Aits-1718-Crt-I-Jeea-Paper-2 - Sol PDF

1 AITS-CRT-I (Paper-2)-PCM (Sol.
)-JEE(Advanced)/18
FIITJEE JEE(Advanced)-2018
ANSWERS, HINTS & SOLUTIONS

CONCEPT RECAPITULATION TEST – I
PAPER-2
Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS

ALL INDIA TEST SERIES
1. C 24. D 47. C
2. A 25. B 48. B
3. B 26. B 49. C
4. ABCD 27. AB 50. BC
5. ABC 28. ABCD 51. ABCD
6. BCD 29. AC 52. ABD
7. ABD 30. AD 53. AD
8. CD 31. B 54. AB
9. D 32. C 55. D
10. B 33. B 56. D
11. 4 34. 6 57. 6
12. 1 35. 3 58. 6
13. 3 36. 4 59. 9
14. 5 37. 3 60. 9
15. 2 38. 5 61. 2
16. 3 39. 3 62. 4
17. 1 40. 1 63. 7
18. 1 41. 8 64. 4
19. 6 42. 1 65. 1
20. 2 43. 3 66. 4
21. 00002.66 44. 00370.65 67. 00610.66
22. 00000.75 45. 00089.40 68. 04008.80
23. 00000.08 46. 00005.70 69. 08275.20
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-CRT-I (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 2
Physics PART – I
SECTION – A
1. C
Kq Kq
Sol. Potential of centre of sphere =  Vi 
r r
where Vi = potential due to induced charge at centre = 0 [ qi = 0 and all induced
charges are equidistance from centre]
Kq Kq
 potential at point P =   Vi (For conductor all points are equipotential)
r r1
q q
 Vi  K   
 r r1 
2. A
Sol. Applying Snell’s law between the points O and P, we have
2 3 2

2  sin 600  sin 900   , 2  1
1  H  2 2 1  H2 
2  2 
1  H  
2
3
, H 
 3
 1

3. B
v v
Sol.   v, , ……
2 3
4 4
  4, ,
3 5
 f = 50, 150, 250 …..
4. ABCD
Sol. Let elongation in spring A, B and C be x1, x2 and x3 respectively.
Considering spring forces and constraint relations
x2 = 4x3 …(i)
x2 = 2x1 …(ii)
and x1 + 2x2 + x3 = x …(iii)
2 4 1
 x1    x ; x 2    x ; x 3    x
 11   11   11 
 x 11m
Also, F = 2K    T  2
 11  2k
5. ABC
fRT
Sol. U 
2
nRT 1
W  where PVx = constant. Here x  
1 x 2
3 AITS-CRT-I (Paper-2)-PCM (Sol.)-JEE(Advanced)/18
6. BCD
Sol. The system is equivalent to a binary system as shown in the diagram.
M  3R
r1  R
M  2M
r2  2R
Considering the circular motion of point mass m
GM2 GM
M22r2  2
; 2   1
36R 72R3
7. ABD
Sol. For ammeter,
i R  R A 
i  max s
R s 
 i  0.1mA for Rs  50  [as R A  50  and imax  50 A ]
For voltmeter,
V  imax (R A  R V )
 V  10V for R v  200 k
8. CD
Sol. If 1 = 0, 2  0
t1 = 0, balancing torques about A
cos 
N1 sin  = mg
2
mg
N1 tan  =
2
If 1  0, 2  0
T2 = 0, equilibrium cannot be attained.
If 1  0, 2  0
N1 = t2 = 2N2 ; N2 + t1 = mg
mg
N2 + 1N1 = mg ; N2 + 1(2N2) = mg ; N2 
1  1 2
9. D
Sol. Because resultant velocity is always perpendicular to line joining C and boat, so path is
circular with center at C.
10. B
Sol. Let any time the velocity of boat with respect to
river makes an angle  with CP.
Since along CP, net velocity is zero
u cos   u sin 

