) In an experiment to determine the specific heat of copper,
a piece of copper weighing 50g is first heated to 100°C in steam. It is then immersed into water at 27°C. The water in the calorimeter weighs 100g and the inner aluminum cap weighs 50g. If the final temperature is 30°C, what is the specific of copper, specific heat of aluminum is 0.22 Cal/g- deg°C. 2.) At STP the density of chlorine is 3.22 kg/m³. What is the weigh of this gas is contained in a flask of 100 cubic centimeters at 24°C and 100kPa? 3.) How much work is necessary to compress air in an insulated cylinder from 0.20 m³ to 0.01 m³? Use T1 = 20°C and P1 = 100 kPa 4.) A heat engine is operated between temperature limits 1370°C and 260°C. Engine is supplied with 14,142 kJ/kwh. Find the Carnot cycle efficiency in percent. 5.) A closed vessel contains air at a pressure of 160 kN/m² gauge and temperature of 30°C. The air is heated at constant volume to 60°C with the atmospheric pressure of 759 mm hg. What is the final gauge pressure? 6.) What is the temperature in °C of 2 liters of water at 30°C after 500 calories of heat have been added? 7.) A volume of 450 cm³ of ai is measured at a pressure of 740 mm Hg absolute and a temperature of 20°C. What is the volume in cm³ at 760 mm Hg absolute and 0°C? 8.) Assuming compression is according to the law PV= constant. Calculate the initial volume of gas at a pressure of 2 bar which will occupy a volume of 6m³ when it is compressed to a pressure of 42 bar. 9.) A steam condenser receives 10 kg per second of steam with an enthalpy of 2,570 kJ/kg. Steam condenses into liquid and leaves with an enthalpy of 160 kJ/kg. Cooling water passes through the condenser with temperature increases from 13°C to 24°C. Calculate the cooling water flow rate in kg/s. 10.) Ammonia weighing 22 kg is confined inside a cylinder equipped with a piston has an initial pressure of 413 kPa at 38°C. If 2900 kJ of heat is added to the ammonia intil its pressure and temperature are 413 kPa and 100°C, respectively. What is the amount of work done by the fluid in kJ ? (Note: Molecular Weight of NH3 = 17) 11.) The maximum thermal efficiency possible for a power cycle operating between 1200°F and 225°F is: 12.) Compute the gas constant of a mixture of 10 kg of oxygen and 20 kg of nitrogen per kg of the mixture? 13.) A tire contains 100 in³ of air of 80°F, and a pressure of 1 atmosphere. It is connected to a pump of capacity 10³. If the pump becomes 17.64 psia after one stroke, at what pressure (psia) must the tire valve open considering that the pump and tire temperature remains constant? 14.) A 30 kg iron was put in a container with water. The water is at 10°C and the iron has an initial temperature of 493 K, until the iron was in thermal equilibrium with the water. Find the change in entropy. 15.) Twenty grams of oxygen gas (O2) are compressed at a constant temperature of 30°C to 5% its original volume. Find the work done on the system? 16.) A device produce 37.5 joules per cycle. There is one power stroke per cycle. Calculate the power output if the device is run at 45 rpm? 17.) Five moles of water vapor at 100°C and 1 atmospheric pressure are compressed isobarically to form liquid at 100°C. The process is reversible and the ideal gas laws apply. Compute the work, in joules, done on the system. Note: R = 0.0821 L-atm/mol. °R 18.) A piston and cylinder arrangement contains saturated water vapor at 110°C. The vapor is compressed in a reversible, adiabatic process until the pressure is 1.6 Mpa. What is the work done by the system per kilogram of water? 19.) When 0.5 g of a liquid is completely evaporated and collected in a liter manometer, the pressure is 0.25 atm and the temperature is 27°C. Assume ideal gas behavior, find the molecular weight if the gas constant is R = 0.0821 atm/mol.K. 20.) For an ideal gas, what is the specific molar entropy change during an isothermal process in which the pressure change from 200kPa to 150 kPa? 21.) A gas is enclosed in a cylinder with a weighted piston as the top boundary. The gas is heated and expands from a volume of 0.04 m³ to 0.10 m³ at a constant pressure of 200kPa. Find the work done on the system. 22.) In the process where the product of pressure and volume Is constant, a gas compression is carried out from an initial pressure of 200 kPa to a final pressure of 800 kPa. Considering that the initial specific volume is 0.10 m³/kg, determine the work done per kilogram of gas.