Вы находитесь на странице: 1из 8

©2020 Society of Economic Geologists, Inc.

Economic Geology, v. XXX, no. XX, pp. X–X

EXPRESS LETTER

ROSEN, BULGARIA: A NEWLY RECOGNIZED IRON OXIDE-COPPER-GOLD DISTRICT

Richard H. Sillitoe,1,† Georgi Magaranov,2 Veselin Mladenov,2 and Robert A. Creaser3


127 West Hill Park, Highgate Village, London N6 6ND, England
2Mundoro Capital Inc., 6th September Street 13A, Sofia 1000, Bulgaria
3Department of Earth and Atmospheric Sciences, University of Alberta, Edmonton, Alberta T6G 2E3, Canada

Abstract
The Rosen copper veins in southeastern Bulgaria are recognized for the first time as an iron oxide-copper-gold
(IOCG) district. The veins are located in the East Srednogorie segment of the Carpathian-Balkan calc-alkaline
volcano-plutonic arc and were formed during an end-stage interval of extreme slab rollback and intra-arc rift-
ing, which gave rise farther east to seafloor spreading in the Western Black Sea basin. The resulting submarine
volcano-sedimentary rift basin is dominated by intermediate to mafic shoshonitic to ultrapotassic volcanism and
subsidiary gabbro to syenite intrusion. The E- to NE-striking veins define a NW-striking alignment along the
western contact of the syenite-dominated Rosen pluton, inferred to be part of a large ring dike. More than 40
veins, the most important formerly mined to depths as great as 1,000 m, contain an early, pegmatoidal, calcic-
potassic assemblage followed by predominant magnetite (including the mushketovite variety), chlorite, and
carbonates but also quartz, chalcopyrite, pyrite, and numerous other metallic minerals, which combine to give
an unusual Fe-Cu-Au-Mo-Co-Ni-U-light rare earth element (LREE)-W-Bi-Zn-Pb geochemical signature. The
close correlation between Fe, Cu, U, and LREEs is evident even in the flotation tailings. Vein molybdenite was
dated during this study at 80.6 ± 0.4 Ma, which is similar to a U-Pb zircon age for monzosyenite from the Rosen
pluton. The mineralogic and compositional features of the Rosen district are comparable to those of well-known
IOCG deposits worldwide and geometrically similar to the vertically extensive IOCG veins in the Coastal Cor-
dillera province of northern Chile. The subsidiary granitophile signature that accompanies the characteristic
siderophile IOCG suite was also recognized recently at the giant Olympic Dam deposit in South Australia and
elsewhere. Although no exposed intrusion is definitively implicated in the genesis of the Rosen veins, coexisting
gabbro and syenite fluid sources may be hypothesized at depth in or beneath the coeval ring dike.

Introduction state enterprise, during which time underground operations


The Rosen (or Rossen) copper district is located at Meden attained maximum depths of 800 to 1,000 m. Before 1977,
rid (Copper ridge) near the Black Sea coast of southeastern when impoundments were constructed, flotation tailings were
Bulgaria, ~12 km southeast of the city of Burgas (Fig. 1). discharged directly into the nearby Black Sea, resulting subse-
The district merits mention in most metallogenic syntheses quently in an extensive cleanup operation (Bley et al., 2003).
of the Carpathian-Balkan segment of the Tethyan orogen— Since mining ceased in 1995, much of the mine infrastruc-
the Apuseni-Banat-Timok-Srednogorie belt—as a series of ture has been dismantled, and there is currently no under-
polymetallic vein deposits of mesothermal character that ground access and little surface exposure of the veins. Hence,
were mined principally for copper (Janković, 1997; Berza et the evidence for an IOCG designation is based on published
al., 1998; Ciobanu et al., 2002; Popov et al., 2002). A case is descriptions—most in Bulgarian or Russian—of the veins and
made here for the Rosen district being a previously unrecog- flotation tailings combined with inspection of sparse dump
nized example of iron oxide-copper-gold (IOCG) mineraliza- material and sample suites from museum and university collec-
tion, sharing many features with the archetypal deposits that tions. This short report highlights the geologic setting and char-
constitute the Olympic (Gawler) and Cloncurry provinces of acteristics of the Rosen IOCG district and presents an Re-Os
Australia, Carajás province of Brazil, and, in particular, the molybdenite age, which provides a precise timing for vein for-
much younger Coastal Cordillera province of Chile and Peru mation. Since the Rosen veins constitute arguably the youngest
(Williams et al., 2005, and references therein). presently known IOCG deposits anywhere in the world, their
The shallow (<100 m), supergene-oxidized parts of the well-defined tectono-magmatic setting further clarifies the for-
Rosen veins supported some of the world’s earliest cop- mational environment of IOCG deposits in general.
per mining, dating back to the late sixth millennium B.C. Geologic Setting
and continuing through the Bronze Age, Greek and Roman
times, and the Middle Ages (Leshtakov, 2013; Rehren et al., The Rosen district is located in the Srednogorie belt, the east-
2016; Kunze et al., 2018). The veins were formally exploited ern portion of the Apuseni-Banat-Timok-Srednogorie belt,
from 1945 to 1995 by Bourgas Copper Mining Company, a which trends east-west through Bulgaria (Fig. 1, inset). The
Srednogorie belt is the site of a Late Cretaceous volcano-
†Corresponding author: e-mail, aucu@compuserve.com plutonic arc of predominantly calc-alkaline composition that

ISSN 0361-0128; doi:10.5382/econgeo.4731; 8 p. Submitted: December 21, 2019 / Accepted: January 2, 2020

