Aldrich Chemistry 2012-2014 - Handbook of Fine Chemicals PDF

2012–2014
Handbook of
Fine Chemicals
©2013 Sigma-Aldrich Co. LLC

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Table of Contents
To Place an Order . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Chemical Listings (Alphabetical Order) . . . . . . . . . . . . . . . . . . . . . 13
Labware . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2641
How to Use This Handbook . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
Molecular Formula Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2898
General Information. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 CAS® Number Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3072
Catalogue Features. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 Product Number Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3133

Trademark Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3203
Safety Information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 Abbreviations and Acronyms. . . . . . . . . . . . . . . . . . . . . . . . . . . . 3204
Aldrich® Chemistry Publications . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 Organic Ring System and Numbering . . . . . . . . . . . . . . . . . . . 3207
Periodic Table . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3211
Supporting the Chemistry Community . . . . . . . . . . . . . . . . . . . . . 12
Conversion Tables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3212
Sigma-Aldrich® and the Environment. . . . . . . . . . . . . . . . . . . . . . . 12 Worldwide Service and Support Information . . . . . . . . . . . . 3216
Interior with an Alchemist and His Assistants at Work

VICTOR MAHU • FLEMISH (1655-CA.1700) OIL ON CANVAS, 23 X 33 IN.
Alchemy and chemistry share the same origins. Prior to

the 18th century, they represented the same subject.
Modern science is uneasy with its trial and error origins,
even though the evolution of chemistry is difficult to
imagine without a journey through alchemy. Many old
Arab manuscripts about medicine and world knowledge
were discovered in the Middle Ages. Based on these
writings and the conjunction of astrology and magic,
alchemy developed as the study of transforming the
inferior into the superior, the impure into the pure and
the imperfect into the perfect. The secret to achieve
transformation was believed to lie just out of human
reach. The objective of the alchemist was to discover the
secret. A unique medium, the universal elixir in which this transformation occurs, was referred to as the
“philosopher’s stone,” the holy grail of alchemy. It was thought that a small amount of this unknown substance
would allow transmutations from a lower to a higher form not only from illness to health, but also from base
metal to precious metal, namely gold. It comes as no surprise that European royalty, with their chronically empty
coffers, were interested in alchemists and supported their work.
The work of these alchemists did not result in producing metallic gold, but in 1707 J.F. Bottger produced a “white
gold” or porcelain which paralleled the porcelain only available from China at that time. This porcelain came to be
known as Dresden. Any portrayal of alchemists must include an oven. The athanor, or philosopher’s oven, was
never to lose its flame. Prominent in the Grohmann Museum Collection paintings of alchemy are numerous
vessels of different kinds filled with essences, and many books. The books contain the ancient and the newly
acquired knowledge of the alchemist. This painting by Mahu displays a large laboratory with numerous assistants
confirming the alchemist is well supported financially by the royal patrons. The alchemist in Mahu’s painting
concentrates on his work at a small oven.
1
11-GermExport-FM.indd 1 6/23/11 3:37 PM

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How to Use This Handbook

Chemical Listings
All chemicals contained in this Handbook are listed by name, in alphabetical order. Prefixes such as bis, tris,
tetra, etc. are considered to be part of the name, whereas descriptors such as R, cis, tert, etc. are not.
Commonly used names and acronyms can also be found in this section cross-referenced to the name. For
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2

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5

Catalogue Features
Key to Product Listings
20 10
n Dimethylchloroa n
1 (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3- 8 Dimethyl carbonate

aza-2-silacyclopentane
[616‑38‑6] Merck 14,3241; Beil. 3,IV,3; Fieser 2,149; 5,234; 12,201
2 (4S,5S)-2-Chloro-3,4-dimethyl-5-phenyl-2-(2-propenyl)-1-oxa-3-aza-2- (CH3O)2CO FW 90.08 6
silacyclopentane; (1S,2S)-pseudoephedrine allylchlorosilane; (4S,5S)-2- mp .................................................................. 2 to 4 °C n20 D .......................................................................... 1.368
Allyl-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazasilolidine bp ............................................................................ 90 °C vd ............................................................... 3.1 (vs air) 8
[447440‑43‑9] C13H18ClNOSi FW 267.83 density ..................................... 1.069 g/mL, 25 °C vp ......................................... 18 mmHg (21.1 °C)
3
bp .................................................. 120 °C/5 mmHg n20
3
4 D .......................................................................... 1.517 Danger H225 P210 12
density ..................................... 1.095 g/mL, 25 °C
7 Reagent used in the enantioselective allylation of aldehydes1

This product is a mixture of diastereomers.
 anhydrous, ≥99%
11
D
water ....................................................................................................................................... <0.005% (100mL pkg)
[α]20
D 72.5°, c = 0.6 in ethanol (200 proof) water ....................................................................................................................................................................... <0.002%
9 Lit. cited: 1. Kinnaird, J. W. A. et al. , J. Am. Chem. Soc. 124, 7920 (2002) APHA color .................................................................................................................................................................... <50
14
37
Danger H226-H261-H315-H319-H335 P231 + P232-P261-P305 517127-100ML Sure/Seal™ 100 mL 23.40
+ P351 + P338-P422
517127-1L Sure/Seal™ 1L 56.70
706671-1G glass btl 1g 76.50
517127-2L Sure/Seal™ 2L 104.50
19 > (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazasilolidine, see 517127-20L 20 L Inquire
(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclo-
pentane Page 70  ReagentPlus®, 99% 13
D152927-500ML 500 mL 18.70
3-Benzoylpropionic acid, 99%
D152927-1L 1L 28.00
4-Oxo-4-phenylbutyric acid
[2051‑95‑8] Beil. 10,IV,2772; Fieser 3,19; 2,26 C6H5COCH2CH2COOH > 2,2′-Dimethyl-1,1′-carbonyldiimidazole, see 1,1′-Carbonylbis(2-methylimi-
dazole) Page 621
FW 178.18 N,N-Dimethylchloroacetamide, see 2-Chloro-N,N-dimethylacetamide
5 mp .............................................................................................................................................................. 114 to 117 °C Page 668
7
Warning H315-H319-H335 P261-P305 + P351 + P338
15 B13802-25G poly btl 25 g 33.00

B13802-100G poly btl 100 g 94.20
> β-Benzoylpropionitrile, see 4-Oxo-4-phenylbutanenitrile Page 1964

3-Benzoylpropionitrile, see 4-Oxo-4-phenylbutanenitrile Page 1964
17 16 18
1 Substance name 10 Index references
2 Substance synonyms 11 Hazard pictograms
3 CAS 12 Hazard and precautionary codes
4 Molecular formula 13 Product grade or special quality
5 Linear formula 14 Product physical data and analytical

specifications
6 Molecular weight
15 Product number
7 Use statements, citations, features
and benefits 16 Unit size
8 Substance physical property data: 17 Packaging description

vp – vapour pressure
18 Price
vd – vapour density
ait – auto ignition temperature 19 Cross references
9 Literature references 20 New product
6

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it most.
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B D E I K L
A M
F
C
G
P O H
Q
NO GHS
SYMBOL
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Shown whenever available. CAS numbers vary in how I Batch Number/Lot Number
specifically they define the material. We make every effort
J Sigma-Aldrich Contact Addresses
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product.
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Safety Information
H Phrases EU Additional
H200 Unstable explosives. EUH 001 Explosive when dry.
H201 Explosive; mass explosion hazard. EUH 006 Explosive with or without contact with air.
H202 Explosive, severe projection hazard. EUH 014 Reacts violently with water.
H203 Explosive; fire, blast or projection hazard. EUH 018 In use may form flammable/explosive vapour-air mixture.
H204 Fire or projection hazard. EUH 019 May form explosive peroxides.
H205 May mass explode in fire. EUH 029 Contact with water liberates toxic gas.
H220 Extremely flammable gas. EUH 031 Contact with acids liberates toxic gas.
H221 Flammable gas. EUH 032 Contact with acids liberates very toxic gas.
H222 Extremely flammable aerosol. EUH 044 Risk of explosion if heated under confinement.
H223 Flammable aerosol. EUH 059 Hazardous to the ozone layer.
H224 Extremely flammable liquid and vapour. EUH 066 Repeated exposure may cause skin dryness or cracking.
H225 Highly flammable liquid and vapour. EUH 070 Toxic by eye contact.
H226 Flammable liquid and vapour. EUH 071 Corrosive to the respiratory tract.
H228
H240
Flammable solid.
Heating may cause an explosion.
P Phrases
H241 Heating may cause a fire or explosion. P101 If medical advice is needed, have product container or label
at hand.
H242 Heating may cause a fire.
P102 Keep out of reach of children.
H250 Catches fire spontaneously if exposed to air.
P103 Read label before use.
H251 Self-heating: may catch fire.
P201 Obtain special instructions before use.
H252 Self-heating in large quantities; may catch fire.
P202 Do not handle until all safety precautions have been read
H260 In contact with water releases flammable gases which may
and understood.
ignite spontaneously.
P210 Keep away from heat/sparks/open flames/hot surfaces. —
H261 In contact with water releases flammable gases.
No smoking.
H270 May cause or intensify fire; oxidiser.
P211 Do not spray on an open flame or other ignition source.
H271 May cause fire or explosion; strong oxidiser.
P220 Keep/Store away from clothing/…/combustible materials.
H272 May intensify fire; oxidiser.
P221 Take any precaution to avoid mixing with combustibles…
H280 Contains gas under pressure; may explode if heated.
P222 Do not allow contact with air.
H281 Contains refrigerated gas; may cause cryogenic burns or injury.
P223 Keep away from any possible contact with water, because of
H290 May be corrosive to metals. violent reaction and possible flash fire.
H300 Fatal if swallowed. P230 Keep wetted with…
H301 Toxic if swallowed. P231 Handle under inert gas.
H302 Harmful if swallowed. P231+P232 Handle under inert gas. Protect from moisture.
H304 May be fatal if swallowed and enters airways. P232 Protect from moisture.
H310 Fatal in contact with skin. P233 Keep container tightly closed.
H311 Toxic in contact with skin. P234 Keep only in original container.
H312 Harmful in contact with skin. P235 Keep cool.
H314 Causes severe skin burns and eye damage. P235+P410 Keep cool. Protect from sunlight.
H315 Causes skin irritation. P240 Ground/bond container and receiving equipment.
H317 May cause an allergic skin reaction. P241 Use explosion-proof electrical/ventilating/lighting/…/
H318 Causes serious eye damage. equipment.
H319 Causes serious eye irritation. P242 Use only non-sparking tools.
H330 Fatal if inhaled. P243 Take precautionary measures against static discharge.
H331 Toxic if inhaled. P244 Keep reduction valves free from grease and oil.
H332 Harmful if inhaled. P250 Do not subject to grinding/shock/…/friction.
H334 May cause allergy or asthma symptoms or breathing difficulties P251 Pressurised container: Do not pierce or burn, even after use.
if inhaled. P260 Do not breathe dust/fume/gas/mist/vapours/spray.
H335 May cause respiratory irritation. P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
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H340 May cause genetic defects. P263 Avoid contact during pregnancy/while nursing.
H341 Suspected of causing genetic defects. P264 Wash … thoroughly after handling.
H350 May cause cancer. P270 Do no eat, drink or smoke when using this product.
H351 Suspected of causing cancer. P271 Use only outdoors or in a well-ventilated area.
H360 May damage fertility or the unborn child. P272 Contaminated work clothing should not be allowed out of
H361 Suspected of damaging fertility or the unborn child. the workplace.
H362 May cause harm to breast-fed children. P273 Avoid release to the environment.
H370 Causes damage to organs. P280 Wear protective gloves/protective clothing/eye protection/
H371 May cause damage to organs. face protection.
H372 Causes damage to organs through prolonged or repeated P281 Use personal protective equipment as required.
exposure. P282 Wear cold insulating gloves/face shield/eye protection.
H373 May cause damage to organs through prolonged or P283 Wear fire/flame resistant/retardant clothing.
repeated exposure. P284 Wear respiratory protection.
H400 Very toxic to aquatic life. P285 In case of inadequate ventilation wear respiratory protection.
H410 Very toxic to aquatic life with long lasting effects. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or
H411 Toxic to aquatic life with long lasting effects. doctor/physician.
H412 Harmful to aquatic life with long lasting effects. P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if
H413 May cause long lasting harmful effects to aquatic life. you feel unwell.
9

Safety Information
P301+ IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P374 Fight fire with normal precautions from a reasonable
P330+ distance.
P331 P375 Fight fire remotely due to the risk of explosion.
P302+P334 IF ON SKIN: Immerse in cool water/wrap in wet bandages. P376 Stop leak if safe to do so.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water. P377 Leaking gas fire: Do not extinguish, unless leak can be
P302+P352 IF ON SKIN: Wash with plenty of soap and water. stopped safely.
P303+ IF ON SKIN (or hair): Remove/Take off immediately all P378 Use … for extinction.
P361+ contaminated clothing. Rinse skin with water/shower. P380 Evacuate area.
P353 P381 Eliminate all ignition sources if safe to do so.
P304+ IF INHALED: Remove victim to fresh air and keep at rest in a P390 Absorb spillage to prevent material damage.
P340 position comfortable for breathing.
P391 Collect spillage.
P304+ IF INHALED: If breathing is difficult, remove victim to fresh air
P402 Store in a dry place.
P341 and keep at rest in a position comfortable for breathing.
P402+P404 Store in a dry place. Store in a closed container.
P305+ IF IN EYES: Rinse cautiously with water for several minutes.
P351+ Remove contact lenses, if present and easy to do. Continue P403 Store in a well-ventilated place.
P338 rinsing. P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P306+P360 IF ON CLOTHING: rinse immediately contaminated clothing P403+P235 Store in a well-ventilated place. Keep cool.
and skin with plenty of water before removing clothes. P404 Store in a closed container.
P307+P311 IF exposed: Call a POISON CENTER or doctor/physician. P405 Store locked up.
P308+P313 IF exposed or concerned: Get medical advice/attention. P406 Store in corrosive resistant/… container with a resistant inner
P309+P311 IF exposed or if you feel unwell: Call a POISON CENTER or liner.
doctor/physician. P407 Maintain air gap between stacks/pallets.
P310 Immediately call a POISON CENTER or doctor/physician. P410 Protect from sunlight.
P311 Call a POISON CENTER or doctor/physician. P410+P403 Protect from sunlight. Store in a well-ventilated place.
P312 Call a POISON CENTER or doctor/physician if you feel unwell. P410+P412 Protect from sunlight. Do no expose to temperatures exceed-
P313 Get medical advice/attention. ing 50 °C/122 °F.
P314 Get medical advice/attention if you feel unwell. P411 Store at temperatures not exceeding … °C/…°F.
P315 Get immediate medical advice/attention. P411+P235 Store at temperatures not exceeding … °C/…°F. Keep cool.
P320 Specific treatment is urgent (see … on this label). P412 Do not expose to temperatures exceeding 50 °C/122 °F.
P321 Specific treatment (see … on this label). P413 Store bulk masses greater than … kg/… lbs at temperatures
P322 Specific measures (see … on this label). not exceeding … °C/…°F.
P330 Rinse mouth. P420 Store away from other materials.
P331 Do NOT induce vomiting. P422 Store contents under …
P332+P313 If skin irritation occurs: Get medical advice/attention. P501 Dispose of contents/container to …
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P334 Immerse in cool water/wrap in wet bandages.
P335 Brush off loose particles from skin.
P335+P334 Brush off loose particles from skin. Immerse in cool water/
wrap in wet bandages.
P336 Thaw frosted parts with lukewarm water. Do no rub affected
area.
P337+ P313 If eye irritation persists: Get medical advice/attention.
P338 Remove contact lenses, if present and easy to do. Continue
rinsing.
P340 Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P341 If breathing is difficult, remove victim to fresh air and keep at
rest in a position comfortable for breathing.
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER
or doctor/physician.
P350 Gently wash with plenty of soap and water.
P351 Rinse cautiously with water for several minutes.
P352 Wash with plenty of soap and water.
P353 Rinse skin with water/shower.
P360 Rinse immediately contaminated clothing and skin with
plenty of water before removing clothes.
P361 Remove/Take off immediately all contaminated clothing.
P362 Take off contaminated clothing and wash before reuse.
P363 Wash contaminated clothing before reuse.
P370+P376 In case of fire: Stop leak if safe to do so.
P370+P378 In case of fire: Use … for extinction.
P370+P380 In case of fire: Evacuate area.
P370+ In case of fire: Evacuate area. Fight fire remotely due to the
P380+ risk of explosion.
P375
P371+ In case of major fire and large quantities: Evacuate area. Fight
P380+ fire remotely due to the risk of explosion.
P375
P372 Explosion risk in case of fire.
P373 DO NOT fight fire when fire reaches explosives.
10

Aldrich Chemistry Publications
TM Materials Science
1 • 2010
Volume 5, Number
ques
erization Techni
Modern Polym
Fragmentation
Reversible Addition
Polymerization
Chain Transfer (RAFT)
a
r Synthesis Using
Block Copolyme Nitroxide-
Commercially Available
Polymerization
Mediated Radical
(NMP) Initiator
Ligands and
ATRP for Everyone: of
Clean Synthesis
Initiators for the
tion Functional Polymers
controlled polymeriza
Start living with tion in a
Asymmetric Polymeriza
Reaction Field
Chiral Liquid Crystal
PM
2/4/2010 3:51:28
indd 1
73066_MM5-1_US_r6.
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12

Alphabetical
Listings
76240_Aldrich Catalog_Divider Pages.indd 2 6/8/2011 7:41:06 AM

AHB A, 0613, UNP EU
n 3ti n
> 3TI, see Tris[2-(3-mercaptopropionyloxy)ethyl] isocyanurate Page 2574 Aceanthrenequinone, 96%
4AP, see 4-Aminopyridine Page 163
2-AA-13C6, see Anthranilic acid-ring-13C6 Page 193 1,2-Aceanthrylenedione O O
AAEM, see 2-(Methacryloyloxy)ethyl acetoacetate Page 1678 [6373‑11‑1] Beil. 7,I,436 C16H8O2 FW 232.23
AAMU-13C4,15N3 (ring-13C4,15N2,amino-15N), see 5-Acetylamino-6-amino-3-
methyluracil-ring-13C4,15N2,amino-15N Page 32
AAN, see N-(Cyanomethyl)acetamide Page 795
AAPH, see 2,2′-Azobis(2-methylpropionamidine) dihydrochloride Page 215
ABCO, see Quinuclidine Page 2241 mp .............................................................................................................................................................. 270 to 273 °C
ABCVA, see 4,4′-Azobis(4-cyanovaleric acid) Page 214
327972-1G glass btl 1g
3 Abietic acid, ~75% (GC) > 1,2-Aceanthrylenedione, see Aceanthrenequinone Page 14
ACE-Cl, see 1-Chloroethyl chloroformate Page 675
[514‑10‑3] Merck 14,7; Beil. 9,IV,2175 C20H30O2 CH3
FW 302.45 Acenaphthene
H3C CH3
1,8-Ethylenenaphthalene
H H
[83‑32‑9] Merck 14,28; Beil. 5,IV,1834 C12H10 FW 154.21
H3C OH
O
mp ............................................................ 90 to 94 °C vd ............................................................. 5.32 (vs air)

mp .............................................................................................................................................................. 139 to 142 °C
bp ......................................................................... 279 °C vp .......................................... 10 mmHg (131 °C)
 technical
79
Warning H315-H319-H335-H410 P261-P273-P305 + P351 +
D −85±10°, c = 1 in ethanol
[α]20 P338-P501
Starting material for natural product synthesis1,2,3; Epoxidation with
MCPBA4  99%
mp ............................................................................................................................................................................ ~155 °C 215376-1G glass btl 1g
Lit. cited: 1. G. Buchbauer, R. Kolbe, Sci. Pharm. 53, 173 (1985) 215376-5G glass btl 5g
2. G. Buchbauer, Monatsh. Chem 116, 1345 (1985) 215376-100G poly btl 100 g
3. H. Okawara et al., Tetrahedron Lett. 23, 1087 (1982)
4. S. Valverde et al., Tetrahedron 42, 573 (1986)  97%
79
Warning H315-H319-H335-H400 P261-P273-P305 + P351 + A104-250G glass btl 250 g
P338 store at: 2-8°C
00010-25G poly btl 25 g
Acenaphthene-d10
00010-100G poly btl 100 g [15067‑26‑2] C12D10 FW 164.27
mp ................................................................................................................................................................... 95 to 97 °C
> ABL, see Dodecanoic acid Page 1171
bp ....................................................................................................................................................................... 277-279 °C
L-Abrine, 99%  99 atom % D

Nα-Methyl-L-tryptophan mol wt 164.17, atom % calculation
H NH2
79
[526‑31‑8] Merck 14,10; Beil. 22,V,14,40 Warning H315-H319-H335-H410 P261-P273-P305 + P351 +
OH
C12H14N2O2 FW 218.25 P338-P501
O
N 451819-5G glass btl 5g
CH3
Acenaphthene-5-boronic acid
An indoleamino acid that shows radical scavenging and antioxidant [183158‑33‑0] C12H9B(OH)2 FW 198.03
properties in vitro.
mp ............................................................................................................................................................. >300 °C (dec.)
[α]20
D +65°, c = 1 in 0.5 M NaOH
5-Acenaphthenecarboxaldehyde, 95%
7
Warning H302-H312-H332 P280
[5345‑46‑0] C13H10O FW 182.22
> p-ABSA, see 4-Acetamidobenzenesulfonyl azide Page 16

(±)-Abscisic acid, see 2-cis,4-trans-Abscisic acid Page 14
O H
2-cis,4-trans-Abscisic acid, 98%
mp .............................................................................................................................................................. 102 to 106 °C
(±)-Abscisic acid; (2Z,4E)-5-(1-Hydroxy-2,6,6-
7
H3C CH3 CH3 Warning H315-H319-H335 P261-P305 + P351 + P338
trimethyl-4-oxo-2-cyclohexen-1-yl)-3-methyl-2,4-
pentadienoic acid; ABA; Dormin OH
O CH3 O OH 526657-5G glass btl 5g
[14375‑45‑2] Merck 14,11 C15H20O4
FW 264.32 5-Acenaphthenecarboxylic acid, 97%
mp .............................................................................................................................................................. 186 to 188 °C
[55720‑22‑4] C13H10O2 FW 198.22
 synthetic
7
Warning H315-H319-H335 P261-P305 + P351 + P338
862169-50MG glass btl 50 mg
862169-250MG glass btl 250 mg 526665-5G glass btl 5g
> ABT, see 1-Aminobenzotriazole Page 94

AcAc, see Acetylacetone Page 32
Acacia gum, see Gum arabic from acacia tree Page 1407
AC-allyl, see Allyl acetoacetate Page 67
AC-benzyl, see Benzyl acetoacetate Page 247
Accufluor™, see 1-Fluoro-4-hydroxy-1,4-diazoniabicyclo[2,2,2]octane bis(tetra-
fluoroborate) on aluminum oxide Page 1305
14 • For Certificate of Analysis and MSDS information, visit Aldrich.com/searchcenter •

AHB A, 0613, UNP EU
n Acetaldehyde n
278
Acenaphthenequinone Danger H224-H319-H335-H351 P210-P261-P281-P305
+ P351 + P338
[82‑86‑0] Beil. 7,IV,2498 C12H6O2 FW 182.17 O O
 ACS reagent, ≥99.5%
Titr. acid .................................................................................................................................................. ≤0.008 meq/g
evapn. residue ................................................................................................................................................ ≤0.005%
402788-5ML ampule 5 mL
mp ............................................................................................................................................... 249 to 252 °C (dec.)
402788-100ML alum btl 100 mL
7
Warning H315-H319-H335 P261-P305 + P351 + P338
A
402788-1L alum btl 1L
A201-25G-A poly btl 25 g  ≥99.0% (GC)

A201-100G-A poly btl 100 g forms easily paraldehyde
store at: 2-8°C
1-Acenaphthenol, 99%
00071-500ML glass btl 500 mL
1-Hydroxyacenaphthene OH 00071-1L glass btl 1L
[6306‑07‑6] Beil. 6,IV,4623 C12H10O FW 170.21
00071-2.5L glass btl 2.5 L
 ReagentPlus®, 99%
mp .............................................................................................................................................................. 145 to 148 °C 110078-5ML ampule 5 mL
110078-100ML alum btl 100 mL
A406-1G glass btl 1g
110078-500ML 500 mL
A406-25G glass btl 25 g
110078-1L alum btl 1L
Acenaphthylene 110078-4X1L 4×1L
[208‑96‑8] Beil. 5,IV,2138 C12H8 FW 152.19 110078-2.5L 2.5 L
110078-4L 4L
Acetaldehyde solution 8
mp ............................................................ 78 to 82 °C density .................................. 0.899 g/mL, 25 °C [75‑07‑0] Merck 14,39 CH3CHO FW 44.05
bp ......................................................................... 280 °C
 5 M in THF
7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338
density ............................................................................................................................................. 0.843 g/mL, 25 °C
n20
D ...................................................................................................................................................................................... 1.389
 ≥99%
Acetaldehyde-13C2
 75% 13
[1632‑98‑0] CH313CHO FW 46.04
acenaphthene ............................................................................................................................................................. 20%
mp ............................................................................................................................................................................ −125 °C
A805-5G glass btl 5g bp .................................................................................................................................................................................... 21 °C
 99 atom % 13C
Acenaphthylene-d8, 98% (CP) mol wt 46.02, atom % calculation
[93951‑97‑4] C12D8 FW 160.24 density ............................................................................................................................................. 0.820 g/mL, 25 °C
278
mp .................................................................................................................................................................... 78 to 82 °C Danger H224-H319-H335-H351 P210-P261-P281-P305
bp ................................................................................................................................................................................. 280 °C + P351 + P338
531227-1G ampule 1g
 99 atom % D
mol wt 160.17, atom % calculation Acetaldehyde-2,2,2-d3
7
[19901‑15‑6] Beil. 1,IV,3102 CD3CHO FW 47.07
mp .................................................................... −125 °C n20 D .......................................................................... 1.332
452459-100MG glass btl 100 mg bp ............................................................................ 21 °C
 98 atom % D
ACES, ≥99.0% (titration) mol wt 47.04, atom % calculation
N-(Carbamoylmethyl)-2-aminoethanesulfonic acid; N-(2-Acetamido)-2- density ............................................................................................................................................. 0.838 g/mL, 25 °C
aminoethanesulfonic acid; N-(Carbamoylmethyl)taurine
278
Danger H224-H319-H335-H351 P210-P261-P281-P305
[7365‑82‑4] Merck 14,36; Beil. 4,III,1707 H2NCOCH2NHCH2CH2SO3H + P351 + P338
FW 182.20 487767-1G ampule 1g
pKa (25 °C) ................................................................ 6.8 useful pH range .................................. 6.1 - 7.5
mp ..................................................... >220 °C (dec.) Acetaldehyde-d4
A9758-25G poly btl 25 g

Tetradeuteroacetaldehyde
[1632‑89‑9] Beil. 1,IV,3102 CD3CDO FW 48.08
mp ...................................................................... -125 °C vp ................................................. 14.05 psi (20 °C)
A9758-250G poly btl 250 g bp ............................................................................ 21 °C ait ......................................................................... 347 °F
A9758-1KG poly btl 1 kg n20
D ........................................................................... 1.3321
> Acetal, see Acetaldehyde diethyl acetal Page 16

 98 atom % D
Acetaldehyde mol wt 48.04, atom % calculation
density ............................................................................................................................................. 0.856 g/mL, 25 °C
Ethanal
278
Danger H224-H319-H335-H351 P210-P261-P281-P305
[75‑07‑0] Merck 14,39; Beil. 1,IV,3094; Fieser 1,3 CH3CHO FW 44.05 + P351 + P338
mp .................................................................... −125 °C vd ............................................................. 1.52 (vs air)
bp ............................................................................ 21 °C vp ................................................. 14.63 psi (20 °C) 176567-1G ampule 1g
density ..................................... 0.785 g/mL, 25 °C ait ......................................................................... 365 °F 176567-5G ampule 5g
n20
D .............................................................................. 1.332
• For additional products and custom pack sizes, visit Aldrich.com/cpr • 15

AHB A, 0613, UNP EU
n Acetaldehydeamm n
Acetaldehyde ammonia trimer, ≥96.0% (NT) Acetamide-15N

Hexahydro-2,4,6-trimethyl-1,3,5-triazine trihydrate CH3 [1449‑72‑5] CH3CO15NH2 FW 60.06
[58052‑80‑5] Merck 14,40; Beil. 26,IV,25 C6H15N3 ·
HN NH
• 3H2O
 98 atom % 15
N
3H2O FW 183.25
H3 C N CH3 487775 Full product information at Aldrich.com
H
Acetamidine hydrochloride, 95%
Structure1
mp .................................................................................................................................................................... 95 to 97 °C
[124‑42‑5] Merck 14,44; Beil. 2,IV,428 CH3C(=NH)NH2 · HCl
A Lit. cited: 1. A.T. Nielson et al., J. Org. Chem. 38, 3288 (1973) FW 94.54
mp .............................................................................................................................................................. 165 to 170 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
store at: 2-8°C Warning H315-H319-H335 P261-P305 + P351 + P338
00090-100G glass btl 100 g
159158-100G poly btl 100 g
> Acetaldehyde cyanohydrin, see DL-Lactonitrile Page 1600
159158-500G poly btl 500 g
Acetaldehyde diethyl acetal, 99% > 2-(Acetamido)acetonitrile, see N-(Cyanomethyl)acetamide Page 795
1,1-Diethoxyethane; Acetal
3′-Acetamidoacetophenone, ≥98.0% (GC)
[105‑57‑7] Merck 14,38; Beil. 1,IV,3103 CH3CH(OC2H5)2 FW 118.17
bp ......................................................................... 102 °C vp ................................................... 8 mmHg (8 °C) [7463‑31‑2] C10H11NO2 FW 177.20
density ..................................... 0.831 g/mL, 25 °C vp .............................................. 20 mmHg (20 °C)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
n20
D ................................................................ 1.379-1.383 ait ......................................................................... 446 °F
vd ................................................................... 4.1 (vs air)
00188-25G poly btl 25 g
27
Danger H225-H315-H319 P210-P305 + P351 + P338
4′-Acetamidoacetophenone, 97%
A902-5ML glass btl 5 mL [2719‑21‑3] CH3CONHC6H4COCH3 FW 177.20
A902-100ML glass btl 100 mL 631361 Full product information at Aldrich.com
A902-500ML glass btl 500 mL
2-Acetamidoacrylic acid, 99%
Acetaldehyde dimethyl acetal, 95%
N-Acetyldehydroalanine
1,1-Dimethoxyethane; Dimethyl acetal [5429‑56‑1] Beil. 4,IV,2840 CH2=C(NHCOCH3)COOH FW 129.11
[534‑15‑6] Merck 14,3226; Beil. 1,IV,3103; Fieser 2,4 CH3CH(OCH3)2 mp ............................................................................................................................................... 185 to 186 °C (dec.)
FW 90.12
7
Warning H315-H319-H335 P261-P305 + P351 + P338
bp ............................................................................ 64 °C n20
D .......................................................................... 1.367
density ..................................... 0.852 g/mL, 25 °C vd ................................................................ 3.1 (vs air)
2
Danger H225 P210
> N-(2-Acetamido)-2-aminoethanesulfonic acid, see ACES Page 15
2-Acetamido-5-aminopyridine, 97%
[29958‑14‑3] C7H9N3O FW 151.17 H2N
> Acetaldehyde ethylene acetal, see 2-Methyl-1,3-dioxolane Page 1770 O
N N CH3
Acetaldehyde oxime, mixture of syn and anti, 99% H
Acetaldoxime mp .............................................................................................................................................................. 154 to 158 °C

[107‑29‑9] Merck 14,42; Beil. 1,IV,3121; Fieser 1,3 CH3CH=NOH
7
Warning H317-H319 P280-P305 + P351 + P338
FW 59.07
bp ......................................................................... 115 °C n20
D .......................................................................... 1.426
density ..................................... 0.969 g/mL, 25 °C
27
Warning H226-H302-H319-H332 P305 + P351 + P338
4-Acetamidobenzaldehyde
A1002-25G glass btl 25 g 4′-Formylacetanilide
> Acetaldehyde polymerized, see Metaldehyde Page 1673 [122‑85‑0] Beil. 14,IV,71 CH3CONHC6H4CHO FW 163.17
Acetaldehyde trimer, see Paraldehyde Page 1980 mp .............................................................................................................................................................. 148 to 153 °C
Acetamide  technical grade

Amide C2 A1800-5G glass btl 5g
[60‑35‑5] Merck 14,43; Beil. 2,IV,399; Fieser 1,3 CH3CONH2 FW 59.07 A1800-25G poly btl 25 g
mp ............................................................ 78 to 80 °C vp ................................................ 1 mmHg (65 °C)
4-Acetamidobenzenesulfonyl azide, 97%
bp ......................................................................... 221 °C
p-ABSA
8
Warning H351 P281
[2158‑14‑7] Beil. 14,II,439 CH3CONHC6H4SO2N3 FW 240.24
mp .............................................................................................................................................................. 107 to 111 °C
 sublimed, 99%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
 ~99% (GC) 404764-25G glass btl 25 g
A0500-1G poly tube 1g > 2-Acetamidobenzoic acid, see N-Acetylanthranilic acid Page 33
16 • PEFC certified paper sourced from sustainably managed forests •

AHB A, 0613, UNP EU
n Acetamidomethyl n
3-Acetamidobenzoic acid, ≥98.0% (HPLC) 2-Acetamido-2-deoxy-β-D-glucopyranosyl azide 3,4,6-triacetate,

≥98.0% (HPLC)
[587‑48‑4] Beil. 14,IV,1103 C9H9NO3 FW 179.17 O
2-Acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D- RO
OH N3
glucopyranosyl azide O O
OR
[6205‑69‑2] R=* CH3
H3C NH RO
HN CH3
O
O
A
mp .............................................................................................................................................................. 247 to 252 °C
[α]D -45.5±2.5°, c = 1 in chloroform
7
Warning H315-H319-H335 P261-P305 + P351 + P338
00225-50G poly btl 50 g 671118-1G glass btl 1g
00225-250G 250 g
2-Acetamido-2-deoxy-α-D-glucopyranosyl chloride 3,4,6-tri-
4-Acetamidobenzoic acid, 98% acetate, 97%
N-Acetyl-PABA 2-Acetamido-3,4,6-tri-O-acetyl-2-deoxy-α-D- RO
[556‑08‑1] Beil. 14,IV,1198 CH3CONHC6H4CO2H FW 179.17 glucopyranosyl chloride O
O
mp ............................................................................................................................................... 259 to 262 °C (dec.)
[3068‑34‑6] Beil. 18,IV,7489 C14H20ClNO8 OR
R=* CH3
FW 365.76 OR
Cl
133337-25G poly btl 25 g NHR
4′-Acetamido-3′-bromoacetophenone, 97% mp ............................................................................................................................................................. >214 °C (dec.)

[101209‑08‑9] C10H10BrNO2 FW 256.10 O
[α]20
D +105°, c = 1 in chloroform
O CH3
H 3C N
H
Br > 2-Acetamido-2-deoxy-D-glucose, see N-Acetyl-D-glucosamine Page 39
Acetamidomethanol, see N-(Hydroxymethyl)acetamide Page 1494
mp .............................................................................................................................................................. 139 to 143 °C
4-Acetamido-2-methylbenzoic acid, 96%
6
Danger H301 P301 + P310
[103204‑69‑9] CH3CONHC6H3(CH3)CO2H FW 193.20
680346-5G glass btl 5g mp .............................................................................................................................................................. 237 to 242 °C
680346-25G glass btl 25 g
2-Acetamido-5-chlorothiazole, 96% 549665-25G glass btl 25 g
[20256‑39‑7] C5H5ClN2OS FW 176.62 S-Acetamidomethyl-L-cysteine hydrochloride, ≥99.0% (AT)
673129 Full product information at Aldrich.com H-Cys(Acm).HCl O O
• HCl
α-Acetamidocinnamic acid, 98% [28798‑28‑9] C6H12N2O3S · HCl
H3C N S OH
FW 228.70 H
NH2
N-Acetyldehydrophenylalanine
[5469‑45‑4] Beil. 14,IV,1769 C6H5CH=C(NHCOCH3)COOH
D −28±2°, c = 1 in H2O
[α]20
FW 205.21
Protected cysteine; cleavage is performed with mercuric acetate or
mp .............................................................................................................................................................. 188 to 190 °C
silver nitrate1,2; Oxidative cleavage to disulfides3
7
Warning H315-H319 P305 + P351 + P338 mp ............................................................................................................................................................. ~165 °C (dec.)
Lit. cited: 1. D.F. Veber et al., J. Am. Chem. Soc. 94, 5456 (1972)
213853-25G glass btl 25 g 2. J. Diaz et al., Bioorg. Chem. 8, 429 (1979)
213853-100G glass btl 100 g 3. B. Kamber et al., Helv. Chim. Acta 63, 899 (1980)
00320-1G 1g
4-Acetamidocyclohexanone, 97% 8
> S-Acetamidomethyl-L-cysteine 2-chlorotrityl ester polymer-bound, see H-
N-(4-Oxocyclohexyl)acetamide; 4-N-Acetyl-amino- O Cys(Acm)-2-ClTrt resin Page 830
O
cyclohexanone
[27514‑08‑5] C8H13NO2 FW 155.19 H3C N
H
2-Acetamido-4-methylthiazole, 98%
[7336‑51‑8] Beil. 27,159 C6H8N2OS FW 156.21 H3C
mp .............................................................................................................................................................. 136 to 140 °C N O
7
Warning H315-H319-H335 P261-P305 + P351 + P338 S N CH3
H

7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Acetamido-2-deoxy-β-D-glucopyranose 1,3,4,6-tetraacetate,
98% 301922-5G poly btl 5g
β-D-Glucosamine pentaacetate; 2-Amino-2- RO
301922-25G poly btl 25 g
deoxy-β-D-glucopyranosyl pentaacetate OR
O O 2-Acetamido-4-methyl-5-thiazolesulfonyl chloride, 97%
[7772‑79‑4] Beil. 31,171 C16H23NO10 OR
FW 389.35 R=* CH3 [69812‑29‑9] Beil. 27,IV,5905 C6H7ClN2O3S2 H3C
OR O
NHR FW 254.71 O
N
Cl S S N CH3
mp .............................................................................................................................................................. 186 to 189 °C O H
[α]24
D +1.7 to +3.0°, c = 10 in chloroform
mp .............................................................................................................................................................. 161 to 164 °C
5
859990-5G glass btl 5g Danger H314 P280-P305 + P351 + P338-P310
• To place an order, contact your local office. • 17

AHB A, 0613, UNP EU
n Acetamidonitrob n
4-Acetamido-3-nitrobenzoic acid, 97% 2-Acetamidophenylboronic acid pinacol ester, 97%

4-Acetylamino-3-nitrobenzoic acid 2′-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)acet- H 3C
CH3
[1539‑06‑6] CH3CONHC6H3(NO2)CO2H FW 224.17 anilide O
CH3
mp .............................................................................................................................................................. 220 to 224 °C [380430‑61‑5] C14H20BNO3 FW 261.12 B
O CH3
7
Warning H317 P280
NH
O CH3
A 647691-25G
2-Acetamidophenol, 97%
glass btl 25 g mp .............................................................................................................................................................. 172 to 176 °C
2′-Hydroxyacetanilide 594989-5G glass btl 5g
[614‑80‑2] Beil. 13,III,778 CH3CONHC6H4OH FW 151.16 3-Acetamidophenylboronic acid pinacol ester, 97%
mp .............................................................................................................................................................. 205 to 210 °C
3′-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl) H 3C
7
Warning H315-H319 P305 + P351 + P338 acetanilide O CH3
[480424‑93‑9] C14H20BNO3 FW 261.12 B CH3
O
A7000-25G-A glass btl 25 g CH3
A7000-100G-A glass btl 100 g
H3C NH
3-Acetamidophenol, 97% O
3′-Hydroxyacetanilide
mp .............................................................................................................................................................. 185 to 190 °C
[621‑42‑1] Beil. 13,IV,977 CH3CONHC6H4OH FW 151.16
7
mp .............................................................................................................................................................. 145 to 148 °C Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
A7205-100G glass btl 100 g 4-Acetamidophenylboronic acid pinacol ester, 97%
4-Acetamidophenol, 98% 4′-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-
H3C CH3
2-yl)acetanilide; 4-Acetamidophenylboro- O
APAP; N-Acetyl-4-aminophenol; 4-Acetamidophenol; 4′-Hydroxyacet- H3C
nic acid, pinacol cyclic ester B
O
anilide; Acetaminophen H3C O
[214360‑60‑8] C14H20BNO3 FW 261.12
[103‑90‑2] Merck 14,47; Beil. 13,IV,1091 CH3CONHC6H4OH N CH3
H
FW 151.16
Analgesic. mp .............................................................................................................................................................. 160 to 164 °C
mp .............................................................................................................................................................. 168 to 172 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
store at: room temp 518778-1G glass btl 1g
A7302-5G-A glass btl 5g 518778-5G glass btl 5g
A7302-100G-A poly btl 100 g
2-Acetamidopyridine-5-boronic acid pinacol ester, 97%
A7302-1KG-A poly btl 1 kg N-[5-(4,4,5,5-Tetramethyl-1,3,2-dioxa- H3C CH3
borolan-2-yl)-2-pyridyl]acetamide O
H3C
4-(4-Acetamidophenyl)-2-aminothiazole, 97% [904326‑87‑0] C13H19BN2O3 FW 262.11 B
H3C O O
C11H11N3OS FW 233.29
N N CH3
H
653527 Full product information at Aldrich.com
2-Acetamidophenylboronic acid mp .............................................................................................................................................................. 130 to 134 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Carbamoylbenzeneboronic acid
[169760‑16‑1] (CH3CONH)C6H4B(OH)2 FW 178.98
mp ............................................................................................................................................................................ >300 °C
May contain varying amounts of anhydride.
683906-250MG glass btl 250 mg 4-Acetamido-TEMPO, free radical
683906-1G glass btl 1g 4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl O
[14691‑89‑5] Beil. 22,8,174 C11H21N2O2 FW 213.30
3-Acetamidophenylboronic acid HN CH3
3-Acetamidobenzeneboronic acid
H3C CH3
[78887‑39‑5] Beil. 16,III,1284 CH3CONHC6H4B(OH)2 FW 178.98 H3C N CH3
mp ................................................................................................................................................................................ 135 °C O
Contains varying amounts of anhydride.

mp .............................................................................................................................................................. 143 to 145 °C
 for ESR-spectroscopy
4-Acetamidophenylboronic acid 98%
7
[101251‑09‑6] CH3CONHC6H4B(OH)2 FW 178.98 Warning H302
Contains varying amounts of anhydride
mp .............................................................................................................................................................. 215 to 220 °C 390380-25G glass btl 25 g
565806-1G glass btl 1g 390380-100G glass btl 100 g

AHB A, 0613, UNP EU
n Aceticacid n
4-Acetamido-2,2,6,6-tetramethylpiperidine, 98% Acethydrazide, 90%

[40908‑37‑0] C11H22N2O FW 198.31 Acetylhydrazine; Acetic acid hydrazide
391298 Full product information at Aldrich.com [1068‑57‑1] Beil. 2,IV,435 CH3CONHNH2 FW 74.08
mp ................................................................................................................................................................... 58 to 68 °C
> 4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl, see 4-Acetamido-TEMPO,
bp ...................................................................................................................................................... 129 °C/18 mmHg
free radical Page 18
acetic acid .................................................................................................................................................................. <10%
2-Acetamidothiazole, 98%
6
Danger H300-H315-H319 P264-P301 + P310-P305 + P351 + P338
[2719‑23‑5] C5H6N2OS FW 142.18
A8309-5G glass btl 5g A
4-Acetamidothiophenol, 90% A8309-100G glass btl 100 g
4′-Mercaptoacetanilide
[1126‑81‑4] Beil. 13,541 CH3CONHC6H4SH FW 167.23
mp .............................................................................................................................................................. 150 to 153 °C Losing Time Calculating
 technical grade Concentrations by Hand?
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Add Aldrich’s Normality and
A8201-1G glass btl 1g Molarity Calculator.
> 2-Acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl azide, see 2- Aldrich.com/calculator
Acetamido-2-deoxy-β-D-glucopyranosyl azide 3,4,6-triacetate Page 17
2-Acetamido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl
azide, ≥98.0% (HPLC) Acetic acid
[214467‑60‑4] C29H32N4O5 FW 516.59 Glacial acetic acid
[64‑19‑7] Merck 14,55 CH3CO2H FW 60.05
mp ....................................................................... 16.2 °C n20
D .......................................................................... 1.371
> Acetaminophen, see 4-Acetamidophenol Page 18 bp ............................................................... 117-118 °C vd ............................................................. 2.07 (vs air)
density ..................................... 1.049 g/mL, 25 °C ait ......................................................................... 800 °F
Acetanilide
25
Danger H226-H314 P280-P305 + P351 + P338-P310
N-Phenylacetamide
[103‑84‑4] Merck 14,50; Beil. 12,IV,373 CH3CONHC6H5 FW 135.16  ≥99.99% (Purity based on metals analysis)
mp ...................................................... 113 to 115 °C vp .............................................. 1 mmHg (114 °C)
bp ......................................................................... 304 °C ait ...................................................................... 1004 °F
vd ................................................................ 4.65 (vs air) 338826-100ML glass btl 100 mL
7
 TraceSELECT® Ultra, for trace analysis, ≥99.0% (T)
 zone-refined, purified by sublimation, ≥99.95% Ag ........................................................... ≤0.01 μg/kg Mn ....................................................... ≤0.02 μg/kg
Al ................................................................ ≤0.2 μg/kg Mo ......................................................... ≤0.1 μg/kg
As ............................................................... ≤0.5 μg/kg Na ............................................................... ≤1 μg/kg
397237-5G glass btl 5g Au ........................................................... ≤0.02 μg/kg Nd ....................................................... ≤0.01 μg/kg
Ba ............................................................ ≤0.01 μg/kg Ni ............................................................ ≤0.1 μg/kg
 purified by sublimation, ≥99.9% Be ............................................................ ≤0.01 μg/kg Pb ........................................................ ≤0.01 μg/kg
397229-5G glass btl 5g Bi .............................................................. ≤0.01 μg/kg Pd ........................................................ ≤0.02 μg/kg
397229-25G glass btl 25 g Ca ................................................................... ≤1 μg/kg Pr .......................................................... ≤0.01 μg/kg
Cd ........................................................... ≤0.01 μg/kg Pt .......................................................... ≤0.02 μg/kg
 reagent grade, 97% Ce ............................................................ ≤0.01 μg/kg Rb ........................................................ ≤0.01 μg/kg
Co ............................................................ ≤0.01 μg/kg Re ........................................................ ≤0.01 μg/kg
Cr ................................................................ ≤0.1 μg/kg Rh ........................................................ ≤0.01 μg/kg
112933-100G poly btl 100 g Cs ............................................................. ≤0.01 μg/kg Ru ........................................................ ≤0.01 μg/kg
112933-500G poly btl 500 g Cu .............................................................. ≤0.2 μg/kg Sb ........................................................ ≤0.05 μg/kg
112933-1KG poly btl 1 kg Dy ............................................................ ≤0.01 μg/kg Sm ....................................................... ≤0.01 μg/kg
Er .............................................................. ≤0.01 μg/kg Sn ........................................................... ≤0.1 μg/kg
Acetanilide-15N Eu ............................................................ ≤0.01 μg/kg Sr .......................................................... ≤0.01 μg/kg
[1449‑75‑8] CH3CO15NHC6H5 FW 136.16 Fe ............................................................... ≤0.5 μg/kg Tb ........................................................ ≤0.01 μg/kg
Ga ............................................................ ≤0.01 μg/kg Te ......................................................... ≤0.01 μg/kg
 98 atom % 15
N Gd ........................................................... ≤0.01 μg/kg Th ........................................................ ≤0.01 μg/kg
487783 Full product information at Aldrich.com Ge ............................................................ ≤0.02 μg/kg Ti .......................................................... ≤0.05 μg/kg
Hf ............................................................. ≤0.01 μg/kg Tl .......................................................... ≤0.01 μg/kg
Hg .................................................................. ≤1 μg/kg Tm ....................................................... ≤0.01 μg/kg
Ho ........................................................... ≤0.01 μg/kg U ........................................................... ≤0.01 μg/kg
In .............................................................. ≤0.01 μg/kg V ........................................................... ≤0.01 μg/kg
Ir ............................................................... ≤0.01 μg/kg W ......................................................... ≤0.01 μg/kg
K .................................................................. ≤0.5 μg/kg Y ........................................................... ≤0.01 μg/kg
La ............................................................. ≤0.01 μg/kg Yb ........................................................ ≤0.01 μg/kg
Li .............................................................. ≤0.01 μg/kg Zn ........................................................... ≤0.2 μg/kg
Lu ............................................................ ≤0.01 μg/kg Zr ......................................................... ≤0.01 μg/kg
Mg ............................................................. ≤0.1 μg/kg
07692-250ML-F 250 mL
07692-1L-F 1L

AHB A, 0613, UNP EU
n Aceticacid n
Acetic acid (continued) APHA color ............................................................ ≤10 Ge ...................................................... ≤0.05 mg/kg
chloride (Cl-) ..................................... ≤0.5 mg/kg K ............................................................. ≤0.1 mg/kg
 TraceSELECT®, for trace analysis, ≥99.0% (T) phosphate (PO43-) ........................ ≤0.5 mg/kg Li ......................................................... ≤0.01 mg/kg
chloride (Cl-) ..................................... ≤0.5 mg/kg Hg ................................................... ≤0.005 mg/kg sulfate (SO42-) .................................. ≤0.5 mg/kg Mg ........................................................ ≤0.1 mg/kg
phosphate (PO43-) ........................ ≤0.5 mg/kg K .......................................................... ≤0.02 mg/kg Ag .......................................................... ≤0.01 mg/kg Mn ..................................................... ≤0.01 mg/kg
sulfate (SO42-) ...................................... ≤1 mg/kg Li ...................................................... ≤0.001 mg/kg Al ............................................................ ≤0.05 mg/kg Mo ..................................................... ≤0.02 mg/kg
Ag ....................................................... ≤0.001 mg/kg Mg ..................................................... ≤0.01 mg/kg As ........................................................... ≤0.01 mg/kg Na ......................................................... ≤0.5 mg/kg
Al ......................................................... ≤0.005 mg/kg Mn .................................................. ≤0.001 mg/kg Ba ........................................................... ≤0.01 mg/kg Ni ........................................................ ≤0.05 mg/kg
As ........................................................ ≤0.005 mg/kg Mo .................................................. ≤0.001 mg/kg Be ........................................................... ≤0.01 mg/kg Pb ...................................................... ≤0.02 mg/kg
A Ba ........................................................ ≤0.003
Be ........................................................ ≤0.001
mg/kg
mg/kg
Na ...................................................... ≤0.03
Ni ..................................................... ≤0.002
mg/kg
mg/kg
Bi ............................................................... ≤0.1 mg/kg
Ca ............................................................. ≤0.2 mg/kg
Sr ........................................................ ≤0.01
Ti ......................................................... ≤0.01
mg/kg
mg/kg
Bi ......................................................... ≤0.001 mg/kg Pb .................................................... ≤0.004 mg/kg Cd .......................................................... ≤0.02 mg/kg Tl ......................................................... ≤0.05 mg/kg
Ca ........................................................... ≤0.03 mg/kg Sn .................................................... ≤0.001 mg/kg Co .......................................................... ≤0.01 mg/kg V .......................................................... ≤0.01 mg/kg
Cd ....................................................... ≤0.001 mg/kg Sr ..................................................... ≤0.001 mg/kg Cr ........................................................... ≤0.05 mg/kg Zn ...................................................... ≤0.05 mg/kg
Co ....................................................... ≤0.001 mg/kg Ti ...................................................... ≤0.001 mg/kg Cu .......................................................... ≤0.01 mg/kg Zr ........................................................... ≤0.1 mg/kg
Cr ......................................................... ≤0.001 mg/kg V ....................................................... ≤0.002 mg/kg Fe .............................................................. ≤0.2 mg/kg
Cu ....................................................... ≤0.002 mg/kg Zn .................................................... ≤0.005 mg/kg
Fe ........................................................... ≤0.01 mg/kg Zr ..................................................... ≤0.001 mg/kg 33209-1L 1L
33209-1L-GL glass btl 1L
45727-100ML-F poly btl 100 mL 33209-6X1L 6×1L
45727-500ML-F poly btl 500 mL 33209-6X1L-GL glass btl 6×1L
45727-1L-F poly btl 1L 33209-2.5L 2.5 L
45727-2.5L-F poly btl 2.5 L 33209-2.5L-GL glass btl 2.5 L
 ACS reagent, ≥99.7% 33209-4X2.5L-GL glass btl 4 × 2.5 L

acetic anhydride ................................................................................................................................................ ≤0.01% 33209-4X2.5L 4 × 2.5 L
Cr2O72- reducers ...................................................................................................................................... passes test 33209-5L 5L
MnO4- reducers ........................................................................................................................................ passes test 33209-200L 200 L
Titr. base ............................................................................................................................................... ≤0.0004 meq/g 33209-30KG 30 kg
APHA color ............................................................. ≤10 sulfate (SO42-) ....................................... ≤1 ppm 33209-60KG 60 kg
evapn. residue ........................................ ≤0.001% Fe ............................................................... ≤0.2 ppm
vp ............................................. 11.4 mmHg (20 °C) heavy metals (as Pb) .................. ≤0.5 ppm  ReagentPlus®, ≥99%
chloride (Cl-) ............................................. ≤1 ppm store at: room temp
320099-500ML PVC coated 500 mL A6283-100ML glass btl 100 mL
320099-2.5L PVC coated 2.5 L A6283-500ML glass btl 500 mL
A6283-2.5L glass btl 2.5 L
acetic anhydride ................................................................................................................................................ ≤0.01% Acetic acid solution, 49-51%
Cr2O72- reducers ...................................................................................................................................... passes test [64‑19‑7] Merck 14,55; Beil. 2,IV,94; Fieser 2,5; 7,1; 5,3; 8,1 CH3CO2H
MnO4- reducers ........................................................................................................................................ passes test FW 60.05
Titr. base ............................................................................................................................................... ≤0.0004 meq/g
APHA color ............................................................. ≤10 sulfate (SO42-) ....................................... ≤1 ppm  for HPLC
evapn. residue ........................................ ≤0.001% Fe ............................................................... ≤0.2 ppm corresponds to standard for RP gradient test
vp ............................................. 11.4 mmHg (20 °C) heavy metals (as Pb) .................. ≤0.5 ppm corresponds to standard for filter test
chloride (Cl-) ............................................. ≤1 ppm λ .................................................................................. neat 300 nm ............................................................. 0.01
260 nm ................................................................. 0.05 500 nm ............................................................. 0.01
695092-100ML glass btl 100 mL 270 nm ................................................................. 0.02
695092-500ML poly btl 500 mL
25
Danger H226-H314 P280-P305 + P351 + P338-P310
695092-6X500ML poly btl 6 × 500 mL
695092-2.5L poly btl 2.5 L 45754-100ML-F glass btl 100 mL
695092-6X2.5L poly btl 6 × 2.5 L 45754-500ML-F glass btl 500 mL
695092-19L 19 L
> Acetic acid bismuth(III) salt, see Bismuth(III) acetate Page 342
Acetic acid magnesium salt, see Magnesium acetate tetrahydrate
 puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.8% Page 1640
for use as solvent for perchloric acid titration Acetic acid silver salt, see Silver acetate Page 2282
passes test for indifference to chromic acid Acetic acid sodium salt, see Sodium acetate Page 2289
freezing point ................................................................................................................................................. ≥16.3 °C
acetaldehyde .................................................................................................................................................. ≤0.0002% Acetic acid-d
acetic anhydride .................................................................................................................................... ≤0.01% (GC) Monodeuteroacetic acid; Acetic (acid-d); mono-Deuteroacetic acid
KMnO4 red. matter (as HCOOH) ......................................................................................................... ≤0.002% [758‑12‑3] Beil. 2,IV,121 CH3COOD FW 61.06
non-volatile matter .................................................................................................................................... ≤0.0005%
water .......................................................................................................................................... ≤0.2% (Karl Fischer, )  99 atom % D
25
Danger H226-H314 P280-P305 + P351 + P338-P310

151777-250G glass btl 250 g
> Acetic (acid-d), see Acetic acid-d Page 20
Acetic acid-1-13C
[1563‑79‑7] Beil. 2,III,203 CH313CO2H FW 61.04
mp ....................................................................... 16.2 °C n20
D .......................................................................... 1.372
bp ............................................................... 117-118 °C
20 • For competitive quotes on larger quantities, visit safcglobal.com •

