Advance Paper Set A PDF

FIITJEE JEE(ADV.
)
BATCHES – 1618 CRP ABC LOT RT-1 PHYSICS, CHEMISTRY & MATHEMATICS
CPT1 - 1 CODE:102882 SET - A
Time Allotted: 3 Hours Maximum Marks: 210
 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into two sections: Section-A & C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.

(i) Section-A (01 – 10) contains 10 multiple choice questions which have one or more than one correct
answer. Each question carries +4 marks and – 2 mark for wrong answer.
(ii) Section-C (01 – 10) contains 10 Numerical based questions with single digit integer as answer,
ranging from 0 to 9 (both inclusive) and each question carries +3 marks for correct answer and – 1
mark for wrong answer.
Name of the Candidate :____________________________________________
Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________
FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4754800/804/811/814

www.fiitjeenoida.com
FIITJEE Towers, C – 56 A/26 Institutional Area, Sec – 62, Noida (U.P), 201307, Ph : 9871113448
2
CRP 1618 ABC LOT –Reshuffling Test-1 – (Paper-1)-CMP-IITJEE/18
Useful Data Chemistry:

Gas Constant R = 8.314 J K1 mol1
= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
= 6.25 x 10-27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66 x 10-27 kg
1 eV = 1.6 x 10-19 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56, Mn=55,
Pb=207, Au=197, Ag=108, F=19, H=2, Cl=35.5, Sn=118.6
Useful Data Physics:
2
Acceleration due to gravity g = 10 m / s

3
PART – I (PHYSICS)
SECTION – A
Multiple Correct Choice Type
1. The water equivalent of a copper calorimeter is 4.5 gm . If the specific heat of copper is
0.09 cal gm1 0C 1 , the
(A) mass of calorimeter is 0.5 kg
(B) thermal capacity of calorimeter is 4.5 cal 0C 1
(C) heat required to raise the temperature of calorimeter by 80 C will be 36 cal
(D) heat required to melt 15 gm of ice  0 0 C  placed in calorimeter  0 0 C  will be 1200 cal 1
2. An U-tube filled with liquid is being rotated about an axis with 

angular speed ' ' as shown in figure. The difference in heights of
liquid in two arms is
2 2
(A)
2g
r 1
2
 r22  (B)
g
r1
2
 r22 
2 2
2
(C)
g
r 1
2
 r22  (D)
2g
 r1  r2 
r1 r2
3. A monoatomic gas undergoes a process given by adU  bdW  0, Now if

a
(A)  1, then process is isobaric (B) b  0 , then process is isothermal
b
a a 2
(C)  1 , then process is adiabatic (D)   , then process is isobaric
b b 3
y  x,t   0.8 /  4x  5t   5  represents a moving pulse, where x and y are in metre and t in
2
4.
second. Then
(A) pulse is moving in +x direction (B) in 2 s it will travel a distance of 2.5 m
(C) its maximum displacement is 0.16 , (D) it is a symmetric pulse
5. If for a liquid in a vessel, force of cohesion is twice the force of adhesion

(A) the meniscus will be convex
(B) the liquid will not wet the solid
(C) the angle of contact will be obtuse
(D) the liquid will descend in capillary made of material of vessel
space for rough work

4
6. Which of the following statements are correct for rolling without slipping on rough horizontal
ground
(A) acceleration of point of contact with ground is zero
(B) there are only two points that have speed 2 times the speed of center of object
(C) Friction force may or may not be zero
(D) velocity of point of contact with ground is zero.
7. Figure shows a system consisting of two massless pulley, two springs

of force constant 'K' and a block of mass 'm' . Frequency of small
oscillations of the block is
5K 1 5K
(A) 2 (B)
m 2 m
1 K 5m K
(C) (D) 2
2 5m K K
m
8. A particle moves in a straight line and its velocity is given by u  2t  3. Then

(A) The distance travelled by the particle in 5 seconds is 14.5 m
(B) The distance travelled by the particle in 5 seconds is 12.5 m
(C) The displacement of the particle in 5 seconds is 10 m
(D) The displacement of the particle in 5 seconds is 8 m
9. A point moves with deceleration along the circle of radius of ‘R’ so that at any time its tangential
and radial accelerations are equal in magnitude. At the initial moment t = 0, the velocity of the
point is v0 . The velocity of the point at any time t is v . Then which of the following are not correct
S
u0 
(A) v  after t seconds (B) v  u0 e R
after s meter
ut
1 0
R
R
R 
(C) v  after t seconds (D) v  u0 e S
after s meter
u0
1 t
R
10. Two blocks are given velocities as shown in figure.

