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Gloss is an optical phenomenon observed when The third option is to develop a resin which is
examining the appearance of a surface. The inherently high gloss, and achieving the desired
evaluation of gloss is equal to the capability of a appearance right out of the mold. To develop an
surface to reflect directed light. Gloss is often used as inherently high gloss resin, it is important to develop
a criterion to evaluate appearance applications, a smooth surface to increase the reflection from the
especially in the case of aesthetic products such as surface, figure 4. This option is used when tool
appliances in which the OEMs requires high gloss, modifications or processing conditions do not permit
but in the case the automotive industry, the low gloss achieving the gloss level, or the application
appearance is the trend. Measuring instruments, requirements are not meet. New engineering resins
figure 1, have been used to associate reflection have been developed which improve the current level
behavior and to define measurement values under of gloss in commercial applications.
certain conditions. A visual gloss examination
includes many subjective sources of error and is not MATERIAL
sufficient when making comparisons in order to select
the best material or process for a specific part. An experimental grade of polyester blend with high
Therefore, to be objective, it is necessary to put a gloss was selected throughout the study. It is a 15%
measured value on the amount of gloss. glass-filled polyester blend (PBT/PET) featuring high
surface gloss and high flow for long flow channels.
The measurement of the reflectometer is a relative The formulation of this grade is proprietary.
measurement compared to a highly polished black
glass with a refractive index of 1.567. The glass has The challenges in a polyester blend for a gas assist
an assigned specular gloss of 100 for each injection molding process are to develop a high gloss
illumination angle considered: 20°, 60° or 85°. Since material with no increase in cycle time, it is colorable
instrument and standard tolerances are tightly in different colors, maintains a good balance of
controlled, the measurement error should not be more mechanical properties, high flow in order to fill 760
than +/- 1 unit. mm with one gate, and all at a reasonable raw
material cost.
HOW TO GET HIGH GLOSS
In order to have a high gloss, the PET in the polyester
There are typically three ways to achieve a high gloss blend reaches the surface quicker than the PBT and it
appearance: (1) modify the surface of the mold to provides the best surface appearance. The formulation
high gloss, (2) modify processing parameters to contains a color package for high gloss. A hot mold
increase gloss, or (3) develop a material which is temperature is necessary for high gloss and best
inherently high gloss right out of the mold. appearance, and for crystallizing the PET.
The tool surface can be polished to achieve a high For polyester blend, an inherently high gloss resin can
gloss finish on the steel which is transferred to the be formulated to achieve gloss values of 90 to 100
plastic during molding, figure 2. Sometimes relying right out of the mold in the conventional injection
strictly on mold texture is generally ineffective and molding. The new formulation is colorable and
costly (tool maintenance) to meet the high gloss maintains excellent indoor UV stability, scratch
requirements, but it is important in order to get the resistance, stain resistance, mechanical strength for
desired gloss. bearing weight and creep resistance, and chemical
resistance to detergents, cleaners and chemicals.
EQUIPMENT AND PROCESS to measure gloss levels on the samples. A sample size
of five parts was taken for each color studied and the
The rod-shaped part was produced in a mold of two average of each was used for the results.
cavities with a combination of hot runner and cold
runner systems. Figure 5 shows the molded part, the EXPERIMENTAL RESULTS
front “show side” is smooth. The back side has
“bumps” or grip features. The front side must look Due to the shape of the grips on the backside of the
glossy for best appearance. Figure 6 shows the cross part, it was a difficult to measure that area, so only
sections of the part. The cavities are highly polished the gloss level of the front “show side” is reported.
(SPI-A2 as minimum) in stainless steel, preferably for The gloss level was 86.7% on the “show side” of the
best appearance. The part is 760 mm long, and the part. The gloss value was very close to the
cavity is filled with one gate and one gas pin. Gas conventional injection molding parts with a gloss
assisted injection molding experiments were level from 90 to 100%. The parts injected with
conducted with a 350 ton clamping force. The current commercial grades have a gloss level of 55%.
injection molding machine was utilized in The gas assisted parts replicated the surface of the
conjunction with a gas injection control unit where mold.
the gas and polymer entered the mold at separate
locations. The mold cavities were cleaned and CONCLUSIONS
polished very well before starting up.
On rod-shaped parts, the gloss level was very close to
The processing conditions for the polyester blend the conventional injection molding parts when a high
followed the recommended material guidelines, but gloss polyester blend is used, and it is better than
during the material trials, some parameters were current commercial grades injected into the same
adjusted for the new polyester blend. The drying mold at the same processing conditions.
temperature was increased from 121 to 135°C in
REFERENCES
order to have a moisture level below 0.01%, required
for the PET in the polyester blend. A high surface
[1]Paul Dier, Richard Goralsky, Gass Assist Injection
mold temperature of 128°C was required for best
Molding, Bauer, 2000, USA.
appearance and to crystallize the material. The
A side, or stationary side of the mold, was hotter
[2]Hansen, Michael, “Application Examples for Gas-
because it is the show side of the part versus the
Assisted Injection Molded Parts”, Journal of Injection
moving side. The material required high melt
Molding Technology, V0l.3, No.3, September 1999.
temperature of 270°C for covering the fiberglass on
the surfaces of the parts. The temperatures of the hot
[3]http://machinedesign.com/article/gas-assist-
runner system were setup slightly lower than the melt
molding-not-just-for-hollow-parts-0809 (2010).
temperature. In the case of temperatures, the goal was
to find a balance between appearance, cycle time, and
[4]http://kiindustries.thomasnet.com/item/all-
avoiding ejector pin push on the part because the
categories/injection-molding/item-1003?&forward=1
material was too soft coming out of the mold, figure
7. At times, the gas pin got dirty and clogged with
[5]Cooper, C., Experimental Studies in Gas-Assist
material and the gas could not vent out of the part and
Injection Molding to Investigate Residual Wall
the parts ruptured or “popped” when the mold
Thickness and Gloss Levels, SPE Technical paper,
opened. This gas assist process was also optimized in
2005.
order to produce the highest quality part, by
minimizing the cycle time and avoiding pin push. The
gas pressure was 85bar and the hold pressure in
conventional injection molding was 950bar.