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Important Instructions:
1. Immediately fill in the particulars on this page of the Test Booklet with Blue / Black Ball Point Pen. Use of pencil is
strictly prohibited.
2. The Answer Sheet is kept inside this Test Booklet. When you are directed to open the Test Booklet, take out the
Answer Sheet and fill in the particulars carefully.
4. The Test Booklet consists of 90 questions. The maximum marks are 360.
5. There are three parts in the question paper A, B, C consisting of Physics, Chemistry and Mathematics having
30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for correct response.
7. There is only one correct response for each question. Filling up more than one response in any question will be
treated as wrong response and marks for wrong response will be deducted accordingly as per instruction 6 above.
8. Use Blue / Black Ball Point Pen only for writing particulars / marking responses on Side-1 and Side-2 of the
Answer Sheet. Use of pencil is strictly prohibited.
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electronic device, etc. except the Admit Card inside the examination hall / room.
10. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the Room /
Hall. However, the candidates are allowed to take away this Test Booklet with them.
11. Do not fold or make any stray marks on the Answer Sheet.
Atomic No.: H=1, He=2, Li=3, Be=4, B=5, C=6, N=7, O=8, F=9, Na=11, Mg=12, Al = 13, Si = 14,
P = 15, S = 16, Cl = 17, Ar =18, K=19, Ca=20,Cr=24, Mn=25, Fe=26, Co=27, Ni=28, Cu=29, Zn=30,
As=33, Br = 35, Ag = 47, Si = 21, Sn = 50, Ti = 22,I = 53, Xe = 54, Ba = 56, Pb = 82, U = 92, V = 50.
Atomic masses: H =1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16, F=19, Na=23, Mg=24, Al=27,
Si=28, P=31, S=32, Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59, Ni=58.7, Cu=63.5,
Zn = 65.4, As = 75, Br = 80, Ag = 108, Sn = 118.7, I = 127, Xe = 131, Ba = 137, Pb = 207, U = 238.
This part contains 30 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.
1. In the shown figure the linear mass density of the rod is and
dimension are shown in figure. The moment of inertia about
the dashed axis is
4 3
(A)
3
8 3
(B)
3
10 3
(C)
3
3
(D) 4
2. A screw gauge gives the following reading when used to measure the diameter of a wire.
Main scale reading : 2mm
Circular scale reading : 26 divisions
Given that 1mm on main scale corresponds to 100 divisions of the circular scale. The diameter of wire
from the above data is
(A) 2.026 mm (B) 2.26 mm
(C) 2.013 mm (D) 1.26 mm
3. A particle moves along an arbitrary path. If v and a are the instantaneous velocity and acceleration
vectors of the particle, then the ratio of magnitude of tangential and centripetal acceleration is
|a v| |a v|
(A) (B)
|a v| |a v|
dv / dt
(C) (D) None of these
dlv / dt
6. A parallel beam of light of all wavelengths greater than 3000 falls on a double slit in a Young's
double slit experiment. It is observed that the wavelengths 3600 and 6000 are absent at a
distance of 31.5 mm from the position of the central maximum, and the orders of the interference at
this point for the two wavelengths differ by 7. If the distance between the slits and the screen is 1m,
the separation between the two slits is
(A) 0.08 mm (B) 0.13 mm
(C) 0.2mm (D) 0.1mm
7. A particle A having charge q is placed at a distance d from another particle B having an equal charge
q. An dielectric slab of thickness t is placed midway between the two. Electrostatic force on A due
to B
(A) decreases
(B) increases
(C) remains constant
(D) may increase or decrease depending upon the magnitudes of the charges
( )
K
(A) (B)
V V
O t O t
(C) (D)
V V
O t O t
a2 a2 O A(a, 0, 0) x
(B) I
4 2
(C) I a2 a2
a2
(D) I a2 .