Friction coefficient for both the blocks is same. In 10m/s 4m/s
the process of motion, net displacement of center 2 kg 5 kg
of mass of two block system will be (assume initial
distance between blocks is large enough so that
they do not collide)
(A) Zero (B) towards right
(C) towards left (D) Insufficient data

5
SECTION – C
Integer Type
1. A body of mass ‘ m1 ’, moving with certain velocity strikes head on a body of mass 'm2 ' at rest.
nm1m2
Assuming collision to be elastic, the fraction of K.E. transferred to stationary body is .
 m1  m2 
2
Find 'n' .
2. A balloon starts rising from surface of earth. The ascent rate is constant and equal to u0 . Due to
wind the balloon gathers a horizontal velocity component U x  Ay , where A is a constant and
Ay 2
. Find 'n' .
'y' is height of ascent, if horizontal drift of balloon is
nu0
3. In the arrangement shown, system is released from rest
from the position shown. If maximum height attained, by
body of mass ‘m’ is 'nh'. Find n.
4m
h m
4. A small particle falls vertically and strikes a smooth inclined plane of inclination 30 0 with
1
horizontal. After collision velocity of ball becomes horizontal. If coefficient of restitution is . Find
n
'n'.
5. The sound level of a point source at a distance 30 m from the source is 100 dB. Then find the
distance (in m) from source where sound level will be 120 dB.
6. If the vectors a  2iˆ  ˆj  kˆ ,b  i  2ˆj  3kˆ and c  3iˆ   ˆj  5kˆ are coplanar, then value of  is
7. A block is resting on a horizontal plank. Coefficient of friction between block and plank is '  ' . The
plank begins to move in x-direction with velocity given by u  at 2 , ‘t’ being time and ‘a’ being
g
constant. The time at which block start sliding is . Then the value of n is
na

6
8. At t  0 , a stone of mass ‘m’ is released from the top of a building of height ‘h’ . At time t0 , kinetic
energy of the particle is 3 times the potential energy of the particle w.r.t. ground. If average power
3 2 3
delivered by 'mg' to the particle between t  0 to t  t0 is m g h . Then the value of n is
n
9. A uniform ladder of mass 10 kg leans against smooth vertical wall

making angle 530 with it. Other end rests on rough horizontal floor.
Smooth
2
Then friction coefficient just necessary for ladder to be at rest is .
n
Then the value of n is 370
Rough
10. The work done in lifting a body from Earth’s surface to a height ‘R’ (radius of Earth) is equal to
R
two times the work done in lifting the same body from Earth’s surface to a height . Then the
n
value of n is

7
PART – II (CHEMISTRY)
SECTION – A
Multiple Correct Choice Type
1. An open ended mercury manometer is used to measure the P = 76 cm

pressure exerted by a trapped gas as shown in the figure. Initially
manometer shows no difference in mercury level in both columns
as shown in diagram. After sparking ‘A’ dissociates according to gas A
following reaction
A  g  
 B  g   3C  g  Hg
If pressure of Gas “A” decreases to 0.9 atm. Then which of the
following is/are correct? (Assume temperature to be constant
and is 300 K)
(A) total pressure increased to 1.3 atm (B) total pressure increased by 0.3 atm
(C) total pressure increased by 22.3 cm of Hg (D) difference in mercury level is 228 mm of Hg.
2. 25 ml of 0.5 M H2O2 solution is added to 50 ml of 0.2 M KMnO4 in acid solution. Which of the
following statement/s is/are true?
(A) 0.01 mole of oxygen is liberated
(B) 0.005 mole of KMnO4 does not react with H2O2
(C) 0.0125 gram-mole of oxygen gas is evolved.
(D) 0.0025 mole of H2O2 does not react with KMnO4
3. Which of the following combinations is/are not allowed? (Assume z-axis as the internulcear axis).
(A) 2s  2pz (B) 2p x  2p x (C) 2s  2p x (D) 2pz  2pz
4. Select correct statement (s) for the reaction:

