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Global Hydrocarbon Processing

Solutions Guide
• Crude Oil
• Refining
• Natural Gas
• Alternative Fuels
• Trace Impurities
• TOGA
• Greenhouse Gases
• Sulfur Analysis
Proven Hydrocarbon Processing solutions
that meet the demands of your company… and your industry
From crude oil and natural gas… to specialty chemicals • Customized analyzers – configured and tested
and alternative fuels… Agilent, together with our to pre-determined specifications agreed with the
Channel Partners, brings you the most complete analy- customer at the time of quote
sis portfolio for the Hydrocarbon Processing industry.
• Customized instrumentation and tools –
On the following pages, you’ll find an overview of our designed, delivered, and supported by Agilent
innovative solutions, all backed by more than 40 years Channel Partners
of trusted industry leadership. These include:
Each solution is factory pre-tested and pre-config-
• Simple instrument modifications – such as use ured – and includes installation and performance veri-
of deactivated tubing and addition of special columns fication, as well as expert consultation and support
or valves from Agilent and our Channel Partners. Together, we
can help you spend less time setting up your analysis
• More than 100 factory tested analyzers –
methods and more time producing outstanding results
including analyzers that conform to industry stan-
right from day one.
dards such as ASTM, UOP, EN, and GPA
2
Table of Contents
Introduction 2
SP1 No. Analyzer Configuration for Published Methods Page
Natural Gas Analysis Solutions

7890-0042 Natural Gas Analyzer GPA 2261 8
7890-0192 Natural Gas Analyzer for sour gas GPA 2261 8
7890-0100 Natural Gas Analyzer ASTM D1945, GPA 2261 9
7890-0012 Natural Gas Analyzer GPA 2261, 10
7890-0110 Natural Gas Analyzer GPA 2177 11
7890-0323 Natural Gas Analyzer ASTM D1945, GPA 2261 12
7890- 0171 Extended Natural Gas Analyzer GPA 2286 (calculation without 13
bridge compounds: iC5, nC5)
7890-0344 Extended Natural Gas Analyzer GPA 2286 (calculation with bridge 14
compounds: iC5, nC5)
7890-0263 Extended LNGA Analyzer GPA 2186 15
Refinery Gas Analyzer

7890-0322 Fast Refinery Gas Analyzer (3-channel) ASTM D1945, D1946, UOP 539 19
7890-0338 Fast Refinery Gas Analyzer (with H2S) ASTM D1945, D1946, UOP 539 20
(3-channel)
7890-0337 Fast Refinery Gas Analyzer (2-channel) ASTM D2163, D1946 21
7890-0339 Fast Refinery Gas Analyzer (with H2S) ASTM D2163, D1946 22
7890-0004 Refinery Gas Analyzer ASTM D1946, D1945, UOP 539 23
7890-0107 Refinery Gas Analyzer–extended up to C9 24
7890-0166 Refinery Gas Analyzer for sour gas ASTM D1946, D1945, UOP 539 25
7890-0226 Refinery Gas Analyzer for sour gas Extended refinery gas analyzer for samples 26
with high hydrogen and 5% H2S
7890-0188 LPG analyzer ASTM D2163, ISO 7941/EN27941/IP405 27
7890-0138 LPG analyzer ASTM D2163, D2593, D2712, D4424 28
Trace Impurities Analysis Solutions

7890-0282 Low CO,CO2 in Natural Gas Analyzer Analyze trace CO and CO2 in process gases 30
containing high methane and heavier HCs
like natural gas
7890-0304. Low CO, CO2 in Process Gas Analyzer by Analyze trace CO and CO2 in higher hydrocarbons 31
PDHID containing low methane like PG ethylene
7890-0366 Trace CO and CO2 in Hydrogen and Light UOP 603 32
Gaseous Hydrocarbons
7890-0219 Trace Impurities in Helium Analyzer by PDHID 33
7890-0237 Trace Impurities in Monomers Analyzer 34
by PDHID
7890-0409 Trace impurities in C2H4/C3H6 by PDHID 35
3
7890-0191 Inert Impurities in Pure Chlorine Analyzer 36

(2-channel)
7890-0305 Inert Impurities in Crude Chlorine Analyzer 37
7890-0341 Trace Oxygenate and Hydrocarbons in Use Deans switch to measure trace 38
Ethylene Analyzer oxygenates and hydrocarbons in ethylene
and propylene in a single run
Transformer Oil Gas Analyzer

7890-0047 Transformer Oil Gas Analyzer ASTM D3612-A 40
7890-0261 Transformer Oil Gas Analyzer ASTM D3612-C 41
Reformulated Fuels Analyzer

7890-0049 Oxygenates in Fuel Analyzer ASTM D4815 43
7890-0183 Oxygenates and Aromatics in Fuel : Single ASTM D4815, D5580 44
Channel Analyzer
7890-0291 Oxygenates and Aromatics in Fuel: Dual ASTM D4815, D5580 45
Parallel Channels Analyzer
7890-0106 Aromatics in Fuel Analyzer ASTM D5580 46
7890-0198 Benzene in Gasoline Analyzer ASTM D3606 47
7890-0308 Oxygenates, Aromatics, Benzene in ASTM D4815, D5580, D3606 48
fuel Analyzer
7890-0098 Oxygenates and Aromatics in Gasoline by EN13132/12177 49
Deans- Switch Analyzer
7890-0178 Low Level Oxygenates in Light Hydrocarbons ASTM D7423 50
by Deans- Switch Analyzer
7890-0340 Trace Oxygenates in Reformulated Gasoline New proposed ASTM method for trace 51
Analyzer oxygenates in gasoline blending materials
Sulfur Analyzer
7890-0148 Volatile Sulfur in C2, C3, C4 monomers ASTM D6228 53
and LPG Analyzer by FPD
7890-0167 Volatile Sulfur in NGA, fuel gas Analyzer ASTM D6228 53
by FPD
7890-0365 Sulfur in light petroleum liquids by SCD ASTM D5623 54
7890-0375 Sulfur in gas fuels by SCD ASTM D5504 55
Bio-diesel Analyzer
7890-0294 Glycerin in Biodiesel Analyzer ASTM D6584 57
7890-0297 Glycerin in Biodiesel Analyzer EN14105 57
7890-0300 FAME Content in Biodiesel Analyzer EN14103 58
7890-0295 Methanol in Biodiesel Analyzer EN14110 59
7890-0307 FAME Content in Biodiesel Blands Analyzer For biodiesel blends (reference: EN14331) 60
7890-0427 Five in one Biodiesel analyzer EN14105 / ASTM D6584, EN14103, 61
EN14110, EN14106
4
SIMDIS Analyzer
G3440A Option 653 SIMDIS Analyzer: Boiling Range from ASTM D2887 64
55 to 538℃
7890-0461 SIMDIS Analyzer Boiling Range from ASTM D7213 (extended 2887) 65
100 to 615℃.
7890-0462 SIMDIS Analyzer Boiling Range from ASTM D6352 66
174 to 700℃.
Greenhouse Gases Analyzer

7890-0468 Greenhouse gases analyzer with single 69
channel
7890-0467 Greenhouse gases analyzer with separated 70
channel
Miscellaneous
7890-0496 Prefractionator for Analysis of Light Ends 72
of Crude Oil
7890-0084 Gas Blender 73
7890-0130 Gas Blender (designed for GCMS system) 73
7890-0244,0204,0145, Stream Selection Valve- type SD 74
0064,0063,0048,0030,
0010,0007
7890-0326,0190,0067, Stream Selection Valve- type SC 75
0037,0005
7890-0287,0077,0067, Stream Selection Valve- type SF 76
0055,0034
7890-0301,0299,0090, Stream Selection Valve- type ST 77
0089,0088,0080
7890-0076,0075 Stream Selection Valve- type STF 78
7890-0082,0103,0239, Special Passivation with Sulfinert™ 79
0240,0243,0313,0382
Solutions from Agilent’s 80
Channel Partner
5
Natural Gas Analysis Solutions
The process of collecting, processing, transmitting, and distributing natural

gas creates an array of analytical needs. Agilent has created a broad prod-
uct suite to address these diverse needs.
The following solutions cover hydrocarbons from C1 to C5, C6 + as backflush,

or extended to C16. The lowest quantification limit for hydrocarbons is 10
ppm by FID or 50 ppm by TCD. The lowest quantification limits for perma-
nent gases by TCD with He carrier gas are: O2, N2, CO, CO2 50 ppm, H2S
500 ppm. Table 2 is a guideline for selecting the right SP1 solution for nat-
ural gas analysis.
6
Extend Full-range Separate High Handles
hydrocarbons capacity air level liquid
SP1 Capability to C16 for H2 (O2 and N2) of H2S samples
SP1 7890-0042
` Single TCD channel with packed No No Yes No No
columns covers C1-C5 ,C6+ as
backflush, O2, N2, H2S, CO2, CO
SP1 7890-0192
` Same configuration as 7890-0042 No No Yes Yes No
` Nickel columns, Hastelloy valve,
nickel plumbing for high H2S analysis
SP1 7890-0100
` Dual TCD channels with packed No Yes Yes No No
columns cover C1-C5, C6+as backflush,
O2, N2, H2S, CO2, CO, He, H2
SP1 7890-0012
` Single TCD channel with packed No No No No No
columns cover C1-C5, C6+ as
backflush, air composite, CO2
SP1 7890-0110 with LSV
` Single TCD channel with packed No No No No Yes
columns covers C1-C6, C7+ as
backflush, air composite, CO2
` LSV is for liquefied natural
gas induction
SP1 7890-0323
` Dual-channel with dual-TCD, FID, No Yes Yes No No
packed columns cover C1-C7, C8+, O2,
N2, H2S, CO2, CO, He, H2
SP1 7890-0171
` Dual channels with TCD and FID, Yes No Yes No No
C1-C3, O2, N2, H2S, CO2 are separated
on packed column and measured on
TCD. C4-C16 hydrocarbons are
separated on PONA capillary column
and measured on FID
SP1 7890-0344
` Special design for GPA 2286, the calculation
uses bridge components: iC5 and nC5
` Fixed gases and hydrocarbons up to C5
on packed columns and TCD
` Hydrocarbons from C5 to C14 are Yes No Yes No No
analyzed on a capillary column and a FID
` Software is supplied that may be used
with the Agilent ChemStation to supply a
report giving the GPA2286 results
` Dual channels with TCD and FID Yes No No No Yes
extend liquefied natural gas analysis.
C6+, C1-C5, CO2, air composite are
separated on packed column and
measured on TCD. C4-C14
hydrocarbons are separated on
PONA column and measured on FID
` LSV is for liquefied natural gas induction
7
Natural Gas Analyzer 7890-0042/7890-0192
Analyzer Description (7890-0042)

