásquez (2014) Experimental study Hybrid solar dryer Mushrooms Paraffin wax Moisture content of 1.91 dry basis and thermal
efficiency fluctuate 10% to 21%
Sain, Songara, Karir, and Balan (2013) Experimental study Natural Convection Type Solar Dryer Ginger Paraffin wax Back up period 2. The overall thermal efficiency of the
solar dryer was found to be 22.7%.
Shanmugam and Natarajan (2007) Experimental Study Indirect forced convection Green peas and Pineapple _ The inclusion of reflective mirror on the desiccant bed
slices increases the drying potential by 20%
Dina, Ambarita, Napitupulu, and Kawai Experimental Study Continuous solar dryer Cocoa beans CaCl2 as absorbent and molecular Maximum temperature of drying chamber varied from
(2015) sieve 13× (Na86 [(AlO2)86. 40 °C to 54 °C that is higher than 9–12 °C from ambient
(SiO2)106].264H2O) as adsorbent temperature
K. Kant et al. / Innovative Food Science and Emerging Technologies 34 (2016) 86–99 93

Table 6
Advantage and drawbacks of different types of thermal energy based solar dryers.

Name of solar dryer Advantages Drawbacks

Direct solar dryer • Least expensive • UV radiation can damage food


• Simple
Indirect solar dryer • Products are protected from UV radiation • More complex and expensive than direct sun
• Lesser damage from temperature extremes
Mixed mode solar dryer • Lesser damage from temperature extremes • UV radiation can damage food
• More complex and expensive than direct sun
Hybrid solar dryer • Ability to operate without solar radiation which reduces chances of food loss • Expensive
• Allows better control of drying • Fuel dependence and hence increase in cost
• Fuel mode may be up to 40 times faster than solar drying
Green house solar dryer • Simple structure, low cost, suitable for basic unit to use • Efficiency is very low
• Suitable for the requirements of low drying temperature is low and allows direct • Effective utilization rate of received total solar radiation is
exposure to the sun. only 15% used for moisture evaporation and remaining is
lost to the atmosphere.