H2O  g  CO  g  
 H2  g   CO2  g 
Substance CO(g) CO2(g) H2O(g) H2(g)
Hf0, 400 K (K Cal mol–1) –25 –95 –55 0
S0 400K (Cal mol–1 K–1) 45 50 40 30
(A) Reaction is enthalpy driven (B) reduction is entropy driven

(C) Reaction is spontaneous at 400 K (D) reaction is non-spontaneous at 400 K
5. Dichromate ion in acidic medium oxidises stannous ion as:

xSn2  yCr2 O72   zH 
 aSn4  bCr 3  cH2O
Which of the following is/are correct?
(A) the value of x : y is 1 : 3
(B) the value of x + y + z is 18
(C) a : b is 3 : 2
(D) The value of z-c is 7

8
6.
O O
O O
O O
(I) (II) (III)

Among the given compounds, the correct order of enol content is/are:
(A) I > III (B) II > I (C) II > III (D) III > I
7. Consider the following reaction and predict the major product (X) obtained. Which of the following
is/are not the major product?

H2 SO4

  X

OH
(A) (B)
(C) (D)

9
8. The % yield of ammonia as a function of time in the reaction

N2  g  3H2  g  2NH3  g  , H  0
at (P, T1) is given below
% yield
T1
time 
If this reaction is conducted at (P, T2), with T2 > T1, the % yield of ammonia as a function of time
cannot be represented by –
T1
% yield
% yield
T2
(A) T1 (B) T2
time  time 
% yield
% yield
T1 T2
(C) T2 (D) 2
T1
time  time 
9. Predict the major product/s ‘X’ formed in the given reaction:

O
H3C C O O H
1 eq
X
major
The product ‘X’ is :
(A) O (B) O
OH
OH
(C) (D)
OH
OH

10
10. Arrange in their decreasing order of rate of electrophilic aromatic substitution.
(i) (ii) (iii)

(A) (ii) > (i) (B) (iii) > (ii)
(C) (iii) > (i) (D) (i) > (iii)
SECTION – C
Integer Type
1. In 1 L saturated solution of AgCl ( Ksp AgCl  1.6  10 10 ), 0.1 mole of CuCl ( KspCuCl  10 6 ) is added.
The resultant concentration of Ag+ in the solution is 1.6 × 10–x. The value of ‘x’ is: ______
2. How many atoms will be bisected during plane of symmetry?

Cl
Cl
3. How many alkene on catalytic hydrogenation (including stereoisomer) gives isopentane as a

product?
4. A 50 mL 1.92% (W/V) solution of a metal ion M n+ (atomic weight = 60) was treated with 5.332 g
hydrazine hydrate (90% pure) and mixture was saturated with CO 2 gas when entire metal gets
precipitated as a complex [M(NH2–NH–COO)n]. The complex was filtered off and the filtrate was
titrated with M/10 KIO3 in the presence of conc. HCl according to the following equation:
N2H4  IO31  2H  2Cl 

 ICl  3H2O  N2 
The volume of M/10 KIO3 solution needed for the end point to arrive was 480 ml. Find the value of
n. (Molecular weight of N2H4.H2O = 50)
5. If the number of products (including stereoisomers) obtained in the reaction (a), (b), (c) and (d)
are (X), (Y), (Z) and (P) respectively by E2 mechanism. Find the sum of (X + Y + Z + P)
(a) 
alc.KOH
 ' X'number of products
Br
Br
(b) 
alc.KOH
 ' Y 'number of products

alc.KOH
 ' Z'number of products
(c)
Br
CH3
H
(d) H3C 
alc.KOH
 'P'number of products
CH3 H Br

11
6. For 3s-orbital of hydrogen atom, the normalised wave function is given by

3/ 2
1  1  r r 2  r /3a
 3s     27  18  2 2  e 0
81 3P  a0   a0 a0 
The above mentioned orbital (3s) has two nodes at 7a0 and xa0. The value of x is approximately
equal to __________
7. The gaseous reaction, A  g   nB  g  mC  g  is represented by following curves:
12
[B]
10

Conc 8 [A]
. 6
[C]
0 Time 
What is the value of n + m?
8. For the equilibrium reaction given below

