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Billet Defects: Off-corner Cracks

Formation, Prevention and Evolution

Jorge Madias
Consultant
metallon
Content
Introduction
Characterization
Formation mechanism
Prevention
Evolution during rolling
Conclusions
About metallon
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References
ArcelorMittal
Gerdau
Tenaris
Ternium
Introduction
Drivers behind preparation of the review
Series of review papers on billet, bloom and beam
blank defects at AISTech, since 2011
Troubleshooting work on off-corner cracks at
several Latin American steel companies
Introduction
 Longitudinal off-corner cracks
 Internal defects that may occur in billets, blooms, slabs, thin slabs
and beam blanks
 Solidification cracks located in some of the eight typical locations,
perpendicular to the surface
 One or more parallel cracks at a given position
 Several mm below the surface, but under certain conditions they
may open to the surface
 Often, they appear below a surface depression
 Manganese sulfides may refill them.
 Continuous casting
 In extreme case, shell breakouts
 Rolling
 Partially or complete welding
 Manganese sulfides remain
 Machining, forging or heat treating
 Defects may occur
Characterization
Macroetching or Baumann printing a transverse
cut of a billet / bloom

130 x 130 mm SAE 1030 steel billet cast


with metering nozzle and oil lubrication,
macroetch with HCl 50%, 70oC
Characterization
Comparison with a chart (plant specific)

Grado I Grado II
Acciaierie Venete, Padova, Italy

Grado IV
Characterization
Countings for improvement plan
Positions affected
Minimum distance to the billet surface
Crack length
Total crack length in a transverse cut
Characterization
Path between columnar grains, occupying
interdendritic spaces
Partially filled with manganese sulfides
For high Cr steels, like valve steels, chromium
carbides may take part in the refilling of the cracks

Macroetching of 240 x 240 blooms; Acciaierie Venete, Padova, Italy


Formation mechanism
 Early research by Brimacombe, Hawbolt
and Weinberg
 Sampling in three billet casters
 Design and operating conditions typical
of those times (short molds, some of
them straight, small sections, low
casting speed)
 Macroetching, Baumann prints,
metallography with several etchants,
cracking under liquid N, SEM
observation of the open cracks
 Solidification modeling
 Off-corner cracks attributed to faster
contraction in billet corners; separation of
the mold, early air gap formation
 Then, less heat transfer in the corner
zones
 Solid shell thinner than in face center
 Down the mold, and after mold exit,
when ferrostatic pressure is enough,
bulging occurs
 Tensile forces acting on the thin shell
may start the crack
Formation mechanism
More recent research by Drs. Park and Brian
Thomas, including the effect of the air gap in a
solidification model, came to the conclusion that
the corner is hot, not cold
The same tensile stress by bulging in the lower
mold or after exit, give place to
Internal off-corner cracks with smaller mold radius
Open corner cracks with larger mold radius
 Powder casting better than oil, given certain
conditions
Formation mechanism
Small and large corner radius; oil vs. powder
Formation mechanism
Critical casting speed to avoid off-corner cracking
Prevention
Mold design
Metallurgical measures
Operating conditions (mold and first cooling zone)
Summary of trobleshooting at several plants
Prevention
Mold design
Improvements in mold design are multipurpose,
including measures to solve rhomboidity, off-corner
cracks and other solidification defects, particularly
at high casting speeds
Mold taper moved from single to double to three /
four different tapers to parabolic taper
Then to transverse variations in taper like
CONVEX and DIAMOLD molds, and modifications
in water cooling like in INVEX and Powermold
Prevention
Mold design
CONVEX mold
Transverse changes in taper
Prevention
Mold design
DIAMOLD mold
Differentiated taper in the corners
Prevention
Mold design
INVEX mold
Slots in water side
Differentiated taper in the corners
Large radius without longitudinal corner cracking

150 x 150 mm billet mold 265 x 385 mm bloom mold


Prevention
Mold design
Powermold / Ecopower mold
Holes in the copper, replacing the gap between
water jacket and mold
Prevention
Metallurgical measures
Mn/S ratio (depends on sulfur content)
Mn/Scritical=1,345 x S (-0.7984)
SAIL Ranchi, India

