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CHEMISTRY FOR THE IB DIPLOMA © CAMBRIDGE UNIVERSITY PRESS 2014 ANSWERS TO EXAMSTYLE QUESTIONS 8 1
The concentration of OH− ions in the solution 14 a CH3CH2COOH(aq) + H2O(l)
has been increased and the solution is alkaline. [3] CH3CH2COO−(aq) + H3O+(aq)
d i The equation for the reaction is: or
CH3CH2CH2COOH(aq) + NaOH(aq) CH3CH2COOH(aq)
→ CH3CH2CH2COONa(aq) + H2O(l) CH3CH2COO−(aq) + H+(aq)
25.00 [2]
no. moles of butanoic acid = × 0.150 −pKa
1000 b Ka = 10
= 3.75 × 10−3 mol For ethanoic acid, Ka = 10−4.76
From the chemical equation: one mole of = 1.74 × 10−5
butanoic acid react with one mole of sodium For propanoic acid, Ka = 10−4.87
hydroxide. Therefore 3.75 × 10−3 mol butanoic = 1.35 × 10−5
acid reacts with 3.75 × 10−3 mol sodium Ethanoic acid is the stronger acid, because it has
hydroxide. So there are 3.75 × 10−3 mol a higher Ka value. A higher Ka indicates that a
present in 27.60 cm3 of sodium hydroxide. greater proportion of the acid molecules have
The concentration of sodium hydroxide is: dissociated. [4]
3.75 × 10−3 c The equation for the dissociation of propanoic
= 0.136 mol dm−3 [3]
(27.60/1000) acid is:
ii NaOH is a strong base and therefore CH3CH2COOH(aq)
completely ionises in solution: CH3CH2COO− (aq) + H+(aq)
[OH−(aq)] = 0.136 mol dm−3 The expression for Ka is:
pOH = −log10 [OH−(aq)] [CH3CH2COO−(aq)][H+(aq)]
Ka =
pOH = −log10 0.136 = 0.866 [CH3CH2COOH(aq)]
Assuming that the temperature is 25 °C: Because one molecule of CH3CH2COOH
14 = pH + pOH dissociates to form one CH3CH2COO−
pH = 14 − 0.866 = 13.1 [3] ion and one H+ ion, the concentration of
iii CH3CH2COO− and H+ ions in the solution will
14
13
final pH approaches 13.1 be equal:
12 [CH3CH2COO−(aq)] = [H+(aq)]
11
10 We will make the assumption that the
9
8 dissociation of the acid is negligible compared
pH
2 ANSWERS TO EXAMSTYLE QUESTIONS 8 CHEMISTRY FOR THE IB DIPLOMA © CAMBRIDGE UNIVERSITY PRESS 2014
f We can write an expression for Kb for The position of equilibrium shifts to the right
CH3CH2COO− as the temperature increases, so the reaction
[CH3CH2COOH(aq)][OH−(aq)] to the right must be endothermic. When the
Kb =
[CH3CH2COO−(aq)] temperature increases, the position of equilibrium
One CH3CH2COO− ion reacts with one shifts in the endothermic direction to take in heat
H2O molecule to form one CH3CH2COOH and minimise the effect of the change. [3]
molecule and one OH− ion; therefore:
16 a A buffer solution is one that resists changes in pH
[CH3CH2COOH(aq)] = [OH−(aq)]
when small amounts of acid or base are added. [2]
We will use the approximation that the amount
b If some hydrochloric acid is added to this
of CH3CH2COO− that reacts with water is
solution, the extra H+ added reacts with the NH3
negligible compared with its concentration and
in the solution:
take [CH3CH2COO−(aq)] to be 0.200 mol dm−3.
NH3 (aq) + H+(aq) → NH4+(aq)
Substituting known values into the Kb expression:
If some sodium hydroxide is added to the
[OH−(aq)]2
7.41 × 10−10 = solution, the extra OH− added reacts with the
0.200
NH4+ in the solution:
[OH−] = 1.22 × 10−5 mol dm−3
NH4+(aq) + OH−(aq) → NH3 (aq) + H2O(l) [2]
pOH =−log10 [OH−(aq)]
c Kb = 10−pKb Kb = 10−4.75
pOH = −log10 1.22 × 10−5 = 4.91
Therefore, Kb = 1.78 × 10−5.
pOH + pH = pKw
The ionisation of ammonia is shown by the
At 25 °C, pOH + pH = 14; therefore:
equation:
pH = 14 − 4.91 = 9.09 [4]
NH3(aq) + H2O(l) NH4+(aq) + OH−(aq)
15 a H2O(l) H+(aq) + OH−(aq) [1] The expression for Kb is:
b Kw = [H+(aq)][OH−(aq)] [NH4+(aq)][OH−(aq)]
Kb =
Because one H2O molecule dissociates to form [NH3(aq)]
one H+ ion and one OH− ion, in pure water One NH3 molecule ionises to produce one
the concentration of H+ ions is equal to the NH4+ and one OH− ion. This means that the
concentration of OH− ions. We can therefore concentration of NH4+ is equal to the OH−
write Kw = [H+(aq)]2 for pure water. So, at 40 °C: concentration and we can write:
5.48 × 10−14 = [H+(aq)]2 [OH−(aq)]2
Kb =
[H+(aq)] = √(5.48 × 10−14) [NH3(aq)]
[H+(aq)] = 2.34 × 10−7 mol dm−3 We will make the approximation that the
pH = −log10 [H+(aq)] concentration of NH3 at equilibrium is equal to
pH = −log10 (2.34 × 10−7) = 6.63 [3] the initial concentration, i.e. that the ionisation
c pOH for a neutral solution at 323 K will be of the base is negligible compared with its
the same as the pH, i.e. 6.63. This solution has concentration. Therefore we take [NH3(aq)] to
a pOH of 7.0. A higher pOH indicates a lower be 0.125 mol dm−3. If we substitute this value and
concentration of OH− ions than in a neutral the value for Kb into the expression for Kb we
solution; therefore the solution is acidic. get:
or [OH−(aq)]2
1.78 × 10−5 =
Kw is 5.48 × 10−14 at 323 K. Therefore 0.125
pKw = 13.26. [OH−(aq)]2 = 1.78 × 10−5 × 0.125 = 2.22 × 10−6
pKw = pH + pOH [OH−(aq)] = 1.49 × 10−3 mol dm−3
If pOH = 7.0, the pH of this solution is pOH = −log10 [OH−(aq)]
13.26 − 7.0 = 6.26. pOH = −log10 (1.49 × 10−3) = 2.83 [3]
This solution has a lower pH than the neutral pH d The amount of HCl that has been added is half
at this temperature and is, therefore, acidic. [3] the amount required for neutralisation; at the
d Kw for water at 288 K is 10−14.34, half-neutralisation point, pOH = pKb because
i.e. 4.57 × 10−15. [NH3(aq)] = [NH4+(aq)]; therefore pOH = 4.75.
Kw is 5.48 × 10−14 at 323 K. So pH = 14 − 4.75 = 9.25 [3]
H2O(l) H+(aq) + OH−(aq)
As the temperature increases, the value of Kw
increases and therefore more water dissociates.
CHEMISTRY FOR THE IB DIPLOMA © CAMBRIDGE UNIVERSITY PRESS 2014 ANSWERS TO EXAMSTYLE QUESTIONS 8 3