LiCl.3NH3  s  LiCl.NH3  s   2NH3  g  K P  9 atm2 at 37°C. A 5 litre vessel contains 0.1
mole of LiCl.NH3. If ‘n’ number of moles of NH3 are added to the flask at this temperature to drive
the backward reaction for completion, report the approximate value of 10n.
Use : R = 0.082 L atm / mol K
9. OH
 
 P 
H excess

HO
OH
If the product (P) is CxHy. Report the value of x – y.
10. Consider the following structure

H 1 H
C C C
H 2
H
Find the value of 1 – 2 . In case the data is insufficient to report the value, mark the answer by
integer ‘9’.

12
PART – III (MATHEMATICS)

SECTION – A
Multi Correct Type
A chord AB, which is bisected at (1, 1) is drawn to the hyperbola x  4xy  y  3  0 with
2 2
1.
centre ‘C’ which intersects its asymptotes in E and F. Then
(A) Radius of the circum circle of  CEF is 2
(B) It ek be the eccentricity of hyperobla x  4xy  y  3k  0  k  1, 2, 3,…..2014, then

2 2
2014
e
k 1
k  21007
1
(C) Slope of the line  to the segment AE is
3
(D) All A, B, C can not be true simultaneously
If two of the lines represented by ax  bx y  cx 2 y 2  dxy 3  ay 4  0 bisects the angle

4 3
2.
between the other two, then
(A) c  6a  0 (B) b  d  0 (C) a  b  c  d
2 2 2 2
(D) None of these
3. Tangent drawn at point P(1, 3) of a parabola intersects its tangent at vertex at M(1, 5) and cuts
the axis of parabola at T. If R(5, 5) is a point on SP; where S is focus of the parabola, then
(A) slope of axis is 3
5
(B) radius of circumcircle of SMP is units
2
(C) (ST)  (SM)  (PM)
2 2 2
(D) tangent cuts the axis of parabola at T (3, 7)
4. If N is the number of three digit numbers of the form a b c such that a < b < c then
(A) N is an even number (B) N is divisible by 7
(C) N = C4  C4
10 9
(D) N is divisible by exactly three primes
5. Which of the following statement(s) is/are true?

(A) If a  b  c and a, b, c are in GP, then x, y, z are in HP
x y z
(B) If a
1/ x
 b1/ y  c1/ z and a, b, c are in GP, then x, y, z are in AP
(C) a, b, c are positive each of them not equal to 1, and are in GP, then, for any positive
u  1, log a u, log b u, log c u are in HP
(D) If a, b, c are in AP and b, c, a are in HP, then c, a, b are in GP

13
6. If the equation x 2  9y 2  4x  3  0 is satisfied for all real values of x and y , then

1 1 1
(A) 1  x  3 (B) 2  x  3 (C)  y  1 (D)   y 
3 3 3
7. If  is a non - real cube root of unity then the value of

1  2     2   2   2   3     3   2   ......   n  1 n     n   2  is
n 2  n  1  n  n  1 
2 2
(A) real (B) n1 (C)   n (D) not real

4  2 
8. If 4a 2  5b 2  6a  1  0 and the line ax  by  1  0 touches a fixed circle, then

(A) centre of circle is at  3,0  (B) radius = 5
(C) radius = 3 (D) circle passes through  1,1
9. If roots of equation x 2   2n  18  x  n  11  0  n  I  are rational numbers for n  a and n  b

then a  b is
(A) 1 (B) 2 (C) 3 (D) 4
10. If n  2016 then find the value of n C0 nC0  n 1C1 nC1  n  2C 2 nC 2  ......... 
(A) 1 (B) 2016 (C) 1 (D) 2016
SECTION – C
Integer Type
x2 y 2
1. A normal to the hyperbola   1, has equal intercepts on positive x and y-axes. If this
4 1
x2 y 2
normal touches the ellipse 2  2  1 , then find
a b 25
 a  b2 
9 2
2. There are 10 girls and 8 boys in a class room including Mr. Ravi, Ms. Rani and Ms. Radha. A list
of speakers consisting of 8 girls and 6 boys has to be prepared. Mr. Ravi refuses to speak if Ms.
Rani is a speaker. Ms. Rani refuses to speak if Ms. Radha is a speaker. The number of ways the
list can be prepared is a 3 digit number n1n2 n3 , then n3  n2  n1 