chamber for drying the product and simultaneously the desiccant bed dryer is tested with and without PCM. The results indicated that PCM
receives solar radiation directly and through the reflected mirror. In smoothens drying air temperature and also shows that the temperature
the off-sunshine hours, the dryer is operated by circulating the air inside of the solar dryer with PCM is higher, 3.5–6.5 °C than the dryer without
the drying chamber through the desiccant bed by a reversible fan. The PCM after 2:00 pm.Shringi, Kothari, and Panwar (2014)carried out a
inclusion of reflective mirror on the desiccant bed increases the drying thermodynamic analysis of indirect solar air heater for drying garlic
potential by 20%. The useful temperature rise of about 10 °C was cloves with PCMs. The initial and final moisture contents of garlic cloves
achieved with mirror, which reduced the drying time by 2 and 4 h for are 55.5% (w.b.) and 6.5% (w.b.) respectively for 8 h. The energy efficien-
green peas and pineapple, respectively. Also, the pick-up efficiency, cy of drying chamber without and with recirculation of air is varied from
drying rates and average dryer thermal efficiency were relatively higher 43.06 to 83.73%, and 3.98 to 14.95%, respectively, while the exergy
when compared to solar drying and desiccant integrated drying. efficiency corresponding to the energy efficiency of the drying process
Uniform drying in all the trays was achieved with good quality in ranged from 5.01 to 55.30% and 67.06 to 88.24%, respectively.
terms of color and microbiological decay when compared to solar Jain and Tewari (2015) designed and fabricated a solar dryer with
drying. Taste of the dried pineapple was found to be satisfactory. The PCMs. Dryer contained four major parts i.e., flat plate collector, packed
desiccant material is stable even after continuous operation for more bed for thermal storage, drying chamber and natural draft system as
than a year. The dryer can be used for drying various agricultural shown in Fig. 10. This stored energy helped in keeping the drying
products. It can reduce drying time and improve the quality of the temperature ranged between 40 and 45 °C, thus extended the period
dried product. of drying. Experiments showed the good performance of the system
A novel indirect solar dryer was used to study the effect of PCMs on over the night and the thermal efficiency of the dryer was found to be
drying performance by Shalaby, Bek, and El-Sebaii (2014). Dryer 28.2%. Considering the reasonable cost of raw material 20₹ kg−1 and
consists of two air heater, PCMs blower and drying chamber. Solar price of product 400₹ kg−1, the solar dryer was found financially viable
with a payback period of 1.5 years.
Sain, Songara, Karir, and Balan (2013) carried out a study on the
natural convection type solar dryer with latent heat storage. The dryer
was tested under full load and no load condition. The full load perfor-
mance of the system was estimated with ginger. The ginger dehydrated
from moisture content (w.b.) of 74% to 3% in 24 h. The typical daily
drying efficiency was found to be 12.4%. Throughout the no load test,
the collector efficiency varied in the range of 53 to 96% and full load
test in the range of 40 to 55%. And backup period 2 h. The overall
thermal efficiency of the solar dryer was found to be 22.7%.
Dina, Ambarita, Napitupulu, and Kawai (2015) carried out an
experimental study to test the effectiveness of continuous solar dryer
combined with desiccant thermal energy storage for drying cocoa
beans. The experimental setup consists of three main components
namely: solar collector, drying chamber and thermal energy storage
as shown in Fig. 11. Two types of desiccant, CaCl2 as absorbent and mo-
lecular sieve 13× (Na86 [(AlO2)86. (SiO2)106]∙264H2O) as adsorbent,
were tested and it showed that during sunshine hours the maximum
temperature of drying chamber varied from 40 °C to 54 °C that is higher
than 9–12 °C from ambient temperature. The drying times for intermit-
tent direct sun drying, solar dryer integrated with an adsorbent, and
solar dryer integrated with absorbent were 55 h, 41 h, and 30 h,
respectively.
Çakmak and Yıldız (2011) carried out an experimental evaluation
for drying kinetics of seeded grapes. The developed drying system con-
tains expanded-surface solar air collector to achieve high heat transfer
and turbulence effect, a solar air collector with the PCM to perform
the drying process even after the sunset and drying room with swirl
Fig. 5. Schematic view of reversed absorber natural convective solar crop dryer with element to give the swirl effect to air flow in drying room as shown in
thermal storage. Fig. 12. The experiment was performed simultaneously under natural
94 K. Kant et al. / Innovative Food Science and Emerging Technologies 34 (2016) 86–99

Fig. 6. Schematic view of experimental setup.

flow and dryer with swirl flow and without swirl flow at three different included angle of 60° was used as the absorber plate. The height be-
air velocities. The obtained moisture ratio values have been compared tween the absorber and the bottom surface is 15 cm. A toughened
to six different moisture ratio models in the literature. The model having glass with thickness 5 mm was placed tightly above the absorber sur-
the maximum correlation coefficient (R) and the minimum chi-square face in rubber footing. The 25 mm and 50 mm thick rock wool was
(χ2) value has been determined as the most relevant one for each used to insulate the two sides and the bottom of the collector, respec-
seeded grape drying status. tively. The thermal energy storage tank with 1.8 m length and 0.4 m
Esakkimuthu, Hassabou, Palaniappan, Spinnler, Blumenberg, and in diameter was made of a galvanized iron sheet and isolated with
Velraj (2013) developed an indirect solar dryer which utilizes a PCM. glass wool which is enclosed with an aluminum covering to prevent
The dryer contains a solar air heater, a blower, a packed bed type PCM the insulation from deteriorating due to rain and wind. High-density
thermal energy storage unit, and a drying compartment. The collector polyethylene is used to construct spherical capsules filled with a PCM
area was 6 m2 and made of three panels. A V-corrugated aluminum (HS 58) and is kept inside the storage tank. The conclusion was drawn
sheet of 1.1 mm thickness with corrugation height of 38 mm and an that the collector efficiency was improved when the mass flow rate

Fig. 7. Inclined multi-pass air heater with inbuilt thermal storage attached with deep-bed drying system.
K. Kant et al. / Innovative Food Science and Emerging Technologies 34 (2016) 86–99 95

Fig. 8. (a) A schematic diagram of the experiment set-up with attached drying chamber. (b) Detailed sketch of the LHS vessel.