2
10. A surface irradiated with light of wavelength 480 nm gives out electrons with maximum velocity m/s,
the cut off wavelength being 600 nm. The same surface would release electrons with maximum
velocity 2 m/s if it irradiated by light of wavelength
(A) 300 nm (B) 360 nm
(C) 384 nm (D) 400 nm
11. When two moles of monoatomic gas expands isobarically, the ratio of the increase in the internal
energy of the gas and work done in the expansion is
(A) (B) 0
(C) 3/2 (D) 2/3
12. In the LCR circuit, the voltmeter and ammeter readings are 400V 400V
(A) 200 volt, 20A (B) 200 volt, 50A V
(C) 1000 volt, 20A (D) 1000 volt, 20A
C
50 L
A 1000V, 50 Hz
~
13. A wave y1 A sin 2x 4t is superposed with a second waveform producing a standing wave
3
with a node at x = 0. In the equation of the waveform, x is in metre and t is in second. The equation of
the second waveform is
(A) y2 Asin 4t 2x /3 (B) y 2 A sin(2x 4t 5 / 3)
(C) y2 A sin(2x 4t 5 / 3) (D) y 2 Asin( 2x 4t / 3) .
14. Two identical vessels A and B contains one mole of O 2 each. The pressure in the vessel A is P 0 and
that in B is P. The root mean square velocity of the molecules in both the vessels are equal. The
vessel A is at rest whereas vessel B is moving with constant speed v 0
1 mole of O 2 at v0 1 mole of O2 at
pressure P0 pressure P
Vessel A Vessel B
Which of the following is correct?
(A) P > P0 (B) P < P0
2
Vrms v 02
(C) P = P0 (D) P = P0 2
v rms
16. The object lens of a compound microscope produces magnification of 10. In order to get an overall
magnification of 100 when image is formed at 25 cm from the eye, the focal length of the eye lens
should be
(A) 4 cm (B) 10 cm
25
(C) cm (D) 9 cm
9
17. A sphere of mass m is kept between to inclined walls, as shown in the (2)
figure, If the coefficient of friction between each wall and the sphere is B
zero then the ratio of normal reaction (N 1 / N2) offered by the walls 1 and
2 on the sphere will be : A (1)
(A) tan (B) tan 2
(C) 2 cos (D) cos 2
18. A block M slide down on a curved frictionless vertical track, starting from rest. x
2
x
the curve obeys the equation y . the tangential acceleration of block as track
2
a function of x is :
gx
(A) g (B)
y
x2 4
g gx
(C) (D)
2 x2 1
19. The net power of all the forces acting on a particle versus time curve is shown. P
Work done upon the particle from A to B: A B
(A) increases (B) decreases
(C) firs increases then decreases (D) firs decreases then increases
x4 x2
20. The potential energy of a 1 kg particle free to move along the x axis is given by : V x J
4 2
The total mechanical energy of the particle is 2 J. Then, the maximum speed (in m/s) is :
3
(A) (B) 3 2
2
9
(C) (D) 2
2
22. A rigid equilateral triangular plate ABC of slide 2m, is motion in the x y Y
plane. At the instant shown in the figure, the point B has velocity
vB 3i 8i m / s and the plate has angular velocity 2k r/s. Find the X
speed of point A. A B
(A) 5 m/s (B) 4 m/s 2m
(C) 3 m/s (D) None of these
23. In a certain oscillatory system the amplitude of motion is 5 m and the time period is 4 sec. the time
taken by the particle for passing between points, which are at distances of 4 m, and 3 m from the
centre and on the same side of it will be
(A) 0.2 sec (B) 0.51 sec
(C) 0.17 sec (D) None of these.