cos   sin      
2
Vresultant = u sin   u cos 
 u cos   u cos   2u cos  . C

u resultant

u
P
2ucos  ucos  d ucos 

Angular velocity    , 
2d d dt d
 /3 t
d u d
   dt  t  ln 2  3 
0
cos  0
d u
SECTION – C
11. 4
Sol. Here 3rd maxima is shifted by 3  10-4 m. It indicates fringe width increases by 1  10-4 m.
 D  0.5  D
Hence     1 10 4
d d
0.5 2  10 3  1 10 4
or  1 10 4 m or   4  10 7 m = 400 nm
d 0.5
12. 1
Sol. For the reflection at the concave mirror, I
u = – 10 cm; v = ?; f = – 15 cm
From the mirror formula, we have I
uf ( 10)  ( 15) 150 P
v=   = + 30 cm
uf 10  15 5
The positive sign indicates that the image is formed 45 cm
O
on the other side of the concave mirror,  35 cm
A
Now, the image formed by the concave mirror serves as a virtual object for refraction at
water surface which takes placed from air to water. So,
Apparent height
=
Real height
4
 AI'' = Apparent height =  × real height =  75 = 100 cm.
3
13. 3
Sol. Let T be the tension in the ideal string and ‘a’ be the acceleration of the blocks at the
instant of release. For the block on the left, the upward acceleration may be found from
T + k1x – mg = ma
For the block on the right, the downward acceleration may be found from
k2x + mg – T = ma
Adding the equations gives the acceleration of the blocks as
a = (k1 + k2)x/(2m)
However, subtracting the equations gives
T = mg – (k1 – k2)x/2
for maximum value of k1T will be zero.
 k  k2 
mg   1  x ; k1 = 300.
 2 
14. 5
Sol. There are four forces acting on the object; a normal force N
perpendicularly away from the incline, gravity mg vertically
downward, the applied force F in the direction of motion and
a static frictional force f before the object begins to move.
Since the object is about to slide along the plane, the
frictional force must be at its maximum value, f = sN. The
sum of the force components perpendicular to the incline is
zero, so,
N = mg cos   f = smgcos …(1)
On the other hand, the force components parallel to the surface of the incline are
sketched in the following free-body diagram.
Note that the frictional force must make some angle  as drawn because it initially
balances the other two forces on this diagram,
F = fcos …(2)
for the minimum applied force to get the object to start sliding, and
mg sin 
f sin   mg sin   f  ...(3)
sin 
Substitute eq. (3) into (2) along with
cos   1  sin2 
to obtain
1
F  mgsin  1 …(4)
sin2 
Also substitute eq (3) into (1) and rearrange to find
1  cos 
 s …(5)
sin  sin 
Now put eq. (5) into (4) to get
F  mg  2s cos 2   sin2  …(6)
where we required s > tan, as otherwise the object will slip even in the absence of an
applied force. Note that if k < s, as is usually the case, then the object will begin to
accelerate after it starts moving.
15. 2
q1 q2
Sol.  ; q1  q2  2Q0
C1 C2
 A  A
C1  0 ; C2  0
d0  vt d0  vt
q1 d0  vt

q2 d0  vt
 d  vt 
q2  0   q2  2Q0
 d0  vt 
 2d0 
q2    2Q0
 d0  vt 
2Q0
q2   d0  vt 
2d0
dq Q v
I  2  0 = 2 amp
dt d0
16. 3
Sol. Initially the rod will be in equilibrium if
2To  Mg with To = kxo …(i)
when the current I is passed through the rod, it will experience a force
F = BIL vertically up,
In equilibriums
2T + BIL = Mg with T = kx …(ii)
from (i) & (ii)
T Mg  BIL x BIL
 i.c.  1
To Mg xo Mg
Mg  xo  x 
or, B 
I L x0
Putting the values we get B  1.5  102 T .
17. 1
Sol. d  (2xdx)kxt 2
2 x dx
  kt 2 x3
3
R
d 4ktx 3

