M aterial S afety D ata Sheets

(MSDS)

Liquid Gas Clean Agent

AF 11
 AF11
Material Safety Data Sheets

IDENTIFICATION OF SUBSTANCE / PREPARATIO N

Identity (as used on label) AF11
Manufacture’s Name Newstar Chemicals (M) Sdn Bhd (324124-V)

No. 5, Block B, Jalan SS13/5

Subang Jaya Industrial Esta te
Address
47500 Petaling Jaya
Selangor Darul Ehsan MALAYSIA

Information / Emergency Telephone Number (603) 5621 2168

Facsimile Number (603) 5621 1168
Date Prepared 28 Dec ember 1994
Prepared By Randall Hart / Agus Paryono
Revision Date 11 November 2002
Revised By Chris Saklatvala
Approved By Randall Hart

HAZARDOUS INFORMATIO N
Hazardous Components Ethane, 2,2 -dichloro -1, 1, 1-trifluoro
CAS No. Mixture
OSHA (ppm) None Established
TWA (mg/ m³) None Established
ACGIH (ppm) None Established
Percent 99.5

INGREDIENT INFORMATI ON
Hydrochlorofluorocarbon (HCFC) CAS No. 306- 83-2
Concentrate Propriety

STABILITY AND REACTIVITY DATA

Stability Ethane, 2,2 -dichloro -1, 1, 1-trifluoro
Conditions to Avoid Mixture
Hazardous Polymerization None Established

Material Safety Data Sheets No. H-008E-R AF11 (1 of 5)

 PHYSICAL / CHEMICAL CHARACTERISTICS
Liquid Density (at 25 °C) 1.46 g/c m³
Vapour Pressure (at 25 °C) 672 mmHg
Boiling Point 27.6 °C at 760 mmHg
Relative Vapour Density (Air = 1) 5.3
Solubility in water (at 25 °C) 39 Percent by Weight
Relative Evaporation Rate (CCI 4) =1) Less than 1
Appearance and Odour Clear, Colourless, Slight Lemon, Liquid
ODP (CFC11 = 1) 0.016
GWP (CFC11 = 1) 0.018

FIRE AND EXPLOSION HAZARD DATA

FLASH POINT
Flammable Limit Non Flamm able
LEL Not Applicable
UEL Not Applicable
Extinguishing Media As appropriate for combustible in area
Use water to cool containers Self -Contained
Breathing Apparatus (SCBA) is required if
Special Fire Fighting Procedures
drums rupture and contents are spilled under
fire conditions.
Containers may rupture under fire c onditions.
Unusual Fire and Explosion Hazards
Decomposition may occur.
Incompatible with Alkali or Alkaline E arth
Metals -Powdered Al, Zn, Be, etc. Long term
Incompatibility contact with water can deplete stabilizers
followed by slow hydrolysis which produces
composite acids.

Decomposition Products can be Hazardous.

The only decomposition b y product is
Hazardous Decomposition or by Products Hydrogen Fluoride. The HF levels are the
lowest of all amongst other Halocarbons (LPC
19 June 2000)

TRANSPORTATION
PROPER SHIPPING NAME Fire Extinguisher
UN ID NUMBER UN1044
HAZARD CLASS 2 Division : 2.2 Non -Flamm able Gas
None - Exc eption 49CFR 173.309. Each fire
PACKAGING GROUP extinguisher must be shipped as an inside
packaging.
The information and re commendations in this publication represent our current data and best opinion as to the proper use and handling of this
material under normal conditions. Any use of the described material which is not in conformance with this publication or which involves using
the described in combination with any other material or any other process is the responsibility of the user.

Material Safety Data Sheets No. H-008E-R AF11 (2 of 5)

 HEALTH AND HAZARD DATA
Health Hazardous (Acute and Chronic)
ANIMAL DATA

LC50 > 750,000 ppm in rats

Oral ALD 9,000 mg/kg in rats
Skin Absorption LD50 > 2,000 mg/kg in rabbits
Ames Assay Negative
Micronucleus Negative
The compound is not skin sensitizer in animals. Toxic effe cts noted in animals from exposure by inhalation at concentrations of 10,000 ppm or
greater include central nervous system effe cts, anesthetic effe cts, liver effe cts, and non- spe cific preterminal effe cts. Preliminary results of a
long term inhala tion study at 300, 1000 or 5000 ppm caused an increased in benign testicular and benign pancreatic tumors in male rats. None
of these benign tumors are considered life- threatening. No animals test reports are available to define reproductive hazards. Anima l testing
indicates that this compound does not have embryo toxic effe cts. Tests in bacterial or mammalian cell cultures demonstrate no
mutagenic activity.

