ByPaper chemistry 1st year… ..

Subjective part 1.
Question no. 1 . Attempt any eight questions.
1.removal of an electron from a neutral atom is always endothermic process.
Justify.
2. Define gram formula mass and gram molecular mass.
3. Define stichiometry and write its assumptions also.
4. What solvent extraction.? By which law it is followed?
5. How drying process of crystals is carried out?
6. Write different scales of thermometry
7.what is mole fraction. How it is related to partial pressure?
8. Write units of constants “a” and “b” in van der wall equation.
9.gases deviate from ideal behavior at high pressure and low temperature. Why?
10. Give applications of solubility product.
11. Depression of freezing point is colligative property. Justify.
12.sodium sulphate give discontinuous solubility curves. Why?
Question No. 2 attempt any eight questions.
1.what are London dispersion forces. How are they produced?
2.what is boiling point . What is effect of external pressure on it.
3.what is crystal lattice? What are crystallographic elements of cubic structure?
4. Why freshly cut metals have shiny surface?
5. Write four properties of neutrons.
6. Write two pastulates of Plank, s quantum theory.
7.how X-rays are produced?
8.what are quantum numbers. Write names of four quantum numbers.
9. What is Le_Chatelier principle.
10. What are buffer solutions. Give example also.
11 What is zero order reaction. Give example
12. Write two properties of catalyst…
Question No. 3 attempt any six questions.
1. 1st electron affinity is negative and 2nd electron affinity is positive why?
2. Why size of an anion is always greater than corresponding atom?
3.lone pair of electrons occupies more space than bond pair of electrons why?
4. Dipole moment of BF3 is zero but of water is 1.84 D why.?

5.differentiate between spontaneous and non spontaneous reactions.

6.what standard enthalpy of a reaction?
7. Define electrochemical Series
8. Why sodium can diaplace hydrogen from acid but platinum cannot?
9.Lead accumulator is chargeable battery. Justify..
Subjective part 2nd… …
Attempt any three questions…
Question no 4. (a) explain combustion analysis of hydrocarbons…
(b) explain ionic solids with their properties
Question no. 5.(a) calculate the mass of 1 dm3 of NH3 gas at 30 C0 temperature
and 1000mmHg pressure. Considering gas is behaving ideally… .
(b) give pastulates of Bohr atomic model.
Question No. 6.(a) draw molecular orbital theory diagram of O2 molecule.
(b) explain Born Haber cycle… ..