UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO

FACULTAD DE ESTUDIOS SUPERIORES ZARAGOZA

Tarea:

Tarea: Propiedades Reducidas.

Alumnos:

Materia: Termodinámica quı́mica

Profesor:

Coeficientes viriales
Forma generalizada
Z = Z 0 + ωZ 1 Se usan tablas Lee-Kessler

Usando segundo coeficiente virial

BP
Z = 1+
RT
BPC
B̂ =
RTC
B T P
= B̂ C → Z = 1 + B̂ r
R PC Tr

B̂ = B0 + ωB1
83 211
Para Abbot B0 = 1000 − 8
500 Tr 5
139 43
Para Abbot B1 = 1000 − 21
250 Tr 5

289 277 121 33

Para Pitzer Carl B0 = − − − 100
2000 2000 Tr2 10000 Tr3 Tr

139 43
Para Pitzer Carl B1 = 1000 − 21
250 Tr 5

289 277 121 5598586826370849 33

Para Tsonopolus B0 = − − − − 100
2000 2000 Tr2 10000 Tr3 9223372036854775808 Tr8 Tr

331 423 1 637

Para Tsonopolus B1 = − − + 10000
1000 Tr2 1000 Tr3 125 Tr8

1
Usando tercer coeficiente virial
BP CP 2
Z = 1+ + 2 2
RT R T
BPC B T
B̂ = ; = B̂ C
RTC R PC

CPC2 C TC2
Ĉ = 2
; = Ĉ
R2 TC R2 PC2

Pr P2
Z = 1 + B̂ + Ĉ r2
Tr Tr
B̂ = B0 + ωB1 ; mismos que para el segundo coeficiente (Abbot, Pitzer-Carl, Tsonopolus).
Ĉ = C 0 + ωC 1
76 313 1407
C0 = 14 − 21 + 100000
3125 Tr 5 100000 Tr 2

1 3 177 57 669
C1 = − + − − 25000
25 Tr3 1000 Tr6 10000 Tr
14
5 25000 Tr
21
2

Problema
Calcular el volumen molar del n-butano a 120°C con una presión de saturación de 22.38 Bar mediante la
correlación de Pitzer-Carl para el factor de compresibilidad

Programa MATLAB

% f a c t o r de c o m p r e s i b i l i d a d
Tc=425.2; %K
Pc = 3 7 . 5 ; %atm
T=120+273.15;
P=22.38/1.01325; %atm
Pr=P/ Pc ;
Tr=T/Tc ;
R=0.08205; %atm L/K gmol
omega = 0 . 1 9 3 ;
% PV=RT
V i d e a l =(R*T ) / P ;
f p r i n t f ( ’ V− i d e a l = %.6 f L/gmol \n ’ , V i d e a l )
% Primer c o e f i c i e n t e v i r i a l
% Z=(P*V ) / ( R*T ) ;
Z 0 P i t z e r =0.5753263; % % % Tablas l e e k e s l e r
Z 1 P i t z e r=−0.14007229; % % % % % Tablas l e e k e s l e r
Z P i t z e r=Z 0 P i t z e r+omega * Z 1 P i t z e r ;
V 1 P i t z e r =( Z P i t z e r *R*T ) / ( P ) ;
f p r i n t f ( ’ Z−1− v i r i a l −Lee / K e s s l e r= %.6 f \n ’ , Z P i t z e r )
f p r i n t f ( ’ V−1− v i r i a l −Lee / K e s s l e r= %.6 f L/gmol \n ’ , V 1 P i t z e r )

% % % % %Segundo c o e f i c i e n t e v i r i a l
B0abbot = 0. 08 3 −( 0. 4 22 / ( Tr ˆ 1 . 6 ) ) ;
B1abbot = 0. 13 9 −( 0. 1 72 / ( Tr ˆ 4 . 2 ) ) ;
%%%%%%
B 0 p i t z e r c a r l =0.1445 −(0.33/ Tr ) − ( 0 . 1 3 8 5 / Tr ˆ 2 ) − ( 0 . 0 1 2 1 / Tr ˆ 3 ) ;
B 1 p i t z e r c a r l =0.075+(0.46/ Tr ) − ( 0 . 5 / Tr ˆ 2 ) − ( 0 . 0 9 7 / Tr ˆ 3 ) − ( 0 . 0 0 7 3 / Tr ˆ 8 ) ;
%%%%%

