SAFETY DATA SHEET

P 1/7

Product name : Seiken LLC NAL SDS DATE : Oct　1　2014

Version : 1.0
SDS number : MA14-301V-1

SECTION 1- Identification
Chemical Name Not applicable CAS Name / CAS No. Not applicable
Synonyms/Common Names Engine Coolant Not applicable,
Chemical Formula
Chemical Family Ethylene Glycol A Mixture

Manufacturer's PT. Indosarana Lokapratama Telephone Number 021-5902129

Name Facsimile Number 021-5924528
and Address
Emergency Erniawati Situmeang Telephone Number 021-5902129
Liaison man Quality Control Department Facsimile Number 021-5924528

SECTION 2 - Hazards identification

Signal Word
Danger

Hazard Classification
Acute Toxicity Category 5
Skin Corrosion /Trritation Category 3
Serious eye damage/ eye Irritation Category 2B
Reproductive toxicity 1B
Specific Target Organ Toxicity (single Exposure)- Category 1
Specific Target Organ Toxicity (Repeated Exposure)- Category 1
Hazardous to the aquatic enviroment(short term,Acute)- Category 3

Hazard Statement(s)
May be harmful if swallowed
Causes mild skin irritation
Causes eye irritation
May damage fertility or unborn child
Cause damage to organs
Harmful to aquatic life

Prevention Precautionary Statement(s)

Wash the hand thorougha fter handling.
Obtain special instructionsb efore use.
Do not handle until all safety precautions have been read a nd understood.
Wear protective gloves/protective clothing/e ye protection/face protection.
Do not breathe mist/vapours.
Do not eat, drink or smoke when using this product.
Avoid release

Response Precautionary Statement(s)

Call a POISON CENTER/doctor/if you feel unwell.
IF IN EYES:
Continue rinsing.
If eye irritation or persists: Get medical advice/attention.
IF exposed or concerned: Get medical advice/attention.
Get medical advice/attention i f you feel unwell.

Storage precautionary statement(s)

Store locked up.

Disposal Precautionary Statement(s)

Dispose of container in accordance with local/regional/national/international regulation.
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Product name : Seiken LLC NAL SDS DATE : Oct　1　2014

Version : 1.0
SDS number : MA14-301V-1

SECTION 3 - Composition/Information on ingredients

Hazardous Components (Specific ACGIH TLV Other Units
CAS No. OSHA PEL %(Optional)
Chemical Identity ; Common Names) (2005) Recommended
Ethylene Glycol 107-21-1 Not applicable 100mg/m3 Not applicable 91
Water Not applicable Not applicable Not applicable Not applicable 4.2
Sodium benzoate 532-32-1 Not applicable Not applicable Not applicable 2.6
Proprietary product. Mixture trace amount Not applicable Not applicable Not applicable Not applicable 2.2
of antioxidant and inhibitor.
SECTION 4 - First-aid measures
SWALLOWED
　・If swallowed do NOT induce vomiting.
　・If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain
　 open airway and prevent aspiration.
　・Observe the patient carefully.
　・Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
　・Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
　・Seek medical advice.

EYE
If this product comes in contact with the eyes:
・Immediately hold eyelids apart and flush the eye continuously with running water.
　・Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids
　 by occasionally lifting the upper and lower lids.
　・Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
　・Transport to hospital or doctor without delay.
　・Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

SKIN
If skin contact occurs:
　・Immediately remove all contaminated clothing, including footwear
　・Flush skin and hair with running water (and soap if available).
　・Seek medical attention in event of irritation.

INHALED
　・If fumes or combustion products are inhaled remove from contaminated area.
　・Other measures are usually unnecessary.

NOTES TO PHYSICIAN
・Treat symptomatically.

SECTION 5 - Fire-fighting measures

EXTINGUISHING MEDIA
　・Foam.
　・Dry chemical powder.
　・BCF (where regulations permit).
　・Carbon dioxide.
　・Water spray or fog - Large fires only.

FIRE FIGHTING
　・Alert Fire Brigade and tell them location and nature of hazard.
　・Wear breathing apparatus plus protective gloves.
　・Prevent, by any means available, spillage from entering drains or water courses.
　・Use water delivered as a fine spray to control fire and cool adjacent area.
　・DO NOT approach containers suspected to be hot.
 SAFETY DATA SHEET
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Product name : Seiken LLC NAL SDS DATE : Oct　1　2014

Version : 1.0
SDS number : MA14-301V-1

・Cool fire exposed containers with water spray from a protected location.
　・If safe to do so, remove containers from path of fire.
　・Equipment should be thoroughly decontaminated after use.

FIRE/EXPLOSION HAZARD
　・Combustible.
　・Slight fire hazard when exposed to heat or flame.
　・Heating may cause expansion or decomposition leading to violent rupture of containers.
　・On combustion, may emit toxic fumes of carbon monoxide (CO).
　・May emit acrid smoke.
　・Mists containing combustible materials may be explosive.

Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of burning organic material
May emit corrosive fumes.
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc.
as ignition may result.
Flash Point (Method used) 122 ℃(252°F) (C.O.C.)
Flammable Limits Upper 15.3 vol%
in Air (As E.G.) Lower 3.2 vol%
Auto ignition Temperature Not determined
Extinguishing Media Water spray, CO2, extinguish bubble, extinguish powder, halogen extinguishing agent
Special Fire Fighting Will choke with spraying or cooling, with extinguishing media.
Procedures Wear full protective clothing and self-contained breathing apparatus.
Unusual Fire and Stable at normal condition,
Explosion Hazards Non-reactive

SECTION 6 - Accidental release measures

MINOR SPILLS
　・Remove all ignition sources.
　・Clean up all spills immediately.
　・Avoid breathing vapours and contact with skin and eyes.
　・Control personal contact by using protective equipment.
　・Contain and absorb spill with sand, earth, inert material or vermiculite.
　・Wipe up.
　・Place in a suitable labelled container for waste disposal.

MAJOR SPILLS
Moderate hazard.
　・Clear area of personnel and move upwind.
　・Alert Fire Brigade and tell them location and nature of hazard.
　・Wear breathing apparatus plus protective gloves.
　・Prevent, by any means available, spillage from entering drains or water course.
　・No smoking, naked lights or ignition sources.
　・Increase ventilation.
　・Stop leak if safe to do so.
　・Contain spill with sand, earth or vermiculite.
　・Collect recoverable product into labelled containers for recycling.
　・Absorb remaining product with sand, earth or vermiculite.
　・Collect solid residues and seal in labelled drums for disposal.
　・Wash area and prevent runoff into drains.
　・If contamination of drains or waterways occurs, advise emergency services.
 SAFETY DATA SHEET
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Product name : Seiken LLC NAL SDS DATE : Oct　1　2014

Version : 1.0
SDS number : MA14-301V-1

SECTION 7 - Handling and storage

PROCEDURE FOR HANDLING
　・Avoid all personal contact, including inhalation.
　・Wear protective clothing when risk of exposure occurs.
　・Use in a well-ventilated area.
　・Prevent concentration in hollows and sumps.
　・DO NOT enter confined spaces until atmosphere has been checked.
　・Avoid smoking, naked lights or ignition sources.
　・Avoid contact with incompatible materials.
　・When handling, DO NOT eat, drink or smoke.
　・Keep containers securely sealed when not in use.
　・Avoid physical damage to containers.
　・Always wash hands with soap and water after handling.
　・Work clothes should be laundered separately.
　・Use good occupational work practice.
　・Observe manufacturer's storing and handling recommendations.
　・Atmosphere should be regularly checked against established exposure standards to ensure safe working
　　conditions.

SUITABLE CONTAINER
　・Metal can or drum
　・Packaging as recommended by manufacturer.
　・Check all containers are clearly labelled and free from leaks.

STORAGE INCOMPATIBILITY
Avoid reaction with oxidising agents.

STORAGE REQUIREMENTS
　・Store in original containers.
　・Keep containers securely sealed.
　・No smoking, naked lights or ignition sources.
　・Store in a cool, dry, well-ventilated area.
　・Store away from incompatible materials and foodstuff containers.
　・Protect containers against physical damage and check regularly for leaks.
　・Observe manufacturer's storing and handling recommendations.

SECTION 8 - Exposure controls/personal protection

EXPOSURE CONTROLS

PERSONAL PROTECTION
EYE
　No special equipment for minor exposure i.e. when handling small quantities.
　・OTHERWISE:
　・Safety glasses with side shields.
　・Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written
　 policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or
　 task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an
　 account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable
　 equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and
　 remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation
　 - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC
　 NIOSH Current Intelligence Bulletin 59]

HANDS/FEET
　No special equipment needed when handling small quantities.
　OTHERWISE: Wear general protective gloves, e.g.. light weight rubber gloves. Or as required:
　Wear chemical protective gloves, e.g.. PVC. Wear safety footwear.
 SAFETY DATA SHEET
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Product name : Seiken LLC NAL SDS DATE : Oct　1　2014

Version : 1.0
SDS number : MA14-301V-1

OTHER
　・Overalls.
　・P.V.C. apron.
　・Barrier cream.
　・Skin cleansing cream.
　・Eye wash unit.

RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant
and the chemical nature of the contaminant. Protection Factors
(defined as the ratio of contaminant outside and inside the mask) may also be important.

ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in specific
circumstances. If risk of overexposure exists, wear approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas. Air contaminants generated in the
workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air
required to effectively remove the contaminant.

SECTION 9 - Physical and chemical properties

3
Boiling Point (760mmHg) 165 ℃(329°F) Density(At 20℃) 1.129 g/cm
Vapor Pressure (As E.G.) 7 Pa (At 20℃) Percent Volatiles by VolumeNot determined
Vapor Density (As E.G.,Air=1) 2.1 Evaporation Rate(BuAc=1) Not determined
Freezing Point -13℃(9°F) pH Value(30vol%) 7.8
Appearance and Odor Green, Transparent liquid, Odorless Solubility in Water Soluble

SECTION 10 - Stability and reactivity

Stability Stable
Incompatibility (Materials to Avoid) Strong oxidizing materials and high oxygen concentrations.
Hazardous Decomposition Products Incomplete combustion can generate carbon monooxide and/or oxygenated
hydrocarbons.
Hazardous Polymerization Will not occur.

