Вы находитесь на странице: 1из 14

tiempo [A] Ln[A] 1/[A]

0 0.335 -1.0936247471571 2.98507462686567


2.25 0.2965 -1.2157080605444 3.37268128161889
0.4
T vs [A]
4.5 0.266 -1.3242589702004 0.35
3.7593984962406
6.33 0.245 -1.4064970684374 0.3
4.08163265306122
0.25 f(x) = − 0.015055087719298 x + 0.3096192982
8 0.2255 -1.4894351200394 4.43458980044346 R² = 0.967559051571624
0.2
10.25 0.205 -1.5847452998437 4.87804878048781

[A]
0.15
12 0.191 -1.6554818509355 5.23560209424084
0.1
13.5 0.1794 -1.7181373293575 5.57413600891862
0.05
15.6 0.1632 -1.8127788364521 6.127450980392160
17.85 0.15 -1.8971199848859 6.66666666666667 0 5 8 12 5.6 9.6 30 41 47
4. 1 1
19.6 0.1429 -1.9456101940463 6.99790062981106
Tiempo
27 0.116 -2.1541650878758 8.62068965517241
30 0.1053 -2.2509418598422 9.49667616334283
38 0.083 -2.4889146711855 12.0481927710843 T
41 0.0767 -2.5678535706089 13.0378096479791 25
45 0.0705 -2.6521425691639 14.1843971631206 20
47 0.0678 -2.6911930840358 14.7492625368732 15 f(x) = 0.88864810
57 0.0553 -2.8949823704539 18.0831826401447 10 R² = 0.890435747

1/[A]
63 0.0482 -3.0323962579256 20.746887966805 5
0
0 5 8 12 .6
4. 15 1
tiempo [A] r Ln[A] Lnr
0 0.335 -0.0365 -1.09362474715707 -3.310443018394 Tiemp
2.25 0.2965 -0.0339127917969 -1.21570806054436 -3.383962996629
4.5 0.266 -0.0342368375 -1.32425897020044 -3.374453094708
6.33 0.245 -0.0564350349234 -1.40649706843741 -2.874665126749
8 0.2255 -0.1039816 -1.4894351200394 -2.26354131857
10.25 0.205 -0.2235125792969 -1.58474529984373 -1.498287583305
0.4
12 0.191 -0.3744584 -1.65548185093551 -0.982274563637
0.3 f(x) = − 1.50794E-07 x⁶ +
13.5 0.1794 -0.5575065125 -1.71813732935744 -0.584281094102
0.2 − 0.00198714 x² − 0.03
R² = 0.99874311127651
15.6 0.1632 -0.926640173312 -1.81277883645213 -0.076189951325
[A]

0.1
17.85 0.15 -1.5289544223339 -1.89711998488588 0.4245841176955
0
19.6 0.1429 -2.208204435712 -1.94561019404632 0.7921797127665 0 8
4.
5 12 .6
27 0.116 -9.0088484 -2.15416508787577 2.1982072499109 15
30 0.1053 -15.0065 -2.25094185984221 2.7084834405738 Tiemp
38 0.083 -50.1312616 -2.48891467118554 3.9146447975257
41 0.0767 -74.7784012 -2.56785357060893 4.3145290892723
45 0.0705 -122.62775 -2.65214256916391 4.8091533437299
47 0.0678 -154.6945684 -2.69119308403579 5.0414526464261
57 0.0553 -435.5382284 -2.89498237045385 6.0765825729223
63 0.0482 -745.6524116 -3.03239625792558 6.6142595554287
T vs [A] T vs Ln[A]
0
-0.5 0 4.5 8 12 5.6 9.6 30 41 47 63
.015055087719298 x + 0.309619298245614 1 1
7559051571624 -1 Ln[A]
[A] -1.5 f(x) = − 0.104781730731517 x − 0.9456556891580

Ln[A]
R² = 0.986678168160668 Linear
Linear ([A])
-2 Linear
-2.5
-3
-3.5
8 12 .6 9.6 30 41 47 63
15 1 Tiempo
Tiempo

T vs 1/[A]
25
20
15 f(x) = 0.888648106353931 x − 0.198045244419884
10 R² = 0.890435747040964 1/[A]
1/[A]

