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DEPARTMENT OF SCIENCE CONTEST IN ENGLISH

EDUCATION AND TRAINING School year: 2019 – 2020

Date: 10th October, 2019

OFFICIAL PAPER
Subject: CHEMISTRY

Full name:…………………………………… Student code:………… Signature:…………….

PART I: MULTIPLE-CHOICE (4 marks)


Question 1. All atoms in halogen group all have?
A. three electrons in the last shell B. five electrons in the last shell
C. seven electrons in the last shell D. eight electrons in the last shell
Question 2. The acidity of acid solution HX sort in descending order in which answer?
A. HF, HCl, HBr, HI B. HI, HBr, HCl, HF
C. HCl, HBr, HI, HF D. HBr, HCl, HI, HF
Question 3. All substances in which answer effect to clo ?
A. Fe, H2O, H2 B. KF, KOH, H2O

C. O2, H2O, NaI D. Fe,O2,K

Question 4. Put a gram KMnO4 completely effect to concentrated HCl solution, residual and obtained
5.6 liters of Cl2 gas in standard conditions. What is the value of a ?

A. 15,8 gram B. 10,58 gram C. 20,56 gram D. 18,96 gram

Question 5. Which of the following is composed of substances that only react with concentrated
H2SO4 acid, but not dilute H2SO4?
A. Ba(NO3)2, BaCl2 B. MgO, CuO, Al2O3
C. Na, MgO, Zn D. Cu, C, S
Question 6. Which of the following ranges contain the oxidation numbers for sulfur?
A. -2; -4 ; +6 ; +8 B. -1; 0 ; +2; +4
C. -2; 0 ; +4 ; +6 D. -2; -4 ; -6 ; 0
Question 7. In the following response: SO2 + 2H2S → 3S + 2H2O
Which of the following statements correctly describes the nature of the substances involved in the
reaction?
A. Sulfur is oxidized and hydrogen is reduced
B. Sulfur is oxidized and no substance is oxidized
C. Sulfur is reduced and hydrogen is oxidized
D. Sulfur in SO2 is reduced and sulfur in H2S is oxidized
Question 8. CO2 gas has impurities - SO2. Which of the following solutions should be aired to remove
impurities?

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A. Ba(OH)2 solution (residual) B. Br2 solution (residual)
C. Ca(OH)2 solution (residual) D. NaOH solution (residual)
Question 9. Apply 31 grams of a mixture of metals: Fe, Al, Mg, Cu effect with excess dilute
sulfuric acid. After the reaction, a solution containing m grams of sulfate salt is obtained; 12.8
grams of an insoluble solid and 15.68 liters of H2 gas under standard conditions. What is the value
of m?
A. 85,4 gram B. 98,2 gram C. 86,8 gram D. 87,5 gram
Question 10. Which of the following is incorrect?
A. All reaction must reach a state of chemical equilibrium
B. Chemical equilibrium is dynamic equilibrium
C. Only reversible reactions have a state of chemical equilibrium
D. In the equilibrium of the reversible reaction, there always have reagents and products present
Question 11. Giving the same amount of aluminum with a volume of 0.1 M HCl, what is the highest
reaction rate when using aluminum in the following form?
A. Small tablet form B. Fine powder form, stir well
C. Thin sheet form D. Aluminum wire form
Question 12. Give the following chemical equilibrium:
N2 (k) + 3H2 (k) 2NH3 (k) (1) H2 (k) + I2 (k) 2HI (k) (2)
2SO2 (k) + O2 (k) 2SO3 (k) (2) 2NO2 (k) N2O4 (k) (4)
When changing the overall pressure of the system, which the chemical equilibrium is shifted?
A. (1), (2), (4) B. (1), (3), (4) C. (1), (2), (3) D. (2), (3), (4)
PART II. ESSAY (6 marks)
Question 1(2 marks). Write chemical equations to complete the following diagram, specify reaction
conditions (if any)

H2S 1→ SO2 2→ H2SO4 3→ SO2 4


→ BaSO3
Question 12(1.5 marks). Apply four solutions: NaCl, KBr, KNO3, K2SO4 store in separate jars, lost
the label. By chemical method, please recognize the above solutions? Write the chemical equation
occurs?
Question 13(2.5 marks). Giving 48,91 ml of hot, concentrated H2SO4 acid solution (density of acid
solution is: d = 1,84 g / ml) sufficiently effect with 33,6 grams of mixture A consisting of Cu and CuO.
After the reaction, solution B is obtained and 8.96 liters (under standard conditions) of SO2 gas are
released (the only reducing product).
a. Write the chemical equations happening (1 mark)
b. Calculate the percentage mass fraction of each substance in mixture A? (1 mark)
c. Calculate the percentage concentration of solute in solution B and the percentage concentration of
the solution of sulfuric acid used (0,5 mark)

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