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Mogol, Yluwei
Pirote, Chester
Ramos, Cyrille
12 STEM-4
According to the Study Fire Retardant Europe (FRE) 2018.,Fire Retardant was first
created around 400 B.C., but the need for them didn’t increase drastically until the 17th Century.
In 1735, The English patent no 551. was granted to Obadiah Wyld for perfecting a mixture of
chemicals used to treat wood, paper and textile for improving their fire resistance. This was the
Base from the study of specialist work clothing on 2014., Fire retardant is a substance
that composed of chemicals that are supposed to slow ignition and prevent fires. There are
chemicals that used as a fire retardant such as Alum, Potassium alum is used as a fire retardant to
render cloth, wood, and paper materials less flammable. Romans covered their boat with vinegar
and alum before encasing it with clay to prevent the spread of fire. Borax is also used as fire
retardant for it tends to reduce the flame spread, but it can promote smoldering or glowing.
Obadiah Wyld received a patent for the first flame retardant mixture of alum, ferrous sulfate
and borax to be used on fabrics. This formulation containing borates in flame retardants still has
merit today.
Fire retardants is used all over the world and it can be used in products made from
plastics, textiles, foams or wood, to delay ignition, slow down the combustion process, or even
make the material self-extinguishing. Therefore, they play a crucial role in fire protection. They
not only reduce the risk of a fire starting, but also the risk of the fire spreading, leaving more
There are studies and tests that carried out in Europe and in the United States, Studies
confirm that flame-retarded materials can provide valuable escape time, as they slow down the
spread of a fire. For example, a series of tests performed on furniture in the United States showed
a longer ignition time in flame-retarded upholstery than in those without flame retardants.
Emmanuel Tupas stated in his article on 2018 that the Philippines Fire Hazard is
continually increasing. From 2013 to 2017, the BFP recorded a total of 77,724 fire incidents, or
an average of 15,545 fire incidents every year or 42 fire incidents a day. During the period, the
total estimated damage to property reached P23. 273 billion or an average of P4. 65 billion every
transportation modes and products in our daily lives, the potential of fire hazard is increasing
that’s why the use of flame retardants makes sure that people have a prolonged evacuation time
and therefore they ensure that fewer people are killed or injured in fires.
This study aims to achieve the effectiveness of using alum and borax to make the
alternative fire retardant. This study also aims to compare the effectiveness of alternative fire
retardant to natural fire retardant in terms of durability, affordability, and efficiency. This study
is beneficial not just to us fellow researchers but also to those people who will read this research
for it can help to reduce the fire hazard especially in the Philippines.
This study aims to achieve the effectiveness of using alum and borax to make an
alternative fire retardant and to compare it to a fire retardant coating that exist in the market. This
1.) Is there an effective collisions when you mix alum and borax that can help to make an
2.) Is there a difference between alternative fire retardant using alum and borax and a fire
retardant coating product that exist in the market in terms of:
a.) Durability?
b.) Affordability?
c.) Efficiency?
3.) Is there a significant difference between the use alum and borax as an alternative fire
retardant coating and a fire retardant coating that exist in the market?
The study entitled “Effectiveness between the use of Alum and Borax as an Alternative
Fire Retardant Coating and a Fire Retardant Coating Product that exist in the market. ” will focus
.Further, the study will indulge through experimentation and test. Moreover, the results of the
study will be compared to the fire retardant coating that exist in the market. This study is only
limited to the analysis of the results by the experiment and test and will only circumscribe
Over the past decades fire incident are increase in number especially at the urban spaces
This will be beneficial for the Bureau of Fire Protection, because the study is opted to test
the feasibility of the alternative fire retardant. As the study will be about the effectiveness and
advantages of the alternative fire retardant. This sector of the Government can recommend it to
the general public to use it to lower the probability of the hazard of fire incidents.
This will be beneficial for the Local households as the studies revolve about advantages
of the use of fire retardant. As the fire- retardant acts as a useful barrier that prevents the spread
of fire within a period of time in case of fire incident. In addition, it will lower the potential
Future Researchers
The study will be beneficial for the future researchers that conducted a study that will
revolves about fire retardant. As it will serves as their foundation and a source of information.
1.5.1 Foreign
According to (Synchwin). Fire retardant paint is designed to increase fire safety by providing
additional time to evacuate buildings in the event of fire. The gas prevents the fire from affecting the
underlying surface and so, fire retardant paint slows down the burning process. The coating can be
applied on critical areas that become fragile when exposed to high heat. For example, metal structures &
wood.
