Академический Документы
Профессиональный Документы
Культура Документы
And
Chemical for consumer
NO MAKTAB: 10618
SUBJECT: CHEMISTRY
Uses of Sulphuric Acid
Sulphuric acid is very important industrially, and has many uses including:
the manufacture of non-soapy detergents: modern detergents are organic compounds 'sulphonated'
with concentrated sulphuric acid;
the making of artificial silks like rayon: here, the fine threads in the alkaline cellulose solution are
neutralised by passing them through a bath of sulphuric acid;
the cleaning of metals by removing the surface oxide coating: this is called pickling and is important
in preparing articles for electroplating.
its use as an electrolyte inside batteries for cars: most car batteries are made up of lead plates in a
sulphuric acid electrolyte; occasionally, the electrolyte needs to be 'topped up' with distilled water ;
this is because small amounts of hydrogen and oxygen gases are given off by the chemical changes
inside the battery, and therefore the sulphuric acid loses water and becomes too concentrated ; in
the manufacture of drugs, paints, dyes and many other chemicals .
The large-scale manufacture of this acid is extremely important as it is the most common acid
used in industry, with over 1 000 million metric tonnes being produced annually.
Stage 1
Combustion of Sulphur sulphur + oxygen sulphur dioxide
S (s) + O2 (g) ---> SO2 (g) or
Heating of metal sulphide such as lead(II) sulphide 2PbS(s) + 3O 2(g) ---> 2PbO(s) + 2SO2(g) or
Combustion of hiydrogen sulphide 2H2S(g) + 3O2(g) ---> 2SO2(g) + 2H2O(ce)
The raw materials are sulphur and air (oxygen). Sulphur dioxide is produced by burning either
sulphur or ores which contain sulphur.
Purification of sulphur dioxide
1. The sulphur dioxide is then purified, by removing impurities like arsenic compounds which
would otherwise poison the catalyst.
2. It is then passed through an electrostatic dust precipitator, which, as its name implies,
charges dust particles which are then removed by being attracted to oppositely charged
plates.
Stage 2
Formation of Sulphur trioxide sulphur dioxide + oxygen ---> sulphur trioxide 2SO 2 (g) + O2 (g) --->
2SO3 (g)
Catalyst: vanadium(V) oxide
Temperature: 450°C
Pressure: 2-3 atmospheres
Sulphur dioxide and air are then washed, dried and passed over a vanadium(V) oxide catalyst
at 450°C and 2-3 atmospheres.
The reaction is reversible but at these temperatures and pressures, 98% conversion to
sulphur trioxide is achieved:
This reaction is exothermic, which means it favours a low temperature for high conversion to
sulphur trioxide.
Stage 3
Formation of oleum H2S2O7
sulphur trioxide + concentrated sulphuric acid ¾¾®oleum SO 3(g) + H2SO4(aq) ---> H2S2O7(l)
The next step is to dissolve the sulphur trioxide produced in concentrated sulphuric acid, to
form oleum, or fuming sulphuric acid.
Stage 4
Formation of Sulphuric acid Oleum + water ---> sulphuric acid H2S207 (1) + H2O (1) ---> 2H2SO4(aq)
This oleum is then diluted with water to the required strength of acid:
Although this may seem a roundabout route to take to form the acid, it is necessary because
sulphur trioxide cannot be dissolved directly in water as it reacts too violently, forming tiny
droplets of sulphuric acid which are very difficult to remove.
Uses of ammonia
Uses of ammonia
Table 3 Uses of ammonia
fertilizers 75
nitric acid 10
solvents 8
Manufacture of Fertilizers
Approximately 75% of all ammonia produced is converted into various ammonium compounds like
ammonium sulphate (NH4)2SO4, ammonium nitrate NH4NO3, ammonium phosphate (NH4)3PO4
and urea NH2CONH2.
Example
Urea NH2CONH2
They are solids for ease in handling and water soluble so that they seep into the soil to be absorbed
by the roots of the plant.
Nitrogen is an essential element for healthy plant growth as we saw earlier with the nitrogen cycle.
Nitrogen is essential for making proteins which are needed for healthy growth of stems and leaves.
The proportion of nitrogen present in a particular fertiliser can be calculated and is usually quoted as
an 'N' value on the fertiliser bag.
Solvent Uses
queous ammonia is used as a degreasing agent, as it is a good solvent of grease and fat.
Many household cleaners boast of the 'power of ammonia' for removing grease stains around the
kitchen.
It is more accurate to say 'ammonia solution', as ammonia does not liquefy until a temperature of
-34 °C is reached.