SECTION 11 - Toxicological information

POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
　The liquid is harmful if swallowed and may be fatal.
　Ingestion may result in nausea, abdominal irritation, pain and vomiting.
EYE
　The vapour and liquid both produce eye discomfort. Tearing and reddening of the eyes are symptomatic of overexposure.
　Higher levels of vapour are generated with increased temperature and engineering controls should be introduced
　when any discomfort is experienced following exposure to mists or vapour.
　The liquid is capable of causing a mild, temporary redness of the conjunctiva (similar to wind-burn),
　temporary impairment of vision and/ or other transient eye damage/ ulceration.
　The material may produce moderate eye irritation leading to inflammation.
　Repeated or prolonged exposure to irritants may produce conjunctivitis.
SKIN
　The liquid may be discomforting to the skin if exposure is prolonged.
　The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness,
　swelling, the production of vesicles, scaling and thickening of the skin.
INHALED
Not normally a hazard due to non-volatile nature of product.
　Inhalation of vapour is more likely at higher than normal temperatures.
　The vapour from heated material is discomforting to the upper respiratory tract and
　may be harmful if inhaled and if exposure is prolonged.
　Inhalation of vapour may result in nausea, headache.
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Product name : Seiken LLC NAL SDS DATE : Oct　1　2014

Version : 1.0
SDS number : MA14-301V-1

CHRONIC HEALTH EFFECTS

Primary route of exposure is usually by skin contact.
As with any chemical product, contact with unprotected bare skin; inhalation of vapour,
　mist or dust in work place atmosphere; or ingestion in any form,
　should be avoided by observing good occupational work practice.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances

TOXICITY IRRITATION
Ethylene Glycol :
Oral (rat) LD50: 4700 mg/kg Skin (rabbit): 555 mg(open)- Mild
Oral (human) LDLo: 398 mg/kg Eye (rabbit): 100 mg/1h - Mild
Oral (child) TDLo: 5500 mg/kg Eye (rabbit): 1440mg/6h- Moderate
Inhalation (human) TCLo: 10000 mg/m³ Eye (rabbit): 500 mg/24h - Mild
Dermal (rabbit) LD50: 9530 mg/kg Eye (rabbit): 12 mg/m³/3D
Inhalation (rat) LC50: 50100 mg/m³/8 hr
[Estimated Lethal Dose (human) 100 ml; RTECS quoted by Orica]
Substance is reproductive effector in rats (birth defects).
Mutagenic to rat cells.

SECTION 12 - Ecological information

none data

SECTION 13 - Disposal consideration

　・Recycle wherever possible or consult manufacturer for recycling options.
　・Consult State Land Waste Management Authority for disposal.
　・Bury residue in an authorised landfill.
　・Recycle containers if possible, or dispose of in an authorised landfill.

SECTION 14 - Transport information

Labels Required:
HAZCHEM: None
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA,
IMDG

SECTION 15 - Regulatory information

REGULATIONS
Ethylene Glycol is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
International Council of Chemical Associations (ICCA) - High Production Volume
List
Japan Chemical Substances Control Law - Existing/New Chemical Substances
Japan Fire Service Law
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Product name : Seiken LLC NAL SDS DATE : Oct　1　2014

Version : 1.0
SDS number : MA14-301V-1

Japan Industrial Safety and Health Law (ISHL) - Notifiable Substances

Japan Marine Pollution and Disasters
OECD Representative List of High Production Volume (HPV) Chemicals
Sodium Benzoate is found on the following regulatory lists;
International Council of Chemical Associations (ICCA) - High Production Volume
List
Japan Chemical Substances Control Law - Existing/New Chemical Substances
Japan Food Sanitation Law - Designated Additives
Japan Food Sanitation Law - Designated Additives (Japanese)
Japan Marine Pollution and Disasters
Japan Working Environment Evaluation Standards
OECD Representative List of High Production Volume (HPV) Chemicals

SECTION 16 - Other information

Reference document

Technologica independent administrative agency product evaluation basic mechanism GHS classification result
data base
JACA(Japan Auto Chemical Industry Association)edit Chemical management data base
Chemical Japanese auto Material Safety Data Sheet making indicator revised editation(industry for auto Chemical
product Meeting)
Dangerous article ship transportation and storing rule(see sentence temple)
NITE(CHRIP)DATA

-Attention
Safety Data Sheet: With reference information to secure safe handling about a dangerous, harmful chemical
product.
It is the one does, and is offered by entrepreneur who handles it. The entrepreneur who handles it: to an own
responsibility referring to this.
After it is understood that putting and lecturing on appropriate treatment according to the individual realities of
handling etc.
are necessary Please use.Therefore,this data sheet is awaited guarantee of safety.