AHB A, 0613, UNP EU
n Aceticaciddiphe n
 99 atom % C 13 Acetic acid-2,2,2-d3

mol wt 61.04, atom % calculation [1112‑02‑3] Beil. 2,III,202 CD3CO2H FW 63.07
density ............................................................................................................................................. 1.066 g/mL, 25 °C mp ....................................................................... 16.2 °C n20
D .......................................................................... 1.369
bp ............................................................... 117-118 °C
25
Danger H226-H314 P280-P305 + P351 + P338-P310
 99 atom % D
279285-250MG ampule 250 mg
mol wt 63.04, atom % calculation
279285-1G ampule 1g
density ............................................................................................................................................. 1.101 g/mL, 25 °C
Acetic acid-1-13C,d4
[63459‑47‑2] Beil. 2,III,203 CD313CO2D FW 65.07
25
Danger H226-H314 P280-P305 + P351 + P338-P310
A
mp ....................................................................... 16.2 °C vd ............................................................. 2.07 (vs air) 487856-5G ampule 5g
bp ............................................................... 117-118 °C vp .......................................... 11.4 mmHg (20 °C)
n20
D ........................................................................... 1.3715 ait ......................................................................... 800 °F
Acetic acid-13C2,d4
13
CD313CO2D FW 66.06
 99 atom % 13C; 98 atom % D mp .............................................................................................................................................................................. 16.2 °C
mol wt 65.02, atom % calculation bp ....................................................................................................................................................................... 117-118 °C
density ............................................................................................................................................. 1.136 g/mL, 25 °C
 99 atom % 13C; 98 atom % D
25
Danger H226-H314 P280-P305 + P351 + P338-P310
density ............................................................................................................................................. 1.153 g/mL, 25 °C
298034-1G ampule 1g
25
Danger H226-H314 P280-P305 + P351 + P338-P310
13
Acetic acid- C2
13
[16651‑47‑1] Beil. 2,III,204 CH313CO2H FW 62.04 607401
mp ....................................................................... 16.2 °C vp .......................................... 11.4 mmHg (20 °C)
bp ............................................................... 117-118 °C ait ......................................................................... 800 °F
Acetic acid-d4
vd ................................................................ 2.07 (vs air) Tetradeuteroacetic acid; Acetic-d3 acid-d
[1186‑52‑3] Beil. 2,IV,122 CD3CO2D FW 64.08
 99 atom % 13C mol wt 64.08
mol wt 62.02, atom % calculation mp ............................................................ 15 to 16 °C vd ............................................................. 2.07 (vs air)
density ............................................................................................................................................. 1.083 g/mL, 25 °C bp ..................................................................... 115.5 °C vp ......................................... 11.4 mmHg (20 °C)
257
Danger H226-H312-H314 P280-P305 + P351 + P338-
P310 n20
D .............................................................................. 1.368
25
282022-250MG ampule 250 mg Danger H226-H314 P280-P305 + P351 + P338-P310
282022-1G ampule 1g
 99.9 atom % D
Acetic acid-2-13C
13 233315-5G glass btl 5g
[1563‑80‑0] Beil. 2,III,203 CH3CO2H FW 61.04
mp ....................................................................... 16.2 °C n20
D .......................................................................... 1.372
bp ............................................................... 117-118 °C
 99.9 atom % D
pk = 10 × 0.5 mL
 99 atom % 13C
mol wt 61.04, atom % calculation 237000-1PAK ampule 1 pkg
density ............................................................................................................................................. 1.066 g/mL, 25 °C
 99.5 atom % D
25
Danger H226-H314 P280-P305 + P351 + P338-P310
279307-250MG ampule 250 mg
279307-1G ampule 1g
18
Acetic acid- O2
 99.5 atom % D 8
[17217‑83‑3] Beil. 2,III,203 CH3C18O2H FW 64.05 density ............................................................................................................................................. 1.119 g/mL, 25 °C
mp ....................................................................... 16.2 °C n20
D ....................................................................... 1.3715
bp ............................................................... 117-118 °C 718270-10X0.5ML ampule 10 × 0.5 mL
 99.5 atom % D
 95 atom % 18O
pk = 10 × 0.75 mL
density ............................................................................................................................................. 1.116 g/mL, 25 °C 530484-1PAK ampule 1 pkg
25
Danger H226-H314 P280-P305 + P351 + P338-P310  99.5 atom % D
pk = 10 × 1 mL
487791-100MG ampule 100 mg
269743-1PAK ampule 1 pkg
> Acetic acid-18O2 sodium salt, see Sodium acetate-18O2 Page 2290
 99.5 atom % D, contains 0.03 % (v/v) TMS
Acetic acid-2-13C,2,2,2-d3 416886-25G glass btl 25 g
13 416886-50G glass btl 50 g
[79562‑15‑5] CD3CO2H FW 64.06
mp ....................................................................... 16.2 °C vd ............................................................. 2.07 (vs air)
> Acetic acid benzyl ester, see Benzyl acetate Page 247
bp ............................................................... 117-118 °C vp .......................................... 11.4 mmHg (20 °C) Acetic acid trans-1,3-diphenylallyl ester, see (±)-trans-1,3-Diphenylallyl
n20
D ................................................................................. 1.37 ait ......................................................................... 800 °F acetate Page 1139
 99 atom % 13C; 99 atom % D

density ............................................................................................................................................. 1.118 g/mL, 25 °C
25
Danger H226-H314 P280-P305 + P351 + P338-P310
299073-1G ampule 1g

AHB A, 0613, UNP EU
n Aceticanhydride n
Acetic anhydride  99 atom % 13C

[108‑24‑7] Merck 14,56; Beil. 2,IV,386; Fieser 8,1; 11,1; 1,3; 2,7; 9,1; 5,3; mol wt 106.02, atom % calculation
6,1; 7,1 (CH3CO)2O FW 102.09 density ............................................................................................................................................. 1.122 g/mL, 25 °C
mp ....................................................................... −73 °C
257
vd ................................................................ 3.5 (vs air) Danger H226-H302-H314-H332 P280-P305 + P351 +
bp ............................................................... 138-140 °C vp ................................................ 4 mmHg (20 °C) P338-P310
density ........................................................ 1.08 g/mL vp .............................................. 10 mmHg (36 °C)
n20
D .............................................................................. 1.390 ait ......................................................................... 629 °F
Acetic anhydride-13C4,d6
A 257
Danger H226-H302-H314-H332 P280-P305 + P351 +
P338-P310 (13CD313CO)2O FW 112.10
 Lonza quality, ≥99.5% (GC) mp ................................................................................................................................................................................ -73 °C
product of Lonza Ltd bp ....................................................................................................................................................................... 138-140 °C
691275-5KG 5 kg  99 atom % 13C; 97 atom % D
691275-25KG comp drum 25 kg mol wt 112.00, atom % calculation
density ............................................................................................................................................. 1.185 g/mL, 25 °C
257
Danger H226-H302-H314-H332 P280-P305 + P351 +
MnO4- reducers ........................................................................................................................................ passes test
P338-P310
evapn. residue ........................................ ≤0.003% sulfate (SO42-) ....................................... ≤5 ppm
chloride (Cl-) ............................................. ≤5 ppm Fe ................................................................... ≤5 ppm 607428-100MG ampule 100 mg
phosphate (PO43-) ................................ ≤0.001% heavy metals ........................................ ≤2 ppm
Acetic anhydride-d6
242845-5G glass btl 5g [16649‑49‑3] (CD3CO)2O FW 108.13
242845-100G glass btl 100 g mp ......................................................................... -73 °C n20
D ....................................................................... 1.3875
242845-1KG glass btl 1 kg bp ............................................................... 138-140 °C
 ReagentPlus®, ≥99%  99 atom % D

320102-1L 1L mol wt 108.07, atom % calculation
density ............................................................................................................................................. 1.143 g/mL, 25 °C
 99.5%
257
Danger H226-H302-H314-H332 P280-P305 + P351 +
539996 P338-P310
175641-1G ampule 1g
 reagent grade, ≥98%
175641-5G ampule 5g
A6404-500ML glass btl 500 mL Acetoacetamide
A6404-1L glass btl 1L [5977‑14‑0] Beil. 3,IV,1545 CH3COCH2CONH2 FW 101.10
A6404-2.5L glass btl 2.5 L mp ................................................................................................................................................................... 53 to 56 °C
Acetic anhydride-1,1′-13C2  Lonza quality, 98.5-100.3 % (w/w) (T)

[90980‑78‑2] (CH313CO)2O FW 104.07 688789-1KG poly btl 1 kg
mp ......................................................................... -73 °C n20
D ............................................................................. 1.39 688789-10KG fiber drum 10 kg
bp ............................................................... 138-140 °C
 97%
 99 atom % 13C 328812-100G glass btl 100 g
mol wt 104.07, atom % calculation 328812-500G glass btl 500 g
density ............................................................................................................................................. 1.101 g/mL, 25 °C
Acetoacetanilide, ≥99.5%
257
Danger H226-H302-H314-H332 P280-P305 + P351 +
P338-P310 [102‑01‑2] Merck 14,58; Beil. 12,IV,955 CH3COCH2CONHC6H5
487813-500MG ampule 500 mg FW 177.20
mp ............................................................ 83 to 88 °C ait ......................................................................... 843 °F
Acetic anhydride-1,1′-13C2,d6 vd ................................................................... 6.1 (vs air)
13
7
(CD3 CO)2O FW 110.11 Warning H302-H312 P280
mp ................................................................................................................................................................................. -73 °C
bp ....................................................................................................................................................................... 138-140 °C 538329-500G poly btl 500 g
 99 atom % 13C; 98 atom % D > Acetoacetic acid benzyl ester, see Benzyl acetoacetate Page 247
mol wt 110.03, atom % calculation 4-Acetobenzoic acid methyl ester, see Methyl 4-acetylbenzoate Page 1729
density ............................................................................................................................................. 1.164 g/mL, 25 °C
Acetohydroxamic acid, 98%
257
Danger H226-H302-H314-H332 P280-P305 + P351 +
P338-P310 AHA
607452-100MG ampule 100 mg [546‑88‑3] Merck 14,63; Beil. 2,IV,432; Fieser 13,2 CH3CONHOH
FW 75.07
Acetic anhydride-2,2′-13C2 mp ................................................................................................................................................................... 88 to 90 °C
[98006‑45‑2] (13CH3CO)2O FW 104.07
8
Danger H360 P201-P308 + P313
 99 atom % 13
C
257
Danger H226-H302-H314-H332 P280-P305 + P351 +
P338-P310 159034-10G glass btl 10 g
487848-250MG ampule 250 mg 159034-50G glass btl 50 g
13
Acetic anhydride- C4
[114510‑14‑4] (13CH313CO)2O FW 106.06
mp ....................................................................... −73 °C n20
D ............................................................................. 1.39
bp ............................................................... 138-140 °C

AHB A, 0613, UNP EU
n Acetone n
Acetoin  CHROMASOLV®, for HPLC, ≥99.9%

3-Hydroxy-2-butanone; Acetylmethylcarbinol purified by glass distillation
[513‑86‑0] Merck 14,64; Beil. 1,IV,3991 CH3COCH(OH)CH3 FW 88.11 Pure-Pac® II containers require the Micromatic MacroValve coupler for
mp .............................................. 15 °C (monomer) density .................................. 1.013 g/mL, 25 °C dispensing solvents, Z560723.
mp ........................................................ 90 °C (dimer) n20 D .......................................................................... 1.417 water ............................................................................................................................................................................. ≤0.5%
bp ......................................................................... 148 °C evapn. residue ..................................... ≤0.0002% 340 nm ............................................................. 0.10
λ .......................................................................... vs H2O 350 nm ............................................................. 0.02
 May exist as crystalline dimer 330 nm ................................................................. 1.00 400 nm ............................................................. 0.01
27
Warning H226-H315-H319 P305 + P351 + P338
270725-1L glass btl 1L A
270725-50L-P2-LS Pure-Pac® 2 50 L
270725-56L-P1-LS Pure-Pac® 1 56 L
> Acetol, see Hydroxyacetone Page 1470  CHROMASOLV®, for HPLC, ≥99.8%
free acid (as CH3COOH) ........................................................................................................................... ≤0.002%
1-Acetonaphthone, 97% non-volatile matter .................................................................................................................................... ≤0.0005%
water ............................................................................................................................................. ≤0.1% (Karl Fischer)
1-Acetylnaphthalene; Methyl 1-naphthyl ketone
transmittance ................................ 330 nm≥15% transmittance ............................. 340 nm≥80%
[941‑98‑0] Beil. 7,IV,1292 C10H7COCH3 FW 170.21 transmittance ................................ 335 nm≥50% transmittance ............................. 350 nm≥98%
mp ....................................................................... 10.5 °C density .................................... 1.12 g/mL, 25 °C
bp ......................................................................... 302 °C n20
D .......................................................................... 1.628 34850-1L glass btl 1L
7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 34850-6X1L glass btl 6×1L
34850-144X1L 144 × 1 L
276766-25G glass btl 25 g 34850-2.5L glass btl 2.5 L
34850-4X2.5L glass btl 4 × 2.5 L
2-Acetonaphthone, 99%
34850-72X2.5L glass btl 72 × 2.5 L
2-Acetylnaphthalene; Methyl 2-naphthyl ketone; 2′-Acetonaphthone 34850-18L 18 L
[93‑08‑3] Beil. 7,IV,1294 C10H7COCH3 FW 170.21
mp .................................................................................................................................................................... 52 to 56 °C  CHROMASOLV®, for HPLC, ≥99.9%
bp ....................................................................................................................................................................... 300-301 °C water ............................................................................................................................................................................. ≤0.5%
evapn. residue ..................................... <0.0002% 340 nm ............................................................. 0.10
7
λ .......................................................................... vs H2O 350 nm ............................................................. 0.02
330 nm ................................................................. 1.00 400 nm ............................................................. 0.01
134775-100G poly btl 100 g 439126-20L NOWPAK® 20 L
 ACS spectrophotometric grade, ≥99.5%

acetaldehyde ..................................................................................................................................................... ≤0.002%
When you need to estimate
isopropanol ........................................................................................................................................................... ≤0.05%
boiling points at reduced methanol ................................................................................................................................................................. ≤0.05%
pressures, Add Aldrich’s interactive MnO4 reducers ......................................................................................................................................... passes test
Pressure-Temperature Nomograph. Titr. acid ................................................................................................................................................ ≤0.0003 meq/g
Titr. base .............................................................................................................................................. ≤0.0006 meq/g
water ............................................................................................................................................................................. ≤0.5%
Aldrich.com/nomograph evapn. residue ........................................ <0.001% 340 nm ............................................................. 0.10
λ .......................................................................... vs H2O 350 nm ............................................................. 0.02
330 nm ................................................................. 1.00 400 nm ............................................................. 0.01
Acetone 154598-1L glass btl 1L

[67‑64‑1] Merck 14,66; Beil. 1,IV,3180; Fieser 6,9; 2,13; 3,4 CH3COCH3 154598-6X1L glass btl 6×1L
FW 58.08 154598-2L glass btl 2L
mp ....................................................................... −94 °C n20
D .......................................................................... 1.359 154598-4X2L glass btl 4×2L
bp ............................................... 56 °C/760 mmHg vd ................................................................... 2 (vs air)
density ..................................... 0.791 g/mL, 25 °C vp ........................................... 184 mmHg (20 °C)  ACS reagent, ≥99.5%
Pure-Pac® II containers require the Micromatic MacroValve coupler for
27
Danger H225-H319-H336-EUH066 P210-P261-P305 + P351 +
P338 dispensing solvents, Z560723.
aldehyde as formaldehyde ..................................................................................................................... ≤0.002%
 CHROMASOLV® Plus, for HPLC, ≥99.9%
isopropanol ........................................................................................................................................................... ≤0.05%
Suitable for HPLC, spectrophotometry, environmental testing
methanol ................................................................................................................................................................. ≤0.05%
Fluorescence (quinine) at 365 nm .................................................................................................. ≤1.0 ppb
Titr. acid ................................................................................................................................................ ≤0.0003 meq/g
water ............................................................................................................................................................................. ≤0.5%
Titr. base .............................................................................................................................................. ≤0.0006 meq/g
halogenated residue ............... <10 ng/L (as 340 nm .............................................................. 0.06
water ............................................................................................................................................................................. ≤0.5%
heptachlor epoxide) 350 nm .............................................................. 0.01
evapn. residue ..................................... ≤0.0003% APHA color .................................................................................................................................................................... ≤10
375-400 nm ................................................ 0.005
λ .......................................................................... vs H2O evapn. residue ................................................................................................................................................ ≤0.001%
330 nm .................................................................... 1.0 179124-500ML glass btl 500 mL
179124-1L glass btl 1L
179124-6X1L glass btl 6×1L
179124-2.5L 2.5 L
179124-20L steel drum 20 L

AHB A, 0613, UNP EU
n Acetone n
Acetone (continued) Acetone-1,3-13C2
13
[7217‑25‑6] CH3CO13CH3 FW 60.06
 ACS reagent, ≥99.5% mp ......................................................................... -94 °C vd ................................................................... 2 (vs air)
aldehyde as formaldehyde ..................................................................................................................... ≤0.002% bp ............................................................................ 56 °C vp .......................................... 184 mmHg (20 °C)
isopropanol ............................................................................................................................................................ ≤0.05% n20
D .............................................................................. 1.359
methanol ................................................................................................................................................................. ≤0.05%
Titr. acid ................................................................................................................................................ ≤0.0003 meq/g  99 atom % 13C
Titr. base ............................................................................................................................................... ≤0.0006 meq/g mol wt 60.06, atom % calculation
A water ............................................................................................................................................................................. ≤0.5%

APHA color .................................................................................................................................................................... ≤10
density ............................................................................................................................................. 0.818 g/mL, 25 °C
27
evapn. residue ................................................................................................................................................ ≤0.001% P338
320110-1L PVC coated 1L 299189-250MG ampule 250 mg
299189-1G ampule 1g
aldehyde as formaldehyde ..................................................................................................................... ≤0.002% Acetone-2-13C
isopropanol ............................................................................................................................................................ ≤0.05%
[3881‑06‑9] Beil. 1,III,2741 CH313COCH3 FW 59.07
methanol ................................................................................................................................................................. ≤0.05%
mp ......................................................................... -94 °C vd ................................................................... 2 (vs air)
Titr. acid ................................................................................................................................................ ≤0.0003 meq/g bp ............................................................................ 56 °C vp .......................................... 184 mmHg (20 °C)
Titr. base ............................................................................................................................................... ≤0.0006 meq/g n20
D .............................................................................. 1.359
water ............................................................................................................................................................................. ≤0.5%
APHA color .................................................................................................................................................................... ≤10  99 atom % 13C
evapn. residue ................................................................................................................................................ ≤0.001% mol wt 59.07, atom % calculation
673781-1L alum btl 1L density ............................................................................................................................................. 0.804 g/mL, 25 °C
27
673781-4L alum btl 4L Danger H225-H319-H336-EUH066 P210-P261-P305 + P351 +
P338
 histological grade, ≥99.5%
299197-250MG ampule 250 mg
water ............................................................................................................................................................................. <0.5%
299197-1G ampule 1g
evapn. residue ................................................................................................................................................ <0.001%
534064-500ML glass btl 500 mL Acetone-13C3
13
534064-20L steel drum 20 L [93628‑01‑4] CH313CO13CH3 FW 61.06
mp ....................................................................... −94 °C n20 D .......................................................................... 1.359
 ReagentPlus®, phenol free, ≥99.5% bp ............................................................................ 56 °C
phenol .................................................................................................................................................................. <50 ppm
323772-500ML glass btl 500 mL  99 atom % 13C
density ............................................................................................................................................. 0.832 g/mL, 25 °C
 Laboratory Reagent, ≥99.5%
27
water ............................................................................................................................................................................. ≤0.5% P338
evapn. residue ................................................................................................................................................ ≤0.002% 491667-250MG ampule 250 mg
Acetone-d6
179973-2.5L 2.5 L
Hexadeuteroacetone
[666‑52‑4] Beil. 1,IV,3199 CD3COCD3 FW 64.12
mp ................................................................... −93.8 °C vd ................................................................... 2 (vs air)
179973-4X5L 4×5L bp ........................................................................ 55.5 °C vp .................................................... 3.67 psi (20 °C)
179973-10L 10 L density ..................................... 0.872 g/mL, 25 °C vp ................................................. 14.39 psi (55 °C)
179973-20L steel drum 20 L n20
D .............................................................................. 1.355 vp .......................................... 184 mmHg (20 °C)
27
179973-25L 25 L Danger H225-H319-H336 P210-P261-P305 + P351 + P338
 PESTANAL®, solvent for residue analysis

 "100%", 99.96 atom % D
suitability for residue analysis ................................................................................................................ ≤5 ng/L
EUH066
water ............................................................................................................................................. ≤0.2% (Karl Fischer) 175862-5G ampule 5g
34480-1L 1L 175862-25G glass btl 25 g
34480-2.5L 2.5 L  "100%", 99.96 atom % D
34480-4X2.5L 4 × 2.5 L pk = 10 × 0.5 mL
34480-72X2.5L 72 × 2.5 L
 semiconductor grade ULSI PURANAL™ (Honeywell 17014)  "100%", 99.96 atom % D
specification on request pk = 10 × 0.75 mL
40308-5L 5L
 semiconductor grade VLSI PURANAL™ (Honeywell 17617)  "100%", 99.96 atom % D
specification on request pk = 10 × 1 mL
40289-2.5L 2.5 L
Acetone solution
[67‑64‑1] Merck 14,66 CH3COCH3 FW 58.08
 contains 20.0 % (v/v) acetonitrile, for HPLC
density ............................................................................................................................................. 0.791 g/mL, 25 °C
27
P338
686530-20L NOWPAK® 20 L

AHB A, 0613, UNP EU
n Acetonitrile n
 99.9 atom % D Acetone cyanohydrin, 99%

EUH066 α-Hydroxyisobutyronitrile; 2-Hydroxyisobutyronitrile
444863-10X0.5ML ampule 10 × 0.5 mL [75‑86‑5] Merck 14,67; Beil. 3,IV,785; Fieser 8,409; 11,1; 1,5
444863-10X0.6ML ampule 10 × 0.6 mL (CH3)2C(OH)CN FW 85.10
444863-10ML ampule 10 mL mp ....................................................................... −19 °C n20
D .......................................................................... 1.399
bp .................................................. 82 °C/23 mmHg vp ...................................................... 0.3 psi (20 °C)
density ..................................... 0.932 g/mL, 25 °C
contains sulfuric acid as stabilizer (US), H3PO4 as stabilizer (Europe)
444863-100ML
 99.9 atom % D
Sure/Seal™ 100 mL
69
Danger H300-H310-H330-H410
P301 + P310
P260-P264-P273-P280-P284- A
540331-10ML glass btl 10 mL A10000-1L 1L
A10000-4X1L 4×1L
 99.9 atom % D
EUH066 1,3-Acetonedicarboxylic acid
151793-10G ampule 10 g 3-Oxoglutaric acid
151793-25G glass btl 25 g [542‑05‑2] Merck 14,68; Beil. 3,IV,1816 HOOCCH2COCH2COOH
151793-50G glass btl 50 g FW 146.10
151793-100G Sure/Seal™ 100 g mp ................................................................................................................................................................ 133 °C (dec.)
 99.9 atom % D  technical grade

pk = 10 × 0.75 mL 165115-25G glass btl 25 g
444855-1PAK ampule 1 pkg 165115-100G glass btl 100 g
> Acetone diethyl acetal, see 2,2-Diethoxypropane Page 963

 99.9 atom % D Acetone dimethyl acetal, see 2,2-Dimethoxypropane Page 1052
pk = 10 × 1 mL Acetone ethylene acetal, see 2,2-Dimethyl-1,3-dioxolane Page 1082
431923-.5PAK ampule 5 × 1 mL
Acetone oxime, 98%
[127‑06‑0] Merck 14,75; Beil. 1,IV,3202 (CH3)2C=NOH FW 73.09
 99.9 atom % D mp ............................................................ 60 to 63 °C density ................................. 0.901 g/mL, 25 °C
530891-1L glass btl 1L bp ......................................................................... 135 °C
 99.9 atom % D, contains 0.03% TMS A10507-100G poly btl 100 g

EUH066
434531-10G ampule 10 g
When you need to estimate
434531-50G glass btl 50 g boiling points at reduced
pressures, Add Aldrich’s interactive
Pressure-Temperature Nomograph.
 99.9 atom % D, contains 0.03 % (v/v) TMS 8 Aldrich.com/nomograph

density ................................................................................................................................................ .873 g/mL, 25 °C
EUH066
718297-10X0.5ML ampule 10 × 0.5 mL Acetonitrile
718297-10X0.6ML ampule 10 × 0.6 mL
Methyl cyanide; ACN
 99.9 atom % D, contains 0.03% TMS [75‑05‑8] Merck 14,70; Beil. 2,IV,419; Fieser 2,13 CH3CN FW 41.05
pk = 10 × 1 mL mp ....................................................................... −48 °C vd ............................................................. 1.41 (vs air)
bp ..................................................................... 81-82 °C vp ......................................... 72.8 mmHg (20 °C)
n20
D .............................................................................. 1.344
27
EUH066 Danger H225-H302-H312-H319-H332 P210-P280-P305 + P351
+ P338
434523-10G ampule 10 g
434523-25G glass btl 25 g  anhydrous, 99.8%
434523-50G glass btl 50 g water ....................................................................................................................................................................... <0.001%
water ..................................................................................................................................... <0.005% (100 mL pkg)
 99.9 atom % D, contains 1 % (v/v) TMS evapn. residue ............................................................................................................................................. <0.0005%
454133-10G ampule 10 g 271004-100ML Sure/Seal™ 100 mL
454133-25G glass btl 25 g 271004-12X100ML Sure/Seal™ 12 × 100 mL
454133-50G glass btl 50 g 271004-1L Sure/Seal™ 1L
271004-6X1L Sure/Seal™ 6×1L
 99.9 atom % D, contains 1 % (v/v) TMS
271004-2L Sure/Seal™ 2L
pk = 10 × 1 mL
271004-4X2L Sure/Seal™ 4×2L
271004-50L-P2 Pure-Pac® 2 50 L
Acetone azine, 98% 271004-200L Pure-Pac® 1 200 L
[627‑70‑3] Beil. 1,651 (CH3)2C=NN=C(CH3)2 FW 112.17 271004-200L-P1 Pure-Pac® 1 200 L
mp .................................................................... −125 °C density .................................. 0.842 g/mL, 25 °C
bp ............................................ 133 °C/763 mmHg n20 D .......................................................................... 1.454
268
Danger H226-H302-H311-H315-H319-H335-H350
P201-P261-P280-P305 + P351 + P338-P308 + P313

AHB A, 0613, UNP EU
n Acetonitrile n
Acetonitrile (continued)
 CHROMASOLV® gradient grade, for HPLC, ≥99.9%
Product filtered through a 0.2 μm filter
 LC-MS CHROMASOLV®, ≥99.9% Pure-Pac® II containers require the Micromatic MacroValve coupler for
in accordance for suitability for LC-MS dispensing solvents, Z560723.
shelf life (limited shelf life, expiry date on the label) baseline drift ................................................................................................................................................... ≤15 mAU
filtered through a 0.2 μm filter (210 nm)
baseline drift ................................................................................................................................................... ≤12 mAU HPLC-gradient 210nm .................................................................................................................................... ≤3 mAU
(210 nm) HPLC-gradient 254nm ................................................................................................................................ ≤0.5 mAU
A HPLC-gradient 210nm ..................................................................................................................................... ≤1 mAU

HPLC-gradient 254nm ................................................................................................................................. ≤0.2 mAU
fluorescence (quinine) at 254 nm ...................................................................................................... ≤1 ppb
fluorescence (quinine) at 365 nm ................................................................................................... ≤0.5 ppb
free acid (as CH3COOH) ............................................................................................................................ ≤0.001% free acid (as CH3COOH) ........................................................................................................................... ≤0.001%
quinine fluor., 254 nm .............................................................................................................................. ≤0.5 ppb free alkali (as NH3) ..................................................................................................................................... ≤0.0002%
quinine fluor., 365 nm .............................................................................................................................. ≤0.5 ppb non-volatile matter .................................................................................................................................... ≤0.0005%
water (Karl Fischer) .......................................................................................................................................... ≤0.01% water .......................................................................................................................................... ≤0.02% (Karl Fischer)
transmittance ................................. 195 nm≥80% Cu ...................................................... ≤0.02 mg/kg transmittance ................................ 195 nm≥75% transmittance ............................. 230 nm≥99%
transmittance ................................. 200 nm≥95% Fe .......................................................... ≤0.1 mg/kg transmittance ................................ 200 nm≥93%
transmittance .................................... 230 nm99% K ............................................................. ≤0.1 mg/kg
store at: room temp
Ag ............................................................. ≤0.1 mg/kg Mg ........................................................ ≤0.1 mg/kg
Al ............................................................... ≤0.5 mg/kg Mn ..................................................... ≤0.02 mg/kg 34851-100ML glass btl 100 mL
Ba .............................................................. ≤0.1 mg/kg Na ......................................................... ≤0.1 mg/kg 34851-1L glass btl 1L
Ca ............................................................. ≤0.1 mg/kg Ni ........................................................ ≤0.02 mg/kg 34851-6X1L glass btl 6×1L
Cd .......................................................... ≤0.05 mg/kg Pb ......................................................... ≤0.1 mg/kg
34851-144X1L glass btl 144 × 1 L
Co .......................................................... ≤0.02 mg/kg Sn .......................................................... ≤0.1 mg/kg
Cr ........................................................... ≤0.02 mg/kg Zn ......................................................... ≤0.1 mg/kg 34851-2.5L 2.5 L
34851-4X2.5L 4 × 2.5 L
34967-250ML glass btl 250 mL 34851-72X2.5L 72 × 2.5 L
34967-1L glass btl 1L 34851-108X2.5L 108 × 2.5 L
34967-6X1L glass btl 6×1L 34851-4L glass btl 4L
34967-144X1L 144 × 1 L 34851-7L ss drum 7L
34967-2.5L glass btl 2.5 L 34851-56L-P1-LS Pure-Pac® 1 56 L
34967-4X2.5L glass btl 4 × 2.5 L 34851-200L-LS-NB Pure-Pac® 1 200 L
34967-72X2.5L 72 × 2.5 L
34967-20L NOWPAK® 20 L  CHROMASOLV® gradient grade, for HPLC, ≥99.9%
purified by sub-micron filtration
 CHROMASOLV® Plus, for HPLC, ≥99.9% Product filtered through a 0.2 μm filter
Enhances sensitivity for critical analytical applications: HPLC, spectro- baseline drift at 210 nm ....................................................................................................................... ≤15 mAU
photometry and residue analysis HPLC gradient analysis .............................................................................................. ≤0.5 mAU (@254 nm)
Product filtered through a 0.2 μm filter HPLC gradient analysis .................................................................................................. ≤3 mAU, @ 210 nm
Pure-Pac® II containers require the Micromatic MacroValve coupler for free acid (as CH3COOH) ........................................................................................................................... ≤0.001%
dispensing solvents, Z560723. free alkali (as NH3) ..................................................................................................................................... ≤0.0002%
baseline drift ................................................................................................................................................... ≤12 mAU quinine fluor., 254 nm ................................................................................................................................. ≤1 ppb
(210 nm) quinine fluor., 365 nm ............................................................................................................................. ≤0.5 ppb
HPLC-gradient 210nm ..................................................................................................................................... ≤1 mAU water .......................................................................................................................................... ≤0.01% (Karl Fischer)
HPLC-gradient 254nm ................................................................................................................................. ≤0.2 mAU evapn. residue ..................................... <0.0002% 200 nm ....................................................... ≤0.032
fluorescence (quinine) at 254 nm ................................................................................................... ≤0.5 ppb λ .......................................................................... vs H2O 230 nm .................................................... ≤0.0044
fluorescence (quinine) at 365 nm ................................................................................................... ≤0.5 ppb 195 nm .............................................................. ≤0.12
free acid (as CH3COOH) ............................................................................................................................ ≤0.001%
439134
free alkali (as NH3) ...................................................................................................................................... ≤0.0001%
 biotech. grade, ≥99.93%
water .......................................................................................................................................... ≤0.01% (Karl Fischer)
Product filtered through a 0.2 μm filter.
halogenated residue ................... 10 ng/L (as λ ....................................................................... vs H2O
heptachlor epoxide) 195 nm ........................................................... 0.100
Pure-Pac® II containers require the Micromatic MacroValve coupler for
transmittance ................................. 195 nm≥80% 200 nm ........................................................... 0.020 dispensing solvents, Z560723.
transmittance ................................. 200 nm≥95% 228 nm ........................................................... 0.005 as quinine ...................................................................................................... ≤0.5 ppb (fluorimetric, 254nm)
transmittance ................................. 228 nm≥99% Titr. acid .............................................................................................................................................................. ≤8 μeq/g
Titr. base ......................................................................................................................................................... ≤0.6 μeq/g
34998-1L glass btl 1L water ....................................................................................................................................................................... <0.001%
34998-6X1L glass btl 6×1L APHA color ............................................................ <10 210 nm ............................................................. 0.03
34998-2.5L glass btl 2.5 L evapn. residue ..................................... <0.0002% 220 nm ............................................................. 0.01
34998-4X2.5L glass btl 4 × 2.5 L λ .......................................................................... vs H2O 235 nm ........................................................... 0.005
190 nm .................................................................... 1.0 400 nm ........................................................... 0.005
34998-72X2.5L 72 × 2.5 L
34998-20L NOWPAK® 20 L 494445-100ML Sure/Seal™ 100 mL
34998-20L-P2 Pure-Pac® 2 20 L 494445-1L Sure/Seal™ 1L
34998-50L-P2-LS Pure-Pac® 2 50 L 494445-2L Sure/Seal™ 2L
34998-50L-P2 Pure-Pac® 2 50 L 494445-4L 4L
34998-200L-P2 200 L 494445-4X4L glass btl 4×4L
494445-25L ss drum 25 L
494445-200L Pure-Pac® 1 200 L
water ........................................................................................................................................................................... ≤0.01%
evapn. residue ..................................... ≤0.0002% 200 nm .......................................................... ≤0.02 494445-400L Pure-Pac® 1 400 L
ait ............................................................................. 525 °F 228 nm ....................................................... ≤0.005
195 nm .............................................................. ≤0.10
675415

AHB A, 0613, UNP EU
n Acetonitrile n
 ACS reagent, ≥99.5%  contains 0.05 % (w/v) ammonium formate, 0.1 % (v/v) formic
Titr. acid .............................................................................................................................................................. ≤8 μeq/g acid, 5 % (v/v) water, for HPLC
Titr. base ......................................................................................................................................................... ≤0.6 μeq/g LC/MS suitability tested
water ............................................................................................................................................................................. ≤0.3% Product filtered through a 0.2 μm filter
APHA color .................................................................................................................................................................... ≤10 density ............................................................................................................................................. 0.807 g/mL, 25 °C
evapn. residue ................................................................................................................................................ ≤0.005%
27
Danger H225-H302-H319-H332 P210-P305 + P351 + P338
A
679186
 contains 0.05% formic acid, 40.0% 2-propanol, 10.0% acetone
360457-10L ss drum 10 L
27
Danger H225-H302-H319-H336 P210-P261-P305 + P351 +
P338
 ≥99.5%, ACS reagent 685461
Titr. acid .............................................................................................................................................................. ≤8 μeq/g
Acetonitrile with 0.1% acetic acid, ≥99.5%
Titr. base ......................................................................................................................................................... ≤0.6 μeq/g
water ............................................................................................................................................................................. ≤0.3%  LC-MS CHROMASOLV®
APHA color .................................................................................................................................................................... ≤10
LC-MS tested
evapn. residue ................................................................................................................................................ ≤0.005%
0.093-0.107% acetic acid basis
437557 transmittance ................................ 210 nm≥20% K ............................................................. ≤0.5 mg/kg
transmittance ................................ 230 nm≥50% Mg ........................................................ ≤0.5 mg/kg
 ReagentPlus®, 99% transmittance ................................ 254 nm≥90% Na ............................................................. ≤2 mg/kg
110086-1L glass btl 1L Ca ............................................................. ≤0.5 mg/kg
110086-2.5L 2.5 L 34678-2.5L-R glass btl 2.5 L

Acetonitrile with 0.1% ammonium acetate, ≥98%
 PESTANAL®, solvent for residue analysis [148642‑19‑7]
suitability for residue analysis ................................................................................................................ ≤5 ng/L  LC-MS CHROMASOLV®
water .......................................................................................................................................... ≤0.05% (Karl Fischer) LC-MS tested
34481-1L 1L
≥98% acetonitrile basis (GC)
HPLC-gradient 254nm ................................................................................................................................. ≤50 mAU
34481-6X1L 6×1L
ammonium acetate .......................................................................................................... 0.093-0.107 % (w/v)
34481-2.5L 2.5 L
water ................................................................................................................................................. ≤2% (Karl Fischer)
34481-4X2.5L 4 × 2.5 L transmittance ............................. ≥254 nm≤90% Mg ........................................................ ≤0.5 mg/kg
Ca ............................................................. ≤0.5 mg/kg Na ............................................................. ≤2 mg/kg
Acetonitrile solution K ................................................................ ≤0.5 mg/kg
[75‑05‑8] Merck 14,55; 14,70 CH3CN FW 41.05
27
Danger H225-H332-H312-H302-H319 P210-P280-P305+P351
density ............................................................................................................................................. 0.782 g/mL, 25 °C +P338
 contains 0.1 % (v/v) acetic acid 34669-2.5L-R glass btl 2.5 L
Product filtered through a 0.2 μm filter
Acetonitrile with 0.1% formic acid, ≥99.5% (GC)
590754
 LC-MS CHROMASOLV®
 contains 0.1 % (v/v) ammonium hydroxide LC-MS tested
Product filtered through a 0.2 μm filter HPLC-gradient 254nm ................................................................................................................................. ≤50 mAU
639133 formic acid ............................................................................................................................................... 0.093-0.107%
transmittance ................................... 210 nm≥5% K ............................................................. ≤0.5 mg/kg
 contains 0.1 % (v/v) formic acid, for HPLC transmittance ................................ 230 nm≥15% Mg ........................................................ ≤0.5 mg/kg
Product filtered through a 0.2 μm filter transmittance ................................ 254 nm≥90% Na ............................................................. ≤2 mg/kg
Ca ............................................................. ≤0.5 mg/kg
27
Danger H225-H302-H312-H319-H332 P210-P280-P305 + P351
+ P338
27
576956-4L 4L + P338
576956-200L-LS Pure-Pac® 1 200 L 34668-2.5L-R glass btl 2.5 L
 contains 0.1 % (v/v) trifluoroacetic acid, for HPLC Acetonitrile with 0.1% formic acid and 0.01% trifluoroacetic
Product filtered through a 0.2 μm filter acid, ≥99.5% (GC)
574732-20L NOWPAK® 20 L  LC-MS CHROMASOLV®
574732-50L comp drum 50 L LC-MS tested
HPLC-gradient 254nm ................................................................................................................................. ≤50 mAU
 contains 0.05 % (v/v) trifluoroacetic acid formic acid ............................................................................................................................................... 0.009-0.107%
Product filtered through a 0.2 μm filter trifluoroacetic acid .............................................................................................................................. 0.009-0.011%
574724 transmittance ................................... 210 nm≥5% K ............................................................. ≤0.5 mg/kg
transmittance ................................ 230 nm≥15% Mg ........................................................ ≤0.5 mg/kg
 contains 0.035 % (v/v) trifluoroacetic acid, for HPLC transmittance ................................ 254 nm≥90% Na ............................................................. ≤2 mg/kg
565423-20L NOWPAK® 20 L Ca ............................................................. ≤0.5 mg/kg
7
34676-2.5L-R glass btl 2.5 L

AHB A, 0613, UNP EU
n Acetonitrile n
Acetonitrile with 0.1% trifluoroacetic acid, >99.5% (GC) Acetonitrile-13C2
 LC-MS CHROMASOLV® Methyl cyanide-13C2

LC-MS tested [1722‑25‑4] 13CH313CN FW 43.04
mp ....................................................................... −48 °C n20
D .......................................................................... 1.344
trifluoroacetic acid .............................................................................................................................. 0.093-0.107%
bp ..................................................................... 81-82 °C
transmittance ................................. 210 nm≥30% K ............................................................. ≤0.5 mg/kg
transmittance ................................. 230 nm≥50% Mg ........................................................ ≤0.5 mg/kg
 99 atom % 13C
transmittance ................................. 254 nm≥90% Na ............................................................. ≤2 mg/kg
Ca ............................................................. ≤0.5 mg/kg mol wt 43.02, atom % calculation
A 34976-2.5L-R glass btl 2.5 L
density ............................................................................................................................................. 0.824 g/mL, 25 °C
485217-250MG ampule 250 mg
Acetonitrile 50%, Water 47.5 % and Trifluoroacetic 8 Acetonitrile-13C2,15N
acid 2.5%, 50% acetonitrile basis (GC)
Methyl cyanide-13C2,15N
 LC-MS CHROMASOLV® [14149‑40‑7] 13CH313C15N FW 44.03
47.5% water basis (Karl Fischer) mp ....................................................................... −48 °C n20
D .......................................................................... 1.344
composition bp ..................................................................... 81-82 °C
trifluoroacetic acid 2.5%
 99 atom % 13C; 98 atom % 15N
27
Danger H225-H302-H315-H319 P210-P305 + P351 + P338
density ............................................................................................................................................. 0.843 g/mL, 25 °C
15
491675-250MG ampule 250 mg
Acetonitrile- N
15 Acetonitrile-d3
Methyl cyanide- N
[14149‑39‑4] CH3C15N FW 42.05 Trideuteroacetonitrile; Methyl-d3 cyanide
mp ....................................................................... −48 °C n20
D .......................................................................... 1.344 [2206‑26‑0] Beil. 2,IV,428 CD3CN FW 44.07
bp ..................................................................... 81-82 °C bp ........................................................................ 80.7 °C n20
D .......................................................................... 1.341
density ..................................... 0.844 g/mL, 25 °C
 98 atom % N 15
27
Danger H225-H302-H312-H319-H332
density ............................................................................................................................................. 0.805 g/mL, 25 °C
 "100%", 99.96 atom % D
27
P210-P280-P305 + P351 + P338
+ P338
233323-5G ampule 5g
487864-500MG ampule 500 mg
13
Acetonitrile-1- C
 "100%", 99.96 atom % D
Methyl cyanide-13C pk = 10 × 0.5 mL
[31432‑55‑0] Beil. 2,IV,427 CH313CN FW 42.04 P210-P280-P305 + P351 + P338
mp ....................................................................... −48 °C n20
D .......................................................................... 1.344
bp ..................................................................... 81-82 °C 237019-1PAK ampule 1 pkg
 99 atom % C 13  "100%", 99.96 atom % D

mol wt 42.04, atom % calculation pk = 10 × 0.75 mL
P210-P305 + P351 + P338
density ............................................................................................................................................. 0.805 g/mL, 25 °C
27
+ P338
 "100%", 99.96 atom % D
485160-500MG ampule 500 mg pk = 10 × 1 mL
13 15 P210-P280-P305 + P351 + P338
Acetonitrile-1- C, N
13 15 423106-1PAK ampule 1 pkg
Methyl cyanide- C, N
[14320‑89‑9] CH313C15N FW 43.04  "100%", 99.96 atom % D, contains 0.03 % (v/v) TMS
mp ....................................................................... −48 °C n20
D .......................................................................... 1.344 P210-P280-P305 + P351 + P338
bp ..................................................................... 81-82 °C
425796-1ML ampule 1 mL
 99 atom % 13C; 98 atom % 15N  99.8 atom % D
mol wt 43.01, atom % calculation P210-P305 + P351 + P338
density ............................................................................................................................................. 0.824 g/mL, 25 °C
151807-5G ampule 5g
485179-250MG ampule 250 mg
151807-10G ampule 10 g
Acetonitrile-2-13C 151807-25G glass btl 25 g
Methyl-13C cyanide 151807-50G glass btl 50 g
[1722‑09‑4] Beil. 2,IV,427 13
CH3CN FW 42.04 151807-100G Sure/Seal™ 100 g
mp ....................................................................... −48 °C n20
D .......................................................................... 1.339
bp ..................................................................... 81-82 °C
 99.8 atom % D
P210
 99 atom % C 13
density ............................................................................................................................................. 0.805 g/mL, 25 °C
 99.8 atom % D
pk = 5 × 0.5 mL
27
P210-P280-P305 + P351 + P338
+ P338
277223-250MG ampule 250 mg
277223-1G ampule 1g

AHB A, 0613, UNP EU
n Acetovanillone n
 99.8 atom % D 8 > (±)-3-(α-Acetonyl-p-chlorobenzyl)-4-hydroxycoumarin, see Coumachlor

density ................................................................................................................................................ .844 g/mL, 25 °C Page 781
Acetonyltriphenylphosphonium chloride, see 2-Oxopropyltriphenylphos-
P210-P280-P305 + P351 + P338 phonium chloride Page 1965
718289-10X0.5ML ampule 10 × 0.5 mL
718289-10X0.6ML ampule 10 × 0.6 mL Acetophenone, 99%
Methyl phenyl ketone
 99.8 atom % D [98‑86‑2] Merck 14,73; Beil. 7,IV,619; Fieser 4,5 CH3COC6H5
pk = 10 × 0.75 mL FW 120.15
P210-P280-P305 + P351 + P338
mp ............................................................ 19 to 20 °C
bp ......................................................................... 202 °C
vd
vp
............................................................... 4.1 (vs air)
......................................... 0.45 mmHg (25 °C)
A
density ........................................ 1.03 g/mL, 25 °C vp ................................................ 1 mmHg (15 °C)
 99.8 atom % D n20
D .............................................................................. 1.534 ait ...................................................................... 1058 °F
pk = 10 × 1 mL
P210-P280-P305 + P351 + P338  ReagentPlus ®
7
236861-1PAK ampule 1 pkg Warning H302-H319 P305 + P351 + P338
236861-.5PAK ampule 5 × 1 mL
A10701-100ML 100 mL
 99.8 atom % D A10701-1L 1L
P210-P280-P305 + P351 + P338
Acetophenone-2′,3′,4′,5′,6′-d5
Acetophenone-(phenyl)-d5
 "Special HOH", 99.8 atom % D [28077‑64‑7] Beil. 7,626 C6D5COCH3 FW 125.18
P210-P280-P305 + P351 + P338 mp ............................................................ 19 to 20 °C n20 D ....................................................................... 1.5335
699543-10G glass btl 10 g bp ......................................................................... 202 °C
 99 atom % D
 99.8 atom % D, contains 0.03 % (v/v) TMS density ............................................................................................................................................. 1.073 g/mL, 25 °C
P210-P305 + P351 + P338 319856-5G ampule 5g
366544-5G ampule 5g
Acetophenone-β,β,β-d3
366544-10G ampule 10 g
Acetophenone-methyl-d3
[17537‑31‑4] Beil. 7,IV,626 C6H5COCD3 FW 123.17
mp ............................................................ 19 to 20 °C n20 D ....................................................................... 1.5329
 99.8 atom % D, contains 0.03 % (v/v) TMS bp ......................................................................... 202 °C

P210-P280-P305 + P351 + P338
 99 atom % D
702579-1PAK 1 pkg mol wt 123.14, atom % calculation
density ............................................................................................................................................. 1.055 g/mL, 25 °C
P210-P280-P305 + P351 + P338 318019-10G ampule 10 g
613134-10G glass btl 10 g Acetophenone-d8
[19547‑00‑3] C6D5COCD3 FW 128.20
 99.8 atom % D, contains 1 % (v/v) TMS mp ............................................................ 19 to 20 °C n20 D ....................................................................... 1.5322
P210-P280-P305 + P351 + P338 bp ......................................................................... 202 °C
233331-25G glass btl 25 g  98 atom % D

233331-50G glass btl 50 g mol wt 128.04, atom % calculation
density ............................................................................................................................................. 1.098 g/mL, 25 °C
(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexa-
fluoroantimonate 296732-1G glass btl 1g
[866641‑66‑9] C22H30AuF6NPSb FW 772.17 > Acetophenone-4-carboxylic acid, see 4-Acetylbenzoic acid Page 34
Au N C CH3
t-Bu P t-Bu
Acetophenone enol trimethylsilyl ether, see 1-Phenyl-1-trimethylsiloxy-
ethylene Page 2056
SbF6-
Acetophenone oxime, 95%

mp ..................................................................................................................................................... 198 to 203 °C (D) [613‑91‑2] C8H9NO FW 135.16 OH
N
79
CH3

697575-1G glass btl 1g mp ............................................................ 55 to 60 °C density .................................... 1.11 g/mL, 25 °C
> Acetonyl acetate, see Acetoxyacetone Page 30 bp .................................... 118-120 °C/20 mmHg
Acetonylacetone, see 2,5-Hexanedione Page 1436
57
Danger H302-H318 P280-P305 + P351 + P338
3-(α-Acetonylbenzyl)-4-hydroxycoumarin sodium salt, ≥98%

4-Hydroxy-3-(3-oxo-1-phenylbutyl)coumarin 647659-25G glass btl 25 g
[129‑06‑6] Merck 14,10038 C19H15O4Na FW 330.31
> Acetophenone-4-sulfonyl chloride, see 4-Acetylbenzenesulfonyl chloride
Isopropanol .................................................................................................................................................................. ~8%
Page 34
water ............................................................................................................................................ may contain traces Acetovanillone, see 4′-Hydroxy-3′-methoxyacetophenone Page 1491
68
Danger H300-H360 P201-P264-P301 + P310-P308 + P313

AHB A, 0613, UNP EU
n Acetoxyaceticac n
Acetoxyacetic acid, 99% 1-Acetoxy-1,3-butadiene, mixture of cis and trans

[13831‑30‑6] Beil. 3,233 CH3CO2CH2CO2H FW 118.09 1,3-Butadienyl acetate
mp .................................................................................................................................................................... 67 to 69 °C [1515‑76‑0] Beil. 2,III,295; Fieser 1,7 CH2=CHCH=CHOCOCH3
bp ............................................................................................................................................ 141-142 °C/12 mmHg FW 112.13
bp .......................................... 60-61 °C/40 mmHg n20
D .......................................................................... 1.469
5
Danger H314 P280-P305 + P351 + P338-P310
density ..................................... 0.945 g/mL, 25 °C vp ............................................. 40 mmHg (60 °C)
302341-5G glass btl 5g contains 0.1% p-tert-butylcatechol. as stabilizer
A 26
302341-25G glass btl 25 g Danger H226-H302-H311-H315-H319-H335 P261-P280-P305
+ P351 + P338-P312
Acetoxyacetone, ≥98.0% (GC)
Acetonyl acetate
[592‑20‑1] Beil. 2,IV,297 CH3COCH2OCOCH3 FW 116.12 [3R(1′R,4R)]-(+)-4-Acetoxy-3-[1-(tert-butyldimethylsilyloxy)
ethyl]-2-azetidinone, 98%
bp ....................................................................................................................................................................... 174-176 °C
density ............................................................................................................................................. 1.075 g/mL, 20 °C [76855‑69‑1] C13H25NO4Si FW 287.43 CH3
H3 C O Si t-Bu
 technical O
H CH3
n20
D ...................................................................................................................................................................................... 1.415 H3C O O
N
00803-10ML glass btl 10 mL H
Acetoxyacetyl chloride, 97% mp .............................................................................................................................................................. 107 to 109 °C

[13831‑31‑7] Beil. 3,240 CH3CO2CH2COCl FW 136.53 [α]20
n20
79
bp .................................................. 55 °C/12 mmHg D .......................................................................... 1.428 Warning H317-H319-H411 P273-P280-P305 + P351 + P338
density ........................................ 1.27 g/mL, 25 °C
57
Danger H314-H335-EUH014 P261-P280-P305 + P351 + P338- 375845-1G glass btl 1g
P310
4-Acetoxybutylzinc bromide
H3CCO2(CH2)4ZnBr FW 260.44
density ............................................................................................................................................. 0.985 g/mL, 25 °C
4-Acetoxy-2-azetidinone, 99%
 0.5 M in THF
[28562‑53‑0] Beil. 21,V,12,4 C5H7NO3 FW 129.11 O
O 630403-50ML Sure/Seal™ 50 mL
NH
H3C O (R)-5-Acetoxy-1-chlorohexane, 99%
mp .................................................................................................................................................................... 38 to 40 °C [154885‑34‑4] CH3CO2CH(CH3)[(CH2)4Cl] FW 178.66
58
Danger H314-H334 P261-P280-P305 + P351 + P338-P310
> 1-Acetoxy-1-cyanoethylene, see 1-Cyanovinyl acetate Page 799
272159-5G glass btl 5g (1R,2R)-trans-2-Acetoxy-1-cyclopentanol, ≥99.0% (GC, sum of
enantiomers)
4-Acetoxybenzaldehyde, 98%
[105663‑22‑7] C7H12O3 FW 144.17
4-Formylphenyl acetate
[878‑00‑2] Beil. 8,74 CH3CO2C6H4CHO FW 164.16
bp ..................................... 152-153 °C/17 mmHg n20 D .......................................................................... 1.538 (1R,4S)-cis-4-Acetoxy-2-cyclopenten-1-ol, ≥98.0% (GC, sum of
density ..................................... 1.168 g/mL, 25 °C enantiomers)
7
Warning H315-H319-H335 P261-P305 + P351 + P338 (1S,4R)-cis-4-Hydroxy-2-cyclopentenyl acetate H3C O OH
[60176‑77‑4] C7H10O3 FW 142.15
O
> 2-Acetoxybenzoic acid, see Acetylsalicylic acid Page 45 D −67±2°, c = 2.3 in chloroform
[α]20
mp ................................................................................................................................................................... 49 to 51 °C
3-Acetoxybenzoic acid, 98% 00848-500MG glass btl 500 mg
[6304‑89‑8] Beil. 10,138 CH3CO2C6H4CO2H FW 180.16
(1S,4R)-cis-4-Acetoxy-2-cyclopenten-1-ol, ≥99%
mp .............................................................................................................................................................. 131 to 134 °C
(1R,3S)-(+)-cis-4-Cyclopentene-1,3-diol 1-acetate; (1R,3S)-4-Cyclo-
7
Warning H315-H319-H335 P261-P305 + P351 + P338
pentene-1,3-diol 1-acetate; (1R,4S)-cis-4-Hydroxy-2-cyclopentenyl
acetate
[60410‑16‑4] C7H10O3 FW 142.15
4-Acetoxybenzoic acid, 96% mp ................................................................................................................................................................... 49 to 51 °C
[2345‑34‑8] Beil. 10,IV,358 CH3CO2C6H4CO2H FW 180.16 Building block for the synthesis of carbocyclic nucleosides and
mp .............................................................................................................................................................. 190 to 194 °C prostaglandins.1,2,3
[α]20
D +68°, c = 2.3 in chloroform
7
Warning H315-H319-H335 P261-P305 + P351 + P338
contains 0.006% amylene as stabilizer
Lit. cited: 1. Theil, F. et al., J. Chem. Soc. Perkin Trans. I 255 (1996)
248517-50G glass btl 50 g 2. Myers, A.G. et al., Tetrahedron Lett. 37, 3083 (1996)
248517-250G glass btl 250 g 3. Paquette, L.A. et al., Org. Synth. 73, 36 (1995)
> 2-Acetoxybenzoic anhydride, see O-Acetylsalicylic anhydride Page 45 446041-50MG glass btl 50 mg
3-Acetoxy-5-bromoindole, see 5-Bromoindoxyl acetate Page 482 446041-1G glass btl 1g

AHB A, 0613, UNP EU
n Acetoxysuccinic n
1-Acetoxy-4-diethylamino-2-butyne, 97% 2-Acetoxyphenylboronic acid pinacol ester