The fire-retardant properties of paint and coatings as well as other materials are measured by
We all know that wood burns fast, yet it is a very common building material in the Philippines.
Today’s technology, fortunately, allows a formula for fire retardant paint for wood to make buildings
safer also in case of fire. Even though the paint for wood does not prevent the structures from catching
The coating is suitable for wood, lumber, plywood and timbers for interiors or exteriors. Clear
fire-retardant pain for wood exists as lacquer-like hard finish, preserving wood treatment and clear fire-
retardant varnish for wood. It is one of the most popular fire preventing coatings because it does not affect
the appearance of the wood, but still provides appropriate protection from fire.
It can take just a few minutes for unprotected steelwork in a building to attain temperatures of
around 550ºC in a fire. At this temperature, steelwork loses its load bearing capacity and the structure is
the fire under control. Fire retardant paint can protect these structures from hazardous situations.
This is again an example of meeting the Philippine safety standard criteria. The coating it will
allow developers to meet the outlined safety standard in a very cost-effective manner. The special paint
offers up to and including 120 minutes of fire protection and can be applied both on and off site. It is a
waterborne product with low odor, often chosen as the ideal solution for on-site application.
Based to (E. Rasit, L. Erkan, O. Ceman, & Y. Fatih). The effects of fire retardants paint on
combustion properties of fir (Abies bornmülleriana M.) were examined. For this purpose, fire retardants
paint was applied on the surface of test sample according to company’s suggestions.
Wood has many good properties from the point of view of processing, physical and mechanical
properties, aesthetic, environmental and health aspects. Wood continues to play an important role as a
structural material in today’s high-tech society. In many countries, wood is widely used as a building
material: in some areas as the main construction and decoration material (Toker et al., 2012).
As lumber and in reconstituted products, wood is commonly used for house siding, trim, decks,
fences, and countless other exterior and interior applications (Cassens et. al., 1991). Wood material has
several advantages such as good mechanical properties but shows a low fire resistance (Bednarek and
Kaliszuk 2007). Borates have several great advantages as wood preservatives as well as imparting flame
retardancy, providing sufficient protection against all forms of wood destroying organisms, have low
mammalian toxicity and low volatility, they are moreover colorless and odorless (Hafizoglu et al., 1994;
Murphy, 1990; Yalinkilic et al., 1999; Drysdale, 1994; Chen et al., 1997).
Combustion properties of wooden materials. Uysal and Kurt studied combustion properties of
oriental spruce (Picea orientalis L.) impregnated with boron compounds. A boraxboric acid 10% solution
was found to be the most successful fire-retardant chemical (Uysal and Kurt, 2005). Yapıcı et. al. studied
oriental beech. It was shown that the highest mass reduction occurred in samples impregnated with boric
According to (T. Mariappan,). There is always misconception about inhibition of fire by using
coating of either fire retardant or fire resistance. Figure 1 shows the development of fire in a
compartment, which distinguishes the usage of coating in a stage of fire. For instance, the material
properties play an important role in prior to flashover, which will be controlled by fire retardant coatings
(ignition, flame spread, release of heat, smoke, and gases), whereas fire resistant coatings are mainly
predominated in protection of structures that occur after flashover, that is, phase of fully developed fire.
Post-flashover fires (temperature above 600°C) are considered as hazardous fires for structures.
In general, conventional organic surface coating is easily ignitable, melts, drips, and it may cause
severe injury and damage to the substrates in the event of fire. Therefore, coatings that are designed to
formulate should not contribute a significant amount of fuel to the fire and, at the same time, limit the
flame spread and smoke development. Fire retardant coating is one of the easiest, oldest, and most
efficient ways to protect the materials against fire. This approach does not cause chemical modification of
the substrate, but rather the formation of a protective layer which alters the heat flux to the substrate and
Typically, the flammable materials are easily combustible and rapidly growing in a fire (reaction-
to-fire), in terms of the spread of fire or propagation of fire, up the stage when flashover occurs in a
compartment. Flashover can occur quickly in seconds or slowly depending on the speed of fire growth
rate. Wood is the most frequently used combustible products in addition with polymers (plastics and
clear or transparent varnish paints, pigmented intumescent reactive coatings, and surface impregnations
are utilized in wood to enable the restriction of growth and/or spread of fire.
