I.

4.

E.) The crystal structure is not the crystal’s fingerprint, but a powder pattern. This powder pattern is different for
every item and has two characteristic features: d-spacings of lines and intensity. A powder pattern is determined by
the size and shape of the unit cell, and the atomic number and position of atoms in the cell.

7.

C.) 2 anions, 3 cations. Every corner of the cube (8 corners) contains one-eighth of an atom (where anions are
located each corner of the cube thus leading to a total of 1 anion). There is also an anion in the center thus there are
2 anions. Each center of a face contains one-half of an atom where it is known to be a cation. Since there are 6
faces, then there are 3 cations.

10.

E.) all of the above.

II.
 Diffraction Sin θ Sin2 θ Ratio Ratio m Planes dhkl √ h2 +k 2 +l2 a (nm)
Angle(°) 1 2 (hkl)
1 19.08 0.3269 0.1069 1 2 2 110 0.2358 √2 0.3335
2 22.17 0.3773 0.1424 1.33 2.66 3 111 0.2043 √3 0.3539
3 32.26 0.5337 0.28456 2.66 5.32 5 210 0.1444 √5 0.3229
4 38.74 0.6258 0.3916 3.36 7.32 7 - - - -
5 40.82 0.6537 0.4273 3.997 7.998 8 220 0.1179 2 √2 0.3335
 6 49.00 0.7547 0.5696 5.328 10.656 11 311 0.1022 √ 11 0.3390
7 55.35 0.8226 0.6767 6.33 12.66 13 321 0.0937 √ 14 0.3506
19.

a. The lattice is a primitive unit cell.

b.

Diffraction Angles(°) Plane(hkl)

19.08 110
22.17 111
32.26 210
38.74 -
40.82 220
49.00 311
55.35 321