[22396‑77‑6] H3CCO2CH2C≡CCH2N(C2H5)2 FW 183.25 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl acetate
543160 Full product information at Aldrich.com [480424‑68‑8] C6H4OCOCH3BO2C2(CH3)4 FW 262.11
mp ................................................................................................................................................................... 47 to 51 °C
> (S)-3-Acetoxy-dihydro-2,5-furandione, see (S)-(−)-2-Acetoxysuccinic
anhydride Page 32 570184-5G glass btl 5g
(R)-2-Acetoxy-3,3-dimethylbutyronitrile, ≥99.0% (GC, sum of 3-Acetoxyphenylboronic acid pinacol ester, 97%

enantiomers)
A
[480424‑69‑9] C6H4OCOCH3BO2C2(CH3)4 FW 262.11
[126567‑38‑2] C8H13NO2 FW 155.19 570192-1G glass btl 1g
00851 Full product information at Aldrich.com 570192-5G glass btl 5g
> trans-3-Acetoxy-1,3-diphenylpropene, see (±)-trans-1,3-Diphenylallyl acetate 4-Acetoxyphenylboronic acid pinacol ester, 97%
Page 1139
3-Acetoxyindole, see Indoxyl acetate Page 1537 [480424‑70‑2] C6H4OCOCH3BO2C2(CH3)4 FW 262.11
4-Acetoxyindole, see 4-Indolyl acetate Page 1537 570206-1G glass btl 1g
1-Acetoxy-4-iodobutane, see 4-Iodobutyl acetate Page 1544
α-Acetoxyisobutyryl chloride, see 1-Chlorocarbonyl-1-methylethyl acetate > 4-(4-Acetoxyphenyl)-2-butanone, see 4-(3-Oxobutyl)phenyl acetate
Page 660 Page 1962
2′,4′-Acetoxylidide, see 2′,4′-Dimethylacetanilide Page 1056
2′,6′-Acetoxylidide, see 2′,6′-Dimethylacetanilide Page 1056
4-(Acetoxymercurio)aniline, see 4-Aminophenylmercuric acetate 2-Acetoxyphenylzinc iodide
Page 155 CH3CO2C6H4ZnI FW 327.43
4-Acetoxy-3-methoxycinnamaldehyde, predominantly trans,  0.5 M in THF
95% 630357-50ML Sure/Seal™ 50 mL
[83071‑67‑4] CH3CO2C6H3(OCH3)CH=CHCHO FW 220.22
3-Acetoxyphenylzinc iodide solution
C8H7IO2Zn FW 327.43
4-Acetoxy-3-methoxyphenylboronic acid pinacol ester, 97%
 0.5 M in THF
C15H21BO5 FW 292.14
630373-50ML Sure/Seal™ 50 mL
4-Acetoxyphenylzinc iodide solution
2-[(Acetoxymethyl)allyl]trimethylsilane, 99%
C8H7IO2Zn FW 327.43
2-(Trimethylsilylmethyl)-2-propen-1-yl acetate; 2-Acetoxymethyl-3-(tri-
methylsilyl)propene; 2-(Trimethylsilylmethyl)allyl acetate  0.5 M in THF
[72047‑94‑0] Fieser 13,3; 14,332 CH3CO2CH2C(=CH2)CH2Si(CH3)3 630365-50ML Sure/Seal™ 50 mL
FW 186.32 (±)-2-Acetoxypropionic acid, ≥97.0% (GC)
bp ..................................................... 95 °C/7 mmHg n20
D .......................................................................... 1.440
density ..................................... 0.877 g/mL, 25 °C [535‑17‑1] Beil. 3,IV,638 CH3COOCH(CH3)COOH FW 132.11
density ............................................................................................................................................. 1.176 g/mL, 20 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
n20
D ...................................................................................................................................................................................... 1.423
7
339830-1G glass btl 1g Warning H315-H319-H335 P261-P305 + P351 + P338
3-Acetoxy-2-methylbenzoic acid, 97% 00878-25ML 25 mL
[168899‑58‑9] CH3CO2C6H3(CH3)CO2H FW 194.18
(S)-(−)-2-Acetoxypropionyl chloride, 97%
AP-Cl; O-Acetyl-L-lactyl chloride
5-Acetoxymethyl-2-furaldehyde, 99% [36394‑75‑9] Beil. 3,II,189 CH3CH(O2CCH3)COCl FW 150.56
[10551‑58‑3] Beil. 18,15 C8H8O4 FW 168.15 bp .................................................... 50 °C/5 mmHg n20
D .......................................................................... 1.423
H3C O H density ..................................... 1.189 g/mL, 25 °C

O
O O D −31°, c = 4 in chloroform
[α]20
5
Danger H314 P280-P305 + P351 + P338-P310
mp .................................................................................................................................................................... 53 to 55 °C
7
Warning H319 P305 + P351 + P338
145424-10G glass btl 10 g > (2-Acetoxypropyl)trimethylammonium chloride, see Acetyl-β-methylcholine

chloride Page 41
> 2-Acetoxy-2-methylpropionyl chloride, see 1-Chlorocarbonyl-1-methylethyl (R)-(+)-2-Acetoxysuccinic anhydride, 96%

acetate Page 660
(R)-3-Acetoxy-dihydro-2,5-furandione; O-Acetyl-D- O CH3
malic anhydride
5-Acetoxypentylzinc bromide O
[79814‑40‑7] Beil. 18,V,2,470 C6H6O5 FW 158.11 O O O
H3CCO2(CH2)5ZnBr FW 274.47
mp ................................................................................................................................................................... 56 to 58 °C
 0.5 M in THF
[α]20
630381 Full product information at Aldrich.com ee (GLC): 99%
> (R)-(−)-α-Acetoxyphenylacetic acid, see (R)-(−)-O-Acetylmandelic acid
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Page 41
(S)-(+)-α-Acetoxyphenylacetic acid, see (S)-(+)-O-Acetylmandelic acid
Page 41 441570-1G glass btl 1g

AHB A, 0613, UNP EU
n Acetoxysuccinic n
(S)-(−)-2-Acetoxysuccinic anhydride, 98% (Acetylacetonato)dicarbonylrhodium(I)

(S)-3-Acetoxy-dihydro-2,5-furandione; O-Acetyl-L-malic anhydride Dicarbonyl-acetylacetonato-rhodium(I); Dicarbonylrhodium(I) 2,4-
[59025‑03‑5] Beil. 18,V,2,479 C6H6O5 FW 158.11 pentanedionate; Rhodium(I) dicarbonyl acetylacetonate; Rh(CO)2acac
mp .................................................................................................................................................................... 54 to 56 °C [14874‑82‑9] Rh(CO)2(C5H7O2) FW 258.03
D −27°, c = 1 in chloroform
[α]20 solid
ee (GLC): 98% mp .............................................................................................................................................................. 154 to 156 °C
7 6
Warning H315-H319-H335 P261-P305 + P351 + P338 Danger H301-H315-H317-H319-H335-EUH044 P261-P280-P301 +
A
P310-P305 + P351 + P338
422800-5G glass btl 5g  98%
422800-25G glass btl 25 g Employed in in situ formation of a fluorous-soluble hydroformylation
> (R)-3-Acetoxy-4-(trimethylammonio)butyrate hydrochloride, see O-Acetyl-L-
catalyst of interest in molecular engineering.1
carnitine hydrochloride Page 36 Lit. cited: 1. Horvath, I.T. et al., J. Am. Chem. Soc. 120, 3133 (1998)
Aceturic acid nitrile, see N-(Cyanomethyl)acetamide Page 795 288101-1G glass btl 1g
Acetylacetaldehyde dimethylacetal, see 4,4-Dimethoxy-2-butanone
Page 1043
3-Acetylacetanilide, see 3′-Acetamidoacetophenone Page 16
 98%
Acetylacetonamine, see 4-Amino-3-penten-2-one Page 152 Product of Umicore
(Acetylacetonato)(bicyclo[2.2.1]hepta-2,5-diene)rhodium(I), see (Acetylace- 683183-500MG glass btl 500 mg
tonato)(norbornadiene)rhodium(I) Page 32
Acetylacetonatobis(ethylene)rhodium(I), 95% 8
2 (Acetylacetonato)(norbornadiene)rhodium(I)
Bis(η -ethene)(2,4-pentanedionato-κO,κO′) H2C CH2
rhodium; (2,4-Pentanedionato)bis(ethylene) (Acetylacetonato)(bicyclo[2.2.1]hepta-2,5-diene) H3C
Rh CH2
rhodium; Bis(ethylene)rhodium(I) acetylacetonate; O O rhodium(I) O
CH2 Rh
Diethylene(acetylacetonato)rhodium; Bis(ethylene) H3C CH3 [32354‑50‑0] C12H15O2Rh FW 294.15 O
(2,4-pentanedionato)rhodium H3C
[12082‑47‑2] C9H15O2Rh FW 258.12

mp .............................................................................................................................................................. 176 to 178 °C
mp .............................................................................................................................................................. 141 to 142 °C
A product of Umicore.
7
Warning H315-H319-H335 P261-P305 + P351 + P338
(Acetylacetonato)(1,5-cyclooctadiene)iridium(I) 683116-500MG glass btl 500 mg

Ir(acac)(COD) H3C
[12154‑84‑6] C13H19IrO2 FW 399.51 O Acetylacetone
Ir
O 2,4-Pentanedione
H3C
[123‑54‑6] Merck 14,81; Beil. 1,IV,3662; Fieser 1,10 CH3COCH2COCH3
mp ............................................................................................................................................... 150 to 155 °C (dec.) FW 100.12
mp ....................................................................... −23 °C vd ............................................................... 3.5 (vs air)
7
Warning H315-H319-H335 P261-P305 + P351 + P338 bp ..................................................................... 140.4 °C vp ................................................ 6 mmHg (20 °C)
429155-100MG glass btl 100 mg n20
D .............................................................................. 1.452

27
Warning H226-H302
A product of Umicore.
 ReagentPlus®, ≥99%
Transition-metal chelating agent
P7754-250ML-A 250 mL
(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I) P7754-1L-A glass btl 1L
Rh(acac)(COD) P7754-2.5L-A 2.5 L
[12245‑39‑5] C13H19O2Rh FW 310.19
 AcAc
solid
Wacker quality, ≥99.5% (GC)
mp .............................................................................................................................................................. 138 to 140 °C
product of Wacker Chemie AG
7
Warning H315-H319-H335 P261-P305 + P351 + P338 prices for bulk quantities on request
10916-1KG poly btl 1 kg
 99% 10916-25KG 25 kg
> Acetylacetoneguanidine, see 2-Amino-4,6-dimethylpyrimidine Page 118
 99% 5-Acetylamino-6-amino-3-methyluracil-ring-13C4,15N2, 8
Product of Umicore amino-15N, 98% (CP)
683108-500MG glass btl 500 mg N-(4-Amino-1,2,3,6-tetrahydro-1-methyl-2,6- O
683108-2G glass btl 2g dioxo-5-pyrimidinyl)acetimide-13C4,15N3 H3C
H
N 13C
CH3
(ring-13C4,15N2,amino-15N); AAMU-13C4,15N3 13C 15N
(Acetylacetonato)dicarbonyliridium(I) O
(ring-13C4,15N2,amino-15N) 13C 13C
13
[14023‑80‑4] Ir(acac)(CO2) FW 347.35 C4C3H1015N3NO3 FW 205.13 H215N 15N O
H
78
Warning H302-H312-H315-H319-H332-H335-H361 P261-
P280-P305 + P351 + P338
mp ............................................................................................................................................................................... 305 °C
429147-250MG glass btl 250 mg store at: 2-8°C

AHB A, 0613, UNP EU
n Acetylaspartica n
 99 atom % C; 98 atom % N 13 15 3′-Acetylamino-4′-methoxyacetophenone, 97%

mol wt 205.03, atom % calculation [74896‑31‑4] CH3COC6H3(OCH3)NHCOCH3 FW 207.23
705578-1MG 1 mg 651524 Full product information at Aldrich.com
705578-5MG 5 mg
5-Acetyl-2-amino-4-methylthiazole, 97%
4-Acetylamino-2-(bis(2-hydroxyethyl)amino)anisole, 97%
[30748‑47‑1] C6H8N2OS FW 156.21 H3C
3′-[Bis(2-hydroxyethyl)amino]-4′-methoxyacetamide N
H 3C
[24530‑67‑4] CH3C(O)NHC6H3(OCH3)N(CH2CH2OH)2 FW 268.31
A
S NH2
mp .............................................................................................................................................................. 116 to 120 °C O
556742-25G glass btl 25 g mp ............................................................................................................................................... 268 to 272 °C (dec.)
7
2-Acetylamino-3-bromo-5-methylpyridine, 97% Warning H315-H319-H335 P261-P305 + P351 + P338
N-(3-Bromo-5-methyl-2-pyridinyl)acetylamide H3C Br
O 586145-1G glass btl 1g
[142404‑83‑9] C8H9BrN2O FW 229.07
N N CH3 586145-5G glass btl 5g
H
> 4-Acetylamino-3-nitrobenzoic acid, see 4-Acetamido-3-nitrobenzoic acid
mp .................................................................................................................................................................... 97 to 99 °C Page 18
N-Acetyl-4-aminophenol, see 4-Acetamidophenol Page 18
57
Danger H302-H317-H318 P280-P305 + P351 + P338 2-Acetylaniline, see 2′-Aminoacetophenone Page 89
3-Acetylaniline, see 3′-Aminoacetophenone Page 90
643483-1G glass btl 1g 4-Acetylaniline, see 4′-Aminoacetophenone Page 90
2-Acetylanisole, see 2′-Methoxyacetophenone Page 1688
2-Acetylamino-5-bromo-3-methylpyridine, 97% 3-Acetylanisole, see 3′-Methoxyacetophenone Page 1688
4-Acetylanisole, see 4′-Methoxyacetophenone Page 1688
[142404‑81‑7] C8H9BrN2O FW 229.07
2-Acetylanthracene, 98%
57
Danger H302-H317-H318 P280-P305 + P351 + P338
1-(2-Anthracenyl)ethanone; 1-(2-Anthracenyl) O
643505-1G glass btl 1g acetone
CH3
[10210‑32‑9] C16H12O FW 220.27
2-Acetylamino-5-bromo-4-methylpyridine, 97%
[142404‑82‑8] C8H9BrN2O FW 229.07 mp .............................................................................................................................................................. 189 to 192 °C
578
Danger H302-H315-H317-H318-H334-H335 P261-
P280-P305 + P351 + P338-P342 + P311 566780-1G glass btl 1g
643491-1G glass btl 1g 9-Acetylanthracene, 98%

2-Acetylamino-5-bromo-6-methylpyridine, 97% [784‑04‑3] Beil. 7,II,450 C16H12O FW 220.27 O CH3
[142404‑84‑0] C8H9BrN2O FW 229.07
578
Danger H302-H315-H317-H318-H334-H335 P261-
P280-P305 + P351 + P338-P342 + P311
643475-1G glass btl 1g mp ................................................................................................................................................................... 75 to 76 °C
2-Acetylamino-5-bromopyridine, 98%
[7169‑97‑3] C7H7BrN2O FW 215.05 Br
O N-Acetylanthranilic acid, 99%
N N
H
CH3 2-Acetamidobenzoic acid
[89‑52‑1] Beil. 14,IV,1041 (CH3CONH)C6H4CO2H FW 179.17
mp .............................................................................................................................................................. 175 to 179 °C mp .............................................................................................................................................................. 184 to 187 °C
7
Warning H302-H315-H317-H319-H335 P261-P280-P305 + P351 +
7
Warning H302
P338
646407-1G glass btl 1g A12658-25G poly btl 25 g
646407-10G glass btl 10 g A12658-100G poly btl 100 g
> (R)-2-(Acetylamino)-3-O-(1-carboxyethyl)-2-deoxy-D-glucose, see N-Acetyl- Nα-Acetyl-L-asparagine, 98%
muramic acid Page 42
4-N-Acetyl-amino-cyclohexanone, see 4-Acetamidocyclohexanone [4033‑40‑3] Beil. 4,III,1517 H2NCOCH2CH(NHCOCH3)CO2H
Page 17 FW 174.15
5-Acetylamino-2,4-dichlorophenol, see 2′,4′-Dichloro-5′-hydroxyacetanilide
Page 927 mp .............................................................................................................................................................. 168 to 170 °C
4-Acetylamino-2-(diethylamino)anisole, 97%
N-Acetyl-L-aspartic acid, ≥99.0% (T)
[19433‑93‑3] CH3C(O)NHC6H3(OCH3)N(CH2CH3)2 FW 236.31
[997‑55‑7] Merck 14,840; Beil. 4,IV,3015
HO2CCH2CH(NHCOCH3)CO2H FW 175.14
1-Acetyl-6-aminoindoline mp .............................................................................................................................................................. 137 to 140 °C
[62368‑29‑0] C10H12N2O FW 176.22 [α]20
D +12±1°, c = 2 in 6 M HCl
Review;1 acetyl donor in acetylcholine formation in brain.2
H2N N CH3
mp .............................................................................................................................................................. 141 to 144 °C
O Lit. cited: 1. R. Bakhash, E. Wertman, Bios (Madison, N.J.) 49, 13 (1978)
2. G.E. Gibson, M. Shimada, Biochem. Pharmacol. 29, 167 (1980)
 powder 00920-5G glass btl 5g
color ........................................................................................................................................................... yellow to tan 00920-25G glass btl 25 g
7
Warning H302-H319 P305 + P351 + P338 store at: 2-8°C
A7675-1G poly btl 1g

AHB A, 0613, UNP EU
n Acetylazaindole n
3-Acetyl-7-azaindole, 97% 8 4-Acetylbenzoic acid, 98%

1-(1H-Pyrrolo[2,3-b]pyridin-3-yl)ethanone O
Acetophenone-4-carboxylic acid
[83393‑46‑8] C9H8N2O FW 160.17 [586‑89‑0] Beil. 10,IV,2769 CH3COC6H4CO2H FW 164.16
CH3
mp .............................................................................................................................................................. 208 to 210 °C
N N
H 177458-1G glass btl 1g
177458-10G poly btl 10 g
mp .............................................................................................................................................................. 202 to 206 °C
3-Acetylbenzonitrile, 97%
A 7
P338
3′-Cyanoacetophenone
702137-1G glass btl 1g [6136‑68‑1] Beil. 10,694 CH3COC6H4CN FW 145.16
1-Acetyl-7-azaindole-3-carbonitrile, 97% mp ................................................................................................................................................................. 98 to 100 °C
7
Warning H302-H312-H315-H319-H332-H335 P261-P280-P305 + P351
1-Acetyl-3-cyano-7-azaindole; 1-Acetyl-1H-pyrrolo[2,3- CN + P338
b]pyridine-3-carbonitrile
[860362‑11‑4] C10H7N3O FW 185.18 292214-1G glass btl 1g
N N CH3
O
4-Acetylbenzonitrile, 99%
mp .............................................................................................................................................................. 165 to 169 °C
4′-Cyanoacetophenone
56
Danger H301-H312-H315-H318-H332-H335 P261-P280-P301
+ P310-P305 + P351 + P338
[1443‑80‑7] Beil. 10,III,3030 CH3COC6H4CN FW 145.16
mp ................................................................................................................................................................... 56 to 59 °C
7
Warning H302
2-Acetylbenzaldehyde, 95%
2-Formylacetophenone 154393-5G glass btl 5g
[24257‑93‑0] CH3C(O)C6H4CHO FW 148.16 154393-25G glass btl 25 g
mp .................................................................................................................................................................... 39 to 43 °C N-Acetylbenzoquinoneimine
NAPQI; N-(4-Oxo-1-cyclohexa-2,5-dienylidene) N CH3
3-Acetylbenzaldehyde, 95% acetamide; N-Acetyl-p-benzo-quinoneimine
O
[50700‑49‑7] Merck 14,57 C8H7NO2 FW 149.15 O
3-Formylacetophenone
[41908‑11‑6] CH3C(O)C6H4CHO FW 148.16 Acetaminophen metabolite that reacts with serum proteins.
mp .................................................................................................................................................................... 51 to 55 °C store at: −20°C
562904-1G glass btl 1g A7300-1MG serum btl 1 mg
A7300-5MG serum btl 5 mg
4-Acetylbenzaldehyde, 97%
> N-Acetyl-p-benzo-quinoneimine, see N-Acetylbenzoquinoneimine
4-Formylacetophenone Page 34
[3457‑45‑2] CH3COC6H4CHO FW 148.16
mp .................................................................................................................................................................... 33 to 36 °C 6-Acetyl-2(3H)-benzothiazolone, 97%
516333-1G glass btl 1g C9H7NO2S FW 193.22
516333-5G glass btl 5g 663182 Full product information at Aldrich.com
4-Acetylbenzenesulfonyl chloride, ≥95.0% (AT) 2-Acetylbenzothiophene, 97%
Acetophenone-4-sulfonyl chloride O 1-Benzo[b]thiophen-2-yl-ethanone O
[1788‑10‑9] C8H7ClO3S FW 218.66 S Cl [22720‑75‑8] C10H8OS FW 176.23
O CH3
H3C S
O
mp ................................................................................................................................................................... 86 to 90 °C
mp .................................................................................................................................................................... 84 to 87 °C Starter in benzothiophene chemistry.1
Lit. cited: 1. Heterocycles 45, 1363 (1997)
5
Danger H314 P280-P305 + P351 + P338-P310
7
Warning H302
00933-50G glass btl 50 g 683477-1G glass btl 1g
> 2-Acetylbenzofuran, see 2-Benzofuranyl methyl ketone Page 235
> 1-Acetylbenzotriazole, see 1-Acetyl-1H-benzotriazole Page 34
2-Acetylbenzoic acid, 99%
1-Acetyl-1H-benzotriazole, 97%
3-Hydroxy-3-methylphthalide; Acetophenone-2-carboxy- O
lic acid 1-Acetylbenzotriazole N
OH
[577‑56‑0] Beil. 10,IV,2766 C9H8O3 FW 164.16 [18773‑93‑8] C8H7N3O FW 161.16 N
CH3 N CH3
O O
mp .............................................................................................................................................................. 115 to 117 °C mp ................................................................................................................................................................... 46 to 50 °C
7
A12801-5G glass btl 5g Warning H302
3-Acetylbenzoic acid, 98%
> 3-Acetylbenzotrifluoride, see 3′-(Trifluoromethyl)acetophenone Page 2502
[586‑42‑5] CH3COC6H4CO2H FW 164.16 4-Acetylbenzotrifluoride, see 4′-(Trifluoromethyl)acetophenone Page 2502
mp .............................................................................................................................................................. 169 to 171 °C

AHB A, 0613, UNP EU
n Acetylbutyryl n
6-Acetyl-2H-1,4-benzoxazin-3(4H)-one, 98% density ............................................................................................................................................. 1.552 g/mL, 25 °C

n20
D ...................................................................................................................................................................................... 1.572
[26518‑71‑8] C10H9NO3 FW 191.18 O H
7
N O Warning H302-H315-H319-H335 P261-P305 + P351 + P338
H3C
O 706701-250MG glass btl 250 mg

mp .............................................................................................................................................................. 193 to 195 °C 3-Acetyl-5-bromopyridine, 97% 8
7
Warning H315-H319-H335 P261-P305 + P351 + P338
1-(5-Bromopyridin-3-yl)ethanone
A
O
[38940‑62‑4] C7H6BrNO FW 200.03 Br
475491-5G glass btl 5g CH3
N
> Acetyl benzoyl, see 1-Phenyl-1,2-propanedione Page 2046
mp ................................................................................................................................................................... 90 to 94 °C
(S)-(+)-3-Acetyl-4-benzyl-2-oxazolidinone, 99%
7
[132836‑66‑9] C12H13NO3 FW 219.24 O
N CH3 703893-1G glass btl 1g

O O
5-Acetyl-2-bromopyridine, 97%
mp .............................................................................................................................................................. 104 to 106 °C 3-Acetyl-6-bromopyridine O
Versatile chiral auxiliary for asymmetric synthesis.1 [139042‑59‑4] C7H6BrNO FW 200.03
CH3
[α]20
D +110°, c = 1 in methanol
Br N
Lit. cited: 1. Ager, D.J., et al., Aldrichimica Acta 30, 3 (1997)
7
Warning H315-H319-H335 P261-P305 + P351 + P338 mp .............................................................................................................................................................. 124 to 128 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
4-Acetylbiphenyl, 98% 595942-1G glass btl 1g

4-Phenylacetophenone; 4-Biphenyl methyl ketone
[92‑91‑1] Beil. 7,IV,1407 C6H5C6H4COCH3 FW 196.24 2-Acetyl-3-bromothiophene, 97%
mp .............................................................................................................................................................. 116 to 118 °C 1-(3-Bromo-2-thienyl)ethanone Br
122726-25G glass btl 25 g [42877‑08‑7] C6H5BrOS FW 205.07
CH3
S
Acetyl bromide, 99% O
[506‑96‑7] Merck 14,82; Beil. 2,IV,398; Fieser 6,9 CH3COBr FW 122.95
mp ....................................................................... −96 °C n20 mp ................................................................................................................................................................... 28 to 35 °C
D ............................................................................. 1.45
bp ..................................................................... 75-77 °C vd ................................................................ 4.3 (vs air) n20
D ...................................................................................................................................................................................... 1.612
7
density ..................................... 1.663 g/mL, 25 °C vp .......................................... 92.2 mmHg (25 °C) Warning H302-H317-H319 P280-P305 + P351 + P338
5
Danger H314-EUH014 P280-P305 + P351 + P338-P310
135968-100G glass btl 100 g 633054-25G glass btl 25 g
135968-500G glass btl 500 g
2-Acetyl-5-bromothiophene, 99%
Acetyl-1-13C bromide 5-Bromo-2-thienyl methyl ketone
[5370‑25‑2] Beil. 17,288 C6H5BrOS FW 205.07 CH3
[79385‑25‑4] CH313COBr FW 123.94 Br S
O
 99 atom % 13
C
491691-1G ampule 1g mp ................................................................................................................................................................... 94 to 96 °C
bp ......................................................................................................................................................... 103 °C/4 mmHg
13
Acetyl bromide- C2
13
[113638‑93‑0] CH313COBr FW 124.93 329738-25G glass btl 25 g
 99 atom % 13
C 4-Acetylbutyric acid, 97%
491713-500MG ampule 500 mg
5-Ketohexanoic acid
> N-Acetyl-4-bromoaniline, see 4-Bromoacetanilide Page 430 [3128‑06‑1] Beil. 3,685 CH3CO(CH2)3CO2H FW 130.14
5-Acetyl-2-bromoaniline, see 3′-Amino-4′-bromoacetophenone Page 96 mp ............................................................ 13 to 14 °C density .................................... 1.09 g/mL, 25 °C
1-Acetyl-3-bromobenzene, see 3′-Bromoacetophenone Page 431 bp ............................................................... 274-275 °C n20
D ....................................................................... 1.4451
1-Acetyl-4-bromobenzene, see 4′-Bromoacetophenone Page 431
2-Acetyl-6-bromopyridine, 97%
[49669‑13‑8] C7H6BrNO FW 200.03
α-Acetylbutyrolactone, ≥99%
CH3
Br N
O
[517‑23‑7] Merck 14,83; Beil. 17,V,11,16 C6H8O3 O
FW 128.13 CH3
mp .................................................................................................................................................................... 51 to 55 °C
O O
7
Warning H315-H319-H335 P261-P305 + P351 + P338
bp ....................................... 107-108 °C/5 mmHg n20 D .......................................................................... 1.459
597872-1G glass btl 1g density ........................................ 1.19 g/mL, 25 °C
7
3-Acetyl-2-bromopyridine, 97% 8 A13409-5ML 5 mL

1-(2-Bromo-3-pyridinyl)ethanone; 3-(2-Bromopyridyl) O A13409-100G glass btl 100 g
methyl ketone A13409-500G glass btl 500 g
CH3
[84199‑61‑1] C7H6BrNO FW 200.03
N Br > Acetyl butyryl, see 2,3-Hexanedione Page 1436

AHB A, 0613, UNP EU
n Acetylcaprolact n
N-Acetylcaprolactam, 99% Acetyl chloride solution 8

1-Acetyl-2-oxohexamethyleneimine; 1-Acetylhexahydro-2H- C2H3ClO FW 78.50
azepin-2-one
[1888‑91‑1] Beil. 21,V,6,460 C8H13NO2 FW 155.19 N O
 1 M in methylene chloride
density ............................................................................................................................................. 1.294 g/mL, 25 °C
O CH3
n20
D ...................................................................................................................................................................................... 1.423
bp ..................................... 134-135 °C/26 mmHg n20 D .......................................................................... 1.489 708496-100ML Sure/Seal™ 100 mL
density ..................................... 1.094 g/mL, 25 °C 708496-500ML Sure/Seal™ 500 mL
A 7 Warning H302-H319 P305 + P351 + P338
Acetyl chloride-1-13C
283010-5ML glass btl 5 mL [1520‑57‑6] CH313COCl FW 79.49
mp ...................................................................... -112 °C vd ............................................................... 2.7 (vs air)
bp ............................................................................ 52 °C vp .......................................... 240 mmHg (20 °C)
2-Acetylcarbazole, 98% n20
D .............................................................................. 1.389
[23592‑74‑7] C14H11NO FW 209.24  99 atom % 13C

CH3
N
H O density ............................................................................................................................................. 1.118 g/mL, 25 °C
ait ................................................................................................................................................................................. 1353 °F
mp .............................................................................................................................................................. 232 to 234 °C
25
Danger H225-H314-EUH014 P210-P280-P305 + P351 + P338-
7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 P310
293156-250MG ampule 250 mg
293156-1G ampule 1g
9-Acetylcarbazole, 97% Acetyl chloride-1-13C,d3
[574‑39‑0] C14H11NO FW 209.24 CD313COCl FW 82.51
mp .............................................................................................................................................................................. -112 °C
N
bp .................................................................................................................................................................................... 52 °C
O CH3
 99 atom % 13C; 98 atom % D
mp .................................................................................................................................................................... 77 to 79 °C mol wt 82.47, atom % calculation
density ............................................................................................................................................. 1.160 g/mL, 25 °C
7
25
649201-1G glass btl 1g P310
649201-5G glass btl 5g 607517-500MG ampule 500 mg
O-Acetyl-L-carnitine hydrochloride, ≥99% (titration) Acetyl -2-13C chloride

13
R-(−)-2-Acetyloxy-3-carboxy-N,N,N-trimethyl-1- O
[14770‑40‑2] CH3COCl FW 79.49
propanaminium chloride; ALCAR; ALC; (R)-3- Cl mp ...................................................................... -112 °C n20 D .......................................................................... 1.389
CH O CH3 bp ............................................................................ 52 °C
Acetoxy-4-(trimethylammonio)butyrate hydro- H3C 3
N CO2H
chloride H3C
 99 atom % 13C
[5080‑50‑2] Merck 14,84 C9H17NO4 · HCl
FW 239.70
density ............................................................................................................................................. 1.118 g/mL, 25 °C
Endogenous mitochondrial metabolite that transports acetyl groups
25
across the mitochondrial membrane.
P310
 powder 293148-250MG ampule 250 mg
D −28°, c = 2 in H2O (lit.)
[α]25
soluble in ....................................................................................................................................... H2O (100 mg/mL) Acetyl chloride-13C2
13
color .............................................................................................................................................................................. white [89186‑79‑8] CH313COCl FW 80.48
mp ...................................................................... -112 °C n20
7
Warning H315-H319-H335 P261-P305 + P351 + P338 D .......................................................................... 1.389
store at: 2-8°C bp ............................................................................ 52 °C vd ............................................................... 2.7 (vs air)
 99 atom % 13C
> Acetylcellulose, see Cellulose acetate Page 632 density ............................................................................................................................................. 1.130 g/mL, 25 °C
ait ................................................................................................................................................................................. 1353 °F
Acetyl chloride
25
[75‑36‑5] Merck 14,85; Beil. 2,IV,395; Fieser 1,11; 5,4; 4,5; 7,3 CH3COCl P310
FW 78.50 293164-250MG ampule 250 mg
mp .................................................................... −112 °C vd ................................................................ 2.7 (vs air)
293164-1G ampule 1g
bp ............................................................................ 52 °C vp ................................................. 11.69 psi (20 °C)
density ..................................... 1.104 g/mL, 25 °C vp ................................................. 32.33 psi (55 °C) Acetyl chloride-d3
n20
D .............................................................................. 1.389 ait ...................................................................... 1353 °F
[19259‑90‑6] Beil. 2,III,392 CD3COCl FW 81.52
25
Danger H225-H314-EUH014 P210-P280-P305 + P351 + P338- mp ...................................................................... -112 °C vd ............................................................... 2.7 (vs air)
P310 bp ............................................................................ 52 °C vp .................................................... 4.97 psi (20 °C)
 reagent grade, 98% n20
D ........................................................................... 1.3865
114189-25G glass btl 25 g  99 atom % D

114189-500G glass btl 500 g mol wt 81.49, atom % calculation
114189-1KG glass btl 1 kg density ............................................................................................................................................. 1.146 g/mL, 25 °C
ait ................................................................................................................................................................................. 1353 °F
 reagent grade, 98%
320129-1KG PVC coated 1 kg

AHB A, 0613, UNP EU
n Acetylcytosine n
25
Danger H225-H314-EUH014 P210-P280-P305 + P351 + P338- 2-Acetylcyclopentanone, 98%
P310
[1670‑46‑8] Beil. 7,IV,1993 CH3COC5H7(=O) FW 126.15
175668-5G ampule 5g bp ............................................. 72-75 °C/8 mmHg n20
D .......................................................................... 1.489
175668-10G ampule 10 g density ..................................... 1.043 g/mL, 25 °C
7
Warning H302
2-Acetyl-5-chlorothiophene, 99%
5-Chloro-2-thienyl methyl ketone
[6310‑09‑4] Beil. 17,287 C6H5ClOS FW 160.62 CH3
Cl
A
S 179779-25G glass btl 25 g
O
179779-100G glass btl 100 g
mp .................................................................................................................................................................... 46 to 49 °C
1-Acetyl-1-cyclopentene, 97%
bp ............................................................................................................................................ 117-118 °C/17 mmHg
[16112‑10‑0] C5H7COCH3 FW 110.15
bp .................................................. 70 °C/20 mmHg n20
D .......................................................................... 1.483
247073-25G glass btl 25 g density ..................................... 0.955 g/mL, 25 °C
Acetylcholine chloride, ≥99% (TLC) 466433-1G glass btl 1g
ACh 466433-5G glass btl 5g
[60‑31‑1] Merck 14,87; Beil. 4,IV,1446 (CH3)3N+CH2CH2OCOCH3Cl-
> Acetylcyclopropane, see Cyclopropyl methyl ketone Page 828
FW 181.66
Endogenous neurotransmitter at cholinergic synapses; amplifies N-Acetylcysteamine, 95%
action potential of the sarcolemma thereby inducing muscle
N-(2-Mercaptoethyl)acetamide
contractions.
mp .............................................................................................................................................................. 146 to 150 °C
[1190‑73‑4] Beil. 4,IV,1607 CH3CONHCH2CH2SH FW 119.19
mp .................................................................. 6 to 7 °C density ................................. 1.121 g/mL, 25 °C
Very hygroscopic bp ....................................... 138-140 °C/7 mmHg n20 D .......................................................................... 1.511
soluble in ....................................................................................................................................... H2O (100 mg/mL)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338

A6625-10MG autosmp vl 10 mg
A6625-100G glass btl 100 g N-Acetyl-L-cysteine, ≥99% (TLC)
A6625-500G glass btl 500 g NAC; LNAC
Acetyl-1,2-13C2 coenzyme A lithium salt, 95% (CP) [616‑91‑1] Merck 14,88; Beil. 4,IV,3160 HSCH2CH(NHCOCH3)CO2H
13
FW 163.19
C2C21H38N7O17P3S · xLi+ FW 811.56 (FA) Antioxidant and mucolytic agent. Increases cellular pools of free
 99 atom % 13
C radical scavengers. Reported to prevent apoptosis in neuronal cells
658650 Full product information at Aldrich.com but induce apoptosis in smooth muscle cells. Inhibits HIV replication.
May serve as a substrate for microsomal glutathione transferase.
3-Acetylcoumarin, 96% mp .............................................................................................................................................................. 106 to 108 °C
[3949‑36‑8] Beil. 17,511 C11H8O3 FW 188.18 O  Sigma Grade, powder
CH3 soluble in ...................................................................................................................................... H2O (100 mg/mL)
O O store at: 2-8°C
mp .............................................................................................................................................................. 119 to 122 °C
> Acetyl cyanide, see Pyruvonitrile Page 2234 A7250-50G poly btl 50 g
1-Acetyl-3-cyano-7-azaindole, see 1-Acetyl-7-azaindole-3-carbonitrile A7250-100G poly btl 100 g
Page 34
2-Acetyl-1,3-cyclohexanedione, 98% A7250-1KG poly btl 1 kg
[4056‑73‑9] Beil. 7,IV,2754 CH3COC6H7(=O)2 FW 154.16 N-Acetyl-L-cysteine methyl ester, ≥90% (HPLC)
mp ................................................................................................................................................................................... 20 °C [7652‑46‑2] Beil. 4,III,1607 C6H11NO3S FW 177.22 O
bp ......................................................................................................................................................... 85 °C/0.1 mmHg
HS OCH3
156493-1G glass btl 1g HN CH3
O
2-Acetylcyclohexanone, 97%
D −24.0±3°, c = 1 in methanol
[α]20
[874‑23‑7] Beil. 7,IV,1997 CH3COC6H9(=O) FW 140.18 Sulfur transfer agent1
bp ..................................... 111-112 °C/18 mmHg n20 D .......................................................................... 1.509
mp ................................................................................................................................................................... 77 to 81 °C
density ..................................... 1.078 g/mL, 25 °C
Lit. cited: 1. A. Gilman, D.M. Spero, Tetrahedron Lett. 33, 1751 (1993)
179760-5G glass btl 5g 01042-5G poly btl 5g
179760-25G glass btl 25 g 4
N -Acetylcytosine, 99%
1-Acetyl-1-cyclohexene, 97% [14631‑20‑0] Beil. 25,IV,3657 C6H7N3O2 FW 153.14 O
[932‑66‑1] Beil. 7,58 C6H9COCH3 FW 124.18
H3C NH
bp ............................................................... 201-202 °C n20
D ............................................................................. 1.49
density ..................................... 0.966 g/mL, 25 °C N
N O
A14405-5G glass btl 5g H
mp ............................................................................................................................................................................ >300 °C

AHB A, 0613, UNP EU
n Acetyldehydroal n
> N-Acetyldehydroalanine, see 2-Acetamidoacrylic acid Page 16 5-Acetyl-2,4-dimethylthiazole, 96%
N-Acetyldehydrophenylalanine, see α-Acetamidocinnamic acid Page 17
[38205‑60‑6] C7H9NOS FW 155.22 H3C
3-Acetyl-2,5-dichlorothiophene, 98% N
H3C
S CH3
2,5-Dichloro-3-thienyl methyl ketone O O
[36157‑40‑1] C6H4Cl2OS FW 195.07
CH3
bp ............................................................... 228-230 °C n20
D .......................................................................... 1.543
Cl S Cl
density ........................................ 1.15 g/mL, 25 °C
A mp .................................................................................................................................................................... 37 to 40 °C
78
Danger H315-H319-H334-H335
P342 + P311
P261-P305 + P351 + P338-
7
+ P338 298085-5G glass btl 5g
439509-5G glass btl 5g 3-Acetyl-2,5-dimethylthiophene, 99%
> 16-Acetyl-6,13-dihydro-15-oxide -13,6-(epithioimino)pentacene, see 13,6- [2530‑10‑1] Beil. 17,298 C8H10OS FW 154.23 O
N-Sulfinylacetamidopentacene Page 2346
2-Acetyldimedone, see 2-Acetyl-5,5-dimethyl-1,3-cyclohexanedione CH3
Page 38
H3C S CH3
3-Acetyl-2,6-dimethoxypyridine, 97% bp .................................... 105-108 °C/15 mmHg n20 D .......................................................................... 1.544

[870703‑62‑1] C9H11NO3 FW 181.19 O
density ..................................... 1.086 g/mL, 25 °C
CH3 225797-10G glass btl 10 g

CH3O N OCH3 225797-50G glass btl 50 g
mp .................................................................................................................................................................... 76 to 80 °C Acetylene-13C2
H13C≡13CH FW 28.02
7
density ................................................................................................................................. 0.96 g/mL, 0 °C (air=1)
658316-5G glass btl 5g mp ................................................................................................................................................................. -81 °C (subl.)
> cis-3-Acetyl-2,2-dimethylcyclobutaneacetic acid, see cis-Pinonic acid  99 atom % 13C

Page 2073 gas
2-Acetyl-5,5-dimethyl-1,3-cyclohexanedione, ≥98.0% (HPLC)
24
Danger H220-H280-EUH006 P210-P410 + P403
Dde; 2-Acetyldimedone H3C
O
[1755‑15‑3] Beil. 7,IV,2756 C10H14O3 FW 182.22 H3C 617520-500ML break seal 500 mL
CH3
O O
> Acetyleneboronic acid MIDA ester, see Ethynylboronic acid MIDA ester
Page 1279
Acetylenecarboxylic acid, see Propiolic acid Page 2195
Protecting group reagent for primary amines; cleavage occurs Acetylene dibromide, see 1,2-Dibromoethylene, mixture of cis and trans
orthogonally to other amine protections1,2 Page 886
mp .................................................................................................................................................................... 36 to 40 °C
Lit. cited: 1. I.A. Nash et al., Tetrahedron Lett. 37, 2625 (1996) Acetylenedicarboxylic acid, 95%
2. B. Kellam et al., Tetrahedron Lett. 38, 4849 (1997) 2-Butynedioic acid
7
Warning H315-H319-H335 P261-P305 + P351 + P338 [142‑45‑0] Beil. 2,IV,2290; Fieser 1,12 HOOCC≡CCOOH FW 114.06
mp ............................................................................................................................................... 180 to 187 °C (dec.)
01070-1G poly tube 1g
6
Danger H301-H315-H319-H335 P261-P301 + P310-P305 + P351 +
01070-10G poly btl 10 g P338
3-Acetyl-2,5-dimethylfuran, 98% A15207-5G glass btl 5g

[10599‑70‑9] Beil. 17,298 C8H10O2 FW 138.16 O
CH3
Acetylenedicarboxylic acid monopotassium salt, ≥98%
H3C O CH3 mono-Potassium 2-butynedioate
[928‑04‑1] Beil. 2,801 HOOCC≡CCOOK FW 152.15
bp .............................................. 62 °C/0.25 mmHg n20
D .......................................................................... 1.485
6
Danger H301-H310-H315-H319-H331-H335 P261-P280-P301 + P310-
density ..................................... 1.038 g/mL, 25 °C P302 + P350-P305 + P351 + P338-P310
3-Acetyl-2,4-dimethylpyrrole, 97% > Acetylenediurea, see Glycoluril Page 1398
[2386‑25‑6] Beil. 21,277 C8H11NO FW 137.18 4,4′-(Acetylene-1,2-diyl)bis(phenylboronic acid pinacol 8

O
H3C ester), 95%
CH3
H 3C CH3
N CH3 O O
H3C CH3
H B B
H3C O O CH3
H 3C CH3
mp .............................................................................................................................................................. 136 to 139 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
1,2-Bis(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)acetylene
C26H32B2O4 FW 430.15
mp .............................................................................................................................................................. 275 to 280 °C
> Acetylene tetrabromide, see 1,1,2,2-Tetrabromoethane Page 2367

Acetylene tetrachloride, see 1,1,2,2-Tetrachloroethane Page 2374

AHB A, 0613, UNP EU
n Acetylhydroxyco n
N-Acetylethanolamine Nα-Acetylglycinamide, 97%

N-(2-Hydroxyethyl)acetamide 2-Acetamidoacetamide
[142‑26‑7] Beil. 4,I,430 CH3CONHCH2CH2OH FW 103.12 [2620‑63‑5] Beil. 4,355 CH3CONHCH2CONH2 FW 116.12
bp ....................................... 151-155 °C/5 mmHg n20
D .......................................................................... 1.472 mp .............................................................................................................................................................. 140 to 143 °C
density ........................................ 1.12 g/mL, 25 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
 technical grade
57
Danger H315-H318-H335 P261-P280-P305 + P351 + P338

N-Acetylglycine, 99% A
Acetamidoacetic acid; Aceturic acid
100455-500G glass btl 500 g
[543‑24‑8] Merck 14,80; Beil. 4,IV,2399 CH3CONHCH2CO2H
> N-Acetylethylenediamine, see N-(2-Aminoethyl)acetamide Page 120 FW 117.10
mp .............................................................................................................................................................. 207 to 209 °C
Acetylferrocene, 95%
(Acetylcyclopentadienyl)cyclopentadienyliron O A16300-100G poly btl 100 g
[1271‑55‑2] C12H12FeO FW 228.07 A16300-500G poly btl 500 g
Fe CH3
1-Acetylguanidine, 98%
mp .................................................................................................................................................................... 81 to 83 °C [5699‑40‑1] Beil. 3,88 CH3CONHC(=NH)NH2 FW 101.11
mp .............................................................................................................................................................. 181 to 183 °C
6
Danger H300 P264-P301 + P310
106860-5G glass btl 5g > 1-Acetylhexahydro-1H-1,4-diazepine, see N-Acetylhomopiperazine
106860-25G glass btl 25 g Page 39
2-Acetylfluorene, 98% Nω-Acetylhistamine, 98%

[781‑73‑7] C15H12O FW 208.26 [673‑49‑4] Beil. 25,II,304 C7H11N3O FW 153.18 H
CH3 H3C N
N
O O
N
H
mp .............................................................................................................................................................. 128 to 129 °C
mp .............................................................................................................................................................. 147 to 149 °C
DL-N-Acetylhomocysteine thiolactone, 98%
3-Acetyl-2-fluorophenylboronic acid
[870778‑95‑3] C8H8BFO3 FW 181.96 2-Acetamido-4-mercaptobutyric acid γ-thiolactone O
OH HN
[1195‑16‑0] Merck 14,2320 C6H9NO2S FW 159.21
B CH3
OH
S O
F
O CH3 mp .............................................................................................................................................................. 109 to 111 °C
6
Danger H301 P301 + P310
651249-2G glass btl 2g A16602-25G glass btl 25 g
N-Acetylhomopiperazine, ≥97.0% (GC)
> 2-Acetylfuran, see 2-Furyl methyl ketone Page 1374
1-Acetylhexahydro-1H-1,4-diazepine H
N-Acetyl-D-glucosamine, ≥99% [61903‑11‑5] C7H14N2O FW 142.20 N
2-Acetamido-2-deoxy-D-glucose; D-GlcNAc N
[7512‑17‑6] Merck 14,4458; Beil. 4,IV,2036 C8H15NO6 FW 221.21 O CH3

mp ................................................................................................................................................................. 211 °C (dec.)
powder density ............................................................................................................................................. 1.077 g/mL, 20 °C
soluble in ......................................................................................................................................... H2O (50 mg/mL) n20
D ...................................................................................................................................................................................... 1.510
5
color ................................................................................................................................................ white to off-white Danger H314 P280-P305 + P351 + P338-P310
store at: −20°C
A8625-10MG autosmp vl 10 mg 01191-10ML glass btl 10 mL
A8625-5G poly btl 5g 01191-50ML 50 mL
A8625-25G poly btl 25 g > Acetylhydrazine, see Acethydrazide Page 19
A8625-100G 100 g 2-Acetylhydroquinone, see 2′,5′-Dihydroxyacetophenone Page 1014
5-Acetyl-2-hydroxybenzamide, see 5-Acetylsalicylamide Page 45
A8625-500G 500 g
N-Acetyl-L-glutamic acid, 99% 8-Acetyl-7-hydroxycoumarin, 97%

[1188‑37‑0] Beil. 4,IV,3047 HO2CCH2CH2CH(NHCOCH3)CO2H [6748‑68‑1] C11H8O4 FW 204.18
FW 189.17
HO O O
mp .............................................................................................................................................................. 194 to 196 °C
O CH3
[α]22
D −15.6°, c = 1 in H2O
855642-25G poly btl 25 g mp .............................................................................................................................................................. 167 to 171 °C
855642-100G poly btl 100 g
7
Warning H319 P305 + P351 + P338

AHB A, 0613, UNP EU
n Acetylhydroxyme n
> 3-Acetyl-4-hydroxy-6-methyl-2-pyrone sodium salt monohydrate, see 1-Acetylindole, 98%
Dehydroacetic acid sodium salt monohydrate Page 841
2-Acetyl-5-hydroxy-3-oxo-4-hexenoic acid δ-lactone, see Dehydroacetic [576‑15‑8] Beil. 20,309 C10H9NO FW 159.18
acid Page 841
2-Acetyl-5-hydroxy-3-oxo-4-hexenoic acid δ-lactone sodium salt, see N CH3
Dehydroacetic acid sodium salt Page 841 O
N-(3-Acetyl-4-hydroxyphenyl)butanamide, 97% bp ....................................... 123-125 °C/8 mmHg n20D .......................................................................... 1.607
[40188‑45‑2] CH3CH2CH2CONHC6H3(OH)COCH3 FW 221.25 density ..................................... 1.387 g/mL, 25 °C
A 7 Warning H315-H319 P305 + P351 + P338 377104-1G

377104-5G
glass btl
glass btl
1g
5g
3-Acetylindole, 98%
3-Indolyl methyl ketone O
1-Acetyl-4-(4-hydroxyphenyl)piperazine, 98% [703‑80‑0] Beil. 21,V,8,297 C10H9NO FW 159.18
CH3
[67914‑60‑7] Beil. 23,2,25 C12H16N2O2 O
FW 220.27 HO N N N
H
CH3
mp .............................................................................................................................................................. 188 to 192 °C

mp .............................................................................................................................................................. 180 to 185 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
511943-25G glass btl 25 g 1-Acetyl-3-indolecarboxaldehyde, 98%
trans-1-Acetyl-4-hydroxy-L-proline, 99% [22948‑94‑3] Beil. 21,II,263 C11H9NO2 FW 187.19 O
N-Acetyl-L-hydroxyproline HO H
[33996‑33‑7] Merck 14,6903; Beil. 22,V,5,13 C7H11NO4 N CH3
OH
FW 173.17 N
O O
H3C O
mp ............................................................................................................................................................................... 165 °C
mp ............................................................................................................................................... 132 to 133 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
D −119°, c = 4 in H2O
[α]20
5
Danger H318 P280-P305 + P351 + P338 375772-5G glass btl 5g
441562-10G glass btl 10 g 1-Acetylindoline, 98%

[16078‑30‑1] C10H11NO FW 161.20
N-Acetyl-5-hydroxytryptamine, ≥99% (TLC)
Normelatonin; N-Acetylserotonin H
N CH3 2-Acetyl-5-iodothiophene, 97%
[1210‑83‑9] C12H14N2O2 FW 218.25 HO
O
N [30955‑94‑3] C6H5IOS FW 252.07
H CH3
I S
O
mp .............................................................................................................................................................. 120 to 122 °C
 powder mp .............................................................................................................................................................. 130 to 134 °C
78
Immediate precursor of melatonin; weak agonist. Danger H315-H319-H334-H335 P261-P305 + P351 + P338-
soluble in ................................................................................................................................. ethanol (50 mg/mL) P342 + P311
color .............................................................................................................................................................................. white 579637-1G glass btl 1g
store at: 2-8°C
N-Acetyl-L-leucine, 99%
A1824-100MG poly btl 100 mg
A1824-250MG poly btl 250 mg [1188‑21‑2] Beil. 4,IV,2755 (CH3)2CHCH2CH(NHCOCH3)CO2H
FW 173.21
mp .............................................................................................................................................................. 187 to 190 °C
D −23±3°, c = 2 in ethanol
[α]25
1-Acetylimidazole, 98%
[2466‑76‑4] Beil. 23,V,4,218 C5H6N2O FW 110.11 N 441511-25G poly btl 25 g
N Nα-Acetyl-L-lysine methyl ester hydrochloride, 98%
O CH3
[20911‑93‑7] H2N(CH2)4CH(NHCOCH3)CO2CH3·HCl FW 238.71
mp ................................................................................................................................................................. 99 to 105 °C mp .............................................................................................................................................................. 108 to 114 °C
D −18°, c = 10 in 6 M HCl
[α]22
157864-100G glass btl 100 g
> O-Acetyl-L-malic anhydride, see (S)-(−)-2-Acetoxysuccinic anhydride
2-Acetyl-1,3-indanedione, 97% Page 32
[1133‑72‑8] C11H8O3 FW 188.18 O O
Acetylmalononitrile, 98%
CH3
[1187‑11‑7] Beil. 3,III,1374 CH3COCH(CN)2 FW 108.10
O mp .............................................................................................................................................................. 138 to 141 °C
7
mp .............................................................................................................................................................. 109 to 112 °C
+ P338
> (−)-O-Acetyl-D-mandelic acid, see (R)-(−)-O-Acetylmandelic acid Page 41

AHB A, 0613, UNP EU
n Acetylmethylfur n
(S)-(+)-O-Acetylmandelic acid, 99% 2-Acetyl-7-methoxybenzofuran, 98%

(S)-(+)-α-Acetoxyphenylacetic acid [43071‑52‑9] C11H10O3 FW 190.20
[7322‑88‑5] Beil. 10,IV,567 CH3CO2CH(C6H5)CO2H FW 194.18 492760 Full product information at Aldrich.com
mp .................................................................................................................................................................... 97 to 99 °C
> N-(5-Acetyl-2-methoxyphenyl)acetamide, see 3′-Acetylamino-4′-methoxya-
[α]28
D +153°, c = 2 in acetone cetophenone Page 33
ee (GLC): 98%
253022-5G glass btl 5g 2-Acetyl-6-methoxypyridine, 97%
(R)-(−)-O-Acetylmandelic acid, 99% 1-(6-Methoxy-2-pyridinyl)ethanone

[21190‑93‑2] C8H9NO2 FW 151.16 CH3
A
(−)-O-Acetyl-D-mandelic acid; (R)-(−)-α-Acetoxyphenylacetic acid H3CO N
[51019‑43‑3] Beil. 10,III,453 CH3CO2CH(C6H5)CO2H FW 194.18 O
mp .................................................................................................................................................................... 97 to 99 °C mp ................................................................................................................................................................... 40 to 44 °C
 ee (GLC): 98% bp ........................................................................................................................................................ 85 °C/0.2 mmHg
D −152.4°, c = 2 in acetone
[α]20
7
> (S)-β-(Acetylmercapto)isobutyric acid, see (S)-(–)-3-(Acetylthio)-2-methylpro-
pionic acid Page 46 662542-5G glass btl 5g
D-(−)-S-Acetyl-β-mercaptoisobutyric acid, see (S)-(–)-3-(Acetylthio)-2-
methylpropionic acid Page 46 5-Acetyl-2-methoxypyridine, 97%
S-Acetyl-3-mercaptopropionic acid, see 3-(Acetylthio)propionic acid [213193‑32‑9] C8H9NO2 FW 151.16
Page 46 O
H3 C
S-Acetylmercaptosuccinic anhydride, 96%
N OCH3
SAMSA; 2-(Acetylthio)succinic anhydride O
[6953‑60‑2] C6H6O4S FW 174.17 S mp ................................................................................................................................................................... 53 to 57 °C
CH3
7
Warning H315-H319-H335 P261-P305 + P351 + P338
O O O
mp .................................................................................................................................................................... 83 to 86 °C 597767-1G glass btl 1g

7
Warning H315-H319-H335 P261-P305 + P351 + P338
4-Acetyl-N-methylaniline, 97%
4-N-Methylaminoacetophenone H
197327-25G glass btl 25 g N
[17687‑47‑7] C9H11NO FW 149.19 CH3
> 2-Acetylmesitylene, see 2′,4′,6′-Trimethylacetophenone Page 2531 H3 C
O
N-Acetyl-L-methionine, ≥98.5% (T)
[65‑82‑7] Merck 14,96; Beil. 4,IV,3206 mp .............................................................................................................................................................. 103 to 107 °C
7
CH3SCH2CH2CH(NHCOCH3)CO2H FW 191.25 Warning H317 P280
mp .............................................................................................................................................................. 103 to 106 °C
≥98.5% (TLC) 665908-1G glass btl 1g
[α]20
D -21.0±1.0°, c = 1 in H2O
Acetyl-β-methylcholine chloride, ≥98% (TLC)
soluble in ......................................................................................................................... methanol (100 mg/mL)
(2-Acetoxypropyl)trimethylammonium chloride; Methacholine
chloride
[62‑51‑1] Merck 14,5940; Beil. 4,IV,1670
N-Acetyl-DL-methionine, 99% CH3COOCH(CH3)CH2N(Cl)(CH3)3 FW 195.69
Methionamine mp .............................................................................................................................................................. 171 to 173 °C
[1115‑47‑5] Merck 14,96; Beil. 4,III,1655  powder

CH3SCH2CH2CH(NHCOCH3)CO2H FW 191.25 Metabolically stable analog of acetylcholine; muscarinic agonist. Its
mp .............................................................................................................................................................. 117 to 119 °C ability to constrict airway smooth muscle is used to assess bronchial
A17900-250G glass btl 250 g reactivity in the laboratory and clinically.
soluble in ......................................................................................................................................... H2O (50 mg/mL)
N-Acetyl-L-methionine-1-13C, 98% (CP) 8
7
13
L-Methionine-1- C,N-acetyl derivative store at: −20°C
O
C613CH13NO3S FW 192.24 H3CS 13C A2251-25G poly btl 25 g
OH
HN CH3
O 2-Acetyl-5-methylfuran, 98%
mp .............................................................................................................................................................. 103 to 106 °C [1193‑79‑9] Beil. 17,III,4548 C7H8O2 FW 124.14
CH3
H3C
 99 atom % 13C O
O
704164 bp .................................... 100-101 °C/25 mmHg n20 D .......................................................................... 1.512
density ..................................... 1.066 g/mL, 25 °C vd ................................................................ >1 (vs air)
> N-Acetyl-N-methoxyacetamide, see N,N-Diacetyl-O-methylhydroxylamine
7
Page 857 Warning H302


AHB A, 0613, UNP EU
n Acetylmethylpyr n
2-Acetyl-4-methylpyridine, 98% 4-Acetylmorpholine, 99%

[59576‑26‑0] Beil. 21,IV,3571 C8H9NO FW 135.16 CH3 [1696‑20‑4] Beil. 27,IV,274 C6H11NO2 FW 129.16 O CH3
N
CH3
N
O
O
mp .................................................................................................................................................................... 30 to 34 °C mp ........................................................................... 14 °C n20

