Академический Документы
Профессиональный Документы
Культура Документы
Brilliant
STUDY CENTRE REPEATERS NEET MODEL EXAM - UNIT III B B1
Puliyannoor P.O., PALA TEST ID
Time: 3 hrs.
Physics + Chemistry + Biology
441
Ph - 04822 206100, 206800
www.brilliantpala.org Max. Mark: 720
1 1 1 3) 4.5 cm 4) 5 cm
3) 2d 4) 2d
n1 n 2 n1n 2 15. A convex lens of focal length ‘f’ is
place d some where in betwe en an
11. A beam of light is converging towards object and a screen. The distance
a point I on a screen. A plane glass between the object and the screen is
plate whose thickness in the direction x. If the numerical value of
of the beam = t, refractive index = n, magnification produced by the lens is
is introduced in the path of the beam. m, then the focal length of the lens is
The covergence point is shifted by
1 mx mx
1) t 1 away from glass plate 1)
m 1
2 2)
m 1
2
n
1
m 1 m 1
2 2
2) t 1 away from glass plate 3) x 4) x
n
m m
1 16. The minimum distance between an
3) t 1 nearer to the glass plate object and its real image formed by a
n
convex lens of focal length f is
1 1) 1.5 f 2) 2 f
4) t 1 nearer to the glass plate
n
3) 6 f 4) 4 f
12. Light takes 8 min 20 seconds to reach
from sun on earth, if the whole space 17. A combination of two thin lenses with
is filled with water, the light will take focal lengths f 1 and f 2 respectively
the time forms an image of distant object at
distance 60 cm when lenses are in
1) 8 min 20 sec 2) 8 min contact. The position of this image
3) 6 min 11 sec 4) 11 min 6 sec shifts by 30 cm towards the
combination when two lenses are
13. A transparent cube of 15cm edge
separated by 10 cm. The corresponding
contains a small air bubble. Its
values of f1 & f2
apparent depth when viewed through
one face is 6cm and when viewed 1) 30 cm, -60 cm
through the opposite face is 4cm. Then
the refractive index of the material of 2) 20 cm, -30 cm
the cube is
3) 15 cm, -20 cm
1) 2 2) 2.5
4) 12 cm, -15 cm
3) 1.6 4) 1.5
FT20P/TP/MOD/NEET/PCB/[B1] 3 Brilliant STUDY CENTRE
18. A convex lens of focal length 12cm is 22. A parallel beam of monochromatic light
is incide nt at one surface of an
3
made of glass of n . What will be equilateral prism. Angle of incidence
2 is 55o and angle of emergence is 46o.
its focal length when immersed in a The angle of minimum deviation will
5 be
liquid of n
4 1) less than 41o 2) equal to 41o
1) 6 cm 2) 12 cm 3) more than 41o 4) none of the above
3) 24 cm 4) 30 cm 23. The light ray is incident at an angle
60o on a prism of angle 45o. When the
19. A point object is moving on the light ray falls on the other surface at
principal axis of a concave mirror of 90 o , the re fractive inde x of the
focal length 24 cm towards the mirror. material of prism and angle of
When it is at a distance of 60 cm from deviation respectively are
the mirror, its velocity is 9 cm/s. What
is the velocity of the image at that 1) 2 and 30o 2) 1.5 and 15o
instant
1) 5 cm/s towards the mirror 3 3
3) and 30o 4) and 15o
2) 4 cm/s towards the mirror 2 2
3) 4 cm/s away from the mirror 24. The separation between the two lenses
4) 9 cm/s away from the mirror of the compound microscope is 14 cm.