5 Linear (1/[A])
0 8
0 5 8 12 .6 .6 30 41 47 63
4. 15 19

Tiempo 6 f(x) = 0.6001204


R² = 0.98328729

T vs [A]
0.4 Ln r 2
0.3 f(x) = − 1.50794E-07 x⁶ + 8.29133E-06 x⁵ − 0.000162842 x⁴ + 0.00129367 x³
0.2 − 0.00198714 x² − 0.036518 x + 0.371352
R² = 0.998743111276514 [A] 0
[A]

0.1 Polynomial ([A]) ... ... ... ... ...


.09 .21 .32 .40 .48
0 -1 -1 -1 -1 -1
0 5 8 12 .6 .6 30 41 47 63 -2
4. 15 19

Tiempo -4
vs Ln[A]

.6 30 41 47 63
19
Ln[A]
1730731517 x − 0.945655689158053
8160668 Linear (Ln[A])
Linear (Ln[A])

po

Ln [A] vs Lnr
8

6 f(x) = 0.60012042220862 x − 5.02510012846347


R² = 0.983287295449034

Lnr
Linear (Lnr)
Ln r

0
... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ...
.09 .21 .32 .40 .48 .58 .65 .71 .81 .89 .94 .15 .25 .48 .56 .65 .69 .89 .03
-1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -2 -2 -2 -2 -2 -2 -2 -3
-2

-4
Ln[A]
tiempo (ns) [O2] tiempo (ns)
0 0 0
2 7.31E-06 2
4 1.46E-05 4
6 2.19E-05 6
8 2.92E-05 8
10 3.65E-04 10

[O2]
0.0004 0
0 2
0.00035
-5E-10
0.0003
-1E-09
Concentracion O2

concentracion O
0.00025
-1.5E-09
0.0002
-2E-09
0.00015
-2.5E-09
0.0001
-3E-09
5E-05
-3.5E-09
0
0 2 4 6 8 10 12 -4E-09
Tiempo (ns)
[O] tiempo (ns) [OH]
0 0 0
-7.51E-10 2 1.46E-05
-1.50E-09 4 2.92E-05
-2.25E-09 6 4.38E-05
-3.00E-09 8 5.85E-05
-3.76E-09 10 7.31E-05

[O] [OH]
0 8E-05
0 2 4 6 8 10 12
-5E-10 7E-05
6E-05
-1E-09

Concentracion OH
concentracion O

5E-05
-1.5E-09
4E-05
-2E-09
3E-05
-2.5E-09
2E-05
-3E-09
1E-05
-3.5E-09
0
-4E-09 0 2 4 6 8

tiempo (ns) tiempo (ns)


[OH]

