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Table 2.

Parameters and statistical estimation of kinetic models

Catalyst Tempe- Methanol Parameters of kinetic models Statistical estimation of kinetic models
rature -to-oil
molar
ratio
Eq(2) Eq (3) Eq(2) Eq (3) F-test
MRP
Type Amount β k (kmt,A)0*104 α ka K cC 0 R2 MRPD R2 F F0.05
D
3
%(w/w) °C - min-1 min-1 - dm6/(mol2min) mol/dm3 mol/dm - % - % - -
CaO 1.0 60 6:1 1.0 0.067 20 0.063 5.591
3.480 1.630 0.00004 0.990 ±11.5 0.991 ±11.7 0.17
0 0
2.5 12 5.591
10.600 3.275 0.063 0.991 ±11.7 0.989 ±5.1 21.70
0
5.0 20.750 80 5.694 0.039 0.991 ±10.0 0.998 ±4.1 -5.87 5.318
10.0 20.800 78 8.787 0.165 0.992 ±19.2 0.989 ±5.3 2.99 5.987
Quicklimeb 1.0 60 6:1 1.0 0.042 20 0.043 5.117
6.219 1.151 0,001 0.975 ±15.2 0.991 ±6.7 -7.24
0 0
2.5 12 5.318
10.331 1.606 0,002 0.927 ±16.0 0.989 ±5.9 -7.50
0
5.0 18.993 80 3.020 0,002 0.958 ±16.2 0.988 ±6.5 -5.09 5.987
10.0 19.474 78 6.050 0,002 0.989 ±10.5 0.977 ±6.5 -0.53 5.591
1.0 12:1 0.047 20 0.047 5.318
6.219 1.153 0,0003 0.977 ±17.4 0.930 ±8.0 -6.83
0
2.5 12 5.987
9.183 1.808 0,002 0.933 ±34.0 0.941 ±12.0 -5.76
0
5.0 13.718 80 3.020 0,002 0.938 ±25.8 0.983 ±4.8 -4.78 5.987
10.0 14.065 78 6.050 0,002 0.903 ±28.6 0.993 ±3.9 -5.75 5.987
1.0 18:1 0.048 20 0.048 5.591
4.523 1.414 0,0006 0.969 ±15.3 0.944 ±5.2 -6.06
0
2.5 12 5.591
10.331 1.808 0,002 0.988 ±9.6 0.984 ±5.3 2.36
0
5.0 13.717 80 2.915 0,002 0.954 ±33.3 0.971 ±11.4 -4.59 5.318
10.0 14.892 78 6.050 0,002 0.929 ±18.9 0.987 ±10.2 -4.58 6.608
Ca(OH)2 1.0 60 6:1 1.0 21 4.965
0.021 1.440 0.539 0.979 ±17.8 0.997 ±32.5 -8.45
0 3 0.025 0.055
2.5 17 5.318
0.042 5.100 1.825 0.998 ±5.5 0.996 ±13.8 14.00
7 0.039 0.134
5.0 0.064 10.200 95 0.061 3.780 0.041 0.996 ±11.1 0.998 ±12.7 -3.14 5.591

1
10.0 0.077 10.200 95 0.075 8.488 0.014 0.995 ±15.8 0.991 ±18.9 7.44 5.987
. c
CaO ZnO 2.0 60 10:1 1.3 37 5.591
0.043 2.100 3.414 0.022 0.960 ±21.7 0.982 ±12.4 -3.58
7 8 0.043
70 1.7 16 4.965
0.051 24.400 2.350 0.093 0.989 ±11.4 0.986 ±10.0 4.74
5 7 0.057
84 1.2 19 6.608
0.083 28.500 3.104 0.511 0.992 ±2.8 0.994 ±3.3 -0.46
7 2 0.083
96 2.9 21 7.709
0.120 326.000 3.398 1.101 0.994 ±1.8 0.997 ±1.6 -1.89
0 5 0.120
a
Values calculated from Eq (4). b Values of parameters of Eq. 3 were taken from Miladinović et al. (2013). c Values of parameters of Eq. 2 were taken from Lukić et al. (2013a).

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