PHYSICAL CHEMISTRY By: Shailendra Kumar

01. Three solutions of HCl having normality 12 N, 6 N and 2 N are mixed to obtain a solution of 4 N
normality. Which among the following volume ratio is correct for the above three components ?
(a) 1 : 1 : 5 (b) 1 : 2 : 6
(c) 2 : 1 : 9 (d) 1 : 2 : 4
02. 6.8 g H2O2 is dissolved in 224 mL solution. This solution will be labelled as :
(a) 0.224 V (b) 20 V
(c) 5 V (d) 10 V
03. A 15-volume sample of an H2O2 solution is equivalent to :
(a) 5.30 N (b) 1.77 N
(c) 2.68 N (d) 7.50 N
04. The pH of 0.5 M aqueous solution of HF (Ka = 2 × 10–4) is :
(a) 2 (b) 4
(c) 6 (d) 10
05. The pH of a solution obtained by mixing 50 mL of 0.4 N HCl and 50 mL of 0.2 N NaOH is :
(a) –log 2 (b) –log 0.2
(c) 1 (d) 2
06. What will be the pH value of 0.05 M Ba(OH)2 solution ?
(a) 12 (b) 13
(c) 1 (d) 12.96
07. The pH of a solution that is 0.1 M NaA and 0.1 M HA (Ka = 1 × 10–6) would be :
(a) 5 (b) 6
(c) 3 (d) 7
08. pKa for acetic acid is 4.74. What should be the ratio of concentrations of acetic acid and acetate
ion to have a solution with pH 5.74?
(a) 1 : 10 (b) 10 : 1
(c) 1 : 1 (d) 2 : 1
09. What is the pH of the buffer solution containing 0.15 mol of NH4OH and 0.25 mol of NH4Cl ? Kb for
NH4OH is 1.98 × 10–5 :
(a) 10 (b) 9
(c) 9.2 (d) 10.2
10. 0.16 g of N2H4 are dissolved in water and the total volume made up to 500 mL. Calculate the
percentage of N2H4 that has reacted with water at this dilution. The Kb for N2H4 is 4.0 × 10–6.
11. What will be the resultant pH when 200 mL of an aqueous solution of HCl (pH = 2) is mixed with
300 mL of an aqueous solution of NaOH (pH = 12) ?
12. How many grams of CaO are required to neutralise 852 g of P4H10 ?
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