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JEE-ADVANCED-2014-P2-Model
Time: 2.00 PM to 5.00 PM IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve
No.of
Section Question Type Mark Mar Total marks
Qs
s ks
Sec – I(Q.N : 1 – 10) Questions with Single Correct Choice 3 -1 10 30
Questions with Comprehension Type
Sec – II(Q.N : 11 – 16) (3 Comprehensions – 2 +2+2 = 6Q)
3 -1 6 18
Sec – III(Q.N : 17 – 20) Matrix Matching Type 3 -1 4 12
Total 20 60
CHEMISTRY:
+Ve
- Ve No.of
Section Question Type Mar Total marks
Marks Qs
ks
Sec – I(Q.N : 21 – 30) Questions with Single Correct Choice 3 -1 10 30
Questions with Comprehension Type
Sec – II(Q.N : 31 – 36) (3 Comprehensions – 2 +2+2 = 6Q)
3 -1 6 18
Total 20 60
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 41 – 50) Questions with Single Correct Choice 3 -1 10 30
Questions with Comprehension Type
Sec – II(Q.N : 51 – 56) (3 Comprehensions – 2 +2+2 = 6Q)
3 -1 6 18
Total 20 60
A) 4 B) 3 C) 2 D) 1
2. A solid horizontal surface is covered with a thin layer of oil. A rectangular block of mass
m 0.4 kg is at rest on this surface. An impulse of 1.0 Ns is applied to the block at time
t 0 so that it starts moving along the x axis with a velocity v t v0e t / , where v0 is a
constant and 4 s . The displacement of the block , in metres, at t is nearly
e 1
0.37
A) 6.30 m B) 4 m C) 16.3 m D) 14 m
3. A block of mass 2 kg is free to move along the x axis. It is at rest and from t 0 onwards
it is subjected to a time – dependent force F t in the x direction. The force F t varies
with time ' t ' as shown in the figure. The kinetic energy of the block after 4.5 seconds nearly
F t
4N
4.5s
t
O 3s
11. When the block has moved through distance ' x0 ' metre to the right, then the elastic potential
energy stored in the right spring is
2 x03 x02 x03 4
A) joule B) joule C) joule D) x03 joule
3 2 6 3
12. The distance covered (approximately) by the block before it comes to instantaneous rest for
the first time is
A) 3.5 m B) 2.5 m C) 4.0 m D) 1.75 m
Passage II :
Consider the situation shown in the figure. The system is released from rest and the block
‘A’ travels a distance 5 m in downward direction (take, g 10 m / s 2 ).
10 kg A
B 5kg
R P
300
Q R
O
x
15. The magnitude of the normal reaction that acts on the block at the point ‘Q’ is
A) 7.5 N B) 8.6 N C) 11.5 N D) 22.5 N
16. The speed of the block when it reaches the point ‘Q’ is
A) 5 ms 1 B) 10 ms 1 C) 10 3 ms 1 D) 20 ms 1
Section-3
(Matching List Type)
This section contains four questions, each having two matching lists (List-1 & List-II). The options for the correct match are provided as (A), (B),(C)
and (D) out of which ONLY ONE is correct.
17. A particle of unit mass is moving along the x axis under the influence of a force and its
total energy is conserved. Four possible forms of the potential energy of the particle are
given in column I ( a and U 0 constants). Match the potential energies (U) in column I to the
corresponding statement(s) in column II
Column-I Column-II
2 2
U0 x
A) U s 1 p) The force acting on the particle is zero at x a
2 a
2
U x
B) U x 0 q) The force acting on the particle is zero at x 0
2 a
2
U0 x x 2
C) U x exp r) The force acting on the particle is zero at x a
2 a a
3
U0 x 1 x The particle experiences an attractive force
D) U x s) towards x 0 in the region x a
2 a 3 a
U0
The particle with total energy
can
t) 4
oscillate about the point x a
A) A-q,r B-p,s C-r,s D-t B) A-p,q,r,t B-q,s C-p,q,r,s D-p,r,t
C) A-p,r B-q,s C-p,s D-p,t D) A-p,q B-s C-q,r D-p,r
18. Match the Column I with the information given in Column II and select the correct option
from the codes given below
Column-I Column-II
A particle is moving along x axis as Kinetic energy first decreases, then
A) such v 0 and a 0 at t 0 p)
x x Increases
During projectile motion of a particle
B) q) Kinetic energy remains constant
under gravity
A particle is moving on a circular path
Kinetic energy Continuously
C) in the condition of a uniform circular r)
decreases during motion
motion.