Configuration:
3-valve/4-column (packed column)/TCD
Sample type:
Natural gas and similar gaseous mixtures
Compounds separated:
C1-C5 (methane, ethane, propane, iso-butane, n-butane, iso-pentane, and n-pentane), C6+ as backflush,
O2, N2, H2S, CO2, and CO
Lowest quantification limit:
50 ppm for all components except H2S, 500 ppm for H2S
Published methods met:
GPA 2261
Typical Chromatogram
Methane
25 µV
4000
Propane
3000 H2S area

Iso-Butane
N-Butane
Ethane
2000
Nitrogen
Iso-Pentane
N-Pentane
1000
C6+
Oxygen
CO2
0
0 5 10 15 20 25 min
Key Features and Benefits

• Single TCD channel
• Rugged packed columns
• 20-minute analysis time
• Second FID capillary channel can be added for extended natural gas
• Natural gas calculation software for ChemStation provided
• The same configuration as 7890-0042 but use nickel columns and Hastelloy valve, sample inlet line, and frit for
high concentrations of H2S containing natural gas (7890-0192)
8
Natural Gas Analyzer 7890-0100
Analyzer Description
Configuration:
4-valve/6-column (packed column)/2-TCD
Sample type:
C1-C5, C6+, H2, He, O2, N2, H2S, CO2, and CO
ASTM D1945, GPA 2261
Front TCD
Propane
Methane
Ethane
Iso-Butane N2
N-Butane
Iso-Pentane
C6+ N-Pentane CO 2 O2
H2
He
Back TCD

• Dual TCD channels
• Full-range capability for H2 and He
9
Configuration:
1-valve/2-column (packed column)/TCD
Sample type:
C1-C5 (methane, ethane, propane, iso-butane, n-butane, iso-pentane, and n-pentane), C6+ as backflush,
air composite, and CO2
Sample type:
50 ppm for all components
GPA 2261
Methane
Ethane
Nitrogen/oxygen
Propane
Carbon dioxide
Iso-Butane
N-Butane
Iso-Pentane
N-Pentane
C6+

• Simple and lowest-cost for light hydrocarbon analysis
10
Configuration:
1-valve/1-liquid valve/2-column (packed column)/TCD
Sample type:
Natural gas and similar gaseous mixtures; liquefied natural gas
C1-C6 (methane, ethane, propane, iso-butane, n-butane, isopentane, n-pentane, 2,2-dimethylbutane,
2,3-dimethylbutane, 2-methyl-pentane, 3-methyl-pentane, cyclopentane, n-hexane), C7+ as backflush,
air composite, CO2
50 ppm for all components
GPA 2177
Propane
Ethane
N-Butane
Heptane C6+
2-3-Diamethylbutane and methylpentane

Iso-Butane
2-Methylpentane and cyclopentane

Methane
N-Pentane
Carbon dioxide
Iso-Pentane
N-Hexane
Nitrogen

• Simple and lowest cost
• Liquid sample valve for liquefied natural gas
11
Configuration:
4-valve/6-column (packed column)/2-TCD/FID
Sample type:
C1-C7, C8+, H2, He, O2, N2, H2S, CO2, and CO
10 ppm for hydrocarbons, 50 ppm for all permanent gases, 500 ppm for H2S
ASTM D1945, ISO 6974, GPA 2261
Front TCD/FID
Propane
Methane
Ethane
Iso-Butane N2
N-Butane
Iso-Pentane
C6+ N-Pentane CO 2 O2
H2
He
Back TCD

• Dual-TCD and FID system is basically the same as 7890-0100, but the FID is added in series to first TCD to
increase the higher sensitivity for hydrocarbons
• 20-minute analysis time (C1-C5, C6+)
12
Extended Natural Gas Analyzer 7890-0171
Configuration:
3-valve/4-column (capillary and packed column)/TCD/FID
Sample type:
C1-C14, O2, N2, CO2, and CO
50 ppm for permanent gases and C1-C3 hydrocarbons on TCD, 10 ppm for C4-C16 hydrocarbons on FID
GPA 2286, but calculation without bridge components: iC5 and nC5
Typical Chromatogram N-Butane
pA
Propane
FID channel
N-Pentane
900
I-Pentane
800
700
I-Butane
Methane/ethane
600
500
Hexane
400
300
200
100
0
2 4 6 8 10 Methane min
25 µV
900
800 TCD channel
700
Nitrogen
600
Carbon dioxide
500
Ethane
400
300
Oxygen
200
100
0
2 4 6 8 10 min

• Dual channels with TCD and FID detectors
• TCD channel with packed column for C1-C3, O2, N2, H2S , CO2 analysis
• C4-C16 hydrocarbons separated on PONA column and measured on FID
• Can be used for liquefied natural gas by adding additional liquid valve
13
Extended Natural Gas Analyzer 7890-0344
Configuration:
4-valve/3-column (capillary and packed column, one of packed column is a ‘composite’ column consisting of
three special columns connected together)/TCD/FID
Sample type:
C1-C14, O2, N2, CO2, and CO
50 ppm for permanent gases and C1-C5 hydrocarbons on TCD, 10 ppm for C5-C14 hydrocarbons on FID
GPA 2286 (calculation uses bridge components: iC5, nC5 required by GPA 2286)
25 µV
Methane
6000
TCD
Ethane
5000
Propane
4000
Nitrogen
3000
Iso-Butane
N-Butane
Carbon dioxide
Iso-Pentane
2000
N-Pentane
Oxygen
1000
0
0 2 4 6 8 10 12 min
pA
8000
7000
6000
FID
5000
4000
Iso-Butane
N-Butane
Iso-Pentane
3000
N-Pentane
2000
Hexane
1000
0
34 36 38 40 42 44 46 48 min

• Two-channel with TCD and FID detectors
• Fixed gases and hydrocarbons up to C5 on packed columns and thermal conductivity detector
• Hydrocarbons from C5 to C14 are analyzed on a capillary column and a flame ionization detector
• The pentanes are used as ‘bridging’ compounds in the calculation
• Software is supplied that may be used with the Agilent ChemStation to supply a report giving the
GPA2286 results
14
Extended LNGA Analyzer 7890-0263
Configuration:
2-valve/2-liquid valve/2-column (capillary and packed column)/TCD/FID
Sample type:
Liquefied natural gas
C1-C16, air, CO2
50 ppm for permanent gases and C1-C3 hydrocarbons, 10 ppm for C4-C16 hydrocarbons
GPA 2186
Methylcyclopentane
2-Methylpentane
3-Methylpentane
I-butane N-butane
Ethane
pA
N-Pentane
N-Hexane
I-Pentane
23 Dimethylbutane/cyclopentane
N-Heptane
200 FID channel

Methane
Methylcyclohexane
Cyclohexane
175
224 Trimethylheptane
150
Tert-Butylcyclohexane
c + t 12 Dimethylhexane
125
Tert-Butylcyclohexane
124 Trimethylbenzene
Benzene
23 Dimethylpentane
22 Dimethylbutane
24 Dimethylpentane
N-Proplcyclohexene
Toluene
100
25 Dimethylhexane
2 Methylheptane
N-Butylbexene
3 Ethylpentane
Ethylbenzene
75
Cyclooctane
N-Norane
N-Octane
O-Xylene
50
25
2 4 6 8 10 12 14 16 18 min
25 µV
Methane
900
800
TCD channel
Ethane
700
600
Carbon dioxide
500
Propane
400
N-Butane
N-Pentane
300
I-Butane
I-Pentane
200
100
0
0 2 4 6 8 10 12 14 min

• Dual channels with TCD and FID detectors for extended liquefied NGA
• C1-C3, CO2, and air composites are separated on packed column and measured on TCD
• C4-C16 hydrocarbons are separated on PONA capillary column and measured on FID
• Liquid valve for sample introduction
• ChemStation macro supplied for GPA 2186 report; Microsoft Excel required
15
Refinery Gas Analysis Solutions
Refinery gas and chemical plant analyzers are an integral part of any refin-
ery or petrochemical plant lab. These analyzers provide valuable informa-
tion regarding operations, unit optimization, and the release of finished
products. Agilent offers many different configurations for extended and fast
(6 minutes) refinery gas analysis.
The refinery gas analysis solutions cover hydrocarbons from C1 to C5, C6 +