D .......................................................................... 1.483
density ..................................... 1.116 g/mL, 25 °C
A 7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H319 P305 + P351 + P338
2-Acetyl-1-methylpyrrole, 98% A18834-100G glass btl 100 g
[932‑16‑1] Beil. 21,272 C7H9NO FW 123.15
CH3
N-Acetylmuramic acid, ≥98%
N
CH3 O
2-Acetamido-2-deoxy-3-O-(D-1-carboxyethyl)-D-glucopyranose;
NAMA; MurNAc; (R)-2-(Acetylamino)-3-O-(1-carboxyethyl)-2-deoxy-D-
bp ............................................................... 200-202 °C n20
D .......................................................................... 1.542
glucose
density ........................................ 1.04 g/mL, 25 °C [10597‑89‑4] Merck 14,6304 C11H19NO8 FW 293.27
methanol ..................................................................................................................................................... ≤1 mol/mol
78
Danger H302-H370 P260-P307 + P311 store at: 2-8°C
3-Acetyl-1-methylpyrrole, 99% A3007-10MG glass btl 10 mg

[932‑62‑7] C7H9NO FW 123.15 A3007-50MG glass btl 50 mg
bp ..................................... 148-150 °C/15 mmHg n20 D .......................................................................... 1.538 A3007-100MG glass btl 100 mg
density ..................................... 1.038 g/mL, 25 °C A3007-500MG glass btl 500 mg
7
Warning H315-H319-H335 P261-P305 + P351 + P338 > 1-Acetyl-2-naphthol, see 2′-Hydroxy-1′-acetonaphthone Page 1470
2-Acetyl-1-naphthol, see 1′-Hydroxy-2′-acetonaphthone Page 1470
(−)-N-Acetylneuraminic acid
2-Acetyl-4-methylthiazole, 97%
N-Acetylneuraminic acid from Escherichia coli; NANA; Lactaminic acid;
1-(4-Methylthiazol-2-yl)ethanone H3C Sialic acid
[7533‑07‑5] C6H7NOS FW 141.19 N
[131‑48‑6] C11H19NO9 FW 309.27
CH3
S mp ............................................................................................................................................... 184 to 186 °C (dec.)
O
 synthetic, crystalline
D −32.0°, c = 1 in H2O
[α]24
mp .................................................................................................................................................................... 34 to 38 °C
7
Warning H302
7
Warning H319 P305 + P351 + P338
656313-1G glass btl 1g 855650-25MG glass btl 25 mg

656313-5G glass btl 5g 855650-100MG poly btl 100 mg
2-Acetyl-3-methylthiophene, 98% N-Acetyl-D-neuraminic acid-1,2,3-13C3
[13679‑72‑6] Beil. 17,295 C7H8OS FW 140.20 CH3 O
O OH
CH3 HO NH O 13C
S
R 13C OH R=* OH
O
OH
13C OH
bp .......................................... 98-99 °C/14 mmHg n20
D .......................................................................... 1.562 OH
density ..................................... 1.124 g/mL, 25 °C
13
Sialic- C3 acid
249645-1G glass btl 1g 13
C3C8H19NO9 FW 312.25
mp ............................................................................................................................................................................... 186 °C
2-Acetyl-4-methylthiophene, 97%  99 atom % 13C
1-(4-Methyl-2-thienyl)ethanone H3C mol wt 312.24, atom % calculation
[13679‑73‑7] C7H8OS FW 140.20
7
Warning H319 P305 + P351 + P338
CH3
S
O
649694
bp ............................................................... 108-109 °C n20
D ....................................................................... 1.5600
3-Acetyl-2-oxazolidinone, 99%
density ..................................... 1.224 g/mL, 25 °C
[1432‑43‑5] Beil. 27,IV,2525 C5H7NO3 FW 129.11
7
Warning H302-H317-H319 P280-P305 + P351 + P338 O
N CH3
633046-5G glass btl 5g O O

mp ................................................................................................................................................................... 69 to 71 °C
2-Acetyl-5-methylthiophene, 98% bp ............................................................................................................................................... 110-114 °C/2 mmHg
[13679‑74‑8] C7H8OS FW 140.20 348511-5G glass btl 5g
mp ............................................................ 24 to 28 °C density .................................. 1.106 g/mL, 25 °C
bp ............................................. 65-67 °C/1 mmHg n20 D .......................................................................... 1.561
> N-Acetyloxindole, see N-Acetyl-2-oxindole Page 43

AHB A, 0613, UNP EU
n Acetylphenyltri n
N-Acetyl-2-oxindole, 97% 2-Acetylphenylboronic acid

N-Acetyloxindole [308103‑40‑4] CH3COC6H4B(OH)2 FW 163.97
[21905‑78‑2] C10H9NO2 FW 175.18 O Contains varying amounts of anhydride
N
mp ................................................................................................................................................................ 170 °C (dec.)
O CH3
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 127 to 131 °C
> R-(−)-2-Acetyloxy-3-carboxy-N,N,N-trimethyl-1-propanaminium chloride,

see O-Acetyl-L-carnitine hydrochloride Page 36
470805-25G
3-Acetylphenylboronic acid
glass btl 25 g
A
N-Acetyl-PABA, see 4-Acetamidobenzoic acid Page 17
[204841‑19‑0] CH3COC6H4B(OH)2 FW 163.97
2-Acetylphenanthrene, 98% mp .............................................................................................................................................................. 204 to 208 °C
[5960‑69‑0] C16H12O FW 220.27 3-acetylphenylboronic anhydride ............................................................................................................ <10%

O
7
Warning H315-H319-H335 P261-P305 + P351 + P338
CH3

mp .............................................................................................................................................................. 144 to 145 °C
A19202-5G glass btl 5g 4-Acetylphenylboronic acid
[149104‑90‑5] CH3COC6H4B(OH)2 FW 163.97
3-Acetylphenanthrene, 90%
[2039‑76‑1] C16H12O FW 220.27 mp .............................................................................................................................................................. 240 to 244 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
CH3
mp .................................................................................................................................................................... 67 to 71 °C
> N-Acetyl-p-phenylenediamine, see 4′-Aminoacetanilide Page 89
 technical grade
Remainder 2-acetylphenanthrene 3-Acetylphenyl isocyanate, 99%
A19407-5G glass btl 5g [23138‑64‑9] CH3COC6H4NCO FW 161.16
A19407-25G glass btl 25 g mp ............................................................ 33 to 34 °C density ................................. 1.174 g/mL, 25 °C
bp .................................................. 155 °C/4 mmHg n20 D .......................................................................... 1.563
9-Acetylphenanthrene, 97%
7
[2039‑77‑2] Beil. 7,I,276 C16H12O FW 220.27 O + P338
H3C
4-Acetylphenyl isocyanate, 97%

[49647‑20‑3] Beil. 14,IV,109 CH3COC6H4NCO FW 161.16
mp .................................................................................................................................................................... 73 to 74 °C mp ................................................................................................................................................................... 35 to 37 °C
A19601-1G glass btl 1g bp ...................................................................................................................................................... 139 °C/14 mmHg
7
A19601-10G glass btl 10 g Warning H302-H312-H315-H319-H332-H335 P261-P280-P305 + P351
+ P338
> 2-Acetylphenol, see 2′-Hydroxyacetophenone Page 1470
2-Acetylphenothiazine, 95% 439932-10G glass btl 10 g
[6631‑94‑3] C14H11NOS FW 241.31 O 4-Acetyl-4-phenylpiperidine hydrochloride, 98%

H
N
CH3 [10315‑03‑4] Beil. 21,IV,3702 C13H17NO · HCl
O
S FW 239.74
CH3
• HCl
mp .............................................................................................................................................................. 180 to 185 °C
N
175226-25G poly btl 25 g H
175226-100G poly btl 100 g

mp .............................................................................................................................................................. 232 to 234 °C
4-Acetylphenoxyacetic acid, 99% 332011-5G glass btl 5g
[1878‑81‑5] CH3COC6H4OCH2CO2H FW 194.18 2-Acetyl-1-(phenylsulfonyl)pyrrole, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[86688‑88‑2] C12H11NO3S FW 249.29
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> N-(4-Acetylphenyl)acetamide, see 4′-Acetamidoacetophenone Page 16 438812-5G glass btl 5g
N-Acetyl-L-phenylalanine, 99% 3-Acetyl-1-(phenylsulfonyl)pyrrole, 98%

[2018‑61‑3] C6H5CH2CH(NHCOCH3)CO2H FW 207.23 [81453‑98‑7] C12H11NO3S FW 249.29
7
[α]22
D +40.0°, c = 1 in methanol
857459-1G glass btl 1g 438820-5G glass btl 5g
857459-5G glass btl 5g > 4-Acetylphenyl triflate, see 4-Acetylphenyl trifluoromethanesulfonate
Page 44

AHB A, 0613, UNP EU
n Acetylphenyltri n
4-Acetylphenyl trifluoromethanesulfonate, 99% Acetylpyrazine, 97%

4-Acetylphenyl triflate [22047‑25‑2] Beil. 24,IV,243 C6H6N2O FW 122.12 N
[109613‑00‑5] CF3SO3C6H4COCH3 FW 268.21 CH3
bp ...................................... 75-76 °C/0.35 mmHg n20
D ............................................................................. 1.47 N
density ..................................... 1.418 g/mL, 25 °C O
68
Danger H301-H311-H315-H319-H331-H335-H351 P261-P280- mp ................................................................................................................................................................... 76 to 78 °C
P301 + P310-P305 + P351 + P338-P311
7
Warning H315-H319-H335 P261-P305 + P351 + P338
A
1-Acetylpiperazine, 99%
[13889‑98‑0] Beil. 23,IV,201 C6H12N2O FW 128.17 H
N 1-Acetylpyrene, 97%
N [3264‑21‑9] Beil. 7,III,2726 C18H12O FW 244.29 O
O CH3 CH3
mp .................................................................................................................................................................... 31 to 34 °C
7
Warning H315-H319 P305 + P351 + P338
mp ................................................................................................................................................................... 86 to 89 °C
2-Acetylpyridine, ≥99%
1-Acetylpiperidine-4-carboxylic acid, 97% Methyl 2-pyridyl ketone
N-Acetylisonipecotic acid O OH
[1122‑62‑9] Beil. 21,V,7,385 C7H7NO FW 121.14 CH3
N
[25503‑90‑6] C8H13NO3 FW 171.19
O
N bp ............................................................... 188-189 °C n20

D .......................................................................... 1.521
O CH3 density ........................................ 1.08 g/mL, 25 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 180 to 184 °C
7
P338
647756-25G glass btl 25 g 3-Acetylpyridine, 98%
1-Acetyl-4-piperidone, 94% Methyl 3-pyridyl ketone
[350‑03‑8] Merck 14,6116; Beil. 21,V,7,394 C7H7NO FW 121.14
[32161‑06‑1] Beil. 21,V,6,426 C7H11NO2 FW 141.17 O mp ............................................................ 11 to 13 °C density ................................. 1.102 g/mL, 25 °C
bp ......................................................................... 220 °C n20
D .......................................................................... 1.534
6
N Danger H301 P301 + P310
O CH3
bp ......................................................................... 218 °C n20
D .......................................................................... 1.503 A21207-100G glass btl 100 g
density ..................................... 1.146 g/mL, 25 °C
388254-5ML glass btl 5 mL 4-Acetylpyridine, 97%
N-Acetylprocainamide, ≥99% Methyl 4-pyridyl ketone
[32795‑44‑1] Merck 14,20 4-(CH3CONH)C6H4CONHCH2CH2N(C2H5)2 [1122‑54‑9] Beil. 21,V,7,400 C7H7NO FW 121.14
FW 277.36 mp ............................................................ 13 to 16 °C density ................................. 1.095 g/mL, 25 °C
bp ......................................................................... 212 °C n20
D .......................................................................... 1.529
mp .............................................................................................................................................................. 138 to 140 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338

> 5-Acetyl-1H-pyrimidine-2,4-dione, see 5-Acetyluracil Page 47
N-Acetylprocainamide hydrochloride, 99%
[34118‑92‑8] 4-(CH3CONH)C6H4CONHCH2CH2N(C2H5)2·HCl 2-Acetylpyrrole, 99%
FW 313.82 Methyl 2-pyrrolyl ketone
205656-1G glass btl 1g [1072‑83‑9] Beil. 21,V,7,204 C6H7NO FW 109.13 CH3
N
205656-5G glass btl 5g H O
> 3-Acetyl-1-propanol, see 5-Hydroxy-2-pentanone Page 1506 mp ................................................................................................................................................................... 88 to 93 °C

Acetylpropionyl, see 2,3-Pentanedione Page 1994
bp ................................................................................................................................................................................. 220 °C
N-Acetylputrescine hydrochloride, ≥98% (TLC)
7
[18233‑70‑0] C6H14N2O · HCl FW 166.65 O

H2 N
N CH3 • HCl 247359-25G poly btl 25 g
H
> 1-Acetyl-1H-pyrrolo[2,3-b]pyridine-3-carbonitrile, see 1-Acetyl-7-azaindole-

store at: 2-8°C
3-carbonitrile Page 34
A8784-25MG poly btl 25 mg 2-Acetylresorcinol, see 2′,6′-Dihydroxyacetophenone Page 1014
4-Acetylresorcinol, see 2′,4′-Dihydroxyacetophenone Page 1014
A8784-500MG 500 mg

AHB A, 0613, UNP EU
n Acetylthiocholi n
5-Acetylsalicylamide, 98% 6-Acetyl-1,2,3,4-tetrahydronaphthalene, 97% 8

5-Acetyl-2-hydroxybenzamide 6-Acetyltetralin; 1-(5,6,7,8-Tetrahydronaphthalen-2- O
[40187‑51‑7] Beil. 10,IV,3635 CH3COC6H3(OH)CONH2 FW 179.17 yl)ethanone
H3C
mp .............................................................................................................................................................. 220 to 222 °C [774‑55‑0] C12H14O FW 174.24
7
+ P338 density ............................................................................................................................................. 1.039 g/mL, 25 °C
346675-25G glass btl 25 g n20
D ...................................................................................................................................................................................... 1.562
Acetylsalicylic acid, ≥99.0% 7

Warning H302
A
ASA; O-Acetylsalicylic acid; 2-Acetoxybenzoic acid; Aspirin 699985-5G glass btl 5g
[50‑78‑2] Merck 14,851; Beil. 10,IV,138 2-(CH3CO2)C6H4CO2H 699985-25G glass btl 25 g
FW 180.16
Blocks the production of prostaglandins by inhibiting cyclooxygenase > 6-Acetyltetralin, see 6-Acetyl-1,2,3,4-tetrahydronaphthalene Page 45
(prostaglandin H synthase), with greater selectivity toward the COX-1
2-Acetyl-1-tetralone, 98%
isoform. The antithrombotic effect is due to the inhibition of COX-1 in
platelets that blocks thromboxane production and platelet aggre- [17216‑08‑9] C12H12O2 FW 188.22 O O
gation. Chemopreventive against colorectal and other solid tumors. CH3
mp .............................................................................................................................................................. 134 to 136 °C
 crystalline mp ................................................................................................................................................................... 55 to 57 °C
solubility in aqueous base ............................................................................................................ decomposes bp ............................................................................................................................................... 135-142 °C/1 mmHg
soluble in ............................................. H2O (3 mg/mL), H2O (10 mg/mL), ethanol (50 mg/mL)
color .............................................................................................................................................................................. white
pKa (25 °C) ........................................................................................................................................................................ 3.5 150371-25G glass btl 25 g
6
Danger H301-H315-H319-H335 P261-P301 + P310-P305 + P351 + N-(1-Acetyl-2,2,6,6-tetramethyl-4-piperidinyl)-2-dodecylsuccini-
P338 mide
A5376-100G poly btl 100 g [106917‑31‑1] C27H48N2O3 FW 448.68
A5376-1KG poly btl 1 kg 2-Acetylthiazole, 99%
[24295‑03‑2] Beil. 27,IV,2617 C5H5NOS FW 127.16
O-Acetylsalicylic anhydride, ≥98.0% (HPLC) N
CH3
2-Acetoxybenzoic anhydride CH3 CH3
S
O
[1466‑82‑6] Beil. 10,IV,165 C18H14O7
O O O O O O
FW 342.30 bp .......................................... 89-91 °C/12 mmHg n20
D .......................................................................... 1.548
O
density ..................................... 1.227 g/mL, 25 °C
7
Warning H302-H317-H319 P280-P305 + P351 + P338
mp .................................................................................................................................................................... 80 to 83 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
01460-1G glass btl 1g > 2-Acetyl-3-thienylboronic acid, see 2-Acetyl-3-thiopheneboronic acid
01460-5G glass btl 5g Page 46
O-Acetylsalicyloyl chloride, 95% 5-Acetyl-2-thienylboronic acid

[5538‑51‑2] Beil. 10,IV,169; Fieser 5,6 2-(CH3CO2)C6H4COCl 5-Acetyl-2-thiopheneboronic acid
FW 198.60 [206551‑43‑1] C6H7BO3S FW 169.99 H3C OH
S B
mp ............................................................ 45 to 49 °C n20
D .......................................................................... 1.536
O OH
bp .................................... 107-110 °C/0.1 mmHg
57
Danger H302-H314 P280-P305 + P351 + P338-P310 mp .............................................................................................................................................................. 133 to 138 °C
Contains varying amounts anhydride
> N-Acetylserotonin, see N-Acetyl-5-hydroxytryptamine Page 40 Acetylthiocholine iodide, ≥98% (TLC)
N1-Acetylsulfanilamide sodium salt, see Sulfacetamide sodium salt hydrate
Page 2345 (2-Mercaptoethyl)trimethylammonium iodide acetate
[1866‑15‑5] Beil. 4,IV,1585 CH3COSCH2CH2N(CH3)3I FW 289.18
N-Acetylsulfanilyl chloride, 98%
Substrate for the colorimetric determination of acetylcholinesterase
4-Acetamidobenzenesulfonyl chloride activity1.
[121‑60‑8] Merck 14,103; Beil. 14,IV,2703; Fieser 1,3 Acetylcholinesterase substrate and nicotinic acetylcholine receptor
4-(CH3CONH)C6H4SO2Cl FW 233.67 agonist.
mp ............................................................................................................................................... 142 to 145 °C (dec.) mp .............................................................................................................................................................. 205 to 210 °C
Lit. cited: 1. G.L. Ellman, et al., Biochem. Pharmacol. 7, 88 (1961)
57
Danger H314-H335 P261-P280-P305 + P351 + P338-P310
 powder
112747-100G glass btl 100 g soluble in ...................................................................................................................................... H2O (100 mg/mL)
112747-1KG glass btl 1 kg color .............................................................................................................................................................................. white
6
> 5-(Acetylsulfanyl)-pentanenitrile, see S-(4-Cyanobutyl)thioacetate Danger H301-H311-H315-H319 P280-P301 + P310-P305 + P351 +
Page 792 P338-P312 store at: 2-8°C
A5751-250MG glass btl 250 mg

AHB A, 0613, UNP EU
n Acetylthioglyco n
S-Acetylthioglycolic acid pentafluorophenyl ester, ≥96.0% 2-Acetyl-3-thiopheneboronic acid 8

(HPLC)
2-Acetyl-3-thienylboronic acid HO
Pentafluorophenyl (acetylthio)acetate; F [36155‑74‑5] C6H7BO3S FW 169.99 B OH
Pentafluorophenyl S-acetylthioglycolate F F
O CH3
[129815‑48‑1] C10H5F5O3S FW 300.20 H3C S S
O F O
O F
mp .............................................................................................................................................................. 120 to 130 °C
A
Reagent for modifying resin-bound, protected peptides1 may contain varying amounts of anhydride
Lit. cited: 1. J.W. Drijfhout et al, Anal. Biochem. 187, 349 (1990)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
store at: 2-8°C > 5-Acetyl-2-thiopheneboronic acid, see 5-Acetyl-2-thienylboronic acid
Page 45
09778-500MG poly btl 500 mg
6-Acetylthiohexanoic acid, 97% 3-(Acetylthio)propionic acid, 96%

[80441‑57‑2] CH3COS(CH2)5CO2H FW 190.26 S-Acetyl-3-mercaptopropionic acid O O
density ............................................................................................................................................. 1.144 g/mL, 25 °C

[41345‑70‑4] C5H8O3S FW 148.18
H3C S OH
n20
D ...................................................................................................................................................................................... 1.491
mp ................................................................................................................................................................... 48 to 52 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Protected 3-mercaptopropionic acid potentially used as enzyme
545554-5G glass btl 5g inhibitor.1,2
Lit. cited: 1. Angew. Chem. Int. Ed. Engl. 43, 3716-3718 (2004)
Acetylthiomethyl-diphenylphosphine borane complex, ≥98.0% 2. J. Am. Chem. Soc. 121, 5319-5327 (1999)
7
[446822‑71‑5] C15H18BOPS FW 288.15 Warning H302-H315-H319-H335 P261-P305 + P351 + P338
O
H3B P S CH3
3-(Acetylthio)propionic acid N-succinimidyl ester, ≥95.0%

N-Succinimidyl 3-(acetylthio)propionate; SATP O
O O
Sold under license for research and development purposes only. US [84271‑78‑3] C9H11NO5S FW 245.25
H3C S O N
Patent 6,974,884 and related patents apply
mp .................................................................................................................................................................... 52 to 55 °C O
7
Warning H315-H319-H335 P261-P305 + P351 + P338
store at: 2-8°C Reagent for the modification of peptides and proteins: thionylation1
Lit. cited: 1. N. Fujii et al., Chem. Pharm. Bull. 33, 362 (1985)
670359-250MG glass btl 250 mg store at: −20°C
10859-50MG poly btl 50 mg
(S)-(–)-3-(Acetylthio)-2-methylpropionic acid, 97% > 2-(Acetylthio)succinic anhydride, see S-Acetylmercaptosuccinic anhydride
(S)-β-(Acetylmercapto)isobutyric acid; D-(−)-S-Acetyl-β-mercaptoiso- Page 41
butyric acid
Acetylthiourea, 99%
[76497‑39‑7] Beil. 3,III,605 C6H10O3S FW 162.21
density ............................................................................................................................................. 1.178 g/mL, 20 °C [591‑08‑2] Beil. 3,IV,354; Fieser 4,7 CH3CONHCSNH2 FW 118.16
[α]20
D -39°, c = 0.1 N in methanol
mp .............................................................................................................................................................. 165 to 169 °C
6
density .......................................................................................................................................... 1.1827 g/mL, 25 °C Danger H300 P264-P301 + P310
n20
D ...................................................................................................................................................................................... 1.490
5
Danger H314 P280-P305 + P351 + P338-P310 A22858-25G glass btl 25 g
> 2-Acetyltoluene, see 2′-Methylacetophenone Page 1728

1-Acetyl-1H-1,2,3-triazolo[4,5-b]pyridine, 97%
2-Acetylthiophene, 98%
[107866‑54‑6] C7H6N4O FW 162.15 N N
Methyl-2-thienyl ketone
N
[88‑15‑3] Beil. 17,V,9,387 C6H6OS FW 126.18 S
CH3 N
O CH3
O
mp ............................................................ 10 to 11 °C density .................................. 1.168 g/mL, 25 °C mp .............................................................................................................................................................. 116 to 118 °C

bp ......................................................................... 214 °C n20
D .......................................................................... 1.565
7
Warning H315-H319-H335 P261-P305 + P351 + P338
6
Danger H300-H311-H331 P261-P264-P280-P301 + P310-P311
A22602-100G glass btl 100 g Acetyltrimethylsilane, 97%
1-(Trimethylsilyl)ethanone
3-Acetylthiophene, 98%
[13411‑48‑8] (CH3)3SiCOCH3 FW 116.23
Methyl-3-thienyl ketone O density ............................................................................................................................................. 0.811 g/mL, 25 °C
[1468‑83‑3] Beil. 17,V,9,399 C6H6OS FW 126.18 n20
D ...................................................................................................................................................................................... 1.411
CH3
27
S Danger H225-H315-H319-H335 P210-P261-P305 + P351 +
P338
bp ......................................................................................................................................... 208-210 °C/748 mmHg

AHB A, 0613, UNP EU
n Acidred014 n
N-Acetyl-DL-tryptophan > Acid Blue 83, see Brilliant Blue R Page 428
[87‑32‑1] Beil. 22,V,14,50 C13H14N2O3 O Acid Blue 113

FW 246.26
OH [3351‑05‑1] C32H21N5Na2O6S2 FW 681.65
HN CH3
N
H O
 Dye content: 50%
λmax ............................................................................................................................................................................ 566 nm
mp ............................................................................................................................................... 204 to 206 °C (dec.) 210439-50G glass btl 50 g
A
store at: 2-8°C
> Acid blue 147, see Xylene Cyanol FF Page 2613
A6251-5G poly btl 5g Acid Blue 215, see Uniblue A sodium salt Page 2592
A6251-1KG poly btl 1 kg Acid Fuchsin
N-Acetyl-L-tyrosine, >99% (TLC) Acid Violet 19; Fuchsin acid; Rubine S; Fuchsin S
[3244‑88‑0] Merck 14,107; Beil. 14,IV,2827 C20H17N3Na2O9S3
[537‑55‑3] Beil. 14,IV,2287 4-(HO)C6H4CH2CH(NHCOCH3)CO2H FW 585.54
FW 223.23
composition
mp .............................................................................................................................................................. 149 to 152 °C Dye content ~70%
store at: −20°C
5
Danger H318 P280-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
A2513-5G 5g F8129-25G glass btl 25 g

N-Acetyl-L-tyrosine ethyl ester monohydrate F8129-50G glass btl 50 g
F8129-100G glass btl 100 g
ATEE
[36546‑50‑6] Beil. 14,IV,2290 C13H17NO4 · H2O FW 269.29 Acid Fuchsin calcium salt
Substrate for chymotrypsin Acid Magenta; Acid Rubin; Fuchsin S, SS, SS, ST, or SIII; Rubin S
store at: −20°C
[123334‑10‑1] C20H17N3O9S3Ca FW 579.64
 certified by the Biological Stain Commission, Dye content: 70%
Certified for use in Van Gieson connective tissue stain.
λmax ............................................................................................................................................................................ 545 nm
5-Acetyluracil, 97% 857408-25G glass btl 25 g
5-Acetyl-1H-pyrimidine-2,4-dione O O 857408-100G glass btl 100 g
[6214‑65‑9] C6H6N2O3 FW 154.12 H3C NH > Acid Green 1, see Naphthol Green B Page 1887
Acid Green 3, see Guinea Green B Page 1407
N O
H Acid Green 5, see Light Green SF Yellowish Page 1611
mp ................................................................................................................................................................. 278 °C (dec.) Acid Green 25

570648-1G glass btl 1g [4403‑90‑1] Merck 14,252; Beil. 14,725 C28H20N2Na2O8S2
FW 622.58
> Acetynylboronic acid MIDA ester, see Ethynylboronic acid MIDA ester
Page 1279 mp .............................................................................................................................................................. 235 to 238 °C
ACh, see Acetylcholine chloride Page 37
ACHN, see 1,1′-Azobis(cyclohexanecarbonitrile) Page 215  Dye content: 75%
ACIB, see Isobutyl acetoacetate Page 1569 λmax ............................................................................................................................................................................ 608 nm
I-Acid, see 7-Amino-4-hydroxy-2-naphthalenesulfonic acid Page 129 λmax .............................................................................................................................................................. 642 nm (2nd)
R-Acid sodium salt, see 3-Hydroxynaphthalene-2,7-disulfonic acid disodium
7
salt Page 1503 Warning H319 P305 + P351 + P338
Acid C3, see Propionic acid Page 2196
Acid C6, see Hexanoic acid Page 1438
Acid C8, see Octanoic acid Page 1948 214566-50G glass btl 50 g
Acid C9, see Nonanoic acid Page 1936
> Acid Green 50, see Lissamine™ Green B Page 1614
Acid C10, see Decanoic acid Page 838
Acid Magenta, see Acid Fuchsin calcium salt Page 47
Acid Black 1, see Naphthol Blue Black Page 1887
Acid Orange A, see Orange II sodium salt Page 1956
Acid black 2, see Nigrosin Page 1902
Acid Orange 6, see Tropaeolin O sodium salt Page 2583
Acid Blue 1, see Patent Blue VF Page 1980
Acid Blue 7, see Alphazurine A Page 77
Acid Blue 9, see Erioglaucine disodium salt Page 1191 Acid Orange 8
[5850‑86‑2] C17H13N2NaO4S FW 364.35
Acid Blue 29
[5850‑35‑1] C22H14N6Na2O9S2 FW 616.49
λmax ............................................................................................................................................................................ 490 nm
 Dye content: 40% 214531-50G glass btl 50 g
λmax ............................................................................................................................................................................. 602 nm
> Acid Orange 52, see Methyl Orange Page 1814
255882-25G glass btl 25 g Acid Orange 10, see Orange G Page 1956
255882-100G glass btl 100 g Acid Orange 7, see Orange II sodium salt Page 1956
> Acid Blue 74, see Indigo carmine Page 1529 Acid Red 1
Acid Blue 80 Amido Naphthol Red G; Azophloxine
[4474‑24‑2] C32H28N2Na2O8S2 FW 678.68 [3734‑67‑6] C18H13N3Na2O8S2 FW 509.42
mp ............................................................................................................................................................................ >300 °C  Dye content: 60%
λmax ............................................................................................................................................................................ 506 nm
λmax .............................................................................................................................................................. 532 nm (2nd)
λmax ............................................................................................................................................................................. 582 nm
λmax .............................................................................................................................................................. 627 nm (2nd) 210633-25G glass btl 25 g
210633-100G glass btl 100 g
7
Warning H319 P305 + P351 + P338
> Acid Red 2, see Methyl Red Page 1844
210323-100G glass btl 100 g Acid Red 14, see Chromotrope FB Page 760

AHB A, 0613, UNP EU
n Acidred018 n
Acid Red 18, see New Coccine Page 1896 cis-Aconitic anhydride, 95%
Acid Red 26, see Ponceau Xylidine Page 2157
Acid Red 27, see Amaranth Page 86 cis-Propene-1,2,3-tricarboxylic anhydride OH
Acid Red 29, see Chromotrope 2R Page 760 [6318‑55‑4] Beil. 18,V,8,530 C6H4O5 FW 156.09
O O
O O
Acid Red 37 diammonium salt form
mp ................................................................................................................................................................... 75 to 78 °C
[302912‑22‑7] C18H22N6O8S2 FW 514.53
5
mp ............................................................................................................................................................................ >300 °C Danger H314 P280-P305 + P351 + P338-P310
A  Dye content: 70%

λmax ............................................................................................................................................................................. 513 nm
217808-1G
217808-5G
glass btl
glass btl
1g
5g
λ .................................................................................................................................................................................. vs H2O
513 nm ......................................................................................................................................................................... 0.00 > ACP, see Calcium phosphate, amorphous Page 607
ACPC, see 1-Aminocyclopropanecarboxylic acid Page 113
7
Warning H315-H319-H335 P261-P305 + P351 + P338
9(10H)-Acridanone, 99%
Acridone; 9,10-Dihydro-9-oxoacridine O
> Acid Red 50, see Sulforhodamine G Page 2348 [578‑95‑0] Beil. 21,V,9,7 C13H9NO FW 195.22
Acid Red 51, see Erythrosin B Page 1192
Acid Red 52, see Sulforhodamine B Page 2349 N
Acid Red 66, see Ponceau BS Page 2157 H
Acid Red 73, see Brilliant Crocein MOO Page 428
Acid Red 87, see Eosin Y Page 1184 mp ............................................................................................................................................................................ >300 °C
Acid Red 91, see Eosin B Page 1184 λmax ............................................................................................................................................................................ 380 nm
Acid Red 92, see Phloxine B Page 2059
Acid Red 94, see Rose bengal Page 2253 λmax .............................................................................................................................................................. 399 nm (2nd)
Acid Rubin, see Acid Fuchsin calcium salt Page 47 150215-1G glass btl 1g
Acid Violet 7
[4321‑69‑1] Beil. 16,II,253 C20H16N4Na2O9S2 FW 566.47 Acridine, 97%
 Dye content: 40% [260‑94‑6] Merck 14,122; Beil. 20,459; 20,V,8,199
λmax ............................................................................................................................................................................. 520 nm
C13H9N FW 179.22
N
210668-2.5G 2.5 g
mp .............................................................................................................................................................. 107 to 110 °C
bp ................................................................................................................................................................................. 346 °C
> Acid Violet 9, see Violamine R Page 2607 λmax ............................................................................................................................................................................ 392 nm
Acid violet 17, see Coomassie Violet R200 Page 770
7
Acid Violet 19, see Acid Fuchsin Page 47 Warning H302
Acid Yellow 3, see Quinoline Yellow Page 2239
Acid Yellow 9, see 4-Amino-1,1′-azobenzene-3,4′-disulfonic acid sodium salt A23609-5G glass btl 5g
Page 91
Acid Yellow 14 9-Acridinecarboxylic acid hydrate, 97%
[6359‑97‑3] C16H11Cl2N4NaO4S FW 449.24 [332927‑03‑4] Beil. 22,101; 22,V,3,413 O OH
576336 Full product information at Aldrich.com C14H9NO2 · xH2O FW 223.23 (Anh)
• xH2O
> Acid Yellow 36, see Metanil Yellow Page 1674
Acid Yellow 23, see Tartrazine Page 2356 N
Acid Yellow 73, see Fluorescein sodium salt Page 1293
ACIP, see Isopropyl acetoacetate Page 1580 mp ................................................................................................................................................................ 290 °C (dec.)
ACN, see Acetonitrile Page 25
7
Warning H315-H319-H335 P261-P305 + P351 + P338
cis-Aconitic acid, ≥98%

cis-Propene-1,2,3-tricarboxylic acid 246344-5G glass btl 5g
[585‑84‑2] Beil. 2,IV,2405 HO2CCH2C(CO2H)=CHCO2H FW 174.11
mp ................................................................................................................................................................................ 122 °C Acridine Orange hemi(zinc chloride) salt
May form trans isomer upon prolonged storage 3,6-Bis(dimethylamino)acridinium chloride hemi(zinc chloride salt);
store at: −20°C 3,6-Bis(dimethylamino)acridine hydrochloride zinc chloride double
8
Warning H351 P281
salt; Basic Orange 14
A3412-1G poly btl 1g [10127‑02‑3] Beil. 22,V,11,326 C17H20ClN3 · HCl · 1/2ZnCl2
A3412-5G poly btl 5g FW 369.96
A3412-10G poly btl 10 g  Dye content: 90%
trans-Aconitic acid, 98% Biological stain
λmax ............................................................................................................................................................................ 489 nm
trans-Propene-1,2,3-tricarboxylic acid
[4023‑65‑8] Beil. 2,IV,2405 HO2CCH2C(CO2H)=CHCO2H FW 174.11
Antimicrobial agent that blocks the transformation of Leishmania
donovani amastigotes to prostigotes. 158550-100G glass btl 100 g
mp ................................................................................................................................................................. 190 °C (dec.) Acridine Orange hydrochloride hydrate, 99% (HPLC)
122750-25G poly btl 25 g 3,6-Bis(dimethylamino)acridine hydrochloride
122750-100G poly btl 100 g [65‑61‑2] Beil. 22,V,11,326 C17H19N3 · HCl · xH2O FW 301.81 (Anh)
> Aconitic acid oxide potassium salt, see (±)-Epoxytricarballylic acid Fluorescent stain for nucleic acids in agarose and polyacrylamide gels.
monopotassium salt Page 1189 Has been used to study apoptosis in various cell culture and tissue
models.

AHB A, 0613, UNP EU
n Acrylamidopropy n
mp .............................................................................................................................................................. 284 to 287 °C Acrolein dimethyl acetal, 98%

λmax ............................................................................................................................................................................. 492 nm 3,3-Dimethoxy-1-propene
318337-1G glass btl 1g [6044‑68‑4] Beil. 1,IV,3437 H2C=CHCH(OCH3)2 FW 102.13
318337-5G glass btl 5g bp ..................................................................... 89-90 °C n20
D .......................................................................... 1.395
density ..................................... 0.862 g/mL, 25 °C
Acridine Orange base
2
Danger H225 P210
3,6-Bis(dimethylamino)acridine; Solvent Orange 15
[494‑38‑2] Beil. 22,487 C17H19N3 FW 265.35
A
mp ................................................................................................................................................................. 165 °C (dec.) 190543-25ML glass btl 25 mL
 Dye content: 75% 190543-100ML 100 mL
λmax ............................................................................................................................................................................. 488 nm > Acrolein ethylene acetal, see 2-Vinyl-1,3-dioxolane Page 2604
235474-25G glass btl 25 g Acrylamide-1-13C
H2C=CH13CONH2 FW 72.07
Acridine Yellow G
 99 atom % 13
C
[135‑49‑9] Beil. 22,488 C15H15N3 · HCl FW 273.76
λmax ............................................................................................................................................................................. 442 nm Acrylamide-2,3,3-d3
78
Warning H302-H312-H315-H319-H332-H335-H351 P261- D2C=CDCONH2 FW 74.10
P280-P305 + P351 + P338 mp ................................................................................................................................................................... 82 to 86 °C
199508-25G glass btl 25 g bp ...................................................................................................................................................... 125 °C/25 mmHg
> Acridone, see 9(10H)-Acridanone Page 48  98 atom % D

Acriflavine
68
Danger H301-H312-H315-H317-H319-H332-H340-H350-H361-
Euflavine; 3,6-Diamino-10-methylacridinium H372 P201-P280-P301 + P310-P305 + P351 + P338-P308 +
P313
chloride mixt. with 3,6-diaminoacridine
H2N N NH2 636568
(proflavine)
[8048‑52‑0] Merck 14,123; Beil. 22,III/IV,5488
Acrylamide-13C3, 98% (CP)
C14H14ClN3 FW 259.73 H2N N+ NH2
Cl- CH3 H213C=13CH13CONH2 FW 74.06
mp ................................................................................................................................................................... 82 to 86 °C
7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 bp ...................................................................................................................................................... 125 °C/25 mmHg
 99 atom % 13C
68
Danger H301-H312-H315-H317-H319-H332-H340-H350-H361-
Acrolein H372 P201-P280-P301 + P310-P305 + P351 + P338-P308 +
P313
2-Propenal
586617
[107‑02‑8] Merck 14,128; Beil. 1,IV,3435; Fieser 10,2; 3,5; 2,15 CH2
=CHCHO FW 56.06 > Acrylamide copolymer, see Poly(N-isopropylacrylamide-co-acrylamide)
mp ....................................................................... −87 °C vd ............................................................. 1.94 (vs air) Page 2128
bp ............................................................................ 53 °C vp .................................................... 4.05 psi (20 °C)
density ..................................... 0.839 g/mL, 25 °C ait ......................................................................... 428 °F 2-Acrylamido-2-methyl-1-propanesulfonic acid, 99%
n20
D .............................................................................. 1.403 [15214‑89‑8] H2C=CHCONHC(CH3)2CH2SO3H FW 207.25
2569
Danger H225-H301-H311-H314-H330-H400 mp ................................................................................................................................................................ 195 °C (dec.)
P210-P260-P273-P280-P284-P301 + P310
7
 contains 0.1-0.2 wt. % hydroquinone as stabilizer, 90%
water and cyclic dimer .................................................................................................................................... <10% 282731-250G glass btl 250 g
110221-25ML Sure/Seal™ 25 mL 282731-1KG glass btl 1 kg
2-Acrylamido-2-methyl-1-propanesulfonic acid sodium salt
solution
 ≥95.0% (GC, as anhydrous)
contains ~0.2% hydroquinone as stabilizer, ~3% water as stabilizer [5165‑97‑9] H2C=CHCONHC(CH3)2CH2SO3Na FW 229.23
store at: 2-8°C density .......................................................................................................................................... 1.2055 g/mL, 25 °C
01680-250ML glass btl 250 mL n20
D ................................................................................................................................................................................... 1.4220
01680-1L glass btl 1L  50 wt. % in H2O

Acrolein diethyl acetal, 96% 655821-250ML glass btl 250 mL
3,3-Diethoxy-1-propene
[3054‑95‑3] Beil. 1,IV,3437; Fieser 9,158 CH2=CHCH(OCH2CH3)2 (3-Acrylamidopropyl)trimethylammonium chloride solution
FW 130.18 [45021‑77‑0] H2C=CHCONH(CH2)3N(CH3)3Cl FW 206.71
bp ......................................................................... 125 °C n20
D .......................................................................... 1.398
density ..................................... 0.854 g/mL, 25 °C  75 wt. % in H2O
contains 3,000 ppm monomethyl ether hydroquinone as stabilizer
27
Danger H225-H319 P210-P305 + P351 + P338
density ................................................................................................................................................ 1.11 g/mL, 25 °C
n20
D ................................................................................................................................................................................... 1.4848
A24001-100G glass btl 100 g 448281-50ML glass btl 50 mL

AHB A, 0613, UNP EU
n Acrylatemonomer n
Acrylate Monomers
Name Structure Purity Additive H&P Prod. No.

Acryloyl chloride 97.0% MEHQ <210 ppm as GHS02, GHS05, GHS06 Danger 549797-5G
O
stabilizer H225-H314-H330 P210-P260- 549797-500G
H 2C
Cl P280-P284-P305 + P351 +
P338-P310
A Acryloyl chloride
H 2C
O
≥97% phenothiazine ~400
ppm as stabilizer
GHS02, GHS05, GHS06 Danger
H225-H314-H330 P210-P260-
A24109-5G
A24109-100G
Cl P280-P284-P305 + P351 + A24109-500G
P338-P310 A24109-1KG
4-Acryloylmorpholine O
97% monomethyl ether GHS05, GHS06 Danger H302- 448273-50ML
hydroquinone 1,000 H317-H318-H331 P261-P280- 448273-250ML
N ppm as inhibitor P305 + P351 + P338-P311
CH2
O
[2-(Acryloyloxy)ethyl] - monomethyl ether GHS07 Warning H302-H317- 496146-200ML

O
trimethylammonium H 2C
CH3 hydroquinone 800 ppm H319 P280-P305 + P351 +
chloride solution O N CH3 as inhibitor P338
Cl CH3
2-(4-Benzoyl-3-hydroxy- O
98% - - 413216-25G
phenoxy)ethyl acrylate H 2C O OH 413216-100G
O
Butyl acrylate ≥99% monomethyl ether GHS02, GHS07 Warning H226- 234923-100ML
O
hydroquinone 10-60 H315-H317-H319-H335 P261- 234923-1L
H2C
O CH3 ppm as inhibitor P280-P305 + P351 + P338 234923-2.5L
234923-18L
tert-Butyl acrylate 98% monomethyl ether GHS02, GHS07, GHS09 Danger 327182-5ML
O CH3
H2C CH3
hydroquinone 10-20 H225-H302-H312-H315-H317- 327182-100ML
O
CH3 ppm as inhibitor H332-H335-H411 P210-P261- 327182-1L
P273-P280
2-[[(Butylamino) O
- - GHS07 Warning H315-H319- 496952-100ML
carbonyl]oxy]ethyl H2C O
H
N CH3 H335 P261-P305 + P351 + 496952-500ML
O
acrylate P338
O
tert-Butyl 2-bromoa- 95% - GHS07 Warning H315-H319- 588458-1G

O CH3
crylate H2C CH3
H335 P261-P305 + P351 +
O P338
CH3
Br
4-tert-Butylcyclohexyl 90% - GHS07 Warning H315-H319- 467545-250ML

CH3
acrylate CH3
H335 P261-P305 + P351 +
O P338
CH3
H2C
O
2-Carboxyethyl acrylate - MEHQ 900-1100 ppm as GHS05 Danger H314 P280- 552348-50ML
O O
H2C inhibitor P305 + P351 + P338-P310 552348-500ML
O OH
2-Carboxyethyl acrylate - MEHQ; preserved with GHS07 Warning H315-H319- 407585-250ML

oligomers O O 0.01% BHA 2000 ppm H335 P261-P305 + P351 +
H2C H
O O as inhibitor P338
n citric acid 0.005% as
inhibitor
2-Chloroethyl acrylate O
97% MEHQ >100 ppm as GHS02, GHS05, GHS06, GHS09 729817-5G
H2C Cl inhibitor Danger H226-H301-H318-
O H400 P273-P280-P301 +
P310-P305 + P351 + P338
2-(Diethylamino)ethyl 95% monomethyl ether GHS05, GHS06 Danger H302- 408972-100ML
CH3
acrylate O hydroquinone 25 ppm as H310-H314-H317 P280-P302
H2C N CH3 inhibitor + P350-P305 + P351 +
O
P338-P310
Di(ethylene glycol) ethyl ≥90% monomethyl ether GHS07 Warning H315-H317- 408298-250ML
O
ether acrylate H2C O
hydroquinone 1000 ppm H319-H335 P261-P280-P305 408298-1L
O O CH3 as inhibitor + P351 + P338
Di(ethylene glycol) 2- - monomethyl ether GHS07 Warning H315-H319- 407542-100ML

O
ethylhexyl ether acrylate H2C O
hydroquinone 500 ppm H335 P261-P305 + P351 +
O O CH3 as inhibitor P338
CH3
2-(Dimethylamino)ethyl 98% MEHQ 2,000 ppm as GHS02, GHS05, GHS06 Danger 330957-100ML
O CH3
acrylate H2C
inhibitor H226-H302-H311-H314-H330 330957-500ML
N
O CH3 P260-P280-P284-P305 +
P351 + P338-P310

AHB A, 0613, UNP EU
n Acrylatemonomer n

3-(Dimethylamino)propyl 95% - GHS05, GHS07 Danger H302- 415650-25ML
O
acrylate H312-H314-H332 P280-P305
H2C CH3
O N + P351 + P338-P310
CH3
Dipentaerythritol penta-/ O
- monomethyl ether GHS07 Warning H315-H319- 407283-100ML
hexa-acrylate RO O OR
CH2 hydroquinone 500 ppm H335 P261-P305 + P351 + 407283-500ML
R = H or * as inhibitor P338
OR OR OR OR
Ethyl acrylate
O
99% hydroquinone GHS02, GHS07 Danger H225- E9706-100ML
A
H2C
monomethyl ether 10- H302-H312-H315-H317-H319- E9706-1L
O CH3 20 ppm as inhibitor H332-H335 P210-P261-P280- E9706-2L
P305 + P351 + P338 E9706-10L
2-Ethylacryloyl chloride 90% BHT 150 ppm as GHS02, GHS05, GHS06 Danger 589144-250MG
O
inhibitor H225-H314-H331 P210-P261-
H3C Cl P280-P305 + P351 + P338-
CH2 P310
Ethyl 2-(bromomethyl) 98% - GHS07 Warning H315-H319- 425222-1G

O
acrylate H2C
H335 P261-P305 + P351 + 425222-5G
O CH3 P338
Br
Ethyl cis-(β-cyano) 97% - GHS07, GHS09 Warning H315- 567663-1G

CN O
acrylate H319-H335-H411 P261-P273-
O CH3 P305 + P351 + P338
Ethylene glycol dicyclo- - monomethyl ether GHS07 Warning H315 407968-100ML

pentenyl ether acrylate O hydroquinone 700 ppm
H2C O
O as inhibitor
Ethylene glycol methyl 98% MEHQ 50-100 ppm as GHS02, GHS05, GHS06 Danger 408913-250ML
O
ether acrylate inhibitor H226-H302-H311-H318-H332 408913-1L
H2C OCH3
O P280-P305 + P351 + P338-
P312
Ethylene glycol phenyl - hydroquinone 75-125 GHS07, GHS09 Warning H315- 408336-250ML
O
ether acrylate ppm as inhibitor H319-H335-H411 P261-P273- 408336-1L
H2C O
O hydroquinone P305 + P351 + P338
monomethyl 0-120 ppm
as inhibitor
Ethyl 2-ethylacrylate 96% - GHS02, GHS07, GHS09 589101-250MG
O
Warning H226-H315-H319-
H3 C O CH3 H335-H411 P261-P273-P305
CH2 + P351 + P338
2-Ethylhexyl acrylate 98% monomethyl ether GHS07 Warning H315-H317- 290815-25ML

O
H2C
hydroquinone ≥0.001- H335 P261-P280 290815-1L
O CH3 ≤0.11% as stabilizer 290815-3L
CH3
290815-18L
Ethyl 2-propylacrylate 99% BHT 150 ppm as - 590118-250MG

O
inhibitor
H3C
O CH3
CH2
Ethyl 2-(trimethylsilyl- 97% - GHS07 Warning H315-H319- 368210-1G

CH3 O
methyl)acrylate H3C Si
H335 P261-P305 + P351 +
CH3
O CH3 P338
CH2
Hexyl acrylate 98% hydroquinone 100 ppm GHS07, GHS09 Warning H315- 408905-25ML
O
H2C
as inhibitor H317-H319-H335-H411 P261- 408905-100ML
OCH2(CH2)4CH3 P273-P280-P305 + P351 +
P338
4-Hydroxybutyl acrylate 90% hydroquinone 300 ppm GHS07 Warning H302-H312- 275573-25G
O
as inhibitor H315-H319-H332-H335 P261-
H2 C OH
O monomethyl ether P280-P305 + P351 + P338
hydroquinone 50 ppm as
inhibitor
2-Hydroxyethyl acrylate 96% monomethyl ether GHS05, GHS07, GHS09 Danger 292818-250ML
O
hydroquinone 200-650 H302-H315-H317-H318-H400 292818-1L
H2C OH
O ppm as inhibitor P273-P280-P305 + P351 + 292818-18L
P338
2-Hydroxy-3-phenoxy- - monomethyl ether GHS07 Warning H315-H319- 407364-100ML
propyl acrylate O hydroquinone 250 ppm H335 P261-P305 + P351 +
H2C as inhibitor P338
O O
OH

AHB A, 0613, UNP EU
n Acrylatemonomer n

Hydroxypropyl acrylate, O
95% hydroquinone GHS05, GHS06 Danger H301- 370932-1L
mixture of isomers H2C CH3
monomethyl ether 200- H311-H314-H317-H331 P261- 370932-18L
O 650 ppm as inhibitor P280-P305 + P351 + P338-
OH P310
O CH3
H2C OH
O
Isobornyl acrylate - monomethyl ether GHS07 Warning H315-H319- 392103-100ML

H3C CH3
hydroquinone 200 ppm H332-H335 P261-P305 + 392103-500ML
A
CH3
O as inhibitor P351 + P338 392103-1L
CH2
O
Isobutyl acrylate ≥99% monomethyl ether GHS02, GHS07 Warning H226- 436305-250ML
O
H2C
hydroquinone 10-20 H312-H315-H317-H332 P280 436305-1L
CH3
O ppm as inhibitor
CH3
Isodecyl acrylate - hydroquinone 70 ppm as GHS07, GHS09 Warning H315- 408956-250ML

O CH3
H2C
inhibitor H400 P273
OCH2(CH2)5CH2 CH3
Isooctyl acrylate - monomethyl ether GHS07, GHS09 Warning H315- 437425-100ML

O
H2C CH3
hydroquinone 75-125 H319-H335-H410 P261-P273-
O ppm as inhibitor P305 + P351 + P338-P501
CH3
Lauryl acrylate 90% monomethyl ether GHS07 Warning H315-H319- 447315-100ML

O
hydroquinone 60-100 H335 P261-P305 + P351 + 447315-500ML
H2C
OCH2(CH2)10CH3 ppm as inhibitor P338
Methyl 2-acetamidoa- 98% - GHS07 Warning H315-H319- 317519-1G

O
crylate H H335 P261-P305 + P351 + 317519-5G
H3 C N
OCH3 P338
O CH2
Methyl acrylate 99% monomethyl ether GHS02, GHS06 Danger H225- M27301-5ML
O
hydroquinone ~100 H301-H312-H315-H317-H319- M27301-250ML
H2C
OCH3 ppm as inhibitor H332-H335 P210-P261-P280- M27301-1L
P301 + P310-P305 + P351 + M27301-18L
P338
Methyl α-bromoacrylate 98% - GHS02, GHS07 Warning H226- 588466-1G
O
H 2C
H315-H319-H335 P261-P305
OCH3 + P351 + P338
Br
Methyl 2-(bromomethyl) 97% - GHS07 Warning H315-H319- 302546-1G

O
acrylate H335 P261-P305 + P351 + 302546-5G
Br OCH3 P338
CH2
Methyl 3-hydroxy-2- 98% - GHS02 Warning H226 404667-5ML

OH O
methylenebutyrate
H3C OCH3
CH2
Neopentyl glycol - monomethyl ether GHS06 Danger H311-H315- 408255-100ML

O O
diacrylate H2C CH2 hydroquinone 225 ppm H317-H319 P280-P305 +
O O as inhibitor P351 + P338
H3C CH3
Neopentyl glycol O O
- monomethyl ether GHS07 Warning H315-H317- 412147-250ML
propoxylate (1 PO/OH) H2C CH2 hydroquinone 300 ppm H319-H335 P261-P280-P305
diacrylate O C3H6O OC3H6 O as inhibitor + P351 + P338
m n
H3C CH3 m+n~2
Octadecyl acrylate 97% - GHS05, GHS07 Danger H315- 409693-250G

O
H317-H318 P280-P305 + 409693-1KG
H2C
OCH2(CH2)16CH3 P351 + P338
Pentabromobenzyl 98% - GHS07 Warning H319-H413 640263-1G

Br O
acrylate Br CH2
P305 + P351 + P338 640263-5G
O
Br Br
Br
Poly(ethylene glycol) - BHT 100 ppm as GHS08 Danger H340-H350 454990-250ML

methyl ether acrylate O
inhibitor P201-P308 + P313 454990-1L
H2C O
O CH3 MEHQ 100 ppm as
n inhibitor

AHB A, 0613, UNP EU
n Acrylicacidhydr n

Poly(ethylene glycol) - MEHQ ≤3,500 ppm as - 730270-1G
O
methyl ether acrylate inhibitor (may contain)
H2C O
O CH3 MEHQ Yes ppm as
n inhibitor
Poly(ethylene glycol) - MEHQ ≤5,500 ppm as - 730289-1G

O
methyl ether acrylate inhibitor (may contain)
H2C O
O CH3
A
n
Poly(propylene glycol) - monomethyl ether GHS07 Warning H315-H317- 469815-100ML

O
acrylate H2C O H
hydroquinone 200-400 H319-H335 P261-P280-P305
O
n
ppm as inhibitor + P351 + P338
CH3
Sodium acrylate 97% - GHS07 Warning H315-H319- 408220-25G

O
H335 P261-P305 + P351 + 408220-100G
H2C
ONa P338
Soybean oil, epoxidized - - monomethyl ether GHS07 Warning H317 P280 412333-1L
acrylate hydroquinone 8,500
ppm as inhibitor
3-Sulfopropyl acrylate - - GHS07 Warning H315-H319- 251631-100G
O O
potassium salt H2C
H335 P261-P305 + P351 + 251631-500G
S OK
O P338
O
Tetrahydrofurfuryl - hydroquinone 500 ppm GHS07 Warning H315-H319 408271-100ML

acrylate O as inhibitor P305 + P351 + P338
O CH2 monomethyl ether
O hydroquinone 500 ppm
as inhibitor
2,2,2-Trifluoroethyl 99% monomethyl ether GHS02, GHS07 Danger H225- 297720-5G
O
acrylate H2C
hydroquinone 200 ppm H302-H312-H315-H319-H332- 297720-25G
O CF3 as inhibitor H335 P210-P261-P280-P305
+ P351 + P338
3-(Trimethoxysilyl)propyl 92% BHT 100 ppm as GHS05, GHS07 Danger H314- 475149-5ML
O OCH3
acrylate H2C
inhibitor H317-H332-H412 P273-P280- 475149-25ML
Si OCH3
O P305 + P351 + P338-P310
OCH3
3,5,5-Trimethylhexyl - monomethyl ether GHS07, GHS09 Warning H315- 424021-25ML

O CH3
acrylate H2C
CH3 hydroquinone 15-20 H319-H335-H411 P261-P273-
O CH3 ppm as inhibitor P305 + P351 + P338
CH3
Acrylic acid, 99% Acrylic acid-1-13C

[79‑10‑7] Merck 14,130; Beil. 2,397; 2,IV,1455 CH2=CHCOOH [95387‑98‑7] H2C=CH13CO2H FW 73.06
FW 72.06 mp ........................................................................... 13 °C n20
D ....................................................................... 1.4202
mp ........................................................................... 13 °C vd ................................................................ 2.5 (vs air) bp ......................................................................... 139 °C
bp ......................................................................... 139 °C vp ................................................ 4 mmHg (20 °C)
density ..................................... 1.051 g/mL, 25 °C ait ......................................................................... 744 °F  99 atom % 13C
 anhydrous, contains 180-200 ppm monomethyl ether hydro- contains hydroquinone as stabilizer
quinone as inhibitor water ................................................................................................................................................................................. ≤5%
2569
Danger H226-H302-H312-H314-H331-H335- density ............................................................................................................................................. 1.065 g/mL, 25 °C
H400 P261-P273-P280-P305 + P351 + P338-P310
2579
Danger H226-H302-H312-H314-H332-H400
147230-1L 1L P273-P280-P305 + P351 + P338-P310
147230-2.5L 2.5 L 487899-250MG ampule 250 mg
Acrylic acid-d4
147230-100G glass btl 100 g
147230-500G glass btl 500 g [285138‑82‑1] D2C=CDCO2D FW 76.09
147230-3KG glass btl 3 kg  98 atom % D
147230-18KG comp drum 18 kg 456349 Full product information at Aldrich.com
Acrylic acid N-hydroxysuccinimide ester, ≥90%

