To determine the empirical formula of magnesium AIM oxide. Problem What is the empirical formula of magnesium oxide ? Statement
Hypothesis The empirical formula for magnesium oxide is MgO.
Manipulated variable : Magnesium ribbon
Variables Responding variable : Mass of magnesium oxide Fixed variables : Excess water / Magnesium ribbon
Crucible with lid, tongs, Bunsen burner, Tripod stand,
Apparatus Pipe-clay triangle and balance.
Materials 10 cm magnesium ribbon, Sandpaper
Figure
1. A crucible and its lid are weighed.
2. A 10 cm length of magnesium ribbon is cleaned with 氧 化 物 sandpaper to remove the oxide layer on its surface. 3. The ribbon is rolled up / coiled loosely and put inside Procedure the crucible. The crucible and its lid and content are weighed. 4. The apparatus is set up as shown in Figure. 5. The crucible is heated strongly without its lid. 6. When the magnesium starts to burn, the crucible is covered with its lid. 7. Using a pair of tongs, the lid is carefully raised a little at 间 隔 intervals. 8. When the burning is complete, the lid is removed and the crucible is heated strongly for 1 to 2 minutes. 9. The crucible with its lid still on is allowed to cool to room temperature. 10. The crucible with its lid and content are weighed again. 11. The processes of heating, cooling and weighing are repeated until a constant mass is obtained. The constant mass obtained is recorded. Description Mass(g) Crucible + lid x Crucible + lid + magnesium y Crucible + lid + magnesium oxide z Magnesium y-x Oxygen z–y Data & Observation Element Magnesium, Mg Oxygen, O Mass (g) y–x z-y Number of y–x z–y moles of atoms 24 16 Simplest ratio of moles 1) Magnesium reacts with oxygen in the air to form white fumes ( magnesium oxide ). Mg + O2 → 2MgO
2) Why is the magnesium ribbon cleaned with
Discussion sandpaper before use ? to remove the oxide layer on the surface of magnesium ribbon.
3) State the reasons for the following.
a) Covering the crucible with lid as soon as the magnesium starts burning to prevent the escaping of white fumes.
b) Raising the lid at intervals during heating to allow
oxygen to enter to react with magnesium.
c) Heating, cooling, weighing process is repeated
until a constant mass is obtained to ensure all the magnesium had reacted completely.
4) This method can also be used to determine the
empirical formulae of oxides of other high reactivity metals such as calcium oxide, aluminium oxide and zinc oxide.
Conclusion The empirical formula for magnesium oxide is MgO.
o Magnesium ribbon is cleaned with sandpaper.
- to remove the oxide layer on the surface of magnesium ribbon.
o Covered the crucible with lid immediately when
magnesium starts to burn. - to prevent the escaping of white fume. Precautions o The lid is raised a little at intervals. - allow oxygen gas to enter to react with magnesium.
o Heating, Cooling, Weighing process is repeated
until a constant mass is obtained. - ensure all the magnesium had reacted completely with oxygen.
The Strength, Fracture and Workability of Coal: A Monograph on Basic Work on Coal Winning Carried Out by the Mining Research Establishment, National Coal Board