as backflush or extended to C15. The lowest quantification limit for hydro-
carbons is 10 ppm by FID or 50 ppm by TCD. The lowest quantification
limits for permanent gases by TCD with He carrier gas are: O2, N2, CO, CO2
50 ppm, H2S 500 ppm. The lowest quantification limit for H2 is 50 ppm by
TCD with Ar or N2 carrier gas. For H2S analysis, Agilent offers analyzers
plumbed with sulfur-resistant material. Table 3 is a guide for selecting the
right analyzer for refinery gas analysis.
16
Extended Full-range High Handles
Fast hydrocarbons capacity level liquid
SP1 Capability analysis to C15 for H2 of H2S samples
SP1 7890-0322
` Three channels with FID, duel TCD Yes No Yes No No
with capillary column and packed
backflush, O2, N2, CO2, CO, He, H2
within 6 minutes. Needed additional
3 to 4 minutes for H2S and COS
SP1 7890-0338
` Three channels with FID, duel TCD Yes No Yes Yes No
with capillary column and packed
backflush, O2, N2, H2S, CO2, CO, He, H2
within about 10 minutes.
` Nickel tubing packed column and
Hastelloy-C, valve for high H2S analysis
` Dual channels with FID, TCD with Yes No No Yes Yes
capillary column and packed column
covers C1-C5, C6+ as backflush, O2, N2,
H2S, CO2, CO, within about 10 minutes.
` LSV for LPG introduction
` Nickel tubing packed column and
Hastelloy-C valve for high H2S analysis
` Dual channels with FID, TCD with Yes No No No Yes
capillary column and packed column
covers C1-C5, C6+ as backflush, O2,
N2, H2S , CO2, CO, within 6 minutes
` LSV for LPG introduction
SP1 7890-0004
` Dual channels with TCD and packed No No Yes No No
column covers C1-C5, C6+ as backflush,
O2, N2, H2S, CO2, CO, He, H2 within
about 40 minutes
SP1 7890-0107
` Dual channels with TCD, capillary and No No Yes No No
packed column covers C1-C10, O2, N2,
H2S, CO2, CO, He, H2 within about
15 minutes (hydrocarbon up to C5)
` Full-range capability for H2 by switching
carrier gas
17
Extended Full-range High Handles
Fast hydrocarbons capacity level liquid
SP1 Capability analysis to C15 for H2 of H2S samples
SP1 7890-0166 (for sour gas)
` Dual channels with TCD and packed No No Yes Yes No
column covers C1-C5, C6+ as backflush,
O2, N2, H2S, CO2, CO, He, H2 within
about 20 minutes
` Same configuration as 7890-0004,
but plumbed with sulfur-resistant
material, such as nickel columns,
Hastelloy valve, nickel plumbing for
sour gas analysis high (H2S)
SP1 7890-0169
` Same configuration as 7890-0107 No Yes Yes No No
` Use PONA column instead of alumina
column to extend hydrocarbon to C15
SP1 7890-0226
` Dual TCD/FID channels for C1-C9, No No No No Yes
H2, O2, N2, CO2, CO, H2S
` Special packed columns in sulfinert plus
spare set, sulfinert-treated needle valve
for H2S in the range 100 ppm to 5%
SP1 7890-0188
` Single packed column with FID channel No No No No Yes
for C1-C6
` Specially designed for commercial
propane and butane by ISO7941/
EN27941/IP405
SP1 7890-0138
` Single alumina column with FID No No No No Yes
channel for C1-C8
` Specially designed for LPG, it is ideal for
the separation of cyclopropane and
propylene
18
Fast Refinery Gas Analyzer 7890-0322 (3-Channel)
Configuration:
5-valve /7-column (PLOT and packed column)/2-TCD/FID
Sample type:
Refinery gas such as atmospheric overhead, FCC overhead, fuel gas, recycle gas
C1-C5, C6+, H2, He, O2, N2, CO2, CO, H2S
50 ppm H2, He, N2, CO2, CO, 500 ppm for H2S, for low concentration of
hydrocarbons use lower split ratio
ASTM D1945, ASTM D1946, UOP 539
5
FID channel
3
2 7 8
4 9 20 22
12 13 18
14 15
1
6 10 11 16 17 19 21 23
1 2 3 4 5 6 min
26
2nd TCD channel
24 2
25 27
1 2 3 4 5 6 min
H2 1. C 6+ 8. Isobutane 15. C-2-butane 22. 1-pentene
2. Methane 9. N-butane 16. Isopentane 23. C-2-pentane
3. Ethane 10. Propadiene 17. N-pentane 24. CO 2
4. Ethylene 11. Acetylene 18. 1,3-butadiene 25. O 2
He 5. Propane 12. T-2-butene 19. Propyne 26. N 2
3rd TCD channel
6. Cyclopropane 13. 1-butene 20. T-2-pentane 27. CO
7. Propylene 14. Isobutylene 21. 2-methyl-2-butene
1 2 3 4 5 6 min

• Three parallel channels with simultaneous detection for complete refinery gas analysis within 6 minutes
• Optimized columns allow faster hydrocarbon and permanent gas analysis with the same oven temperature
program
• Full-range capability for H2 by third TCD using N2 or argon carrier gas
• Need additional 3 to 4 minutes for H2S and COS (7890-0338)
• Sample should contain no water if H2S analysis is required
19
Fast Refinery Gas Analyzer (with H2S) 7890-0338
(3-Channel)
Configuration:
5-valve/7-column (PLOT and packed column)/2-TCD/FID/nickel tubing packed column/Hastelloy-C valve
Sample type:
Refinery gas such as atmospheric overhead, desulfurizer off gas, FCC overhead, fuel gas, recycle gas
C1-C5, C6+, H2, He, O2, N2, CO2, CO, H2S, COS
50 ppm for H2, He, N2, CO2, CO, 500 ppm for H2S, 300 ppm for COS, for low
concentration of hydrocarbons use lower split ratio
ASTM D1945, ASTM D1946, UOP 539
2 3 8
9 13 FID channel
7 15
4 12 14 21
18
1 6 1011 16 17
22
19 20 23
0 2 4 6 8 10 min
µV
55
50
45
2nd TCD channel
26
40
2 3 H2S COS
24 4/11 25 27
0 2 4 6 8 10 min
H2 1. C 6+ 8. Isobutane 15. C-2-butane 22. 1-pentene

He 5. Propane 12. T-2-butene 19. Propyne 26. N 2 3rd TCD channel
1 2 3 4 5 6 min

• Three parallel channels with simultaneous detection for complete RGA analysis within 10 minutes
• Optimized columns allow faster hydrocarbon and permanent gas analysis with the same oven temperature
program
• Full-range capability for H2 by third TCD using N2 or Ar as a carrier gas
• Nickel tubing packed column and Hastelloy-C valve for high H2S analysis
• Sample should contain no water
20
Fast Refinery Gas Analyzer 7890-0337 (2-Channel)
Configuration:
4-valve/LSV/5-column (PLOT and packed column)/TCD/FID
Sample type:
Refinery gas, liquid petroleum gas
C1-C5, C6+, O2, N2, CO2, CO
50 ppm for H2, He, N2, CO2, CO, 500 ppm for H2S, 300 ppm for COS, for low
concentration of hydrocarbons use lower split ratio
ASTM D2163, ASTM D1946
5 FID channel
3
2 7 8
4 9 12 18 20 22
13 14 15
6 19 21 23
1 10 11 16 17
1 2 3 4 5 6 min
1. C 6+ 8. Isobutane 15. C-2-butane 22. 1-pentene

26 3. Ethane 10. Propadiene 17. N-pentane 24. CO 2
5. Propane 12. T-2-butene 19. Propyne 26. N 2
TCD channel
24 2 27
25
1 2 3 4 5 6 min

• Dual channels for fast refinery gases analysis, including liquid petroleum gases analysis
• LSV for liquid petroleum gases introduction
• Optimized columns allow faster hydrocarbon and permanent gas analysis with the same oven
temperature program
• Need additional 3 to 4 minutes for H2S and COS (7890-0339)
• Low concentration of H2 uses 7890-0322
• Sample should contain no water if H2S analysis is required
21
Fast Refinery Gas Analyzer (with H2S) 7890-0339
(2-Channel)
Configuration:
4-valve/LSV/5-column (PLOT and packed column)/TCD/FID/nickel tubing packed column/Hastelloy-C valve
Sample type:
Refinery gas, liquid petroleum gas
C1-C5, C6+, O2, N2, CO2, CO, H2S, COS
50 ppm for H2, He, N2, CO2, CO, 500 ppm for H2S, 300 ppm for COS, for
low concentration of hydrocarbons use lower split ratio
1. C 6+ 8. Isobutane 15. C-2-butane 22. 1-pentene
pA 5. Propane 12. T-2-butene 19. Propyne 26. N 2
5 7. Propylene 14. Isobutylene 21. 2-methyl-2-butene
400
300 3
2 8 FID channel
7 9 13
200 15
4 12 14 21
100 18
1 6 1011 16 17
22
19 20 23
0
0 2 4 6 8 10 min
25 µV
17500 µV
15000 55
12500 50
10000 45
TCD channel
7500
26
40
5000
2500 2 3 H2S COS
24 4/11 25 27
0
0 2 4 6 8 10 min

• Dual channels with FID and TCD fast refinery gases system includes liquid petroleum gases analysis
• Nickel tubing packed column and Hastelloy-C valve for high H2S analysis
• 9- to 10-minute analysis time
• Low concentration of H2 uses 7890-0322
22
Refinery Gas Analyzer 7890-0004
Configuration:
4-valve/5-column (packed column)/2-TCD
Sample type:
C1-C5, C6+, H2, He, O2, N2, CO2, CO, H2S
UOP 539, ASTM D1946, and ASTM D1945
25 µV
I-Butane
600
1-Butene
Nitrogen Front TCD

Propane
500
N-Butane
trans-2-butene
Carbon dioxide
Ethane
400
cis-2-butene
Carbon monoxide
300
I-Pentane
Methane
Propylene
N-Pentane
200
Ethylene
100
0 5 10 15 20 25 30 35 40 min
25 µV
2500
2000 Hydrogen
Back TCD
1500
1000
500
Backflush Peak
0
0 5 10 15 20 25 30 35 40 min

• Dual TCD channels
23
Refinery Gas Analyzer 7890-0107/7890-0316/7890-0169
Analyzer Description (7890-0107)

Configuration:
4-valve/5-column (PLOT and packed column)/TCD/FID
Sample type:
C1-C9, H2, He, O2, N2, CO2, CO, H2S
50 ppm for permanent gases, 10 ppm for hydrocarbons, 500 ppm for H2S
FID channel TCD channel
Propane
Ethane
Isobutane
H2 N2
1-Butene
N-Butane
trans-2-butene
cis-2-butene
I-Pentane
CO 2
Ethylene
N-Pentane
Propylene
CH 4 CO

• Alumina column provides excellent separation of hydrocarbons from C1 to nC9
• Full-range capability including H2 and He can be achieved by unique carrier gas switching (Argon or N2 is used
for H2 analysis and He for the rest)
• Approximate 15-minute analysis time (depending on hydrocarbon range) for hydrocarbons up to C5
• Use PLOT Q instead of alumina column when olefin resolution is not mandatory (7890-0316); extend
RGA to C7
• Use PONA instead of alumina column to extend hydrocarbons to C14 (7890-0169); extend RGA to C14
24
Configuration:
4-valve (Hastelloy )/5-column (packed column)/2-TCD/plumbed with sulfur-resistant material
Sample type:
Refinery gas such as atmospheric overhead, FCC overhead, fuel gas, recycle gas, sour gas
C1-C5, C6+, H2, He, O2, N2, CO2, CO, H2S
50 ppm for all compounds except H2S, 500 ppm for H2S
ASTM D1945, ASTM D1946, GPA 2261
25 µV
Isobutane
600
1-Butene
Nitrogen
Front TCD
Propane
500
N-Butane
trans-2-butene
Carbon dioxide
Ethane
400
cis-2-butene
Carbon monoxide
300
Isopentane
Methane
Propylene
N-Pentane
200
Ethylene
100
0 5 10 15 20 25 30 35 40 min
25 µV
2500
2000 Hydrogen
Back TCD
1500
1000
500
Backflush Peak
0
0 5 10 15 20 25 30 35 40 min

