14-05-19 SR - ICON ALL Jee-Adv (2013 P1) GTA-11 QP PDF

Sri Chaitanya IIT Academy.
, India
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Sr.ICON ALL Date: 14-05-19
Time: 09:00 AM to 12:00 Noon Max.Marks:180
Name of the Student: ___________________ I.D. NO:
2013_PAPER–I
Jee Advanced_GTA-11
TOTAL SYLLABUS
Sri Chaitanya IIT Academy 14-05-19_Sr. ICON ALL_Ph-III_JEE-Adv_(2013_P1)_GTA-11_Q'P
JEE-ADVANCE-2013-P1-Model
Time: 09:00 AM to 12:00 Noon IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 10) Questions with Single Correct Choice 2 0 10 20
Sec – II(Q.N : 11 – 15) Questions with Multiple Correct Choice 4 -1 5 20
Sec – III(Q.N : 16 – 20) Questions with Integer Answer Type 4 -1 5 20
Total 20 60
CHEMISTRY:
Total 20 60
MATHEMATICS:
Total 20 60
Sec: Sr. ICON ALL space for rough work Page 2

PHYSICS Max Marks: 60

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 10 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +2 for correct answer, 0 if not attempted and 0 in all other cases.
1. The vernier scale of a vernier calliperse is divided into 10 divisions which coincide
with 9 divisions of the main scale, each main scale division being 0.5 mm. When the
two jaws of the instrument are in contact with each other, the 4th division of the vernier
scale coincides with a main scale division and the zero of the vernier lies to the right
of the zero of the main scale. When a sphere is inserted between the jaws, the zero of
vernier scale lies slightly to the right of 1.8 cm and the sixth vernier division coincides
with a main division. The diameter of sphere will be
A) 1.85 cm B) 1.81 cm C) 1.75 cm D) 1.71 cm
2. Statement-1: The twinkling of star is due to reflection of light.
Statement-2: The velocity of light changes while going from one medium to the
other.
A) Both Statement-1 and Statement-2 are true and Statement-2 is the correct
explanation of Statement-1
B) Both Statement-1 and Statement-2 are true but Statement-2 is not the correct
C) Statement-1 is false but Statement-2 is true
D) Both Statement-1 and Statement-2 are false

3. A uniform right-angled triangular lamina is suspended from the ceiling with the help
of three light strings. The plane of the lamina is horizontal and the strings are vertical
as shown in the figure. In which of the following options, tensile forces TA , TB and TC
developed in the strings connected to the vertices A, B and C respectively of the
lamina are arranged in correct order of their magnitudes?
A) TA  TB  TC B) TB  TA  TC C) TC  TA  TB D) TA  TB  TC
4. A mixture of 2 moles of helium gas (atomic mass = 4 amu) and 1 mole of argon gas
(atomic mass = 40 amu) is kept at 300 K in a container. The ratio of the rms speeds of
vrms  helium
helium and argon atoms in the container is nearly
vrms  arg on
A) 10 B) 0.45 C) 2.24 D) 3.16

5. A composite slab consists of two parts of equal thickness. The thermal conductivity of
one is twice that of the other. What will be ratio of temperature difference across the
two layers in the state of equilibrium?
A) 1 B) 2 C) 3 D) 4
6. Statement-1: A spark occur between the poles of a switch when the switch is opened.
Statement-2: Current flowing in the conductor produces magnetic field.
C) Statement-1 is true but Statement-2 is false
7. An object is projected with an initial velocity of u  10 m / s at angle of   450 with
the horizontal surface. At the highest point of the path of the projectile, the object
breaks into two parts of mass ratio 1: 3 . The lighter part comes to momentary rest just
after the break. Then the separation between the points of landing of lighter and

heavier parts is g  10m / s 2 
20 5
A) 20 m B) 5 m C) m D) m
3 3
8. Statement-1: If a pendulum clock is taken to mountain top, it will gain time
Statement-2: The value of acceleration due to gravity is low at the mountain
top than at the plane.(bottom)
D) Both Statement-1 is false and Statement-2 is true
9. Statement-1: If the frequency of alternating current in an A.C. circuit having a real
inductor alone is increased then current gets decreased.
Statement-2: The current is inversely proportional to frequency of alternating current.