Downloaded from https://pubs.geoscienceworld.org/segweb/economicgeology/article-pdf/doi/10.5382/econgeo.4731/4965491/4731_sillitoe_et_al.pdf


by Uppsala Universetet user
2 EXPRESS LETTER

Fig. 1. Simplified geologic map of East Srednogorie, Bulgaria (taken from Cheshitev and Kânčev, 1989), showing the posi-
tion of the Yambol-Burgas intra-arc basin (after Georgiev et al., 2012) and the main vein districts (after Popov et al., 1993).
Box in inset shows location of East Srednogorie with respect to the Apuseni-Banat-Timok-Srednogorie metallogenic belt.

was constructed during northward subduction of Neotethyan Fig. 1). Limited U-Pb zircon dating suggests that the most
oceanic lithosphere beneath the Eurasian plate (Dewey et intense intra-arc magmatism was active between ~81 and 79
al., 1973). Copper mineralization occurs throughout much Ma (Georgiev et al., 2012). The Yambol-Burgas basin was
of the arc, although the Panagyurishte district in the Cen- inverted by N-vergent thrusting during Neotethys closure
tral Srednogorie belt hosts the most important porphyry and and continental collision, beginning in the latest Cretaceous
high-sulfidation epithermal copper-gold deposits, which were (Burchfiel and Nakov, 2015; Fig. 1).
emplaced under mildly extensional conditions resulting from In contrast to the rest of the Srednogorie arc, the intra-arc
southward slab rollback (von Quadt et al., 2005; Zimmerman basin in East Srednogorie hosts copper-bearing, polymetallic
et al., 2008). vein deposits, interpreted here to be of IOCG type, instead
East Srednogorie differs from the West and Central seg- of porphyry and high-sulfidation epithermal deposits (Popov
ments of the belt, because the calc-alkaline arc underwent et al., 1993; Fig. 1), possibly because the extension was so
extreme end-stage extension and crustal thinning to form extreme (Gallhofer et al., 2015). Traditionally, the veins were
the Yambol-Burgas intra-arc basin, which broadens and assigned an intrusion-related origin (e.g., Bogdanov, 1987;
deepens eastward on approach to the Black Sea (Georgiev Popov et al., 1993).
et al., 2012; Gallhofer et al., 2015; Fig. 1). The Yambol- IOCG deposits have not been reported from elsewhere in
Burgas basin was the site of deep submarine sedimentation the Apuseni-Banat-Timok-Srednogorie belt. However, mag-
and voluminous shoshonitic basalt and basaltic andesite to netite-rich copper-gold occurrences considered of IOCG type
ultrapotassic volcanism, and subsidiary coeval gabbro to have been described farther east in the Tethyan orogenic belt,
syenite intrusions that define a number of volcanic centers at Divrigi and Hasançelebi in east-central Turkey, where they
(Boccaletti et al., 1978; Stanisheva-Vassileva, 1980; Popov are closely associated with Late Cretaceous (77–74 Ma) mon-
et al., 1993; Dabovski et al., 2009; Georgiev et al., 2012; zonitic to syenitic intrusions emplaced during arc extension

Downloaded from https://pubs.geoscienceworld.org/segweb/economicgeology/article-pdf/doi/10.5382/econgeo.4731/4965491/4731_sillitoe_et_al.pdf


by Uppsala Universetet user
EXPRESS LETTER 3

induced by slab rollback (Kuşcu et al., 2013)—a tectono-mag- m in width but attaining 6 m near vein intersections, were
matic setting closely similar to that of the Rosen district. exploited, and another 50 or so are known (Popov et al., 1993;
Figs. 2, 3). The main veins, up to ~3,000 m long and known
Rosen District Veins from drilling to a depth of ~2,000 m, partly follow syenite por-
The six main deposits and nearby prospects in the Rosen phyry dikes, which were emplaced at about the same time as
district define an 11-km-long, northwest alignment that fol- monzogabbro porphyry dikes but later than the Rosen pluton
lows the topographically prominent Meden rid near the west- (Bogdanov et al., 1969; Fig. 3). From 1945 to 1995, the three
ern contact of the Rosen pluton (Figs. 1, 2). The pluton, 23 main mines, Rosen, Meden rid, and Propadnala voda (Fig.
km long and 1 to 4 km wide, is composed mainly of syenite, 3), produced 15.4 Mt of ore averaging 1.04% Cu (Milev et
monzonite, and a multiplicity of dikes, including widespread al., 1996) plus undisclosed amounts of Au, Mo, Co, and other
aplite. A sample of monzosyenite from the monzonite phase by-products. However, production during the early years of
returned a U-Pb isotope dilution-thermal ionization mass formal mining averaged >3% Cu (Milev et al., 1996).
spectrometry zircon concordia age of 79.62 ± 0.47 Ma (Geor- Hydrothermal alteration minerals recorded from the wall
giev et al., 2012). The parallelism of the elongate pluton and rocks of the Rosen veins include albite, K-feldspar, actinolite,
the deposit alignment was considered by Bogdanov et al. epidote, and chlorite (Bogdanov, 1987; Popov et al., 1993).
(1969) to reflect the presence of fundamental, NW-striking More than 100 hypogene and supergene minerals have been
structural control (Fig. 2). However, more recent geophysi- identified in the veins (Todorov, 1983; Popov et al., 1993).
cal evidence suggests that the Rosen pluton is just a western Early, pegmatoidal biotite, pyroxene, amphibole, K-feldspar,
segment of a large ring dike, much of which is submerged and apatite, reportedly best represented in the southwestern
beneath the westernmost Black Sea (Dabovski et al., 2009, portions of the veins, predate sulfide introduction (Bogda-
and references therein). nov et al., 1968; Fig. 4A). They are followed by the main vein
Each of the six deposits comprises one or two main veins constituents: magnetite (including the mushketovite variety),
accompanied by a series of hanging- and footwall splays (Fig. chlorite, chalcopyrite, pyrite, calcite, ankerite (plus other car-
2). The veins follow an array of moderately to steeply dip- bonates), and quartz (Bogdanov et al., 1968; Todorov, 1983;
ping, NE- to E-striking, NW- or SE-dipping normal faults and Popov et al., 1993). Observed ore samples comprise inter-
fractures that cut a sequence of predominantly trachyandes- grown magnetite ± chlorite containing centimeter-scale clots
itic lavas and volcaniclastic rocks intruded by diorite porphyry and veinlets of chalcopyrite but commonly lesser or no pyrite
dikes and, at depth, by one or more larger bodies of monzo- (Fig. 4B, C). The calcite, ankerite, and other minor carbonate
diorite porphyry (Bogdanov et al., 1969; Popov et al., 1993; minerals are far more abundant than quartz and, in part, para-
Fig. 3). At least 40 subparallel veins, ranging from 0.5 to 2 genetically late and commonly barren (Todorov, 1983; Popov