24. A U-tube of base length and uniform cross sectional area is filled with
two liquids of equal volume and densities & 2 respectively. It is
moving with an acceleration a on the horizontal plane. If the height
difference between the two surfaces (open to atmosphere) becomes h a
zero, then the height h is
a 3a
(A) (B)
2g 2g
a 2a
(C) (D)
g 3g
26. A metal wire PQ slides on parallel metallic rails having separation 0.25 P
m, each having negligible resistance. There is a 2 resistor and 10 V 10 V
battery as shown in figure. There is a uniform magnetic field directed into 0.25 m
2
the plane of the paper of magnitude 0.5T. A force of 0.5 N to the left is
required to keep the slide wire PQ moving with constant speed to the
right. With what speed is the wire PQ moving? Q
(A) 14 m/s (B) 16 m/s
(C) 18 m/s (D) 20 m/s
28. Two seconds after projection a particle is traveling in a direction inclined at 30 to the horizontal, after
2
one more second it is traveling horizontally. (Take g = 10 m/s ), then
(A) speed of projection is 25 m/s (B) angle of projection is = 60
(C) speed after 2 sec is 10 m/s (D) maximum height reached is 10 m
29. A meteor of mass M breaks up into two parts. The mass of one part is m. For a given separation r the
mutual gravitational force between the two parts will be maximum if
(A) m = (M/2) (B) m = (M/3)
M M
(C) m = (D) m
2 2 2
30. The minimum and maximum magnitude which is possible by adding four forces of magnitudes 1N,
3N, 9N and 10N is
(A) 0 and 23 N (B) 1N and 23 N
(C) 2N and 23 N (D) 3N and 23 N
This part contains 30 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.
1. Examine the following resonating structures of formic acid and arrange them in decreasing order of
stability :
O O O O
H C OH H C O H H C OH H C OH
(I) (II) (III) (IV)
(A) II > I > III > IV (B) I > II > IV > III
(C) III > II > IV > I (D) IV > III > I > II
3. 3 3 2
4. The correct order of magnetic moments (spin only values in BM) among the following is
(A) [MnCl4 ]2 [CoCl4 ]2 [Fe(CN)6 ]4 (B) [Fe(CN)6 ]4 [CoCl4 ]2 [MnCl4 ]2
(C) [Fe(CN)6 ]4 [MnCl4 ]2 [CoCl4 ]2 (D) [MnCl4 ]2 [Fe(CN)6 ]4 [CoCl4 ]2
5. In the clathrates xenon with water, the nature of bonding between xenon and water molecule is
(A) covalent (B) hydrogen bonding
(C) coordinate (D) dipole-induced dipole interaction
N N
H
(I) (II) (III) (IV)
(A) III > IV > I > II (B) II > I > IV > III
(C) IV > III > II > I (D) III > I > IV > II
12
7. Solubility product constant of a sparingly soluble salt MCl2 is 4 10
8
of MCl2 in an aqueous solution of CaCl2 is 4 10 times less compared to its solubility in pure water.
Hence, concentration (molarity) of CaCl2 solution is
(A) 1 (B) 2
(C) 3 (D) 4
8. At STP the volume of nitrogen gas required to cover a sample of silica gel, assuming Langmuir
3 1
monolayer adsorption, is found to be 1.30 cm g of the gel. The area occupied by a nitrogen
2 23
molecule is 0.16 nm . What is the surface area per gram of silica gel ? [Given NA = 6 10 ]
2 1 2 1
(A) 3.48 m g (B) 5.568 m g
2 1
(C) 1.6 m g (D) none of these
2 1
9. Molar conductivity of a 0.05 M aqueous solution of MgCl2 is 195 S cm mol
2
electrodes that are 1.5 cm in surface area and 0.5 cm apart is filled with 0.05 M MgCl2 solution. How
much current will flow when a potential difference across the electrodes is 5.00 V.