14
(x – 3)2 (y – 4)2
3. Given the equation of the ellipse + = 1, a parabola is such that its vertex is the
16 49
lowest point of the ellipse and it passes through the ends of the minor axis of the ellipse. The
A H K
 
2
equation of the parabola is in the form 16y = A(x – H) – K. Determine the value of is
7 3 16
equal to
4. If f  x   sin 1 x and lim f  3 x  4 x 3   a  3 lim f  x  , then  a   ________
1 1
x x
2 2
5. Two curves ax 2  2hxy  by 2  2 gx  2 fy  c  0 and

a ' x 2  2hxy   a ' a  b  y 2  2 g ' x  2 f ' y  c  0 intersect in four concyclic points A, B, C
 g  g' f  f ' PA2 PB 2 PC 2
and D. If P be the point  ,  then   is equal to
 a a' a a'  PD 2 PD 2 PD 2
6. A straight line cuts the x-axis at point A 1, 0  , and y-axis at point B, such that
 
OAB       . C is middle point of AB and B’ is a mirror image of point B with respect to
 4
line OC and C’ is a mirror image of point C with respect to line BB’, then the ratio of the areas of
triangles ABB’ and BB’C’ is equal to
x x
Find the maximum value of 4sin x  3cos x  sin  cos  2
2 2
7.
2 2
8. If the product of the roots of the equation x2 − 3kx + 2e2lnk − 1 = 0 is 7, then the roots are real for k
is equal to
9. Suppose ABCD (in order) is a quadrilateral inscribed in a circle then

cot A  cot C  cos ecA  cos ecC  tan B  tan D is equal to
10. Length of the chord on the line 4x  3y  10  0 cut-off by the circle x 2  y 2  2x  4y  20  0

is

15
FIITJEE COMMON
TEST
BATCHES: CRP 1618 ABC LOT
Reshuffling Test – 1
ANSWER KEY
SET-A
SECTION – A
1. B, C, D 2. A 3. B, C, D 4. B,C,D
5. A, C, D 6. C, D 7. C 8. A, C
9. A, C, D 10. B
SECTION – C
1. 4 2. 2 3. 3 4. 3
5. 3 6. 4 7. 2 8. 8
9. 3 10. 3
SECTION – A
1. A,B,D 2. B,C 3. C 4. A,C
5. B,C,D 6. A,C 7. A,C,D 8. A,C,D
9. B 10. A, B, C
SECTION – C
1. 7 2. 6 3. 3 4. 3
5. 8 6. 2 7. 5 8. 8
9. 0 10. 0
SECTION – A
1. A,B,C 2. A, B 3. A, B, C, D 4. A, B, C, D
5. A, B, C, D 6. A, D 7. A, C 8. A, B, D
9. C 10. C
SECTION – C
1. 3 2. 6 3. 5 4. 3
5. 3 6. 2 7. 4 8. 2
9 0 10. 6

16
HINTS & SOLUTIONS

SECTION – A
1. B, C, D
Sol. W  ms  m  50 gm
Q  W   36 cal
Q  mL  15  80  1200 cal
2. A
1
Sol. P1  P0   2 r12  Patm   gh1
2
1
P2  P0   2 r22  Patm   gh2
2
3. B, C, D
4. B,C,D
5. A, C, D
6. C, D
7. C
K
Sol. K eq 
5
1 K eq
f 
2 m
8. A, C
Sol. Distance = Area under u - t graph
9. A, C, D
dv dv v 2
Sol.   u 
dt ds R
10. B
Sol. Block of mass 2 kg will be in motion for some time, even after block of mass 4 kg stops.
SECTION – C
1. 4
1
m2 v22 2m1
Sol. f  2 and v2  v0
1 m1  m2
m1 v02
2
2. 2
dx dy
Sol.  Ay and  u0
dt dt
Au0 t 2
y  u0 t  x 
2
3. 3
Sol. T  mg  ma
a
4mg  2T  4m
2
g
a 
2
When 4m strikes surface, m will continue to move upwards.
 g 
 2. 2 .2h 
Maximum height H  2h 
 