Fig. 2. Map showing the main veins in the Rosen district relative to the Rosen pluton (taken from Popov et al., 1993). Note
the location of Vromos Bay. Section line A-A’ shows the position of Figure 3.

Downloaded from https://pubs.geoscienceworld.org/segweb/economicgeology/article-pdf/doi/10.5382/econgeo.4731/4965491/4731_sillitoe_et_al.pdf


by Uppsala Universetet user
4 EXPRESS LETTER

Fig. 3. Northwest-southeast section through the Rosen district veins (taken from Popov et al., 1993). Section line shown
in Figure 2.

et al., 1993; Fig. 4D), although crosscutting calcite veins can et al., 1993). The gold and electrum are encapsulated mainly
contain chalcopyrite. Minor fluorite and barite are also pres- in chalcopyrite, pyrite, and carbonates (Strashimirov and
ent (Popov et al., 1993). Kovachev, 1994). Other minor vein constituents include ura-
Specular hematite, molybdenite, and bornite are also promi- ninite and light rare earth element (LREE)-bearing minerals:
nent vein minerals, along with subsidiary scheelite, wolframite, allanite and the fluorocarbonates bastnäsite, parisite, and syn-
cubanite, arsenopyrite, Co-bearing species (cobaltian pyrite, chysite (Antonova, 1988; Popov et al., 1993). Uranium grades at
cobaltite, carrollite), Ni-bearing species (pentlandite, violarite, Rosen were <0.1% (Simov and Bojkov, 1992). This suite of vein
nickeline, bravoite), Bi-bearing species (mainly aikinite), sphal- minerals gives rise to a complex and somewhat unusual Fe-Cu-
erite, galena, native gold, and electrum (Todorov, 1983; Popov Au-Mo-Co-Ni-W-Bi-Zn-Pb-U-LREE geochemical signature.

Fig. 4. Selected samples from the Rosen veins. A. Pegmatoidal aggregates of biotite books (black) cut by a vein of fine-
grained amphibole (pale green) enclosing euhedral apatite crystals (white). Note lack of sulfide minerals. B. Massive mag-
netite cut by irregular chalcopyrite veinlet. C. Massive, coarse-grained mushketovite, showing former specular hematite
crystal faces. D. Massive magnetite and intergrown chalcopyrite cut by late calcite. Scribe tip for scale.

Downloaded from https://pubs.geoscienceworld.org/segweb/economicgeology/article-pdf/doi/10.5382/econgeo.4731/4965491/4731_sillitoe_et_al.pdf