The magnifying power for relaxed eye
20. A prism (n = 1.5) has the refracting is 25. If the focal length of the eye lens
angle of 30 o . The deviation of a is 5 cm, then the object distance for
monochromatic ray incident normally objective lens will be
on its one surface will be (sin 48o 36’ =
0.75) 1) 1.8 cm 2) 1.5 cm
3) 2.1 cm 4) 2.4 cm
1) 18o 36
25. The magnifying power of a simple
2) 20 30o microscope can be increased, if we
used eye-piece of
3) 18o 1) higher focal length
4) 22o 1 2) smaller focal length
4 4 275 325
3) 4) 3) cm 4) cm
3 1 6 6
FT20P/TP/MOD/NEET/PCB/[B1] 4 Brilliant STUDY CENTRE
27. What focal length should the reading 33. Unpolarised light of intensity 32 w/
spectacles have for a person for whom m 2 passes through three polarisers
the least distance of distinct vision is such that transmission axes of the first
75 cm and second polariser makes an angle
1) 25 cm 2) 22.5 cm 30 o with e ach other and the
transmission axis of the last polariser
3) 37.5 cm 4) 40 cm is crossed with that of the first. The
28. The far point of a myopic person is 2m intensity of final emerging light will
in front of the eye. What is the power be
of the lens required to enable him to 1) 32 w/m2 2) 3 w/m2
see very distant objects clearly.
3) 8 w/m2 4) 4 w/m2
1) -0.5 D 2) +0.5 D
3) +2 D 4) -2 D 34. In the spectrum of light of a luminous
heavenly body the wavelength of a
29. A telescope of diameter 2m uses light spectral line is measure d to be
o
of wavelength 5000 A for viewing stars. o
4747 A . While actual wavelength of the
The minimum angular separation o
between two stars whose image is just line is 4700 A . The relative velocity of
resolved by this telescope is the body with respect to earth will be
1) 4 × 10-4 rad 2) 0.25 × 10-6 rad 1) 3 × 10 5 m/s moving towards the
3) 0.31 × 10-6 rad 4) 5 × 10-3 rad earth
30. The ratio of intensities of two waves is 2) 3 × 105 m/s moving away from the
9:1. They are producing interference. earth
The ratio of maximum and minimum
3) 3 × 10 6 m/s moving towards the
intensities will be
earth
1) 10:8 2) 9:1
4) 3 × 106 m/s moving away from the
3) 4:1 4) 2:1 earth
31. If two waves represented by y1 4sin t 35. A slit of width a is illuminated by white
o
and y 2 3sin t i nterfere at a light. For red light 6500 A the
3
point, the amplitude of the resulting first minima is obtained at 30o .
wave will be about Then the value of a will be
1) 7 2) 6
o
3) 5 4) 3.5 1) 3250 A 2) 6.5 × 10-9 mm
2) 31 2 2
1) 2 2)
3
3) 1 3.5 2
3) 4)
3
4) 0.3 1 3 2
42. In YDSE, the slit separation is made 3
38. In two separate set-ups of YDSE, fold. The fringe width becomes
fringes of equal widths are observed
when lights of wavelengths in the ratio 1 1
1:2 are used. If the ratio of the slit 1) times 2) times
3 9
separation in the two cases is 2:1, the
ratio of distance between the plane of 3) 3 times 4) 9 times
slits and screen in the two set-ups is
43. The refractive index of glass is 1.5 for
1) 4:1 2) 1:1 light whose wavelength in vacuum is
o
3) 1:4 4) 2:1 6000 A . The wavelength of this light
when it passes through glass is
39. In YDSE using sodium light
o o
o
1) 4000 A 2) 6000 A
5898 A , 92 fringes are seen. If
o o
o 3) 9000 A 4) 15000 A
5461A is used, how many fringes
44. A convex lens of focal length 40 cm is
will be seen
in contact with a concave lens of focal
1) 62 2) 67 length 25 cm. The power of the
combination is
3) 85 4) 99
1) -1.5 D 2) +1.5 D
40. In YDSE, the distance between slits
3) +6.5 D 4) -6.67 D
is 0.28 mm and distance between slits
and screen is 1.4 m. Distance between 45. A point object is placed at a distance
central bright fringe and third bright of 30 cm from a convex mirror of focal
fringe is 0.9 cm. What is the length 30 cm. The image will form at
wavelength of used light
1) infinity
o o 2) focus
1) 5000 A 2) 6000 A
3) pole
o o
3) 7000 A 4) 9000 A 4) 15 cm behind the mirror
FT20P/TP/MOD/NEET/PCB/[B1] 6 Brilliant STUDY CENTRE
CHEMISTRY 50. Which one of the following statements
is not correct?