2g
 3h
4. 3

17
Sol. v cos 30 0  ucos 60 0 u

v cos 60 0
e
ucos 30 0 v
1

3 30
o
5. 3
I1
Sol. 100  10 log
I0
I
120  10 log 2
I0
I
20  10 log 2
I1
I 2  100I1
1
I  2 for a point source
r
r
r2  1  3m
10
6. 4
Sol.  
a  b c  0
7. 2
Sol. Block will start sliding when acceleration of plank   g
8. 8
Sol. K  3U and K  U  mgh
h 3
 h'  , K  mgh
4 4
3
mgh
W 4
Pavg  
t 2 3
 h
g 4
9. 3
Sol. For equilibrium N2
N1  Mg  100N
f  N2 N1
l
Mg cos 37 0  N 2 l sin 37 0
2 mg
200 f
 N2  N
3
2

3
10. 3
mgh
Sol. W
h
1
R
SECTION – A
1. A,B,D
Sol. A  g  B  g  3C  g 
t=0 1 atm
t=t 1–x x 3x
18
=0.9 =0.1 =0.3

PTotal = 1.3 atm
2. B,C
Sol. If meq = milli equivalent
H
H2O2 + KMnO4  O2 + Mn+2
meq. 25 50
meq left /formed – 25 25 25
meq of O2 formed = 25
25  10 3
 moles of O2 formed =  12.5  10 3
2
meq of KMnO4 left unreacted = 25
25  10 3
 moles of KMnO4 left unreacted =  5  10 3
5
3. C
Sol. 2s  2pz    bond
2p x  2p x    bond
2pz  2pz    bond
4. A,C
Sol. Hreaction
o
 0  95  25  55  15K cal
Sreaction
o
 30  50  45  40  5 cal K–1
G° = H°– TS° = –15 × 103 –400×(–5) = (–ve)
5. B,C,D
Sol. Sn2  Sn4  2e 
6e   Cr2O72   14H  2Cr 3  7H2O
Cr2O72   3Sn2  14H  3Sn4  2Cr 3  7H2O
 x =3 ; y = 1; z = 14; a = 3; b = 2 ; c = 7
x:y=3:1
x + y +z = 18
a:b=3:2
z–c=7
6. A,C
Sol.
H
OH OH
O O
O O
(I) (II) (III)
Aromatic with intramolecular H-bond Aromatic Non Aromatic

7. A,C,D
Sol.

19
+
H
OH OH 2
CH3
8. A,C,D
Sol. % yield will increase in initial stage due to enhanced speed but as time proceeds, final yield is
governed by thermodynamics due to which yield decrease since reaction is exothermic.
9. B
Sol. The middle double bond is most electron rich and hence electrophilic attack occurs on it.
10. A, B, C
Sol. –Ph group can release the electron density through resonance effect and –CH2– by
hyperconjugative effect.
SECTION – C
1. 7
Sol. CuCl Cu1  Cl1 KspCuCl  10 6  s  s  s' 
s s  s'
AgCl Ag1  Cl1 Ksp AgCl  1.6  10 10  s'  s  s' 

s' s  s'
10 6 s
10

1.6  10 s'
4
 s'  1.6  10 s
10  s  s  1.6  10 4 s   s2
6
 s  10 3
 s'  1.6  10 4  10 3 =1.6 × 10–7
x = 7
2. 6
Sol.
Cl
H C
H
Cl
3. 3
Sol.
CH3 CH3 CH3

CH3   H3C CH CH2 CH3   H3C
H2 /Ni H2 /Ni
H2C C CH2 CH CH CH3
H2/Ni
CH3
H3C CH CH CH2
4. 3
Sol.

20
Mn   M NH2  NH  COO n 

 nNH2  NH2 .H2O  CO2 
0.96 g 4.7988 g
moles 0.016 0.09597
N2H4  IO3  2H  2Cl 
 ICl  3H2O  N2
M
,480ml
10
1
neq N2H4 left unreacted (with Mn+) =  480  4  10 3
10
Number of moles of N2H4 left unreacted with N2H4 = 48×10–3
4.7988
Number of moles of N2H4 taken =  0.09597
50
Number of moles of N2H4 reacted with Mn+ = 0.0479
0.0479
1 mole of Mn+ reacts with mole i.e.2.99 moles of hydrazine hydrate.
0.016
5. 8
Sol.