by Uppsala Universetet user
EXPRESS LETTER 5

The other Late Cretaceous, volcanic rock-hosted vein dis- to the Re and Os concentrations in molybdenite. Reference
tricts farther west in the Yambol-Burgas intra-arc basin, most material 8599 Henderson molybdenite (Markey et al., 2007)
notably Varli Bryag, Zidarovo, and Bakadjik (Fig. 1), pos- is routinely analyzed as a standard, and during the past five
sess mineralogic and geochemical similarities to those in the years returned an average Re-Os date of 27.78 ± 0.07 Ma (n =
Rosen district. However, quartz, Au, Zn, and Pb contents are 15), indistinguishable from the reference age value of 27.66 ±
higher and Mo, W, Co, and Ni contents lower, possibly due to 0.1 Ma (Wise and Watters, 2011).
shallower levels of erosion than in the Rosen district (Todorov, The results of the Re-Os age determination are detailed
1983; Popov et al., 1993). in Table 1. The age uncertainty is quoted at 2σ level and
includes all known analytical uncertainty, including that in the
Rosen Flotation Tailings decay constant of 187Re. The analysis yielded a Late Creta-
The Black Sea coast at Vromos Bay (Fig. 2) was heavily con- ceous (Campanian) age of 80.6 ± 0.4 Ma. The molybdenite
taminated by flotation tailings from the Rosen plant, giving mineral separate was replicated with an identical age result,
rise to high levels of radioactivity (Vapirev et al., 1996). Ap- within uncertainty (Table 1). This Re-Os age accords with an
proximately 8 Mt of magnetite-rich tailings were discharged imprecise K-Ar age of 83.0 ± 3.0 Ma reported by Palshin et al.
into the bay, with ~10% of them being concentrated by wave (1989) for biotite from one of the Rosen veins.
action to form a black-sand beach placer 2.3 km long, up to
150 m wide, and 2.3 m (locally up to 6 m) thick (Bley et al., Timing of Vein Formation and Intrusion
2003). The sand contained 60% magnetite along with specu- The new Re-Os molybdenite age is consistent with the Rosen
lar hematite, chalcopyrite, pyrite, molybdenite, and subsidiary veins having formed during the Yambol-Burgas intra-arc rift-
bornite, supergene chalcocite, and other sulfide minerals. In ing event and falls within the 81 to 79 Ma peak of volcano-
the early 1990s, the mining company began removal of the plutonic activity defined by Georgiev et al. (2012). The vein
black sand from the beach; it was subjected to regrinding pri- molybdenite appears to be 0.1 to 1.9 m.y. older than the age
or to magnetic separation and flotation to recover a magnetite (79.62 ± 0.47 Ma) of the monzosyenite from the nearby Rosen
concentrate, averaging 55% Fe, and a chalcopyrite concen- pluton, taking into account the age uncertainties (Georgiev et
trate grading 13 to 15% Cu and 4 to 5 g/t Au (Bley et al., al., 2012). Significantly, however, only two zircons were ana-
2003). lyzed to produce the concordia age (Georgiev et al., 2012),
The nonmagnetic fraction of the black sand contained ura- and, bearing in mind the likelihood of multiple intrusive phas-
nium and LREE minerals, including uraninite and allanite es in the Rosen pluton, it is possible that the crystallization age
(Bley et al., 2003). Even 14 years after beach restoration was of part of the pluton could have been essentially synchronous
completed, the remaining black sand returned values of 12 to with vein formation.
32 ppm U and 290 to 1,050 ppm REEs, mostly LREEs. High The difficulty of precisely identifying the causative intru-
correlation coefficients (r = 0.90–0.93) between Fe, Cu, U, sion for the Rosen veins is typical of IOCG deposits in general
and LREEs support the close association of these elements (e.g., Williams et al., 2005; Groves et al., 2010). Nonetheless,
(Surguchev et al., 2011). irrespective of whether any exposed intrusion overlaps tem-
porally with vein formation, the proximity of the vein array
Molybdenite Age Determination and parallel dike swarm to the Rosen pluton (Fig. 2) strongly
A sample of molybdenite-bearing copper ore was collected suggests a genetic relationship between the IOCG deposits
at the Propadnala voda mine shaft for Re-Os dating. The and intrusions comprising the ring dike.
sample consists of massive magnetite and chlorite containing
coarsely intergrown clots of chalcopyrite and molybdenite. Discussion
A molybdenite mineral separate was prepared by metal-free A comparison of the geologic and mineralogic features report-
crushing followed by gravity and magnetic concentration. The ed for the Rosen veins with those considered by Groves et
187Re and 187Os concentrations in the molybdenite were de- al. (2010) to typify true IOCG deposits strongly supports the
termined by isotope dilution mass spectrometry using Carius proposal that the district may be considered as a legitimate
tube, solvent extraction, anion chromatography, and negative member of the IOCG clan rather than simply as a series of
thermal ionization mass spectrometry techniques (Selby and mesothermal vein deposits. Following Groves et al. (2010),
Creaser, 2004; Markey et al., 2007). A mixed double spike the defining criteria are magmatic-hydrothermal origin, eco-
containing known amounts of isotopically enriched 185Re, nomic Cu and Au contents, structural control, abundance of
190Os, and 188Os was used. Isotopic analysis was made using low-Ti iron oxides, LREE enrichment, subordinate role of py-
a ThermoScientific triton mass spectrometer by means of a rite and quartz, temporal relationship to intrusive rocks, and
Faraday collector. Total procedural blanks for Re and Os were large scale of pre-ore alteration. In the Rosen district, only the
<3 and <2 pg, respectively, which are insignificant compared last criterion remains to be further assessed.

Table 1. Molybdenite Re-Os Isotope and Age Data, Rosen District, Bulgaria

Re 187Re 187Os Model age ±2σ


Sample (ppm) ±2σ (ppm) ±2σ (ppb) ±2σ (Ma) (Ma)

Bulgaria 260.6 0.8 163.8 0.5 220.0 0.2 80.6 0.4


Bulgaria rpt 286.0 0.9 179.7 0.5 241.7 0.2 80.7 0.4

Downloaded from https://pubs.geoscienceworld.org/segweb/economicgeology/article-pdf/doi/10.5382/econgeo.4731/4965491/4731_sillitoe_et_al.pdf