• Dual TCD channels, the hardware configuration is the same as 7890-0004, but plumbed with sulfur-resistant
material such as nickel columns, Hastelloy valve, nickel plumbing for sour gas
• Full-range capability for H2
• Approximate 20-minute analysis time
25
Configuration:
3-valve/liquid valve (optional)/4-column (PLOT and packed column – sulfinert treated)/FID/TCD/plumbed with
sulfur-resistant material
Sample type:
Refinery gas (contains H2S in the range of 100 ppm to 5%)
C1-C9, H2,O2, N2, CO2, CO, H2S
50 ppm for permanent gases except H2, 10 ppm for hydrocarbons, 500 ppm for H2S, 15 Vol% for H2
Front FID
4.142 - Propane
pA
13.130 - 1-Butane
2.587 - Ethane
8.412 - t-Butane
5000
2.241 - Methane
14.127 - c-2-Butane
4500 12.805 - t-2-Butane
9.192 - n-Butane
4000
15.034 - t-Pentane
3500
15.628 - n-Pentane
3.103 - Ethylene
3000
7.210 - Propylene
2500
2000
1500
1000
500
0
0 2 4 6 8 10 12 14 16 18 min
12.603 - Nitrogen
3.855 - Carbon dioxide
25 uV
13.777 - Carbon monoxide
Back TCD
1000
13.248 - Methane
800
1.459 - Hydrogen
4.953 - Ethylene
12.198 - Oxygen
600
400
200
0 2 4 6 8 10 12 14 16 18 min

• TCD/FID channels for hydrocarbons, permanent gas, and H2S
• Special packed columns in sulfinert plus spare set, sulfinert-treated needle valve for H2S in the range
100 ppm to 5% on TCD
26
LPG Analyzer 7890-0188
Configuration:
Liquid valve/1-column (packed column)/FID
Sample type:
LPG, commercial propane and butane
C1-C6
10 ppm for hydrocarbons
ISO 7941/EN27941/IP405, ASTM D2163
pA
I-Butane
Ethane
400
350
300
1-Butane
Propane
250
N-Butane
Methane
200
T-2-Butane
C-2-Butane
150
I-Pentane
Ethylene
N-Pentane
Propylene
100
50
0 2 4 6 8 10 12 min

• Single channel with single LSV
• Rugged packed column
• The GC is configured to analyze liquefied petroleum gas, specifically propane and butane, for commercial use
27
LPG Analyzer 7890-0138
Configuration:
Liquid valve/1-column (PLOT Alumina)/FID
Sample type:
LPG
C1-C8
10 ppm for hydrocarbons
ASTM D2163
Isobutane
pA
n-Butane
Propane
Ethane
4500
Propylene
4000
Methane
3500
trans-2-Butene
Ethylene
3000
2500
cis-2-Butene
Butene-1
2000
n-Pentane
1,3 Butadiene
Isobutylene
Acetylene
Isopentane
1500
2-m-2 Butene
c-2-Pentene
1000
t-2-Pentene
1-Pentene
n-Hexane
500
0
0 2 4 6 8 10 12 14 16 18 min

• Single channel with single LSV
• PLOT Alumina is ideal for the separation of the C1 to C8 isomers, especially for the separation of
cyclopropane and propylene
28
Trace Impurities Analysis Solutions
Producers of high-purity monomers such as ethylene and propylene face

stiff competition and increasingly tight customer specifications. They are
called on to test for more and more impurities at lower and lower detection
limits, as buyers of these chemicals utilize more selective and sensitive
polymerization catalysts. With the catalysts' susceptibility to poisoning and
contamination and the high cost of catalyst replacement and plant down-
time, impurity measurement becomes critical.
29
Low CO, CO2 in Natural Gas Analyzer 7890-0282
Configuration:
2-valve/2-column (packed column)/methanizer/FID
Sample type:
Natural gases, process gas containing high levels of methane
CO2, CO
0.1 ppm for CO2, CO
CO
CO2

• Single channel with packed columns
• High concentration of hydrocarbons are cut on the pre-column while CH4 is vented during the analysis
with 4-port valve
• Trace levels of CO and CO2 can be analyzed by conversion to CH4 and detection with FID
30
Low CO, CO2 in Process Gas Analyzer 7890-0304
Configuration:
1-valve/2-column (packed column)/methanizer/FID
Sample type:
PG ethylene, propylene, or process gases containing low concentrations of methane
CO2, CO
0.1 ppm for CO2, CO
pA
Methane
45
40
35
CO (4.6 ppm)
30
CO 2 (4.5 ppm)
25
20
15
0 2 4 6 8 min

• Hydrocarbons are cut on the pre-column while trace levels of CO and CO2 pass through to a methanizer to be
analyzed by conversion to CH4 and detection with FID
31
Trace CO and CO2 in Hydrogen and Light Gaseous
Hydrocarbons Analyzer 7890-0366
Configuration:
2-valve/2-column (packed column)FID/methanizer
Sample type:
H2/Light gaseous hydrocarbons
CO, CO2, and CH4
0.4 ppm for CO, CO2
UOP603

32
Trace Impurities in Helium Analyzer 7890-0219
Configuration:
1-valve/PDHID
H2, O2, N2, CH4, CO
Sample type:
Bulk helium
0.1 ppm
2.828 - Methane
Carbon monoxide
1.301 - Oxygen
0.825

• Single-valve, single-column system using PDHID in helium ionization mode allows determination of impurities
at 0.1 ppm level
• Use low-leakage GSV
• Universal in response means positive peaks for all components
• No need to change bias voltage to adjust peak polarity or sensitivity
• No dead volume inside the detector, quick recovery from bulk peaks
33
Impurities in Monomers Analyzer 7890-0237
Configuration:
1-valve/2-column (packed column)/PDHID
H2, O2 + N2 composite peak, CH4, CO, CO2
Sample type:
Monomers (gas)
10 ppm for H2, 1.5 ppm for O2 + N2 composite peak, 2 ppm for CO and CO2
2.745 - Carbon monoxide
pA
5.647 - Methane
1.994 - Nitrogen
9.137 - Carbon dioxide

2000
1900
1800
1700
1.832 - Oxygen
1600
0.627
5.131
1500
0 2 4 6 8 10

• Single-valve, dual-column system using PDHID in helium ionization mode allows determination of impurities
at ppm level
• Use a 10-port, low-leakage valve
• Matrix effects are eliminated by cutting out the light components on a packed pre-column
• Inerts including H2 + O2, N2, CO, CH4, and CO2 are separated on micro-packed column and detected at
ppm and higher
34
Impurities in C2H4/C3H6 Analyzer by PDHID 7890-0409
Configuration:
Valve/2-column (packed column)/PDHID
Sample type:
C2H4/C3H5
H2, O2, N2, CO, CH4
Quantification ranges:
H2: 0.1–40 ppm, N2, CO: 0.1–10 ppm

• Single-valve, dual-column system using PDHID in helium ionization mode allows determination of impurities
at 0.1 ppm level
• Use a 10-port, low-leakage valve
• Matrix effects are eliminated by cutting out the matrix on a packed pre-column
• Inerts including H2, O2, N2, CO, CH4, are separated on packed column and detected at 0.1 ppm and higher
35
Inert Impurities in Pure Chlorine Analyzer 7890-0191
(2-Channel)
Configuration:
3-valve/5-column (packed column)/2-TCD/Hastelloy valve, inlet tubing, sample filter, nickel stripper
Sample type:
Gas
H2, O2, N2, CH4, CO2, CO
50 ppm for fixed gases
25 µV TCD1 A.
1200
1000
Nitrogen
800
Carbon dioxide
600
400
200 Carbon monoxide

Oxygen
0
0 1 2 3 4 5 6 min
25 µV TCD1 B.
1200
1000 Hydrogen
800 Carbon dioxide
Nitrogen
600
400 Carbon
200 monoxide V2 ON
0
0 1 2 3 4 5 6 7 8 min

• Dual TCD channels with packed column system measures low levels of inert impurities in pure chlorine
• Chlorine is cut to the vent at the sampling
• Hastelloy valve, inlet tubing, sample filter, nickel stripper to avoid corrosion
• Full-range capability, including H2 by the use of second TCD with argon carrier gas
36
Inert Impurities in Crude Chlorine Analyzer 7890-0305
Configuration:
2-valve/3-column (packed column)/TCD/Hastelloy valve, inlet tubing, sample filter, nickel stripper
Sample type:
Gas
H2, O2, N2, CH4, CO2, CO
50 ppm for fixed gases except H2, 3 Vol% for H2 (for low concentrations of H2 use 7890-0191)
25 µV
1200
1000
Nitrogen
800
Carbon dioxide
600
400
200
Oxygen Carbon monoxide
0
0 1 2 3 4 5 6 min

• Single TCD channel with packed columns measures ppm levels of inert impurities (3% or higher for H2)
in crude, dry chlorine
• Chlorine is cut at the sampling and vented in the backflush
• Use Hastelloy valve, inlet tubing, sample filter, nickel stripper to avoid corrosion
37
Trace Oxygenates and Hydrocarbons in Ethylene
Analyzer 7890-0341
Configuration:
1-valve/2-column (capillary/PLOT)/VI (Volatile Inlet)/Deans switch/2-FID
Sample type:
Ethylene, propylene
C1-C5 hydrocarbons, methanol
2 ppm hydrocarbons, 10 ppm for methanol
Cut time: 2.3–4.3 min
pA
37.5 Primary column
35.0 HP-INNOWax
32.5 5 (methanol)
30.0
27.5
25.0
22.5
20.0
17.5
0 5 10 15 20 25 min
3 Secondary column
140 Alumina HP-PLOT M
4
120 2
C1 to C4 hydrocarbons separated on secondary column
100
7 8
80 6 11 12 13 14 15
1
60 9 16
10
40
20
0 5 10 15 20 25 min
Capillary Flow Technology Deans switch used to separate 100 ppm V

oxygenate and hydrocarbon impurities in ethylene.