A car is moving with a uniform Kinetic energy increases
D) s)
deceleration continuously during motion
A) A-p; B-p; C-q; D-r B) A-s; B-r; C-q; D-p
C) A-p,q; B-p,q; C-s; D-q D) A-p; B-q; C-r; D-s
19. Two balls of masses m1 and m2 are moving towards each other with speed u1 and u2 . They
collide head on and their speeds are v1 and v2 after collision m1 8 kg , m2 2 kg , u2 3 m / s
Column-I Column-II
The speed u1 in m / s so that both balls move in same 1
A) p)
direction if coefficient of restitution 0.5 is 4
The speed u1 in m / s so that maximum energy is transferred 1
B) q)
to m2 (assume elastic collision) 8
Co – efficient of restitution if m2 stops after collision and
C) r) 2
u1 0.5 m / s
If collision is perfectly inelastic and u1 3 m / s the loss of
D) s) 4
kinetic energy of System is (in J)
t) 28.8
A) A-s; B-q; C-p; D-t B) A-rs; B-r; C-p; D-t
C) A-r; B-t; C-p; D-q,s D) A-q; B-p; C-r,s; D-r,r
20. A block of mass ‘m’ is stationary with respect to a rough wedge as shown in figure.
Starting from rest in time ‘t’, m 1kg , 300 , a 2 ms 2 , t 4sec . For work done on the
Column-I Column-II
A) By gravity p) 144 J
B) By normal reaction q) 32 J
C) By friction r) 48 J
25. In SO32
A) d p bond between S and O is delocalised
B) Bonds between S and O are equivalents
C) There is sp3 hybridized sulphur atom
D) All of the facts given above are true
26. Mark the correct order of increasing reactivity:
A) CH 3CONH 2 CH 3COOC2 H 5 CH 3COCl
B) CH 3COOC2 H 5 CH 3COCl CH 3CONH 2
C) CH 3COCl CH 3CONH 2 CH 3COOC2 H 5
D) CH 3COOC2 H 5 CH 3CONH 2 CH 3COCl
27.
A is
Sec : BT-1_Sr.Chaina-II_Sr.C-IPL_Sr.IPL-IC Space for Rough Work Page 9
Sri Chaitanya IIT Academy, India 01-12-19_ Sr.Chaina-II_Sr.C-IPL_Sr.IPL-IC_BT-1_Jee-Adv(2014-P2)_RPTA-12_Q.P
A) B)
HOOC OH
C-
C) D)
28. Which of the following is the best method for the synthesis of ester Me3C COOMe ?
A) Me3C COCl MeOH B) Me3C COOH MeOH
C) Me3C COOH CH 2 N 2 D) Me3C COCl MeONa
29.
Cl
MeO
B
O
Product B is:
COOH COOMe
COOH COOMe
A) B) C) D)
30. When propionic acid is treated with aqueous sodium bicarbonate, CO2 is liberated. The C of
CO2 comes from:
A) Methyl group B) Carboxylic acid group
C) Methylene group D) Bicarbonate group
Passage II:
NH 4 NO3 ' P ' H 2O
H
NaNO2 FeSO4 'Q '
250 K
Q S ' R '
Pb NO3 2
673 K
'S '
HNO3 P4O10 'U ' ( P, Q, R, S ,U are nitrogen compounds)
Sec : BT-1_Sr.Chaina-II_Sr.C-IPL_Sr.IPL-IC Space for Rough Work Page 11
Sri Chaitanya IIT Academy, India 01-12-19_ Sr.Chaina-II_Sr.C-IPL_Sr.IPL-IC_BT-1_Jee-Adv(2014-P2)_RPTA-12_Q.P
33. Which of the following is correct regarding P, Q, S ,U
P Q S U
A) N 2O NO NO2 N 2O5
B) N 2O NO N 2O5 NO2
C) NO N 2O N 2O3 N 2O5
D) N 2O NO NO2 N 2O4
34. The correct order of acidic strength
A) U Q P R B) U Q R S C) U S R P D) U S R P
Passage II:
Consider the following sequence of reaction. If A is H 2 SO4 , then given the answer of
following Questions.
O O
B) EtOH CH3 COCCH3 H
q) Acetylation reaction
A) 2 B) 4 5 C) 3 D) 4 5
45. If , , are such that 2, 2 2 2 6, 3 3 3 8, then 4 4 4 is
A) 5 B) 18 C) 12 D) 36
1 1
46. Let H n 1 ...... , then the sum to n terms of the series
2 n
1 1 2 1 2 32
2 2 2 2 2
...... is
13 13 23 13 23 33
4 4 1 4 4 2 n
A) H n 1 B) H n C) H n D) H n
3 3 n 3 3 3 n 1
47. If the ratio of sums to n terms of two A.P’s is 5n 3 : 3n 4 , then the ratio of their 17th
terms is
A) 172 : 99 B) 168 :103 C) 175 : 99 D) 171:103
B) q) 8
C) 2 2 2 r) -2
D) 3 3 3 s) -1
Column-I Column-II
2n 2n xy 2
A) sin
n0
cos p)
xy 2 1
2n y
B) tan
n 0
q)
x y
2n xy
C) sin cos 4 n r)
n0 xy 1
2n 4n x2 y
D) cos
n0
sin s)
x2 y 1