by Uppsala Universetet user
6 EXPRESS LETTER

The Late Cretaceous intra-arc rift setting of the Rosen dis- particularly northeastern portions of the Rosen veins (Bogda-
trict, with its thinned crust and high heat flow (Georgiev et al., nov et al., 1968; Todorov, 1983), as it is in some of the northern
2012), is consistent with the extensional environments widely Chile deposits (e.g., Manto Verde; Vila et al., 1996).
proposed for most IOCG deposits worldwide (Groves et al., The Fe-Cu-Au-Mo-Co-Ni-U-LREE association at Rosen
2010), and closely comparable to the intra-arc extensional/ is typical of many IOCG deposits, although the additional
transtensional setting of the Middle Jurassic to mid-Creta- presence of appreciable W, Bi, Zn, and Pb is less common.
ceous IOCG deposits in the Coastal Cordillera of the central Nonetheless, these metals have been reported from other
Andes (Sillitoe, 2003, and references therein), where intra- deposits considered as IOCG type, with major Bi and Co
arc (and back-arc) basin formation was also caused by slab and minor W being present at NICO, Great Bear magmatic
rollback (Ramos, 2009). The Yambol-Burgas basin appears to zone (Acosta-Góngora et al., 2015); Bi, Co, Ni, and LREEs
be the aborted on-land prolongation of the seafloor spreading at Guelb Moghrein, Mauritania (Kirschbaum and Hitzman,
center responsible for oceanic crust generation and opening 2016); Zn at Candelaria (Marschik and Fontboté, 2001); Bi,
of the Western Black Sea basin (Tari et al., 2015). The Rosen Sn, Pb, Zn, Ni, Co, and REEs at Alvo 118, Carajás province
district occupies the part of the Yambol-Burgas basin nearest (Torresi et al., 2012); Mo, Co, As, Bi, W, Sn, U, and REEs
to the Black Sea (Fig. 1) and, as a consequence, is underlain at Ernest Henry, Cloncurry province (Mark et al., 2006); and
by the thinnest crust (~28 km; Yosifov and Pchelarov, 1977). W, Mo, As, and Sb in the southeastern lobe of Olympic Dam
The mafic tendency of the magmatism in the Yambol-Bur- (Dmitrijeva et al., 2019), where hematite throughout the
gas intra-arc rift—attributed to remelting of clinopyroxene- deposit is enriched in W, U, Sn, and Mo (Verdugo-Ihl et al.,
and amphibole-bearing upper mantle-lower crustal cumulates 2017). A mafic rock association would offer a ready explana-
(Georgiev et al., 2009, 2012)—recalls the intimate association tion for the elevated Co and Ni values in the Rosen district
of some IOCG deposits elsewhere with mafic and even ultra- and elsewhere, but the occurrence of elevated W, Sn, Mo, Bi,
mafic intrusions, as in the Coastal Cordillera of northern Chile and even U and LREEs favors a granitophile affinity. Perhaps
(Sillitoe, 2003) and at Olympic Dam (Ehrig et al., 2012). The the combination of siderophile and granitophile geochemistry
intermediate to mafic shoshonitic suite that dominates the could imply involvement, perhaps comingling, of both gab-
Yambol-Burgas intra-arc rift is also reminiscent of the high-K broic and syenitic magmas at Rosen and a comparable deeply
calc-alkaline to shoshonitic volcanic rocks present in parts of sourced, compositionally bimodal magmatic input to some
some other IOCG provinces, including the Mesozoic Coastal other IOCG districts.
Cordillera of the central Andes (Sillitoe, 2003, and references
therein) and Paleoproterozoic Great Bear magmatic zone of Conclusions
Northwest Territories, Canada (Ootes et al., 2017). The newly obtained Late Cretaceous mineralization age con-
Many IOCG deposits comprise either irregular, structurally firms the Rosen veins to be the youngest example of unam-
and/or stratigraphically controlled replacement bodies, and/ biguous IOCG deposits encountered to date anywhere in the
or hydrothermal breccias, which can be intimately associ- world. The veins formed in an extensional, intra-arc, subma-
ated with discrete, subvertical veins (e.g., Candelaria-Punta rine basinal setting that concluded conventional calc-alkaline
del Cobre district, northern Chile; Marschik and Fontboté, magmatic arc construction and are broadly associated with
2001). However, geometrically, the Rosen veins are most intermediate to mafic shoshonitic magmatism triggered by
closely comparable with the steep, vertically extensive, stand- extreme slab rollback. The veins are coeval with the nearby
alone IOCG vein systems in the Coastal Cordillera of north- syenite-dominated Rosen pluton but cannot be genetically
ern Chile (Sillitoe, 2003). linked with any confidence to a specific intrusive phase. Por-
The Rosen veins are dominated by magnetite and lesser phyry and high-sulfidation epithermal copper-gold depos-
specular hematite that are closely associated with chalcopy- its, widely developed farther west in the Carpathian-Balkan
rite—a defining feature of more deeply exposed IOCG depos- (Apuseni-Banat-Timok-Srednogorie) belt, are notably absent
its (Hitzman et al., 1992; Sillitoe, 2003; Groves et al., 2010). from this end-stage rift setting.
A notable difference, however, is the intergrowth of magnetite The Rosen veins contain anomalously high Mo, W, Bi, Zn,
with chlorite in the Rosen veins instead of with actinolite, bio- and Pb values in addition to the more typical Fe-Cu-Au-Co-
tite, and/or K-feldspar as in most IOCG deposits worldwide Ni-U-LREE IOCG suite, and a similar subsidiary lithophile
(e.g., Sillitoe, 2003; Williams, 2010; Corriveau et al., 2016); element signature was also recently recognized at the Olym-
however, a magnetite-chlorite association has been described pic Dam deposit and elsewhere, perhaps indicating a hybrid
elsewhere (e.g., Carajás province; Tallarico et al., 2000; Tor- siderophile and granitophile magmatic source. In the case of
resi et al., 2012). The abundance of magnetite pseudomorphs Rosen, this source presumably lies in relatively deep seated
after specular hematite (mushketovite) is another characteristic gabbroic and syenitic magmas that fed the contiguous Rosen
IOCG mineralogic feature (e.g., Marschik and Fontboté, 2001; pluton portion of the inferred ring dike.
Sillitoe, 2003; de Haller and Fontboté, 2009). Although quartz
is present at Rosen, it is not the dominant gangue mineral as Acknowledgments
it is in most base and precious metal-bearing vein deposits Initial field work was conducted on behalf of Mundoro Capi-
worldwide. The abundance and partly late timing of calcite and tal Inc., with subsequent studies benefiting from inspection of
other carbonate minerals is also typical of the IOCG depos- sample suites at Sofia University St. Kliment Ohridski, Earth
its in northern Chile and elsewhere, as is the intergrowth of and Man National Museum, and University of Mining and
minor chalcopyrite with some of the late calcite (e.g., Sillitoe, Geology St. Ivan Rilski, and discussions with Kamen Bogda-
2003). Furthermore, calcite is more abundant in the distal, nov. Publication is with permission of Teo Dechev.

