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HAZARDS

R1 – Explosive when dry. R37 – Irritating to respiratory


R2 – Risk of explosion by shock, system.
friction, fire or other sources R38 – Irritating to skin.
of ignition. R39 – Danger of very serious
R3 – Extreme risk of explosion by irreversible effects.
shock, friction, fire or other R40 – Limited evidence of a
sources of ignition. carcinogenic effect.
R4 – Forms very sensitive explosive R41 – Risk of serious damage to
metallic compounds. eyes.
R5 – Heating may cause an R42 – May cause sensitization by
explosion. inhalation.
R6 – Explosive with or without R43 – May cause sensitization by
contact with air. skin contact.
R7 – May cause fire. R44 – Risk of explosion if heated
R8 – Contact with combustible under confinement.
material may cause fire. R45 – May cause cancer.
R9 – Explosive when mixed with R46 – May cause heritable genetic
combustible material. damage.
R10 – Flammable. R48 – Danger of serious damage to
R11 – Highly flammable. health by prolonged exposure.
R12 – Extremely flammable. R49 – May cause cancer by
R14 – Reacts violently with water. inhalation.
R15 – Contact with water liberates R50 – Very toxic to aquatic
extremely flammable gases. organisms.
R16 – Explosive when mixed with R51 – Toxic to aquatic organisms.
oxidizing substances. R52 – Harmful to aquatic organisms.
R17 – Spontaneously flammable in R53 – May cause long-term adverse
air. effects in the aquatic
R18 – In use, may form environment.
flammable/explosive vapor-air R54 – Toxic to flora.
mixture. R55 – Toxic to fauna.
R19 – May form explosive peroxides. R56 – Toxic to soil organisms.
R20 – Harmful by inhalation. R57 – Toxic to bees.
R21 – Harmful in contact with skin. R58 – May cause long-term adverse
R22 – Harmful if swallowed. effects in the environment.
R23 – Toxic by inhalation. R59 – Dangerous for the ozone
R24 – Toxic in contact with skin. layer.
R25 – Toxic if swallowed. R60 – May impair fertility.
R26 – Very toxic by inhalation. R61 – May cause harm to the unborn
R27 – Very toxic in contact with child.
skin. R62 – Possible risk of impaired
R28 – Very toxic if swallowed. fertility.
R29 – Contact with water liberates R63 – Possible risk of harm to the
toxic gas. unborn child.
R30 – Can become highly flammable R64 – May cause harm to breastfed
in use. babies.
R31 – Contact with acids liberates R65 – Harmful: may cause lung
toxic gas. damage if swallowed. R66 –
R32 – Contact with acids liberates Repeated exposure may cause
very toxic gas. skin dryness or cracking.
R33 – Danger of cumulative effects. R67 – Vapors may cause drowsiness
R34 – Causes burns. and dizziness.
R35 – Causes severe burns. R68 – Possible risk of irreversible
R36 – Irritating to eyes. effects.
FIRST AID

S1 -
Keep locked up S41 - In case of fire and/or
S3 -
Keep in a cool place explosion do not breathe fumes
S4 -
Keep away from living quarters S42 - During fumigation/spraying
S5 -
Keep contents under liquid* wear suitable respiratory
S6 -
Keep under inert gas* equipment*
S7 -
Keep container tightly closed S43 - In case of fire use, * (If
S8 -
Keep container dry water increases the risk add:
S9 -
Keep container in a well- Never use water)
ventilated place S45 - In case of accident or if you
S12 - Do not keep the container feel unwell seek medical advice
sealed immediately (show the label
S 13 - Keep away from food, drink where possible)
and animal feeding stuffs S46 - If swallowed, seek medical
S14 - Keep away from materials* advice immediately and show
S15 - Keep away from heat this container or label
S16 - Keep away from sources of S47 - Keep at temperature not
ignition – No smoking exceeding *°C
S17 - Keep away from combustible S48 - Keep wetted with material*
material S49 - Keep only in the original
S18 - Handle and open container container
with care S50 - Do not mix with reagent*
S20 - When using do not eat or S51 - Use only in well-ventilated
drink areas
S21 - When using do not smoke S52 - Not recommended for interior
S22 - Do not breathe dust use on large surface areas
S23 - Do not breathe S53 - Avoid exposure – Obtain
gas/fumes/vapor/spray* special instructions before use
S24 - Avoid contact with skin S56 - Dispose of this material and
S25 - Avoid contact with eyes its container to hazardous or
S26 - In case of contact with eyes, special waste collection point
rinse immediately with plenty S57 - Use appropriate containment
of water and seek medical to avoid environmental
advice contamination
S27 - Take off immediately all S59 - Refer to
contaminated clothing manufacturer/supplier for
S28 - After contact with skin, wash information on
immediately with plenty of* recovery/recycling
S29 - Do not empty into drains S60 - This material and its
S30 - Never add water to this container must be disposed of
product as hazardous waste
S33 - Take precautionary measures S61 - Avoid release to the
against static discharges environment. Refer to special
S35 - This material and its instructions/safety data sheet
container must be disposed of S62 - If swallowed, do not induce
in a safe way vomiting: seek medical advice
S36 - Wear suitable protective immediately and show this
clothing container or label
S37 - Wear suitable gloves S63 - In case of accident by
S38 - In case of insufficient inhalation: remove casualty to
ventilation wear suitable fresh air and keep at rest
respiratory equipment S64 - If swallowed, rinse mouth
S39 - Wear eye/face protection with water (only if the person
S40 - To clean the floor and all is conscious)
objects contaminated by this
material use* * indicated by manufacturer

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