N-Acryloxysuccinimide O
[38862‑24‑7] C7H7NO4 FW 169.13 O
H2C N
O
O
store at: 2-8°C


AHB A, 0613, UNP EU
n Acrylonitrile n
Acrylonitrile > N-Acryloxysuccinimide, see Acrylic acid N-hydroxysuccinimide ester

Page 53
Vinyl cyanide Acryloyl chloride, see Acrylate Monomers under Page 50
[107‑13‑1] Merck 14,131; Beil. 2,IV,1473; Fieser 1,14; 7,4 CH2=CHCN
FW 53.06 Acryloyl chloride, ≥97%
An industrial carcinogen that is a multisite carcinogen in rats and 2-Propenoyl chloride
possibly carcinogenic to humans. [814‑68‑6] Beil. 2,IV,1471 CH2=CHCOCl FW 90.51
mp ....................................................................... −83 °C vd ............................................................. 1.83 (vs air) bp ..................................................................... 72-76 °C vd ................................................................ >1 (vs air)
bp ............................................................................ 77 °C vp .............................................. 86 mmHg (20 °C)
A
density ..................................... 1.114 g/mL, 25 °C vp .................................................... 1.93 psi (20 °C)
n20
D .............................................................................. 1.391 ait ......................................................................... 897 °F n20
D .............................................................................. 1.435
25689
Danger H225-H301-H311-H315-H317-
H318-H330-H335-H350-H411 P201-P210-  contains ~400 ppm phenothiazine as stabilizer
P260-P273-P280-P284
256
Danger H225-H314-H330 P210-P260-P280-P284-P305
 ≥99%, contains 35-45 ppm monomethyl ether hydroquinone as + P351 + P338-P310
inhibitor A24109-5G glass btl 5g
110213-5ML glass btl 5 mL A24109-100G glass btl 100 g
110213-100ML glass btl 100 mL A24109-500G glass btl 500 g
110213-500ML glass btl 500 mL A24109-1KG glass btl 1 kg
110213-1L glass btl 1L (R)-α-Acryloyloxy-β,β-dimethyl-γ-butyrolactone, 95%
[102096‑60‑6] C9H12O4 FW 184.19 H3C
110213-4L glass btl 4L O
H3C CH2
110213-18L steel drum 18 L O
O O
 ≥99%, contains 35-45 ppm monomethyl ether hydroquinone as
mp .................................................................. 7 to 8 °C density ................................. 1.125 g/mL, 20 °C
inhibitor
bp ................................................. 84 °C/0.1 mmHg n20 D ............................................................................. 1.46
320137-1L PVC coated 1L
[α]20
D +6.0°, c = 17 in methylene chloride
Acrylonitrile-15N contains 0.1% monomethyl ether hydroquinone as stabilizer
H2C=CHC15N FW 54.06
7
Warning H315-H319-H335 P261-P305 + P351 + P338
 98 atom % 15
N
13 3-(Acryloyloxy)-2-hydroxypropyl methacrylate
Acrylonitrile-1- C
[1709‑71‑3] H2C=C(CH3)CO2CH2CH(OH)CH2O2CCH=CH2 FW 214.22
[91628‑87‑4] H2C=CH13CN FW 54.06
density ................................................................................................................................................ 1.14 g/mL, 25 °C
 99 atom % 13
C n20
D ...................................................................................................................................................................................... 1.473
491721 Full product information at Aldrich.com contains 200 ppm monomethyl ether hydroquinone as inhibitor,
350 ppm BHT as inhibitor
Acrylonitrile-2-d
57
Danger H315-H317-H318 P280-P305 + P351 + P338
[4635‑82‑9] Beil. 2,IV,1479 H2C=CDCN FW 54.07
mp ....................................................................... −83 °C n20 D .......................................................................... 1.391 454982-100ML glass btl 100 mL
bp ............................................................................ 77 °C
 98 atom % D > ACTB, see tert-Butyl acetoacetate Page 556
contains hydroquinone as stabilizer Actinomycin D, ≥95%
density ............................................................................................................................................. 0.830 g/mL, 25 °C [50‑76‑0] C62H86N12O16 FW 1255.42
491756-1G glass btl 1g  from Streptomyces sp., suitable for cell culture
6
Acrylonitrile-d3 Danger H300 P264-P301 + P310 store at: 2-8°C
[53807‑26‑4] D2C=CDCN FW 56.08

mp ....................................................................... −83 °C n20 A9415-2MG glass btl 2 mg
D .......................................................................... 1.391
bp ............................................................................ 77 °C A9415-5MG glass btl 5 mg
 98 atom % D A9415-25MG glass btl 25 mg
contains hydroquinone as stabilizer > Actinomycin C1, see Actinomycin D Page 54
Actinomycin IV, see Actinomycin D Page 54
density ............................................................................................................................................. 0.860 g/mL, 25 °C Activated alumina, weakly acidic, see Aluminum oxide Page 83
2568
Danger H225-H301-H315-H318-H331-H334-
H335-H350 P201-P210-P261-P280-P301 + P310- Activated charcoal
P305 + P351 + P338
Charcoal activated
485314-1G ampule 1g
[7440‑44‑0] Merck 14,1807; Fieser 7,52 C FW 12.01
Acrylonitrile-3-13C resistivity ............................................................................................................ 1375 μΩ-cm, 20°C (graphite)
mp ..................................................................... 3550 °C ait ......................................................................... 842 °F
[55757‑47‑6] H213C=CHCN FW 54.06 vp ............................................. <0.1 mmHg (20 °C)
 99 atom % 13
C
 untreated, granular, 4-8 mesh
C2764-500G poly btl 500 g
Acrylonitrile-13C3 C2764-2.5KG poly drum 2.5 kg
13 13 13
H2 C= CH CN FW 56.04
 99 atom % 13
C C2889-500G poly btl 500 g
586641 Full product information at Aldrich.com C2889-2.5KG poly drum 2.5 kg

AHB A, 0613, UNP EU
n Activeamylalcoh n
 decolorizing  DARCO® KB-WJ
2
161551-1KG fiber drum 1 kg Warning H252 P235 + P410
161551-5KG fiber drum 5 kg
675342-250G 250 g
 granular, 4-14 mesh 675342-1KG fiber drum 1 kg
292591-250G glass btl 250 g
> Activated charcoal, see Carbon Page 54
A
Activated Charcoal Norit®
 DARCO®, particle size 4-12 mesh, granular
Acid-washed lignite carbon for general uses. Charcoal activated Norit®
242233-250G glass btl 250 g
[7440‑44‑0] Merck 14,1807 C FW 12.01
242233-1KG fiber drum 1 kg  type Darco® 12x20, from lignite, granulated material, granular
for removing organic impurities from aqueous solutions in electro-
 DARCO®, 12-20 mesh, granular plating and in drug research
Acid-washed lignite carbon for general uses. size .............................................................................................................................................................................. ~1 mm
242241-250G glass btl 250 g
96831-1KG 1 kg
96831-5KG 5 kg
 DARCO®, particle size 20-40 mesh, granular  type Norit® CA1, from wood, chemically activated, powder
Acid-washed lignite carbon for general uses. carrier for catalysts, good filtering properties
242268-250G glass btl 250 g
2
Warning H252 P235 + P410
242268-500G glass btl 500 g
242268-1KG fiber drum 1 kg 97876-1KG 1 kg
 DARCO®, particle size −100 mesh, powder  type Norit® GAC 1240W, from coal, for potable water processing,
High-purity carbon, especially useful for minimizing contamination in steam activated, granular
products. for potable water processing
242276-250G glass btl 250 g diam. .......................................................................................................................................................................... ~1 mm
242276-1KG fiber drum 1 kg LOD ................................................................................................................................................................................ ≤4.0%
ign. residue .............................................................................................................................................................. ≤12%
 NORIT® RO 0.8, pellets
37771-1KG 1 kg
Designed for use in liquid-phase adsorption systems.
329428-500G glass btl 500 g  type Norit® PK 1-3, from peat, steam activated, granular
329428-2KG fiber drum 2 kg for decolorizing and deodorizing
particle size .......................................................................................................................................................... 1-3 mm
22874-250G 250 g
C3014-2.5KG poly drum 2.5 kg  type Norit® RB3, for gas purification, steam activated, rod
diam. .......................................................................................................................................................................... ~3 mm
 untreated powder, 100-400 mesh butane adsorption ............................................................................................................... 18-23% (p/p0 = 1)
C3345-500G poly btl 500 g LOD .................................................................................................................................................................................... ≤5%
C3345-1KG poly btl 1 kg 29204-500G 500 g
C3345-2.5KG poly drum 2.5 kg
 type Norit® RB4C, steam activated, rod, for the purification of gas
C3345-5KG poly drum 5 kg
diam. .......................................................................................................................................................................... ~4 mm
 acid-washed with hydrochloric acid ..................................................................................................... 18-23% (butane adsorption (p/po = 0.1))
Used in a wide variety of biochemical and immunological LOD .................................................................................................................................................................................... ≤5%
applications to remove reactants and waste products. 51127-1KG-F 1 kg
 type Norit® SX ultra, from peat, corresponds U.S. Food chemicals
codex (3rd Ed.), steam activated and acid washed, highly
 acid-washed with phosphoric and sulfuric acids purified, powder
LOD ................................................................................................................................................................................. ≤10%
ign. residue ................................................................................................................................................................ ≤6%
53663-250G 250 g
 purified by resistive heating of graphite 53663-1KG 1 kg
Fullerene yield 5-10%
 from peat, multi-purpose activated charcoal, steam activated
8
Warning H351 P281
and acid washed, powder
type Norit® SX2
390127-25G glass btl 25 g 93067-250G 250 g
 DARCO® KB-G Activated Nickel Catalyst

Suitable for the purification of highly colored and/or foaming process Nickel sponge
liquids. [7440‑02‑0] Merck 14,8107; 14,6498
2
 suspension in water
shelf life (limited shelf life, expiry date on the label)
675326-250G glass btl 250 g
278
Danger H250-H317-H351-H372 P222-P231-P280-
675326-1KG fiber drum 1 kg P314-P422
83440-100G 100 g
83440-500G 500 g
> Active amyl alcohol, see (S)-(−)-2-Methylbutanol Page 1751

AHB A, 0613, UNP EU
n Acva n
ACVA, see 4,4′-Azobis(4-cyanovaleric acid) Page 214 1,3-Adamantanedicarboxylic acid, 98%
1-AD, see 1-Adamantanethiol Page 56
ADC
Adamantane, ≥99% [39269‑10‑8] Beil. 9,IV,2997 C12H16O4 FW 224.25
[281‑23‑2] Merck 14,149; Beil. 5,IV,469 C10H16 FW 136.23 mp .............................................................................................................................................................. 276 to 278 °C
mp .............................................................................................................................................. 209 to 212 °C (subl.) 340820-1G glass btl 1g
9 1,3-Adamantanediol, ≥99.0% (GC)

Warning H400 P273
A
1,3-Dihydroxyadamantane OH
100277-25G poly btl 25 g
[5001‑18‑3] C10H16O2 FW 168.23
100277-100G poly btl 100 g
OH
Adamantane-d16
[30470‑60‑1] C10D16 FW 152.33 mp ............................................................................................................................................................................ ~260 °C
93749-5G-F poly btl 5g
 98 atom % D
586668 Full product information at Aldrich.com 4,4′-(1,3-Adamantanediyl)diphenol, 98%
1-Adamantaneacetic acid, 98% [37677‑93‑3] C22H24O2 FW 320.42

1-Adamantylacetic acid O
[4942‑47‑6] Beil. 9,IV,256 C12H18O2 FW 194.27 1-Adamantaneethanol, 98%
OH
2-(1-Adamantyl)ethanol
[6240‑11‑5] C12H20O FW 180.29
mp ................................................................................................................................................................... 66 to 69 °C
mp .............................................................................................................................................................. 134 to 137 °C
127272-25G poly btl 25 g
1-Adamantanemethanol, 99%
1-Adamantanecarbonitrile, 97%
1-(Hydroxymethyl)adamantane
1-Cyanoadamantane CN [770‑71‑8] Beil. 6,IV,400 C11H18O FW 166.26
[23074‑42‑2] C11H15N FW 161.24 mp .............................................................................................................................................................. 114 to 117 °C
mp .............................................................................................................................................................. 193 to 196 °C 1-Adamantanemethylamine, 98%
7
Warning H302-H312-H332 P280 1-(Aminomethyl)adamantane NH2
[17768‑41‑1] C11H19N FW 165.28
1-Adamantanecarbonyl chloride, 95%

[2094‑72‑6] Fieser 2,15 C11H15ClO FW 198.69 bp ......................................... 83-85 °C/0.3 mmHg n20
D ....................................................................... 1.5137
O Cl
density ..................................... 0.933 g/mL, 25 °C
5
Danger H314 P280-P305 + P351 + P338-P310

mp .................................................................................................................................................................... 49 to 51 °C
bp ............................................................................................................................................ 135-136 °C/10 mmHg 1-Adamantanethiol
5
Danger H314-EUH014 P280-P305 + P351 + P338-P310 1-AdmSH; 1-AdSH; 1-AD SH
[34301‑54‑7] C10H16S FW 168.30
6
1-Adamantanecarboxamide, 97% Danger H301-H319 P301 + P310-P305 + P351 + P338
[5511‑18‑2] C11H17NO FW 179.26

 95%
390607-1G glass btl 1g Reagent used to prepare 1-adamantylthio sialosides for glycosylation
1-Adamantanecarboxylic acid, 99% with mono- and oligosaccharides on treatment with NIS in triflic
acid.1
[828‑51‑3] Beil. 9,IV,253 C11H16O2 FW 180.24 O OH mp ................................................................................................................................................................. 99 to 106 °C
Lit. cited: 1. J. Org. Chem. 72, 7794 (2007)
mp .............................................................................................................................................................. 172 to 174 °C  ADT 8

99% (GC)
106399-25G poly btl 25 g
solid
106399-100G poly btl 100 g
mp .............................................................................................................................................................. 103 to 105 °C
1,3-Adamantanediacetic acid, 97% 719234-500MG glass btl 500 mg
H2ADA 1-Adamantanol, 99%
[17768‑28‑4] Beil. 19,278 C14H20O4 FW 252.31
1-Hydroxyadamantane
mp .............................................................................................................................................................. 234 to 237 °C
[768‑95‑6] Beil. 6,IV,391 C10H16O FW 152.23
mp ............................................................................................................................................................... 247 °C (subl.)
130346-25G poly btl 25 g

AHB A, 0613, UNP EU
n Adamantylphosph n
2-Adamantanol, 97% 1-Adamantyl fluoroformate, ≥90%

2-Hydroxyadamantane OH [62087‑82‑5] C11H15FO2 FW 198.23 O
[700‑57‑2] C10H16O FW 152.23
F O
mp .............................................................................................................................................................. 258 to 262 °C

mp ................................................................................................................................................................... 30 to 32 °C
2-Adamantanone, 99% 5
Danger H314 P280-P305 + P351 + P338-P310
A
[700‑58‑3] C10H14O FW 150.22 O
5-(2-Adamantylidene)-2,2-dimethyl-1,3-dioxane-4,6-dione, 99%
[51757‑47‑2] C16H20O4 FW 276.33 CH3
O O
mp .............................................................................................................................................. 256 to 258 °C (subl.) CH3
O
O
146048-25G poly btl 25 g
146048-100G poly btl 100 g
mp .............................................................................................................................................................. 207 to 208 °C
1-Adamantylamine, 97%
1-Aminoadamantane NH2
[768‑94‑5] Merck 14,374 C10H17N FW 151.25 1-Adamantyl isocyanate, 97%
[4411‑25‑0] C11H15NO FW 177.24 NCO
mp .............................................................................................................................................................. 206 to 208 °C

Building block for an L-piperidinamide catalyst used in an enantio-
selective Strecker reaction of phosphinoyl imines.1 mp .............................................................................................................................................................. 144 to 146 °C
7
7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 + P338
138576-100G glass btl 100 g 1-Adamantyl isothiocyanate, 99%
[4411‑26‑1] C11H15NS FW 193.31 NCS
2-Adamantylamine hydrochloride, 99%
2-Adamantanamine hydrochloride; 2-Aminoadamantane hydro-
chloride
[10523‑68‑9] C10H17N · HCl FW 187.71 mp .............................................................................................................................................................. 166 to 168 °C
mp ............................................................................................................................................................................ >300 °C
7
7
Warning H315-H319-H335 P261-P305 + P351 + P338 + P338
153818-25G glass btl 25 g 1-Adamantyl methyl ketone, 99%
[1660‑04‑4] C12H18O FW 178.27 O CH3
> 1-Adamantyl bromide, see 1-Bromoadamantane Page 432
1-Adamantyl bromomethyl ketone, 97%

[5122‑82‑7] C12H17BrO FW 257.17 O
Br
mp ................................................................................................................................................................... 53 to 55 °C
mp .................................................................................................................................................................... 76 to 79 °C
2-(1-Adamantyl)-4-methylphenol, 99%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[41031‑50‑9] C17H22O FW 242.36 OH
1-(1-Adamantyl)ethylamine hydrochloride, 99% CH3

Rimantadine hydrochloride H3C NH2
[1501‑84‑4] Merck 14,8224 C12H21N · HCl FW 215.76 mp .............................................................................................................................................................. 128 to 130 °C
7
• HCl Warning H315-H319-H335 P261-P305 + P351 + P338

mp ............................................................................................................................................................................ >300 °C
1-Adamantylphosphaethyne, ≥97.0% (GC/CH)
7
1-(2-Phosphaethynyl)adamantane C P
390593-1G glass btl 1g [101055‑70‑3] C11H15P FW 178.21
mp ................................................................................................................................................................... 69 to 72 °C
store at: −20°C
44478-500MG-F glass btl 500 mg

AHB A, 0613, UNP EU
n Adamantyltrimet n
> 1-(1-Adamantyl)-3-(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium > Adenine-9-β-D-ribofuranoside, see Adenosine Page 58
chloride, see 1-(1-Adamantyl)-3-(2,4,6-trimethylphenyl)imidazolinium Adenine riboside, see Adenosine Page 58
chloride Page 58
Adenosine, ≥99%
1-(1-Adamantyl)-3-(2,4,6-trimethylphenyl)imidazolinium
chloride 9-β-D-Ribofuranosyladenine; Adenine riboside; Adenine- NH2
9-β-D-ribofuranoside N N
1-(1-Adamantyl)-3-(2,4,6-trimethylphenyl)-4,5- H3C CH3 [58‑61‑7] Merck 14,153; Beil. 26,IV,3598 C10H13N5O4
dihydroimidazolium chloride FW 267.24 N N
HO
C22H31ClN2 FW 358.95 N N
A Cl O
CH3
OH OH
mp .............................................................................................................................................................. 263 to 280 °C
Sold under license from Kanata Chemical Technologies Inc. for mp .............................................................................................................................................................. 234 to 236 °C
research purposes only. store at: 2-8°C
7
Warning H315-H319-H335 P261-P305 + P351 + P338 A9251-1G poly btl 1g
665029-100MG glass btl 100 mg A9251-25G poly btl 25 g
1-Adamantylzinc bromide solution > Adenosine 3′,5′-cyclophosphate, see Adenosine 3′,5′-cyclic monophosphate
Page 58
[312624‑15‑0] C10H15BrZn FW 280.52 ZnBr
Adenosine 3′,5′-cyclic monophosphate, ≥98.5% (HPLC)

3′,5′-Cyclic AMP; Adenosine 3′,5′-cyclophosphate; NH2
cAMP N N
 0.5 M in THF [60‑92‑4] Merck 14,2708; Beil. 26,IV,3618
N
N
Product of Rieke® Metals, Inc. ®Registered trademark of Rieke Metals, C10H12N5O6P FW 329.21
O O
Inc.
density ................................................................................................................................................ 0.97 g/mL, 25 °C O P O OH
497606-50ML Sure/Seal™ 50 mL OH
2-Adamantylzinc bromide solution mp ................................................................................................................................................................ 260 °C (dec.)
[171860‑65‑4] C10H15BrZn FW 280.52  powder

 0.5 M in THF
color .............................................................................................................................................................................. white
497614-50ML Sure/Seal™ 50 mL store at: −20°C
> Adam’s catalyst, see Platinum(IV) oxide Page 2084 A9501-1G poly btl 1g
ADC, see 1,3-Adamantanedicarboxylic acid Page 56
ADD, see 1,1′-(Azodicarbonyl)dipiperidine Page 215
Adenine, ≥99%
Adenosine 5′-monophosphate monohydrate, ≥97%
Vitamin B4; 6-Aminopurine NH2 5′-Adenylic acid; A-5′-P; 5′-AMP; AMP
[73‑24‑5] Merck 14,152; Beil. 26,IV,3561 C5H5N5 N
N [18422‑05‑4] Merck 14,158; Beil. 26,IV,3615 C10H14N5O7P · H2O
FW 135.13
N N FW 365.24
H
 from yeast
mp ............................................................................................................................................................................ >360 °C
soluble in ........................................................................................................................................................................ H2O
6
Danger H301 P301 + P310 store at: −20°C
A8626-100G poly btl 100 g Adenosine 5′-triphosphate disodium salt hydrate, 99%
A8626-1KG poly btl 1 kg 5′-ATP-Na2; ATP disodium salt hydrate
Adenine hemisulfate salt, ≥99% [34369‑07‑8] Merck 14,155; Beil. 26,IV,3654 C10H14N5Na2O13P3 ·
xH2O FW 551.14 (Anh)
Adenine sulfate salt; 6-Aminopurine hemisulfate salt mp ................................................................................................................................................................ 176 °C (dec.)
[321‑30‑2] Beil. 26,V,16,100 C5H5N5 · 1/2H2SO4 FW 184.17 Contains solvent of crystallization, varying amounts of water
A9126-25G poly btl 25 g A26209-1G glass btl 1g
A9126-100G poly btl 100 g A26209-5G glass btl 5g
A9126-1KG poly btl 1 kg A26209-10G glass btl 10 g
Adenine monohydrochloride, ≥99.0% (HPLC) Adenosine-15N5 5′-triphosphate sodium salt solution, 8
[2922‑28‑3] C5H5N5 · HCl FW 171.59 NH2 • HCl
95% (CP)
N N 15NH
2
N N 15N
H 15N
mp ............................................................................................................................................................. ~285 °C (dec.) 15N

15N
• xNa
O O O
LOD .................................................................................................................................................................................... ≤5%
HO P O P O P O O
7
Warning H302 OH OH OH
OH OH
ATP-15N5 sodium salt solution

AHB A, 0613, UNP EU
n Adipicd8aciddih n
C10H1615N5O13P3 · xNa FW 512.15 (FA) +

ADI-PURE® high purity adipic acid; ADI-PURE® LGA adipic acid
contains 5 mM Tris buffer
7
Warning H319 P305 + P351 + P338
Molecular weight and empirical formula are based on the free acid.
concentration .................................................................................................................................. 100 mM in H2O A26357-25G poly btl 25 g
ship: dry ice A26357-100G poly btl 100 g
 supplied as the sodium salt in 100 mM soln with H2O, with 5 mM A26357-500G poly btl 500 g
Tris buffer, 98 atom % 15N A26357-1KG poly btl 1 kg
A
mol wt 512.06, atom % calculation (as free acid) A26357-3KG poly btl 3 kg
707783-1MG 1 mg
Adipic acid-1,6-13C2
707783-10MG 10 mg 13 13
707783-25MG 25 mg
[133954‑44‑6] HO2 C(CH2)4 CO2H FW 148.13
13  99 atom % 13
C
Adenosine- C10 5′-triphosphate sodium salt solution, 8
95% (CP) 489697 Full product information at Aldrich.com
NH2 Adipic acid-2,2,5,5-d4

13C
N 13C N HO2CCD2(CH2)2CD2CO2H FW 150.17
13C
13
C 13
C
N
 98 atom % D
N
7
O O O Warning H319 P305 + P351 + P338
HO P O P O P O 13 • xNa+
C
OH OH OH O
13C 13C
614262-10G 10 g
13C 13C
Adipic acid-d10
OH OH
Hexanedioic acid-d10
13
ATP- C10 sodium salt solution [25373‑21‑1] DO2C(CD2)4CO2D FW 156.20
13
C10H16N5O13P3 · xNa+ FW 517.11 (FA) mp .............................................................................................................................................................. 151 to 154 °C
contains 5 mM Tris buffer bp .................................................................................................................................................... 265 °C/100 mmHg
Molecular weight and empirical formula are based on the free acid.
 98 atom % D
concentration .................................................................................................................................. 100 mM in H2O
ship: dry ice
7
Warning H319 P305 + P351 + P338
 supplied as sodium salt in 100 mM soln in H2O, with 5 mM Tris
buffer, 98 atom % 13C 451762-1G glass btl 1g
mol wt 516.91, atom % calculation (as free acid) 451762-5G glass btl 5g
710695-1MG 1 mg
> Adipic acid di(2-ethylhexyl) ester, see Bis(2-ethylhexyl) adipate Page 332
710695-10MG 10 mg
710695-25MG 25 mg Adipic acid dihydrazide, ≥98%
Adenosine-13C10,15N5 5′-triphosphate sodium salt solution, 90% [1071‑93‑8] Beil. 2,IV,1977 NH2NHCO(CH2)4CONHNH2 FW 174.20
(CP) mp .............................................................................................................................................................. 180 to 182 °C
ATP-13C10,15N5 sodium salt solution Homobifunctional cross-linking reagent specific for aldehydes
13
C10H1615N5O13P3 · xNa+ FW 522.07 (FA) resulting in relatively stable hydrazone linkages. Typically, used in the
contains 5 mM Tris buffer linking of glycoproteins, such as antibodies, in a site specific fashion
concentration .................................................................................................................................. 100 mM in H2O following periodate oxidation. Oxidation and coupling may conven-
iently be performed at pH 5.0 due to the low pKa of the hydrazide
 Supplied as sodium salt in 100 mM soln in H2O, with 5 mM Tris which avoids competition by primary amines.
buffer, 98 atom % 13C; 98 atom % 15N Note that the hydrazone bond may be stabilized by selective
mol wt 521.77, atom % calculation (as the free acid) reduction using, for example, sodium cyanoborohydride.
ship: dry ice store at: −20°C
soluble in ...................................................................................................................................... H2O (100 mg/mL)
645702-1MG poly btl 1 mg store at: −20°C
645702-10MG poly btl 10 mg A0638-25G poly btl 25 g
645702-25MG poly btl 25 mg A0638-100G poly btl 100 g
Adipamide, 98% Adipic acid monoethyl ester, 97%
[628‑94‑4] Beil. 2,653 H2NCO(CH2)4CONH2 FW 144.17 Mono-ethyl adipate
mp .............................................................................................................................................................. 226 to 229 °C [626‑86‑8] Beil. 2,I,277 HO2C(CH2)4CO2C2H5 FW 174.19
7
Warning H315-H319-H335 P261-P305 + P351 + P338 mp ............................................................ 28 to 29 °C density .................................... 0.98 g/mL, 25 °C
bp ............................................... 180 °C/18 mmHg n20 D .......................................................................... 1.439

122769-25G poly btl 25 g
Adipic acid, 99% > Adipic acid monomethyl ester, see mono-Methyl adipate Page 1730
Hexanedioic acid Adipic acid monomethyl ester chloride, see Methyl adipoyl chloride
Page 1730
[124‑04‑9] Merck 14,162; Beil. 2,IV,1956; Fieser 1,15
HOOC(CH2)4COOH FW 146.14 Adipic-d8 acid dihydrazide, 98% (CP) 8
mp ...................................................... 151 to 154 °C vp .......................................... 1 mmHg (159.5 °C)
NH2NHCO(CD2)4CONHNH2 FW 182.25
bp ............................................ 265 °C/100 mmHg ait ......................................................................... 788 °F
vd ....................................................................... 5 (vs air) mp .............................................................................................................................................................. 180 to 182 °C
 98 atom % D
717266

AHB A, 0613, UNP EU
n Adipicsemialdeh n
Adipic semialdehyde methyl ester, ≥95% Lit. cited: 1. J. Org. Chem. 57, 2768 (1992)
2. Aldrichimica Acta 27, 70 (1994)
[6654‑36‑0] C7H12O3 FW 144.17 O 3. J. Org. Chem. 71, 7741 (2006)
H
OCH3 4. Eur. J. Org. Chem. 2669 (2006)
O
7
Warning H315-H319-H335 P261-P305 + P351 + P338
density ....................................................................................................................................................... 1 g/mL, 25 °C
store at: −20°C 392758-10G glass btl 10 g
A
A0786
> Adipoin, see 2-Hydroxycyclohexanone dimer Page 1478

AD-mix-β
H3C H3C
Adiponitrile, 99% H
H
1,4-Dicyanobutane N N
[111‑69‑3] Beil. 2,IV,1975 NC(CH2)4CN FW 108.14 H O O
N N H
mp .................................................................. 1 to 3 °C vd ................................................................ 3.7 (vs air) H3CO H3CO
bp ......................................................................... 295 °C vp .......................................... 0.01 mmHg (40 °C)
density ..................................... 0.951 g/mL, 25 °C ait ...................................................................... 1022 °F N N
n20
D .............................................................................. 1.438
Reagent for Sharpless Asymmetric Dihydroxylation.1,2
DuPont product Catalyst employed in the Sharpless Asymmetric Dihyroxylation of (E,
6
Danger H301-H315-H319-H330-H335 P260-P284-P305 + P351 + E)- or (E,Z)-1,3-dienoates.3 Also used in the preparation of ß-hydroxy-
P338-P310
γ-lactones from ß,γ-unsaturated esters.4
D77001-100ML glass btl 100 mL Contains chiral ligand (DHQD)2PHAL
D77001-1L glass btl 1L Mixture contains:
(DHQD)2PHAL (Cat. No. 392731) 0.0016 mole
Adiponitrile-d8
Potassium carbonate, powder 0.4988 mole
[34006‑32‑1] NC(CD2)4CN FW 116.19 Potassium ferricyanide 0.4988 mole
 98 atom % D Potassium osmate dihydrate 0.0007 mole
Sold under license from Rhodia Pharma Solutions.
Lit. cited: 1. Chem. Rev. 94, 2483 (1994)
Adipoyl chloride, 98% 2. J. Org. Chem. 57, 2768 (1992)
3. J. Org. Chem. 71, 7741 (2006)
Adipyl chloride 4. Eur. J. Org. Chem. 2669 (2006)
[111‑50‑2] Beil. 2,IV,1972 ClCO(CH2)4COCl FW 183.03
7
Warning H315-H319-H335 P261-P305 + P351 + P338
bp ....................................... 105-107 °C/2 mmHg n20D .......................................................................... 1.471
density ..................................... 1.259 g/mL, 25 °C
Used in a preparaton of biphenyl end-capped liquid crystals.1 392766-50G glass btl 50 g
Material may darken in storage
Lit. cited: 1. Tetrahedron Lett. 47, 5569 (2006) > 1-AdmSH, see 1-Adamantanethiol Page 56
5
Danger H314 P280-P305 + P351 + P338-P310
Adogen® 464
165212-5G glass btl 5g Methyltrialkyl(C8-C10)ammonium chloride
165212-25G glass btl 25 g [72749‑59‑8] Fieser 7,4; 6,10
density ..................................... 0.898 g/mL, 25 °C vd ................................................................ >1 (vs air)
165212-100G glass btl 100 g
n20
D ........................................................................... 1.4665 vp ............................................. 33 mmHg (20 °C)
> ADI-PURE® high purity adipic acid, see Adipic acid Page 59
2569
Danger H226-H301-H315-H318-H410 P273-
ADI-PURE® LGA adipic acid, see Adipic acid Page 59 P280-P301 + P310-P305 + P351 + P338-P501
Adma 8, see N,N-Dimethyloctylamine Page 1101
ADMCS, see Allyl(chloro)dimethylsilane Page 70 856576-100ML poly btl 100 mL
856576-500ML poly btl 500 mL
AD-mix-α
> (−)-Adrenalin, see (−)-Epinephrine Page 1186
H3C H3 C Adrenalone hydrochloride, see 3′,4′-Dihydroxy-2-(methylamino)aceto-
H H phenone hydrochloride Page 1019
N N
N O O N
H H
Adrenochrome semicarbazone
H3CO OCH3
Carbazochrome O OH
N N
[69‑81‑8] Merck 14,1788 C10H12N4O3 N
H2N N
FW 236.23 H
O N
Reagent for Sharpless Asymmetric Dihydroxylation.1,2 CH3
Catalyst employed in the Sharpless Asymmetric Dihyroxylation of (E,
E)- or (E,Z)-1,3-dienoates.3 Also used in the preparation of ß-hydroxy-γ- store at: −20°C
lactones from ß,γ-unsaturated esters.4 A5877-1G glass btl 1g
Contains chiral ligand (DHQ)2PHAL
Mixture contains: Adrenosterone, 98%
(DHQ)2PHAL (Cat. No. 392723) 0.0016 mole Androst-4-ene-3,11,17-trione; 4-Androstene- H3C O
Potassium carbonate, powder 0.4988 mole 3,11,17-trione; Reichstein’s substance G; O
H3C H
Potassium ferricyanide 0.4988 mole 11-Ketoandrostenedione
Potassium osmate dihydrate 0.0007 mole [382‑45‑6] Merck 14,176; Beil. 7,III,4601 C19H24O3 H H
O
FW 300.39
mp .............................................................................................................................................................. 219 to 222 °C
[α]20

AHB A, 0613, UNP EU
n Alanine n
> 1-AdSH, see 1-Adamantanethiol Page 56 H-Ala-HMPB-ChemMatrix® resin
ADT, see 1-Adamantanethiol Page 56
8
Aedotron™ C3-NM, see Poly(3,4-ethylenedioxythiophene), bis-poly(ethyl- O
eneglycol), lauryl terminated Page 2108 O OCH3
Aedotron™ C3-PC, see Poly(3,4-ethylenedioxythiophene), bis-poly(ethylene- N NH2
H
glycol), lauryl terminated Page 2108 O
CH3
Aedotron™ C-NM, see Poly(3,4-ethylenedioxythiophene)-block-poly(ethylene
glycol) solution Page 2109 O
Aedotron™ P-NM, see Poly(3,4-ethylenedioxythiophene)-block-poly(ethylene
glycol) solution Page 2109 4-{4-[(L-Alanyloxy)methyl]-3-methoxyphenoxy}butyric acid, polymer-
A
Aedotron™ P3-DCB, see Poly(3,4-ethylenedioxythiophene), bis-poly(ethyl- bound to ChemMatrix® resin
eneglycol), lauryl terminated Page 2108
Aedotron™ P3-NM, see Poly(3,4-ethylenedioxythiophene), bis-poly(ethylene- loading ............................................................................................................................................. 0.40-0.65 mmol/g
glycol), lauryl terminated Page 2108 particle size ............................................................................................................... 35-100 mesh (wet sieved)
Aedotron™ C-PC, see Poly(3,4-ethylenedioxythiophene)-block-poly(ethylene
glycol) solution Page 2109 727822-1G glass btl 1g
AEM Q9-6346, see Dimethyloctadecyl[3-(trimethoxysilyl)propyl]ammonium 727822-5G glass btl 5g
chloride Page 1100
2-AEP, see 2-Aminoethylphosphonic acid Page 122 Alane N,N-dimethylethylamine complex solution
Aeroxide® Alu C, see Aluminum oxide Page 83
AET, see 2-(2-Aminoethyl)isothiourea dihydrobromide Page 122 [124330‑23‑0] C2H5N(CH3)2 · AlH3 FW 103.14
 0.5 M in toluene
Agar
density ............................................................................................................................................. 0.837 g/mL, 25 °C
Gum agar; Agar-agar
2578
Danger H225-H250-H261-H304-H314-H336-
[9002‑18‑0] Merck 14,184 (C12H18O9)n H361d-H373-EUH014 P210-P222-P231 + P232-
P261-P280-P422
 ash 2-4.5%
A7002-500G poly btl 500 g L-Alaninamide hydrochloride, 95%
A7002-1KG poly btl 1 kg [33208‑99‑0] Beil. 4,IV,2487 CH3CH(NH2)CONH2·HCl FW 124.57
A7002-5KG poly drum 5 kg mp .............................................................................................................................................................. 212 to 217 °C
Agmatine sulfate salt, ≥97% [α]25
D +11.0°, c = 1 in methanol
1-Amino-4-guanidinobutane sulfate salt; 4-Guanidinobutylamine 459216-1G glass btl 1g

sulfate salt; N-(4-Aminobutyl)guanidine sulfate salt 459216-5G glass btl 5g
[2482‑00‑0] Merck 14,188; Beil. 4,IV,1291 D-Alanine, ≥98% (TLC)
H2N(CH2)4NHC(=NH)NH2·H2SO4 FW 228.27
(R)-2-Aminopropionic acid
mp .............................................................................................................................................................. 234 to 238 °C
[338‑69‑2] Merck 14,204; Beil. 4,IV,2480 CH3CH(NH2)CO2H
 powder FW 89.09
solubility in ethanol .................................................................................................................................... insoluble mp ................................................................................................................................................................ 291 °C (dec.)
color ................................................................................................................................................ white to off-white
15
D-Alanine- N
> AgSn25, see Silver-tin alloy Page 2287
AHA, see Acetohydroxamic acid Page 22 CH3CH(15NH2)CO2H FW 90.09
Aib, see 2-Aminoisobutyric acid Page 133
AIBN, see 2,2′-Azobis(2-methylpropionitrile) Page 215  98 atom % 15
N
AIBN solution, see 2,2′-Azobis(2-methylpropionitrile) solution Page 215 618527 Full product information at Aldrich.com
H-Aib-OBzl, see Benzyl α-aminoisobutyrate hydrochloride Page 249
AIP, see Aluminum isopropoxide Page 81
L-Alanine, ≥98% (TLC)
Air (S)-2-Aminopropionic acid; L-α-Aminopropionic acid O
[56‑41‑7] Merck 14,204 C3H7NO2 FW 89.09 H3C
bp .............................................................................................................................................................................. −189 °C OH
vd ............................................................................................................................................................................... 1 (vs air) NH2
 dry
A7627-1G poly tube 1g
Brass control valve Z146943 or either of brass regulators Z146706 and
Z146714 is recommended.
water ........................................................................................................................................................................ ≤3 ppm
A7627-1KG poly btl 1 kg
4
15
L-Alanine- N
294977-57L steel cyl 57 L
[25713‑23‑9] Beil. 4,III,1212 CH3CH(15NH2)CO2H FW 90.09
> D-Ala(P), see (S)-(+)-1-Aminoethylphosphonic acid Page 122 mp ............................................................................................................................................................. 314.5 °C (dec.)
L-Ala(P), see (R)-(−)-1-Aminoethylphosphonic acid Page 122
β-Ala, see β-Alanine Page 62  98 atom % 15N
[α]25
D +14.5°, c = 2 in 1 M HCl
H-Ala-2-ClTrt resin mol wt 90.07, atom % calculation
 L-Alanine 2-chlorotrityl ester polymer-bound
loading: ~0.8 mmol/g 332127-500MG glass btl 500 mg
particle size ................................................................................................................................................... 75-150 μm
store at: 2-8°C
80929-1G-F poly tube 1g

AHB A, 0613, UNP EU
n Alanine n
DL-Alanine, ≥99% (TLC) 13 15

L-Alanine-2- C, N
(±)-2-Aminopropionic acid [285977‑86‑8] CH313CH(15NH2)CO2H FW 91.08

[302‑72‑7] Merck 14,204; Beil. 4,IV,2481 CH3CH(NH2)COOH mp ............................................................................................................................................................. 314.5 °C (dec.)
FW 89.09
 99 atom % 13C; 98 atom % 15N
mp ................................................................................................................................................................. 289 °C (dec.)
[α]25
D +14.5°, c = 2 in 1 M HCl
A7502-1KG poly btl 1 kg mol wt 91.06, atom % calculation
A7502-5KG poly drum 5 kg 485853-250MG glass btl 250 mg
A 15
DL-Alanine- N DL-Alanine-2-d
[71261‑64‑8] CH3CH(15NH2)CO2H FW 90.09 [31024‑91‑6] CH3CD(NH2)CO2H FW 90.10
 98 atom % 15
N  98 atom % D
299308-1G glass btl 1g 13
L-Alanine-2,3- C2
β-Alanine, 99% 13
CH313CH(NH2)CO2H FW 91.08
β-Ala; 3-Aminopropionic acid
 99 atom % 13
C
[107‑95‑9] Merck 14,205; Beil. 4,IV,2526; Fieser 1,16; 5,6; 6,10; 17,3
NH2CH2CH2COOH FW 89.09 604682 Full product information at Aldrich.com
mp ................................................................................................................................................................. 202 °C (dec.) 13
DL-Alanine-2,3- C2
146064-25G poly btl 25 g [70753‑82‑1] 13
146064-500G poly btl 500 g
 99 atom % 13
C
β-Alanine-15N
15 L-Alanine-2,3,3,3-d4
H2 NCH2CH2CO2H FW 90.09
[18806‑29‑6] Beil. 4,IV,2485 CD3CD(NH2)CO2H FW 93.12
 98 atom % 15
N
mp ............................................................................................................................................................. 314.5 °C (dec.)
 98 atom % D
13
D-Alanine-1- C [α]25
D +14.5°, c = 2 in 1 M HCl
CH3CH(NH2)13CO2H FW 90.09 mol wt 93.04, atom % calculation
mp ................................................................................................................................................................. 291 °C (dec.) 485845-1G glass btl 1g
 99 atom % 13C DL-Alanine-2,3,3,3-d4

[α]25
D -14.5°, c = 2 in 1 M HCl [53795‑92‑9] CD3CD(NH2)CO2H FW 93.12
mp ................................................................................................................................................................ 289 °C (dec.)
 98 atom % D
13
L-Alanine-1- C mol wt 93.04, atom % calculation
[21764‑56‑7] CH3CH(NH2)13CO2H FW 90.09 488917-1G glass btl 1g
[α]25
D +14.5°, c = 2 in 1 M HCl 13
D-Alanine- C3
mp ............................................................................................................................................................. 314.5 °C (dec.)
13
[286460‑72‑8] CH313CH(NH2)13CO2H FW 92.07
 99 atom % 13C
mp ................................................................................................................................................................ 291 °C (dec.)
489867-500MG glass btl 500 mg  99 atom % 13C
[α]25
D -14.5°, c = 2 in 1 M HCl
13
DL-Alanine-1- C mol wt 92.05, atom % calculation
[102029‑81‑2] Beil. 4,III,1230 CH3CH(NH2)13CO2H FW 90.09 492116-100MG glass btl 100 mg
mp ................................................................................................................................................................. 289 °C (dec.) 13
D-Alanine-3- C
 99 atom % 13C [133665‑48‑2] 13
mp ................................................................................................................................................................ 291 °C (dec.)
 99 atom % 13C
L-Alanine-2-d D −14.5°, c = 2 in 1 M HCl
[α]25
[21386‑65‑2] CH3CD(NH2)CO2H FW 90.10 mol wt 90.08, atom % calculation
mp ............................................................................................................................................................. 314.5 °C (dec.) 492124-500MG glass btl 500 mg
 98 atom % D 13
L-Alanine- C3, 95% (CP)
[α]25
D +14.5°, c = 2 in 1 M HCl [100108‑77‑8] 13
CH313CH(NH2)13CO2H FW 92.07
mol wt 90.09, atom % calculation mp ............................................................................................................................................................. 314.5 °C (dec.)
 98 atom % 13C
13
L-Alanine-2- C [α]25
D +14.5, c = 2 in 1 M HCl
[62656‑85‑3] CH313CH(NH2)CO2H FW 90.09 mol wt 92.05, atom % calculation
mp ............................................................................................................................................................. 314.5 °C (dec.) 489875-100MG glass btl 100 mg
 99 atom % 13C
[α]25
D +14.5°, c = 2 in 1 M HCl

AHB A, 0613, UNP EU
n Alaninemethyles n
13
L-Alanine-3- C L-Alanine benzyl ester p-toluenesulfonate salt, ≥95.0% (T)
13
[65163‑25‑9] CH3CH(NH2)CO2H FW 90.09 [42854‑62‑6] Beil. 6,IV,2501 CH3CH(NH2)COOCH2C6H5 ·
mp ............................................................................................................................................................. 314.5 °C (dec.) HOSO2C6H4CH3 FW 351.42
D −5.0±0.5°, c = 3 in methanol
[α]20
 99 atom % 13C
mp .............................................................................................................................................................. 112 to 116 °C
[α]25
D +14.5°, c = 2 in 1 M HCl
mol wt 90.08, atom % calculation 05183-5G glass btl 5g
489948-500MG glass btl 500 mg > 13 13
L-Alanine-1- C,N-t-Boc derivative, see Boc-Ala-OH-1- C Page 369
A
13 13
L-Alanine- C3,N-t-Boc derivative, see Boc-Ala-OH- C3 Page 369
13 15
L-Alanine- C3, N
[312623‑85‑1] 13
CH313CH(15NH2)13CO2H FW 93.06 D-Alanine tert-butyl ester hydrochloride, ≥99.0% (AT)
mp ............................................................................................................................................................. 314.5 °C (dec.) [59531‑86‑1] CH3CH(NH2)COOC(CH3)3 · HCl FW 181.66
 98 atom % 13C; 98 atom % 15N D −1.4±0.3°, c = 2 in ethanol
[α]20
[α]25
D +14.5°, c = 2 in 1 M HCl
mol wt 92.99, atom % calculation L-Alanine tert-butyl ester hydrochloride, ≥99.0% (AT)
[13404‑22‑3] CH3CH(NH2)COOC(CH3)3 · HCl FW 181.66
13
DL-Alanine- C3 [α]20
D +1.4±0.2°, c = 2 in ethanol
13 store at: 2-8°C
[144476‑54‑0] CH313CH(NH2)13CO2H FW 92.07
 99 atom % C 13
mol wt 92.05, atom % calculation > DL-Alanine tert-butyl ester isocyanide, see tert-Butyl 2-isocyanopropionate
Page 577
485543-500MG glass btl 500 mg L-Alanine 2-chlorotrityl ester polymer-bound, see H-Ala-2-ClTrt resin
13 Page 61
DL-Alanine-3- C
13 L-Alanine ethyl ester hydrochloride, 99%
[131157‑42‑1] CH3CH(NH2)CO2H FW 90.09
 99 atom % 13
C [1115‑59‑9] Beil. 4,382; 4,IV,2485 CH3CH(NH2)COOC2H5 · HCl
FW 153.61
mp ..................................................................................................................................................... 78 to 80 °C (dec.)
β-Alanine-13C3,15N [α]22
D +2.5°, c = 2.5 in H2O
3-Aminopropionic acid-13C3,15N 855669-5G glass btl 5g
[285978‑07‑6] H215N13CH213CH213CO2H FW 93.06 855669-25G poly btl 25 g
mp ................................................................................................................................................................. 205 °C (dec.)
DL-Alanine ethyl ester hydrochloride, ≥99.0% (AT)
 99 atom % 13C; 98 atom % 15N [617‑27‑6] CH3CH(NH2)COOC2H5 · HCl FW 153.61
mol wt 93.02, atom % calculation mp ................................................................................................................................................................... 85 to 87 °C
13
L-Alanine-3- C,2,3,3-d3, 98% (CP) 8 05180-25G poly btl 25 g
13
CD2HCD(NH2)CO2H FW 93.10 β-Alanine ethyl ester hydrochloride, 98%
mp ............................................................................................................................................................. 314.5 °C (dec.) Ethyl 3-aminopropionate hydrochloride
 98 atom % 13C; 97 atom % D [4244‑84‑2] Beil. 4,IV,2528 NH2CH2CH2COOCH2CH3 · HCl
mol wt 92.99, atom % calculation FW 153.61
710512 mp ................................................................................................................................................................... 67 to 70 °C
L-Alanine-3,3,3-d3
[63546‑27‑0] CD3CH(NH2)CO2H FW 92.11
mp ............................................................................................................................................................. 314.5 °C (dec.) D-Alanine methyl ester hydrochloride, 98%
[14316‑06‑4] Beil. 4,IV,2485 CH3CH(NH2)CO2CH3·HCl FW 139.58
 99 atom % D
[α]25 mp .............................................................................................................................................................. 108 to 110 °C
D +14.5°, c = 2 in 1 M HCl
mol wt 92.09, atom % calculation D −8.0°, c = 1.6 in methanol
[α]20
DL-Alanine-3,3,3-d3
L-Alanine methyl ester hydrochloride, 99%
[53795‑94‑1] CD3CH(NH2)CO2H FW 92.11
mp ................................................................................................................................................................. 289 °C (dec.) [2491‑20‑5] Beil. 4,IV,2485 CH3CH(NH2)COOCH3 · HCl FW 139.58
mp .............................................................................................................................................................. 109 to 111 °C
 99 atom % D [α]25
D +7.0°, c = 1.6 in methanol
Alanine anhydride, 99% 330639-100G glass btl 100 g
3,6-Dimethyl-2,5-piperazinedione H β-Alanine methyl ester hydrochloride, ≥98.0% (AT)
[5625‑46‑7] Beil. 24,297 C6H10N2O2 FW 142.16 H3C N O
Methyl 3-aminopropionate hydrochloride
O N CH3 [3196‑73‑4] Beil. 4,IV,2527 NH2CH2CH2COOCH3 · HCl FW 139.58
H
mp .............................................................................................................................................................. 103 to 105 °C
mixture of DL and meso store at: 2-8°C

AHB A, 0613, UNP EU
n Alaninol n
> D-Alaninol, see (R)-(−)-2-Amino-1-propanol Page 160
L-Alaninol, see (S)-(+)-2-Amino-1-propanol Page 160  99 atom % 13C; 98 atom % D
DL-Alaninol, 98%
6
Danger H300-H310-H330 P260-P264-P280-P284-P301 + P310-P302 +
(±)-2-Amino-1-propanol P350
[6168‑72‑5] Beil. 4,IV,1614 CH3CH(NH2)CH2OH FW 75.11 733873-1MG 1 mg
bp ............................................................... 173-176 °C n20
D .......................................................................... 1.450 733873-5MG 5 mg
density ..................................... 0.943 g/mL, 25 °C 733873-10MG 10 mg
A [α]D +1.0 to −1.0° 733873-25MG 25 mg
5
Danger H314 P280-P305 + P351 + P338-P310
Aldicarb (N-methyl-13Cd3,carbamoyl-13C) sulfoxide, 8
98% (CP)
O H3 C CH3
D313C 13C N CH3
> β-Alanyl-L-histidine, see L-Carnosine Page 627 N O S
4-{4-[(L-Alanyloxy)methyl]-3-methoxyphenoxy}butyric acid, polymer- H
bound to ChemMatrix® resin, see H-Ala-HMPB-ChemMatrix® resin O
Page 61
L-Alanyl-L-tryptophan, see Ala-Trp Page 64 13
C2C5D3H11N2O3S FW 211.27
N3-Ala-OH CHA salt, see (S)-2-Azido-propionic acid cyclohexylammonium salt
Page 213 store at: 2-8°C
 99 atom % 13C; 98 atom % D
Ala-Trp, ≥99.0% (TLC) mol wt 211.19, atom % calculation
L-Alanyl-L-tryptophan
6
CH3 O Danger H300 P264-P301 + P310
H
[16305‑75‑2] Beil. 22,IV,6801 C14H17N3O3 N
H2N OH
FW 275.30 O 733881-1MG 1 mg
733881-5MG 5 mg
N
H 733881-10MG 10 mg
733881-25MG 25 mg
[α]20
D +15.5±0.5°, c = 2.7 in H2O
05400-250MG glass btl 250 mg > 18-Aldocorticosterone-2,2,4,6,6,21,21-d7, see Aldosterone-2,2,4,6,6,21,21-d7
Page 65
05400-1G 1g
> ALC, see O-Acetyl-L-carnitine hydrochloride Page 36 Aldolase Antibody 38C2, murine catalytic monoclonal antibody
ALCAR, see O-Acetyl-L-carnitine hydrochloride Page 36
 average Mw ~150,000, powder (Lyophilized)
Alcian Blue, pyridine variant Catayzes antibody for aldol reactions; first antibody to be commer-
[123439‑83‑8] C56H40Cl4CuN12 FW 1086.36 cially available for organic synthesis applications.
chunks
λmax ............................................................................................................................................................................. 616 nm
335630-25G glass btl 25 g  average Mw ~150,000, powder (Lyophilized, contains pbs)
Biocatalyst for aldol condensations, especially for the si-facial addition
> Alcohol C9, see 1-Nonanol Page 1936
Alcohol C10, see 1-Decanol Page 838
of aliphatic ketones to aldehydes. Antibody 38C2 catalyzes aldol,
Alcohol C11, see 1-Undecanol Page 2591 crossed aldol, retro aldol, decarboxylation of β-keto acids, self aldol,
Alcohol C12, see 1-Dodecanol Page 1171 and Robinson annulations. The biocatalyst can accept a variety of
Aldehyde C7, see Heptaldehyde Page 1415 substrates with different physico-chemical properties.1,2,3,4,5,6
Aldehyde C12, see Dodecyl aldehyde Page 1172
Aldehyde C14, see Undecanoic γ-lactone Page 2591 Components
Aldehyde resin, see (4-Formyl-3-methoxyphenoxymethyl)polystyrene
Page 1365 10 mg
StratoSpheres™ PL-FMP resin Page 1365 5-6.5mg
Aldicarb (N-methyl-13C,d3carbamoyl-13C), 98% (CP) antibody 10mg
8
phosphate buffer salts 5-6.5mg
O H3C CH3 Lit. cited: 1. J. Am. Chem. Soc. 119, 8131 (1997)
2. J. Am. Chem. Soc. 118, 11720 (1996)
D313C 13C N
N O SCH3
3. Science 252, 659 (1991)
H 4. Acc. Chem. Res. 26, 391 (1993)
13 5. Science 270, 1797 (1995)
C2C5D3H11N2O2S FW 195.27
6. Science 270, 1775 (1995)
 99 atom % 13C; 98 atom % D 479950-10MG glass btl 10 mg
Aldolase Antibody 84G3, murine catalytic monoclonal antibody
69
Danger H300-H311-H330-H410 P260-P264-P273-P280-P284-
P301 + P310 Novel biocatalyst for aldol condensation, especially for the re-facial
733865-1MG 1 mg addition of aliphatic ketones to aldehydes. Antibody 84G3 catalyzes
733865-5MG 5 mg aldol, crossed aldol, retroaldol, decarboxylation of β-keto acids, self
733865-10MG 10 mg aldol, and Robinson annulations.1,2
Lit. cited: 1. Angew. Chem. Int. Ed. Engl. 38, 3738-3741 (1999)
733865-25MG 25 mg
2. Org. Lett. 1, 1623-1626 (1999)
Aldicarb (N-methyl-13C,d3carbamoyl-13C) sulfone, 98% 8 527858-10MG glass btl 10 mg
(CP)
O H3 C O
H3C
D313C 13C N S CH3
N O
H O
13
C2C5D3H11N2O4S FW 227.27
mp .............................................................................................................................................................. 132 to 135 °C

AHB A, 0613, UNP EU
n Alizarinfluorin n
Aldosterone-2,2,4,6,6,21,21-d7 , 98% (CP) 8 Algal fatty acid mixture-13C

11β,21-Dihyroxy-3,20-dioxo-4-pregnen-  99 atom % 13
C
O H O
18-al-d7(2,2,4,6,6,21,21-d7); 11β,21-Dihyr- HO OH
oxypregn-4-ene-3,18,20-trione-d7 D H3C H R D D
(2,2,4,6,6,21,21-d7); 18-Aldocortico- D
H H
Alginic acid from brown algae
R = H or D
sterone-2,2,4,6,6,21,21-d7; Reichstein X O Mixed polymer of mannuronic and guluronic acid; Alginic acid from
(2,2,4,6,6,21,21-d7) D D D
Macrocystis pyrifera (kelp)
A
C21D7H21O5 FW 367.49 [9005‑32‑7] Merck 14,242 (C6H8O6)n
 (variable deuteration on C17); 98 atom % D (based on d7) A straight-chain, hydrophilic, colloidal, polyuronic acid composed
mol wt 366.38, atom % calculation primarily of anhydro-β-D-mannuronic acid residues with 1→4 linkage.
706035-1MG 1 mg solubility in H2O ................................................................................................................. insoluble, but swells
706035-2MG 2 mg soluble in ................................................................................................................................................ aqueous base
706035-5MG 5 mg A7003-100G poly btl 100 g