alc.KOH

Br cis  trans
Br

alc.KOH

CH3
cis  trans

alc.KOH

cis  trans
Br
CH3
H3C C CH 2 Br 
alc.KOH
E2
 No reaction
CH3
X : 3, Y : 3, Z : 2
6. 2
Sol. Condition for node is 2 = 0
r 2r 2
27  18  2 0
a0 a0
r
Let y
a0
 2y 2  18y  27  0
18  182  4  2  27 18  324  216 18  108 18  10.39
y   
4 4 4 4
y = 7.09, 1.9
 r  1.9a0
 x = 1.9
7. 5
A  g   nB  g  mC  g 
Sol.
8 x  6 12  nx  8 mx  6
 x=2
21
 m = 3 and n = 4/2 = 2
n+m=5
8. 8
Sol.
LiCl.3NH3  s  LiCl.NH3  s   2NH3  g  K P  9 atm2  PNH3  3
moles 0.1mole n
x 0.1  x 0 n  2x  n  0.2
PV  n'RT
3  5   n  0.2   0.082  310
n = 0.79
9. 0
Sol.
CH2 OH CH2 OH2

CH2
+
HO H HO HO
OH OH OH
OH HO
(P)
10. 0
Sol.
H
1
H
C 
C C 1 2
2 H
H
SECTION – A
1. ABC
Sol. The given hyperbola is a rectangular hyperbola so  CEF is right angle and eccentricity of the
hyperbola is 2
2. A, B
Sol.  ax 4
 bx3 y  cx 2 y 2  dxy 3  ay 4    ax 2  pxy  ay 2  x 2  qxy  y 2 
On comparing; b  aq  p ... 1 , c  pq  2a ....  2  , d  q  aq ...  3
(1) + (3) b  d  0 from (2) pq  c  2a ...  4 
x2  y 2 xy x2  y 2 a
   ...  5   x 2  qxy  y 2  0
a   a  p / 2 4 xy p

22
x2  y 2 q
  ...  6 
4 xy 4
(5) = (6)
a q
   pq  4a
p 4
4a  c  2a  c  6a  0
3. A, B, C, D
Sol. A,B,C,D
Equation of tangent at P is x+y=4
Clearly mirror image of R(5,5) lies on line PQ. Q
P
Now mirror image R or R M
R
  5   5 2( 5  5  4)
   4 S
1 1 2 T(3,7)
 (, )  ( 1,9)
Let PM cuts the axis at T; As M is midpoint of PT
 T is (3, 7)

We know that SP = ST and SMP=
2
1
Equation SP  y  3   (x  1)
3
 x + 3y10 = 0
Let S  (10  3, )
7 93
Again TS || PQ    3
13  3 1  1
 focus is (2, 4)
4. A, B, C, D
9  8 7
Sol. 9
C3   24  7  168
3
5. A, B, C, D
k k k
Sol. (A) x ln a  y ln b  z lnc  x  ,y ,z
ln a ln b lnc
2ab 2
(D) 2b  a  c ; c  , a  bc
ab
6. A, D
Sol. x 2  4x  3  9y 2  0 D  0  4 2  4  3  9y 2   0
9y 2  x 2  4x  3  0 D  0  0 2  4  9  x 2  4x  3   0
7. A, C
Sol. x 3  1  0  x 3  1   x  1 x     x   2 
Now put x  2,3,......,n
23  1  33  1  4 3  1  5 3  1  ....  n 3  1
 n  n  1 
2
  n
 2 
8. A, B, D
3a  1
Sol.  5  perpendicular distance of  3,0  from ax  by  1  0 is 5
a2  b 2
9. C
Sol. discriminant = 4  n 2  19n  92  and n2  19n  92  K 2 (since discriminant should be perfect square)

23
  2K  2n  19  2K  2n  19   7
10. C
C0 nC0  n 1C1 nC1  n  2C 2 nC 2 .......   1
n n
Sol.
SECTION – C
1. 3
x2 y2
Sol. Equation of normal at  1
4 1
is 2x cos   y cot   4  1 .... 1
x2 y2 x cos  y sin 
Equation of tangent at 2
 2 1  1 ....  2 
a b a b
Now compare (1) and (2)
2. 6
Sol. 8
C7  8C6  8C7  7 C6  280
3. 5
 x  3  y  4
2 2
Sol. Given ellipse   1 (vertical ellipse)