4
10. Two parallel rays are travelling in a medium of refractive index 1  . One of the
3
3
rays passes through a parallel glass slab of thickness ‘t’ and refractive index 2 
2
which is kept in the first medium. The optical path difference between the two rays
due to the glass slab will be
4t 3t t t
A) B) C) D)
3 2 8 6
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
11. Sinusoidal waves 5.00 cm in amplitude are to be transmitted along a string having a
linear mass density equal to 4.00  102 kg / m . If the source can deliver a maximum
power of 90W and the string is under a tension of 100N, then the highest frequency at
which the source can operate is (take  2  10 ).
A) 45.3 Hz B) 50 Hz C) 30 Hz D) 62.3 Hz
12. Two blocks A and B, each of mass ‘m’ are connected by a massless spring of natural
length ‘L’ and spring constant ‘K’. The blocks are initially resting on a smooth
horizontal floor with the spring at its natural length as shown in figure. A third
identical block C, also of mass m, moves on the floor with a speed ‘ v ’ along the line
joining A and B, and collides elastically with A. Then
A) the kinetic energy of the A – B system, at maximum compression of the spring, is

zero
mv 2
B) the kinetic energy of A – B system, at maximum compression of the spring, is
4
 m
C) the maximum compression of the spring is v  
 K
 m
D) the maximum compression of the spring is v 
 2 K 
13. In the diagram shown in figure,
A) absolute acceleration of 1 kg block is 4m / s 2 (in magnitude)

B) absolute acceleration of 2 kg block is 11m / s 2 (in magnitude)
C) relative acceleration between the two blocks is 15 m / s 2 (in magnitude)
D) relative acceleration between the two blocks is 17 m / s 2 (in magnitude)

14. Two identical charges  Q each are kept fixed at some distance apart. A small particle
‘P’ with charge ‘q’ is placed at midpoint between them. If ‘P’ is given a small
displacement ‘ d ’ it will undergo simple harmonic motion if
A) q is positive and ‘ d ’is along the line joining the charges
B) q is positive and ‘ d ’ is perpendicular to the line joining the charges
C) q is negative and ‘ d ’ is perpendicular to the line joining the charges
D) q is negative and ‘ d ’ is along line joining the charges
15. Three large identical parallel conducting plates A, B and C are placed as shown.
Switches S1 and S 2 are opened and can connect A and C to earth when closed.  Q
charge is given to B.
A) If S1 is closed with S 2 open, a charge of magnitude Q will pass through S1

B) If S 2 is closed with S1 open, a charge of magnitude Q will pass through S 2
C) If S1 and S 2 are closed together, a charge of magnitude Q/3 will pass through S1
and a charge of magnitude 2Q/3 will pass through S2
D) If S1 and S 2 are closed, the magnitude of charge on the outer surfaces of A and C
is same.
SECTION – III
INTEGER TYPE
(This section contains 5 questions. The answer to each question is a single digit integer ranging from 0 to 9.
The correct digit below the question number in the ORS is to be bubbled ).
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
16. The work functions of Silver and Sodium are 4.6 eV and 2.3 eV respectively. The
ratio of the slope of the stopping potential versus frequency plot for Silver to that of
Sodium is
7
17. Starting with a sample of pure Cu 66 ; of it decays to Zinc in 15 minutes. The half life
8
of copper is “x” minutes. Then ‘ x ’ is
18. In the figure, the wedge is pushed with an acceleration of 10 3 m / s 2 . It is seen that
the block starts climbing up on the smooth inclined of wedge. The length of the
1
inclined plane is 1 m. The time taken by the block to reach the top is t  . Then
x
‘ x ’ value is

19. A 2cm diameter coin rests flat on the bottom of a bowl in which water is 20cm deep
 4
 w   . If the coin is viewed directly from above, then the apparent diameter is (in
3
cm)
20. A particle is given an initial speed u inside a smooth fixed spherical shell of radius R
so that it is just able to complete the circle. Acceleration of the particle, when its
velocity is vertical, is a  g 8  x then x 