Aldrich® Negative Photoresist Kit I
Components A7003-1KG poly btl 1 kg
Negative resist remover I (Aldrich 651761) 250 mL Alginic acid sodium salt
Negative resist developer I (Aldrich 651788) 250 mL
Negative photoresist I (Aldrich 651796) 100 mL Algin; Sodium alginate
Negative resist thinner I (Aldrich 651974) 100 mL [9005‑38‑3] Merck 14,241
654892  powder
viscosity 15-20 cP, 1% in H2O(lit.)
Aldrithiol™-2, 98%
180947-100G poly btl 100 g
2,2′-Dithiodipyridine; 2,2′-Dipyridyl disulfide 180947-250G poly btl 250 g
[2127‑03‑9] Beil. 21,V,2,48; Fieser 6,246; 5,285 S N
N S 180947-500G poly btl 500 g
C10H8N2S2 FW 220.31
> Aliquat™ 128, see Tricaprylylmethylammonium chloride Page 2472
mp .................................................................................................................................................................... 56 to 58 °C Aliquat™ 336
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Tricaprylylmethylammonium chloride; Trioctylmethylammonium
chloride
[63393‑96‑4] Fieser 7,380; 5,460; 6,404 CH3N[(CH2)7CH3]3Cl
143049-5G glass btl 5g FW 404.16
143049-25G glass btl 25 g density ............................................................................................................................................. 0.884 g/mL, 25 °C
143049-500G glass btl 500 g n20
D ................................................................................................................................................................................... 1.4665
569
Aldrithiol™-4, 98% Danger H301-H315-H318-H410 P273-P280-P301 +
P310-P305 + P351 + P338-P501
4,4′-Dithiodipyridine; 4,4′-Dipyridyl disulfide
[2645‑22‑9] Beil. 21,II,35 C10H8N2S2 FW 220.31
mp .................................................................................................................................................................... 76 to 78 °C
Thiol reagent.1,2 Used to modify gold surfaces for protein studies.3
Lit. cited: 1. Aldrichimica Acta 4, 33 (1971) Aliquat™ HTA-1
2. Anal. Biochem. 363, 77 (2007)
3. J. Vac. Sci. Technol. B 12, 1486, 1494 (1994) [1166837‑27‑9]
density ............................................................................................................................................. 1.055 g/mL, 20 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
 High-Temperature Phase Transfer Catalyst, 30-35% in H2O
143057-1G glass btl 1g Virtually all quaternary ammonium based PTC catalysts decompose
143057-5G glass btl 5g below 100 °C and/or in the presence of caustics. Aliquat™ HTA-1 has
143057-25G glass btl 25 g been found to be stable at temperatures well above 100 °C
pH ........................................................................................................................................................................................... 6-9
> Al2O3 Etch, see Ceramic Etchant A Page 633
7
Warning H315-H319 P305 + P351 + P338
Aleuritic acid, ≥90% (T)
44506-50ML-F poly btl 50 mL
OH O 44506-250ML-F poly btl 250 mL
HO
OH
OH Alizarin
1,2-Dihydroxyanthraquinone; Mordant Red 11
DL-threo-9,10,16-Trihydroxypalmitic acid [72‑48‑0] Merck 14,251; Beil. 8,IV,3256 C14H8O4 FW 240.21
[533‑87‑9] Merck 14,231; Beil. 3,III,901 C16H32O5 FW 304.42 mp .............................................................................................................................................................. 279 to 283 °C
mp .............................................................................................................................................................. 100 to 101 °C
 technical Biological stain
An abundant source of prostanoid synthons1 λmax .............................................................................................................................................................. 567 nm (2nd)
mp .................................................................................................................................................................... 90 to 97 °C λmax ............................................................................................................................................................................ 609 nm
Lit. cited: 1. J.M. Reuter, R.G.Salomon, J. Org. Chem. 43, 4247 (1978) visual transition interval ......................................................................... 5.5 - 6.8, yellow to red (acid)
05540-25G poly btl 25 g visual transition interval ............................................................. 10.1 - 12.1, red to violet (alkaline)
7
Warning H302-H319 P305 + P351 + P338
122777-100G glass btl 100 g

122777-500G glass btl 500 g
> Alizarin Fluorine Blue, see Alizarin-3-methyliminodiacetic acid Page 66

AHB A, 0613, UNP EU
n Alizarinmethyli n
Alizarin-3-methyliminodiacetic acid Allenylboronic acid pinacol ester, 97%

Alizarin Fluorine Blue; 3,4-Dihydroxyanthraquinon-2-yl-methylimino- 2-Allenyl-4,4,5,5-tetramethyl(1,3,2)-dioxaborolane H
diacetic acid; Alizarin Complexone C9H15BO2 FW 166.03 H3C O
B C
[3952‑78‑1] Beil. 14,IV,931 C19H15NO8 FW 385.32 H3 C
O
CH2
H3 C CH3
density .......................................................................................................................................... 0.9237 g/mL, 25 °C
n20
D ...................................................................................................................................................................................... 1.459
A Alizarin Red S 678554-1G glass btl 1g

Alizarin sulfonate sodium; 3,4-Dihydroxy-9,10-dioxo-2-anthracene- 678554-5G glass btl 5g
sulfonic acid sodium salt; Alizarin Red, water soluble; Alizarin Carmine; > 2-Allenyl-4,4,5,5-tetramethyl(1,3,2)-dioxaborolane, see Allenylboronic acid
Alizarin sodium monosulfonate; Alizarinsulfonic acid sodium salt; pinacol ester Page 66
Sodium alizarinsulfonate
[130‑22‑3] Merck 14,8573; Beil. 11,IV,683 C14H7NaO7S FW 342.26 Allenyltributyltin(IV), 80%
 certified by the Biological Stain Commission [53915‑69‑8] [CH3(CH2)3]3SnCH=C=CH2 FW 329.11
bp ......................................................................... 265 °C n20
D ................................................................................ 1.5
Certified for use in Dahl′s method for calcium
density ..................................... 1.107 g/mL, 25 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
 technical grade
689
Danger H301-H312-H315-H319-H372-H410 P273-
P280-P301 + P310-P305 + P351 + P338-P314-P501
> Alizarin Yellow R, see Mordant Orange 1 Page 1873
Alizarin Yellow GG
(−)-Alloaromadendrene, ≥98.0% (GC, sum of enantiomers)
5-(3-Nitrophenylazo)salicylic acid sodium salt; Mordant Yellow 1;
Metachrome Yellow; Alizarin Yellow 2G (−)-allo-Aromadendrene H3C
[25246‑27‑9] Beil. 5,IV,1187 C15H24 FW 204.35 H3C HH CH3
[584‑42‑9] Merck 14,5919; Beil. 16,III,238 C13H8N3NaO5 FW 309.21
H
λmax ............................................................................................................................................................................. 362 nm H
H2C
bp ....................................................................................................................................................................... 265-267 °C
> p-Alkoxy-benzyl alcohol polymer-bound, see Wang resin Page 2609
p-Alkoxybenzyl alcohol resin, see Wang resin Page 2609 density ............................................................................................................................................. 0.923 g/mL, 20 °C
Alkylbenzyldimethylammonium chloride, see Benzalkonium chloride D −33±1°, neat
[α]20
solution Page 225 n20
D ...................................................................................................................................................................................... 1.501
store at: 2-8°C
Allantoin, ≥98.0% (N)
5-Ureidohydantoin; Glyoxylic(acid) diureide O
[97‑59‑6] Merck 14,258; Beil. 25,IV,4071 C4H6N4O3 O NH > (Alloc)2O, see Diallyl pyrocarbonate Page 858
FW 158.12 H 2N N O N-Alloc-1,2-diaminoethane hydrochloride, see N-Alloc-ethylenediamine
N
H H hydrochloride Page 66
Purine metabolite via the uric acid pathway. Uric acid also reacts with N-Alloc-ethylenediamine hydrochloride, ≥98.0% (AT)
free radicals to produce allantoin, thus allantoin may be a useful N-Alloc-1,2-diaminoethane hydrochloride; O
biomarker for oxidative stress. Allyl-N-(2-aminoethyl)carbamate hydro- H2C NH2
O N
mp ................................................................................................................................................................. 230 °C (dec.) chloride H
• HCl
ign. residue ............................................................................................................................................................. ≤0.2% C6H12N2O2 · HCl FW 180.63
7
Warning H302 51036-1G-F poly tube 1g
51036-5G-F 5g
05670-25G poly btl 25 g
> Nγ-Alloc-Nα-Fmoc-L-2,4-diaminobutyric acid, see Fmoc-Dab(Alloc)-OH
05670-100G poly btl 100 g Page 1343
Nβ-Alloc-Nα-Fmoc-L-2,3-diaminopropionic acid, see Fmoc-Dap(Alloc)-OH
Allene, 97% Page 1344
Propadiene Nε-Alloc-Nα-Fmoc-D-lysine, see Fmoc-D-Lys(Alloc)-OH Page 1349
Nδ-Alloc-L-lysine, see H-Lys(Alloc)-OH Page 1637
[463‑49‑0] Beil. 1,IV,966; Fieser 1,18 H2C=C=CH2 FW 40.06 Alloc-OBt, polymer-bound, see Alloc protecting group introducing reagent,
mp .................................................................... −136 °C vd ............................................. 1.42 (20 °C, vs air) polymer-bound Page 66
bp ......................................................................... −34 °C vp ........................................ 6795 mmHg (21 °C) 1-(Alloc-oxy)benzotriazole-6-carboxamidomethyl-polystyrene, see Alloc
protecting group introducing reagent, polymer-bound Page 66
contains 100 ppm Monomethyl ether hydroquinone as inhibitor
Stainless steel control valves Z146951, Z187224 or either of stainless Alloc protecting group introducing reagent, polymer-bound
steel regulators Z148504 and Z148512 and a "T"-purge valve Z151661
1-(Alloc-oxy)benzotriazole-6- N
is recommended. H N O
carboxamidomethyl-polystyrene; N N CH2
4
Warning H280 P410 + P403 Benzotriazol-1-yl allyl carbonate, O O
O
polymer-bound; Alloc-OBt,
294985-170G ss cyl 170 g polymer-bound
 loading: ~1.0 mmol/g
Polymer-bound reagent for introducing the Alloc protecting group1
matrix .......................................................................................................................... crosslinked with 2% DVB
particle size ........................................................................................................................................... 200-400 mesh
Lit. cited: 1. K. Dendrinos et al., J. Chem. Soc. Perkin Trans. I 1463 (1998)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
store at: 2-8°C

AHB A, 0613, UNP EU
n Allylamine n
> see DL-allo-Isoleucine Page 1574
DL-Alloisoleucine, (R)-(+)-α-Allylalanine, ≥98.0% (HPLC)
Alloocimene, see 2,6-Dimethyl-2,4,6-octatriene Page 1100
(R)-2-Amino-2-methyl-4-pentenoic acid O
D-Allose, 98% [96886‑56‑5] C6H11NO2 FW 129.16 H2C
OH
All; β-D-Allopyranose; β-D-Allose HO
H3C NH2
[2595‑97‑3] Merck 14,280; Beil. 1,IV,4299 C6H12O6

FW 180.16
O
OH
ee (HPLC): ≥98.0%
water .............................................................................................................................................................................. ≤15%
HO OH OH
7 A
Warning H315-H319-H335 P261-P305 + P351 + P338
store at: 2-8°C
mp .............................................................................................................................................................. 148 to 150 °C
[α]19
D +15°, c = 3.8 in H2O
285005-250MG glass btl 250 mg (S)-(−)-α-Allylalanine, ≥98.0% (HPLC)
Alloxan monohydrate [96886‑55‑4] C6H11NO2 FW 129.16
7
2,4,5,6(1H,3H)-Pyrimidinetetrone; 2,4,5,6-Tetraoxy- Warning H315-H319-H335 P261-P305 + P351 + P338
O
store at: 2-8°C
pyrimidine; 5,6-Dioxyuracil HN
O
• H2O 691011-100MG glass btl 100 mg
[2244‑11‑3] Merck 14,282; Beil. 24,500 C4H2N2O4 ·
O N O
H2O FW 160.08 H 691011-500MG glass btl 500 mg
mp ................................................................................................................................................................. 255 °C (dec.) Allyl alcohol

solubility in H2O ................................................................................................................. may be hazy yellow 2-Propen-1-ol
[107‑18‑6] Merck 14,286; Beil. 1,IV,2079 CH2=CHCH2OH FW 58.08
7
Warning H302-H312-H332 P280 store at: 2-8°C
mp .................................................................... −129 °C vd ................................................................... 2 (vs air)
bp ..................................................................... 96-98 °C vp ......................................... 23.8 mmHg (25 °C)
A7413-25G glass btl 25 g n20
D .............................................................................. 1.412
269
Alloxazine, 96% Danger H225-H301-H311-H315-H319-H331-H335-H400
P210-P261-P273-P280-P301 + P310-P305 + P351 + P338
Benzo[g]pteridine-2,4(1H,3H)-dione; Isoalloxazine O
[490‑59‑5] Beil. 26,498 C10H6N4O2 FW 214.18 N  ≥99%
NH
N N O
H 240532-100ML Sure/Seal™ 100 mL
A28651-5G glass btl 5g  ≥98.5%
A product of Lyondell Chemical Company
Allyl acetate, 99%
[591‑87‑7] Merck 14,285; Beil. 2,IV,180 CH3COOCH2CH=CH2
FW 100.12  ≥98.5%
bp ............................................................... 103-104 °C n20
D .......................................................................... 1.404 A product of Lyondell Chemical Company
density ..................................... 0.928 g/mL, 25 °C ait ......................................................................... 705 °F 459798
26
Danger H225-H301-H312-H319-H330 P210-P260-P280-P284-
P305 + P351 + P338-P310 Allylamine
185248-100ML glass btl 100 mL 2-Propen-1-ylamine; 3-Amino-1-propene
185248-500ML glass btl 500 mL [107‑11‑9] Merck 14,287; Beil. 4,IV,1057 CH2=CHCH2NH2 FW 57.09
mp ....................................................................... −88 °C n20 D .......................................................................... 1.420
> Allylacetic acid, see 4-Pentenoic acid Page 1997 bp ............................................................................ 53 °C vd ................................................................... 2 (vs air)
Allylacetic acid methyl ester, see Methyl 4-pentenoate Page 1820 density ..................................... 0.761 g/mL, 25 °C vp .................................................... 4.09 psi (20 °C)
269
Allyl acetoacetate Danger H225-H301-H310-H331-H411 P210-P261-
P273-P280-P301 + P310-P302 + P350
[1118‑84‑9] Beil. 3,IV,1538 CH3COCH2COOCH2CH=CH2 FW 142.15
bp .................................. 194-195 °C/737 mmHg n20 D .......................................................................... 1.439
 ≥99%
density ..................................... 1.037 g/mL, 25 °C 241075-50ML glass btl 50 mL
6
P338-P312
 98%
Used in a direct monocarboxymethylation reaction.1
 AC-allyl Lit. cited: 1. Synlett 1573 (2007)
Wacker quality, ≥98.5% (GC) 145831-250ML Sure/Seal™ 250 mL
product of Wacker Chemie AG 145831-1L Sure/Seal™ 1L
prices for bulk quantities on request
10893-1KG glass btl 1 kg Allyl-13C3-amine-15N, 98% (CP) 8
10893-25KG 25 kg 2-Propen-13C3-1-ylamine-15N; 3-Amino-15N-1-propene-13C3
H213C=13CH13CH215NH2 FW 61.07
 98%
bp .................................................................................................................................................................................... 53 °C
254959-100G glass btl 100 g
254959-500G glass btl 500 g  99 atom % 13C; 98 atom % 15N
> Allylacetone, see 5-Hexen-2-one Page 1442 density ............................................................................................................................................. 0.813 g/mL, 25 °C
26
Danger H225-H301-H311-H331 P210-P261-P280-P301 +
P310-P311
706698

AHB A, 0613, UNP EU
n Allylaminehydro n
13 15
Allyl- C3-amine- N hydrochloride, 98% (CP) 8 O-Allyl-N-benzylcinchonidinium bromide
3-Aminopropene-13C3,15N hydrochloride [158195‑40‑5] C29H33BrN2O FW 505.49
H 2C
13
CH213CH13CH215NH2·HCl FW 97.53
N Br
mp ................................................................................................................................................................................ 106 °C
O
 99 atom % 13C; 98 atom % 15N
mol wt 97.48, atom % calculation N
CH2
A 6
Danger H301 P301 + P310
mp ............................................................................................................................................... 140 to 144 °C (dec.)
707287 D −158°, c = 1 in chloroform
[α]20
> Allyl-N-(2-aminoethyl)carbamate hydrochloride, see N-Alloc-ethylenedi- Contains varying amounts of O-allyl-N-benzylcinchonidinium chloride
7
amine hydrochloride Page 66 Warning H315-H319-H335 P261-P305 + P351 + P338
N-Allylaniline, 95% 514276-1G glass btl 1g

[589‑09‑3] Beil. 12,170 C6H5NHCH2CH=CH2 FW 133.19
bp ............................................................... 218-220 °C n20 .......................................................................... 1.563
Allyl benzyl ether, 99%
D
density ..................................... 0.982 g/mL, 25 °C [14593‑43‑2] Beil. 6,III,1459 C6H5CH2OCH2CH=CH2 FW 148.20
bp ............................................................... 204-205 °C n20
D .......................................................................... 1.507
7
+ P338 density ..................................... 0.959 g/mL, 25 °C
A29003-5G glass btl 5g 428418-10ML glass btl 10 mL
2-Allylanisole, 96% 8 (S,S)-2-Allyl-1,3-bis-(4-bromobenzyl)-2-chloroocta- 8

hydro-2-1H-1,3,2-benzodiazasilole, 95%
1-Allyl-2-methoxybenzene CH2
[3698‑28‑0] C10H12O FW 148.20 (S,S)-1,3-Bis-[(4-bromophenyl)methyl]-2-chloroocta- Br
OCH3 hydro-2-(2-propenyl)-1H-1,3,2-benzodiazasilole
C23H27Br2ClN2Si FW 554.82
density ............................................................................................................................................. 0.962 g/mL, 25 °C N CH2
Si
7
Warning H302 N Cl
706760-5G glass btl 5g Br
4-Allylanisole, 98% mp ................................................................................................................................................................... 94 to 99 °C

Chavicol methyl ether; Estragole [α]22
[140‑67‑0] Merck 14,3705; Beil. 6,IV,3810 H2C=CHCH2C6H4OCH3 U.S. Patent No. 7,534,905
7
FW 148.20 Warning H302
bp ............................................................... 215-216 °C n20
D .......................................................................... 1.521
density ..................................... 0.965 g/mL, 25 °C 705098-1G glass btl 1g
7
Warning H302-H315 705098-5G glass btl 5g
> (3aR,7aR)-2-Allyl-1,3-bis(4-bromobenzyl)-2-chlorooctahydro-1H-benzo[d]
A29208-25G glass btl 25 g [1,3,2]diazasilole, see (R,R)-1,3-Bis[(4-bromophenyl)methyl]-2-chloroocta-
A29208-100G glass btl 100 g hydro-2-allyl-1H-1,3,2-benzodiazasilole Page 300
O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide, 90% Allyl[1,3-bis(2,6-diisopropylphenyl)-2-imidazolidinyl- 8

idene]chloropalladium(II), 97%
[200132‑54‑3] C37H37BrN2O H2C H Allylchloro-[1,3-bis-(2,6-diisopropylphenyl)-2- i-Pr i-Pr
FW 605.61
H2 C H
imidazolidinylidene]palladium(II); (SIPr)Pd(allyl)Cl; N N
O N Br CX 23 i-Pr i-Pr
H [478980‑01‑7] C30H43ClN2Pd FW 573.55 Pd
Cl
N
mp .............................................................................................................................................................. 206 to 210 °C
Sold in cooperation with Umicore for research purposes only. US
mp ................................................................................................................................................................. 170 °C (dec.)
Patent 6,316,380 and foreign equivalents apply.
D −345±30°, c = 0.45 in chloroform
[α]20
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338

Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloro-
Allylbenzene, 98% palladium(II), 98%
3-Phenyl-1-propene Allylchloro[1,3-bis(2,6-diisopropylphenyl) i-Pr i-Pr
[300‑57‑2] Beil. 5,IV,1362 C6H5CH2CH=CH2 FW 118.18 imidazol-2-ylidene]palladium(II), CX 21
bp ............................................................... 156-157 °C n20
D .......................................................................... 1.511 N N
[478980‑03‑9] C30H42ClN2Pd FW 572.54
density ..................................... 0.892 g/mL, 25 °C
i-Pr Pd i-Pr
Cl
28
Danger H226-H304 P301 + P310-P331
A29402-25ML glass btl 25 mL mp ............................................................................................................................................................................ >300 °C

A29402-100ML glass btl 100 mL Sold in cooperation with Umicore for research purposes only. US
Patent US 6,316,380; EP 721 953, and foreign equivalents apply
7
Warning H315-H319-H335 P261-P305 + P351 + P338


AHB A, 0613, UNP EU
n Allylchlorodime n
Allyl[1,3-bis(mesityl)imidazol-2-ylidene]chloropalladium(II), > o-Allylbromobenzene, see 1-Allyl-2-bromobenzene Page 69

97% 1-Allyl-2-bromobenzene, 97% 8
CX 22 CH3 H3C
2-Allylbromobenzene; 2-Allylphenyl bromide; 2- CH2
[478980‑04‑0] C24H29ClN2Pd
H3C N N CH3 Bromo-1-allylbenzene; o-Allylbromobenzene
FW 487.37
[42918‑20‑7] C9H9Br FW 197.07 Br
CH3 Pd H3C
Cl
density ............................................................................................................................................. 1.311 g/mL, 25 °C
n20
D ...................................................................................................................................................................................... 1.559
mp ............................................................................................................................................... 228 to 232 °C (dec.)
Sold in cooperation with Umicore for research purposes only. 7
Warning H302-H319 P305 + P351 + P338 A
7
Warning H315-H319-H335 P261-P305 + P351 + P338 730408-1G glass btl 1g
> 2-Allylbromobenzene, see 1-Allyl-2-bromobenzene Page 69

663042-1G glass btl 1g Allyl 2-bromo-2-methylpropionate, 98%
N-Allyl-N,N-bis(trimethylsilyl)amine, 97% [40630‑82‑8] BrC(CH3)2CO2CH2CH=CH2 FW 207.07
bp .......................................... 50-51 °C/12 mmHg n20
D .......................................................................... 1.462
[7688‑51‑9] CH2=CHCH2NH[Si(CH3)3]2 FW 201.46 density ..................................... 1.302 g/mL, 25 °C
liquid
7
bp .................................................. 72 °C/15 mmHg n20 Warning H315-H319-H335 P261-P305 + P351 + P338
D .......................................................................... 1.440
density ..................................... 0.816 g/mL, 25 °C
27
Allyl butyl ether, 98%
[3739‑64‑8] Beil. 1,IV,2084 CH2=CHCH2OCH2CH2CH2CH3
> 2-Allyl-1-Boc-2-pyrrolidinecarboxylic acid, see Boc-α-allyl-DL-Pro-OH FW 114.19
Page 369 density ............................................................................................................................................. 0.783 g/mL, 25 °C
(S)-2-Allyl-1-Boc-2-pyrrolidinecarboxylic acid, see Boc-(S)-α-allyl-Pro-OH
Page 369 n20
D ...................................................................................................................................................................................... 1.406
27
Danger H225-H315-H319-H335 P210-P261-P305 + P351 +
Allylboronic acid MIDA ester P338
2-Allyl-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione 362603-25G glass btl 25 g
H3 C
C8H12BNO4 FW 197.00 N
> Allylcarbinol, see 3-Buten-1-ol Page 549
B O O
H2 C O O
Allyl chloride
May contain up to 10 wt. % dimethyl sulfoxide. 3-Chloro-1-propene; Chlorallylene
698709-1G glass btl 1g [107‑05‑1] Merck 14,289; Beil. 1,IV,738 CH2=CHCH2Cl FW 76.52
mp .................................................................... −130 °C vd ............................................................... 2.6 (vs air)
Allylboronic acid pinacol ester, 97% bp ..................................................................... 44-46 °C vp .................................................... 5.71 psi (20 °C)
density ..................................... 0.939 g/mL, 25 °C vp ................................................. 20.58 psi (55 °C)
2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; Pinacol allylboronate
n20
D .............................................................................. 1.414
[72824‑04‑5] ((CH3)4C2O2)BCH2CH=CH2 FW 168.04
2789
bp ............................................. 50-53 °C/5 mmHg n20
D ....................................................................... 1.4268
Danger H225-H302-H312-H315-H319-H332-
density ..................................... 0.896 g/mL, 25 °C H335-H341-H351-H373-H400
Allylboronation reagent for the preparation of allylic alcohols,1 and  ReagentPlus®, 99%
homoallylic amines.2 P210-P261-P273-P281-P305 + P351 + P338
Lit. cited: 1. Organometallics 2, 230 (1983) 236306-5ML glass btl 5 mL
2. Org. Synth. 83, 170 (2006) 236306-100ML glass btl 100 mL
27
 reagent grade, 98%
324647-1G glass btl 1g P210-P261-P273-P280-P305 + P351 + P338
324647-10G glass btl 10 g A30702-500ML glass btl 500 mL
A30702-1L glass btl 1L
Allyl bromide
A30702-4X1L 4×1L
3-Bromo-1-propene A30702-2L glass btl 2L
[106‑95‑6] Merck 14,288; Beil. 1,IV,754 CH2=CHCH2Br FW 120.98 A30702-2.5L 2.5 L
mp .................................................................... −119 °C n20D .......................................................................... 1.469
bp ..................................................................... 70-71 °C vd ................................................................ 4.2 (vs air) 98.0% (returnable containers)
density ..................................... 1.398 g/mL, 25 °C ait ......................................................................... 554 °F P210-P261-P273-P280-P305 + P351 + P338
25689
Danger H225-H301-H314-H340-H350- 481378
H400 P201-P210-P273-P280-P301 +
P310-P305 + P351 + P338 Allyl chloroacetate, 98%
 ReagentPlus®, 99%, contains ≤1000 ppm propylene oxide as [2916‑14‑5] Beil. 2,198 ClCH2CO2CH2CH=CH2 FW 134.56
stabilizer bp ............................................ 164 °C/265 mmHg n20
D .......................................................................... 1.446
density ..................................... 1.159 g/mL, 25 °C
7
A29585-100G glass btl 100 g Warning H302-H312-H315-H319-H332-H335 P261-P280-P305 + P351
+ P338
A29585-1KG glass btl 1 kg 392944-50ML glass btl 50 mL
A29585-3KG glass btl 3 kg > Allylchloro-[1,3-bis-(2,6-diisopropylphenyl)-2-imidazolidinylidene]
palladium(II), see Allyl[1,3-bis(2,6-diisopropylphenyl)-2-imidazolidinylidene]
 reagent grade, 97%, contains ≤1000 ppm propylene oxide as chloropalladium(II) Page 68
stabilizer (4R,5R)-2-Allyl-2-chloro-3,4-dimethyl-1,3,2-oxazasilolidine, see (4R,5R)-2-
Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane
337528-250ML glass btl 250 mL Page 70

AHB A, 0613, UNP EU
n Allylchlorodime n
(4R,5R)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa- 8 Allyl cyanoacetate

3-aza-2-silacyclopentane, 97%
[13361‑32‑5] NCCH2CO2CH2CH=CH2 FW 125.13
(2S,4R,5R)-2-Chloro-3,4-dimethyl-5-phenyl-2-(2- H3C CH3 bp ............................................... 110 °C/20 mmHg n20
D .......................................................................... 1.443
propen-1-yl)-1-oxa-3-aza-2-silacyclopentane; 1- N Cl density ..................................... 1.065 g/mL, 25 °C
Si
oxa-3-aza-2-Silacyclopentane(1R,2R)-pseudo-
6
O CH2 Danger H301-H312-H315-H319-H332-H335 P261-P280-P301 + P310-
ephedrine allylchlorosilane; (4R,5R)-2-Chloro-3,4- P305 + P351 + P338
dimethyl-5-phenyl-2-(2-propenyl)-1-oxa-3-aza-2-
 Lonza quality, ≥99.0% (GC)
silacyclopentane; (4R,5R)-2-Allyl-2-chloro-3,4-
A
product of Lonza Ltd
dimethyl-1,3,2-oxazasilolidine
bp .................................................................................................................................................................... 89-90/5 hPa
[596851‑24‑0] C13H18ClNOSi FW 267.83
bp .......................................................................................................................................................... 120 °C/5 mmHg 691186-1KG poly btl 1 kg
density ............................................................................................................................................. 1.086 g/mL, 25 °C 691186-25KG 25 kg
[α]20
D −79°, c = 0.6 in ethanol
U.S. Patent No. 7,534,905  98%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
360961-100G glass btl 100 g
719056-1G glass btl 1g Allylcyclohexane, 96%
(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3- 8 [2114‑42‑3] C9H16 FW 124.22 CH2
aza-2-silacyclopentane
(4S,5S)-2-Chloro-3,4-dimethyl-5-phenyl-2-(2-propenyl)-1-oxa-3-aza-2-
silacyclopentane; (1S,2S)-pseudoephedrine allylchlorosilane; (4S,5S)-2- bp ................................. 148-149 °C/760 mmHg n20 D .......................................................................... 1.450
Allyl-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazasilolidine density ..................................... 0.803 g/mL, 25 °C
[447440‑43‑9] C13H18ClNOSi FW 267.83
256
Danger H226-H301-H318-H413 P280-P301 + P310-
bp .................................................. 120 °C/5 mmHg n20
D .......................................................................... 1.517 P305 + P351 + P338
density ..................................... 1.095 g/mL, 25 °C
Reagent used in the enantioselective allylation of aldehydes1 662844-25G glass btl 25 g
This product is a mixture of diastereomers.
[α]20
D 72.5°, c = 0.6 in ethanol (200 proof) 2-Allylcyclohexanone, 97%
U.S. Patent No. 7,534,905 [94‑66‑6] Beil. 7,I,53 H2C=CHCH2C6H9(=O) FW 138.21
Lit. cited: 1. Kinnaird, J. W. A. et al. , J. Am. Chem. Soc. 124, 7920 (2002) bp .................................................. 94 °C/23 mmHg n20
D .......................................................................... 1.469
27
Danger H226-H261-H315-H319-H335 P231 + P232-P261-P305 density ..................................... 0.927 g/mL, 25 °C
+ P351 + P338-P422
7
706671-1G glass btl 1g + P338
> (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazasilolidine, see 405752-1G glass btl 1g

(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclo- 405752-5G glass btl 5g
pentane Page 70
Allylcyclohexylamine, 98%
Allyl(chloro)dimethylsilane, 97% [6628‑00‑8] C6H11NHCH2CH=CH2 FW 139.24
ADMCS; Allyldimethylchlorosilane bp .......................................... 65-66 °C/12 mmHg n20
D ....................................................................... 1.4664
[4028‑23‑3] Beil. 4,IV,4080 H2C=CHCH2Si(CH3)2Cl FW 134.68 density ..................................... 0.962 g/mL, 25 °C

bp ............................................................... 111-113 °C n20
D .......................................................................... 1.427
25
Danger H226-H314 P280-P305 + P351 + P338-P310
density ..................................... 0.891 g/mL, 25 °C
25
Danger H225-H314 P210-P280-P305 + P351 + P338-P310 A31008-5G glass btl 5g
A31008-100G 100 g
Allylcyclopentane, 97%
Allyl chloroformate, 97%
[3524‑75‑2] C8H14 FW 110.20
[2937‑50‑0] Beil. 3,IV,29; Fieser 13,9; 12,15 ClCOOCH2CH=CH2
27
Danger H225-H302-H312-H332 P210-P280
FW 120.53
bp .............................................. ~27 °C/11 mmHg n20
D .......................................................................... 1.422
density ..................................... 1.134 g/mL, 20 °C vp .................................................... 3.67 psi (20 °C)
Reagent employed in ring-expanding allylation leading to 1,4-
cycloheptanediones.1 N-Allylcyclopentylamine, 97%
Lit. cited: 1. Angew. Chem. Int. Ed. Engl. 46, 3966 (2007) [55611‑39‑7] C5H9NHCH2CH=CH2 FW 125.21
256
Danger H226-H301-H314-H330 P260-P280-P284-P301 bp ............................................................... 155-160 °C n20
D ............................................................................. 1.46
+ P310-P305 + P351 + P338-P310 density ..................................... 0.855 g/mL, 25 °C
27
242306-5G glass btl 5g Warning H226-H315-H319-H335 P261-P305 + P351 + P338
242306-100G glass btl 100 g
Allyl cyanide, 98%
3-Butenenitrile; Vinylacetonitrile
[109‑75‑1] Merck 14,290; Beil. 2,IV,1491 CH2=CHCH2CN FW 67.09 Allyl(dichloro)methylsilane, 95%
bp ............................................................... 116-121 °C n20
D .......................................................................... 1.405 Allyl-methyl-dichlorosilane
[1873‑92‑3] Beil. 4,IV,4188 H2C=CHCH2Si(Cl)2CH3 FW 155.10
26
Danger H226-H301-H312-H315-H319-H331 P261-P280-P301 bp ..................................................................... 119.5 °C n20
D .......................................................................... 1.440
+ P310-P305 + P351 + P338-P311 density ..................................... 1.067 g/mL, 25 °C
25
122793-5G glass btl 5g Danger H225-H314-EUH014 P210-P280-P305 + P351 + P338-
122793-100G glass btl 100 g P310
122793-500G glass btl 500 g 447277-25ML glass btl 25 mL

AHB A, 0613, UNP EU
n Allylfluorobenz n
Allyl P,P-diethylphosphonoacetate, 97% Unlike most 2-pyridyl metal complexes, this compound participates in
Phosphonoacetic acid P,P-diethyl allyl ester Pd-catalyzed cross-coupling reactions with aryl iodides in the
[113187‑28‑3] Beil. 4,IV,3610 (C2H5O)2P(O)CH2COOCH2CH=CH2 presence of silver(I) oxide.1
FW 236.20 Lit. cited: 1. Nokami, T. et al., Org. Lett. 8, 729 (2006)
7
bp ..................................... 157-158 °C/10 mmHg n20 D .......................................................................... 1.445
Warning H315-H319-H335 P261-P305 + P351 + P338
density ........................................ 1.12 g/mL, 25 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
405701-5ML glass btl 5 mL Allyldiphenylphosphine, 95% A
> Allyldiglycol, see Diethylene glycol monoallyl ether Page 975 Diphenyl-2-propenylphosphine
[2741‑38‑0] Beil. 16,IV,951 (C6H5)2PCH2CH=CH2 FW 226.25
7-Allyl-7,8-dihydro-8-oxoguanosine, 95% bp .................................... 194-200 °C/15 mmHg n20 D .......................................................................... 1.619
[121288‑39‑9] C13H17N5O6 FW 339.30 CH2 density ..................................... 1.049 g/mL, 25 °C
O
7
Warning H315-H319-H335 P261-P305 + P351 + P338
HN N
O
H 2N N N
HO O 336874-10G glass btl 10 g
OH OH Allyldiphenylphosphine oxide, 97%

mp .............................................................................................................................................................. 227 to 230 °C [4141‑48‑4] Beil. 16,III,863 H2C=CHCH2P(C6H5)2(O) FW 242.25
D −32°, c = 1 in H2O
[α]21 mp .............................................................................................................................................................. 110 to 114 °C
7
496812-250MG glass btl 250 mg Warning H315-H319-H335 P261-P305 + P351 + P338
> (−)-B-Allyldiisopinocampheylborane solution, see (−)-Ipc2B(allyl)borane

solution Page 1558 477966-10G glass btl 10 g
(+)-B-Allyldiisopinocampheylborane solution, see (+)-Ipc2B(allyl)borane
solution Page 1558 Allyl disulfide, 80%
Diallyl disulfide
4-Allyl-1,2-dimethoxybenzene, 99% [2179‑57‑9] Beil. 1,IV,2098 CH2=CHCH2SSCH2CH=CH2 FW 146.27
Eugenol methyl ether; 4-Allyl-1,2-dimethoxybenzene bp ............................................................... 180-195 °C vd ................................................................ >5 (vs air)
[93‑15‑2] Merck 14,6073; Beil. 6,IV,6337 H2C=CHCH2C6H3(OCH3)2 density ..................................... 1.008 g/mL, 25 °C vp ................................................ 1 mmHg (20 °C)
n20
D .............................................................................. 1.541
FW 178.23
mp .......................................................................... −4 °C density .................................. 1.036 g/mL, 25 °C
bp ............................................................... 254-255 °C n20
 technical grade
D .......................................................................... 1.534
Remainder other allyl sulfides
78
Warning H302-H315-H319-H335-H351 P261-P281-P305 +
6
P351 + P338
P338
284424-100G glass btl 100 g
317691-100G glass btl 100 g
4-Allyl-2,6-dimethoxyphenol, ≥90%
Allyl ether, 98%
[6627‑88‑9] Beil. 6,I,556 H2C=CHCH2C6H2(OCH3)2OH FW 194.23
Diallyl ether
bp ..................................... 168-169 °C/11 mmHg n20
D .......................................................................... 1.548
density ..................................... 1.092 g/mL, 25 °C [557‑40‑4] Merck 14,292; Beil. 1,438 (H2C=CHCH2)2O FW 98.14
bp ..................................................................... 94-95 °C n20
D .......................................................................... 1.416
 technical grade density ..................................... 0.803 g/mL, 25 °C
26
Danger H225-H302-H311-H315-H319-H332-H335 P210-P261-
7
Warning H315-H317-H319-H335 P261-P280-P305 + P351 + P338
P280-P305 + P351 + P338-P312
A31601-5G glass btl 5g 259470-25G glass btl 25 g
A31601-10G glass btl 10 g 259470-100G glass btl 100 g
(±)-trans-1-Allyl-2,5-dimethylpiperazine, 97% > 2-Allylethyl alcohol, see 4-Penten-1-ol Page 1997
[155766‑33‑9] C9H18N2 FW 154.25 H Allyl ethyl ether, 95%

H3C N
3-Ethoxypropene; Ethyl allyl ether
N CH3
H2C [557‑31‑3] Merck 14,293; Beil. 1,IV,2083 C2H5OCH2CH=CH2
FW 86.13
bp ............................................. 60-61 °C/5 mmHg n25
D ....................................................................... 1.4730
bp ..................................................................... 65-66 °C n20
D .......................................................................... 1.388
density ..................................... 0.903 g/mL, 25 °C density ........................................ 0.76 g/mL, 25 °C

ethanol ........................................................................................................................................................................... 1-5%
27
27
P280-P305 + P351 + P338 Danger H225-H315-H319-H335 P210-P261-P305 + P351 +
578118-1G glass btl 1g P338
> Allyldimethyl(2-pyridyl)silane, see 2-(Allyldimethylsilyl)pyridine Page 71 1-Allyl-4-fluorobenzene, 97% 8

2-(Allyldimethylsilyl)pyridine, 90% [1737‑16‑2] C9H9F FW 136.17 CH2
Allyldimethyl(2-pyridyl)silane F
[118722‑54‑6] (CH2CHCH2)Si(CH3)2(C5H4N) FW 177.32
density ............................................................................................................................................. 1.009 g/mL, 25 °C
density ............................................................................................................................................. 0.913 g/mL, 25 °C
n20
D ...................................................................................................................................................................................... 1.494
n20
D ................................................................................................................................................................................... 1.5046
257
Danger H226-H302-H318 P280-P305 + P351 + P338

AHB A, 0613, UNP EU
n Allylgalactopyr n
Allyl α-D-galactopyranoside, 97% Reagent used with allylindium sesquiiodide in the cis-double
[48149‑72‑0] Beil. 17,IV,2939 C9H16O6 HO
allylation of cyclopropenes.1
FW 220.22 contains copper as stabilizer
HO O
OH
Lit. cited: 1. Org. Biomolecular Chem. 5, 2154 (2007)
25
O Danger H225-H314 P210-P280-P305 + P351 + P338-P310
CH2
OH
mp .............................................................................................................................................................. 141 to 145 °C
238325-100G glass btl 100 g
A [α]20
D +170°, c = 1.5 in H2O
515566-5G glass btl 5g Allyl isocyanate, 98%
[1476‑23‑9] Beil. 4,IV,1081 CH2=CHCH2NCO FW 83.09
Allyl glycidyl ether, ≥99% bp ..................................................................... 87-89 °C n20
D .......................................................................... 1.417
Allyl 2,3-epoxypropyl ether; 1-Allyloxy-2,3-epoxy- H2 C
density ........................................ 0.94 g/mL, 25 °C
propane O
Reacts with pyroglutamate in the presence of sodium hydride to form
O
[106‑92‑3] Beil. 17,V,3,12 C6H10O2 FW 114.14 N-allylhydantoins.1
bp ......................................................................... 154 °C vd ................................................................ 3.9 (vs air) Lit. cited: 1. Eur. J. Org. Chem. 2649 (2006)
density ..................................... 0.962 g/mL, 25 °C vp ............................................. 4.7 mmHg (25 °C)
268
Danger H226-H301-H311-H315-H317-H319-H331-H334
n20
D .............................................................................. 1.433 P261-P280-P301 + P310-P305 + P351 + P338-P311
Useful in hydrosilylation, including the H2PtCl6·xH2O (cat. no. 206083) 243272-5G glass btl 5g
catalyzed hydrosilylation of siloxanes to epoxysiloxanes.1 243272-25G glass btl 25 g
Lit. cited: 1. Macromolecules 27, 3397 (1994)
Allyl isothiocyanate, 95%
2578
Danger H226-H302-H315-H317-H318-H332-
H335-H341-H351-H361-H412 P261-P273-P280- Oil of mustard; AITC
P305 + P351 + P338 [57‑06‑7] Merck 14,295; Beil. 4,IV,1081 CH2=CHCH2NCS FW 99.15
A32608-100ML Sure/Seal™ 100 mL Naturally occurring constituent of cruciferous vegetables that has
A32608-500ML Sure/Seal™ 500 mL anti-tumor and anti-oxidant properties. Induces the activity of phase II
detoxification enzymes in the urinary bladder and, thus, may be
> L-Allylglycine, see (S)-(−)-2-Amino-4-pentenoic acid Page 152
chemoprotective against bladder cancer.
mp ....................................................................... −80 °C density ................................. 1.013 g/mL, 25 °C
DL-2-Allylglycine
bp ......................................................................... 150 °C n20
D .......................................................................... 1.529
(±)-2-Amino-4-pentenoic acid; DL-C-Allylglycine
2689
Danger H226-H301-H310-H315-H317-H319-
[7685‑44‑1] Beil. 4,IV,2852 H2C=CHCH2CH(NH2)CO2H FW 115.13 H331-H334-H410 P261-P273-P280-P301 + P310-
mp .............................................................................................................................................................. 258 to 260 °C P302 + P350-P305 + P351 + P338
7
Warning H315-H317-H319-H335 P261-P280-P305 + P351 + P338 377430-5G glass btl 5g
A8378-1G poly btl 1g 377430-500G glass btl 500 g
Allylmagnesium bromide solution
A8378-25G poly btl 25 g [1730‑25‑2] Beil. 4,II,1042 CH2=CHCH2MgBr FW 145.28
density ............................................................................................................................................. 0.851 g/mL, 25 °C
3′-Allyl-4′-hydroxyacetophenone, 97%
257
Danger H225-H260-H302-H314-H336-EUH019-EUH014
[1132‑05‑4] CH2=CHCH2C6H3(OH)COCH3 FW 176.21 P210-P223-P231 + P232-P261-P370 + P378-P422
632759 Full product information at Aldrich.com  1.0 M in diethyl ether
> Allyl N-(2-hydroxyethyl)carbamate, see N-(Allyloxycarbonyl)ethanolamine 225754-100ML Sure/Seal™ 100 mL
Page 74 225754-800ML Sure/Seal™ 800 mL
O-Allylhydroxylamine hydrochloride, ≥98.0% (AT)  1.0 M in diethyl ether

O-(2-Propenyl)hydroxylamine hydrochloride Angled septum-inlet adapter Z118206 or straight septum-inlet
[38945‑21‑0] Beil. 1,IV,2087 CH2=CHCH2ONH2 · HCl FW 109.55 adapter, 6mm I.D. inlet, Z118141 or straight septum-inlet adapter,
mp ............................................................................................................................................................. ~170 °C (dec.)
13mm I.D. inlet, Z118192 is recommended.
256609-200ML Sure/Pac™ 200 mL
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Allylmagnesium chloride solution
[2622‑05‑1] Beil. 4,III,1995 CH2=CHCH2MgCl FW 100.83
density ............................................................................................................................................. 0.995 g/mL, 25 °C
O-Allylhydroxylamine hydrochloride hydrate, 97%  2.0 M in THF
[206557‑03‑1] Beil. 1,III,1887 H2C=CHCH2ONH2·HCl·xH2O Used in a study of the nucleophilic ring-opening of 2-methylenea-
FW 109.55 (Anh) ziridines to imines and subsequent conversion to 5,5′-disubstituted
mp ................................................................................................................................................................. 175 °C (dec.) hydantoins.1
Lit. cited: 1. Tetrahedron Lett. 47, 9207 (2006)
5
Danger H314 P280-P305 + P351 + P338-P310
257
Danger H260-H314-H335-EUH019 P223-P231 + P232-
P261-P280-P370 + P378-P422
254568-5G glass btl 5g 225908-100ML Sure/Seal™ 100 mL
> 2-(3-Allyl-2-hydroxy-5-methylphenyl)-2H-benzotriazole, see 2-(2H-Benzo-
triazol-2-yl)-4-methyl-6-(2-propenyl)phenol Page 242  2.0 M in THF
Allyl iodide, 98% 256617-200ML Sure/Pac™ 200 mL
3-Iodo-1-propene
[556‑56‑9] Merck 14,294; Beil. 1,IV,761 CH2=CHCH2I FW 167.98
bp ............................................................... 102-103 °C n20
D .......................................................................... 1.554
density ..................................... 1.837 g/mL, 25 °C

AHB A, 0613, UNP EU
n Allylmethylimid n
Allylmalonic acid, ≥98.0% (T) 2-Allyl-2-methyl-1,3-cyclopentanedione, 97%

[2583‑25‑7] Beil. 2,III,1945 CH2=CHCH2CH(COOH)2 FW 144.13 [26828‑48‑8] C9H12O2 FW 152.19
mp .............................................................................................................................................................. 102 to 105 °C O O
H3C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
CH2
06023-10G poly btl 10 g bp ............................................. 61-62 °C/1 mmHg n20

D .......................................................................... 1.477
density ..................................... 1.026 g/mL, 25 °C
> Allyl mercaptan, see 2-Propene-1-thiol Page 2194
1-Allyl-2-methoxybenzene, see 2-Allylanisole Page 68
2-Allyl-6-methoxyphenol, see o-Eugenol Page 1283 7
Warning H315-H319-H335 P261-P305 + P351 + P338
A
N-Allylmethylamine, 96%
N-Methylallylamine > 2-Allyl-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione, see Allylboronic acid
MIDA ester Page 69
[627‑37‑2] Beil. 4,IV,1058 CH2=CHCH2NHCH3 FW 71.12
bp ..................................................................... 64-66 °C n20
D .......................................................................... 1.412
Allyl methyl ether, 97%
density ..................................... 0.741 g/mL, 25 °C
3-Methoxy-1-propene
256
Danger H225-H301-H311-H314-H331 P210-P261-
P280-P305 + P351 + P338-P310 [627‑40‑7] CH2=CHCH2OCH3 FW 72.11
bp ....................................... 42-43 °C/760 mmHg n20D ....................................................................... 1.3803
317748-1G ampule 1g density ..................................... 0.768 g/mL, 25 °C
317748-5G ampule 5g
27
Danger H225-H302-H319 P210-P305 + P351 + P338
1-Allyl-2-methylbenzene, 97% 8
2-Allyltoluene CH2
[1587‑04‑8] C10H12 FW 132.20
CH3 1-Allyl-3-methylimidazolium bis(trifluoromethylsul- 8
fonyl)imide, ≥98.5% (HPLC)
density ............................................................................................................................................. 0.895 g/mL, 25 °C
n20
D ...................................................................................................................................................................................... 1.517
[655249‑87‑9] C9H11F6N3O4S2 FW 403.32 CH3
N+ O O
257
Danger H226-H302-H318 P280-P305 + P351 + P338 F3C S N S CF3
N O O
CH2
1-Allyl-3-methylbenzene, 97% water ................................................................................................................................................................................. ≤1%

8
7
Warning H319 P305 + P351 + P338
3-Allyltoluene CH2
[3333‑20‑8] C10H12 FW 132.20
727695-5G poly btl 5g
CH3 727695-50G poly btl 50 g
bp .................................................. 60 °C/11 mmHg n20

D .......................................................................... 1.511
1-Allyl-3-methylimidazolium bromide, ≥97.0%
density ..................................... 0.873 g/mL, 25 °C [31410‑07‑8] C7H11BrN2 FW 203.08 CH3
27
Warning H226-H302 N
Br
N
> 1-Allyl-4-methylbenzene, see 4-Allyltoluene Page 76 water ............................................................................................................................................................................. ≤1.0%

n20
D ...................................................................................................................................................................................... 1.578
(R)-(+)-N-allyl-α-methylbenzylamine, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[126275‑19‑2] C6H5CH(CH3)NHCH2CH=CH2 FW 161.24
[α]20
D +60°, c = 1 in chloroform 41382-5G poly btl 5g
bp ............................................. 58-59 °C/1 mmHg n20
D ....................................................................... 1.5145
density ..................................... 0.919 g/mL, 25 °C 1-Allyl-3-methylimidazolium chloride, ≥97.0% (T)
5
Danger H314 P280-P305 + P351 + P338-P310 AMIM-Cl CH3
[65039‑10‑3] C7H11ClN2 FW 158.63 N
559032-1G glass btl 1g Cl
N
> Allyl methyl carbinol, see 4-Penten-2-ol Page 1997

7
Warning H315-H319-H335 P261-P305 + P351 + P338
store at: −20°C
Allyl methyl carbonate, 98%
43961-5G-F glass btl 5g
[35466‑83‑2] Beil. 3,IV,10; Fieser 14,12 CH2=CHCH2OCOOCH3
43961-50G-F glass btl 50 g
FW 116.12
bp .......................................... 59-60 °C/35 mmHg n20
D .......................................................................... 1.406 1-Allyl-3-methylimidazolium dicyanamide, ≥98.5% 8
density ..................................... 1.022 g/mL, 25 °C (HPLC)
27
Warning H226-H315-H319-H335 P261-P305 + P351 + P338 [917956‑73‑1] C9H15N3 FW 165.24 CH3
N+
381381-5ML glass btl 5 mL N C N C N
N
381381-25ML glass btl 25 mL CH2
water ............................................................................................................................................................................. ≤1.0%
7
Warning H319 P305 + P351 + P338

727709-50G poly btl 50 g

AHB A, 0613, UNP EU
n Allylmethylimid n
7
1-Allyl-3-methylimidazolium iodide, 98% 8 Warning H315-H319-H335 P261-P305 + P351 + P338
[65039‑07‑8] C7H11IN2 FW 250.08 CH3

N
I
N > Nβ-Allyloxycarbonyl-Nα-Fmoc-L-2,3-diaminopropionic acid, see Fmoc-Dap
CH2 (Alloc)-OH Page 1344
1-Allyloxy-2,3-epoxypropane, see Allyl glycidyl ether Page 72
≥98.0% (HPLC)
2-Allyloxyethanol, 98%
A 7
water ............................................................................................................................................................................. <1.0%
Warning H319 P305 + P351 + P338
Ethylene glycol allyl ether
[111‑45‑5] Beil. 1,468 H2C=CHCH2OCH2CH2OH FW 102.13
bp ......................................................................... 159 °C n20
D .......................................................................... 1.436
727717-5G glass btl 5g density ..................................... 0.955 g/mL, 25 °C
5
Danger H315-H318 P280-P305 + P351 + P338
2-Allyl-6-methylphenol, 98%
[3354‑58‑3] H2C=CHCH2C6H3(CH3)OH FW 148.20 476234-250ML glass btl 250 mL
A34007 Full product information at Aldrich.com
4-Allyloxy-2-hydroxybenzophenone, 99%
Allyl methyl sulfide, 98%
[2549‑87‑3] H2C=CHCH2OC6H3(OH)COC6H5 FW 254.28
[10152‑76‑8] Beil. 1,440 H2C=CHCH2SCH3 FW 88.17
bp ..................................................................... 91-93 °C n20 mp ................................................................................................................................................................... 67 to 70 °C
D ....................................................................... 1.4714
density ..................................... 0.803 g/mL, 25 °C Copolymerizable UV absorber
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2
Danger H225 P210
A34201-5G glass btl 5g 415839-25G poly btl 25 g

A34201-25G glass btl 25 g 3-Allyloxy-2-hydroxy-1-propanesulfonic acid sodium salt
solution
Allyl methyl sulfone, 96% 8
[52556‑42‑0] H2C=CHCH2OCH2CH(OH)CH2SO3Na FW 218.20
MAS; 3-(Methylsulfonyl)-1-propene O
[16215‑14‑8] C4H8O2S FW 120.17 H2C S CH3  40 wt. % in H2O
O density ................................................................................................................................................ 1.17 g/mL, 25 °C
n20
D ...................................................................................................................................................................................... 1.394
density ............................................................................................................................................. 1.171 g/mL, 25 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
n20
D ...................................................................................................................................................................................... 1.472
7
Warning H317 P280
718203-5G glass btl 5g > 2-(Allyloxymethyl)-2-ethyl-1,3-propanediol, see Trimethylolpropane allyl

ether Page 2539
2-Allyloxybenzaldehyde
3-Allyloxy-1,2-propanediol, 99%
[28752‑82‑1] H2C=CHCH2OC6H4CHO FW 162.19
bp ............................................... 130 °C/10 mmHg n20
D ............................................................................. 1.55 Glycerol 1-allyl ether; Glycerol α-monoallyl ether
density ..................................... 1.079 g/mL, 25 °C [123‑34‑2] Beil. 1,IV,2759 HOCH2CH(OH)CH2OCH2CH=CH2
FW 132.16
 technical grade bp ............................................... 142 °C/28 mmHg n20
D .......................................................................... 1.462
445509-5ML glass btl 5 mL density ..................................... 1.068 g/mL, 25 °C
7
445509-25ML glass btl 25 mL Warning H319 P305 + P351 + P338
4-Allyloxybenzaldehyde, 97%
251739-500G glass btl 500 g
[40663‑68‑1] H2C=CHCH2OC6H4CHO FW 162.19
bp ..................................... 150-152 °C/18 mmHg n20
D .......................................................................... 1.568 2-Allyloxytetrahydropyran, 98%
density ..................................... 1.058 g/mL, 25 °C [4203‑49‑0] C8H14O2 FW 142.20
7
Warning H317 P280 CH2
O O
544396-10G glass btl 10 g Refrigerate

544396-50G glass btl 50 g bp .......................................... 76-77 °C/25 mmHg n20
D ....................................................................... 1.4275
density ..................................... 0.940 g/mL, 25 °C
Allyloxy-tert-butyldimethylsilane, 98%
contains ~1% K2CO3 as stabilizer
[105875‑75‑0] H2C=CHCH2OSi(CH3)2C(CH3)3 FW 172.34
257
bp ............................................... 120 °C/50 mmHg n20 Danger H226-H302-H315-H317-H318-H335-EUH019
D .......................................................................... 1.421
density ..................................... 0.811 g/mL, 25 °C P261-P280-P305 + P351 + P338
2
Warning H226
556335-100G glass btl 100 g
444294-5ML glass btl 5 mL Allyloxytrimethylsilane, 98%
3-(Trimethylsiloxy)propene
N-(Allyloxycarbonyl)ethanolamine, ≥98.0% (GC) [18146‑00‑4] Beil. 4,IV,3999 H2C=CHCH2OSi(CH3)3 FW 130.26
bp ............................................................... 100-102 °C n20
D .......................................................................... 1.397
Allyl N-(2-hydroxyethyl)carbamate density ..................................... 0.773 g/mL, 25 °C
[66471‑00‑9] CH2=CHCH2OCONHCH2CH2OH FW 145.16
27
Danger H225-H315-H319-H335 P210-P261-P305 + P351 +
density ............................................................................................................................................. 1.125 g/mL, 20 °C
P338
Building block for introducing an Alloc-protected 2-aminoethoxy
group1
n20
D ...................................................................................................................................................................................... 1.471
Lit. cited: 1. D.T. Hung et al., J. Am. Chem. Soc. 118, 11065 (1996)

AHB A, 0613, UNP EU
n Allylsulfide n
Allylpalladium(II) chloride dimer Allyl phenyl sulfide, ≥96.5% (GC)