Downloaded from https://pubs.geoscienceworld.org/segweb/economicgeology/article-pdf/doi/10.5382/econgeo.4731/4965491/4731_sillitoe_et_al.pdf


by Uppsala Universetet user
EXPRESS LETTER 7

REFERENCES origin, lithospheric setting, and distinction from other epigenetic iron oxide
Acosta-Góngora, P., Gleeson, S.A., Samson, I.M., Corriveau, L., Ootes, L., deposits: Economic Geology, v. 105, p. 641–654.
Taylor, B.E., Creaser, R.A., and Muehlenbachs, K., 2015, Genesis of the Hitzman, M.H., Oreskes, N., and Einaudi, M.T., 1992, Geological character-
Paleoproterozoic NICO iron oxide-cobalt-gold-bismuth deposit, Northwest istics and tectonic setting of Proterozoic iron oxide (Cu-U-Au-REE) depos-
Territories, Canada: Evidence from isotope geochemistry and fluid inclu- its: Precambrian Research, v. 58, p. 241–287.
sions: Precambrian Research, v. 268, p. 168–193. Janković, S., 1997, The Carpatho-Balkanides and adjacent area: A sector
Antonova, D., 1988, Mineralogy and geochemical features of rare-metal ores of the Tethyan Eurasian metallogenic belt: Mineralium Deposita, v. 32,
in the Rosen ore field: Unpublished Ph.D. thesis, Sofia, University of Min- p. 426–433.
ing and Geology St. Ivan Rilski, 250 p. (in Bulgarian). Kirschbaum, M.J., and Hitzman, M.W., 2016, Guelb Moghrein: An unusual
Berza, T., Constantinescu, E., and Vlad, S.N., 1998, Upper Cretaceous mag- carbonate-hosted iron oxide copper-gold deposit in Mauritania, northwest
matic series and associated mineralisation in the Carpathian-Balkan orogen: Africa: Economic Geology, v. 111, p. 763–770.
Resource Geology, v. 48, p. 291–306. Kunze, R., Abele, J., Leshtakov, P., Dimitrov, K., Krauß, R., and Rödel, T.,
Bley, D.C., Droppo, J.G., Eremenko, V.A., and Lundgren, R., eds., 2003, 2018, Archaeometallurgical prospections in the highlands of Medni Rid,
Cleanup of radioactive floating refuse at Vromos Bay, in Risk method- southeastern Bulgaria: Preliminary report on fieldwork 2013–2015 with
ologies for technological legacies: NATO Science Series IV: Earth and a focus upon remote sensing methods by means of LiDAR: Journal of
Environmental Sciences, v. 18, p. 107–121. Archaeological Science: Reports, v. 19, p. 596–617.
Boccaletti, M., Manetti, P., Peccerillo, A., and Stanisheva-Vassileva, G., 1978, Kuşcu, I., Tosdal, R.M., Gencalioğlu-Kuşcu, G., Friedman, R., and Ullrich,
Late Cretaceous high-potassium volcanism in Eastern Srednogorie, Bul- T.D., 2013, Late Cretaceous to middle Eocene magmatism and metallog-
garia: Geological Society of America Bulletin, v. 89, p. 439–447. eny of a portion of the southeastern Anatolian orogenic belt, east-central
Bogdanov, B., 1987, Copper deposits in Bulgaria: Sofia, Tehnika Government Turkey: Economic Geology, v. 108, p. 641–666. 
Publishing House, 388 p. (in Bulgarian). Leshtakov, P., 2013, Early copper metallurgy on the west Black Sea coast:
Bogdanov, B., Rashkov, R., Yarmov, G., and Raev, L., 1968, Hypogene zon- Archaeological evidence on prehistoric exploitation of the Rosen ore field:
ing of copper-molybdenum deposits of Rossen ore field: International Geo- Centre for Underwater Archaeology, International Conference: Where are
logical Congress, 23rd, Prague, 1968, Proceedings, section 7, p. 281–293 (in the sites? Research, protection and management of cultural heritage, Ahto-
Russian). pol, Bulgaria, 2013, Proceedings, p. 35–54.
Bogdanov, B., Rashkov, R., and Yarmov, G., 1969, Structural features of the Mark, G., Oliver, N.H.S., and Williams, P.J., 2006, Mineralogical and chemical
Rossen ore field: Bulletin of the Geological Institute—Series Metallic and evolution of the Ernest Henry Fe oxide-Cu-Au ore system, Cloncurry district,
Non-metallic Mineral Deposits (Sofia), v. 18, p. 7–25 (in Bulgarian with northwest Queensland, Australia: Mineralium Deposita, v. 40, p. 769–801.
English abs.). Markey, R., Stein, H.J., Hannah, J.L., Zimmerman, A., Selby, D., and Creaser,
Burchfiel, B.C., and Nakov, R., 2015, The multiply deformed foreland fold-thrust R.A., 2007, Standardizing Re-Os geochronology: A new molybdenite refer-
belt of the Balkan orogen, northern Bulgaria: Geosphere, v. 11, p. 463–490. ence material (Henderson, USA) and the stoichiometry of Os salts: Chemi-
Cheshitev, G., and Kânčev, I., eds., 1989, Geological map of P.R. Bulgaria: cal Geology, v. 244, p. 74–87.
Sofia, Committee of Geology—Department of Geophysical Prospecting Marschik, R., and Fontboté, L., 2001, The Candelaria-Punta del Cobre iron
and Geological Mapping, scale 1:500,000. oxide Cu-Au (-Zn-Ag) deposits, Chile: Economic Geology, v. 96, p. 1799–1826.
Ciobanu, C.L., Cook, N.J., and Stein, H., 2002, Regional setting and geochro- Milev, V., Stanev, V., and Ivanov, V., 1996, Mined ores in Bulgaria 1878–1995:
nology of the Late Cretaceous Banatitic magmatic and metallogenetic belt: Sofia, Zemya ’93 Publishing House, 196 p. (in Bulgarian).