46. A metal has a fcc lattice. The edge
length of the unit cell is 404 pm. The 1) Catalyst does not initi ate any
density of the metal is 2.72 gcm3. The reaction
molar mass of the metal is : 2) The value of equilibrium constant is
changed in the presence of a catalyst
(NA Avogadro’s constant = 6.02 × 1023 mol– in the reaction at equilibrium
1)
3) Enzymes catalyse mainly bio -
1) 30 g mol–1 2) 27 g mol–1 chemical reactions
4) Coenzymes increase the catalytic
3) 20 g mol–1 4) 40 g mol–1
activity of enzyme
47. Iron exhibits bcc structure at room 51. Nucleophilic addition reaction will be
temperature. Abo ut 900 0 C, it most favoured in
transforms to fcc structure. The ratio 1) (CH3)2C=O
of density of iron at room temperature
to that at 9000C (assuming molar mass 2) CH3CH2CHO
and atomic radii of iron re mains 3) CH3CHO
constant with temperature) is :
O
3 4 3
1) 2) 4) CH3 CH2 CH2 C CH3
2 4 2
52. The product of the reaction shown
3 3 1 below is
3) 4)
4 2 2
COOH
48. The addition of a catalyst during a
chemical reaction alters which of the
following quantities?
NaOH,H2 O
1) Activation energy Cl
2) Entropy
CH2OH
3) Internal energy
COOH COOH
4) Enthalpy
49. Which o ne of the fo llowing
characteristics is associated with 1) 2)
adsorption? Cl Cl
1) G and S are negative but H is
COOH CH2ONa
positive
COOH
2) G is negative but H and S are COONa
positive
3) 4)
3) G, Hand S all are negative
Cl
OH
4) G and H are negative but S is CH2OH
CH2OH
positive
FT20P/TP/MOD/NEET/PCB/[B1] 7 Brilliant STUDY CENTRE
53. m-chlorobenzaldehyde on reaction 57. The coagulating power of electrolytes
with conc.KOH at room temperature having ions Na + , Al 3+ and Ba 2+ for
gives Arsenic Sulphide Sol increases in the
order
1) Potassium m-chlorobenzoate and
m-hydroxybenzaldehyde 1) Al3+ < Ba2+ < Na+
2) Na+ < Ba2+ < Al3+
2) m-Hydrobenzaldehyde and m-chloro
benzyl alcohol 3) Ba2+ < Na+ < Al3+
4) Al3+ < Na+ < Ba2+
3) m-chlorobenzyl alcohol and m-hydroxy
benzyl alcohol 58. The coagulation values in millimoles
per litre of the electrolytes used for
4) Potassium m-chlorobenzoate and the coagulation of As 2 S 3 are given
m-chorobenzyl alcohol below
54. What is the product formed when (I) NaCl = 52 , (II) BaCl 2 = 0.69, (III)
ketones reacts with ethylene glycol in MgSO4 = 0.22. The correct order of
the presence of dry HCl gas? their coagulating power is
1) III > I > II
1) Ethylene glycol ketal
2) I > II > III
2) Ethylene glycol hemiketal
3) II > I > III
3) Cyanohydrin 4) III > II > I
4) Oxalic acid 59. The formation of cyanohydrin from a
ketone is an example of
55. Which one is an example of gel
1) Electrophilic addition
1) Smoke 2) Nucleophilic substitution
CN
CH 3 CH 2 CO CH 3 G
95% H2 SO4
Heat
H
O
(i)CH3NH2
(ii )LiAlH4
... is 1) CH3 CH C COOH
(iii)H O
2
CH3
H
2) CH3 CH C CN
NCH3
1)
CH3
OH
OH
4) CH3 CH C CO NH2
ONHCH3
3) CH3
3) Na2SO4 4) NaCl
1) Benzaldehyde
66. Oxalic acid being heated upto 90 0 C
with conc.H2SO4 forms
2) Trichloro acetaldehyde
1) HCOOH + CO2
3) Dimethyl acetaldehyde 2) CO2 + H2O
3) CO2 + CO + H2O
4) Formaldehyde
4) HCOOH + CO
FT20P/TP/MOD/NEET/PCB/[B1] 9 Brilliant STUDY CENTRE
67. CH3COOH
LiAlH4
X
Cu
300 0 C
Y
dil. NaOH
Z. 70. A compound A C5H10Cl 2 o n
In the above reaction Z is : hydrolysis gives C5H10O which reacts
with NH2OH, forms iodoform but does
1) Aldol 2) Ketol
not give Fehling Test. ‘A’ is
3) Acetol 4) Butanol
Cl
68. The correct order of decreasing acid
1) CH3 C CH2 CH2 CH3
strength of trichloroacetic acid (A),
trifluoroacetic acid (B), acetic acid (C)