Characteristic of ammonia
As an alkali, ammonia can react with acid to form salt and water.
Example
The hydroxide ion can react with many kinds of positive ion to form precipitate.
Example
Ammonia is the only common alkaline gas, so it can be identified with moist red litmus paper turning
blue.
However, a more specific chemical test is to hold close to the suspected ammonia, a glass rod
dipped into some concentrated hydrochloric acid.
This will give off fumes of hydrogen chloride gas which, in the presence of ammonia, form a dense,
white 'smoke' of ammonium chloride:
In the same way, mixing a gas jar of hydrogen chloride and ammonia gas produces the same dense,
white smoke. The smoke again is the fine-particled solid called ammonium chloride.
9.3 Understanding Alloys
An alloy is a mixture of two or more metals mixed in a certain percentage.
Characteristic of metal
High density
Many metal are also soft. Metals like iron and copper also form oxides easily.
As a result, the uses of pure metals are limited, and alloys are made to improve the malleability,
ductileness and hardness of a metal.
A pure metal is composed of layers of atoms which are arranged in an even, orderly and close
manner at fixed positions (see Figure 9.8). Each atom is surrounded by 8-12 atoms.
This arrangement of atoms causes the metal to be very dense with high melting and boiling points.
The strong forces of attraction between atoms require a great amount of heat to overcome.
However, in spite of strong forces of attraction between atoms, the metal is not hard. If a force is
applied on the metal, the layers of atoms can glide and slide on top of each other, causing them to
move to new positions. This allows the metal to be drawn into wires (ductile). (See Figure 9.9.)
The spaces left naturally between layers of metal atoms also make it easy to be beaten into sheets
(malleable).
The formation of alloys occurs when these empty spaces between metal atoms are filled with atoms
of another metal, which may be higher or smaller than the original metal atoms. (Figure 9.10)
The foreign atoms are usually another metal but sometimes a non-metal, like a carbon or silicon is
used.
The foreign atoms filling up the spaces between the atoms of the pure metal help to prevent the
slipping and sliding of atom layers, thus making the metal harder, and less malleable and ductile.
Purpose of Making Alloys
Hardness of metals:
Carbon is added to iron to obtain steel to make it stronger and harder than pure iron. Other metals
like manganese, chromium and tungsten are also added to add to the hardness.
Magnalium is made from aluminium and magnesium to improve the hardness of the pure metals but
at the same time, maintaining their lightness.
Tin and iron are used vastly in building but they rust easily, thereby causing economical loss. Adding
other metals or non-metals to them can prevent rusting.
Adding phosphorus to bronze also improves the lustre and prevents corrosion of bronze.Beauty and
lustre of metals:
Making alloys also improve the beauty and lustre of metals. They are thus used as decorative items
as they do not tarnish easily.
Copper and antimony added to tin produces pewter, used to make decorative items.
Composition, Characteristic, and Uses of Alloy
Alloy Composition Properties Uses
Al 95%
Aeroplane parts, electric cables, racing
Duralumin Cu 4% Light, strong
bicycles
Mg 1%
Fe 99%
Steel Hard, strong, cheap Vehicles, ships, bridges, buildings
C 1%
Pb 50%
Snider Low melting point, strong Welding and soldering work
Sn 50%
Sn 91%
Malleable, ductile, rust
Pewter Sb 7% Decorative items, souvenirs
resistant
Cu 2%
It is made up of many smaller units called monomers, which are joined together through a process
called polymerisation. Thus the monomer is actually the repititive unit of a long polymer chain.
picture
Natural polymers
These occur naturally in living things. Some examples of natural polymers are:
Natural rubber
Natural rubber comprises the molecules of the monomer 2-methyl-1,3-butadiene, also called
isopropene, joined together to form a long chain, as in:
picture
Protein is obtained by the combination of amino acid molecules which represent the monomer
units.
picture
Carbohydrates are formed through the combination of glucose molecule which act as the monomer.
picture
[edit]Synthetic Polymers
Synthetic polymer is a polymer that is manufactured in industry from chemical substances through
the polymerisation process. Through research, scientists are now able to copy the structure of
natural polymers to produce synthetic polymers.
The raw materials for the manufacture of synthetic polymers are distillates of petroleum.
polymerisation by addition
polymerisation by condensation
Polymerisation by addition involves monomers with >C = C< bonding, where the monomers join
together to make a long chain without losing any simple molecules from it. Examples of polymers
produced through this process are polythene, PVC perspex and other plastics.
Polymerisation by condensation involves the elimination of small molecules like water, methanol,
ammonia or hydrogen chloride during the process. Examples of products of this process are terylene
and nylon-66.s
Plastics
Plastics are light, strong and do not react with any chemical substances, like acids and alkalis.