dt 3
4 ktx 3 2 2 2  Q
E2x  ; E ktx ; d   ktx 2  2 (2xdx)x
3 3 3  R
R
4 ktQ 4 4 ktQ R5
 d  x dx  =
3 R2 0 3 R2 5
At t = 15sec,  = 1 N-m
18. 1
dU k k mv 2
Sol. F=   ,  ..... (i)
dr r r r
1
En  mv 2  k lnr ..... (ii)
2
nh
mvr = ..... (iii)
2
k  n2h2  
Solving these En   1  ln  2  
2   4  mk  
E 2  E1
required ratio =  1.
E4  E2
19. 6
v v
Sol. f1   a(11  1) and f2   a(Z  1)
1 2
2 10  10
By dividing,   
1 Z  1 1 Z 1
 Z = 6.
20. 2
dNA dNB
Sol.  1NA ,  2λ1NA   2NB ,
dt dt
dNB
NB = maximum  0
dt
 21NA   2NBmax
21
 NBmax  NA
2
2
 NBmax  1 N0e 1t = 2.
2
SECTION – D
21. 00002.66
Sol. The observed reading will be = 10 mm + 1 × 01 mm = 1.01 cm
Mass 2.7369
density = = = 2.65654  2.66 gm/cm3
vol (1.01)3
22. 00000.75
v  v1
Sol. e 2
u1  u2
v 2   2 
1
u1
u1  v 2  2
u1  1 2   5  u1  2 
u1  2  5u1  10
12
u1   3m / s
4
v2  1 m / s
2
1  3  3
Kinetic energy of the given particle of mass 6 kg =  1  5      J
2  1 5  4
23 00000.08
Sol. D  1m, d  5  103 m
D
shift =  t1(1  1)  t 2 ( 2  1)
d
1 0.4
 3 
2(1.5  1)  1.5(1.4  1)  10 3   0.08m
5  10 5
Chemistry PART – II
SECTION – A
24. D
Sol. Relatively lowering will be minimum for [Co(NH3)3Cl3] as i = 1 and hence it will have
maximum vapour pressure.
25. B
4 0 6
Sol. 6 XeF4  12H2O  4 Xe 2 XeO3  24HF  3 O2
26. B
Sol. BF3 has back bonding
F
B F
F
27. AB
Ea
k  Ae Ea /RT or nk  nA
Sol. RT
28. ABCD
dP
Sol. At the point of maximum value of RDF 0
dR
 2Zr 2  a0
 2r    0; r 
 a0  Z
Where Z = 3 for Li , Z = 2 for He+; Z = 1 for hydrogen.
2+
29. AC
Hvap
Sol. At 400 K S vap  = 100 J/mol K.
Tb
30. AD
Sol. In (A) pressure of H2 is different
(D) conc of electrolyte is different
31. B
Sol. Antiaromatic
32. C
33. B
(Sol. for Q. no. 32 & 33)
Stronger the ligand field, more is .
SECTION – C
34. 6
Sol. P4  3NaOH  3H2O  PH3  3NaH2PO2
X+y=6
35. 3
Sol. 

2X  g  
 2Y  g   Z  g 
  2
1-  Total moles = 1  
2 2 2
2
KP 
 PY  PZ 
PX 2
2
 2  2   
  P . P
  2     2
 2
neglecting  compared to 1 and solving
 2 1     2
  P
 2   
1/3
 2K P 
  n3
 P 
36. 4
Sol. Nylon-6 & Teflon are homopolymer rest all are co-polymers
37. 3
Sol. Zr, Ni & Ti are refined by vapour phase refining.
38. 5
Sol. 