• Use Deans switch to enhance ASTM D6159 method, which allows trace oxygenates and hydrocarbons in a
single run
- Primary column INNOWax separates oxygenates and prevents polar oxygenates (water, alcohols) from
damaging the sensitive stationary phase
- Deans switch selectively transfers only the hydrocarbons to alumina column
• 7890A PCM second channel can be used in back-pressure regulation mode to control sample pressure in loop to
improve the precision and sensitivity
• Dynamic blending system (7890-0130) can be used for providing easy calibration and assisting with method
development
• The system can be used for propylene sample
38
Transformer Oil Gas Analysis Solutions
Agilent’s transformer oil gas analyzers (TOGAs) use an Agilent TCD detector
and an FID with methanizer to analyze fixed gas impurities and light hydro-
carbon compounds in transformer oil. Our solutions include both traditional
packed-column and new capillary-based systems and comply with stan-
dard ASTM test methods.
39
Transformer Oil Gas Analyzer 7890-0047
Configuration:
2-valve/2-column/TCD/FID/methanizer
Sample type:
Gas
H2, O2, N2, CH4, CO, CO2, C2's (ethane, ethylene, acetylene), C3's (propane, propylene), C4 (1-butene)
Meets ASTM D3612A
ASTM D3612-A
Propane/Propylene
N2 1-Butene
Ethane
Ethylene Acetylene
CH 4 CO 2
H2 CO

• Agilent ChemStation macros program for data analysis supplied
40
Transformer Oil Gas Analyzer 7890-0261
Configuration:
1-valve/2-column/TCD/FID/methanizer/headspace
Sample type:
Gas
H2, O2, N2, CH4, CO, CO2, C2's (ethane, ethylene, acetylene), C3's (propane, propylene), C4 (1-butene)
Meet the specifications listed in table 3 in ASTM D3612-C
ASTM D3612-C
FID Channel
I-Butene
Acetylene
Ethylene
Ethane Propylene
Propane
CO 2 Methane CO
H2
TCD Channel
O2 N2

• Single channel with PLOT columns
• Use direct transfer line to column connection
• Improved precision through 7890 PCM back-pressure regulation of headspace gas sampling valve loop
41
Reformulated Fuels Analysis Solutions
Analyzers based on GC are the heart of any refinery laboratory. These types
of analyzers, whether they measure additives such as oxygenates or aro-
matic content for blending, provide critical information for the effective pro-
duction of reformulated gasoline. Many of these analyzers comply with
international and regional analytical methods, such as ISO, ASTM, and EN.
Agilent Technologies has been instrumental in the development of most of
these methods and continues to innovate and create new solutions tailored
to meet the diverse needs of this market segment.
42
Oxygenates in Fuel Analyzer 7890-0049
Configuration:
1-valve/2-column (micro-packed and capillary)/FID/TCD
Sample type:
Finished gasoline
MTBE, ETBE, TAME, DIPE, ethanol, iso-propanol, n-propanol, iso-butanol, tert-butanol, sec-butanol, n-butanol,
tert-pentanol
Concentration range:
0.1 to 20 Wt% for individual ethers, 0.1 to 12 Wt% for individual alcohols
ASTM D4815
1 Methanol 13
2 Ethanol 14
3 Isopropanol
4 tert-Butanol
5 n-Propanol 3
6 MTBE 5
7 sec-Butanol
8 DIPE 11
9 Isobutanol 1
10 tert-pentanol
11 DME 10
9
12 n-Butanol 7
8
13 TAME
14 Heavier 2 4 6 12
hydrocarbon
0 2 4 6 8 10 12 14 16

• Analyzer has the capability to determine ether and alcohol additives in gasoline
• Improved TCEP column and mounting hardware greatly improve method stability
43
Oxygenates and Aromatics in Fuel:
Single-Channel Analyzer 7890-0183
Configuration:
1-valve/2-column (micro-packed and capillary)/FID/TCD
Sample type:
Finished gasoline
ASTM D4815: MTBE, ETBE, TAME, DIPE, ethanol, isopropanol, n-propanol, isobutanol, tert-butanol,
sec-butanol, n-butanol, tert-pentanol. ASTM D5580: benzene, toluene, ethylbenzene, xylene, C9 and heavier
aromatics, total aromatics
0.1 to 5 Vol% for benzene, 1 to 15 Vol% for toluene
0.5 to 10 Vol% for individual C8 aromatics, 5 to 30 Vol% for total C9 and heavier aromatics,10 to 80 Vol%
for total aromatics
1
1 Benzene 4
2 Toluene 2
1 Methanol 3 2-hexanone 3
13 2 Ethanol 4 Backflush
14
3 Isopropanol peaks
4 tert-Butanol
3 5 n-Propanol
6 MTBE
5 7 sec-Butanol ASTM D5580 - 1st run
8 DIPE
11 9 Isobutanol 3
1 4
10 tert-Pentanol
10 11 DME 1 2-hexanone
9 12 n-Butanol 2
7 2 Ethylbenzene 1
13 TAME 5
8 3 m/p-xylene
2 4 14 Heavier 4 o-xylene
6 12
hydrocarbon 5 C 9 + aromatics
ASTM D4815 ASTM D5580 - 2nd run

• Same GC system including the column is designed for both ASTM D4815 and D5580 methods
• Analyzer has the capability to determine oxygenates (ASTM D4815) and aromatics (ASTM D5580) in gasoline
by using either helium or nitrogen (which is lower cost) carrier gas
44
Oxygenates and Aromatics in Fuel:
Dual Parallel Channels Analyzer 7890-0291
Configuration:
2-valve/4-column (micro-packed and capillary)/2-FID
Sample type:
Finished gasoline
ASTM D4815: MTBE, ETBE,TAME, DIPE, ethanol, isopropanol, n-propanol, isobutanol, tert-butanol,
aromatics, total aromatics
0.5 to 10 Vol% for individual C8 aromatics, 5 to 30 Vol% for total C9 and heavier aromatics,10 to 80 Vol%
for total aromatics
1
1 Benzene 4
2 Toluene 2
13 2 Ethanol 4 Backflush
14
3 Isopropanol peaks
4 tert-Butanol
3 5 n-Propanol
6 MTBE
5 7 sec-Butanol ASTM D5580 - 1st run
8 DIPE
11 9 Isobutanol 3
1 4
10 tert-Pentanol
10 11 DME 1 2-hexanone
9 12 n-Butanol 2
7 2 Ethylbenzene 1
13 TAME 5
8 3 m/p-xylene
2 4 14 Heavier 4 o-xylene
6 12

• Dual parallel channels are configured on one GC system, one is for ASTM D4815 and the other for ASTM D5580
• Analyzer has the capability to determine oxygenates (ASTM D4815) and aromatics (ASTM D5580) in gasoline
45
Aromatics in Fuel Analyzer 7890-0106
Configuration:
1-valve/2-column (micro-packed and capillary)/2-FID (or FID/TCD)
Sample type:
Finished gasoline
Benzene, toluene, ethyl benzene, xylene, C9 and heavier aromatics, total aromatics
0.5 to 10 Vol% for individual C8 aromatics
5 to 30 Vol% for total C9 and heavier aromatics
10 to 80 Vol% for total aromatics
ASTM D5580
1
4
1 Benzene 2
2 Toluene 3 ASTM D5580 - 1st run
3 2-hexanone
4 Backflush
peaks
3
ASTM D5580 - 2nd run
1 2-hexanone
4
2 Ethylbenzene 2
3 m/p-xylene 1 5
4 o-xylene
5 C 9 + aromatics

• Dual-column system is used to determine benzene, toluene, ethyl benzene, and xylene in finished gasoline
• Improved TCEP column and mounting greatly improve method stability
46
Benzene in Gasoline Analyzer 7890-0198
Configuration:
1-valve/2-column/TCD or FID
Sample type:
Finished motor and aviation gasoline
Benzene, toluene
0.1 to 5 Vol% for benzene
2 to 20 Vol% for toluene
ASTM D3606
1 Nonaromatics
2 Benzene
1 3 MEK (internal standards)
4 Toluene
4
3

• Single channel with dual packed-column system is used to determine benzene and toluene in finished motor and
aviation gasoline
• Independently heated valve system prevents heavy components in the sample from condensing
47
Oxygenates, Aromatics, and Benzene in Fuel Analyzer
7890-0308
Configuration:
3-valve/5-column/FID/TCD
Sample type:
Finished motor and aviation gasoline
ASTM D4815: MTBE, ETBE, TAME, DIPE, ethanol, isopropanol, n-propanol, isobutanol, tert-butanol,
aromatics, total aromatics. ASTM D3606: benzene, toluene
0.1 to 20 Wt% for individual ethers, 0.1 to 12% Wt% for individual alcohols
0.1 to 5 Vol% for benzene, 1 to 15 Vol% for toluene, 0.5 to 10 Vol% for individual C8 aromatics, 5 to 30 Vol%
for total C9 and heavier aromatics, 10 to 80 Vol% for total aromatics, 0.1 to 5 Vol% for benzene, 2 to 20 Vol%
for toluene
ASTM D4815, ASTM D5580, and ASTM D3606
1
1 Benzene 4
2 Toluene 2
13 4 Backflush
2 Ethanol 14
3 Isopropanol peaks
4 tert-Butanol
3 5 n-Propanol
6 MTBE
5
7 sec-Butanol ASTM D5580 - 1st run
8 DIPE
11 3
1 9 Isobutanol 4
10 tert-Pentanol
10 11 DME 1 2-hexanone 2
7
9 12 n-Butanol 2 Ethylbenzene 1
8 13 TAME 5
3 m/p-xylene
2 4 6 14 Heavier 4 o-xylene
12
1 Nonaromatics 4
2 Benzene 3
3 m/p-xylene
2
4 Toluene
ASTM D3606

• Dual-channel system combining 7890-0198 and 7890-0291 on one GC, meets ASTM D4815,
• 10-port valve is used for column selection for ASTM D5580 and D3606
48
Oxygenates and Aromatics in Gasoline by
Deans-Switch Analyzer 7890-0098
Configuration:
Deans-switching/2-column/2-FID
Sample type:
Commercial or raw gasoline
Benzene, toluene, ethylbenzene, and oxygenates: MTBE, ETBE, TAME, DIPE, ethanol, isopropanol,
n-propanol, isobutanol, tert-butanol, sec-butanol, n-butanol, tert-pentanol
0.05 to 6 Vol% for benzene, 0.17 to 15 Vol% for individual organic oxygenates
EN13132/EN12177
TCEP Column (FID A)
4 6 8 10 12 14 16 18 20 min
MTBE 11.01 wt% found

DB-1 Column (FID B)
DME (int. std)
4 6 8 10 12 14 16 18 20 min
TCEP Column (FID A)
4 6 8 10 12 14 16 18 20 22 min
DB-1 Column (FID B)
2 5
Ref (wt%) Found (wt%)
1 Benzene 1.18 1.21
2 Toluene 11.62 11.85 4
3 Ethylbenzene 4.65 4.70
3
4 2-Hexanone(IS) 10.87 na
5 o-Xylene 4.71 4.78 1
4 6 8 10 12 14 16 18 20 22 min