and formic acid (D) is : Cl
Cl
1) B > A > D > C
2) CH3CH2 C CH2CH3
2) B > D > C > A
Cl
Cl
69. The correct order of acidity for the
following compounds is Cl Cl
4) Colloidal Fe(OH)3
CH2Cl
CH3
74. Which one is an incorrect statement?
Cl
1) FeO0.98 has non-stoichiometric metal 1) 2)
deficiency defect
1) 127 pm O
O
2) 80 pm
O
3) 108 pm 3) 4)
4) 40 pm O
FT20P/TP/MOD/NEET/PCB/[B1] 11 Brilliant STUDY CENTRE
81. Identify the major products P, Q and R 82. Of the following, which is the product
in the following sequence of reactions : formed when cyclohexanone
undergoes aldol condensation followed
by heating?
1)
+ CH3CH2CH2Cl
anhydrous AlCl
P 3
O
(i)O2
(ii)H O /
Q R
3
2)
P Q R
OH
CH2CH2CH3 CHO
3)
1) , , CH3CH2 OH
O O
2) , , OH
CH(CH3)2 OH
1) Aromatic acid 2) Schiff’s base
3) Pentanal 4) 2-pentanone
FT20P/TP/MOD/NEET/PCB/[B1] 12 Brilliant STUDY CENTRE
85. Which one is most reactive towards 90. Sodium metal crystallizes as a body
nucleophilic addition reaction? centred cubic lattice with the cell edge
4.29 Å . What is the radius of sodium
CHO COCH3 atom
1) 2) 1) 1.857 × 10–8 cm
2) 2.371 × 10–7 cm
CHO CHO 3) 3.817 × 10–8 cm
4) 9.312 × 10–7 cm
3) 4) BIOLOGY
91. When two individuals, heterozygous for
CH3 NO2 the same genes, are bred together,
they produce :
86. Consider the following reaction : 1) Only dominant phenotypes, all of
them are with same genotypes
COCl
2) Only recessive phenotypes
H2
Pd,BaSO4
A. The product
3) Only dominant phenotypes of
different genotypes
A is
1) C6H5Cl 2) C6H5OH 4) both recessive and dominant
phenotypes. The latter being of two
3) C6H5COCH3 4) C6H5CHO genotypes
87. CH 3 CHO and C 6 H 5 CH 2 CHO can be 92. Genes A and B are ne ce ssary for
distinguished chemically by, normal hearing. A deaf man marries
1) Tollen’s reagent test a deaf woman and all their children
2) Fehling’s solution test have normal hearing. The genotype of
the parents are :
3) Benedict’s test
1) AA bb and AA bb
4) Iodoform test
88. f-centre is : 2) Aa bb and aa Bb
3) All females white eyed and males 4) change of amino acid in either or
red eyed chain of haemoglobin
4) All offspring white eyed 108. Extranuclear DNA (genes) are located
in :
103. Haemophilia is a X-linked disease. A
haemophilic male marries a normal 1) lysosomes and chloroplasts
woman, whose father is also a 2) Golgi complex and ribosomes
haemophilic. It is expected that :
3) Chloroplasts and mitochondria
1) half their childre n will be
4) ribosomes and mitochondria
haemophilic
109. The daughters born to haemophilic
2) all the children will be haemophilic father and normal mother could be :
3) one fourth of the children will be 1) normal 2) carrier
haemophilic
3) haemophilic 4) none of these
4) none of the children will be 110. In human be ings, polyge ne s are
haemophilic involved in the inheritance of :
104. A normal woman whose father was 1) skin colour
colourblind is married to a normal man.