4H  MnO4 
 MnO2  2H2O
 1.5  5  2  1.25 
Go  3F    5F
 3 
x=5
39. 3
Sol. At 300 K volume be V
At 500 K volume = V + 2
V V
Using 1  2
T1 T2
V = 3L
40. 1
Sol. KMnO4 H2O2
N1V1 = N2V2
5  0.1  10 = 28  N2
5
N2  1 N = 5.6 V
28
5 5.6 5
N   1V
28 10 28
41. 8
r 1.7
Sol. = radius ratio = = 0.944
r 1.8
Hence C.No. 8
42. 1
H
Sol. Slope 
2.303R
H 1
so, 
2.303R 4.606
H = 1 cal
43. 3
Sol. H
H H
B B
H H
H
Bridge hydrogen are 3c – 2e bond
SECTION – D
44. 00370.65 K
P H  T2  T1 
Sol. 2.303log 2   
P1 R  T1T2 
T2 = 100oC P2 = 760 mm (1 atm)
= 373 K
T1 = ? P1 = 700 mm
 H = 540  18 cal/ mol
760 540  18  373  T1 
2.303 log   
700 2  T1  373 
T1 = 370.65 K
45. 00089.40 kJ
1
Sol. N2  O2  N  N  0
NN 2
OO
H   BER   BEP
 497 
  946.2     418  605.3   171.4 kJ / mol
 2 
RE = Hexp - Hcal = 82 – 171.4 = -89.4 kJ = 89.4 kJ
46. 00005.70
Sol. pH   logK a  log

Conj.base
 Acid
For - I : 4   log105  log
Conj.base 
0.5
Conjugate base = 0.05 M = salt
For – II: 6 = -log10–5 + log

Conj.base
0.5
[C.base] = [Salt] = 5 M
On mixing equal volumes
0.05  V  5  V 5.05
New conc. of salt NaA =  M
2V 2
0.5V  5V
New conc. of HA in mixed buffer =
2V
5.05
pH   log105  log  0.5M = 5.70
2  0.5
Mathematics PART – III
SECTION – A
47. C
Sol. Rotate the triangle in clockwise direction B B'
through an angle 60 . Let the points
A,B,C and P will be A,B’, B and P’
respectively after the rotation. P'
We have PA=P’A=3 4 90 3
And PAP '  60  PP '  3
Also CP=BP’=5 P
3
C A
So BPP ' is right angle triangle which BPP '  90 .
Now apply cosine rule in triangle BPA because
BPA  90  60  150 , PA=3 and BP=4, we can get AB
48. B
d2 f 1  x 
Sol. If f   x   0 and f ''  x   0  0
dx 2
d2 f 1  x 
If f   x   0 and f ''  x   0  0
dx 2
49. C
cot 1 
 tan x 
Sol. We have, f(  )    tan x  cot x  dx …(1)
tan1 
 
cot 1 
cot x
 f(  )   dx …(2)
1 cot x  tan x
tan 
 Adding (1) and (2), we get
1 1  
2
 22

f(  )  cot 1   tan1     2 tan1     tan1 
 4
  3 
Clearly, range of f() is   ,  .
 4 4 
50. BC
Sol. n (All couples are together)
 2  2  2  2  2  16 ways
 x  Total – 16
x  5! 16  105
H1 – W1
H2
W3
W2
H3
To find y, first Let H1, W1,H2 ,W2 sit in 2  2  4 ways

H1 – W1
W 2 – H2
Now H3 , and W3 can sit in 2 ways

 y  4 2  8
51. ABCD
Sol. a,b  ar, c  ar 2 are in G.P. where r  1
a  b  c  bx  1  r  r 2  rx …………(i)
2
 r  1  x  r  1  0
2
  0  1  x   4  0
 x  12  22  0,  x  3  x  1  0
x   ,  1   3,  
If x  1, then r  1  x  1 (rejected)
and x  3, then r  1  r  3 (rejected)
 x   ,  1   3,  
52. ABD
 1
 1 x , 0  x  1

 2
Sol. f  x   , 1 x  2
 x
 3 5
 x  1, 2  x  2

Clearly, f(x) is discontinuous and bijective y

function
3
1
lim f  x   , lim f  x   2 ’’
x 1 2 x 1
1
min  lim f  x  , lim f  x     f 1
 2
 x1 
x 1
 2
1
1/2
x' x
O 5/2
1 2 3
53. AD
2xz
Sol. y  x, y and z are in H.P.
xz
1 1 1 1
   
z y y x
x xy
 
z yz
54. AB
Sol. Let E: second drawn marble is green.
1  1 3 1  1 1  1  2 1  3 1    3 1 1 1  3 1  
P E     .1  .              .  .     
3  4 4 2  2 4  2  3 2  4 4    4 3 4 2  4 2  
1  73  73
  