Mineralium Deposita, v. 37, p. 541–567. Ootes, L., Snyder, D., Davis, W.J., Acosta-Góngora, P., Corriveau, L., Mumin,
Corriveau, L., Montreuil, J.-F., and Potter, E.G., 2016, Alteration facies A.H., Gleeson, S.A., Samson, I.M., Montreuil, J.F., Potter, E., and Jackson,
linkages among iron oxide copper-gold, iron oxide-apatite, and affiliated V.A., 2017, A Paleoproterozoic Andean-type iron oxide copper-gold envi-
deposits in the Great Bear magmatic zone, Northwest Territories, Canada: ronment, the Great Bear magmatic zone, northwest Canada: Ore Geology
Economic Geology, v. 111, p. 2045–2072. Reviews, v. 81, p. 123–139.
Dabovski, C., Kamenov, B., Sinnyovsky, D., Vassilev, E., and Dimitrova, Palshin, I., Skenderov, G., Bojkov, I., Mihailov, J., Kotov, E., Bedrinov, I., and
E., 2009, Upper Cretaceous geology, in Zagorchev, I., Dabovski, C., and Ivanov, I., 1989, New geochronological data on the Cimmerian and Alpine
Nikolov, T., eds., Geology of Bulgaria, v. 2, part 5. Mesozoic geology: Sofia, magmatic and hydrothermal formations in Srednogorie and Stara Planina
Professor Marin Drinov Academic Publishing House, p. 303–589 (in zones, Bulgaria: Review of the Bulgarian Geological Society, v. 50, p. 75–92
Bulgarian). (in Bulgarian with English abs.).
de Haller, A., and Fontboté, L., 2009, The Raúl-Condestable iron oxide cop- Popov, P., Kovachev, V., Strashimirov, S., Jelev, V., Arnaudova, R., Banushev,
per-gold deposit, central coast of Peru: Ore and related hydrothermal alter- B., Stavrev, P., and Radichev, R., 1993, Geology and metallogeny of the
ation, sulfur isotopes, and thermodynamic constraints: Economic Geology, Burgas ore region: Sofia, University of Mining and Geology St. Ivan Rilski,
v. 104, p. 365–384.  93 p. (in Bulgarian).
Dewey, J.F., Pitman, W.C., III, Ryan, W.B.F., and Bonnin, J., 1973, Plate tec- Popov, P., Berza, T., Grubic, A., and Ioane, D., 2002, Late Cretaceous Apuseni-
tonics and the evolution of the Alpine system: Geological Society of Amer- Banat-Timok-Srednogorie (ABTS) magmatic and metallogenic belt in the
ica Bulletin, v. 84, p. 3137–3180. Carpathian-Balkan orogen: Geologica Balcanica, v. 32, p. 145–163.
Dmitrijeva, M., Ehrig, K.J., Ciobanu, C.L., Cook, N.J., Verdugo-Ihl, M.R., Ramos, V.A., 2009, Anatomy and global context of the Andes: Main geologic
and Metcalfe, A.V., 2019, Defining IOCG signatures through compositional features and the Andean tectonic cycle: Geological Society of America,
data analysis: A case study of lithogeochemical zoning from the Olympic Memoir 204, p. 31–65.
Dam deposit, South Australia: Ore Geology Reviews, v. 105, p. 86–101. Rehren, T., Leshtakov, P., and Penkova P., 2016, Reconstructing chalcolithic
Ehrig, K., McPhie, J., and Kamenetsky, V., 2012, Geology and mineralogical copper smelting at Akladi cheiri, Chernomorets, Bulgaria, in Nikolov, V.,
zonation of the Olympic Dam iron oxide Cu-U-Au-Ag deposit, South Aus- and Schier, W., eds., Der Schwarzmeerraum vom Neolithikum bis in die
tralia: Society of Economic Geologists, Special Publication 16, p. 237–267. Früheisenzeit (6000–600 v.Chr.). Kulturelle Interferenzen in der zirkum-
Gallhofer, D., von Quadt, A., Peytcheva, I., Schmid, S.M., and Heinrich, C.A., pontischen Zone und Kontakte mit ihren Nachbargebieten: Rahden, Ger-
2015, Tectonic, magmatic, and metallogenic evolution of the Late Creta- many, Verlag Marie Leidorf, p. 205–214.
ceous arc in the Carpathian-Balkan orogen: Tectonics, v. 34, p. 1813–1836. Selby, D., and Creaser, R.A., 2004, Macroscale NTIMS and microscale
Georgiev, S., Marchev, P., Heinrich, C.A., von Quadt, A., Peytcheva, I., and LA-MC-ICP-MS Re-Os isotopic analysis of molybdenite: Testing spatial
Manetti, P., 2009, Origin of nepheline-normative high-K ankaramites and restrictions for reliable Re-Os age determinations, and implication for the
the evolution of eastern Srednogorie arc in SE Europe: Journal of Petrol- decoupling of Re and Os within molybdenite: Geochimica et Cosmochi-
ogy, v. 50, p. 1899–1933. mica Acta, v. 68, p. 3897–3908.
Georgiev, S., von Quadt, A., Heinrich, C.A., Peytcheva, I., and Marchev, P., Sillitoe, R.H., 2003, Iron oxide-copper-gold deposits: An Andean view: Min-
2012, Time evolution of a rifted continental arc: Integrated ID-TIMS and eralium Deposita, v. 38, p. 787–812.
LA-ICPMS study of magmatic zircons from the Eastern Srednogorie, Bul- Simov, S.D., and Bojkov, I.B., 1992, Case histories and new areas for ura-
garia: Lithos, v. 154, p. 53–67. nium exploration in Bulgaria, in New developments in uranium exploration,
Groves, D.I., Bierlein, F.P., Meinert, L.D., and Hitzman, M.W., 2010, Iron resources, production and demand: Vienna, International Atomic Energy
oxide copper-gold (IOCG) deposits through Earth history: Implications for Agency, p. 81–88.