CHEMISTRY Max Marks: 60
SECTION – I
21. Statement-1: In a reversible endothermic reaction, activation energy of forward
reaction is higher than that of backward reaction.
Statement-2: The threshold energy of forward reaction is more than that of backward
reaction.
A) Statement 1 is true, statement 2 is true; statement 2 is a correct explanation for
statement 1
B) statement 1 is true, statement 2 is true; statement 2 is not a correct explanation for
statement 1
C) statement 1 is true, statement 2 is false
D) statement 1 is false, statement 2 is true
22. Choose the major product of the following reaction sequence
CH3 O
Cl S CH3
O 
1.BH3 I
2 
.OH,H O
 S major product
2 2 2
Pyridine N

CH 3
H 3C
I
I
A) B)
CH 3
CH 3
C) D) I
23. Statement-1 : For a fixed amount of a gas, the product PV is always constant.
Statement-2 : Gases deviate more from ideal behaviour at high pressure and low
temperature.
statement 1
statement 1
24. The relative yield of the following alkenes produced by the reaction of 1 – chloro –
(Z) – 1, 2 – dimethylcyclohexane with KOH/heat is
(i) (ii) (iii)
A) i  ii  iii B) ii  iii  i C) i  iii  ii D) iii  i  ii

25. Statement-1: Polyhalide ions of the type AB2 are isostructural with XeF2
Statement-2: Both the polyhalide ions of the type AB2 and XeF2 have same number
of valance electrons
statement 1
statement 1

Br
 i  Mg ether
O  ii  CO2
 Z
CH 3  iii  H 3O 
O
26.
The final product Z is
COOH COOMgBr
O O
CH 3 CH 3
O O
A) B)
COOH COOH
CHO COOH
CH 3 CH 3
C) D)

27. Statement-1: If pure haematite is used as an ore for iron extraction, there is no need of
the roasting step.
Statement-2: Final product of the roasting step is Fe2O3 in the extraction of Fe .
statement 1
statement 1
28. Product of the following reaction is
AlCl2
 H 3C  CH  CH 2  CH 2  CH  CH 3  
Cl Cl
Cl
A) B)
C) D)
29. Statement-1: The IUPAC name of citric acid is 2  hydroxy – propane – 1, 2, 3 –
tricarboxylic acid
COOH
HOOC COOH
OH
citric acid
Statement-2: When an unbranced C atom is directly linked to more than two like –
functional groups, then it is named as a derivative of the parent alkane which does not
include the C atoms of the functional group.
statement 1
statement 1
30. Which of the following compounds of elements in group IV is expected to be most
ionic?
A) PbCl2 B) PbCl4 C) CCl4 D) SiCl4
SECTION – II
31. pOH of 0.1 molar aqueous NaCN solution found to be 2, then
A) hydrolysis constant K h  1.11  10 3
B) p H of the solution is 12
C) K a of HCN is 1010
D) the value of dissociation constant of HCN in its aqueous solution is 9  1012

32.
 b trans to c 
a
 Mabcd  
b
 cis   Ma2cd   a
b d
(sq. planar complex)
a c
Correct geometrical arrangement of reactant complex is/are
a c c
b
M M
b d
A) d B) a

a b d c
M M
c a
C) d D) b
33. Reagent which can’t be used to carry out this conversion are:
O OH
OH
O OH
 
A) 1.LiAlH 4 2.H 3O B) N 2 H 4 / OH /  C) NaBH 4 D) Zn  Hg  / HCl
34. Identify correct order(s) of acidic strength?
COOH COOH
COOH
OH
 
OH
A) OH

OH OH
NO2
NO2

OH
NO
B) 2
C) HF  HCl  HBr  HI  in aqueous solution 
D) HOCl  HClO2  HClO3  HClO4

35. 1 mole of a non – volatile non – dissociative solid solute is dissolved in 200 moles of
water. The solution is taken to a temperature TK (lower than freezing point of
solution) to cause ice formation. After removal of ice the remaining solution is taken
to 373 K where vapour pressure is observed to be 740 mm of Hg. Identify the correct
options:
Given data: K f  H 2O   2 K kg mol 1 and normal boiling point of H 2O  373K .
A) 125 moles of ice will be formed
2000
B) Temperature to which original solution was cooled should be K
37  18
10 0
C) Freezing point of original solution should be  C
18
1
D) Relative lowering of vapour pressure of final solution will be
201