3  48  144
n=144, m= 73 hence n-m= 71 and n-2m +2 =0
correct options are A & B
55. D
56. D
(Solution-(55 to 56)
Let P  h,k  be a point with the given property and assume h, k > 0
Now, without loss of generality, we take PC > PA
So, 2PC  PB  PD
2 2 2
 2h2  2  k  a    h  a   h  a   2k 2  2  h  a 2  k 2   h  a 2  k 2
 locus comes out to be x 2  y2  a2
So, circumcircle of square ABCD will be locus of point P.
SECTION – C
57. 6
Sol.  f  x   x 3  x 2 f ' 1  xf "  2   f "'  3 
 f '  x   3x 2  2x f ' 1  f "  2 
Put x 1
 f ' 1  f "  2   3 ………………..(i)

Again, f "  x   6x  2f ' 1 , f "'  x   6
Put x2
 f "  2   12  2f ' 1 ………………(ii)
Solving equation (i) and (ii), we get
f ' 1  5 and f "  2   2
 f  x   x 3  5x 2  2x  6
 f  2   f 1  6  f  0 
58. 6
2r 2
Sol. tr 
2r 2  60r  900
2r 2

 r  30 2  r 2
 t1  t 30  2
But t15  1
 Final sum = 31
So required answer is 7
59. 9
Sol. We have f  x   f   x   6x
 f  4   f  4   24
 N  f  4   24  2286  2310  2.3.5.7.11
Hence number of divisors  2n 1  25 1  16
60. 9
 2 2  2 2  
Sol. We have OP     e  e  a    e  e   2  e  e  e
t t t t t t t
 et   a.b 
  2  2   2    
2 2 
  a   a  9,  b   b  16 and a.b  a b cos 3 
 
 2 2 2  1

 OP  9 e t  e t  
 16 e t  e  t   
 2 e2t  e 2t .3.4.     13e2t  5e 2t  14
 2
d  2 5
Now OP  0  26e2t  10e2t  0  e 4t  ,
dt 13
5
So e2t 
13
 2  5   13   2
 OP  13    5   14  OP  2 65  14
min  13   5  min
   

 OP  2 65  7  2 a  b ,
min
So a  65, b  7
Hence  a  b   72 or
a  b 
9
8
61. 2
2
Sol. Given that AA T  4.I  A  4  A  2, so
 a11 a21 a31   c11 c 21 c 31 
adj A 4 
T
A  4A  4 1
 a12 a22 
a32    c12 c 22 c 32 
A A
a13 a23 a33  c13 c 23 c 33 
4 4
Now aij 
A
cij  2c ij 
A
 
cij As aij  2c ij  0  A  2
T
Now A  4I  A  AA T  A I  A T  2 I  A   2 I  A
2
 A  4I  2 A  I  0, so on comparing we get 5  2   
5
Hence 5  2
62. 4
 x2 
Sol. Let f "  x   6a  x  1 a  0  then f '  x   6a 
 2
 x   b  3a x 2  2x  b
  
 
Now f '  1  0  9a  b  0  b  9a
 
 f '  x   3a x 2  2x  3  0  x  1 and 3
So y  f  1 and y  f  3  are two horizontal tangent s  f  3   f  1  22  10  32

D
So is 4
8
63. 7
Sol. Given R :r  3:1.5  2  ABC must be equilateral.