• Analyzer determines the oxygenates (EN13132) and benzene (EN12177) in gasolines
• Capillary Flow Technology Deans switch provides easier method setup and reliable performance by eliminating
carry-over and minimizing peak tailing for very polar compounds. Backflush is used to save time
49
Low-Level Oxygenates in Light Hydrocarbons by
Deans-Switch Analyzer 7890-0178
Configuration:
Capillary Flow Technology micro volume tee/2-column/FID/Auto-sampler(for liquid samples), gas sampling
valve (for gas samples), LSV ( for liquefied gases)
Sample type:
Ethene, propene, hydrocarbon matrices that do not have a final boiling point greater than 200 °C
MTBE, ETBE, DIPE, TAME, methanol, n-propanol, i-propanol, n-butanol, i-butanol, tert-butyl alcohol,
sec-butyl alcohol, tert-pentanol
0.5 ppm for MTBE
ASTM D7423

• Analyzer has the capability to determine low level of oxygenates in any hydrocarbon matrix where the final
boiling point is below 200 °C
• Capillary Flow Technology fluidic switch with backflush is used to remove higher hydrocarbons
• Agilent GS-OxyPLOT column separates light hydrocarbons from oxygenates. GS-OxyPLOT is surprisingly inert to
polar compounds and is an excellent column for quantitative analysis of oxygenates at low concentrations.
50
Trace Oxygenates in Reformulated Gasoline Analyzer
7890-0340
Configuration:
1-valve/2-column/FID
Sample type:
Reformulated gasoline, ethanol/gasoline blends, naphtha
MTBE, ETBE, DIPE, TAME, methanol, n-propanol, i-propanol, n-butanol, i-butanol, tert-butyl alcohol,
sec-butyl alcohol, tert-pentanol
10 to 1,000 ppm (wt/wt) for oxygenates
1 to 15 Vol% for ethanol
New proposed ASTM method for trace oxygenates in reformulated gasoline
Light hydrocarbons Ethanol
Ethers C3 to C5 Alcohols
Methanol
MTBE
TAME
ETBE DIPE i,n-Pentanol
t,s,i-Butanol 1,2-DME(IS)
t-Pentanol
n-Butanol
MeOH

• Analyzer has the capability to analyze oxygenates (at the 10 to 1,000 ppm level) in gasoline containing
1 to 15 Wt% ethanol additive
• Excellent separation of oxygenates from light hydrocarbons
• Resolves all ethers (ETBE, MTBE, DIPE, and TAME)
• High quantitative precision for both high and low concentrations in the presence of ethanol at levels of
1 to 15 Wt%
51
Sulfur Analysis Solutions
Sulfur compounds are ubiquitous in refining and petrochemical products.

This is a consequence of their occurrence in crude oil and natural gas.
Sulfur compounds create processing problems for refiners, natural gas
companies, and petrochemical plants and have a negative impact on prod-
uct quality. Sulfur compounds are often small, polar, and reactive. In some
cases, such as hydrogen sulfide, they are highly toxic as well. They may
cause corrosion and embrittlement and can permanently poison expensive
catalysts. Due to these reasons, as well as the environmental damage they
may cause when burned, most regulatory bodies such as the EPA have
passed laws to limit their presence in hydrocarbon products. Agilent Tech-
nologies offers a complete portfolio for trace sulfur analysis. An Agilent
7890A can be equipped with our enhanced FPDs or highly sensitive and
selective SCDs to analyze trace-level sulfur compounds in a wide range of
matrices.
52
Volatile Sulfur Analyzer 7890-0148/7890-0167
Configuration:
3-valve/2-column/2-VI (volatile inlets)/2-FPD
Sample type:
C2, C3, C4 monomers (7890-0148), natural gas, fuel gas streams (7890-0167)
Volatile sulfur such as H2S, COS, MeSH, EtSH, DMS, CS2, t-BuSH, THT
50 ppb for sulfur compounds, 26 ppb in He for arsine
ASTM D6228
H 2S 45 ppb (v/v) each of the eight sulfur compounds in
natural gas, split ratio: 0.5:1
60 m × 0.53 mm × 5.0 µm DB-1
COS (lost in C 3 CS 2
interference) DMS
n-C 5 THT
CH 3 SH t-BuSH
EtSH
n-C 4
2 4 6 8 10 12 14 min
CS 2
30 m × 0.32 mm GS-GasPro
COS H 3 S (lost in C 3 CH 3 SH THT

interference) t-BuSH
2 4 6 8 10 12 14 16 18 min

• Dual-channel FPD system utilizing DB1 and GasPro column allows COS and H2S to be measured
simultaneously in propylene and other light hydrocarbon streams
• Same GC configuration for 7890-167 (natural gas, fuel gas streams) and 7890-0148
(for C2, C3, C4 monomers), which uses a longer column
• The system can be used for measuring S, P, and As
• Dynamic blending system (7890-0130) can be used for providing easy calibration and assists with method
development
• System passivation with SilcoSteel® and Sulfinert enhance sulfur analysis
• Excellent alternative to more expensive specialty detectors SCD, PFPD, MSD
53
Sulfur Analyzer by SCD 7890-0365
Configuration:
Capillary inlet/Capillary column / SCD, Automatic Liquid Sampler is required for liquid sample
Sample type:
Gasoline motor fuels, petroleum liquids with a final boiling point of approximately 230℃ or lower at
atmospheric pressure
Volatile sulfur-containing compounds in light petroleum liquids, such as CS2, COS, mercaptans, aromatic sulfur
compounds, sulfides
20 ppb of sulfur in gasoline
Linear range:
0.1 to 10 ppm
ASTM D 5623, UOP791
Chromatogram of gasoline standard sample
8/9
15 uV
1000
2 11
800
600
7 12 14
3
400 10
6 13
200 4 5
0
0 2 4 6 8 10 12 14 16 18 min
Components Formula
1 Ethyl mercaptan CH3CH3SH 8 Thiophene C4H4S
2 Dimethyl sulfide (CH3)2S 9 Sec-butyl mercaptan CH3CH2CH(SH)CH3
3 Carbondisulfide C2S 10 n-butyl mercaptan CH3(CH2)3SH
4 Isopropyl mercaptan (CH3)2CHSH 11 Dimethyl disulfide CH3SSCH3
5 T-buyyl mercaptan (CH3)3CSH 12 2-methyl thiophene C5H6S
6 n-propyl mercaptan CH3CH2SCH 13 3-methyl thiophene C5H6S
7 Methylethyl sulfide CH3CH2SCH3 14 Dimthyl disulfide (C2H5)2S2

• 7890GC with Sulfur Chemiluminescence Detector-SCD for sulfur analysis in gasoline and light petroleum liquids
(LPG)
ï High Selectivity–higher selectivity for sulfur over carbon
ï No Quenching–detector response not inhibited by hydrocarbons
ï Equimolar–simplifies quantification of unknowns
ï Linear– simplifies calibration
ï Sulfinert treated capillary inlet to enhance sulfur analysis
54
Sulfur Analyzer by SCD 7890-0375
Configuration:
1- valve Capillary column /SCD
Sample type:
Natural Gas, gaseous fuels
Sulfur compounds in Natural Gas or Gaseous fuels, such as H2S CS2, COS, mercaptans, aromatic sulfur
compounds, sulfides
100 ppb of H2S
ASTM D 5504
15 µV Chromatogram of sulfurs in natural gas
6
200 1 2
11/12
150
3
4 5 7 10 13 14
8 9 15
100
50
0
0 1 2 3 4 5 6 7 8
Components Formula 8 Tert-butyl mercaptan (CH3)3CSH

1 Hydrogen sulfide H2S 9 1-propanethiol CH3(CH2)2SH
2 Carbonyl sulfide COS 10 Thiophene C4H4S
3 Methyl mercaptan CH3SH 11 n-butanethiol CH3(CH2)3SH
4 Ethyl mercaptan CH3SH 12 Diethyl sulfide CH3CH2SCH2CH3
5 Dimethyl sulfide CH3SCH3 13 Methyl ethyl sulfide CH3SCH2CH3
6 Carbon disulfide CS2 14 2-methyl-1-propanethiol (CH3)2CHCH2SH
7 2-propanehiol CH3SHC2H5 15 1-methyl-1-propanethiol CH3CH2CHSHCH3

• 7890GC with Sulfur Chemiluminescence Detector-SCD for sulfur analysis in natural gas and gaseous fuels
ï High Selectivity– higher selectivity for sulfur over carbon
ï No Quenching–detector response not inhibited by hydrocarbons
ï Equimolar–simplifies quantification of unknowns
ï Linear–simplifies calibration
ï Sulfinert treated capillary inlet , valve plumbing to enhance sulfur analysis
55
Biodiesel Analysis Solutions
The recent run up in crude oil prices combined with disruptions in supply
and refining capacity have driven the prices of motor fuels to new highs
and created spot shortages throughout the world. This has given new
urgency to the development of locally produced, alternative, renewable
fuels. This effort offers the potential to reduce the reliance on crude oil as
well as to lower emissions of airborne pollutants and greenhouse gases.
Biodiesel is a motor or heating fuel produced from renewable vegetable

oils derived from crops such as sunflower, soybean, rapeseed, and palm.
As with petroleum diesel, biodiesel must undergo extensive chemical analy-
ses before it can be sold as a fuel. This presents new challenges to labora-
tories using gas chromatography to measure the properties and quality of
biodiesel and biodiesel blends. Agilent Technologies offers three complete
solutions for the most widely run industry-standard B100 methods, plus a
new two-dimensional GC solution for biodiesel blends.
56
Glycerin in Biodiesel Analyzer 7890-0294/7890-0297
Configuration:
on-column capillary inlet/FID
Sample type:
B100 biodiesel, not applicable to vegetable oil methyl esters obtained from lauric oils, such as coconut oil
and palm kernel oil
Free glycerin, monoglycerides, diglycerides, triglycerides, bound glycerin, total glycerin
0.005 to 0.05 Wt% for free glycerin, 0.05 to 0.5 Wt% for total glycerin
7890-0294 for ASTM D6584, 7890-0297 for EN14105
Rapeseed
Tricaprin (istd 2)
Butanetriol (istd 1)
Soybean
Tricaprin (istd 2)
Butanetriol (istd 1)

• Utilizes a COC inlet with a retention gap column in front of the analytical column, providing the following
advantages:
- Significantly improves peak shape for better accuracy and reproducibility
- Use of standard syringes instead of special narrow-bore syringes
• Uses Agilent “Ultimate Union” to connect retention gap/column
- Reliable, leak-free, high-temperature connection
• Exceeds ASTM and CEN specifications for calibration and precision
57
FAME Content in Biodiesel Analyzer 7890-0300
Configuration:
Split/splitless inlet/FID
Sample type:
B100 biodiesel, which contains methyl esters between C14-C24
Methyl esters between C14-C24
> 90 Wt% for esters, 1 to 15 Wt% for linolenic acid content
EN14103
C17:0
(int std) C18:1
C16:0
C18:2
C18:3
C18:0
C14:0 C20:1
C20:0 C22:0 C22:1
C24:0 C24:1