Fig. 9. (a) Schematic of the desiccant integrated solar dryer. 1. Blower, 2. flat plate solar air collector, 3. drying chamber, 4. insulation, 5. absorber plate, 6. bottom plate, 7. transparent cover,
8. desiccant bed, 9. plywood, 10. air inlet, 11. duct for air exit, 12. drying trays, 13. reversible fan, 14. valve, 15. plywood. (b) A pictorial view of the experimental set-up.
96 K. Kant et al. / Innovative Food Science and Emerging Technologies 34 (2016) 86–99

Fig. 10. Schematic view of flat plate absorber with the thermal storage natural convective solar crop dryer.

increased; this increment can be associated to the reduction in the heat supply of the storage system can be achieved by using lower mass flow
losses associated with the reduction in the average temperature of the rate.
collector. Furthermore, the increase in the value of the heat transfer co-
efficient at a greater mass flow rate can be considered as another factor.
The selection of the PCM with a suitable melting temperature is very im- 4.2.2. Greenhouse dryer
portant and is a key factor to avoid the spoiling of the food products. The Berroug, Lakhal, El Omari, Faraji, and El Qarnia (2011) carried out a
recommended storage tank with the particular size of the PCM balls and numerical study on solar greenhouse dryer with PCM integrated its
a mass flow rate of 200 kg/h can offer a near-uniform rate of heat ex- north wall. The dryer is oriented in east–west direction and CaCl2·6H2O
change with minimum additional energy consumption. Therefore, it was used as a PCM. The rise of inside air temperature was found to be in
will overcome the pressure drop during the melting and solidification the range of 6–12 °C and the cover temperature was 4–5 °C due to the
of PCM. Furthermore, the maximum capacity of the PCM and a uniform use of 4 cm thick PCM north wall (NW) as a storage medium. Fluctuation

Fig. 11. Picture of the experimental setup of solar dryer (a), drying tray (b) and thermal resistance analogy (c) of solar collector envelope.
K. Kant et al. / Innovative Food Science and Emerging Technologies 34 (2016) 86–99 97

Fig. 12. Schematic view of manufactured experimental set-up, (1) fan, (2) valves, (3) connection pipe, (4) expanded-surface solar air collector, (5) collector with PCM, (6) adjustable
mirror, (7) adjustable collector tripod, (8) diffuser, (9) observation glass, (10) drying room, (11) air exit chimney, (12) data logger and (13) PC.

