Narayana IIT Academy 11-01-20_Jr.

IIT-N-SUPERCHAINA(R)_Jee-Adv_2014-P1_WAT-11_Q’P
20. A thin equiconvex lens of glass of refractive index   3 / 2 and of focal length 0.3 m in air is sealed
into an opening at one end of tank filled with water (   4 / 3 ). On the opposite side of the lens, a
mirror is placed inside the tank on the tank wall perpendicular to the lens axis as shown in figure. If
the image of the object ‘O’ is at a distance of 10x cm from the lens, then x is

CHEMISTRY Max Marks: 60

SECTION-1
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 10 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of
which ONE or MORE THAN ONE are correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
21. Which of the following is correct about following reaction?
x2
RCOOAg  

A) only Cl2 can give alkylhalide B) I 2 will give ester
C) The reaction proceeds through freeradical D) F2 cannot give alkylhalide
22. Racemic mixture is obtained due to the monohalogenation of
A) n- pentane B) isopentane C) neopentane D) Isobutane
23. Choose the correct statement (s) from the following regarding freeradical chlorination and
bromination reaction of alkane.
A) The first propagation step is exothermic in bromination reaction and endo thermic in
chlororination reaction
B) The first step is endothermic in bromination reaction and exothermic in chlorination reaction.
C) Chlorination reaction is more reactive process but very less selective, reverse is true for
bromination.
D) Chlorination is more selective but less reactive process and reverse is true for bromination
24. 1-chlorobutane canbe reduced to butane
A) NaBH 4 B) LiAlH 4 C) Zn / CH 3COOH D)  C6 H 5 3 SnH

25. Consider the two lines shown in the diagram given below which of the following apply appropriately
to a SN 2 reaction?

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Energy
I

II

Reaction coordinate

A) Graph I could represent Cl and Graph II represents I  leaving group.
B) Graph I could represent OH  and graph II represents CH 3COO nucleophile
C) Graph I could represent H 2O and graph II H 2 S as nucleophile
D) Graph I could represent  CH 3  2 NH and Graph II to  CH 3  2 N  nucleophile
26. What is / are true regarding following reaction
NO

Fe
 Br2  

A) Bromination occurs above at a rate faster than at benzene

B) Bromination occurs above at a rate slower than at benzene
C) Bromination occur at ortho and para position giving para isomer as major product
D) Bromination occur predominantly at meta position
27. What is / are true about chlorination of toluene
A) In presence of light, benzyl chloride is formed when treated with chlorine
B) In presence of AlCl3 , ortho and para chloro toluenes are formed
C) Once a chlorine atom is introduced into benzene ring, further chlorination at benzene ring become
difficult compared to first chlorination
D) Chlorination of toluene in presence of AlCl3 is more difficult than benzene
28. Pickup the correct statement (s ) regarding product (P ) in the following reaction.

H
Product
 (P)

OH
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Narayana IIT Academy 11-01-20_Jr.IIT-N-SUPERCHAINA(R)_Jee-Adv_2014-P1_WAT-11_Q’P
A) It is a aromatic compound
B) It gives only one monobromo derivative on reaction with Fe / Br2
C) It has six benzylic hydrogens
D) It gives tri carboxylic acid on reaction with hot alkaline KMno4 following by acidification.
29. Which of the following reaction of benzene shows primary isotopic effect.
A) Nitration B) Sulphonation C) Bromination D) Iodination
30. Choose the correct relations on the bases of Bohr’s theory.
1 1
A) Velocity of electron  B) Frequency of revolution  3
n n
1
C) Radius of the orbit  n 2 Z D) Force of electron  4
n
SECTION-II
INTEGER TYPE
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
31. Howmany different isomeric dibromo alkanes on refluxing with ‘Na’ metal in dimethyl ether can
given the same 1,4- dimethyl cyclohexane
32. Consider the following reaction
CH 3CH 2 I  NaOH  CH 3CH 2OH  NaI
The above reaction was started taking equal concentrations of ethyl iodide and NaOH. After I.0 hr
rd
1
conc of idoethane of is dropped to   of initial value By what faction, the rate of reaction would
 3
have been dereased by the same time ?
33. Consider the following reaction
O
H 3C  CH 2
hr
CH 2 + N Br
CCl4
H 3C  CH 2
O
How many different monobromoderivatives would be produced?
34. The compound below has four phenyl rings, but very less stable due to an opposing factor of
stability. Therefore, this compound absorb bromine in dark. How many bromine molecules when
added to this molecule, would make it stable and prevent further bromine addition ?

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Hydrolysis Polymerisation
35. Mg 2C3   A g   " B "
Number of benzylic hydrogen in product “B”
36. Half life of a reaction become half when initial concentration of reactants are made double the order
of the reaction will be
37.
(1)

(2)
O

NH
(3)

(4)
Sulphonation of the above molecule is most favourable at the carbon number--------------
38. How many of the following molecules are more reactive in electrophilic aromation substitution
reaction than in benzene
+
Cl SOR NO2 NH 3 CONH 2 CF3

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39.

C5 H10
Alc.KOH
Major product  x 

Br
The number of isomers possible for " x " excluding stereomers is equal to 2  a .Numerical value of
‘a’ is
40. How many of the following acts as electrophiles
+
SH  , H 3O  , H 2O, NH 3 , CH 3 NH 3 , R  O  R

MATHEMATICS Max Marks: 60

SECTION-1
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 10 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of
which ONE or MORE THAN ONE are correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
41. For a family circles passing through the points A 3,7 B  6,5 which of the following is/are true.
2 2 2
A) If P is a point on a circle of the family with least area then PA  PB  AB
B) Only two circles of the family touches x  axis
C) for every point on the line 2 x  3 y  27  0 the powers are equal with respect to every member
of the family
D) If every member of the family cuts the circle x 2  y 2  4 x  6 y  3  0 then the common chords
 23 
pass through  2, 
 3 
42. The equation of a circle C1 is x2  y 2  4 . The locus of point of intersection of perpendicular
tangents to the circle C1 is the curve C2 and the locus of midpoints of the chords of the circle C1
subtending a right angle at the origin is the curve C3 . Then
A) C2 and C3 are circles with same centre
B) area enclosed by C3 is 2
C) The angle between the tangents to C3 from any point on C1 is  / 3 .
D) Only one line touches C1 , C2 , C3
43. If the line 3x  4y    0 touches the circle x 2  y 2  4x  8y  5  0 at  a, b  , then   a  b
can be equal to
A) 20 B) 22 C) -30 D) -28

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