• Great precision with a very simple, easy-to-use method
• Esters are separated isothermally on wax-type column
• Internal standard (methyl heptadecanoate ) is used for quantification
• Analysis time is about 25 minutes
58
Methanol in Biodiesel Analyzer 7890-0295
Configuration:
Headspace/FID
Sample type:
B100 biodiesel
Methanol
0.01 to 0.5 Wt% for methanol
EN14110
1.156
pA FID1 A. (OCT 8\013F1301.D)
600
DB-ALC1 30 m × 0.32 mm × 1.80 µm
500
400
300
200
100
0
0 1 2
pA
700 FID2 B. (OCT 8\013F1301.D) 1.204
600
500
400
300
200
100
0
0 1 2

• Uses Agilent G1888 headspace sampler, automated sample preparation
• Precision through back-pressure regulation of headspace gas sampling valve loop
• Increased sensitivity for low-concentration methanol through pressurization of the headspace sample loop
• Quantitative analysis uses external calibration, no internal standard to add
• J&W DB-ALC columns are optimized for alcohol analysis by headspace GC
• Improved peak shape for easy quantification
59
FAME Content in Biodiesel Blends Analyzer 7890-0307
Configuration:
Deans switch/FID
Sample type:
B1 to B25 biodiesel blends
Methyl esters between C14-C24
1 to 20 Wt% for esters
Primary Column: HP-1 Cut times (minutes) for FAMES
C14 8.20 _ 8.35
C16 9.65 _10.00
C18 11.20 _12.90
C20 14.90 _16.20
C22 18.30 _19.50
C23 22.50 _24.00
C24 27.20 _34.00
C18:1
C18:2
C16:0
C21:0 (int std)
Secondary Column: INNOWax

C18:3
C18:0
C20:0
C20:1
Total FAME content found

20.8 vol %
0 5 10 15 20 25 30 Min

• Innovative method of analysis for biodiesel content in blended fuel
- Avoids complicated sample preparation using EN14331
- Minimizes consumable costs: silica columns, solvents
- Leverages Agilent’s lock-out capillary flow technologies Dean switch technique
60
Five in One Biodiesel Analyzer 7890-0427
Configuration:
On-column capillary inlet/S/SL inlet/Auxiliary isothermal oven/Capillary column /2-FID. Head space sampler,
7693A ALS and 7693A tray are required for EN14110
Sample type:
B100 bio-diesel. (Not applicable to vegetable oil methyl esters obtained from lauric oils, such as coconut oil
and palm kernel oil for ASTM D 6584/EN14105)
EN14103: Methyl esters between C14-C24, ASTM D 6584, EN14105: Free glycerin, monoglycerides,
diglycerides, triglycerides, bound glycerin, total glycerin. EN14110: Methanol
EN14103: > 90 Wt% for esters, 1 to 15 Wt% for linolenic acid content. EN14105/ASTM D6584: 0.005 to
0.05 Wt % for free glycerin, 0.05 to 0.5 Wt% for total glycerin. EN14110: 0.01 to 0.5 Wt% for methanol
Published methods met: EN14103, ASTM D 6584, EN14105, EN14106, EN14110

ï New external capillary column oven for isothermal chromatography
ï Thermally isolated low temperature column from high temperatures in main column oven
ï New 7693 ALS automate complex standard and sample preparation
ï A single GC for complete analysis of biodiesel using 5 different methods:
EN14103, ASTM D 6584, EN14105, EN14106, EN14110
61
SIMDIS Analysis Solutions
Agilent (HP) was one of the first to develop SIMDIS – now an industry
standard – over 25 years ago. Today, our SIMDIS solutions have evolved
to include:
• A high-performance Multimode inlet
• Fast calculations, fast analyses, and easy-to-use software
• A complete solution for ASTM D2887, D7213 (extended D2887), and D6352
• Complete support and distribution by Agilent
62
ASTM methods Carbon number Sample range Boiling range Agilent solution
ASTM D3710 C15 Gasoline naphtha IBP–260 °C Channel partner
ASTM D2887 C44 Jet fuel diesel 55–538 °C G3440A Option 653
ASTM D7213 C60 Lube oil base stocks 100–615 °C 7890-0461
(D2887 extended)
ASTM D6352 C100 Lube oil base stock 174–700 °C 7890-0462
ASTM D5307 C44 Crude oil IBP–538 °C Channel partner
63
SIMDIS Analyzer (G3440A Option 653): Boiling Range
from 55 to 538 °C
Configuration:
Multimode inlet/FID/SIMDIS software
Sample type:
Jet fuel, diesel, petroleum fraction with boiling range from 55 to 538 °C
ASTM D2887
Norm
500
400
300
200
100
2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5 min

• Easy-to-use software
• Multiple report options offer a range of reports that can be customized to the lab requirements
• Cost effective
• 6-minute fast SIMDIS can be achieved by use of short, small-diameter capillary column, 5 m × 180 µm × 0.4 µm
64
SIMDIS Analyzer 7890-0461: Boiling Range from
100 to 615 °C
Configuration:
Multi mode inlet /FID/SIMDIS software
Sample type:
Lube oil, base stocks, petroleum distillate fractions having a boiling range from 100 to 615 °C
ASTM D7213 (D2887 extended)
Heavy vacuum gas oil simulated distillation analysis

• Multi-mode inlet
- No syringe-needle discrimination, minimal inlet discrimination
- Temperature range of –160 °C to 450 °C
- Solvent vent/matrix vent – decrease interference/maintenance
- Flexibility (hot/cold split/splitless, temperature programmed vaporization)
- Cold trapping in liner – improves chromatographic peak shape, resolution
• Easy-to-use software
• Multiple report options offer a range of reports that can be customized to the lab requirements
65
SIMDIS Analyzer 7890-0462 Boiling Range from
174 to 700 °C
Configuration:
Multi- mode inlet /FID/SIMDIS software
Sample type:
Lube oil, base stocks, petroleum distillate fractions having a boiling range from 174 to 700 °C
ASTM D6352
pA
500
400
300
200
100
0
5 10 15 20 25 min
80
84
88
92 94 96 98 100

• Complete solution for extend ASTM D2887 (D7213), and D6352 on one GC
• High-performance multi-mode inlet
• Columns designed and perfected for SIMDIS
• SIMDIS software partially integrated with ChemStation
• Multiple report options
66
Greenhouse Gases Analysis Solutions
Carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) are consid-
ered the main greenhouse gases in the Earth's atmosphere. These gases
trap heat in the atmosphere and affect the temperature of the Earth. Con-
tinuous measurement of these gases provides meaningful information to
track greenhouse gas emission trends and help in the fight against climate
change.
67
Greenhouse Gases Analyzer
SP1 7890-0468 SP1 7890-0467

Configuration Channel Single channel Two separated channels
Detector FID, uECD FID, uECD,TCD
Valve/Column 3-Valve/2-Column 4-Valve/4-Column
Methanizer Yes Yes
Allow the use of auto-sampling by a HSS Yes No
(optional, not standard )
Fast analysis No Yes
Quantification N2O( Lowest 30 ppb 30 ppb
ranges quantification limit)
CH4 0.2 ppm –20% 0.2 ppm –20%
CO2 0.4 ppm –0.2% by 0.4 ppm – 0.2% by FID-methanizer
FID-methanizer 20 ppm –20% by TCD
68
Greenhouse Gases Analyzer 7890-0468
Configuration:
3-valve/2-packed column/ECD /FID/Methanizer
Sample type:
Greenhouse gases, soil gases where the analytes of interest contain gases such as CH4, N O and CO2
2
CH4, N2O, CO2
30 ppb for N2O (Lowest quantification limit), 0.2 ppm –20% for CH4, 0.4 ppm –0.2% for CO2
Chromatogram for real sample (laboratory air)

• Analyzer provides simultaneous analysis of greenhouse gas with one injection
• The ECD’s high sensitivity ensures the detection of N2O at ppb level.
• An easy-to-use union based on Capillary Flow Technology is used to connect valves and µECD improving the
chromatographic performance including the peak shape
• The systems are easily expanded to include the determination of SF6
• Analyzer SP1 7890-0468 has single channel with a simpler valve configuration and It is possible to use a 6-port
valve instead of a 10-port to allow auto-sampling by a Headspace sample
69
Greenhouse Gases Analyzer 7890-0467
Configuration:
4-valve/4-packed column/ECD/TCD/FID/Methanizer
Sample type:
Greenhouse gases, soil gases where the analytes of interest contain gases such as CH4, N2O and CO2
CH4, N2O, CO2
30 ppb for N2O (Lowest quantification limit), 0.2 ppm –20% for CH4, 0.4 ppm –20% for CO2
Chromatogram for real sample (laboratory air)

• Analyzer provides simultaneous analysis of greenhouse gas with one injection
• The ECD’s high sensitivity ensures the detection of N2O at ppb level.
• An easy-to-use union based on Capillary Flow Technology is used to connect valves and µECD improving the
chromatographic performance including the peak shape
• The systems are easily expanded to include the determination of SF6
• Analyzer SP1 7890-0467 has 2 separate channels with three detectors achieve enen faster results. The esparate
channels inrease flexibility to make the valve switching time less critical and the method easier to set up. The use
of the third TCD, also allows measure a wide concentration range of CO2
70
Miscellaneous Analysis Solutions
In addition to turnkey analyzers, Agilent can also pre-configure your GC with

devices for sample blending, sample selection, deactivated plumbing, stream
selection valves with up to 16 ports and other valves and sample loops. These
valves are available with dead-ended, common, and individually vented return
paths for the unselected samples. Let Agilent provide an integrated sample
introduction system that fits your analytical requirements.
71
Prefractionator for Analysis of Light Ends of Crude Oil
Analyzer 7890-0496
Configuration:
Multi- mode inlet/ CFT Prefractionator /Capillary column/FID
Sample type:
Crude oil, other petroleum fractions where sample components elute (or in some cases never elute) after the
last compound of interest
Backflush start
Crude oils with prefractionation up to approximately C12