HUMAN HEALTH EFFECT

Human health effects of over exposure by eye conta ct may inc lude eye irritation with
discomfort, tearing or blurring of vision. Overexposure by inhalation to the vapors may cause
temporary nervous system depression with anesthetic effects such as dizziness, headache,
confusion, in coordination, and loss of consciou sness; or with gross overexposure (>20), possibly
temporary alteration of heart’s electrical a ctivity with irregular pulse.

CARCINOGENICITY
NTP None Established
IARC Monographs None Established
OSHA Regulated None Established

SIGNS AND SYMPTOMS O F EXPOSURE

At normal room temperature AF11E c annot
Inhalation sustain a vapour, thus negating any inhalation
problems under normal conditions.
Skin The compound is not a skin irritant.
Eye The compound causes mild eye irritation.

Intentional misuse or deliberate inhalation

may cause possible disturbances of the
Medical Conditions gener ally Aggravated by
c ardiac rhythm, c atecholamine drugs, such
Exposure
as epinephrine should be considered only as
a last resort in life -threatening emergencies.

Material Safety Data Sheets No. H-008E-R AF11 (3 of 5)

 EMERGENCY AND FIRST AID PROCEDURES
If high concentrations are inhaled,
immediately remove to fresh air. Keep persons
Inhalation calm. If not breathing, give artificial
respiration. If breathing is difficult, give
oxygen. Call a physician.
In case of skin c ontact, flush with water for 15
Skin Contact minutes. Get medical attention if irritation is
present.
In case of eye contact, immediately flush
Eye Contact eyes with plenty of water for 15 minutes. Call a
physician.
No specific intervention is ind icated as the
compound is not likely to be hazardous by
ingestion. Consult a physician if necessary. Do
Ingestion
not induce vomiting because the hazard of
aspirating the material into the lungs is
considered greater than swallowing it.

PRECAUTION FOR SAFE HANDLI NG AND USE

Steps to be taken in cases material is Released or Spilled

Review Fire and Explosion Hazard Data and

Precautions to be taken in Handling and Storing
Note before proceeding with clean up. Use
appropriate personal protective equipment during
clea n up.

Prevent liquid from entering sewers,

waterways or low areas. Ventilate area.
Collect on absorbent material and transfer to
Dike Spill
steel drums for recovery/disposal. Comply with
Federal, States, and Local Regulations on
reporting releases.
Rec over by distillation or remove to permit ted
Waste Disposal Method waste disposal facility. Comply with Federal,
State, and Local Regulations.
Use with sufficient ventilation to keep
employee exposure below rec ommended
limits. Provid e adequate ventilation for
storage, handling, and use, especially for
Precaution to be Taken in Handling and enclosed or low spaces. Avoid contact of
Storing liquid with eyes and prolonged skin exposure.
Do not allow product to contact open flame
or electrical heating elements because
dangerous decomposition products may
form.
Clean, dry, well- ventilated area. Do not heat
Storage Conditions
above 30 oC.

Material Safety Data Sheets No. H-008E-R AF11 (4 of 5)

 CONTROL MEASURES
Under normal manufacturing conditions, no
respiratory protection is required when using
Respiratory Protection (Specify Type) this product. Self -Contained breathing
apparatus (SCBA is required if a large spill
occurs).

Normal ventilation for standard

manufacturing proc edures is generally
adequate. Local exhaust should be used
Ventilation
when large amounts a re released.
Mechanical ventilation should be used in low
pla ces.

Impervious gloves should be used to avoid

prolonged or repeated exposure. Chemical
Eye / Skin Protection
splash goggles should be available for use as
needed to prevent eye contact.

ADDITIONAL INFORMATION
Though no ACGIH TLV or OSHA PEL are
assigned, the result of long term toxicity
Other Comments testing is now being discussed by PAFT I
(Program for Alternative Fluoroc arbon Toxicity
Testing I).

The information contained herein is be lieved to be reliable, but no representations, guarantees or warranties of any kind are made as to its
accuracy, suitability for particular applications or the results to be obtained therefrom. The information is based on labora tory work with small -
scale e quipment and does not ne cessarily indicate end product performance. Full -scale testing and end product performance are the
responsibility of the user. HARTINDO shall not be liable for and the customer assumes all risk and liability of any user or h andling of any material
beyond HARTINDO’s direct control. The SELLER MAKES NO WARRANTIES, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, THE IMPLIED
WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Nothing contained herein is to be considered as permission,
re commendation, nor as an inducement to practice any patented invention without permission of the patent owner.

Newstar Chemicals (M) Sdn Bhd (324124- V)

Copyright 1995 © No.5, Block B, Jalan SS13/5, Subang J aya
September 1995
Newstar Chemicals (M) Sdn Bhd Industrial Estate 47500 Petaling Jaya
Selangor Darul Ehsan MALAYSIA

Material Safety Data Sheets No. H-008E-R AF11 (5 of 5)