According to (S.L,).The construction sector has evolved a lot in recent years and more and more
requirements are demanded when building a building. In addition to considering the sustainability and
isolation of buildings, the focus has also been placed on safety. In this sense, one of the most important
The fire-retardant paint helps that fire does not spread in case of fire in a building. Therefore, it is
one of the most efficient measures to prevent fire spreading rapidly, as it contributes flame and smoke not
to spread. Fire-retardant paint is essential especially when it comes to residential buildings, since
containing fire allows people inside the building to have more time to leave it.
It is important to differentiate fire retardant paint from intumescent paint. The first one avoids the
spread of the flame, while the second one reacts when there is an increase in temperature in the building
by swelling and creating a thick layer of foam that insulates the elements that cover it, containing the fire
Fire-retardant paint does not prevent fires from occurring but delays the expansion of fires.
There are different types and, depending on each type, it can be applied on metal, wood,
A study conducted by K. Wally. The definition of a fire-retardant coating is not clear-cut and
often confused or interchanged with the term “fire-resistant,” but there is a distinction. A fire-resistant
coating doesn’t ignite or support flame when an ignition source is applied, while a fire-retardant coating
protects the substrate from burning. In performance-based testing, the mechanism of protection is
Fire retardant coatings are largely used in two important parts of everyday life: occupancy and
mobility. By this I mean, fire retardant coatings are most used within the built environments we occupy or
the modes of transportation we use to move between them. The three most important application areas for
Building products: structural steel, interior and exterior cladding (wood, composite)
Fire resistance is typically evaluated by impinging an ignition source on a test sample under
controlled conditions and measuring one or more of the following performance parameters.
Flame Spread measures the extent of the burned surface from the original site of ignition.
Self-Extinguishing is defined as the ability to extinguish a flame after the ignition source is
sample.
Smoke Toxicity requires specific chemical analysis for targeted toxic components in the smoke
Heat Release uses calorimetry to determine peak and average energy produced by combustion of
Compounds that generate free radicals interfere with the oxidation/reduction reaction, driving
Intumescent agents increase in volume and create an non-flammable char layer which insulates
Fire retardants which absorb the heat of combustion when undergoing dehydration or
endothermic decomposition reactions act by cooling the flames below the ignition temperature.
According to (C. Future).Investigations into taming fire go back centuries and, as with most
things, it was the Chinese who first innovated solutions. They covered wood with vinegar and alum
before encasing it with clay to prevent the spread of fire, a tactic copied by the Romans to protect the
Gay-Lussac’s Method
He described two methods of fire resistance, both of which involved the use of salts – ammonium
phosphates, a salt of ammonium and phosphates, and borax, a salt of boric acid. The former has a low
melting point, forming a protective glassy layer over the material allowing it to absorb more heat before
the agents would wash out of fabrics rendering them impressive but ultimately useless for clothing.
The development of flame-resistant fabrics didn’t really accelerate until the military found a use
for it. The American Armies Quartermaster Corp’s search for flame retardant uniforms allowed for a huge
injection of money and resources into research and development and advanced our understanding a great
deal. Commercial ventures also brought about the invention of methods that chemically altered the
cellulose molecules of the cotton increasing the fire resistance while maintaining strength and durability.
Changes in Legislation
The Flammable Fabrics Act of 1953 brought in strict regulations on how clothing was made and
sold commercially. Clothing was no longer made from flammable textiles and an immense amount of
money was invested developing flame-resistant clothing that could be made cheaply.
A study conducted by S. Kara. First, you'll need baking soda. This recipe will make a little over 1
cup of paint. For a quart of paint, quadruple the amount, but remember that it dries out quickly.
Mix 1/2 cup of baking soda with 1 cup of latex paint. Make sure to mix it well—you’ll need the
consistency that my mixture had in the video. Lastly, add a few tbs of cold water.
Mix your ingredient until they create a thin, non-grainy texture. It takes a bit of time to dissolve
all the baking soda, but, as you can see in the video, once it’s dissolved it will look just like the chalk
This one cup of paint was more than enough to paint my end table and coffee table. I’m loving
you've ever searched the refrigerator for food after school, you may have noticed that it also usually
contains all sorts of other items that don't make a good after-school snack.