They can be made into many shapes and sizes. They are also good insulators of heat and
electricity.
Perspex (polymethyl2-methyl picture Aeroplane window panes, lenses, car lamp covers
propene)
–light, strong, translucent, stable towards sunlight
Synthetic rubber
Synthetic rubber is an elastomer or polymer which regains its size original shape after being
pulled or pressed. [Natural rubber is an elastomer too.]
It is used to make
Neoprene picture * rubber gloves and
* to insulate electric wires.
Synthetic Fibre
Nylon and terylene are synthetic fibres which undergo the condensation polymerisation
process.
These fibres resemble natural fibres but more resistant to stress and chemicals, and more
long-lasting.
In both cases, water is eliminated during the polymerisation process.
Nylon
umbrellas
curtains
socks
carpets
toothbrush
comb and so on
Terylene
fishing nets
2. Cheap
Synthetic polymers are also used to replace natural polymers such as cotton, silk and rubber.
3. The open burning of plastics gives rise to poisonous and acidic gases like carbon monoxide,
hydrogen chloride and hydrogen cyanide. These are harmful to the environment as they
cause acid rain.
4. Burning of plastics can also produce carbon dioxide, too much of this gas in the atmosphere
leads to the `green house effect'.
The raw materials used to manufacture synthetic polymers are petroleum and its by-
products. Petroleum is a non-renewable source of fuel which is fast diminishing from the
earth's crust.
1. Recycling polymers: Plastics can be decomposed by heating them without oxygen at 700°C.
This process is called pyrolysis. The products of this process are then recycled into new
products.
2. Inventing biodegradable polymers: Such polymers should be mixed with substances that can
be decomposed by bacteria (to become biodegradable) or light (to become
photodegradable) .
9.5 Ceramics
Uses of Glass and Ceramics
The raw materials used in the making of glass and ceramic materials are obtained from the
earth's crust. Silica or silicon(IV) dioxide, SiO2, form the most important component of glass and
ceramics.
In the SiO2 molecule, each silicon atom is held in a tetrahedral structure by four oxygen atoms.
Each oxygen atom is held by two silicon atoms. This is repeated until a giant three-
dimensional molecule results.[
It is a mixture of two or more types of metallic silicates but the main component is silicon(IV)
dioxide.
Glass has the following properties:
Due to the above reasons and the low cost involved to produce glass, it is used in industry to
make bottles, cooking utensils, plates and bowls, laboratory apparatus (such as conical flask,
beakers and test tubes), window panes, bulbs and others.
Different types of glass can be obtained depending on the composition of substances in it.
[edit]Soda lime glass:
This is obtained when limestone (CaCO3) and sodium carbonate (Na2CO3) are mixed with
molten silica and cooled down.
It is also known as soft glass as it has a low melting point.
Most glass produced is soda lime glass. But it breaks easily, thus it is mainly used to make
kitchen utensils.
Lead glass:
This is formed when a mixture of lead(II) oxide, sodium oxide and silica is heated together.
Lead glass of better quality contains a higher percentage of PbO.
Its refractive index and density being high, it has a glittering and attractive surface, thus it is
also called crystal glass.
Borosilicate glass:
Boron oxide (B2O3) and sodium carbonate is added to molten silica to obtain borosilicate glass
or pyrex..
The presence of B2O3 makes the glass able to withstand high temperatures and chemical
reaction. It does not break easily, thus it is used to make laboratory apparatus and cooking
utensils.
Fused silicate glass:
Sand (silica) is heated until it melts at 1700°C, and the viscous liquid is cooled immediately.
This produces a transparent solid with an uneven arrangement of atoms, called fused silicate
glass.
This glass cannot expand or contract easily when there are temperature changes. But it
cannot become misshapen because of its high melting point.
It is known as quartz glass.
Summary
Glass Composition Properties Uses
• Low melting point
(700°C)
SiO2 – 70%
• Mouldable into shapes Glass containers, Glass panes, Mirrors,
Na20 – 15%
Soda lime,glass Lamps and bulbs, Plates and bowls
CaO – 10% • Cheap
Bottles
Others – 4% • Breakable
Ceramic is a substance that is made from clay and hardened by heat in a furnace maintained
at a high temperature.
Clay is composed of aluminosilicate with sand and iron(III) oxide as impurities. Iron(III) oxide,
Fe203, gives a reddish colour to the clay.
Kaolin, or clay in its pure form, is white in colour. It consists of crystals of hydrated
aluminosilicate with the formula Al2Si2O7.2H2O or Al2O3.2SiO2.2H2O.