42 72
(3, 4)
x x
(–1,4) (7, 4)

(3, –3)
Parabola can be taken as
(x-3)2 = A (y+3)
It passes through (-1, 4)
 16 = 7A  A = 16/7
 parabola is 7(x-3)2 = 16y + 48
 16y = 7(x-3)2 – 48
 A = 7, H = 3, K = 48
A H K
   5
7 3 16
4. 3
 1 1 1
 3sin x;  x
Sol. sin  3x  4x   
1 3 2 2
  3sin 1 x; 1
x
 2
5. 3
Sol. Equation of circle will be
ax 2  2hxy  by 2  2gx  2 fy  c   a'x 2  2hxy   a' a  b  y 2  2g'x  2 f 'y  c   0
 g  g' f  f ' 
centre is  , 
 a  a' a  a' 
Now PA  PB  PC  PD
6. 2
 1 tan    2tan 2  tan 3   tan  
Sol. A   1,0  , B   0,tan   , C   ,  , B'   , 
 1  tan  1  tan 2  
2
2 2 
ABB'
2
BB'C
24
C’
B P
B’
C

x
O A
7. 4
    
Sol. Put x   4 sin 2  3cos 2  sin  cos  2  4
2 2 2 4 4
8. 2
Sol. x 2  3kx  2k 2  1  0
 ,   2k 2  1  7  k  2
D  0  9k 2  8k 2  4  0
k2  4  0
9 0
Sol. B  D  180 0
A  C  180 0
D  180 0  B
C  180 0  A
D
C
A
B
10. 6
Sol. r  22  12  20  5
1, -2
5
4
3
4x - 3y +10=0


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FIITJEE JEE(ADV.

CPT1 - 1 CODE:102882 SET - A

Time Allotted: 3 Hours Maximum Marks: 210

B. Filling of OMR Sheet

C. Marking Scheme For All Three Parts.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4754800/804/811/814

Useful Data Chemistry:

FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4754800/804/811/814

2. An U-tube filled with liquid is being rotated about an axis with 

3. A monoatomic gas undergoes a process given by adU  bdW  0, Now if

5. If for a liquid in a vessel, force of cohesion is twice the force of adhesion

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7. Figure shows a system consisting of two massless pulley, two springs

8. A particle moves in a straight line and its velocity is given by u  2t  3. Then

10. Two blocks are given velocities as shown in figure.

space for rough work

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space for rough work

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9. A uniform ladder of mass 10 kg leans against smooth vertical wall

space for rough work

FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4754800/804/811/814

1. An open ended mercury manometer is used to measure the P = 76 cm

4. Select correct statement (s) for the reaction:

(A) Reaction is enthalpy driven (B) reduction is entropy driven

5. Dichromate ion in acidic medium oxidises stannous ion as:

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(I) (II) (III)

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8. The % yield of ammonia as a function of time in the reaction

9. Predict the major product/s ‘X’ formed in the given reaction:

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10. Arrange in their decreasing order of rate of electrophilic aromatic substitution.

(i) (ii) (iii)

2. How many atoms will be bisected during plane of symmetry?

3. How many alkene on catalytic hydrogenation (including stereoisomer) gives isopentane as a

N2H4  IO31  2H  2Cl 

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FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4754800/804/811/814

6. For 3s-orbital of hydrogen atom, the normalised wave function is given by

7. The gaseous reaction, A  g   nB  g  mC  g  is represented by following curves:

What is the value of n + m?

8. For the equilibrium reaction given below

10. Consider the following structure

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PART – III (MATHEMATICS)

(A) Radius of the circum circle of  CEF is 2

(B) It ek be the eccentricity of hyperobla x  4xy  y  3k  0  k  1, 2, 3,…..2014, then

If two of the lines represented by ax  bx y  cx 2 y 2  dxy 3  ay 4  0 bisects the angle

(D) tangent cuts the axis of parabola at T (3, 7)

5. Which of the following statement(s) is/are true?

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6. If the equation x 2  9y 2  4x  3  0 is satisfied for all real values of x and y , then

7. If  is a non - real cube root of unity then the value of

Batch :__ Date of Examination :_