of temperature for greenhouse air is less in a greenhouse with PCM NW embedded in various geometries and boundary conditions. MATLAB is
and relative humidity is 10–15% lower in a greenhouse with PCM NW. successfully used to investigate the crop temperature, air temperature,
the moisture evaporated and for forecasting the thermal performance
4.2.3. Hybrid solar dryer of the solar dryer by Kumar and Tiwari (2006). Statistical software
Reyes, Mahn, and Vásquez (2014) carried out a study on the hybrid SPSS is an important tool for analysis of statistical data obtained from
solar dryer with PCMs for dehydration of mushrooms. The temperature experiments. It computes the coefficient of determination (R2), the per-
was maintained at up to 60 °C after recycling of air (70% to 80%). Several centage of root mean square error (RMSE) and reduced chi-square,
runs were carried out in a day and every run showed a varying darken- which can be used for, catch the best-fit equation to analyze the drying
ing and shrinkage of mushrooms. Thermal efficiency swung between procedure. Another software Statistica can also be used for statistical
22% and 62% while the efficiency of the accumulator panel varied analysis and Sigma Plot V software is used for data fitting (Tripathy,
between 10% and 21%. The accumulator allowed dropping the electric 2015). TRNSYS software has been found useful for modeling and under-
energy input. standing the drying behavior (Reuss, Benkert, Aeberhard, Martina,
An extensive review of different types of solar dryer based on sensi- Raush, Rentzell, & Sogari, 1997).
ble and latent heat storage is carried out. The summary of research work
carried out by the different researchers on the different types of solar 6. Summary and conclusions
dryer is represented in Table 5.
The present study gives an overview of solar dryers based on
5. Use of software in solar drying systems thermal energy storage materials. A brief summary of the same study
has been presented in Table 6, which gives a comparative look of the
Solar dryers exist in a variety of designs and sizes depending on the available solar dryers based on thermal energy storage materials. As
requirement and drying capability. To investigate a dryer, it is important can be seen, a great deal of experimental, as well as theoretical work,
to calculate its complete and relative performance with the other has been performed over the last few decades, which has resulted in
similar dryers. The investigation results provide the related facts to the the fruitful development of solar dryer technology for drying of agricul-
researchers, producers and end consumers (Augustus Leon, Kumar, & tural food products. The effective thermal energy storage technology in
Bhattacharya, 2002). The use of software has proved to be very signifi- solar dryers for drying of products is an area, where existing information
cant in developing and analyzing the mathematical models to forecast should be consolidated to better facilitate the end user in cost effective
the performance of different types of solar dryers. The design of solar manner. For a better thermal performance of solar dryers, a PCM with
dryer can be improved with the help of software and it saves time a high latent heat of fusion and with a large surface area for heat transfer
which otherwise is spent in performing real-time experiments. It is is mandatory and is currently explored widely. The poor thermal
also useful for predicting the moisture content, crop temperature and conductivity characterizes a common problem to most of the PCMs. A
drying rate, texture drying kinetics, and color of the crop. Computational number of studies are currently underway to investigate and enhance
fluid dynamics (CFD) can be used for the analysis and investigation of the heat transfer between the heat transfer fluid and the PCM is still of
air flow rate, temperature distribution pattern and humidity inside the significant interest. Fan and Khodadadi (2011) carried out a novel re-
solar dryer, through appropriate simulation of energy and momentum view of thermal conductivity enhancement with nonmoving structure
equations and heat and mass transfer in both gaseous and solid phases and suspension of nanoparticles in PCM is also suggested by the defer-
(Chen, Huang, Tsai, & Mujumdar, 2008). It is also very helpful to inves- ent researchers (Das, Choi, Yu, & Pradeep, 2007). Drying of medical
tigate the melting of PCMs used in solar dryers. The commonly used plants is proposed to be a new trend in using PCMs, where it needs rea-
software tools for such studies are Ansys, Comsol Multi-physics, CFX, sonable and constant temperature throughout the drying process. It is
FORTRAN etc. by various researchers (Qiu, Yan, & Tan, 2012; Biwole, found that the addition of highly thermal conductive of nanoparticle
Eclache, & Kuznik, 2013; Giangi, 2000; Galione, Lehmkuhl, Rigola, & and use of encapsulation and metallic fins can improve the thermal con-
Oliva, 1991) applied such software based on CFD to investigate the ther- ductivity of PCMs significantly; consequently, they could be combined
mal performance of solar dryers in general and PCMs particularly when with solar energy storage devices to enhance their charging/discharging
98 K. Kant et al. / Innovative Food Science and Emerging Technologies 34 (2016) 86–99

capabilities. It is also suggested to use commercial numerical packages, Hasnain, S. M. (1998). Review on sustainable thermal energy storage technologies, part I:
Heat storage materials and techniques. Energy Conversion and Management, 39(11),
Comsol Multi-Physics, CFX, FORTRAN, OpenFOAM and Fluent-Ansys, 1127–1138.
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Energy and Buildings, 20(1), 77–86.
Hawlader, M. N. a., Chou, S. K., Jahangeer, K. a., Rahman, S. M. a., & Lau, K. W. E. (2003).
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