The door full of condiments contains items that are usually only good if they're added to
something else. You're also likely to find other items that are used in the cooking process, such as
vinegar. You might also find a box of baking soda intended to absorb odors in the refrigerator.
If you can't find edible food, you might be tempted to conjure up your own concoction with some
of the things you found inside. Before you become a mad scientist in the kitchen, though, you should
know that some of those things might not make a tasty treat.
Take baking soda and vinegar, for example. Mixing those two ingredients will get you a reaction,
but it won't taste good. In the right amounts and containers, the mixture can even be downright explosive.
Baking soda and vinegar react chemically because one is a base and the other is an acid. Baking
soda is a basic compound called sodium bicarbonate. Vinegar is a diluted solution that contains acetic
acid. The baking soda and vinegar reaction is two separate reactions. The first reaction is the acid-base
reaction.
When vinegar and baking soda are first mixed, hydrogen ions in the vinegar react with the
sodium and bicarbonate ions in the baking soda. The result of this initial reaction is two new chemicals:
The second reaction is a decomposition reaction. The carbonic acid formed as a result of the first
reaction immediately begins to decompose into water and carbon dioxide gas.
Just like carbon dioxide bubbles in a carbonated drink, the carbon dioxide (that formed as the
carbonic acid decomposed) rises to the top of the mixture. This creates the bubbles and foam you see
expect an impressive eruption! Many science teachers use this simple chemical reaction to teach students
about chemistry. If you've ever made a homemade volcano as a science experiment, then you know
A study conducted by R. J. Linhardt. Several biobased fibers such as wood, sisal, jute, flax,
abaca, banana, oil palm, pineapple leaf, and bamboo have been studied as reinforcements for polymers.
Among natural fibers, wood was the most extensively and more frequently used reinforcement for
polymers. However, due to expensive manufacturing process of wood fibers, inexpensive and sustainable
Properties of the flame-retardant urea formaldehyde (UF) board made from saw dust fibers were
investigated. Flame retardant chemicals that were evaluated include boric acid (BA) and borax (BX)
which were incorporated with saw dust fibers to manufacture experimental panels. Three concentration
levels, (0.5, 1, and 5%) of fire retardants and 10% urea formaldehyde resin based on oven dry fiber
weight were used to manufacture experimental panels. Physical and mechanical properties including
water absorption, modulus of rupture (MOR), and modulus of elasticity (MOE) were determined. The
results showed that water absorption and bending strength decreased as the flame retardant increased. The
highest concentration of (BA + BX) enhanced the fire retardant more than the lower ones. Scanning
According to (U. Oneugbu, & V. N. Ejimofor). Fire is a worldwide problem which claims lives
and causes significant loss of properties. The effectiveness of potassium aluminum sulphate (alum) as
flame retardant on kraft sheet was studied by incorporating varying concentrations of it: 0.1M, 0.2M,
Loss of life and possessions caused by the fire hazards due to the use of polymeric materials has
aroused much concern among government regulatory bodies, consumers and manufacturers Zyon (1994),
flame retardants are used to reduce combustibility and suppress the smoke or toxic fume production from
the polymers. Flame retardants denote that material which when added to or chemically incorporated in
the formulation of flammable materials (mainly polymers), substantially suppresses/quenches the ease of
ignition or flame propagation of the material Kroshwitz, (1987). Flame-retardant can be classified as:
durable-finishes, semi-durable finishes and non-durable finishes. For a material to burn, the surface
receives heat from an external source as well as from the burning mass. Heat losses occur in two ways,
viz, that needed for the gasification of the polymer and by other usual methods of convection, conduction,
radiation, dripping, etc. The function of a flame retardant is to interrupt pyrolysis or combustion. Flame
retardancy can be achieved through the following agents Eboatu (1992) additives which evolve non-
flammable gases, such as carbon dioxide, water, hydrogen chloride, Sulphur dioxide, ammonia, etc. and
sometimes also raise the flash points of the gaseous pyrolysis. Again, there are materials capable of
forming glassy coatings on the pyrolysis/burning mass. Finally, there are materials forming low
flammable char. The aim of this study is to produce cheap and harmless flame-retardant that can rise the
Materials
The molar mass of crushed alum which is K2SO4.Al2 (SO4)3.24H2O was first calculated as
948(g)mol-1 and was times by different concentrations of moles which are O.1M, O.2M, O.3M, O.4M,
O.5M and O.6M. An empty beaker was weighed on an electronic weighing balance for each
concentration of mole and the value was added to the sum got from multiplying the molar mass of alum
by different.