(A) 0.15 A (B) 0.3 A
(C) 0.45 A (D) 0.60 A
10. Which of the following methods is not correct for the synthesis of benzaldehyde ?
H Pd BaSO LiAlH(OCMe )
(A) PhCOCl 2 4
(B) PhCOCl 3 3
Me
H /KMnO4 /
(C) Me 2
AlH
(D) PhCH2OH
PhC N
13. In a H like species, an electron jumps from an orbital having two radial and two angular nodes to the
orbital having same sign of wave function in all direction, at any distance, if energy of the emitted
photon is 326.4 eV, the species is
+
(A) H (B) He
+2 +4
(C) Li (D) B
MnO2
(a)
14. OH jones reagent
(b)
OH
The compounds (a) and (b) respectively are
O O O O
(A) (B)
O OH OH O
OH O Both O
(C) (D)
O OH O
15. Which statement about the composition of vapour over an ideal 1 : 1 molar mixture of benzene and
toluene is correct ? Assume the temperature is constant
Ph
17. O Mg/Hg
(B)
HCl
Me
The compound (B) is
O O
(A) Ph Ph (B) Ph
Ph
O O
OH OH OH OH
Ph Ph Me
(C) (D)
Me Ph Me
Me Ph
19. Bond dissociation enthalpy of E H (E = element) bonds is given below. Which of the compounds will
act as strongest reducing agent ?
Compound NH3 PH3 AsH3 SbH3
1
Ddiss (E H)/kJ mol 389 322 297 255
(A) NH3 (B) PH3
(C) AsH3 (D) SbH3
19
23. For the reaction, Ag(CN)2 Ag (2CN) , the Kc 10 . Calculate [Ag ] in solution
which was originally 0.1 M in KCN and 0.03 M in AgNO3.
14 10
(A) 7.5 10 (B) 7.5 10
18 28
(C) 7.5 10 (D) 7.5 10
24. An atomic solid crystallizes in a body centre of cubic lattice and the inner surface of the atoms at the
adjacent corner are separated by 60.3 pm. If the atomic weight of A is 48, then density of the solid, is
nearly
(A) 5.07 g/cc (B) 2.7 g/cc
(C) 3.5 g/cc (D) 1.75 g/cc
25. Which of the following is the correct order for increasing bond angle ?
(A) NH3 < PH3 < AsH3 < SbH3 (B) H2O < OF2 < Cl2O
+ + + +
(C) H3Te < H3Se < H3S < H3O (D) BF3 > BCl3 > BBr3 < BI3
26. Which of the following compounds will show faster aromatic nucleophilic substitution reaction ?
F Cl
(A) (B)
NO 2 NO 2
Br I
(C) (D)
NO 2 NO 2
30. Given that k is the rate constant for some order of a reaction at temperature T, the value of lim log k
T
This section contains 30 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D), out of which only ONE option is correct
x z
1. The equation of plane containing line x y = 3, z = 5 and parallel to 1 , y = 3 is
1 3
(A) 3x + y 2z = 2 (B) 3x 3y z = 4
(C) 3x + 3y + 2z = 1 (D) 3x + y + 2z = 1
1
t ln t
2. I= dt is equal to
0 1 t2
(A) ln 2 (B) 1
(C) 1 ln 2 (D) ln 2 1
4a 2b c
3. Let f(x) is ax2 + bx + c (3a + b > 0) and f(x) 0 R, then minimum value of is
3a b
(A) 4 (B) 3
(C) 2 (D) 1
4. Suppose that z is a complex number that satisfies |z 2 2i| 1. Then the maximum value
of |3iz + 6| is equal to
(A) 4 (B) 5
(C) 9 (D) none of these
5. The equation of locus of foot of perpendicular drawn from (5, 6) on the family of lines
(x 2) + (y 3) = 0 (where R) is
(A) (x 1)(x 3) + (y 2) = 0 (B) (x 1)(x 2) + (y 2)(y 3) = 0
(C) (x 2)(x 5) + (y 3)(y 6) = 0 (D) (x 1) + (y 3)(x 2) = 0
6. Pair of straight lines through A(2, 7) are drawn to intersect the line x + y = 5 at C and D. If
angle between the pair of straight lines is , then the locus of incentre of ACD is
2
(A) xy 3x + 2y = 14 (B) xy 6x + 4y = 29
