PROBLEM 1 (30%) Consider a well-insulated piston-cylinder assembly that contains 12 kg of water vapor, initially at 540°C and 6 MPa. It undergoes a reversible expansion at 2 MPa, The surroundings are at 0.1 MPa and 25°C. Answer the following questions (a) What is the entropy change (AS,,,,,, AS,,,..A5,,.) for this system? (5%) (b) What is the final temperature of the water? (5%) (c) What is the value of work in kJ for this process? (5%) (d) What is the final volume of the system? (5%) (e) What is the temperature of the water if the efficiency of the process was 70%? (10%) PROBLEM 2 (30%) ‘A steam power plant operates on the Rankine cycle according to the specified conditions below. Using stream numbering from Figure below (reproduce this Figure with your solution), determine: (a) The work output of the turbine per kg of steam (10%) (b) The heat output required in condenser (5%) and the heat input in the boiler/superheater (5%) (c) The entropy generated in the cycle assuming that Ty = Ts (10%) Hot Side, Qjy $_ - Beiter 3 (Csuperheater r W, res turbine! Pump Condenser) Cold Side, Oc TCC) PsMPa) | Pa(MPa) Newrtine Nowe 500 T 0.01 0.75 0.70PROBLEM 3 (40%) (a). Propane at 350°C and 600 cm*/mol is expanded isentropically in a turbine The exit pressure is 0.1 MPa. What is the pressure at the entry (5%)? What is the exit temperature (15%)? The PVT behavior of the gas follows the van der Waals equation of state Given: C,/R=8.85 and C,/R=7.85) (b) For the process above a relevant quantity is (=r or), Develop an expression for this quantity in terms of measurable variables by using the van der Waals equation of state (15%), Calculate its value at the entry (5%). Note: You can solve part (b) without solving part (a)