[PdCl(C3H5)]2 CH2 Cl H2C
[5296‑64‑0] Beil. 6,IV,1479 CH2=CHCH2SC6H5 FW 150.24
[12012‑95‑2] Fieser 9,132; 7,5; 17,96; 5,189; 2,109 Pd Pd bp ....................................................................................................................................................................... 223-225 °C
C6H10Cl2Pd2 FW 365.89 CH2 Cl H2C
density ............................................................................................................................................. 1.024 g/mL, 20 °C
n20
D ...................................................................................................................................................................................... 1.572
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H312-H332 P280
 98%
Catalyst for cross-coupling reactions.1 Heck coupling with simple
olefins2 and enol ethers.3
06060-10ML
Allyl phenyl sulfone, 98%

glass btl 10 mL
A
2. Synthesis 1683 (2007) [16212‑05‑8] Beil. 6,IV,1480 C6H5SO2CH2CH=CH2 FW 182.24
bp ................................... 110-113 °C/0.5 mmHg n20 D .......................................................................... 1.548
3. Eur. J. Org. Chem. 3122 (2007)
density ..................................... 1.189 g/mL, 25 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
A product of Umicore. Allylphosphonic acid monoammonium salt, 95%
C3H10NO3P FW 139.09
7
Warning H302-H319 P305 + P351 + P338
Allylpalladium chloride dimer ChemDose™ tablet 8
[PdCl(C3H5)]2 CH2 Cl H2C
[12012‑95‑2] C6H10Cl2Pd2 FW 365.89 Pd Pd 1-Allylpiperazine, 96%
CH2 Cl H2C
[13961‑36‑9] C7H14N2 FW 126.20 H
N
composition
allylpalladium chloride dimer <5% N
magnesium aluminometasilicate >90% CH2
methylene chloride <5%

bp ............................................................... 181-182 °C n20
D ....................................................................... 1.4830
8
Warning H351 P281
density ..................................................... 0.902 g/mL
25
Danger H226-H314 P280-P305 + P351 + P338-P310
705020-10TAB glass btl 10 tablets
705020-100TAB glass btl 100 tablets
Allylpentafluorobenzene, 97%
(R)-α-Allyl-proline hydrochloride, ≥98.0% (TLC)
[1736‑60‑3] C6F5CH2CH=CH2 FW 208.13
bp ............................................................... 148-149 °C n20
D .......................................................................... 1.427
α-Allyl-L-proline hydrochloride; (R)-2-Allyl-2- CH2
density ..................................... 1.358 g/mL, 25 °C pyrrolidinecarboxylic acid hydrochloride
• HCl
[177206‑69‑8] C8H13NO2·HCl FW 191.66 OH
27
Warning H226-H315-H319-H335 P261-P305 + P351 + P338 N
H O

06541-500MG-F poly btl 500 mg
> α-Allyl-L-proline hydrochloride, see (R)-α-Allyl-proline hydrochloride
2-Allylphenol, 98% Page 75
(R)-2-Allyl-2-pyrrolidinecarboxylic acid hydrochloride, see (R)-α-Allyl-proline
[1745‑81‑9] Beil. 6,IV,3807 H2C=CHCH2C6H4OH FW 134.18 hydrochloride Page 75
bp ......................................................................... 220 °C n20
D .......................................................................... 1.546
density ..................................... 1.028 g/mL, 25 °C
3-Allylsalicylaldehyde, 97%
56
Danger H301-H311-H314 P280-P305 + P351 + P338-P310
[24019‑66‑7] CH2=CHCH2C6H3(OH)CHO FW 162.19
density ............................................................................................................................................. 1.099 g/mL, 25 °C
n20
D ................................................................................................................................................................................... 1.5645
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> 2-Allylphenyl bromide, see 1-Allyl-2-bromobenzene Page 69
Allyl phenyl carbonate, 97% 636339-5G glass btl 5g
[16308‑68‑2] C10H10O3 FW 178.18
O Allyl sulfide, 97%
CH2
O O Diallyl sulfide
bp ......................................... 67-70 °C/0.3 mmHg n20
D ....................................................................... 1.4990
[592‑88‑1] Merck 14,297; Beil. 1,IV,2097 (CH2=CHCH2)2S FW 114.21
density ..................................... 1.096 g/mL, 25 °C Organosulfur compound from garlic that inhibits chemically-induced
carcinogenesis in experimental animals. Competitive inhibitor of
7
Warning H302-H317-H319 P280-P305 + P351 + P338
Cytochrome P450 2E1 (CYP2E1) that, in turn, blocks the activation of
several chemcal carcinogens.
mp ....................................................................... −83 °C n20D .......................................................................... 1.490
630659-5G glass btl 5g bp ......................................................................... 138 °C vd ............................................................... 3.9 (vs air)
density ..................................... 0.887 g/mL, 25 °C vp ................................................ 7 mmHg (20 °C)
Allyl phenyl ether, 99%
27
[1746‑13‑0] Beil. 6,IV,562; Fieser 11,14 C6H5OCH2CH=CH2
FW 134.18
bp ......................................................................... 192 °C n20 A35801-25ML glass btl 25 mL
D .......................................................................... 1.522
density ..................................... 0.978 g/mL, 25 °C

AHB A, 0613, UNP EU
n Allyltetraacety n
Allyl-tetra-O-acetyl-β-D-glucopyranoside, 98% O-Allyl 2,2,2-trichloroacetimidate, 96%

[10343‑15‑4] C17H24O10 FW 388.37 RO CH2
2,2,2-Trichloroacetimidic acid allyl ester NH
O [51479‑73‑3] C5H6Cl3NO FW 202.47 CH2
O Cl3C O
OR O
OR OR R=* CH3 bp ........................... 54-70 °C/7.5-11.25 mmHg n20 D .......................................................................... 1.489
density ..................................... 1.333 g/mL, 25 °C
mp .................................................................................................................................................................... 87 to 90 °C
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
[α]20
A
P338
> 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, see Allylboronic acid pinacol Allyltrichlorosilane, 95%

ester Page 69
[107‑37‑9] Beil. 4,IV,4260 H2C=CHCH2SiCl3 FW 175.52
N-Allylthiourea, 98% bp ............................................ 116 °C/750 mmHg vd ................................................................ >1 (vs air)
density ..................................... 1.211 g/mL, 25 °C vp ......................................... 10 mmHg (16.1 °C)
Thiosinamine; 1-Allyl-2-thiourea n20
D .............................................................................. 1.443
[109‑57‑9] Merck 14,9362; Beil. 4,IV,1072 CH2=CHCH2NHCSNH2
25
Danger H225-H314 P210-P280-P305 + P351 + P338-P310
FW 116.18
mp .................................................................................................................................................................... 70 to 72 °C
density ................................................................................................................................................ 1.11 g/mL, 25 °C
6
Danger H301 P301 + P310
Allyltriethoxysilane, 97%
108804-50G glass btl 50 g [2550‑04‑1] Beil. 4,IV,4261 H2C=CHCH2Si(OC2H5)3 FW 204.34
108804-250G glass btl 250 g liquid
bp .................................................. 78 °C/21 mmHg n20
D .......................................................................... 1.406
> 2-Allyltoluene, see 1-Allyl-2-methylbenzene Page 73
3-Allyltoluene, see 1-Allyl-3-methylbenzene Page 73 density ..................................... 0.903 g/mL, 25 °C vd ................................................................ >1 (vs air)
27
4-Allyltoluene, 97% Danger H225-H315-H319-H335 P210-P261-P305 + P351 +
8 P338
1-Allyl-4-methylbenzene CH2 A36301-5G glass btl 5g
[3333‑13‑9] C10H12 FW 132.20
H3 C Allyltrifluoroacetate, 98%
[383‑67‑5] CF3CO2CH2CH=CH2 FW 154.09
density ............................................................................................................................................. 0.865 g/mL, 25 °C
257
Danger H225-H314-H335 P210-P261-P280-P305 +
n20
D ...................................................................................................................................................................................... 1.509
P351 + P338-P310
27
Warning H226-H302
706728-5G glass btl 5g 1-Allyl-4-(trifluoromethyl)benzene 8

Allyl p-toluenesulfonate, ≥95.0% (GC) 4-(Trifluoromethyl)allylbenzene CH2
[4873‑09‑0] Beil. 11,IV,254 C10H12O3S [1813‑97‑4] C10H9F3 FW 186.17
O
CH2 F3C
FW 212.27 S O
O
density ............................................................................................................................................. 1.112 g/mL, 25 °C
H3C
n20
D ...................................................................................................................................................................................... 1.449
27
density ............................................................................................................................................. 1.180 g/mL, 20 °C Warning H226-H302
n20
D ...................................................................................................................................................................................... 1.523
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Allyltriisopropylsilane, 98%
[24400‑84‑8] Fieser 13,11 [(CH3)2CH]3SiCH2CH=CH2 FW 198.42
Allyl 2,4,6-tribromophenyl ether, 98% density ............................................................................................................................................. 0.824 g/mL, 25 °C
[3278‑89‑5] Br3C6H2OCH2CH=CH2 FW 370.86 n20
D ...................................................................................................................................................................................... 1.467
7
419664-250G glass btl 250 g Warning H315-H319-H335 P261-P305 + P351 + P338
419664-1KG glass btl 1 kg

Allyltributylstannane, 97%
Allyltrimethoxysilane
[24850‑33‑7] Merck 14,10295; Beil. 4,IV,4317; Fieser 9,8; 17,12; 13,10;
14,14; 12,21; 11,15; 16,7 CH2=CHCH2Sn(CH2CH2CH2CH3)3 [2551‑83‑9] H2C=CHCH2Si(OCH3)3 FW 162.26
bp ............................................................... 146-148 °C n20
D .......................................................................... 1.405
FW 331.12
density ..................................... 0.963 g/mL, 25 °C
bp ......................................... 88-92 °C/0.2 mmHg n20
D .......................................................................... 1.486
27
density ..................................... 1.068 g/mL, 25 °C Warning H226-H315-H319-H335 P261-P305 + P351 + P338
Efficient allylation of aldehydes leading to homoallylic alcohols with

trichloro-1,3,5-triazene.1  ≥98%, deposition grade
Lit. cited: 1. Tetrahedron Lett. 47, 9103 (2006) liquid
689
Danger H301-H312-H315-H319-H372-H410 P273- 679267-50G glass btl 50 g
P280-P301 + P310-P305 + P351 + P338-P314-P501
 95%

AHB A, 0613, UNP EU
n Alpineborane n
Allyltrimethylsilane, 98% (S)-Alpine-Boramine™

3-(Trimethylsilyl)propene H3C CH
CH3 3
[762‑72‑1] Merck 14,10335; Beil. 4,IV,3927; Fieser 10,6; 14,18; 15,8; H3C
H
H
13,11; 11,16; 12,23 H2C=CHCH2Si(CH3)3 FW 114.26 CH3 CH3
H3C
bp ..................................................................... 84-88 °C n20
D .......................................................................... 1.407 BH2 N
N H 2B
density ..................................... 0.719 g/mL, 25 °C CH3 H
H CH3
27
Danger H225-H315-H319-H335 P210-P261-P305 + P351 +
P338 (+)-Isopinocampheylborane TMEDA complex; (+)-N,N′-Bis(monoiso-
208264-10G glass btl 10 g pinocampheylborane)-N,N,N′,N′-tetramethylethylenediamine
[68297‑74‑5] C26H54B2N2 FW 416.34
A
mp .............................................................................................................................................................. 139 to 141 °C
Allyltriphenylphosphonium bromide, 99%
2
Danger H228 P210
[1560‑54‑9] H2C=CHCH2P(C6H5)3Br FW 383.26
mp .............................................................................................................................................................. 222 to 225 °C 495794-5G glass btl 5g
7
Warning H315-H319-H335 P261-P305 + P351 + P338
R-Alpine-Borane®, 97%
A36603-100G poly btl 100 g B-Isopinocampheyl-9-borabicyclo[3.3.1]nonane H3C CH3
[73624‑47‑2] C18H31B FW 258.25 CH3
Allyltriphenylsilane, 98%
B
[18752‑21‑1] Beil. 16,IV,1372 H2C=CHCH2Si(C6H5)3 FW 300.47
mp .................................................................................................................................................................... 87 to 90 °C
375853-5G glass btl 5g bp ................................................................................................................................................................................ >55 °C
density ............................................................................................................................................. 0.947 g/mL, 25 °C
Allyltriphenylstannane, 97% [α]21
D -22°, c = 12 in THF
2-Propenyl-triphenylstannane; Allyltriphenyltin
2
Danger H250 P222-P231-P422
[76‑63‑1] Beil. 16,IV,1592; Fieser 13,14; 14,20 CH2=CHCH2Sn(C6H5)3
FW 391.09 417203
mp .................................................................................................................................................................... 71 to 74 °C
R-Alpine-Borane® solution
69
Danger H301-H311-H331-H410 P261-P273-P280-P301 +
P310-P311-P501 B-Isopinocampheyl-9-borabicyclo[3.3.1]nonane solution
332364-50G glass btl 50 g [73624‑47‑2] C18H31B FW 258.25
> Allyltriphenyltin, see Allyltriphenylstannane Page 77  0.5 M in THF
D −3.0°, neat
[α]20
N-Allylurea, 95% density ............................................................................................................................................. 0.896 g/mL, 25 °C
27
[557‑11‑9] Merck 14,298; Beil. 4,IV,1070 CH2=CHCH2NHCONH2 Danger H225-H319-H335-EUH019 P210-P261-P305 + P351 +
FW 100.12 P338
mp .................................................................................................................................................................... 84 to 86 °C 232734-100ML Sure/Seal™ 100 mL
7
S-Alpine-Borane®, 97%
B-Isopinocampheyl-9-borabicyclo[3.3.1]nonane H3C CH3
L-Allysine ethylene acetal, ≥98% (TLC) 8 [42371‑63‑1] C18H31B FW 258.25 CH3
(S)-2-Amino-5-(1,3-dioxolan-2-yl)pentanoic acid B
[215054‑80‑1] C8H15NO4 FW 189.21 O O
O
OH
NH2
bp ................................................................................................................................................................................ >55 °C
density ............................................................................................................................................. 0.947 g/mL, 25 °C
[α]D +4.0±0.3°, c = 1 in H2O
H413
[α]22
D +20°, c = 12 in THF
2
Danger H250 P222-P231-P422
> AlNiCo, see Aluminum nickel cobalt Page 82 417041
Alphazurine A S-Alpine-Borane® solution

Patent Blue A; Acid Blue 7 B-isopinocampheyl-9-borabicyclo[3.3.1]nonane
[3486‑30‑4] Beil. 14,856 C37H35N2NaO6S2 FW 690.80 [42371‑63‑1] C18H31B FW 258.25
mp ................................................................................................................................................................. 290 °C (dec.)  0.5 M in THF
 Dye content: 60% [α]22
D +1.2°, neat
λmax ............................................................................................................................................................................. 409 nm density ............................................................................................................................................. 0.897 g/mL, 25 °C
λmax ............................................................................................................................................................................. 637 nm
27
Danger H225-H250-H319-H335-EUH019 P210-P222-P231-
P261-P305 + P351 + P338-P422
198145-100G glass btl 100 g 237701-100ML Sure/Seal™ 100 mL
> (R)-Alpine-Boramine™, see (−)-Isopinocampheylborane TMEDA complex
Page 1577

AHB A, 0613, UNP EU
n Alpinehydride n
R-Alpine-Hydride®  evaporation slug, diam. 6.3 mm × L 6.3 mm, 99.999% trace

Lithium B-isopinocampheyl-9-borabicyclo[3.3.1]nonyl H3C CH3
metals basis
hydride solution CH3 weight of one slug ......................................................................................................................................... ~0.5 g
9
[64081‑12‑5] Fieser 8,303 C18H32BLi FW 266.20 Li+ Warning H400 P273
B H
 flakes, 1 mm, 99.99% trace metals basis

A density ............................................................................................................................................. 0.919 g/mL, 25 °C
 0.5 M in THF 2
Danger H250-H261 P222-P231 + P232-P422
D −8.5°
[α]20 518573-500G poly btl 500 g
Made from (+)-α-pinene
 foil, thickness 1.0 mm, 99.999% trace metals basis
257
Danger H225-H260-H314-H332-H335-EUH019 P210-
P223-P231 + P232-P261-P370 + P378-P422 27.2 g = 100 × 100 mm
9
229024-100ML Sure/Seal™ 100 mL Warning H400 P273
S-Alpine-Hydride® 266957-27.2G rigd mailer 27.2 g

Lithium B-isopinocampheyl-9-borabicyclo[3.3.1]nonyl hydride solution
[100013‑07‑8] Fieser 8,303 C18H32BLi FW 266.20
3.4 g = 50 × 50 mm; 13.6 g = 100 × 100 mm
density ................................................................................................................................................ 0.92 g/mL, 25 °C
9
Warning H400 P273
 0.5 M in THF
[α]20
D +5.5°, neat 266574-3.4G rigd mailer 3.4 g
25
Danger H260-H314-EUH014 P223-P231 + P232-P280-P305 + 266574-13.6G rigd mailer 13.6 g
P351 + P338-P370 + P378-P422
237728-100ML Sure/Seal™ 100 mL  foil, thickness 0.25 mm, 99.999% trace metals basis
1.7 g = 50 × 50 mm; 6.8 g = 100 × 100 mm
> ALPYPHOS, see 2-(1,1-Dimethylpropyl)-6-(diphenylphosphino)pyridine
9
Page 1110 Warning H400 P273
Alq3, see Tris-(8-hydroxyquinoline)aluminum Page 2574
Altretamine, see 2,4,6-Tris(dimethylamino)-1,3,5-triazine Page 2571 326852-1.7G rigd mailer 1.7 g
Alumina, see Aluminum oxide Page 83
Aluminum oxide, mesoporous Page 84 326852-6.8G rigd mailer 6.8 g
Aluminon, see Aurintricarboxylic acid ammonium salt Page 205
 foil, thickness 0.13 mm, ≥99.99% trace metals basis
Aluminosilicate, mesostructured 900 mg = 50 × 50 mm; 3.6 g = 100 × 100 mm
9
[1318‑02‑1] (SiO2)x(Al2O3)y Warning H400 P273
Adsorbent, acid catalyst, catalyst support, nanoscale template
powder 326860-900MG rigd mailer 900 mg
326860-3.6G rigd mailer 3.6 g
7
Warning H335 P261

 MCM-41 (hexagonal) 3.1 g = 150 × 150 mm; 20.4 g = 150 × 1000 mm
(SiO2)0.9875(Al2O3)0.0125·xH2O
9
Warning H400 P273
composition
aluminum ~3% 356859-3.1G rigd mailer 3.1 g
unit cell size .................................................................................................................................................. 4.6-4.8 nm
356859-20.4G poly tube 20.4 g
spec. surface area ... 940-1000 m2/g (BET) pore size ................................................... 2.5-3 nm
pore volume ........................................... 1.0 cm3/g  grit, ≥97.0% (complexometric)
2
643653-5G glass btl 5g Danger H228-H261 P210-P231 + P232-P422
11008-500G 500 g
 Al-MSU-F (cellular foam) 11008-1KG 1 kg
(SiO2)0.9875(Al2O3)0.0125·xH2O 11008-6X1KG 6 × 1 kg
composition
aluminum 3.0% (mol)  powder, particle size <1 μm, 99.5% trace metals basis
spec. surface area ........................................................................................................................ 605 m2/g (BET)
2
Danger H250-H261 P222-P231 + P232-P422
pore volume ................................................................................................................................................ 2.03 cm3/g
643629-5G glass btl 5g 653608
 pellets, 3-8 mesh, ≥99.999% trace metals basis
Aluminum
9
Warning H400 P273
[7429‑90‑5] Merck 14,323; Fieser 2,19; 4,9 Al FW 26.98
resistivity ................................................................................................................................................ 2.6548 μΩ-cm 326941-25G poly btl 25 g
mp ................................................................. 660.37 °C density ....................................... 2.7 g/mL, 25 °C
bp ....................................................................... 2460 °C ait ...................................................................... 1400 °F  pellets, 3-8 mesh, 99.99% trace metals basis
9
Warning H400 P273
 ReagentPlus®, beads, 5-15 mm, 99.9% trace metals basis
9
Warning H400 P273 338788-50G poly btl 50 g
 ReagentPlus®, powder, <75 μm, 99%

266523-250G glass btl 250 g
2
Danger H250-H261 P222-P231 + P232-P422

AHB A, 0613, UNP EU
n Aluminumbutoxid n
 powder, <75 μm, ≥99.95% trace metals basis  contains boric acid as stabilizer
powder
2
Danger H250-H261 P222-P231 + P232-P422
composition
202584 Al 19%
8
Danger H360 P201-P308 + P313
 20 μm, spherical powder, ≥99%
2
Danger H250-H261 P222-P231 + P232-P422 294853-250G glass btl 250 g
A
266515
Aluminum acetylacetonate
 powder, ≥91% (complexometric) Aluminum 2,4-pentanedionate; Al(acac)3
heavy metals (as Pb) ...................................................................................................................................... ≤0.03%
[13963‑57‑0] Beil. 1,IV,3668 Al(C5H7O2)3 FW 324.31
soluble in ether .................................................................................................................................................... 0.3-3%
solid
Fe ................................................................................................................................................................. ≤5000 mg/kg
mp .............................................................................................................................................................. 190 to 193 °C
2
Danger H250-H261 P222-P231 + P232-P422
bp ................................................................................................................................................................................. 315 °C
6
Danger H300-H315-H319-H335 P261-P264-P301 + P310-P305 + P351
11009-500G-R 500 g + P338
11009-6X500G-R 6 × 500 g
 purified by sublimation, 99.999%
 rod, diam. 3.0 mm × L 100 mm, 99.999% trace metals basis 674753-5G glass btl 5g
9
Warning H400 P273 674753-25G glass btl 25 g
202576-10G poly tube 10 g  ReagentPlus®, 99%

208248-100G poly btl 100 g
 ACS reagent, 99%, wire, wire diam. 1.5 mm 208248-500G poly btl 500 g
N compounds .................................................................................................................................................. ≤0.001%
insol. dil. HCl ......................................................................................................................................................... ≤0.05% > Aluminum ammonium sulfate dodecahydrate, see Ammonium aluminum
Cu ........................................................................ ≤0.02% Si ......................................................................... ≤0.1% sulfate dodecahydrate Page 174
Fe ........................................................................... ≤0.1% Ti ...................................................................... ≤0.03%
Mn ................................................................... ≤0.002% Aluminum bromide
[7727‑15‑3] Merck 14,332; Fieser 1,22; 2,19; 3,7; 9,11; 5,10; 4,10; 6,17
9
Warning H400 P273
AlBr3 FW 266.69
mp ............................................................ 94 to 98 °C vp ............................................ 1 mmHg (81.3 °C)
310360-100G poly spool 100 g
density ..................................... 3.205 g/mL, 25 °C
 wire, diam. 1.0 mm, 99.999% trace metals basis
57
Danger H302-H314-EUH014 P280-P305 + P351 + P338-P310
10.5 g = 5 m; 52.5 g = 25 m
9  anhydrous, powder, 99.999% trace metals basis

Warning H400 P273
449601-5G ampule 5g
266558-10.5G poly spool 10.5 g
266558-52.5G poly spool 52.5 g  ≥99.99% trace metals basis
 wire, diam. 0.58 mm, ≥99.99% trace metals basis
7 g = 10 m; 35 g = 50 m
 powder and chunks, ≥98%
9
Warning H400 P273
326887-7G poly spool 7g 210072-100G glass btl 100 g
326887-35G poly spool 35 g
Aluminum bromide solution
[7727‑15‑3] Merck 14,332 AlBr3 FW 266.69
Ion Standard Solutions  anhydrous, 1.0 M in dibromomethane
density ............................................................................................................................................. 2.522 g/mL, 25 °C
We offer a wide range of standards for vp ........................................................................................................................................................ 1 mmHg (81.3 °C)
calibration of ICP-MS, ICP-OES, AAS and IC.
57
P338-P310
sigma-aldrich.com/tracecert 250066-100ML Sure/Seal™ 100 mL
> Aluminum butoxide, see Aluminum tributoxide Page 85

Aluminum sec-butoxide, see Aluminum-tri-sec-butoxide Page 85
Aluminum acetate, basic Aluminum tert-butoxide

Aluminum diacetate hydroxide; Aluminum hydroxide acetate Aluminum-tri-tert-butoxide
[142‑03‑0] Merck 14,344; Beil. 2,IV,115 Al(OH)(C2H3O2)2 FW 162.08 [556‑91‑2] Merck 14,333; Beil. 1,IV,1612; Fieser 1,23; 2,21
Insoluble form Al[OC(CH3)3]3 FW 246.32
No stabilizers added.
 technical grade
289825-100G glass btl 100 g
powder
289825-500G glass btl 500 g
25
Danger H228-H314 P210-P280-P305 + P351 + P338-P310
Aluminum acetate, basic
Dihydroxyaluminum acetate
[7360‑44‑3] C2H5O4Al FW 120.04

AHB A, 0613, UNP EU
n Aluminumcarbide n
Aluminum carbide, 99% Aluminum chloride hexahydrate, 99%

[1299‑86‑1] Merck 14,335 Al4C3 FW 143.96 [7784‑13‑6] Merck 14,337; Fieser 6,17; 11,25; 1,24; 4,10; 5,10; 12,26;
density ................................................................................................................................................ 2.36 g/mL, 25 °C 13,15; 3,7; 9,11; 2,21; 8,13 AlCl3 · 6H2O FW 241.43
vp ......................................................................................................................................................... 1 mmHg (100 °C)
 powder, −325 mesh
cubic phase  ReagentPlus ®
27 7
Danger H261-H315-H319-H335 P231 + P232-P261-P305 + Warning H315-H319-H335 P261-P305 + P351 + P338
P351 + P338-P422
A 241873-100G glass btl 100 g 237078-100G

237078-500G
poly btl
poly btl
100 g
500 g
Aluminum cerium oxide, 99% trace metals basis
Cerium aluminum oxide; Cerium aluminate Aluminum chloride hydrate, 99.999% trace metals basis
[12014‑44‑7] AlCeO3 FW 215.10 [10124‑27‑3] Fieser 5,10; 9,11; 11,25; 4,10; 2,21; 6,17; 12,26; 13,15; 3,7;
8,13; 1,24 AlCl3·xH2O FW 133.34 (Anh)
 nanopowder, particle size <50 nm (BET)
mp ......................................................... 100 °C (dec.) vp ............................................. 1 mmHg (100 °C)
BET surf. area ............................................................................................................................................ >18.7 m2/g density ..................................... 2.398 g/mL, 25 °C
7
Warning H335
crystalline
composition
Degree of hydration 6‑7
5
Danger H314 P280-P305 + P351 + P338-P310
Aluminum chloride
[7446‑70‑0] Merck 14,337; Fieser 3,7; 4,10; 8,13; 7,7; 16,10; 1,24; 6,17; 229393-25G poly btl 25 g
14,21; 17,15; 2,21; 10,9; 11,25; 12,26; 9,11; 13,15; 5,10 AlCl3 229393-100G poly btl 100 g
FW 133.34 Aluminum chloride solution
mp ................................................................................................................................................................................ 190 °C
vp ......................................................................................................................................................... 1 mmHg (100 °C)
[7446‑70‑0] Merck 14,337 AlCl3 FW 133.34
 1.0 M in nitrobenzene
5
Danger H314 P280-P305 + P351 + P338-P310
density ............................................................................................................................................. 1.249 g/mL, 25 °C
 anhydrous, powder, 99.999% trace metals basis
5689
Danger H301-H311-H314-H331-H351-H361f-
H372-H411-EUH014 P261-P273-P280-P301 +
563919-5G ampule 5g P310-P305 + P351 + P338-P310
563919-25G ampule 25 g
 anhydrous, powder, 99.99% trace metals basis 249882-800ML Sure/Seal™ 800 mL
449598-5G ampule 5g Aluminum chloride, functionalized silica gel
449598-25G ampule 25 g
Aluminum trichloride, functionalized silica gel
 99.99% trace metals basis  40-63 μm, loading: 1.5 mmol/g
powder Silica-bound Lewis acid. Catalyst for Friedel-Crafts reactions.
294713-5G glass btl 5g surface area ................................................................................................................................................... 500 m2/g
294713-100G glass btl 100 g pore size ........................................................................................................................................................................ 60 Å
 ReagentPlus®, anhydrous, ≥99.9% trace metals basis
495352-1KG glass btl 1 kg Aluminum chloride THF complex
[192656‑42‑1] C4H8AlCl3O FW 205.45
bp .................................................................................................................................................................................... 65 °C
237051-5G glass btl 5g density ............................................................................................................................................. 0.953 g/mL, 25 °C
237051-100G glass btl 100 g
 0.5 M in THF
237051-500G glass btl 500 g
257
Danger H225-H314-H335-EUH019 P210-P261-P280-
 reagent grade, 98% P305 + P351 + P338-P310

206911-1KG glass btl 1 kg > Aluminum diacetate hydroxide, see Aluminum acetate, basic Page 79
 anhydrous, sublimed, ≥98% Aluminum diboride

Caution when opening! Due to production the supernatant gas phase
can contain small amounts of toxic phosgene. [12041‑50‑8] AlB2 FW 48.60
heavy metals (as Pb) ................................................................................................................................... ≤0.005%  −325 mesh
sulfate (SO42-) ........................................................................................................................................ ≤500 mg/kg powder
Fe .................................................................................................................................................................... ≤200 mg/kg 399612-5G glass btl 5g
11019-500G 500 g
> Aluminum dihydrogen phosphate, see Aluminum phosphate monobasic
11019-1KG 1 kg solution Page 84
11019-6X1KG 6 × 1 kg
11019-50KG-H 50 kg

AHB A, 0613, UNP EU
n Aluminumnaphtha n
Aluminum ethoxide, 97% Aluminum isopropoxide

Aluminum triethoxide Aluminum isopropylate; Aluminum triisopropoxide; AIP
[555‑75‑9] Merck 14,338; Beil. 1,III,1223 Al(OC2H5)3 FW 162.16 [555‑31‑7] Merck 14,347; Beil. 1,IV,1468; Fieser 5,14; 1,35; 4,15; 3,10;
solid 6,19; 11,29; 8,15; 9,14 Al[OCH(CH3)2]3 FW 204.24
mp .............................................................................................................................................................. 154 to 159 °C solid
mp .............................................................................................................................................................. 128 to 133 °C
25
Danger H228-H314 P210-P280-P305 + P351 + P338-P310
density ............................................................................................................................................. 1.035 g/mL, 25 °C
2 A
235857-25G glass btl 25 g Danger H228 P210
235857-100G glass btl 100 g
 ≥99.99% trace metals basis
Aluminum fluoride
Commonly used as a precursor to prepare alumina1,2,3
[7784‑18‑1] Merck 14,339 AlF3 FW 83.98 Lit. cited: 1. Mueller, A.; et al., MRS Bull. 40(12), 2153-2169 (2005)
density ................................................................................................................................................... 3.1 g/mL, 25 °C 2. Chandradass, J.; et al., Mater. Sci. Eng., A A408 (1-2), 165-168 (2005)
3. Chandradass, J.; et al., J. Mater. Proc. Tech. 173 (3), 275-280 (2006)
7
229407-10G poly btl 10 g
229407-50G poly btl 50 g
 anhydrous, powder, ≥99.9% trace metals basis
229407-250G poly btl 250 g
449628-50G glass btl 50 g  ≥98%
220418-100G glass btl 100 g
 reagent grade
332917-10G poly btl 10 g
332917-100G poly btl 100 g Aluminum L-lactate, 97%
Aluminum fluoride trihydrate, 97% L-Lactic
acid aluminum salt
Merck 14,348 [CH3CH(OH)COO]3Al FW 294.19
[15098‑87‑0] AlF3·3H2O FW 138.02
mp ............................................................................................................................................................................ >300 °C
density ................................................................................................................................................ 2.88 g/mL, 25 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
430633-100G glass btl 100 g

236098-100G poly btl 100 g
430633-500G glass btl 500 g
236098-500G poly btl 500 g
Aluminum metaphosphate
Aluminum hydroxide
[13776‑88‑0] Al(PO3)3 FW 263.90
[21645‑51‑2] Merck 14,342 Al(OH)3 FW 78.00
density ................................................................................................................................................ 2.78 g/mL, 25 °C
 reagent grade powder
composition
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Al2O3 50‑57%
may contain aluminum carbonate species 344915-500G poly btl 500 g
7
Warning H319 P305 + P351 + P338
Aluminum monostearate, ~75% (Al)
239186-25G poly btl 25 g Stearic acid aluminum dihydroxide salt
239186-500G poly btl 500 g [7047‑84‑9] Beil. 2,IV,1214 CH3(CH2)16COOAl(OH)2 FW 344.47
 technical, powder
Aluminum hydroxide hydrate 06270-1KG poly btl 1 kg
[1330‑44‑5] Al(OH)3 · xH2O FW 78.00 (Anh) Aluminum 2,3-naphthalocyanine chloride
7
Warning H319 P305 + P351 + P338
[33273‑14‑2] C48H24AlClN8 FW 775.19
N
A1577-1KG poly drum 1 kg
N N
> Aluminum 8-hydroxyquinolinate, see Tris-(8-hydroxyquinoline)aluminum N Al Cl N
Page 2574 N N
N
Aluminum iodide
[7784‑23‑8] Merck 14,346; Fieser 16,11; 15,10; 1,35; 12,30; 13,17 AlI3
FW 407.70
mp ........................................................................ 191 °C density .................................... 3.98 g/mL, 25 °C  Dye content: 80%
bp ......................................................................... 360 °C vp .............................................. 1 mmHg (178 °C)
λmax ............................................................................................................................................................................ 381 nm
57
Danger H314-H317-EUH014 P280-P305 + P351 + P338-P310
7
Warning H315-H319-H335 P261-P305 + P351 + P338
 anhydrous, powder, 99.999% trace metals basis 404497-500MG glass btl 500 mg
409324-1G ampule 1g
409324-5G ampule 5g
409324-25G ampule 25 g
 technical grade, 95%

chunks
208493-100G glass btl 100 g

AHB A, 0613, UNP EU
n Aluminumnickelc n
Aluminum-nickel catalyst Aluminum nitrate nonahydrate

[12635‑27‑7] Fieser 12,422; 1,723; 2,293; 6,502; 5,570; 7,312 AlNi [7784‑27‑2] Merck 14,352 Al(NO3)3 · 9H2O FW 375.13
FW 85.67 mp .................................................................................................................................................................................. 73 °C
density ................................................................................................................................................ 3.46 g/mL, 25 °C
37
Warning H272-H315-H319 P220-P305 + P351 + P338
Raney-type alloy for the preparation of Raney® Nickel catalyst. ,
composition  99.997%
Al-Ni 50:50 wt. % crystals and lumps
product of W.R. Grace and Co. Raney®
A 278 Danger H228-H317-H351 P210-P280
229415-10G
229415-100G
poly btl
poly btl
10 g
100 g
221651  ACS reagent, ≥98%

Aluminum nickel cobalt 98.0-102.0% (ACS specification)
insolubles ............................................................................................................................................................. ≤0.005%
AlNiCo chloride (Cl-) ............................................. ≤0.001% heavy metals (as Pb) ..................... ≤0.001%
 alloy 11, disc, 13 mm × 6 mm sulfate (SO42-) .......................................... ≤0.005% K ........................................................................ 0.002%
Ca ......................................................................... 0.005% Mg ................................................................... 0.001%
composition
Fe ..................................................................... ≤0.002% Na .................................................................... 0.005%
Aluminum 7.5‑8.7 wt. %
Cobalt 23.5‑25 wt. % 237973-100G poly btl 100 g
Copper 2‑3.5 wt. % 237973-500G poly btl 500 g
Iron 45.3‑52.85 wt. % 237973-2.5KG poly btl 2.5 kg
Nickel 12.5‑15.5 wt. %
Silicon 1.5 wt. % Aluminum nitride
Titanium 0.15‑0.5 wt. % [24304‑00‑5] Merck 14,353 AlN FW 40.99
Magnetic parameters/properties: mp ......................................................................................................................................................................... >2200 °C
• Maximum Energy Product (BH): 84 kJ/m3 (10.6 MGsOe) density ................................................................................................................................................ 3.26 g/mL, 25 °C
• Residual Induction (Br): 1.12 T (11.2 kGs)
57
Danger H314-H335 P261-P280-P305 + P351 + P338-P310
• Coercive Force (Hc): 109 kA/m (1.37 kOe)
692867-2EA rigd mailer 2 ea
 powder, 10 μm, ≥98%
 alloy 5, disc, 13 mm × 6 mm 241903-50G glass btl 50 g
composition 241903-250G glass btl 250 g
Aluminum 7.5‑8.7 wt. %
Cobalt 23.5‑25 wt. %  nanopowder, particle size <100 nm
Copper 2‑3.5 wt. % 593044-10G glass btl 10 g
Iron 45.3‑52.9 wt. % 593044-50G glass btl 50 g
Nickel 12.5‑15.5 wt. %
> Aluminum oxide, see Substrate, single crystal under Page 83
Silicon 1.5 wt. %
Titanium 0.15‑0.5 wt. % Aluminum oxide
Magnetic parameters/properties:
• Maximum Energy Product (BH): 40 kJ/m3 (5.0 MGsOe) [1344‑28‑1] Merck 14,356 Al2O3 FW 101.96
• Residual Induction (Br): 1.25 T (12.5 kGs) dispersion
• Coercive Force (Hc): 48 kA/m (0.60 kOe)  nanoparticles, particle size <50 nm (TEM), 20 wt. % in H2O
692875-3EA rigd mailer 3 ea No dispersant
density ................................................................................................................................................ 1.06 g/mL, 25 °C
 alloy 1, disc, 13 mm × 6 mm
composition
Aluminum 14.5 wt. %  nanoparticles, particle size <50 nm (DLS), 20 wt. % in 8
Cobalt >0.5 wt. % isopropanol
Iron (remainder) density .............................................................................................................................................. 0.79 g/cm3, 25 °C
Nickel 33.5 wt. % pH ........................................................................................................................................................................................ 8-10
Silicon 1.125 wt. %
27
Danger H225-H319-H336 P210-P261-P305 + P351 + P338
Titanium 0.45 wt. %
Magnetic parameters/properties: 702129-100G glass btl 100 g
• Maximum Energy Product (BH): 8.0 kJ/m3 (1.0 MGsOe) 702129-500G glass btl 500 g
• Residual Induction (Br): 0.43 T (4.3 kGs)
• Coercive Force (Hc): 58 kA/m (0.73 kOe)
692883-3EA rigd mailer 3 ea

AHB A, 0613, UNP EU
n Aluminumoxideet n
Aluminum oxide
Alumina
[1344‑28‑1] Merck 14,356; Fieser 4,8; 13,14; 1,19; 9,8; 2,17; 10,8; 6,16; 14,20; 16,9; 3,6; 11,22; 7,5; 8,9 Al2O3 FW 101.96
mp .................................................................................................................................................................................................................................................................................................................................................................................................... 2040 °C
Description Assay (%) pH In H2O Particle Size Pore Size (Å) Prod. No.
powder - 7.0 ±0.5 ~150 mesh 58 199974-5G
199974-100G
199974-1KG
199974-5KG
A
neutral, Brockmann I
activated
standard grade, CAMAG 507-C-I
powder - 9.5 ±0.5 ~150 mesh 58 199443-5G
199443-100G
199443-1KG
199443-5KG
basic, Brockmann I
activated
standard grade, CAMAG 5016-A-I
powder - 4.5 ±0.5 ~150 mesh 58 199966-100G
199966-1KG
199966-5KG
acidic, Brockmann I
activated
standard grade, CAMAG 504-C-I
powder - ~6.0 ~150 mesh 58 267740-250G
267740-1KG
267740-5KG
weakly acidic
calcined ≥99% - 100 - 325 mesh - 342718-100G
powder
primarily α-phase
calcined - - 150 - 325 mesh - 342726-100G
powder
primarily α-phase
- 99% - ~100 mesh - 234745-500G
234745-2.5KG
Corundum, α-phase
fused - - -325 mesh - 342688-100G
powder 342688-1KG
primarily α-phase
fused ≥99% - 100 - 200 mesh - 342653-100G
powder 342653-1KG
primarily α-phase
fused ≥99% - 200 - 325 mesh - 342661-1KG
primarily α-phase
nanopowder - - <50 nm (TEM) - 544833-10G
544833-50G
gamma phase
nanopowder 99.8% trace metals basis - 13 nm - 718475-100G
nanopowder - - - - 551643-10G
551643-50G
whiskers
pellets - - 3 mm - 414069-250G
414069-1KG
powder 99.998% trace metals basis - - - 202606-20G
202606-100G
powder 99.99% trace metals basis - - - 229423-25G
229423-100G
powder 99.9% - -100 mesh - 319767-25G
319767-100G
powder 99.7% trace metals basis - 10 μm - 265497-25G
265497-500G
265497-2.5KG
pieces 99.8% trace metals basis - ≤6 mm - 342750-50G
sintered 342750-250G
primarily α-phase
> Aluminum Oxide Etchant, see Ceramic Etchant A Page 633

AHB A, 0613, UNP EU
n Aluminumoxideme n
Aluminum oxide, mesoporous  Dye content: 85%

Alumina λmax ............................................................................................................................................................................ 698 nm
7
[1344‑28‑1] Merck 14,356 Al2O3 FW 101.96 Warning H315-H319-H335 P261-P305 + P351 + P338
molecular sieve
powder 446637-1G glass btl 1g
 MSU-X (wormhole), average pore size 3.8 nm Aluminum potassium sulfate dodecahydrate, ≥98%
particle size ........................................................................................................................................... 5.65 μm (avg.)
Potassium aluminum sulfate dodecahydrate; Alum; Potassium alum
A 517747-5G glass btl 5g [7784‑24‑9] AlK(SO4)2 · 12H2O FW 474.39
mp .................................................................................................................................................................................. 92 °C
 MSU-X (wormhole)
density ............................................................................................................................................. 1.757 g/mL, 25 °C
particle size .............................................................................................................................................. 4.4 μm (avg.)
pore size ................................................................................................................................................................... 6.5 nm  ACS reagent
517755-5G glass btl 5g 98.0-102.0% (ACS specification)
insolubles ............................................................................................................................................................. ≤0.005%
> Aluminum oxinate, see Tris-(8-hydroxyquinoline)aluminum Page 2574 chloride (Cl-) ............................................. ≤5 ppm Na .................................................................... ≤0.02%
Aluminum 2,4-pentanedionate, see Aluminum acetylacetonate Page 79 Fe ..................................................................... ≤0.001% NH4+ ........................................................... ≤0.005%
heavy metals (as Pb) ......................... ≤0.001%
Aluminum perchlorate nonahydrate, 98%
[81029‑06‑3] Al(ClO4)3·9H2O FW 487.47 237086-100G poly btl 100 g
237086-500G poly btl 500 g
35
Danger H272-H314 P220-P280-P305 + P351 + P338-P310
237086-2.5KG poly btl 2.5 kg
208485-5G glass btl 5g Aluminum silicate, 82% SiO2 basis (based on calcined
208485-100G glass btl 100 g substance)
Aluminum phenoxide, 99.9% trace metals basis P 820 A; Aluminum sodium silicate
[1344‑00‑9]
[15086‑27‑8] Beil. 6,137 (C6H5O)3Al FW 306.29
mp ................................................................................................................................................................. 156 °C (dec.)  synthetic, 9.5% Al2O3 basis (based on calcined substance), 8%
Na2O basis (based on calcined substance)
5
Danger H314 P280-P305 + P351 + P338-P310
LOI .................................................................................................................................................................................... ≤18%
7
Aluminum phosphate 09772-250G poly btl 250 g

[7784‑30‑7] Merck 14,358 AlO4P FW 121.95
Aluminum silicate
Nonstoichiometric compound
density ................................................................................................................................................ 2.56 g/mL, 25 °C Mullite
[37287‑16‑4] 3Al2O3 · 2SiO2 FW 426.05
5
Danger H314 P280-P305 + P351 + P338-P310
 powder
 99.99% trace metals basis 520179-250G glass btl 250 g
crystals and lumps
> Aluminum silicate, see Drying pearls Orange (heavy metal free) Page 1180
255963-10G poly btl 10 g Kaolinite Page 1596
Aluminum sodium silicate, see Aluminum silicate Page 84
 reagent grade
powder Aluminum sulfate, 99.99% trace metals basis
341452-100G poly btl 100 g [10043‑01‑3] Merck 14,366 Al2(SO4)3 FW 342.15
341452-500G poly btl 500 g mp ................................................................................................................................................................ 770 °C (dec.)
density ................................................................................................................................................ 2.71 g/mL, 25 °C
Aluminum phosphate monobasic solution
powder and chunks
Aluminum dihydrogen phosphate; prim-Aluminum phosphate
57
Danger H315-H318-H335-H412 P261-P273-P280-P305 + P351
[13530‑50‑2] Al(H2PO4)3 FW 317.94 + P338
density ................................................................................................................................................... 1.5 g/mL, 20 °C 202614-5G poly btl 5g
 ~50% in H2O 202614-25G poly btl 25 g
06234-1L glass btl 1L 202614-100G poly btl 100 g
Aluminum phthalocyanine chloride Aluminum sulfate octadecahydrate, ≥98%

Chloro(29H,31H-phthalocyaninato)aluminum [7784‑31‑8] Merck 14,366 Al2(SO4)3 · 18H2O FW 666.43
[14154‑42‑8] C32H16AlClN8 FW 574.96  ACS reagent
mp ............................................................................................................................................................................ >300 °C 98.0-102.0% (ACS specification)
insolubles ................................................................................................................................................................ ≤0.01%
 Dye content: ~85%
chloride (Cl-) ............................................. ≤0.005% K ........................................................................ 0.005%
λmax ............................................................................................................................................................................. 680 nm
Ca ........................................................................... 0.01% Mg ................................................................... 0.002%
362530-1G glass btl 1g Fe ..................................................................... ≤0.002% Na ....................................................................... 0.02%
heavy metals (as Pb) ......................... ≤0.001%
Aluminum phthalocyanine hydroxide
5
Danger H318 P280-P305 + P351 + P338
Hydroxy(29H,31H-phthalocyaninato)aluminum
[15554‑15‑1] C32H17AlN8O FW 556.51 N
227617-100G poly btl 100 g
N N
227617-500G poly btl 500 g
N Al OH N
N N
227617-2.5KG poly btl 2.5 kg
mp ............................................................................................................................................................................ >300 °C

AHB A, 0613, UNP EU
n Amanolipase n
Aluminum sulfate hydrate Aluminum-tri-sec-butoxide

[17927‑65‑0] Merck 14,366 Al2(SO4)3 · xH2O FW 342.15 (Anh) Aluminum sec-butoxide
density ................................................................................................................................................ 1.69 g/mL, 25 °C [2269‑22‑9] Beil. 1,372 Al[OCH(CH3)C2H5]3 FW 246.32
5
Danger H318 P280-P305 + P351 + P338 Features and Benefits
Has been utilized in making high-surface-area alumina using 2,4-
 99.998% trace metals basis pentanedione (Aldrich product P775-4) as a chelating agent.1
powder and chunks liquid
A
bp .................................... 200-206 °C/30 mmHg ait ......................................................................... 763 °F
density ..................................... 0.967 g/mL, 25 °C
 98% Lit. cited: 1. Ji, L. et al., Chem. Mater. 12, 931 (2000)
composition
26
Danger H226-H302-H311 P280-P312
Degree of hydration 14‑18
368458-500G poly btl 500 g  99.99% trace metals basis
368458-2.5KG poly btl 2.5 kg 511609-5G glass btl 5g
Aluminum sulfide, 98%  97%
[1302‑81‑4] Merck 14,367 Al2S3 FW 150.16 201073-100G glass btl 100 g
density ................................................................................................................................................ 2.02 g/mL, 25 °C 201073-500G glass btl 500 g
 granular, −4 mesh Aluminum tri-sec-butoxide solution
Al[OCH(CH3)C2H5]3 FW 246.32
> Aluminum terephthalate, see Basolite® A100 Page 222
 1.0 M in methylene chloride
Aluminum tetrakis-(4-chlorophenyl)porphine bis-tetrahydro- solution
furan tetracarbonylcobaltate bp .................................................................................................................................................................................... 40 °C
density ............................................................................................................................................. 1.237 g/mL, 25 °C
[C44H24AlCl4N4 · 2C4H80] [CO(CO)4] FW 1092.67
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> Aluminum triflate, see Aluminum trifluoromethanesulfonate Page 85
681474
Aluminum trifluoromethanesulfonate, 99.9% trace metals basis
Aluminum 1,8,15,22-tetrakis(phenylthio)-29H,31H-phthalo-
cyanine chloride Aluminum triflate
[74974‑61‑1] (CF3SO3)3Al FW 474.19
[167093‑23‑4] C56H32AlClN8S4 FW 1007.60
mp ............................................................................................................................................................................... 300 °C
mp ............................................................................................................................................................................ >300 °C
5
Danger H314 P280-P305 + P351 + P338-P310
λmax ............................................................................................................................................................................. 759 nm 515884-10G glass btl 10 g
7
Warning H315-H319-H335 P261-P305 + P351 + P338 515884-50G glass btl 50 g
418269-500MG glass btl 500 mg Aluminum tris(2,2,6,6-tetramethyl-3,5-heptanedionate), 98%

Al(TMHD)3
Aluminum titanate
[14319‑08‑5] Al(OCC(CH3)3CHCOC(CH3)3)3 FW 576.78
Aluminum titanium oxide solid
[12004‑39‑6] Al2O3·TiO2 FW 181.83 mp .............................................................................................................................................................. 264 to 267 °C
Features and Benefits 397288-5G glass btl 5g
Used as a barrier material on β-silicon nitride.1
Lit. cited: 1. Karunaratne, B.S.B.; Lewis, M.H., J. Eur. Ceram. Soc. 10, 1133 > Alum lake of carminic acid, see Carmine Page 626
(1996)
Alverine citrate salt
7
Warning H335
O OH
CH3 O O
 nanopowder, particle size <25 nm (BET), 98.5% trace metals basis
N • HO OH
634131-20G glass btl 20 g OH
634131-100G glass btl 100 g

N-Ethyl-3,3′-diphenyldipropylamine
 powder [5560‑59‑8] Merck 14,371 C20H27N · C6H8O7 FW 473.56
520209-250G glass btl 250 g A0424-5G poly btl 5g
> Aluminum titanium oxide, see Aluminum titanate Page 85 > (R,R)-AMAC, see (1R,2R)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesity-
lethylenediaminato cobalt(II) Page 291
Aluminum tributoxide, 95% (S,S)-AMAC, see (1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesity-
lethylenediaminato cobalt(II) Page 291
Aluminum butoxide
[3085‑30‑1] Al(O(CH2)3CH3)3 FW 246.32 Amano Acylase
mp .............................................................................................................................................................. 103 to 110 °C activity: ≥30,000 U/g, pH 8.0, 50 °C (Optimum pH and temperature)
solid 534862-10G glass btl 10 g
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Amano Lipase from Pseudomonas fluorescens
403350-5G glass btl 5g [9001‑62‑1] Merck 14,5511
activity: ≥20,000 U/g, pH 8.0, 55 °C (Optimum pH and temperature)

AHB A, 0613, UNP EU
n Amanolipase n
Amano Lipase A from Aspergillus niger  Poly(styrene-co-divinylbenzene) with quaternary amine

[9001‑62‑1] Merck 14,5511 functionality, chloride form
activity: ≥12,000 U/g, pH 6.5, 45 °C (Optimum pH and temperature) chloride form, beads
Ion exchange resin (strongly basic anion exchanger)
activity: 3.5-4.5 mmol Cl-/g
Amano Lipase G from Penicillium camemberti 1% cross-linked
activity: ≥50,000 U/g, pH 5.0, 45 °C (Optimum pH and temperature) total impurities ................................................................................................................................................... 50-60%
A
534838-10G glass btl 10 g 517976-100G poly btl 100 g
Amano Lipase M from Mucor javanicus  Poly(styrene-co-divinylbenzene), quaternary amine functionality,

chloride form
[9001‑62‑1] Merck 14,5511
chloride form
activity: ≥10,000 U/g, pH 7.0, 40 °C (Optimum pH and temperature)
total impurities ........................................................................................................................................................... 50%
436747-250G poly btl 250 g
Amano Lipase PS 8 Amberlite® IR120
 (immobilized on diatomite) [68441‑33‑8] Fieser 5,355; 1,511; 4,266; 6,302; 9,256
708011-10G poly btl 10 g 8% cross-linked
matrix ................................................................................................................... styrene-divinylbenzene (gel)
Amano Lipase PS, from Burkholderiacepacia particle size ......................................... 16-50 mesh ait ......................................................................... 800 °F
vd ................................................................... >1 (vs air)
 activity: ≥30,000 U/g, pH 7.0, 50 °C (Optimum pH and
temperature)  Na+-form
534641-10G glass btl 10 g vp ......................................................................................................................................................... 17 mmHg (20 °C)
7
534641-50G glass btl 50 g Warning H319 P305 + P351 + P338
Amano lipase PS-IM (immobilized on diatomaceous 8

earth) 224359-250G poly btl 250 g
Amberlite® IRA-67
Amaranth
[65899‑87‑8]
Acid Red 27; FD & C Red Dye No. 2; Previously known as IRA-68.
O ONa
Azorubin S HO S
matrix .......................................................................................................................................................... Acrylic (gel)
O O
[915‑67‑3] Merck 14,375 moisture ...................................................................................................................................................................... ~60%
NaO S N N
C20H11N2Na3O10S3 FW 604.47 O
 free base
O Weakly basic gel, tertiary amine functionality
S
O capacity ...................................................................................................................................................... 1.6 meq/mL
ONa
exchange capacity ............................................................................................................................. 1.6 meq/mL
 Dye content: 85‑95% 476633-100G poly btl 100 g

7
Warning H315-H319-H335 P261-P305 + P351 + P338
Amberlite® IRA-400
[60177‑39‑1] Fieser 6,302; 2,267; 4,267; 1,511; 7,182
by wetted bed volume .................................................................................................................. 1.4 meq/mL
Amberjet® 1200 functional group ......................................................................................................... quaternary ammonium
cross-linkage ................................................................................................................................................................. 8%
[39389‑20‑3] moisture ...................................................................................................................................................................... ~45%
 hydrogen form operating pH ................................................. 0 - 14 max. temp. .................................................... 77 °C
particle size ......................................... 16-50 mesh max. temp. .................................................... 60 °C
Features and Benefits
Strongly acidic cation exchanger with sulfonic acid functionality,  chloride form
hydrogen form useful in water treatment.
total impurities ........................................................................................................................................................... 50%
Strongly basic gel-type resin, quaternary ammonium functionality.
7
Warning H319 P305 + P351 + P338
247669-100G poly btl 100 g
247669-500G poly btl 500 g
Amberlite® IRA-410
Amberjet® 4200 chloride form
[63181‑94‑2] Fieser 2,267; 1,511; 5,432; 4,267; 6,302; 7,182
[60177‑39‑1]
Strongly basic (type II) anion exchange resin for water conditioning,
Strongly basic (type I) anion exchange resin for water deminerali-
removing iodine ions, neutralization of solutions, capturing xanthan
zation; useful for removal of iron and zinc from hydrochloric acid, and
and xanthene dyes, etc.; better regeneration efficiency than type I
recovery of silver from photographic effluents.
base resin.
by wetted bed volume ............................................................................................................ ≥1.30 meq/mL
by dry weight ............................................................................................................................................ 3.4 meq/g
functional group ......................................................................................................... quaternary ammonium
moisture ................................................................................................................................................................. 49-55%
functional group ......................................................... benzyldimethyl(2-hydroxyethyl)ammonium
particle size ................................................................................................................................................ 425-850 μm
moisture ...................................................................................................................................................................... ~42%
max. temp. ................................................................................................................................................................ 60 °C
operating pH ................................................. 0 - 14 max. temp. .................................................... 40 °C
particle size ......................................... 20-50 mesh vd ................................................................ <1 (vs air)
max. temp. ........................................................ 77 °C ait ......................................................................... 800 °F