The sons would be : 2) phenylketonuria
3) colourblindness
1) 75% colourblind
4) sickle cell anaemia
2) 50% colourblind
111. M onosomy and trisomy can be
3) all normal represented as :
4) all colourblind 1) 2n + 1, 2n + 3 2) 2n - 1, 2n - 2
105. HbA HbS is an example of : 3) 2n, 2n + 1 4) 2n - 1, 2n + 1
1) Incomplete dominance 112. Jumping genes are called :
130. Nobel Prize to A. Kornberg and S. 3) 3' GCU 5' 4) 3' GGG 5 '
Ochoa was given for : 135. Linear RNA can be synthesised without
the aid of another nucleic acid using :
1) artificial synthesis of DNA and RNA
1) Kornberg’s enzyme
2) theory of natural selection
2) Teminase
3) one gene-one enzyme theory 3) Ochoa enzyme
4) mutation theory 4) RNA primase
FT20P/TP/MOD/NEET/PCB/[B1] 18 Brilliant STUDY CENTRE
136. 3.3 × 10 9 bp are distributed in how 142. How many of the given enzymes are
many chromosomes in human cell : proteolytic?
1) 46 2) X and Y Trypsin, Chymotrypsin, Lipases,
Nucleases, Rennin, Pepsin, Maltase,
3) Only X 4) 23 Carboxy peptidase, Amylase
137. Which among the following is smallest 1) 4 2) 5
RNA :
3) 6 4) 3
1) Short lived RNA 2) Insoluble RNA
143. Read the following statements and
3) Soluble RNA 4) Codon RNA choose the incorrect one
138. How many cistron can be seen in one 1) The wall of alimentary canal from
gene? oesophagus to rectum possess 4 lay-
ers
1) 2 2) many
2) Muscularis is formed by smooth
3) 1 4) None muscles usually arranged into an in-
ner longitudinal and outer circular
139. Upon examination of nucleic acid of a
layer
sample cell, it was observed that codon
UGU code for alanine, glycine and 3) The opening of the stomach into the
protein. The property of codon reflects: duodenum is guarded by pyloric sphinc-
ter
1) Unambiguous 2) Ambiguous
4) The salivary glands are situated just
3) Degeneracy 4) Over-lapping outside the buccal cavity
140. Match column I with column II and 144. Match the following :
select the correct option :
Colunm I Column II Column I Column II
A) Parietal cells (i) Succus entericus
(Sex determination type) B) Goblet cells (ii) Enterokinase
(Examples)
C) Peptic cells (iii) Pepsinogen
A) ZO - ZZ i) Grass hopper D) Trypsinogen (iv) Mucus
E) Intestinal juice (v) HCl and intrinsic factor
B) XX - XY ii) Birds
C) ZW - ZZ iii) Butterflies 1) A - (v), B - (iv), C - (iii), D - (ii), E - (i)
2) cholesterol
3) phospholipids
4) bile salts
Column I Column II
1) Oxyntic cells A secretion with pH below 3
i) Between ileum and
A) Pyloric sphincter
Secretion of Langerhans that caecum
2) Alpha cells of islets
decreases blood sugar level ii) Between oesophagus
B) Sphincter of Oddi
and stomach
A digestive enzyme that hydrolysis
3) Kupffer cells iii) Between stomach and
nucleic acids C) Ileo-caecal valve
duodenum
A secretion that evaporates for iv) Hepato-pancreatic
4) Sebaceous glands D) Gastro-oesophageal sphincter
cooling duct
of reptiles
III. Ramapithecus was more ape - like
and Dryopithecus was more man-like C. Palaeocene iii) Raise of modern
PHYSICS
1. 2 Convergent
Real image O
I
virtual
2. 2 Incident ray and finally reflected ray are parallel to each other means, angle
of deviation = 180o.