(C) x2 + y2 6x + 4y = 29 (D) none of these
2x 5
7. The integral dx is equal to
x 1 x 2 x 3 x 4
1 3x 4 1 x2 3x 4
(A) ln c (B) ln c
2 5x 6 2 x2 5x 6
1 x2 5x 4
(C) ln c (D) none of these
2 x2 5x 6
40 40 40 40 40 40 40
8. The value C0 C1 C2 C3 ..... C10 C11 ..... C20 is _____
39 39
(A) C10 (B) C20
40 40
(C) C10 (D) C2
x2 y2 2 2
9. The positive slope of tangent to 1 which is normal to (x + 2) + (y + 2) = 1 is
9 1
8 74 4 31
(A) (B)
10 5
7 50
(C) (D) none of these
5
n
4r 2 2
10. The value of lim 4
is
1 4r 1
n
r
(A) 1 (B) 2
(C) 3 (D) none of these
11. From a point on the ground, the angles of elevation of a bird flying with a constant speed in a
2 2
horizontal direction at equal intervals of time are , , and . Then cot cot is equal to
2 2 2 2
(A) 3(cot cot ) (B) 3(cot cot )
2 2 2 2
(C) cot cot (D) cot cot
13. If equation of a curve passing through (1, 1) which satisfies the equation
dy ex y3
xy3 y3 x2ex + 3xy2 0 is f x , then f(1) belongs to
dx x
(A) (0, 2) (B) (2, 4)
(C) (4, 6) (D) (6, 8)
15. A focal chord of hyperbola 3x2 4y2 = 12 intersects the hyperbola at A, B and the hyperbola
8y2 6x2 = 12 at C and D. Number of integers in the range of |AC BD| is
(A) 1 (B) 2
(C) 3 (D) infinite
16. The mean of n items is x . If the first term is increased by 1, second by 2 and so on, then
new mean is
n
(A) x n (B) x
2
n 1
(C) x (D) none of these
2
10 10 11
C4 C5 Cm
11 11 12
18. If the value of C6 C7 Cm 2 is zero, then m is
12 12 13
C8 C9 Cm 4
(A) 6 (B) 4
(C) 5 (D) 3
19. [3(sin(cos 1) + cos(cos 1))] is equal to (where [.] is denotes the greatest integer function)
(A) 3 (B) 4
(C) 5 (D) 6
3 1
20. For x , sin 1 4 1 x2 2x3 x is equal to
2 2
a
21. ln cot a tan x dx where a 0, is
0
2
(A) a ln sin a (B) a ln (sin a)
(C) a ln cos a (D) none of these
22. If the vector OA 2i j 2k turns by a right angle about origin (O) so that it passes through
j k , then vector in new position is
3
(A) 2i j 2k (B) 2j k
5
3 i j
(C) 2i 2j k (D)
2
x 1
23. Let x > 0, then lim tan x sec x x is equal to
x 0
1
(A) (B) 1
e
1
(C) (D) 2
e2
24. Let A and B be two distinct points on the parabola y2 = 4x. If the axis of the parabola touches
a circle of radius r with AB as its diameter, then the slope of the line AB can be
1 1
(A) (B)
r r
2 3
(C) (D)
r r
x2 x2
25. If f x ; g x where x 0, , then
x sin x 1 cos x 2
(A) both f and g are increasing (B) f is increasing and g is decreasing
(C) f is decreasing and g is increasing (D) both f and g are decreasing
26. If the position vectors of points A and B with respect to origin O are a i j k and
b i j k respectively, then the projection of the vector 2a 3b 4 a b on a line
perpendicular to the plane OAB is
(A) 2 2 (B) 4 2
(C) 8 2 (D) 16 2
27. Two diagonals of a regular hexagon are selected at random. The probability that these
diagonals intersect inside the hexagon is
2 5
(A) (B)
3 9
4 5
(C) (D)
9 12
x tan x
28. Number of points in [0, ], where f x is non-differentiable is/are (where [.]
sin x cos x
denotes the greatest integer function)
(A) 0 (B) 4
(C) 9 (D) none of these
29. The area (in square units) enclosed by the curve C : y x 9 x 2 (x 0) and the x-axis is
3
(A) (B) 3
2
9
(C) (D) 9
2
30.
(A) 45 (B) 46
(C) 47 (D) 48