4 6 8 10 12
tiempo (ns)
Experimento 1 Experimento 2 Experimento 3 Experimento 4 Experimento 5
t(S)
[A] (mol/L) [A] (mol/L) [A] (mol/L) [A] (mol/L) [B] (mol/L)
0 0.01 0.02 0.04 0.06 0.0202
1000 0.009456 0.018912 0.037825 0.056737 0.019102
2000 0.008942 0.017884 0.035768 0.053652 0.018063
3000 0.008456 0.016912 0.033823 0.050735 0.017081
4000 0.007996 0.015992 0.031984 0.047976 0.016152
5000 0.007561 0.015122 0.030245 0.045367 0.015274
6000 0.00715 0.0143 0.0286 0.0429 0.014443
7000 0.006761 0.013523 0.027045 0.040568 0.013658
8000 0.006394 0.012787 0.025574 0.038362 0.012915
9000 0.006046 0.012092 0.024184 0.036276 0.012213
10000 0.005717 0.011434 0.022869 0.034303 0.011549
11000 0.005406 0.010813 0.021625 0.032438 0.010921
12000 0.005112 0.010225 0.020449 0.030674 0.010327
13000 0.004834 0.009669 0.019337 0.029006 0.009765
14000 0.004571 0.009143 0.018286 0.027429 0.009234
15000 0.004323 0.008646 0.017292 0.025937 0.008732
16000 0.004088 0.008176 0.016351 0.024527 0.008257
17000 0.003866 0.007731 0.015462 0.023193 0.007808
18000 0.003655 0.007311 0.014621 0.021932 0.007384
19000 0.003457 0.006913 0.013826 0.02074 0.006982
20000 0.003269 0.006537 0.013075 0.019612 0.006603
21000 0.003091 0.006182 0.012364 0.018545 0.006244
22000 0.002923 0.005846 0.011691 0.017537 0.005904
23000 0.002764 0.005528 0.011056 0.016583 0.005583
24000 0.002614 0.005227 0.010454 0.015682 0.005279
25000 0.002471 0.004943 0.009886 0.014829 0.004992
26000 0.002337 0.004674 0.009348 0.014023 0.004721
27000 0.00221 0.00442 0.00884 0.01326 0.004464
28000 0.00209 0.00418 0.008359 0.012539 0.004221
29000 0.001976 0.003952 0.007905 0.011857 0.003992
30000 0.001869 0.003738 0.007475 0.011213 0.003775
31000 0.001767 0.003534 0.007069 0.010603 0.00357
32000 0.001671 0.003342 0.006684 0.010026 0.003376
33000 0.00158 0.00316 0.006321 0.009481 0.003192
34000 0.001494 0.002989 0.005977 0.008966 0.003018
35000 0.001413 0.002826 0.005652 0.008478 0.002854
36000 0.001336 0.002672 0.005345 0.008017 0.002699
37000 0.001264 0.002527 0.005054 0.007581 0.002552
38000 0.001195 0.00239 0.004779 0.007169 0.002414
39000 0.00113 0.00226 0.004519 0.006779 0.002282
40000 0.001068 0.002137 0.004274 0.00641 0.002158
41000 0.00101 0.002021 0.004041 0.006062 0.002041
42000 0.000955 0.001911 0.003821 0.005732 0.00193
43000 0.000903 0.001807 0.003614 0.005421 0.001825
44000 0.000854 0.001709 0.003417 0.005126 0.001726
45000 0.000808 0.001616 0.003231 0.004847 0.001632
46000 0.000764 0.001528 0.003056 0.004583 0.001543
47000 0.000722 0.001445 0.00289 0.004334 0.001459
48000 0.000683 0.001366 0.002732 0.004099 0.00138
49000 0.000646 0.001292 0.002584 0.003876 0.001305
50000 0.000611 0.001222 0.002443 0.003665 0.001234
51000 0.000578 0.001155 0.00231 0.003466 0.001167
52000 0.000546 0.001092 0.002185 0.003277 0.001103
53000 0.000517 0.001033 0.002066 0.003099 0.001043
54000 0.000488 0.000977 0.001954 0.002931 0.000987

Experimento 1 Experimento 2 Experimento 3 Experimento 4 Experimento 5


[A] 0.01 0.02 0.04 0.06 0.2
[B] 0.2 0.2 0.2 0.2 0.0202
Velocidad -0.0006 -0.0011 -0.0023 -0.0034 -0.0012
Experimento 6 Experimento 7 Experimento 8
[B] (mol/L) [B] (mol/L) [B] (mol/L)
0.0404 0.0606 0.0808
Experimento 1
0.012
0.038203 0.057305 0.076406
0.036126 0.054189 0.072252 0.01
f(x) = 1.00176303E-09 x⁴ − 1.854652E-07 x³ + 1.4294565
0.034161 0.051242 0.068323 0.008 + 0.010541368
R² = 0.999993656684201
0.032304 0.048456 0.064608 0.006
0.030547 0.045821 0.061095