• Many petroleum materials contain high boilers that can never elute. Analysis time can also be an issue even for
compatible samples and columns because heavy material may require longer eluting from the column. By use of
prefractionator, the analysis of wide range petroleum material such as crude oils can be easily optimized, provid-
ing a high resolution time optimized separation for only the fraction required without damaging the column or
detector
• Backflush is carried out while analysis is occurring on the analytical column
• Midpoint pressure control allows the analytical column to run at the desired flow while the precolumn is back-
flushed during the run
• The use of an uncoated precolumn transfers the desired compounds at a low temperature. This has the added
benefit of faster backflushing of the heavier material
• The CFT purged union designed for leak-free connections, superior inertness, and lack of unswept volumes yields
chromatographic performance identical to single column systems
72
Gas Blender 7890-0084/7890-0130
Description
The Dynamic blending system uses the Agilent 7890A 3-Channel AUX EPC module to automate
precise preparation of multilevel gas phase calibration standards. The AUX EPC module delivers
variable diluent gas flows to change the final concentration of the standard. Different gas dilu-
ents can also be used to observe matrix effects. This is very useful when measuring trace levels
of active compounds that would not be stable in preprepared mixtures.
A very low concentration gas standard (CL) can be generated by diluting a higher concentration
standard (CH) with another diluent gas (D). The final concentration (CL) is proportional to the
ratio of gas flows (FH, FD) shown by the equation in the following blending scheme.
Dynamic Blending Scheme

C L = C H x (F H/[F H + F D])
Flow restrictor
FH
CL
Standard
High-concentration FD
gas standard To GSV
PG PG H
Blending tee
4
6
6
3-channel
AUX EPC
Diluent Diluents

• Automatically prepare multilevel trace component calibration standards
• Ensure accurate calibration of active, unstable compounds
• Reduce cost of purchasing multiple premixed calibration gases in different matrices
• 7890-0130 is designed for GCMS systems
73
SP1 for Stream Selection Valve – Type SD
Description
Stream selection valves (SSVs) can be used for building unique integrated sample introduction
systems, offering an array of possibilities for sample introduction. SSVs can even be used for
on-line sample preparation. Different type of SSVs can be selected for different purposes.
SD valves select one of 4 to 16 dead-ended streams. The selected stream flows from the valve
outlet to a sample valve, pressure sensor, detector, column, etc. The same configuration may
also be used to direct one stream to a number of outlets for applications such as fraction
collection.
Typical Application
SD configuration (low pressure), for automated sampling of nonpressurized containers
List of SP1 Stream Selection Valve – SD

SP1 number Stream selection Type
7890-0244 10-stream selector SD
7890-0204 6-stream selector (Hastelloy) SD
Valve Drawing (Diagrams reproduced courtesy of Valco instruments)

3-port and
57
6-port valves 4-position SD valve
Containers 56 58
Vacuum Inlet/
pump Vent In-line outlet
filters
55 51
To column/
detector
Carrier 54 52
53
74
SP1 for Stream Selection Valve – Type SC
Description
SSVs can be used for building unique integrated sample introduction systems, offering an array
of possibilities for sample introduction. SSVs can even be used for online sample preparation.
Different types of SSVs can be selected for different purposes.
SC valves select one of 4 to 16. The selected stream flows from the outlet to a sample valve,
pressure sensor, detector, column, etc. SC valves are similar to the SD configuration in that
regard, but instead of being dead-ended as in the SD valves, the nonselected streams flow to a
common outlet so that flow of all streams is constantly flowing.
Typical Application
SC configuration (low pressure) for automated sampling of nonpressurized containers
List of SP1 Stream Selection Valve – SC

7890-0326 6-stream selector SC

6-port valves 4-position SC valve 57
Vacuum pump Sample inlets 56

Common 58
outlet
Selected
Vacuum In-line stream
regulator filters output
Common
vacuum 55
51
To column/
detector
54
Carrier 52
53
75
SP1 for Stream Selection Valve – Type SF
Description
SF valves select one of 4 to 16 streams, which are similar to SD and SC valves, selecting a
stream and sending it to the outlet. However, SFs allow the nonselected streams to flow
through individual outlets instead of a common outlet.
Typical Application
SF configuration (low pressure) is the ideal solution when reactions or process streams with
differing upstream pressures must be analyzed. SF valve configuration can also provide
independent containment of toxic or noxious streams.
List of SP1 Stream Selection Valve – SF

7890-0287 10-stream selector SF

S7
6-port valve 4-position SF valve
S6 S8
Vent
In-line Selected
filter stream
outlet
Loop
Vent S5 S1
To column/
detector
Carrier
S4 S2
S3
76
SP1 for Stream Selection Valve – Type ST
Description
ST valves are used for multicolumn, multisample, or multitrap operations, and are available for
use with 4 to 16 loops or positions.
Typical Application
ST configuration – low pressure. A typical application is the collection of fractions at timed
intervals for analysis at a later time.
List of SP1 Stream Selection Valve – ST

7890-0301 16-stream selector (Hastelloy) ST
7890-0299 16-stream selector ST

6-port valve 4-position ST valve S7
Process stream Loop 1
S6 S8
Inlet
In-line Outlet
filter Vent
Loop 4 Loop 2
S5 S1
Carrier
To column S4 S2
Loop 3
S3
77
SP1 for Stream Selection Valve – Type STF
Description
The STF valve is a variation of the ST flow path, with the single difference that the nonselected
streams are returned to their own vents or sources rather than being dead-ended or trapped, as
they are in the standard ST configuration.
Typical Application
STF configuration (low pressure) is ideal for reactor processes in which removal of substantial
amounts of sample would upset the equilibrium within the reactor, or if the stream is toxic or
noxious and must be isolated.
List of SP1 Stream Selection Valve – STF

7890-0076 6-stream selector STF
7890-0075 10-steam selector STF

6-port valve 4-position ST valve S7
S6 S8
Vent
Inlet
Outlet
Loop
Vent
To column/ S5 S1
detector Vent
In-line
Carrier filter
Vent
S4 S2
S3
78
Special Passivation with Sulfinert®
Description
Special passivation with Sulfinert® is provided to enhance trace levels of sulfur analysis. It is
developed specifically to sample or transfer organo-sulfur compounds at concentrations of less
than 20 ppb.
SP1s with Sulfinert-Treated System
7890-0082 Supply Sulfinert® lines and sample loop
Supply sample inlet lines and connection to one valve and inlet in Sulfinert® tubing.
7890-0103 Supply Sulfinert® treated capillary inlet system
Supply a Sulfinert® treated Capillary inlet system
7890-0239 Supply option 702/732 in Sulfinert®
Supply a valve option 702 or 732 with Sulfinert® fittings for packed columns and a
Sulfinert® treated needle valve.
7890-0240 Supply other valve options in Sulfinert®
Supply a 6-port valve option other than option 701/731 and 702/732 and all 10-port
valve options with Sulfinert® fittings for packed columns.
7890-0243 Supply LSV with Sulfinert® tubing
Supply an LSV option with Sulfinert inlet and outlet lines and connection to a valve
or volatiles inlet.
7890-0313 Valco 1/16 Zero Dead Volume Sulfinert tee mounted in oven
Supply 1/16 VALCO Zero Dead Volume Tee, Sulfinert treated for merging two streams
into one. The Tee will be mounted inside the GC oven
7890-0382 Supply inert option #873 (Siltek treated)
Supply 1 inert option #873 (Siltek treated). If customer requires extra columns then
please order multiples of this SP1.
Customer can order spare part from Agilent with p/n G1580-60060
For inert option #872, please order SP1 7890-0381;
For inert adjustable need valve, please order SP1 7890-0406;
For inert interface of valve to 1/8" packed column, please order SP1 7890-0407;
7890-0381 Supply inert option #872 (Siltek treated)
Supply 1 inert option #872(Siltek treated). If customer requires extra adaptors then
please order multiples of this SP1.
Customer can order spare part from Agilent with p/n G1580-60062
For inert interface of valve to 1/8" packed column, please order SP1 7890-0407;
7890-0407 Supply inert interface of valve to 1/8” packed column (Siltek treated)
Supply 1 inert interface of valve to 1/8" packed column (Siltek treated). If customer
requires extra columns then please order multiples of this SP1.
7890-0406 Supply inert adjustable needle valve (Siltek treated option #870)
Supply 1 inert adjustable needle valve (Siltek treated option #870). If customer requires
extra columns then please order multiples of this SP1.
For inert interface of valve to 1/8" packed column, please order SP1 7890-0407
79
Solutions from Agilent’s Channel Partners
At Agilent, our resources are not limited to our own. Our industry leadership has enabled us to
nurture valuable partnerships that complement our hydrocarbon processing analysis capabilities.
Following are examples of solutions provided by selected channel partners.
• Refinery gas analyzers /fast RGA (UOP 539)
- Hi-Speed RGA (ASTM D2163 /ISO 7941/DIN 51666)
- Micro GC
- Sulfur in LPG
• Natural gas analyzers
• Petrochemical analyzers
- Trace sulfur in ethylene and propylene
• PIONA/Reformulyzer M3
• Olefins analyzer
• DHA analyzer
• Oxygenates analyzer
• Aromatics analyzer
• 8634 analyzer for ASTM D86 equivalent for groups 3 and 4
• SIMDIS analyzer/HT SIMDIS analyzer
• DHA front end
• Apply lab GC on line
• HPLC-based solutions
80
81
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performance

Global Hydrocarbon Processing

Natural Gas Analysis Solutions

Refinery Gas Analyzer

Trace Impurities Analysis Solutions

7890-0191 Inert Impurities in Pure Chlorine Analyzer 36

Transformer Oil Gas Analyzer

Reformulated Fuels Analyzer

Greenhouse Gases Analyzer

The process of collecting, processing, transmitting, and distributing natural

The following solutions cover hydrocarbons from C1 to C5, C6 + as backflush,

Analyzer Description (7890-0042)

3000 H2S area

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2-3-Diamethylbutane and methylpentane

2-Methylpentane and cyclopentane

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Typical Chromatogram N-Butane

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200 FID channel

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The refinery gas analysis solutions cover hydrocarbons from C1 to C5, C6 +

2nd TCD channel

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H2 1. C 6+ 8. Isobutane 15. C-2-butane 22. 1-pentene

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1. C 6+ 8. Isobutane 15. C-2-butane 22. 1-pentene

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Nitrogen Front TCD

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Analyzer Description (7890-0107)

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Producers of high-purity monomers such as ethylene and propylene face

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9.137 - Carbon dioxide

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200 Carbon monoxide

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Capillary Flow Technology Deans switch used to separate 100 ppm V

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ASTM D4815 ASTM D5580 - 2nd run

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ASTM D4815 ASTM D5580 - 2nd run

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