SECTION – III
INTEGER TYPE
36. Photon having energy equivalent to the binding energy of 4th state of He ion is used
to eject an electron from the metal with KE of 2eV . If electron is further accelerated
through a potential difference of 4V then the minimum value of de Broglie wavelength
associated with the electron is:
h  6.6  10 34 J .S , me  9.1  10 31 kg ,1eV  1.6  1019 J 
O
O
9 1 2
Br / FeBr
8 3 
2

3

7 6 5 4
37.
Major organic product will have Bromine at position.
38. How many lone pairs are there at Xenon in XeOF4 ?
39. Find the number of paramagnetic compound(s) with octahedral anion.
K3  CoF6  ; K3  Fe(CN )6 ;  Ni  NH 3 6  SO4 ; K 2  CoCl4  ; K3 Co  CN  6  ;
 Pt  NH 3  6   Fe  CN  6  ; K 2 CoF6 
40. D-fructose + phenylhydrazine  Osazone . ‘x’ value is _____

1mole  x moles 

MATHEMATICS Max Marks: 60
SECTION – I
y z
41. If lines x  y  z and x   and third line passing through 1,1,1 form a triangle
2 3
of area 6 units, then the point of intersection of third line with the second line will
be
 4 8 12 
A) 1,2,3 B)  2,4,6 C)  , ,  D)  0,1,0
3 3 3
42. If the equation of any two diagonals of a regular pentagon belongs to the family of
lines 1  2  y   2    x  1    0 and their lengths are sin 360 , then the locus of the
centre of circle circumscribing the given pentagon (the triangles formed by these
diagonals with the sides of pentagon have no side common) is
A) x 2  y 2  2 x  2 y  1  sin 2 720  0
B) x 2  y 2  2 x  2 y  cos2 720  0
C) x 2  y 2  2 x  2 y  1  cos 2 720  0
D) x 2  y 2  2 x  2 y  sin 2 720  0
43. The value of the parameter a such that the area bounded by y  a 2 x 2  ax  1,
coordinate axes and the line x  1 attains its least value, is equal to
1 1 3
A)  B)  C)  D) 1
4 2 4
44. A student appears for tests I, II and III. The student is successful if he passes either in
tests I and II or tests I and III. The probabilities of the student passing in tests I, II and
III are, respectively, p, q and 1/ 2 . If the probability that the student is successful is
1/ 2 , then p 1  q 
A) 1/ 2 B) 1 C) 3/ 2 D) 3/ 4
45. If  ,  be the roots of the equation u 2  2u  2  0 and if cot   x  1, then
 x    n   x    n  /     is equal to
 
sin n cos n sin n cos n
A) B) C) D)
sin n  cos n  cosn  sin n 
3e x  4e  x
 e x  2e x dx  Ax  B ln 1  2e   C then,
2 x
46. Let
11
Statement - 1: A  B  , because
2
dx 1
Statement - 2:  1 e 2x
  ln 1  e2 x   C .
2
A) Statement–1 is True, Statement–2 is True; Statement–2 is a correct explanation for
Statement–1
B) Statement–1 is True, Statement–2 is True; Statement–2 is NOT a correct
explanation for Statement–1
C) Statement–1 is True, Statement–2 is False
D) Statement–1 is False, Statement–2 is True
47. Statement-1: Curve satisfying the differential equation y1  y / 2 x passing
through  2,1 is a parabola with focus 1/ 4, 0 
Statement-2: The differential equation y1  y / 2 x is of variable separable.

A) Statement-1 is true, statement-2 is true; Statement-2 is a correct explanation for
statement-1
B) Statement-1 is true, statement-2 is true; Statement-2 is not correct explanation for
statement-1
C) Statement-1 is true, statement-2 is false
D) Statement-1 is false, statement-2 is true



48. Statement-1:  cot 1 2 k 2  4
k 1
1
Statement-2: tan 1  tan 1  2 k  1  tan 1  2 k  1 , k  N
2k2
A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct
Explanation for Statement-1
B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation
for Statement-1
C) Statement-1 is True, Statement-2 is False
D) Statement-1 is False, Statement-2 is True
49. Statement-1: The greatest integral value of  for which (2  1) x 2  4 x  (2  1)  0 has
real roots is 2
Statement-2: For real root of ax 2  bx  c  0, D  0
statement-1
statement-1