The different classes of ceramic include:
Group Composition
Quartz – SiO2
Calcite – CaCO3
Mixture of CaSiO3 and aluminium silicate
Aluminium oxide – Al2O3
1. A layer of water exists between the aluminosilicate crystals. This gives it a plastic-like
property when wet. Thus the clay is first wet to make it soft before it is shaped.
2. The shaped object is then dried. At this stage, the product can still be reshaped by adding
more water.
3. The dried object is heated to a temperature of 1000°C in a furnace. The product of this stage
cannot be softened with water or reshaped.
The surface of ceramic object is usually coated with a layer of mineral or metallic silicate and
baked again in the furnace to produce a shining and impervious ceramic object.
The properties of ceramics include the following:
1. Hard
2. Strong but brittle
3. Chemically inactive
4. Poor conductor of heat and electricity
5. High melting point – heat resistant
6. Cannot be compressed easily
The differences between the properties of ceramics, metals and non-metals are given below.
Property Metals Non-metals Ceramic
Hard but malleable and
Hardness Soft and brittle Hard but brittle
ductile
Density High Low Average
Melting point High Low Very high
Resistance to heat High Low Very high
Heat and Electrical
Good conductor Good insulator Good insulator
conductivity
Chemical reactions Corrodes Corrodes Stable, does not corrode
New Uses of Glass and Ceramics
The latest use of glass is to make photochromic glass and conducting glass while ceramics is
used to produce superconductors and car engine blocks.
[edit]Photochromic glass
Photochromic glass is very sensitive to light. It darkens in the presence of bright light and
lightens when the amount of sunlight lessens.
The glass is produced by adding silver chloride (or silver bromide) and some copper(II)
chloride to normal glass.
Silver halides decompose to silver and its halogen when exposed to ultraviolet rays. Thus we
have:
Conducting glass
Conducting glass is a type of glass which can conduct electricity. It is obtained by coating a
thin layer of a conducting material around the glass, usually indium tin(IV) oxide or ITO.
Conducting glass can also be obtained by embedding thin gold strips into a piece of glass.
This is used to make the front windows of aeroplanes which tend to mist at very high heights. By
passing an electric current through this glass (containing gold as conductors), the water of
condensation will dry up.
Superconductors are electrical conductors which have almost zero (0) electrical resistance.
Therefore, this conductor minimises the loss of electrical energy through heat.
Perovsite is a type of ceramic superconductor composed of itrium oxide, copper oxide and
barium oxide.
Superconductors are also used to make magnets which are light but thousands of times
stronger than the normal magnet.
Car Engine Block--When clay is heated with magnesium oxide, the ceramic that is produced
has a high resistance to heat. This material is used to build the engine blocks in cars as they can
withstand high temperatures.
They are used to make various substances in daily life because of the following reasons:
3. Metals are good conductors but have high resistance, leading to loss of electrical energy as
heat
Composite materials have been created to overcome these problems and to make materials
stronger, more long-lasting and light for specific purposes.
Ordinary concrete is strong but heavy. Concrete pillars must be big to support the weight.
They take up space and cannot withstand stress for example from earthquakes.
Reinforced concrete, containing steel rods in the concrete pillars, can make them stronger
and able to support larger loads. It also does not rust.
Optical fibre
This is a fine transparent glass tube that is made of molten glass. Glass cannot conduct
electricity or electronic data in the form of electrons. But optical fibre allows light to be
transmitted through the tube so that data is transmitted at a faster rate.
In telecommunications, light has replaced electrons as the transmitter of signals. This light
transmits signals through optical fibre and the field is called optoelectronics.
1. laser to do operation
Photochromic glass
Photochromic glass contains AgCI or AgBr which causes the glass to darken in sunlight and
lighten in the absence of sunlight. (See 9.5.)
It is used to make photochromic lenses of spectacles and protects our eyes from extreme
sunlight.
While plastic is light and hard, it is brittle. Glass is harder than plastic but breaks easily. Thus
fibre glass is obtained by adding a polyster resin to molten glass. It cannot be compressed
easily and is more tensile than the original materials.
Fibre glass is light, withstands corrosion, can be cast into different shapes, is impervious to
water, not very flammable, not brittle and stronger than even steel.
It is used to make racquets, construction panels, electrical appliances, pipes, and water
tanks.
Superconductor
1. In the medical field: to replace organs in the form of plastic composite organs.
2. Car parts now use composite materials instead of iron and steel. This increases the speed of
the car (car is lighter) and saves on fuel consumption.