= 90o
3. 3 Vio = vi - v0 = 6 - - 6 = 12m/s
1 v
4. 1 m
n u
u
v
n
1 1 1
f u u
n
5. 3 Convex mirror
f 50
6. 1 m = -2, m , 2 , u = -75 cm
f u 50 u
7. 4
8. 4 Convergence (power) is independent of medium for mirror.
9. 3 To see the container half filled from the top, water should be filled upto height
x so that bottom of the container should appear to be raised upto height 21 - x
Real depth, h = x
Apparent depth, h’ = 21 - x
h 4 x
n x = 12 cm
h 3 21 x
FT20P/TP/MOD/NEET/PCB/[B1] 2 Brilliant STUDY CENTRE
d1 d 2
10. 2 h
n1 n 2
11. 1
Vair t v 4
12. 4 n w ; t w a t a 500
Vwater t a vw 3
x 15 x
13. 4 n on solving x = 9
6 4
n = 1.5
1 3
14. 1 sin i C
n 4
4
3
iC r = 3cm
7
15. 1
16. 4
1 1 1
17. 2 ....(1)
60 f1 f 2
1 1 1 10
....(2)
30 f1 f 2 f1f 2
On solving f1 = 20 f2 = -30
1 1 1 f m n l 1 n m
18. 4 n 1 ;
f R1 R 2 fa n1 n m
Vi m V0
2
19. 3
FT20P/TP/MOD/NEET/PCB/[B1] 3 Brilliant STUDY CENTRE
90o 30o
20. 1 90o
o
e
30
1 sin 30o 1
; sin e n sin 30 1.5 0.75
o
n sin e 2
18o 36
9
1
Dw n1 1 8 1
21. 4 Da n 2 1 3 1 4
2
m , so m 41o
45o
o
60 90o
23. 4
e r2 0o ; A r1 r2
r1 A 45o
sin i sin 60 3
n
sin r1 sin 45 2
i e A 60 0 45
15o
FT20P/TP/MOD/NEET/PCB/[B1] 4 Brilliant STUDY CENTRE
24. 1 L v0 f e 14 v 0 5 v0 9
v0 D 9 25 9
m ; 25 u 1.8 cm
u 0 fe u0 5 ; 0 5
D
25. 2 m 1 ; smaller focal length
f
fe D
26. 4 L f0 u e f0 50 5 25 325 cm
fe D 5 25 6
1 1 1 1 1 1
27. 3 ; ; f = 37.5 cm
v u f 75 25 f
28. 1
1 1.22
29. 3
R.P. d
30. 3
31. 2 A 32 4 2 2 3 4 cos 60 6
32. 4 n = tan ip
1 1
n 3 ; c sin
n
2
I 3
I1 0 16 ; I 2 I1 cos 30 16 12
2
33. 2
2 2
2
1
I3 I 2 cos 60 12 3
2
2
V
34. 4
C
Since wavelength increases body moving away from earth.
6500 1010 6
35. 3 ; a 1.24 m
a
2 D
36. 3 1.4 mm
d
FT20P/TP/MOD/NEET/PCB/[B1] 5 Brilliant STUDY CENTRE
37. 3 Position of first minima = position of 3rd maxima
1 1D 2 3 1 2 D
3.5 2
d 2 d
D
38. 1
d
39. 4 n11 n 2 2
3D x 3d o
40. 2 x3 6000 A
d 3D
1
42. 1
d
a 6000 o
43. 1 m 4000A
n 1.5
1 1 1
44. 1 ; P 1
F f1 f 2 F
1 1 1
45. 4
f v u
v = +15 cm, behind the mirror.