[A]
0.004
0.028886 0.043329 0.057773
0.002
0.027316 0.040973 0.054631
0.02583 0.038745 0.05166 0
0 00 00 00 00 00 00 00 00 00 00 00 00 00
0.024426 0.036639 0.048851
40 8 0 1 2 0 16 0 20 0 2 4 0 2 8 0 3 2 0 36 0 40 0 44 0 48 0 5 2 0
0.023098 0.034646 0.046195
0.021842 0.032762 0.043683 Tiempo
0.020654 0.030981 0.041308
0.019531 0.029296 0.039062
0.018469 0.027703 0.036938 Experimento 2
0.017465 0.026197 0.034929 0.025
0.016515 0.024772 0.03303
0.015617 0.023425 0.031234 0.02
f(x) = 1.999661E-09 x⁴ − 3.705192E-07 x³ + 2.857525E-05 x² − 0.001
0.014768 0.022152 0.029535 R² = 0.99999369175476
0.015
0.013965 0.020947 0.02792
0.013205 0.019808 0.026411 0.01
0.012487 0.018731 0.024975
0.011808 0.017712 0.023617 0.005
0.011166 0.016749 0.022332
0
0.010559 0.015838 0.021118
0 2 9 2 8 7 2 5 7 6 3 7 2 7 18 4 2 7 2 3 7 0 9 6 6 9 2
0.009985 0.014977 0.01997 0. 5 9 2 7 0 2 8 1 6 5 5 2 0 4 3 3 2 6 2 1 1 7 1 3 1 0
01 01 01 00 00 00 0.0 .00 .00 .00 .00 .00 .00
0.009442 0.014263 0.018884 0. 0 . 0 . 0. 0. 0. 0 0 0 0 0 0
0.008928 0.013393 0.017857
0.008443 0.012664 0.016886 Experimento 3
0.007984 0.011976 0.015968
0.045
0.00755 0.011325 0.0151 0.04
0.007139 0.010709 0.014278 0.035 f(x) = 4.003657E-09 x⁴ − 7.415241E-07 x³ + 5.716837E-05 x² − 0.00
R² = 0.999993724929107
0.006751 0.010127 0.013502 0.03
0.006384 0.009576 0.012768 0.025
0.006037 0.009055 0.012074 0.02
0.015
0.005709 0.008563 0.011417
0.01
0.005398 0.008097 0.010796 0.005
0.005105 0.007657 0.010209 0
0.004827 0.007241 0.009654 04 8 4 7 4 4 9 51 75 5 4 5 9 84 45 7 4 1 7 32 85
0. 1 9 5 5 0 4 6 3 3 0 0 4 8 3 6 6 5 3 4 2 3 4 2 7 2 1
0.004565 0.006847 0.009129 03 0 2 0 2 01 01 01 0 0 00 00 0 0 0 0 00 00
0. 0 . 0 . 0. 0. 0. 0 . 0. 0. 0. 0 . 0. 0.
0.004316 0.006475 0.008633
0.004082 0.006122 0.008163
0.00386 0.00579 0.007719 Experimento 4
0.07
0.06
f(x) = 6.004368E-09 x⁴ − 1.112146E-06 x³ + 8.574677E-05 x² − 0.003
0.05 R² = 0.999993728043621
0.04
Experimento 4
0.00365 0.005475 0.0073 0.07
0.003451 0.005177 0.006903 0.06
0.003264 0.004896 0.006527 f(x) = 6.004368E-09 x⁴ − 1.112146E-06 x³ + 8.574677E-05 x² − 0.003
0.05 R² = 0.999993728043621
0.003086 0.004629 0.006172
0.04
0.002918 0.004378 0.005837
0.03
0.00276 0.00414 0.005519
0.02
0.00261 0.003914 0.005219
0.002468 0.003702 0.004935 0.01
0.002334 0.0035 0.004667 0
0.002207 0.00331 0.004413 06 7 6 6 2 7 4 2 7 1 2 8 2 3 9 2 6 1 7 4 1 2 6 9 9 7 7
0. 7 9 8 3 0 6 4 5 9 6 5 6 2 5 0 0 8 0 0 6 5 1 4 0 3 2
0.002087 0.00313 0.004173 04 03 03 02 01 01 01 01 00 0.0 .00 .00 .00
0 . 0 . 0. 0. 0. 0. 0. 0. 0 . 0 0 0
0.001973 0.00296 0.003946

Experimento 6 Experimento 7 Experimento 8


0.2 0.2 0.2
0.0404 0.0606 0.0808
-0.0023 -0.0035 -0.0046
perimento 1 Experimento 5
0.025

− 1.854652E-07 x³ + 1.4294565E-05 x² − 0.000574348 x 0.02


f(x) = 2.021018E-09 x⁴ − 3.743916E-07 x³ + 2.886822E-05 x² − 0.001160146 x
+ 0.021293824
[A] (mol/L) 0.015 R² = 0.999993745452487
[B] (mol/L)
Polynomial ([A] (mol/L))
0.01 Polynomial ([B] (m
Polynomial ([A] (mol/L))