So a  b  c  2R sin  R 3 (By sine rule)
3
2 3 4
 1  2  1  3  1 
Now a cot 2 A  b 2 cot 3 B  c 3 cot 4 C  R 3 
 3
  R 3   
 3
  R 3   
 3

R R2 R3 3  32  33 39
      13 3  m n
3 3 3 3 3
Hence  m  2n   7
64. 4
Sol. Since a, b, c, d are in A.P.
 b  a  c  b  d  c  D (let common difference)
 d  a  3d  a  d  3D and d  b  2D  b  d  2d
Also c  a  2D  c  a  2D
2 3 2 3
 Given equation 2  a  b   4k  b  c    c  a   2  a  d    b  d    c  d
3
becomes 2D  4kD2   2D   6D  4D2  D3
 9D2   4k  4  D  4  0
2
Since D is real   4k  4   4  4  9   0
 16 k 2  32k  128  0   4k  16  4k  8   0
 k   ,  2   4,  
Hence smallest positive value of k = 4
65. 1
Sol. Let x  10k.ak  10k 1.ak 1  ......  10.a1  a0 where ak ,ak 1.....a0 are its digits.
From a0 .a1.......ak  x 2  10x  22  0
 x  11
For every positive integer x using digits ak ,ak 1,.......a1,a0
a0 .a1a2 ........ak  ak .9k  ak .10k  ak 110k 1  ......  10.a1  a0
or, x 2  10x  22  x
11  209
Hence, x   13
2
So, x  11,13   only possible value of x is 12.
Hence answer is 1.
66. 4
16  3x  5x
Sol. S  8  4x
2
Now 3x  5x  16  x  2
3x  16  5x  x  8  x   2,8 
5x  16  3x  x  8

Now A 2  x    8  4x  4x  18  x  8  8  x   16x 2  64 64  x 2  

Let x 2  t  t   4,64  ,f  t   16  t  4  64  t   16 64t  t 2  256  4t 
 
 f  t   16 t 2  68t  256 ,f '  t   2t  68  0  t  34
f "  t   32  0
Maxima occurs at t=34
F(34)=16(30)(30)
 largest possible area = 120
SECTION – D
67. 00610.66
Sol. Given y  tan z
dy dz
 sec 2 z. - - - - (1)
dx dx
d2 y d2 z dz d
Now
dx 2
 sec 2
z.
dx 2

dx
.
dx
 
sec 2 z [Using product rule]
d2 z dz d dz
 sec 2 z.
dx 2
 .
dx dz
sec 2 z
dx
 
2
d2 y d2 z  dz 
 sec 2 z.    .2sec 2 z.tan z - - - - (2)
dx 2 dx 2
 dx 
2 1  y   dy  2
Now 1   
1  y 2  dx 
2 2
2 1  tan z   dz   dz 
 1 .sec 4 z.    1  2 1  tan z  .sec 2 z.  
sec 2 z  dx   dx 
2 2
 dz   dz 
 1  2 sec z    2 tan z.sec 2 z  
2
(3)
 dx   dx 
From (2) and (3), we have RHS of (2) = RHS of (3)
2
d2 z  dz 
sec 2 z. 2
 1  2 sec 2 z  
dx  dx 
2
d2 z  dz 
2
 2
 cos z  2  
dx  dx 
 k  2 so  305.33   k = 610.66
68. 04008.80
Sol. Let A  t1  ,B  t 2  and C  t 3  be the points on the parabola
4
Since AB  BC   1
 t1  t2  t 2  t3 
t 22  t 2  t1  t 3   t1t 3  4  0
2 2
  t1  t 3   4  t1t 3  4    t1  t3   16
2 2
  t1  t 3   4  t1t 3  4    t1  t3   16
also length of intercept cut off by tangents from y-axis is t1  t 3  4 , hence 1002.2 is
greater than 4008.80
69. 08275.20
Sol.  AB  AD   200
AB  AD  2a
2
BD2  AB2  AD2   2ae  D C
 AB  AD 2  AB2  AD2  2  AB  AD 
 4a2  4a 2 e2  400  b  10
A B
 
 a2 1  e2  b2  100  a  20
P  2  AB  AD   4a  80
Or 103.44P = 8275.20

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 f ' 1  f "  2   3 ………………..(i)

So y  f  1 and y  f  3  are two horizontal tangent s  f  3   f  1  22  10  32

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