1.5.2 Local
According to the Bureau of Fire Protection (2015), there have been 17,138 fire incidents
in the year 2015. The fire incidents involved structural buildings such as residential, industrial,
mercantile, storage, business, and education. It also involved forest and motor vehicular. The
ideal response time of BFP is five to seven minutes but it is not usually attained due to some
factors and these factors as stated by Vallejo (as cited by Mayuga, 2018) are traffic congestion,
obstruction of roads, and the narrow streets that the fire trucks are trying to pass by to get to the
affected area. One of the solutions to prevent the fire from spreading so that the time span
mentioned earlier will be expanded, making it enough for the firefighters to come on time, is by
using fire retardants. Fire retardants as defined by American Chemistry Council (2018) are added
According to Hopper (2013), they are often used in areas where a high degree of abuse
and variations in temperature are present, and fire retardants enhance this ability of enamel paint.
Usually, fire retardants contain chlorinated alkyds or brominated epoxy resin and filled
ENAMEL PAINT film exposure. However, according to Weil (2014), fire retardants are harmful
to health because of its chemical composition. It is said that the chemicals used in most fire
that are given off during fire incidents. This study aims to make an organic fire retardant paint by
the use of B. glabra leaves extract. This plant has flowers that are used for ornamental purposes.
It is found growing throughout tropical countries. It has a thin paper-like bracts that is why it is
also called a paper flower with different vibrant colors also known as “Bunga kertas” and these
bracts or leaves from the axil of which a flower grows are rich sources of polyphenol
compounds, which act as natural antioxidants (Markandan, Abdullah, Musa, Subramaniam, &
Stockham, 2016). Due to the chemical components of B. glabra, its leaves extract will be
substituted as an additive component in making fire retardant enamel paint in order to avoid the
Agriculture plays an important role in the country's economy. The Philippines is famous for its
crops like coffee, corn, coconut, etc. Along with these crops, rice tops the list and find it as
Production of rice requires milling which is a popular machining process in the modern
industry because of its ability to remove materials with a multi-point cutting tool at a faster rate
with a reasonably good surface quality (De Lacalle, 2011). In this procedure, by-products of rice
are removed, such as the husk and the bran. Other by-products in rice production such as rice
straw also contribute in the challenge that is faced by the agriculture sector today, and that is the
reached a record high of 14,197 fire incidents in the Philippines. Fire incidents are mainly
occupied by residential houses, (Philippine Statistics, BFP) because most of the residential
houses in the country are made with light materials or mostly wood, whereas wood is a material
that is vulnerable to fire and can rapidly spread (Lowden, L.A. & Hull, T.R., 2013). In the
production of structures and furnishes, varnish coating on wood is applied. Varnishes are used to
achieve film for gloss, as well as to create a protective finish in the wood.
Rice husk ash has been widely utilized in different products such as building materials
(fibre boards), fuel, production of furfural, and as cattle feeds (The People’s University). Recent
studies had discovered that rice husk contains higher silica content, which results in better
thermal properties (Ekaputri & Antoni, 2016). In a study conducted by Hung (2013), results
show that rice husks present very good non-fire-aflame properties, which can be used in fire-
resistant applications.
The Philippines, being an agricultural country, may generate rice husk as an alternative
component in creating a fire retardant varnish. The country has a higher chance of making these
products because of the presence of rice husks in a larger quantity that would compensate to
solve both the agricultural problem and alarming fire cases in the Philippines.
1.6.Conceptual Framework
Potassium
Alum (0.3
M) Chemical Alternative Fire
Borax (2.5 Mixtures Retardant Coating
table spoon)
Paint ( 6 oz-
1 gallon )
1.7.Hypothesis
Alum and Borax and a Fire Retardant Coating product that exist in the market.
HA: There is significant difference between Alternative Fire Retardant Coating using
Alum and Borax and a Fire Retardant Coating product that exist in the market.
Borax- a material that can be used as an additive to make an alternative fire retardant coating due
Durability- The Alternative Fire Retardant Coating must have the ability to resist damage in a
Fire retardant - A substance that is applied to fabric, wood, or other material in order to make it
Potassium alum - a crystalline solid, aluminum potassium sulfate, that will be used as an additive
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