2
 B0tsono =0.1445 −(0.33/ Tr ) − ( 0 . 1 3 8 5 / Tr ˆ 2 ) − ( 0 . 0 1 2 1 / Tr ˆ 3 ) − ( 0 . 0 0 0 6 0 7 / Tr ˆ 8 ) ;
B1tsono =0.0637+(0.331/ Tr ˆ 2 ) − ( 0 . 4 2 3 / Tr ˆ 3 ) − ( 0 . 0 0 8 / Tr ˆ 8 ) ;
%%%%%%
%f p r i n t f ( ’ B0abbot= %.6 f \n ’ , B0abbot )
%f p r i n t f ( ’ B1abbot= %.6 f \n ’ , B1abbot )
%f p r i n t f ( ’ B 0 p i t z e r c a r l = %.6 f \n ’ , B 0 p i t z e r c a r l )
%f p r i n t f ( ’ B 1 p i t z e r c a r l = %.6 f \n ’ , B 1 p i t z e r c a r l )
%f p r i n t f ( ’ B0tsono= %.6 f \n ’ , B0tsono )
%f p r i n t f ( ’ B1tsono= %.6 f \n ’ , B1tsono )
%%%%%%%
Zabbot=1+B0abbot * ( Pr / Tr )+omega * B1abbot * ( Pr / Tr ) ;
f p r i n t f ( ’ Z−2−abbot= %.6 f \n ’ , Zabbot )
Z p i t z e r c a r l =1+ B 0 p i t z e r c a r l * ( Pr / Tr )+omega * B 1 p i t z e r c a r l * ( Pr / Tr ) ;
f p r i n t f ( ’ Z−2− p i t z e r c a r l = %.6 f \n ’ , Z p i t z e r c a r l )
Ztsono=1+B0tsono * ( Pr / Tr )+omega * B1tsono * ( Pr / Tr ) ;
f p r i n t f ( ’ Z−2− tsono= %.6 f \n ’ , Ztsono )
%%%%%%%
Vabbot =(R* Zabbot *T ) / P ;
f p r i n t f ( ’ V−2− v i r i a l −abbot= %.6 f L/gmol \n ’ , Vabbot )
V p i t z e r c a r l =(R* Z p i t z e r c a r l *T ) / P ;
f p r i n t f ( ’ V−2− v i r i a l − p i t z e r c a r l = %.6 f L/gmol \n ’ , V p i t z e r c a r l )
Vtsono =(R* Ztsono *T ) / P ;
f p r i n t f ( ’ V−2− v i r i a l −tsono= %.6 f L/gmol \n ’ , Vtsono )
%%%%%%%
% Tercer c o e f i c i e n t e v i r i a l .
C 0 p i t z e r =0.01407+(0.02432/( Tr ˆ 2 . 8 ) ) − ( 0 . 0 0 3 1 3 / ( Tr ˆ 1 0 . 5 ) ) ;
C 1 p i t z e r = −0.02676+(0.01770/( Tr ˆ 2 . 8 ) ) + ( 0 . 0 4 / ( Tr ˆ 3 ) ) − ( 0 . 0 0 3 / ( Tr ˆ 6 ) ) − . . .
( 0 . 0 0 2 2 8 / ( Tr ˆ 1 0 . 5 ) ) ;
C p i t z e r=C 0 p i t z e r+omega * C 1 p i t z e r ;
Z3abbot=1+B0abbot * ( Pr / Tr )+omega * B1abbot * ( Pr / Tr )+ C p i t z e r * ( ( Pr / Tr ) ˆ 2 ) ;
f p r i n t f ( ’ Z−3− v i r i a l −abbot − P i t z e r = %.6 f \n ’ , Zabbot )
Z 3 p i t z e r c a r l =1+ B 0 p i t z e r c a r l * ( Pr / Tr )+omega * B 1 p i t z e r c a r l * ( Pr / Tr ) . . .
+C p i t z e r * ( ( Pr / Tr ) ˆ 2 ) ;
f p r i n t f ( ’ Z−3− v i r i a l − p i t z e r c a r l − P i t z e r = %.6 f \n ’ , Z p i t z e r c a r l )
Z3tsono=1+B0tsono * ( Pr / Tr )+omega * B1tsono * ( Pr / Tr ) . . .
+C p i t z e r * ( ( Pr / Tr ) ˆ 2 ) ;
f p r i n t f ( ’ Z−3− v i r i a l −tsono − P i t z e r = %.6 f \n ’ , Ztsono )
%%%%%%%
V3abbot =(R* Z3abbot *T ) / P ;
f p r i n t f ( ’ V−3− v i r i a l −abbot= %.6 f L/gmol \n ’ , V3abbot )
V 3 p i t z e r c a r l =(R* Z 3 p i t z e r c a r l *T ) / P ;
f p r i n t f ( ’ V−3− v i r i a l − p i t z e r c a r l = %.6 f L/gmol \n ’ , V 3 p i t z e r c a r l )
V3tsono =(R* Z3tsono *T ) / P ;
f p r i n t f ( ’ V−3− v i r i r a l −tsono= %.6 f L/gmol \n ’ , V3tsono )

Resultados para Pitzer-Carl

Z Ideal 1
Z-1-virial-Lee/Kessler 0.548292
Z-2-pitzercarl 0.733466
Z-3-virial-pitzercarl-Pitzer 0.733466
V-ideal 1.460473 L/gmol
V-1-virial-Lee/Kessler 0.800766 L/gmol
V-2-virial-pitzercarl 1.071207 L/gmol
V-3-virial-pitzercarl 1.097376 L/gmol