St. Paul H. S.

School
1st Class test 2020 – 2021
Sub: Chemistry Class 12 MM: 20
Note: Each question is of 2 Marks
Q. 01. Which aqueous solution has higher concentration 1 molar or 1 molal solution of the same solute?
Give reasSton.
Q. 02. What concentration of nitrogen should be present in a glass of water at room temperature?
Assume a temperature of 25° C, a total pressure of 1 atmosphere and mole fraction of nitrogen in
air of 0.78 (KH for nitrogen = 8.42 x 10–7 M/mm Hg)
Q. 03. A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure
of 2.8 kPa at 298 K. Further, 18 g of water is then added to the solution and the new vapour
pressure becomes 2.9 kPa at 298 K. Calculate: (i) molar mass of the solute (ii) vapour pressure
of water at 298 K.
Q. 04. Benzoic acid completely dimerises in benzene. What will be the vapour pressure of a solution
containing 61g of benzoic acid per 500g benzene when the vapour pressure of pure benzene at
the temperature of experiment is 66.6 torr?
Q. 05. Van’t Hoff factor for aqueous 0.01 M mono basic acid HA is 1.08. What is:
𝐶𝑥 2
(a) percent ionisation of HA (b) ionisation constant 𝐾𝑎 = [(1−𝑥)]= ?

Q. 06. B.P. elevation of 0.30 g acetic acid in 100g benzene is 0.0633 K. Calculate molar mass of acetic
acid. What conclusion can you draw about molecular state of solute? [Given Kb for Benzene =
2.53 K kg mol–1]
Q. 07. Calculate the boiling point of solution when 2g of Na2SO4 (M = 142 g mol–1) was dissolved in
50g of water, assuming Na2SO4 undergoes complete ionization.
(Kb for water = 0.52 K kg mol–1)
Q. 08. 0.6 mL of acetic acid (CH3COOH), having density 1.06 g mL–1, is dissolved in 1 litre of water.
The depression in freezing point observed for this strength of acid was 0.0205°C. Calculate the
van’t Hoff factor and the dissociation constant of acid (Kf for water 1.86 K kg mol–1).
Q. 09. 100ml of a solution having osmotic pressure of 2atm is mixed with 300ml of a solution with
osmotic pressure of 4 atm at 27oC determine final osmotic pressure
Q. 10. What is the advantage of using osmotic pressure as compared to other colligative properties for
the determination of molar masses of solutes in solutions?