1

PART-I
Answer All the Questions, [15 X1 =15]
Choose and write the correct answer:
1. Osmotic pressure (p) of a solution is given by the relation
a) p = nRT b) pV = nRT c) pRT = n d) none of these
2. The general formula for alkadiene is
a) CnH2n b) CnH2n-1 c) CnH2n-2 d) CnHn-2
3. Homolytic fission of covalent bond leads to the formation of
a) electrophile b) nucleophile c) Carbo cation d) free radical
4. Which one of the following is non aromatic ?

a) b) c) d)
5. With respect to the position of – Cl in the compound CH3 – CH = CH – CH2 – Cl, it is classified as
a) Vinyl b) Allyl c) Secondary d) Aralkyl
6. Haemoglobin of the blood forms carboxy haemoglobin with
a) Carbon dioxide b) Carbon tetra chloride
c) Carbon monoxide d) Carbonic acid
7. Which sequence for green house gases is based on GWP?
a) CFC > N2O > CO2> CH4 b) CFC > CO2> N2O > CH4
c) CFC > N2O > CH4> CO2 d) CFC > CH4> N2O > CO2
8. In which of the following equilibrium, KP and KC are not equal?
a) 2 NO(g) ⇌ N2(g) + O2(g) b) SO2 (g) + NO2 ⇌ SO3(g) + NO(g)
c) H2(g) + I2(g) ⇌ 2HI(g) d) PCl5 (g) ⇌ PCl3(g) + Cl2(g)
9. For an ideal solution
a. Δ𝑉𝑚𝑖� = 0 b. Δ𝑉𝑚𝑖� ≠ 0
c. Δ𝑉𝑚𝑖� > 0 d. Δ𝑉𝑚𝑖� < 0
10. Which of the following aqueous solutions has the highest boiling point ?
a) 0.1 M KNO3 b) 0.1 M Na3PO4
c) 0.1 M BaCl2 d) 0.1 M K2SO4

11. Lassaigne’s test for the detection of nitrogen fails in

a) H2N – CO– NH.NH2.HCl b) NH2 – NH2. HCl

c) C6H5 – NH – NH2. HCl d) C6H5 CONH2
12. Which of the following group has highest +I effect?
a. 𝐶�3 − b. 𝐶�3 − 𝐶�2 −
c. (𝐶�3)2𝐶� − d. (𝐶�3)3𝐶 −

(𝑖)�3
(𝑖𝑖)𝑍� /�2�
13. (𝐶�3)2𝐶 = 𝐶(𝐶�3)2 → � . �𝑖�
a) Acetic acid b) propanone
c) acetaldehyde d) ethanol

14. The name of C2F4Cl2 is ___________

a) Freon – 112 b) Freon – 113
c) Freon – 114 d) Freon – 115
15. The pH of normal rain water is
 2

a) 6.5 b) 7.5 c) 5.6 d) 4.6

PART II

Answer any six questions (Q.No 24 is compulsory; answer any five from the remaining)
[6X2=12]

16. What is electrovalent bond?

17. State Henry’s law.
18. State law of mass action.
19. Predict the number of lone pair and bond pair electrons and mention the shape of 𝐶𝑙�3 𝑎�𝑑 𝑁�3
using VSEPR theory.
20. What is osmosis?
21. Define metamerism.Give an example.
22. Identify the functional group in the following compounds.
(a) acetaldehyde (b) oxalic acid
(c) di methyl ether (d) methylamine
23. What is chemical oxygen demand(COD)?
24. Write the IUPAC names of the following.

a) b)

PART-III
Answer any six questions (Q.no 33 is compulsory, and answer any five from remaining) .
[6 X 3 = 18]
25. State Lechatlier principle.
26. Define Molarity. If 5.6 g of KOH is present in 250 ml of the solution, calculate the molarity of the
solution.
27. What is reaction quotient’Q’? What happens when Q>KC?
28. Define hybridization.
29. State Markonikov’s rule.
30.How will you detect the presence of sulphur in organic compound?
31. What is ‘Green house effect’?
32. What is DDT?How it is prepared?
33. 0.24g of an organic compound gave 0.287 g of silver chloride in the carius method. Calculate the
percentage of chlorine in the compound.

PART-IV
Answer all the Questions [5 X 5 = 25]
34. a. (i)Derive the relation between Kp and Kc. (3)
(ii)Explain the effect of catalyst on an equilibrium reaction.(2)
(Or)
b. (i)Explain Fajan’s rule. (3)
(ii)Define bond order. (2)

35. a. (i)State Raoults law and obtain an expression for lowering of vapour pressure when a non
volatile solute is dissolved in a solvent. (3)
(ii) Define the term ‘isotonic solution’.(2)
(or)
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b. (i) Draw the M.O diagram of O2 molecule and calculate bond order.(3)
(ii) Draw the Lewis dot structures for sulphur trioxide and HNO 2 (2).

36. a. (i) What are electrophiles and nucleophiles? Give suitable examples for each.(3)
(ii) Give the structure for the following compound.(2)
1) 3- ethyl - 2 methyl -1-pentene 2) 2 - methylbutan - 3 - ol
(or)
b. (i) Write the conditions for optical activity(2)
(ii) Write note on Thin layer chromatography.(3)

37. a. (i) Explain the mechanism of SN1 reaction.( 3)

(ii) Write notes on i)Finkelstein reaction and ii)Sandmeyer reaction.(2)
(or)

b.(i) Describe the mechanism of Nitration of benzene. (3)

(ii) How does Huckel rule help to decide the aromatic character of a compound. (2)

38. a. (i) Write the preparation of the following compounds using CH3MgI(3)
i) ethanol ii) acetaldehyde iii) acetic acid
(ii)Write Wurtz- fittig reaction (2)

(or)

b. (i)How does chemical smog differ from photochemical smog?(3)

(ii) Write any two harmful effects of acid rain.(2)