0.005

00 00 00 00 00 00
2 0 36 0 40 0 44 0 48 0 5 2 0 0
0 2 52 1 5 2 7 5 7 0 3 7 9 2 1 76 9 9 58 26 38 0 3
.02 1 61 12 9 1 03 08 2 06 6 052 04 2 0 33 02 6 0 21 0 17 001 01 1
0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 0. .0
0 0 0 0 0 0 0 0 0 0 0 0

perimento 2 Experimento 6
0.045
0.04
f(x) = 4.041405E-09 x⁴ − 7.486627E-07 x³ + 5.772905E-05 x² − 0.002320126 x
0.035 + 0.042586763
-07 x³ + 2.857525E-05 x² − 0.001148534 x + 0.021082394
0.03 R² = 0.999993713217423
[A] (mol/L) 0.025 [B] (mol/L)
Polynomial ([A] (mol/L)) 0.02 Polynomial ([B] (m
Polynomial ([A] (mol/L)) 0.015
0.01
0.005
0
2 72 3 7 0 9 66 92 0 4 0 4 83 5 4 1 5 0 5 5 9 4 3 5 1 9 8 1 6 5 1 7 6 0 7
26 21 1 7 13 10 .0 4 3 2 3 0 2 5 2 0 6 1 6 5 1 3 2 1 0 5 0 8 4 0 6 7 0 5 3 0 4 3 0 3 4 00 2 0 2 2
0 .0 0. .0 .0 .0 .0 .0 .0 .0 .0 .0 0. .0
00 .00 .00 .00 .00 0 0 0 0 0 0 0 0 0 0 0
0 0 0 0

perimento 3 Experimento 7
0.07
0.06
E-07 x³ + 5.716837E-05 x² − 0.00229731 x + 0.042165515 f(x) = 6.11083895E-09 x⁴ − 1.128415E-06 x³ + 8.677918E-05 x² − 0.003482135 x
0.05 + 0.063884533
R² = 0.999993002079081
0.04
[A] (mol/L) [B] (mol/L)
Polynomial ([A] (mol/L)) 0.03 Polynomial ([B] (m
0.02
0.01
0
4 45 7 4 1 7 32 85
53 42 3 4 27 21 0 6 5 6 4 5 8 1 7 2 0 8 3 8 6 4 2 7 9 7 7 5 7 7 14 31
00 .00 .00 .00 .00 .06 48 4 38 7 30 9 24 7 19 8 15 8 126 1 01 08 0 064 05 1 004 003
0 0 0 0 0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 0. 0.
0 0 0 0 0 0 0 0 0 0 0

perimento 4 Experimento 8
0.09
0.08
f(x) = 8.084543E-09 x⁴ − 1.497605E-06 x³ + 0.0001154725 x² − 0.004640519 x + 0.0851
-06 x³ + 8.574677E-05 x² − 0.003445878 x + 0.063248033 0.07 R² = 0.999993757732982
0.06
0.05
perimento 4 Experimento 8
0.09
0.08
f(x) = 8.084543E-09 x⁴ − 1.497605E-06 x³ + 0.0001154725 x² − 0.004640519 x + 0.0851
-06 x³ + 8.574677E-05 x² − 0.003445878 x + 0.063248033 0.07 R² = 0.999993757732982
0.06
0.05 [B] (mol/L)
[A] (mol/L)
0.04 Polynomial ([B] (m
Polynomial ([A] (mol/L))
0.03
0.02
0.01
0
6 1 7 41 26 99 77 0 8 0 8 66 0 8 03 1 1 1 8 8 6 0 2 9 6 3 3 0 3 1 9 1 3
8 0 0 6 51 40 32 .08 64 6 051 41 3 033 26 4 21 1 168 1 35 10 7 086 06 9 05 5 04 4
00 0.0 .00 .00 .00 0 .0 0. .0 0. .0 .0 .0 .0 .0 .0 .0 .0 .0
0 0 0 0 0 0 0 0 0 0 0
0 0 0
to 5

86822E-05 x² − 0.001160146 x

[B] (mol/L)
Polynomial ([B] (mol/L))

3 8 10 3
01
.0

to 6

72905E-05 x² − 0.002320126 x

[B] (mol/L)
Polynomial ([B] (mol/L))

6 7
2 7 2 20
00
0.

o7

677918E-05 x² − 0.003482135 x

[B] (mol/L)
Polynomial ([B] (mol/L))

14 3 31
00
0.

o8

54725 x² − 0.004640519 x + 0.08517452


o8

54725 x² − 0.004640519 x + 0.08517452

[B] (mol/L)
Polynomial ([B] (mol/L))

1 9 41 3
04
.0

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