125 x 125 mm medium


carbon steel billets for
forging, open casting
Prevention
Metallurgical measures
Superheat
Higher superheat: more cracking
Less shell thickness, easier bulging and more
probability of off-corner cracks formation
60 billets of HVN valve
steel, submerged cast,
Villares Metals, Sumare
plant, Brazil
Prevention
Metallurgical measures
 Chemical analysis
Most of the studies on off-
corner cracks relates to
steels in the range of 0.15 –
0.35% C
 Partial coincidence with the
range favorable for higher
rhomboidity
0,35% C is prone to off-
corner cracks, in particular
when taper is small
Cracks reported in low and
high carbon steels, too
It seems that steels outside
the peritectic range are
more prone to off-corner
cracks
Prevention
Operating conditions – mold
Casting speed
In a previously shown case, there is a positive effect of
increasing casting speed on off-corner cracking
One possible reason for this is that the taper, if optimized for
high casting speed, is not enough for a lower speed, giving
place to a higher gap, bulging and off-corner cracking
Instead, a case on high carbon steel reports the opposite
Primary cooling
Application of more intense primary cooling gave better
results in two different plants
Prevention
Operating conditions – mold
Mold flux
The lower the mold flux viscosity (and basicity), the
higher the heat transfer
This promotes a thicker shell, minimizing bulging and off-
corner cracking
Prevention
Operating conditions – Mold
Mold flux
Tata Steel Thailand, high carbon steel
Heat extraction higher in strands cast with the flux of lower
viscosity
With low viscosity flux, heat extraction increased with
increasing casting speed
Prevention
Operating conditions – mold
M-EMS
Very short columnar zone, followed by equiaxed
solidification, should impair off-corner cracking
Proven in ArcelorMittal Monlevade
Prevention
Variable AM Villares Tata Steel Gerdau Acciaierie AM SAIL Ranchi, Sideno
Monlevade Metal, Thailand Charqueadas Venete Piracicaba India rBasau
, Brazuk Brazil , Brazil CCM3, Italy , ri,
Brazil Spain
Section (mm) 155 x 155 Bloom 155 x 155 240 x 240 120 x 120 125 x 125 145 x
145
170 x
170
Casting type SEN SEN SEN SEN SEN Open Open SEN
Steel types 1035 HNV3 0.6-0.75%C 0.15-0.25%C 0,15-0,25%C 0.26- Medium C 12L14
304 L 0,04-0,07%S >0,02%S 0.32% forging
Ti-B
Mn/S Constant 15-20 20-30 3.2-4.8
(>30) 20-25 >25 ideal
optimum
Superheat (oC) Constant The The lower 35 typical 30-50 no 48+/-
+/- 5oC lower the better influence 12
the
better
Casting speed Constant 1.7 -2.2 1,7-2,5 1.5-1.7
(m/min) 1.7-2.0 Optimum (145)
optimum 2,2-2,5 1.3-1.7
(170)
Oscillation Constant Low Stroke 5 mm Consta
parameters frequenc nt
y better
Mold Cu-Ag Constant Consta
material, Cu-Zr 780 >330 nt
Prevention
Variable AM Villares Tata Steel Gerdau Acciaierie AM SAIL Ranchi Sideno
Monlevad Metals Thailand Charqueadas Venete Piracicaba rBasau
e CCM3 ri
Mold taper Double Simple Triple Less friction Consta
Parabolic Parabolic with nt
parabolic
Primary High better 6-8 l/kg High Consta
cooling better nt
Mold flux Low visc. 1.48 dP 0,9 dP
better better than 1300oC
2.5 dP1300
EMS Stronger
better
Roll gap Less bulging
with 0
instead of
0.3
Zone 1 Medium 0.3 l/kg total High Consta
cooling better better nt
Evolution during rolling
 Welding during rolling
 Unless they break to the
billet surface to become
oxidized during reheating
 Sulfides remain
 After rolling, a macroetching
on a transverse cut would
revealed the ghost lines, or
remaining sulfides
 Reagents revealing
segregation, like Oberhoffer,
Béchet-Beaujard, ingot
pattern, ammonium
persulfate, may be used
 Then, observation with
stereo microscope to identify
ghost lines, measuring crack
length in the transverse cut,
as well as distance to the
bar surface
Evolution during rolling
Assessment of ghost lines
On macroetched transverse cut of rolled bars,
according to its degree

Hot compression of a bar (simulating forging)


Conclusions
Off-corner cracks in billets and blooms are internal
defects refilled with manganese sulfides
Strand breakout during casting
Aligned manganese sulfides in rolled bar and wire rod
Defects in forging and heat treatment
Formation mechanism well understood since the early
eighties, after characterization by macroetching and
metallography, as well as solidification modelling
Many modifications in mold design include as aim a
minimization of off-corner cracks, in particular for high
casting speed
Conclusions
While the defect is present both in open and submerged
casting, troubleshooting reports mostly deal with
submerged casting, probably due to the influence of these
cracks in special bar quality rolled products
 Mid carbon steels seems to be more prone to the defect.
Measures proposed to minimize its occurrence include
metallurgical measures as lower Mn/S ratio and low
superheat, as well as changes in mold design, mold flux of
lower viscosity, stronger primary cooling (and first zone of
secondary cooling), more intense electromagnetic stirring,
negative tolerance for foot rolls, and others
Jorge Madias

metallon
Full paper (not included in Proceedings): request to
jorge.madias@metallon.com.ar

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