50. Statement - 1: If u and v are unit vectors inclined at angle ‘  ’ and ‘ x ’ is a unit
uv
vector bisecting the angle between them, then x 
2sin  / 2
Statement - 2: If ABC is an isosceles triangle with AB = AC = 1, then the vector
AB  AC
representing bisector of angle ‘A’ is given by AD 
2
statement-1
statement-1
SECTION – II
51.  
Let P1 denote the equation of a plane to which the vector iˆ  ˆj is normal and which

 
contains the line whose equation is r  iˆ  ˆj  kˆ   iˆ  ˆj  kˆ and P2 denote the

equation of the plane containing the line L and a point with position vector ĵ . Which
of the following holds good?
A) The equation of P1 is x  y  2

 
B) The equation of P2 is r . iˆ  2 ˆj  kˆ  2
C) The acute angle between P1 and P2 is cot 1  3

D) The angle between the plane P2 and the line L is tan 1 3
52. Let f  x be an increasing function defined on  0, . If
   
f 2a 2  a  1  f 3a 2  4 a  1 , then the possible integers in the range of a is/are
A) 1 B) 2 C) 3 D) 4
53. The consecutive digits of a three digit number are in G.P. If the middle digit be
increased by 2, then they form an A.P. If 792 is subtracted from this, then we get the
number constituting of same three digits but in reverse order. Then number is divisible
by
A) 7 B) 49 C) 19 D) 20
54. Let A and B are two non – singular square matrices, AT and BT are the transpose
matrices of A and B, respectively, then which of the following are correct?

T
A) B AB is symmetric matrix if A is symmetric
B) BT AB is symmetric matrix if B is symmetric
C) BT AB is skew – symmetric matrix for every matrix A
D) BT AB is skew – symmetric matrix if A is skew – symmetric
55. The lateral edge of a regular hexagonal pyramid is 1 cm. If the volume is maximum,
then
1 1
A) height in c.m B) height is c.m
3 3
2 1
C) maximum volume  c.u.cm D) maximum volume  c.u.cm
3 3
SECTION – III
INTEGER TYPE
  
56.  
Let a three – dimensional vector V satisfy the condition, 2V  V  iˆ  2 ˆj  2iˆ  kˆ . If

3 V  m . Then the value of m is

57. The bag contains 10 different balls. Five balls are drawn simultaneously and then
replaced and then seven balls are drawn. The probability that exactly three balls are
common to the two drawn is p , then the value of 12 p is.
58.   n
Given 1  2 x  5 x 2  10 x 3 1  x   1  a1 x  a2 x 2  ........ and that a12  2a2 then the
value of n is
59. The difference between the sum of the first k terms of the series
13  23  33  .......  n 3 and the sum of the first k terms of 1  2  3  ......  n is 1980.
The value of k is
x2 y2
60. Consider an ellipse E , 2  2  1, centered at point O and having AB and CD as its
a b
major and minor axes, respectively. If S1 is one of the focus of the ellipse, the radius
of the in circle of triangle OCS1 is 1 unit, and OS1  6 units, then the value of
 a  b / 2 ________

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Sri Chaitanya IIT Academy.

Name of the Student: ___________________ I.D. NO:

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PHYSICS Max Marks: 60

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A) the kinetic energy of the A – B system, at maximum compression of the spring, is

A) absolute acceleration of 1 kg block is 4m / s 2 (in magnitude)

C) relative acceleration between the two blocks is 15 m / s 2 (in magnitude)

D) relative acceleration between the two blocks is 17 m / s 2 (in magnitude)

A) If S1 is closed with S 2 open, a charge of magnitude Q will pass through S1

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(i) (ii) (iii)

A) i  ii  iii B) ii  iii  i C) i  iii  ii D) iii  i  ii

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D) the value of dissociation constant of HCN in its aqueous solution is 9  1012

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C) HF  HCl  HBr  HI  in aqueous solution 

D) HOCl  HClO2  HClO3  HClO4

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40. D-fructose + phenylhydrazine  Osazone . ‘x’ value is _____

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Statement-2: The differential equation y1  y / 2 x is of variable separable.

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C) The acute angle between P1 and P2 is cot 1  3

52. Let f  x be an increasing function defined on  0, . If

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