Downloaded from https://pubs.geoscienceworld.org/segweb/economicgeology/article-pdf/doi/10.5382/econgeo.4731/4965491/4731_sillitoe_et_al.pdf


by Uppsala Universetet user
8 EXPRESS LETTER

Stanisheva-Vassileva, G., 1980, The Upper Cretaceous magmatism in Sred- Williams, P.J., 2010, “Magnetite-group” IOCGs with special reference to
nogorie zone, Bulgaria: A classification attempt and some implications: Cloncurry (NW Queensland) and northern Sweden: Settings, alteration,
Geologica Balcanica, v. 10, p. 15–36. deposit characteristics, fluid sources, and their relationship to apatite-rich
Strashimirov, S., and Kovachev, V., 1994, Gold in copper deposits of the Sred- iron ores: Geological Association of Canada, Short Course Notes, v. 20, p.
nogorie zone (Bulgaria): Bulletin of the Geological Society of Greece, v. 30, 23–38.
p. 275–285. Williams, P.J., Barton, M.D., Johnson, D.A., Fontboté, L., De Haller, A.,
Surguchev, I., Cherneva, Z., Vergilov, I., Georgieva, V., and Boteva, P., 2011, Mark, G., Oliver, N.H.S., and Marschik, R., 2005, Iron oxide-copper-gold
Geochemical data on contaminated beach sands of the Vromos Bay, Bulgar- deposits: Geology, space-time distribution, and possible modes of origin:
ian Black Sea coast [abs.]: Bulgarian Geological Society, National Confer- Economic Geology 100th Anniversary Volume, p. 371–405.
ence Geosciences, Sofia, 2011, Abstracts, p. 73–74. Wise, S.A., and Watters, R.L., 2011, Reference material 8599 Henderson
Tallarico, F.H.B., Oliveira, C.G., and Figueiredo, B.R., 2000, The Igarapé molybdenite: National Institute of Standards and Technology, Report of
Bahia Cu-Au mineralization, Carajás province: Revista Brasileira de Geo- Investigation, March 30, 2011, 3 p., www.labmix24.com/files/info/37217.
ciências, v. 30, p. 230–233. pdf.
Tari, G., Fallah, M., Kosi, W., Schleder, Z., Turi, V., and Krezsek, C., 2015, Yosifov, D., and Pchelarov, V., 1977, A scheme of the thickness of the Earth’s
Regional rift structure of the Western Black Sea basin: Map-view kinemat- crust in the Balkan peninsula and some features of its structure: Geologica
ics: Petroleum systems in “rift” basins: Society of Economic Paleontologists Balcanica, v. 7, p. 7–22 (in Russian with English abs.).
and Mineralogists, Gulf Coast Section Foundation, 34th Annual GCSSEPM Zimmerman, A., Stein, H.J., Hannah, J.L., Koželj, D., Bogdanov, K., and
Foundation Perkins-Rosen Research Conference, Houston, Texas, 2015, Berza, T., 2008, Tectonic configuration of the Apuseni-Banat-Timok-
Proceedings, p. 372–395, CD-ROM. Srednogorie belt, Balkans-South Carpathians, constrained by high preci-
Todorov, T., 1983, Comparative mineralogical and geochemical analysis of sion Re-Os molybdenite ages: Mineralium Deposita, v. 43, p. 1–21.
the alpine copper deposits in East Srednogorie: Geologica Balcanica, v. 13,
p. 41–58.
Torresi, I., Xavier, R.P., Bortholoto, D.F.A., and Monteiro, L.V.S., 2012,
Hydrothermal alteration, fluid inclusions and stable isotope systematics of
the Alvo 118 iron oxide-copper-gold deposit, Carajás mineral province (Bra-
zil): Implications for ore genesis: Mineralium Deposita, v. 47, p. 299–323.
Vapirev, E.I., Dimitrov, M., Minev, L., Boshkova, T., Pressyanov, D., and
Guelev, M.G., 1996, Radioactively contaminated sites in Bulgaria, in Plan-
ning for environmental restoration of radioactively contaminated sites in
central and eastern Europe, v. 1: Identification and characterization of con-
taminated sites: Vienna, International Atomic Energy Agency, p. 43–63.
Verdugo-Ihl, M.R., Ciobanu, C.L., Cook, N.J., Ehrig, K.J., Courtney-Davies,
L., and Gilbert, S., 2017, Textures and U-W-Sn-Mo signatures in hematite Richard Sillitoe gained B.Sc. and Ph.D. degrees
from the Olympic Dam Cu-U-Au-Ag deposit, South Australia: Defining the from the University of London, England. After
archetype for IOCG deposits: Ore Geology Reviews, v. 91, p. 173–195. working for the Geological Survey of Chile and then
Vila, T., Lindsay, N., and Zamora, R., 1996, Geology of the Manto Verde returning to the University of London as a Shell
copper deposit, northern Chile: A specularite-rich, hydrothermal-tectonic
postdoctoral research fellow, he has operated for
breccia related to the Atacama fault zone: Society of Economic Geologists,
Special Publication 5, p. 157–169. over 45 years as an independent consultant to more
von Quadt, A., Moritz, R., Peytcheva, I., and Heinrich, C.A., 2005, Geo- than 300 mining companies, international agencies,
chronology and geodynamics of Late Cretaceous magmatism and Cu-Au and foreign governments. He has worked on a wide variety of precious, base,
mineralization in the Panagyurishte region of the Apuseni-Banat-Timok- and lithophile metal deposits and prospects in 100 countries worldwide but
Srednogorie belt, Bulgaria: Ore Geology Reviews, v. 27, p. 95–126. focuses primarily on the epithermal gold and porphyry copper environments.

Downloaded from https://pubs.geoscienceworld.org/segweb/economicgeology/article-pdf/doi/10.5382/econgeo.4731/4965491/4731_sillitoe_et_al.pdf


by Uppsala Universetet user

Вам также может понравиться