CHEMISTRY
4r
47. 3 For bcc lattice : n = 2, a ; For fcc lattice : n = 4, a 2 2 r
3
nM
3
3
d 250 C NA a bcc 2 2 2 r 3 3
d9000 C nM 4 4r 4 2
3 3
NA a fcc
FT20P/TP/MOD/NEET/PCB/[B1] 6 Brilliant STUDY CENTRE
48. 1 Catalyst lowers the activation energy and thereby increases the rate of the
chemical reaction. It does not influence any other thermodynamic parameters,
i.e, H, G, S
51. 3 Aldehydes are more reactive than ketones due to +I effect of –CH3 group. There
are 2 –CH3 group in acetone which reduces +ve charge density, on carbon atom
of carbonyl group. More hindered carbonyl group too becomes less reactive
52. 3 Only acids form sodium salt with NaOH and not alcohols. Nuclear Cl is not
replaced by OH under ordinary conditions
COO K+ CH2OH
53. 4 +
Cl Cl
Pot-m-chlorobenzoate m-chlorobenzyl alcohol
54. 1 Ketones react with ethylene glycol under similar conditions to form cyclic
products known as ethylene glycols ketals
O OH
+
HCl
OH O O
ethylene glycol
ketal
55. 2 Gels are a dispersion of molecules of a liquid within a solid in which the solid
is the continuous phase and the liquid is the discontinuous phase.
56. 3
57. 2 According to Hardy Schulze rule, greater the charge on cation, greater is its
coagulating power for negatively charged solution, so order of coagulating power.
1
58. 4 Coagulation Power Coagulation Value
O OH
59. 4 C O + CN C
H C
from H2 O/HCN
CN CN
Cyanohydrin
Nucleophilic addition reaction
O N CH3 NHCH3
61. 2
H2 NCH3
H2 O
LiAlH4
CN
CN
63. 2 95 % H2SO4
HCN OH Heat
CN
OMgX OH
O
OH
+RMgX C
H2 O/H
C
64. 3 R R + Mg
C R R
R R R X
R
65. 4 According to Hardy Schulze law, greater the charge on anion greater will be its
coagulating power
Here, PO34 have highest charge. Hence PO34 have highest coagulating power
FT20P/TP/MOD/NEET/PCB/[B1] 8 Brilliant STUDY CENTRE
0
COOH + H2SO4 CO + CO2 + H2O
95 C
66. 3
COOH
OH
O NOH
NH2OH
CH3 C CH2CH2CH3 CH3C CH2CH2CH3
H2O I2/NaOH
CHI3
OH Cl
H2O
CH3 C CH2 CH2 CH3 CH3 C CH2CH2CH3
OH Cl
O H O
R C C R
O H O
intermolecular
H-bonding
O O O
74. 1 FeO0.98 has a non-stoichiometric molecule having metal excess defect and not
metal deficiency defect. Frenkel defect is favoured in those ionic compounds if
there is a large difference between sizes of cation and anions.
F– is surrounded by 4 Ca2+
a 361
76. 1 For fcc structure, r
2 1.4141
127 pm
2 2
Cl2 /hv
H2O
373 K
Benzal
chloride
78. 2 Fog is a colloidal system having water (dispersed phase) dispersed in air
(dispersion medium)
*
80. 2
O
It contains the most reactive methylene group (*) and resulting anion is
stabilised by resonance.
O O O
..
O O O
AlCl3
+ CH3 CH2 CH2 Cl CH3 CH2 + CH2
81. 4
Friedel craft alkylation
carbocation rearrangement to 20
CH3 CH CH3 +
H3C CH3
C O O H
CH3
OH
+
H 3O
+ CH3 C O O2
(R) (Q)
Isopropyl benzene
(P)
82. 1 O +O
O
Mechanism :
O O
H
OH
H OH O
O
O
H2 O
OH
FT20P/TP/MOD/NEET/PCB/[B1] 11 Brilliant STUDY CENTRE
83. 2
84. 1
85. 4 Any substituent in the carbonyl compound that increases the positive charge
on the carbonyl carbon will increase reactively towards nucleophilic addition.
–NO2 shows –M effect hence;
CHO
NO2
4>1>3>2
O
COCl
C H
86. 4
H2
Pd.BaSO4
87. 4 CH3CHO will give positive iodoform test as it has CH3 C unit attached to
O
H (or C)
88. 1
89. 2
3a 3 4.29
90. 1 Radius of Na (if bcc lattice) = = 1.8574 Å = 1.8574 × 10–8 pm
4 4
FT20P/TP/MOD/NEET/PCB/[B1] 12 Brilliant STUDY CENTRE
BIOLOGY