AHB A, 0613, UNP EU
n Amberlitexad7hp n
 chloride form Amberlite® IRP-69

vp ......................................................................................................................................................... 17 mmHg (20 °C) [55464‑99‑8]
7
Warning H315-H319 P305 + P351 + P338 ait .................................................................................................................................................................................... 800 °F
 100-500 mesh
216569-100G poly btl 100 g
216569-500G poly btl 500 g
Sulfonic acid functionality (strongly acidic), sodium form.
Amberlite® IRA743 exchange capacity ..................................................................................................................... 4.3 meq/g (dry)
[63181‑98‑6]
Borate-specific chelating resin for the removal of borate, boric acid,
274275-100G glass btl 100 g A
274275-500G glass btl 500 g
other boron species from water; highly selective so that salts,
including bases, do not interfere significantly. Amberlite® MB-20
weakly basic anion exchange resin  mixed bed ion exchange resin, regenerated
matrix ........................................................................................ styrene-divinylbenzene (macroreticular)
LOD ................................................................................................................................................................ ~60%, 110°C
functional group ......................................................................... N-methylglucamine (free base form)
particle size ................................................................................................................................................. 20-50 mesh
particle size ......................................... 20-50 mesh ait ...................................................................... ~800 °F
vd .................................................................... <1 (vs air) 74451-250G-F poly btl 250 g
74451-1KG-F poly btl 1 kg
 free base
vp ......................................................................................................................................................... 17 mmHg (20 °C)
Amberlite® XAD16
216445-250G poly btl 250 g [9003‑69‑4]
216445-1KG poly btl 1 kg Nonionic macroreticular resin that adsorbs and releases ionic species
through hydrophobic and polar interactions; usually used under
Amberlite® IRA-900 isocratic conditions.
[9050‑97‑9] CH3  20-60 mesh, mean pore size 100 Å, pore volume 1.82 mL/g
N CH3 Cl Hydrophobic polyaromatic resin
CH3 matrix ......................................................................................................................................... polystyrene, apolar
surface area ................................................................................................................................................... 800 m2/g
7
Warning H319 P305 + P351 + P338
moisture ....................................................................................................................................................................... ~60% XAD16-500G poly btl 500 g
operating pH ................................................. 0 - 14 max. temp. .................................................... 60 °C XAD16-1KG poly btl 1 kg
particle size ......................................... 16-50 mesh vd ................................................................ <1 (vs air)
max. temp. ........................................................ 77 °C ait ......................................................................... 800 °F Amberlite® XAD4
[37380‑42‑0]
 chloride form Nonionic macroreticular resin that adsorbs and releases ionic species
vp ......................................................................................................................................................... 17 mmHg (20 °C) through hydrophobic and polar interactions; usually used under
216585-500G poly btl 500 g isocratic conditions.
Two particle sizes are available:
> Amberlite® IRA-900 BH3CN form, see Cyanoborohydride on polymer support
Page 791 Mesh 20-60 are Cat. Nos. 20276, 10358, XAD4
Amberlite® IRA-900 Br3--form, see Bromine on polymer support Page 429 Mesh 20-50 is Cat. No. 06444
Amberlite® IRA 900 NaCO3--form, see Carbonate on polymer support matrix ............................................................................................................................... styrene-divinylbenzene
Page 616 surface area ............................................ 725 m2/g pore volume ................................... ~0.98 mL/g
density .............................. 1.02 g/mL (true wet) mean pore size ............................................. 40 Å
Amberlite® IRP-64 density ................................. 1.08 g/mL (skeletal) ait ......................................................................... 800 °F
Polyacrilex Resin
[80892‑32‑6]  20-60 mesh
Weakly acidic cation exchange resin for taste masking, drug Hydrophobic polyaromatic resin
stabilization, carrier for cationic drugs, controlled release formulations XAD4-500G poly btl 500 g
(such as a carrier for certain basic (cationic) drugs and related XAD4-1KG poly btl 1 kg
substances), etc.
Amberlite® XAD7HP
For Research Use Only.
Pharmaceutical Grade [37380‑43‑1]
Particle size: Nonionic macroreticular resin that adsorbs and releases ionic species
>750 μm 15.0 to 30.0 % through hydrophobic and polar interactions; usually used under
>1500 μm 1.0 % maximum. isocratic conditions.
Sodium content: 0.20 % max Two particle sizes are available:
Heavy metals: 10 ppm max. Mesh 20-60 is Cat. No. XAD7
Residual methacrylic acid: 200 ppm max. Mesh 20-50 is Cat. No. 06445
Loss on drying 5.0 % max. matrix .......................................................................................................................................................... acrylic ester
Dry, white powder. surface area ........................................ ~450 m2/g vd ................................................................ <1 (vs air)
by dry weight .......................................................................................................................................... ~10 meq/g surface area ................................................................... vp ............................................. 17 mmHg (20 °C)
matrix .............................................................................. methacrylic-divinylbenzene (macroreticular) pore volume .......................................... 1.14 mL/g ait ......................................................................... 800 °F
functional group ......................................................................................................................................... weak acid
particle size ........................................................................................................................................... 100-400 mesh
 20-60 mesh
Moderately polar acrylic resin
 hydrogen form XAD7-100G poly btl 100 g
7
Warning H319 XAD7-500G poly btl 500 g
XAD7-1KG poly btl 1 kg
274267-100G poly btl 100 g
274267-500G poly btl 500 g

AHB A, 0613, UNP EU
n Amberlyst n
Amberlyst® 15 hydrogen form  hydroxide form

[39389‑20‑3] Fieser 13,152; 5,355; 15,178; 6,302; 9,256 beads
Swelling (dry to solvent saturated, %): concentration .................................................................... 1 N in NaOH (Regenerant concentration)
hexane 10-15; toluene 10-15; ethylene dichloride 15-20; ethylene bed D ......................................................................................................................................................................... ≥24 in.
acetate 30-40; 95% ethylene alcohol 60-70; water 60-70. regenerant flow rate .............................................................................................................................. 1-4 bv/hr.
total impurities ......................................................................................................................... 45-65% (moisture)
by wetted bed volume .................................................................................................................. 1.8 meq/mL 542571-100G glass btl 100 g
A
operating pH ................................................. 0 - 14 max. temp. ................................................. 120 °C
particle size ......................................... 16-50 mesh > Amberlyst® A-26 Br--form, see Bromide, polymer-supported Page 429
7
Warning H319 P305 + P351 + P338 Amberlyst® 16 wet
[125004‑35‑5]
 dry, moisture ≤1.5%
vp ......................................................................................................................................................... 17 mmHg (20 °C)  hydrogen form, strongly acidic
especially for heterogeneous catalysis, with more resistance to
216380-25G poly btl 25 g
thermal degradation
216380-500G poly btl 500 g
LOD ................................................................................................................................................................ ~50%, 110°C
216380-2.5KG poly drum 2.5 kg particle size ....................................................................................................................................................... ~700 μm
 wet, moisture ~48% 86317-250G-F poly btl 250 g

216399-25G poly btl 25 g (−)-Ambroxide, 99%
216399-500G poly btl 500 g
1,5,5,9-Tetramethyl-13-oxatricyclo[8.3.0.04,9]tridecane H3C
216399-2.5KG poly btl 2.5 kg [6790‑58‑5] Beil. 17,IV,352 C16H28O FW 236.39 O
CH3
Amberlyst® 36
H3C H
[39389‑20‑3] CH3
density ................................................................................................................................................... 1.2 g/mL, 25 °C

mp ................................................................................................................................................................... 74 to 76 °C
Shrinkage:
D −29°, c = 1 in toluene
[α]20
Water to phenol: 45%
Water to dry: 54% 379220-5G glass btl 5g
contains 51-57% Moisture content (H+ form) > AMCA, see trans-4-(Aminomethyl)cyclohexanecarboxylic acid Page 140
composition AMCHA, see trans-4-(Aminomethyl)cyclohexanecarboxylic acid Page 140
water 55% AMEBA resin, see (4-Formyl-3-methoxyphenoxymethyl)polystyrene
Page 1365
exchange capacity ........................................................................................................................... >5.40 meq/g StratoSpheres™ PL-FMP resin Page 1365
exchange capacity ................................................................................................................................. >1.95 eq/L
surface area ......................................................................................................................................................... 33 m2/g L-Amethopterin hydrate, 98%
particle size ............. <0.425 mm (0.5% max) total pore volume .......................... 0.20 mL/g
particle size ... 0.600-0.850 mm (uniformity average pore diameter ......................... 240 Å N N NH2
CH3
coefficient: <1.6)
N N
particle size ............. >1.180 mm (4.0% max) N
O NH2
7
Warning H319 P305 + P351 + P338
H NH • xH2O
HO OH
436712-250G poly btl 250 g
436712-1KG poly btl 1 kg O O
Amberlyst® A21 L-Amethopterin hydrate; L-4-Amino-N10-methylpteroylglutamic acid

Fieser 8,263; 6,302; 7,182 hydrate; MTX hydrate; Methylaminopterin hydrate; 4-Amino-10-
by wetted bed volume .................................................................................................................. 1.3 meq/mL methylfolic acid hydrate; Antifolan hydrate; Methotrexate hydrate
moisture ........................................................................................................................................................................ 58% [133073‑73‑1] Merck 14,5985 C20H22N8O5 · xH2O FW 454.44 (Anh)
particle size ......................................... 20-50 mesh ait ......................................................................... 800 °F
vd .................................................................... <1 (vs air) Potent inhibitor of dihydrofolate reductase1 and agent for antitumor
studies.2,3 Use to inhibit dihydrofolate reductase in DHFR-based
 free base protein expression systems.
Features and Benefits Lit. cited: 1. Sasso, S.P., et al., Biochim. Biophys. Acta 1207, 74 (1994)
Weakly basic, macroreticular resin with alkyl amine functionality. 2. Huennekens, F.M., Adv. Enzyme Regul. 34, 397 (1994)
vp ......................................................................................................................................................... 17 mmHg (20 °C)
3. Nagy, A., et al., Proc. Natl. Acad. Sci. U. S. A. 90, 6373 (1993)
[α]25
D +17°, c = 1 in 0.05 M Na2CO3
68
Danger H301-H315-H319-H360 P201-P301 + P310-P305 +
216410-250G poly btl 250 g P351 + P338-P308 + P313
Amberlyst® A26 (±)Amethopterin hydrate, ≥95%
[39339‑85‑0] 10
DL-4-Amino-N -methylpteroylglutamic acid; MTX; 4-Amino-10-
by dry weight ............................................................................................................................................ 4.2 meq/g methylfolic acid; Methylaminopterin
by wetted bed volume ............................................................................................................... 0.95 meq/mL
C20H22N8O5 · xH2O FW 454.44 (Anh)
bulk density .................................................................................................................................................... 41 lb/cu.ft
matrix ........................................................................................ styrene-divinylbenzene (macroreticular)  powder
functional group ......................................................................................................... quaternary ammonium Amethopterin is a folic acid antagonist and potent anticancer agent.
moisture ........................................................................................................................................... ~69% (OH- form) solubility in H2O ............................................................................................................................................ insoluble
surface area ........................................... ~30 m2/g pore volume ...................................... 0.30 mL/g soluble in ................................................................................................................................................................... NaOH
particle size ......................................... 16-45 mesh mean pore size .......................................... 400 Å color ................................................................................................. yellow to yellow with an orange cast
particle size ...................................... 350-1200 μm max. temp. .................................................... 60 °C

AHB A, 0613, UNP EU
n Aminoacetopheno n
68
Danger H301-H315-H319-H360 P201-P301 + P310-P305 + 2′-Aminoacetanilide, 98%
P351 + P338-P308 + P313 store at: −20°C
[34801‑09‑7] CH3CONHC6H4NH2 FW 150.18
A7019-25MG poly btl 25 mg mp .............................................................................................................................................................. 133 to 137 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
AM-ex-OL™ 549606-5G glass btl 5g

4-Chloro-2-phenylquinazoline
A
Cl
[6484‑25‑9] Fieser 4,86 C14H9ClN2 FW 240.69 3′-Aminoacetanilide, 97%
N
N [102‑28‑3] Beil. 13,45 CH3CONHC6H4NH2 FW 150.18

mp ................................................................................................................................................................... 86 to 88 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 124 to 126 °C
> Amide C4, see Butyramide Page 597
Amidinobenzene hydrochloride, see Benzamidine hydrochloride hydrate
4′-Aminoacetanilide, 99%
Page 226 N-(4-Aminophenyl)acetamide; N-Acetyl-p-phenylenediamine
4-Amidinosarcosine-methyl-13C, see Creatinine-(methyl-13C) Page 784
4-Amidinosarcosine-d3 (methyl-d3), see Creatinine-(methyl-d3) Page 784 [122‑80‑5] Merck 14,411; Beil. 13,IV,137 CH3CONHC6H4NH2
FW 150.18
3-(Amidinothio)-1-propanesulfonic acid, 97% mp .............................................................................................................................................................. 164 to 167 °C
8
[21668‑81‑5] Beil. 4,IV,89 H2NC(=NH)S(CH2)3SO3H FW 198.26 Danger H317-H319-H334 P261-P280-P305 + P351 + P338-P342 +
P311
mp .............................................................................................................................................................. 254 to 256 °C
100528-100G glass btl 100 g
5
Danger H314 P280-P305 + P351 + P338-P310
> Aminoacetic acid, see Glycine Page 1396
Aminoacetonitrile
> Amidinothiourea, see 2-Imino-4-thiobiuret Page 1526
1-Amidino-1H-1,2,4-triazole hydrochloride, see 1H-1,2,4-Triazole-1-carboxa- Cyanomethylamine; Glycinonitrile
H 2N CN
midine hydrochloride Page 2462 [540‑61‑4] Merck 14,412 C2H4N2 FW 56.07
‘Amidol’, see 2,4-Diaminophenol dihydrochloride Page 866
store at: −20°C
78
Amido Naphthol Red G, see Acid Red 1 Page 47 Warning H302-H312-H332-H351 P280
Amidosulfonic acid, see Sulfamic acid Page 2345
AMIM-Cl, see 1-Allyl-3-methylimidazolium chloride Page 73
Aminoacetaldehyde diethyl acetal, 98% Aminoacetonitrile hydrogensulfate, 97%
2,2-Diethoxyethylamine Glycinonitrile bisulfate; Glycinonitrile hydrogensulfate; Aminoaceto-
[645‑36‑3] Beil. 4,IV,1918 NH2CH2CH(OC2H5)2 FW 133.19 nitrile bisulfate; Cyanomethylamine monosulfate
bp ............................................................... 162-163 °C n20
D .......................................................................... 1.417
[151‑63‑3] Merck 14,412; Beil. 4,III,1120 NH2CH2CN · H2SO4
density ..................................... 0.916 g/mL, 25 °C
FW 154.15
27
mp .............................................................................................................................................................. 120 to 125 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Aminoacetaldehyde dimethyl acetal, 99% 279994-100G glass btl 100 g
2,2-Dimethoxyethylamine 2′-Aminoacetophenone, 98%
[22483‑09‑6] Beil. 4,IV,1918 NH2CH2CH(OCH3)2 FW 105.14
bp ..................................... 135-139 °C/95 mmHg n20
2-Acetylaniline
D .......................................................................... 1.417
density ..................................... 0.965 g/mL, 25 °C [551‑93‑9] Beil. 14,IV,91 H2NC6H4COCH3 FW 135.16
bp ......................................... 85-90 °C/0.5 mmHg n20
D .......................................................................... 1.614
Used in an efficient 3-step synthesis of a bicyclic proline analog from density ..................................... 1.112 g/mL, 25 °C
1
L-ascorbic acid. Also used in a 3-component reaction catalyzed by
7
Warning H315-H319-H335 P261-P305 + P351 + P338
MgClO4 leading to α-aminophosphonates.2
Lit. cited: 1. Synthesis 3122 (2006)
2. J. Org. Chem. 72, 1263 (2007) A37804-5G glass btl 5g
25
Danger H226-H314 P280-P305 + P351 + P338-P310
2′-Aminoacetophenone hydrochloride, 95%
[25384‑14‑9] CH3COC6H4NH2 · HCl FW 171.62
mp .............................................................................................................................................................. 285 to 289 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Aminoacetamidine dihydrobromide, ≥80.0% (CE)
[69816‑37‑1] C2H7N3 · 2HBr FW 234.92 186228-5G glass btl 5g
NH
H 2N
NH2 • 2HBr
2-Aminoacetophenone hydrochloride, 99%
acetic acid ................................................................................................................................................................. ≤0.5% ω-Aminoacetophenone hydrochloride; Phenacylamine hydrochloride
TBME .............................................................................................................................................................................. ≤0.5%
[5468‑37‑1] Beil. 14,III,105 C6H5COCH2NH2 · HCl FW 171.62
toluene .................................................................................................................................................. ≤0.1% (H-NMR)
mp ................................................................................................................................................................ 194 °C (dec.)
mp .............................................................................................................................................................. 227 to 232 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> 2-(2-aminoacetamido)acetic acid-15N2, see Glycyl-glycine-15N2 Page 1398

AHB A, 0613, UNP EU
n Aminoacetopheno n
3′-Aminoacetophenone, 97% > (S)-3-Aminoadipic acid hydrochloride, see L-β-Homoglutamic acid hydro-
chloride Page 1451
3-Acetylaniline (S)-3-Aminoadipic acid 6-amide hydrochloride, see L-β-Homoglutamine
[99‑03‑6] Beil. 14,IV,96 H2NC6H4COCH3 FW 135.16 hydrochloride Page 1451
3-Amino-D-alanine monohydrochloride, see D-2,3-Diaminopropionic acid
mp .................................................................................................................................................................... 94 to 98 °C monohydrochloride Page 867
bp ....................................................................................................................................................................... 289-290 °C 3-Amino-L-alanine hydrochloride, see L-2,3-Diaminopropionic acid hydro-
chloride Page 867
7
Warning H302-H319 P305 + P351 + P338
2-Amino-3-(2-aminobenzoyl)propionic acid, see DL-Kynurenine Page 1598
S-(+)-2-Amino-5-[(aminoiminomethyl)amino]pentanoic acid monohydro-
A
139351-25G poly btl 25 g chloride, see L-Arginine monohydrochloride Page 198
2-Amino-4-(2-aminophenyl)-4-oxobutyric acid, see DL-Kynurenine
139351-100G poly btl 100 g Page 1598
4′-Aminoacetophenone, 99% 2-Amino-4-(4-aminophenyl)thiazole, 97% 8
4-Acetylaniline [3673‑53‑8] C9H9N3S FW 191.25 H2N
[99‑92‑3] Beil. 14,IV,100; Fieser 4,18 H2NC6H4COCH3 FW 135.16
mp .............................................................................................................................................................. 103 to 107 °C N
bp ................................................................................................................................................................................. 293 °C S NH2
7
mp .............................................................................................................................................................. 177 to 182 °C
6
A38002-25G glass btl 25 g Danger H301-H319 P301 + P310-P305 + P351 + P338
> 4-(Aminoacetyl)morpholine hydrochloride, see 2-Amino-1-(4-morpholinyl)
ethanone hydrochloride Page 147 2-Amino-4-tert-amylphenol, 97%
9-Aminoacridine hydrochloride monohydrate, 98% [91339‑74‑1] Beil. 13,III,1816 C2H5C(CH3)2C6H3(NH2)OH FW 179.26

mp .............................................................................................................................................................. 119 to 120 °C
[52417‑22‑8] Beil. 21,V,11,9 C13H10N2 · HCl · H2O NH2
7
Warning H315-H319-H335 P261-P305 + P351 + P338
FW 248.71
• HCl
N • H2O 412589-5G glass btl 5g
mp ................................................................................................................................................................................ 300 °C > 2-Aminoanisole, see o-Anisidine Page 191

Mutagen.1
λmax ............................................................................................................................................................................. 400 nm
1-Aminoanthracene, 90%
λmax .............................................................................................................................................................. 420 nm (2nd) 1-Anthramine NH2
Lit. cited: 1. Nature 253, 324 (1975) [610‑49‑1] Beil. 12,IV,3435 C14H11N FW 193.24
mp .............................................................................................................................................................. 114 to 118 °C
> 1-Aminoadamantane, see 1-Adamantylamine Page 57
 technical grade
3-Amino-1-adamantanol, 96%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[702‑82‑9] C10H17NO FW 167.25 OH
NH2 A38606-5G glass btl 5g
mp ................................................................................................................................................................. 265 °C (dec.)
2-Aminoanthracene, 96%
Employed in the synthesis of inhibitors with antihyperglycemic
properties.1 2-Anthramine NH2
Lit. cited: 1. J. Med. Chem. 46, 2774-2789 (2003) [613‑13‑8] Beil. 12,IV,3435 C14H11N FW 193.24
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 238 to 241 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
D-2-Aminoadipic acid A38800-1G glass btl 1g

(R)-2-Aminohexanedioic acid; D-Homoglutamic acid
[7620‑28‑2] Beil. 4,IV,3070 HO2C(CH2)3CH(NH2)CO2H FW 161.16
mp .............................................................................................................................................................. 208 to 210 °C 1-Aminoanthraquinone, 97%
Glutamine synthetase inhibitor. Less potent enatiomer; gliotoxic only [82‑45‑1] Merck 14,417; Beil. 14,IV,429 C14H9NO2 O NH2
on mitotic astrocytes. FW 223.23
L-2-Aminoadipic acid, ≥98% (TLC) O
Aad; (S)-2-Aminohexanedioic acid; L-Homoglutamic acid mp .............................................................................................................................................................. 253 to 255 °C

[1118‑90‑7] Beil. 4,IV,3070 HO2C(CH2)3CH(NH2)CO2H FW 161.16 A39009-100G glass btl 100 g
mp ............................................................................................................................................... 203 to 205 °C (dec.)
Glutamine synthetase inhibitor; gliotoxin.

AHB A, 0613, UNP EU
n Aminobenzamidox n
2-Aminoanthraquinone 2-Aminobenzaldehyde
[117‑79‑3] Beil. 14,IV,447 C14H9NO2 FW 223.23 [529‑23‑7] Beil. 14,IV,42 C7H7NO FW 121.14 O
mp ............................................................................................................................................... 292 to 295 °C (dec.)
H
 technical grade NH2
8
Warning H351 P281
Polymerizes rapidly at room temperature. May yield slightly hazy
165549-100G poly btl 100 g solution in ethanol due to the presence of a small amount of
165549-500G poly btl 500 g polymer.
A
7
Warning H315-H319-H335 P261-P305 + P351 + P338 ship: dry ice
4-Aminoantipyrine store at: −20°C
4-Amino-2,3-dimethyl-1-phenyl-3-pyrazolin-5-one; H2N CH3 A9628-100MG poly btl 100 mg
Ampyrone A9628-500MG poly btl 500 mg
N CH
[83‑07‑8] Merck 14,591; Beil. 25,IV,3554 C11H13N3O O N 3
FW 203.24
> 2-Aminobenzamide, see Anthranilamide Page 193
3-Aminobenzamide, 97%
mp .............................................................................................................................................................. 105 to 110 °C
3-AB; 3-ABA
 reagent grade [3544‑24‑9] Beil. 14,390 H2NC6H4CONH2 FW 136.15
Reagent for glucose determination in the presence of phenol and
mp .............................................................................................................................................................. 115 to 116 °C
peroxidase.
7
7
253014
A4382-25G poly btl 25 g 4-Aminobenzamide, 98%
A4382-50G poly btl 50 g [2835‑68‑9] Beil. 14,425 H2NC6H4CONH2 FW 136.15
A4382-100G poly btl 100 g mp .............................................................................................................................................................. 181 to 183 °C
7
Warning H302-H315-H319-H332 P305 + P351 + P338
3-Amino-3-azabicyclo[3.3.0]octane hydrochloride, 97%
[58108‑05‑7] C7H14N2 · HCl FW 162.66
N NH2 • HCl 284572-100G glass btl 100 g
3-Aminobenzamide oxime, 97% 8

mp .............................................................................................................................................................. 170 to 174 °C
[100524‑07‑0] C7H9N3O FW 151.17
7
Warning H315-H319-H335 P261-P305 + P351 + P338 OH
N
NH2
3-Amino-7-azaindazole, 97% 8 NH2
1H-Pyrazolo[3,4-b]pyridine-3-amine NH2 mp .............................................................................................................................................................. 123 to 127 °C

[6752‑16‑5] C6H6N4 FW 134.14
6
N
N N P338
H
mp .............................................................................................................................................................. 187 to 192 °C
4-Aminobenzamide oxime, 97% 8
6
Danger H301 P301 + P310
4-Aminobenzamidoxime OH
N
729469-500MG glass btl 500 mg [277319‑62‑7] C7H9N3O FW 151.17
NH2
> 1-Amino-11-azido-3,6,9-trioxaundecane, see 11-Azido-3,6,9-trioxaundecan-
H2N
1-amine Page 214
mp .............................................................................................................................................................. 167 to 171 °C

4-Amino-1,1′-azobenzene-3,4′-disulfonic acid sodium salt
6
Danger H301-H317 P280-P301 + P310
2-Amino-5-([4-sulfophenyl]azo)benzenesulfonic acid; Acid Yellow 9
[2706‑28‑7] Beil. 16,II,219 RO3SC6H4N=NC6H3(NH2)SO3R, R = H or
Na FW 379.34
 Dye content: 95% 3-Aminobenzamidine dihydrochloride, 96%
λmax ............................................................................................................................................................................. 489 nm [37132‑68‑6] H2NC6H4C(=NH)NH2·2HCl FW 208.09
7
250309-100G glass btl 100 g
4-Aminobenzamidine dihydrochloride, 98%
> o-Aminoazotoluene, see Fast Garnet GBC base Page 1286
[2498‑50‑2] Beil. 14,IV,1159 H2NC6H4C(=NH)NH2·2HCl FW 208.09
mp ............................................................................................................................................................................ >300 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338

> 4-Aminobenzamidoxime, see 4-Aminobenzamide oxime Page 91

AHB A, 0613, UNP EU
n Aminobenzanilid n
4′-Aminobenzanilide, 95% 2-Aminobenzimidazole, 97%

[17625‑83‑1] Beil. 13,98 C6H5CONHC6H4NH2 FW 212.25 2-Benzimidazolamine N
mp .............................................................................................................................................................. 127 to 131 °C [934‑32‑7] Beil. 25,IV,2528 C7H7N3 FW 133.15 NH2
N
7
Warning H315-H319-H335 P261-P305 + P351 + P338 H
mp .............................................................................................................................................................. 226 to 230 °C

7
4-Aminobenzanilide, 95% P338
A [782‑45‑6] H2NC6H4CONHC6H5 FW 212.25 171778-5G

171778-25G
glass btl
poly btl
5g
25 g
mp .............................................................................................................................................................. 127 to 131 °C
7
Warning H315-H317-H319 P280-P305 + P351 + P338 6-Aminobenzimidazole, 95% 8
1H-1,3-Benzodiazol-6-amine; 3H-Benzoimidazol-5- N
ylamine
H2N N
> 4-Aminobenzenearsonic acid, see p-Arsanilic acid Page 199 [934‑22‑5] C7H7N3 FW 133.15 H
3-Aminobenzeneboronic acid, see 3-Aminophenylboronic acid monohy-
drate Page 154 mp .............................................................................................................................................................. 163 to 168 °C
3-Aminobenzeneboronic acid hemisulfate salt, see 3-Aminophenylboronic
7
acid hemisulfate salt Page 154 Warning H302-H319 P305 + P351 + P338
3-Aminobenzeneboronic acid hydrochloride, see 3-Aminophenylboronic
acid hydrochloride Page 154 725005-500MG glass btl 500 mg
4-Aminobenzenecarbothioamide, see 4-Aminothiobenzamide Page 169
5-Aminobenzene-1,3-dicarboxylic acid, see 5-Aminoisophthalic acid 6-Amino-3,4-benzocoumarin, 99%
Page 133
p-Aminobenzenesulfonamide, see Sulfanilamide Page 2346 [83527‑99‑5] C13H9NO2 FW 211.22
2-Aminobenzenesulfonamide, 98%
[3306‑62‑5] Beil. 14,682 H2NC6H4SO2NH2 FW 172.20 4′-Aminobenzo-15-crown-5, 97%
mp .............................................................................................................................................................. 155 to 157 °C (Benzo-15-crown-5)-4′-ylamine H2N
[60835‑71‑4] C14H21NO5 FW 283.32
7
Warning H319 P305 + P351 + P338 O O
O O
245887-5G glass btl 5g O
245887-25G poly btl 25 g
mp ................................................................................................................................................................... 76 to 78 °C
3-Aminobenzenesulfonamide, 98% 8
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[98‑18‑0] C6H8N2O2S FW 172.20 O
S NH2 393428-500MG glass btl 500 mg
O
4′-Aminobenzo-18-crown-6
NH2
(Benzo-18-crown-6)-4′-ylamine
O
mp .............................................................................................................................................................. 141 to 143 °C [68941‑06‑0] C16H25NO6 FW 327.37 O O
H2N O O
O
> 2-Aminobenzenesulfonic acid, see Aniline-2-sulfonic acid Page 190
3-Aminobenzenesulfonic acid, 97%  technical

Metanilic acid Derivative of 18-crown-6 which can be derivatized by alkylation or
[121‑47‑1] Merck 14,5927; Beil. 14,IV,2640 H2NC6H4SO3H acylation1,2,3,4
FW 173.19 water .............................................................................................................................................................................. ≤10%
mp ............................................................................................................................................................................ >300 °C Lit. cited: 1. R. Ungaro et al., J. Am. Chem. Soc. 98, 5198 (1976)
2. S. Shinkai et al., J. Am. Chem. Soc. 109, 4458 (1987)
7
3. E. Ozeki et al., J. Chem. Soc., Chem. Commun. 1353 (1988)
4. Bull. Chem. Soc. Jpn. 61, 4385 (1988)
165794-250G poly btl 250 g
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> 4-Aminobenzenesulfonic acid, see Sulfanilic acid Page 2346
3-Aminobenzenethiol, see 3-Aminothiophenol Page 169 06913-100MG glass btl 100 mg
2-Aminobenzhydrazide, 97%
[1904‑58‑1] H2NC6H4CONHNH2 FW 151.17 > 6-Amino-1,4-benzodioxan, see 1,4-Benzodioxan-6-amine Page 233
5-Amino-1,3-benzodioxole, see 3,4-(Methylenedioxy)aniline Page 1774
mp .............................................................................................................................................................. 121 to 125 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338 3-Aminobenzofuran-2-carboxamide, 97%
[54802‑10‑7] C9H8N2O2 FW 176.17 NH2
565490-50G glass btl 50 g NH2
O
O
mp .............................................................................................................................................................. 157 to 161 °C
6

> 2-Aminobenzoic acid, see Anthranilic acid Page 193

2-Aminobenzoic acid-13C6, see Anthranilic acid-ring-13C6 Page 193

AHB A, 0613, UNP EU
n Aminobenzothiaz n
3-Aminobenzoic acid, 98% 3-Aminobenzonitrile, 99%

[99‑05‑8] Merck 14,421; Beil. 14,IV,1092 H2NC6H4CO2H FW 137.14 3-Cyanoaniline
mp .............................................................................................................................................................. 178 to 180 °C [2237‑30‑1] Beil. 14,IV,1095 H2NC6H4CN FW 118.14
7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 mp ................................................................................................................................................................... 48 to 53 °C
7
Warning H302-H312-H317-H319-H332 P280-P305 + P351 + P338
127671-500G
4-Aminobenzoic acid
glass btl 500 g 164771-25G
4-Aminobenzonitrile, 98%
glass btl 25 g
A
Vitamin Bx; Vitamin H1; PABA 4-Cyanoaniline
[150‑13‑0] Merck 14,423; Beil. 14,IV,1126; Fieser 2,24 H2NC6H4CO2H [873‑74‑5] Beil. 14,IV,1158 H2NC6H4CN FW 118.14
FW 137.14 mp ................................................................................................................................................................... 83 to 85 °C
6
mp .............................................................................................................................................................. 187 to 189 °C Danger H301-H319 P301 + P310-P305 + P351 + P338
density ............................................................................................................................................. 1.374 g/mL, 25 °C
7
Warning H315-H317-H319-H335-H413 P261-P280-P305 + P351 + 147753-10G glass btl 10 g
P338
 ≥99%
2-Aminobenzophenone, 98%
store at: 2-8°C
2-Aminophenyl phenyl ketone; 2-Benzoylaniline
[2835‑77‑0] Beil. 14,IV,243 H2NC6H4C(O)C6H5 FW 197.23
mp .............................................................................................................................................................. 103 to 107 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
 purified by sublimation, ≥99%
429767-1G glass btl 1g A41208-5G glass btl 5g
429767-10G glass btl 10 g A41208-25G glass btl 25 g
 99% 3-Aminobenzophenone, 97%

100536-50G glass btl 50 g 3-Benzoylaniline
100536-250G glass btl 250 g [2835‑78‑1] Beil. 14,81 H2NC6H4C(O)C6H5 FW 197.23
100536-1KG poly drum 1 kg mp ................................................................................................................................................................... 81 to 84 °C
7
Warning H315-H319 P305 + P351 + P338
4-Aminobenzoic acid potassium salt, ≥99%
PABA 255254-5G glass btl 5g
[138‑84‑1] Merck 14,7606 C7H6NO2K FW 175.23
4-Aminobenzophenone
7
Warning H315-H319-H335 P261-P305 + P351 + P338
4-Aminophenyl phenyl ketone; 4-Benzoylaniline
A0254-100G poly btl 100 g [1137‑41‑3] Beil. 14,IV,248 H2NC6H4C(O)C6H5 FW 197.23
A0254-500G 500 g mp .............................................................................................................................................................. 121 to 124 °C
7
4-Aminobenzoic acid sodium salt, ≥99%
PABA A41402-10G glass btl 10 g
[555‑06‑6] C7H6NO2Na FW 159.12 A41402-25G glass btl 25 g
 powder 2-Aminobenzophenone-2′-carboxylic acid, 98%
color ............................................................................................................................................................................ yellow
[1147‑43‑9] H2NC6H4C(O)C6H4CO2H FW 241.24
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338

> 4-Aminobenzoic acid 2-diethylaminoethylamide, see Procainamide hydro-
chloride Page 2186 4-Amino-2,1,3-benzothiadiazole, 98%
4-Aminobenzoic acid 2-diethylaminoethyl ester, see Procaine hydrochloride
Page 2186 4-Aminopiazthiole NH2
[767‑64‑6] C6H5N3S FW 151.19 N
4-Aminobenzoic hydrazide, 95% S
N
[5351‑17‑7] Beil. 14,I,570 H2NC6H4C(O)NHNH2 FW 151.17
mp ................................................................................................................................................................... 67 to 69 °C
mp .............................................................................................................................................................. 225 to 227 °C
7
Warning H302
7
Warning H315-H319-H335 P261-P305 + P351 + P338

2-Aminobenzonitrile, 98%
2-Aminobenzothiazole, 97%
Anthranilonitrile; 2-Cyanoaniline
[1885‑29‑6] Beil. 14,IV,1013 H2NC6H4CN FW 118.14 2-Benzothiazolamine N
[136‑95‑8] Merck 14,424; Beil. 27,IV,4824 C7H6N2S NH2
mp .................................................................................................................................................................... 45 to 48 °C S
bp ....................................................................................................................................................................... 267-268 °C
FW 150.20
mp .............................................................................................................................................................. 126 to 129 °C
7
Warning H302-H312-H315-H317-H319-H332-H335 P261-P280-P305 +
P351 + P338
7
Warning H302-H319 P305 + P351 + P338
A89901-100G glass btl 100 g 108812-5G glass btl 5g
108812-100G poly btl 100 g

AHB A, 0613, UNP EU
n Aminobenzothiaz n
7
6-Aminobenzothiazole, 97% Warning H315-H319-H335 P261-P305 + P351 + P338
[533‑30‑2] Merck 14,425 C7H6N2S FW 150.20 N
H2N S 191396-25G glass btl 25 g
mp .................................................................................................................................................................... 87 to 91 °C 4-Aminobenzyl alcohol, 98%

4-(Hydroxymethyl)aniline
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[623‑04‑1] Beil. 13,IV,1771 H2NC6H4CH2OH FW 123.15
A 562440-1G glass btl 1g mp ................................................................................................................................................................... 60 to 65 °C
7
> 6-Amino-2-benzothiazolecarbonitrile, see 6-Amino-2-cyanobenzothiazole

6-Amino-2-benzothiazolethiol, see 6-Amino-2-mercaptobenzothiazole 191558-25G glass btl 25 g
Page 134
4-Aminobenzothioamide, see 4-Aminothiobenzamide Page 169 2-Aminobenzylamine, 98%
1-Aminobenzotriazole [4403‑69‑4] Beil. 13,165 H2NC6H4CH2NH2 FW 122.17
mp ................................................................................................................................................................... 58 to 61 °C
ABT; 1-Benzotriazolamine N
57
[1614‑12‑6] Beil. 26,1,435 C6H6N4 FW 134.14 N Danger H302-H314 P280-P305 + P351 + P338-P310
N
NH2
Suicide inhibitor of cytochrome P450 and chloroperoxidase.
mp .................................................................................................................................................................... 81 to 84 °C 3-Aminobenzylamine, 99% 8
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[4403‑70‑7] C7H10N2 FW 122.17
NH2

A3940-250MG glass btl 250 mg NH2
> 2-Aminobenzotrifluoride, see 2-(Trifluoromethyl)aniline Page 2503 mp ................................................................................................................................................................... 41 to 45 °C

3-Aminobenzotrifluoride, see 3-(Trifluoromethyl)aniline Page 2503
579
4-Aminobenzotrifluoride, see 4-(Trifluoromethyl)aniline Page 2503 Danger H302-H314-H411 P273-P280-P305 + P351 +
P338-P310
2-Aminobenzoxazole, ≥97.0% 8 721492-5G glass btl 5g
2-Benzoxazolamine; Benzooxazol-2-ylamine N 721492-25G glass btl 25 g
[4570‑41‑6] C7H6N2O FW 134.14 NH2
O 4-Aminobenzylamine, 99%
97.0-103.0% (NT) [4403‑71‑8] Beil. 13,174 H2NC6H4CH2NH2 FW 122.17
mp ........................................................................... 37 °C density ................................. 1.078 g/mL, 25 °C
≥97.0% (GC)
bp ........................................... 101 °C/0.05 mmHg n20 D ............................................................................. 1.61
7
5
Danger H314 P280-P305 + P351 + P338-P310
6-Amino-2-benzoxazolinone, 97% 8 368466-50G Sure/Seal™ 50 g
[22876‑17‑1] C7H6N2O2 FW 150.13 H > α-Aminobenzyl cyanide hydrochloride, see 2-Phenylglycinonitrile hydro-
N
chloride Page 2037
O
H2N O
2-Aminobenzyl cyanide, 97%
mp .............................................................................................................................................................. 204 to 209 °C 2-Aminophenylacetonitrile
7 [2973‑50‑4] Beil. 14,IV,1310 H2NC6H4CH2CN FW 132.16

Warning H302
mp ................................................................................................................................................................... 69 to 72 °C
6
P305 + P351 + P338-P311
N-(4-Aminobenzoyl)-L-glutamic acid diethyl ester, 97%
[13726‑52‑8] C2H5O2CCH2CH2CH(NHCOC6H4NH2)CO2C2H5
FW 322.36
221120-5G glass btl 5g 4-Aminobenzyl cyanide, 99%
> N-(4-Aminobenzoyl)glycine, see p-Aminohippuric acid Page 128 4-Aminophenylacetonitrile
[3544‑25‑0] Beil. 14,457 H2NC6H4CH2CN FW 132.16
2-Aminobenzyl alcohol, 98% mp ................................................................................................................................................................... 45 to 48 °C
bp ................................................................................................................................................................................. 312 °C
2-(Hydroxymethyl)aniline
7
[5344‑90‑1] Beil. 13,III,1615 H2NC6H4CH2OH FW 123.15 Warning H302-H312-H332 P280
mp .................................................................................................................................................................... 81 to 83 °C
bp ....................................................................................................................................................... 162 °C/15 mmHg A42050-10G glass btl 10 g
7
Warning H315-H319-H335 P261-P305 + P351 + P338 (S)-4-(4-Aminobenzyl)-2(1H)-oxazolidinone, 97%
(4S)-4-[(4-Aminophenyl)methyl]-2-oxazolidinone
122831-10G glass btl 10 g NH
[152305‑23‑2] C10H12N2O2 FW 192.21
122831-25G glass btl 25 g H2N O O
3-Aminobenzyl alcohol, 97% mp .............................................................................................................................................................. 107 to 111 °C
7
3-(Hydroxymethyl)aniline Warning H302-H315-H319-H335 P261-P305 + P351 + P338
[1877‑77‑6] Beil. 13,IV,1770 H2NC6H4CH2OH FW 123.15
mp .................................................................................................................................................................... 92 to 95 °C 658405-10G glass btl 10 g

AHB A, 0613, UNP EU
n Aminobinaphthal n
> (1R,2R)-1-Amino-2-benzyloxycyclohexane, see (1R,2R)-trans-2-Benzyloxycy- N-[4-(4-Aminobenzyl)phenyl]-5-norbornene-2,3-dicarboximide,
clohexylamine Page 267 99%
(1S,2S)-1-Amino-2-benzyloxycyclohexane, see (1S,2S)-trans-2-Benzyloxycy-
clohexylamine Page 267 [76079‑45‑3] C22H20N2O2 FW 344.41 O
(1R,2R)-1-Amino-2-benzyloxycyclopentane N NH2
(1R,2R)-trans-2-Benzyloxy-cyclopentylamine; (1R)- O
NH2
trans-2-(Phenylmethoxy)cyclopentanamine mp .............................................................................................................................................................. 191 to 193 °C
O
[181657‑56‑7] C12H17NO FW 191.27
7
A
57
Danger H302-H312-H314 P280-P305 + P351 + P338-P310 347620-1G glass btl 1g
 97%
≥96.5% (GC) 4-Aminobenzylphosphonic acid, ~95%
enantiomeric excess: ≥98.0% [5424‑27‑1] C7H10NO3P FW 187.13 O
store at: 2-8°C P OH
671533-1G glass btl 1g OH
H2 N
7
Warning H315-H319-H335 P261-P305 + P351 + P338
 ChiPros®, produced by BASF, 99% 8 store at: −20°C
≥98.5% (GC)
enantiomeric excess: ≥98.5%
726826-25G glass btl 25 g 4-Amino-1-benzylpiperidine, 98%
(1S,2S)-1-Amino-2-benzyloxycyclopentane [50541‑93‑0] Beil. 22,IV,3752 C12H18N2 FW 190.28 NH2
(1S,2S)-trans-2-Benzyloxycyclopentylamine; (1S)-trans-2-(Phenyl-
methoxy)cyclopentanamine N
[181657‑57‑8] C12H17NO FW 191.27
56
Danger H301-H311-H314 P280-P305 + P351 + P338-P310
density ............................................................................................................................................. 0.933 g/mL, 25 °C

 98% n20
D ...................................................................................................................................................................................... 1.543
≥97.5% (GC)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
enantiomeric excess: ≥98%
water ................................................................................................................................................................................. ≤5%
195812-100G glass btl 100 g
 ChiPros®, produced by BASF, ≥99% 8 > (R)-2-Amino-3-(benzylthio)-1-propanol, see S-Benzyl-L-cysteinol Page 254
≥99.0% (GC)
enantiomeric excess: ≥99.0% (2-Aminobenzyl)triphenylphosphonium bromide, 97%
726494-5G glass btl 5g [78133‑84‑3] H2NC6H4CH2P(C6H5)3Br FW 448.33
726494-25G glass btl 25 g mp ................................................................................................................................................................ 245 °C (dec.)
7
(R)-(+)-2-Amino-3-benzyloxy-1-propanol, 97% Warning H315-H319-H335 P261-P305 + P351 + P338
[58577‑87‑0] C6H5CH2OCH2CH(NH2)CH2OH FW 181.23

mp .................................................................................................................................................................... 34 to 37 °C
bp ................................................................................................................................................................................. 307 °C (cis)-3-Aminobicyclo[2.2.1]heptane-2-carboxylic acid hydro-
[α]20
D +4°, c = 1 in methylene chloride
chloride, ≥98.0% (TLC)
5
Danger H314 P280-P305 + P351 + P338-P310 (cis)-2-Amino-3-carboxybicyclo[2.2.1]heptane H 2N
O
hydrochloride
C8H13NO2 · HCl FW 191.66 OH • HCl
7
> (R)-2-Amino-3-benzyloxypropionic acid, see O-Benzyl-D-serine Page 275 Warning H302
(S)-2-Amino-3-benzyloxypropionic acid, see O-Benzyl-L-serine Page 275
2-Amino-3-benzyloxypyridine, 99%
[24016‑03‑3] C12H12N2O FW 200.24 (R)-(+)-2′-Amino-1,1′-binaphthalen-2-ol, 97% 8
O (R)-(+)-2-Amino-2′-hydroxy-1,1′-binaphthalene; (R)-
NOBIN
NH2
N NH2 [137848‑28‑3] C20H15NO FW 285.34
OH
mp .................................................................................................................................................................... 92 to 94 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
≥96.5% (HPLC)
144487-5G glass btl 5g enantiomeric excess: ≥98.0%
59
144487-25G glass btl 25 g Danger H318-H410 P273-P280-P305 + P351 + P338-P501
> D-(−)-α-Aminobenzylpenicillin, see Ampicillin Page 187

Ampicillin trihydrate Page 187 713708-100MG glass btl 100 mg
D-(−)-α-Aminobenzylpenicillin sodium salt, see Ampicillin sodium salt 713708-500MG glass btl 500 mg
Page 187

AHB A, 0613, UNP EU
n Aminobinaphthal n
(S)-(−)-2′-Amino-1,1′-binaphthalen-2-ol, 97% 8 (R)-(−)-3-Amino-1-Boc-piperidine, ≥98.0% (TLC)

(S)-(−)-2-Amino-2′-hydroxy-1,1′-binaphthalene; (S)-NOBIN (R)-1-Boc-3-piperidinamine; tert-Butyl (R)-3-amino-1-piper- NH2
[137848‑29‑4] C20H15NO FW 285.34 idinecarboxylate
≥96.5% (HPLC) [188111‑79‑7] C10H20N2O2 FW 200.28 N
Boc
59
Danger H318-H410 P273-P280-P305 + P351 + P338-P501 [α]D -28.5±2°, c = 1 in DMF
7
A 713694-100MG
713694-500MG
glass btl
glass btl
100 mg
500 mg 07858-1G-F poly btl 1g
2-Aminobiphenyl, 97% (S)-(+)-3-Amino-1-Boc-piperidine, ≥98.0% (TLC)

2-Phenylaniline; 2-Biphenylylamine (S)-1-Boc-3-piperidinamine; tert-Butyl (S)-3-amino-1-piperidine-
[90‑41‑5] Beil. 12,IV,3223 C6H5C6H4NH2 FW 169.22 carboxylate
mp ............................................................ 47 to 50 °C vd ................................................................ 5.8 (vs air) [625471‑18‑3] C10H20N2O2 FW 200.28
bp ......................................................................... 299 °C ait ......................................................................... 842 °F [α]D +28.5±2°, c = 1 in DMF
7
4-aminobiphenyl .................................................................................................................................................. <0.1% Warning H302-H315-H319-H335 P261-P305 + P351 + P338
78
Warning H302-H351-H412 P273-P281
4-Amino-1-Boc-piperidine, 97%
3-Aminobiphenyl, 97% 8 1-Boc-4-piperidinamine; tert-Butyl 4-amino-1-piperidine- NH2
[2243‑47‑2] C12H11N FW 169.22 NH2
carboxylate
[87120‑72‑7] C10H20N2O2 FW 200.28
N
Boc
mp .................................................................................................................................................................... 28 to 33 °C Employed in a microwave-assisted solid-phase synthesis of N-
7 substituted piperidines via direct annulation of primary amines with

resin-bound dimesylates.1
716448-1G glass btl 1g Lit. cited: 1. J. Comb. Chem. 8, 132 (2006)
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
4-Aminobiphenyl P338
4-Biphenylamine; 4-Biphenylylamine; 4-Phenylaniline 640042-1G glass btl 1g
[92‑67‑1] Merck 14,1235; Beil. 12,IV,3241 C6H5C6H4NH2 FW 169.22 640042-5G glass btl 5g
mp ............................................................ 52 to 54 °C ait ......................................................................... 842 °F
bp ............................................... 191 °C/15 mmHg > 4-Amino-1-Boc-piperidine-4-carboxylic acid, see 1-Boc-4-aminopiperidine-
4-carboxylic acid Page 378
Hepatic tumor initiator in experimental animal model.1
Lit. cited: 1. Dooley, KL.; Von Tungeln, LS. et al., Cancer Lett. 62(3), 205 2-Amino-4′-bromoacetophenone hydrochloride, 96%
(1992)
[5467‑72‑1] Beil. 14,III,127 BrC6H4COCH2NH2·HCl FW 250.52
78
Danger H302-H350 P201-P308 + P313
mp ................................................................................................................................................................ 285 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> 4′-Aminobiphenyl-3-carbonitrile, see 3-(4-Aminophenyl)benzonitrile
Page 153 3′-Amino-4′-bromoacetophenone, 97% 8
4′-Aminobiphenyl-4-carbonitrile, see 4-(4-Aminophenyl)benzonitrile
Page 154 1-(3-Amino-4-bromophenyl)ethanone; 5-Acetyl-2- O
bromoaniline CH3
2-Amino-4,5-bis(4-methoxyphenyl)furan-3-carbonitrile, 97% [37148‑51‑9] C8H8BrNO FW 214.06
Br
[94556‑80‑6] C19H16N2O3 FW 320.34 NH2
mp .............................................................................................................................................................. 114 to 118 °C
3-Amino-4-(Boc-amino)pyridine, 97% 8
7
3-Amino-4-[(N-tert-butoxycarbonyl)amino]pyridine; 4-N- Boc
HN 714437-5G glass btl 5g
Boc-3,4-diaminopyridine; (3-Aminopyridin-4-yl)-carbamic
NH2
acid tert-butyl ester
2-Amino-5-bromobenzenesulfonamide, 97%
[183311‑28‑6] C10H15N3O2 FW 209.25 N
[54734‑84‑8] C6H7BrN2O2S FW 251.10
mp .............................................................................................................................................................. 123 to 127 °C 682470 Full product information at Aldrich.com
7
Warning H302
2-Amino-4-bromobenzoic acid, 97%
702056-1G glass btl 1g [20776‑50‑5] (H2N)C6H3(Br)CO2H FW 216.03
mp .............................................................................................................................................................. 230 to 234 °C
6
Danger H301-H319 P301 + P310-P305 + P351 + P338


AHB A, 0613, UNP EU
n Aminobromobenzo n
2-Amino-5-bromobenzoic acid, 97% 2-Amino-5-bromobenzonitrile, 96%

5-Bromoanthranilic acid [39263‑32‑6] H2NC6H3(Br)CN FW 197.03
[5794‑88‑7] Merck 14,1405; Beil. 14,IV,1081 H2NC6H3(Br)CO2H mp ................................................................................................................................................................. 96 to 100 °C
FW 216.03
7
Warning H302-H312-H317-H319-H332 P280-P305 + P351 + P338
mp .............................................................................................................................................................. 213 to 215 °C
6
Danger H301-H315-H319-H335 P261-P301 + P310-P305 + P351 + 642827-1G glass btl 1g
P338 642827-5G glass btl 5g
260118-5G
260118-25G
glass btl
poly btl
5g
25 g
4-Amino-3-bromobenzonitrile, 97% A
[50397‑74‑5] H2NC6H3(Br)CN FW 197.03
3-Amino-2-bromobenzoic acid, 95% 8 mp .............................................................................................................................................................. 106 to 110 °C
7
[168899‑61‑4] C7H6BrNO2 FW 216.03 O Warning H302-H317-H319 P280-P305 + P351 + P338
OH
Br
NH2 642770-5G glass btl 5g
mp .............................................................................................................................................................. 153 to 158 °C

2-Amino-4′-bromobenzophenone, 95%
2-Aminophenyl (4-bromophenyl)methanone
6
Danger H301 P301 + P310 O NH2
[1140‑17‑6] C13H10BrNO FW 276.13
724920-500MG glass btl 500 mg Br
3-Amino-4-bromobenzoic acid, 97% mp .............................................................................................................................................................. 103 to 110 °C

[2840‑29‑1] C7H6BrNO2 FW 216.03
7
O Warning H317 P280
OH
Br
NH2
2-Amino-5-bromobenzothiazole, 97%
mp .............................................................................................................................................................. 226 to 230 °C [20358‑03‑6] C7H5BrN2S FW 229.10 Br N
6
Danger H301-H315-H319-H335 P261-P301 + P310-P305 + P351 + NH2
S
P338
7
686433-25G glass btl 25 g Warning H302-H315-H317-H319-H335 P261-P280-P305 + P351 +
P338
[42237‑85‑4] C7H6BrNO2 FW 216.03 O 647683-5G glass btl 5g
Br
OH
2-Amino-6-bromobenzothiazole, 97%
NH2 [15864‑32‑1] C7H5BrN2S FW 229.10 N
NH2
Br S
mp .............................................................................................................................................................. 217 to 221 °C
6
Danger H301 P301 + P310 mp .............................................................................................................................................................. 213 to 217 °C
7
Warning H302-H317-H319 P280-P305 + P351 + P338
4-Amino-3-bromobenzoic acid, 97% 538507-5G glass btl 5g
[6311‑37‑1] H2NC6H3(Br)CO2H FW 216.03
mp .............................................................................................................................................................. 211 to 215 °C 3-Amino-5-bromobenzotrifluoride, 97%
6
Danger H301-H315-H319-H335 P261-P301 + P310-P305 + P351 + [54962‑75‑3] H2NC6H3(Br)CF3 FW 240.02
P338 bp ............................................................... 220-223 °C n20
D .......................................................................... 1.528
7

[2840‑02‑0] C7H6BrNO2 FW 216.03 O 539813-25G glass btl 25 g
H2N
OH
2-Amino-3-(4-bromobenzoyl)thiophene, 97%
Br
[399043‑24‑4] C11H8BrNOS FW 282.16 O
mp .............................................................................................................................................................. 171 to 179 °C
6
S NH2 Br
P338
mp .............................................................................................................................................................. 180 to 184 °C
78
Danger H302-H315-H319-H334-H335 P261-P305 + P351 +
P338-P342 + P311

AHB A, 0613, UNP EU
n Aminobromobutyr n
7
(S)-(+)-2-Amino-4-bromobutyric acid hydrobromide, 97% Warning H302-H315-H319-H335 P261-P305 + P351 + P338
[15159‑65‑6] BrCH2CH2CH(NH2)CO2H · HBr FW 262.93
[α]20 722391-5G glass btl 5g
7 > 4-Amino-5-bromo-2-hydroxypyrimidine, see 5-Bromocytosine Page 452

Warning H315-H319-H335 P261-P305 + P351 + P338
2-Amino-5-bromo-3-iodopyridine, 97% 8
[381233‑96‑1] C5H4BrIN2 FW 298.91
A
Br I
> 2-Amino-3-bromo-5-chlorobenzotrifluoride, see 2-Bromo-4-chloro-6-
(trifluoromethyl)aniline Page 449
N NH2
6-Amino-3-bromo-4-chloropyrazolo[3,4-d]pyrimidine, 8
95% mp .............................................................................................................................................................. 112 to 113 °C
57
3-Bromo-4-chloro-1H-pyrazolo[3,4-d]pyrimidin-6- Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
Cl Br
amine P338
N
[1003298‑79‑0] C5H3BrClN5 FW 248.47 N 704032-1G glass btl 1g
H2N N N
H
8-Amino-5-bromoisoquinoline, 90%
mp .............................................................................................................................................................. 267 to 273 °C 5-Bromo-8-isoquinolineamine Br
6
Danger H301 P301 + P310 [90721‑35‑0] C9H7BrN2 FW 223.07
N
NH2
3-Amino-5-bromo-2-chloropyridine, 97% 8 mp .............................................................................................................................................................. 186 to 190 °C

[588729‑99‑1] C5H4BrClN2 FW 207.46
6
Br NH2 Danger H301-H319 P301 + P310-P305 + P351 + P338
N Cl
mp .............................................................................................................................................................. 128 to 132 °C
> 6-Amino-3-bromo-2,4-lutidine, see 2-Amino-5-bromo-4,6-dimethylpyridine
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 + Page 98
P338
2-Amino-5-bromo-3-methoxypyrazine, 95% 8
3-Bromo-5-methoxy-2-pyrazinamine Br N OCH3
> 1-Amino-4-bromo-9,10-dihydro-9,10-dioxo-2-anthracenesulfonic acid [5900‑13‑0] C5H6BrN3O FW 204.02
sodium salt, see Bromaminic acid sodium salt Page 428 N NH2
2-Amino-5-bromo-4,6-dimethylpyridine, 97% mp .............................................................................................................................................................. 135 to 140 °C
57
5-Bromo-4,6-dimethyl-2-pyridinamine; 6-Amino-3- CH3 Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
bromo-2,4-lutidine Br P338
[89856‑44‑0] C7H9BrN2 FW 201.06 732125-500MG glass btl 500 mg
H3C N NH2
2-Amino-5-bromo-3-(methylamino)pyrazine, 97%
mp .............................................................................................................................................................. 144 to 148 °C
5-Bromo-N3-methyl-pyrazine-2,3-diamine N NH2
57
Danger H302-H317-H318 P280-P305 + P351 + P338
[55635‑63‑7] C5H7BrN4 FW 203.04
Br N NHCH3
7
Warning H317 P280
2-Amino-7-bromofluorene, 90%
[6638‑60‑4] Beil. 12,II,780 C13H10BrN 696110-250MG glass btl 250 mg
FW 260.13 Br NH2 696110-1G glass btl 1g
1-Amino-4-bromo-2-methylanthraquinone, 99%
mp .............................................................................................................................................................. 148 to 149 °C
[81‑50‑5] Beil. 14,223 C15H10BrNO2 FW 316.15
7
Warning H315-H319-H335 P261-P305 + P351 + P338 O NH2
CH3

O Br
2-Amino-3-bromo-5-fluoropyridine, 97% 8
mp ................................................................................................................................................................ 245 °C (dec.)
[869557‑43‑7] C5H4BrFN2 FW 191.00 F Br
7
Warning H315-H319-H335 P261-P305 + P351 + P338
N NH2
mp .................................................................................................................................................................... 62 to 66 °C
2-Amino-3-bromo-5-methylbenzoic acid, 97%
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338 [13091‑43‑5] H2NC6H2(Br)(CH3)CO2H FW 230.06
7
3-Amino-5-bromo-2-fluoropyridine, 97% 8 631531-1G glass btl 1g

[884495‑22‑1] C5H4BrFN2 FW 191.00 Br NH2 631531-5G glass btl 5g
N F
mp .................................................................................................................................................................... 75 to 80 °C

AHB A, 0613, UNP EU
n Aminobromopheny n
7
5-Amino-4-bromo-3-methylisoxazole, 97% 8 Warning H315-H319-H335 P261-P305 + P351 + P338
4-Bromo-3-methylisoxazol-5-amine Br CH3
[33084‑49‑0] C4H5BrN2O FW 177.00
H2N N
O 2-Amino-5-bromo-4-methylpyrimidine, 97% 8
mp .................................................................................................................................................................... 66 to 71 °C [17321‑93‑6] C5H6BrN3 FW 188.03 CH3
7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 Br
N

N NH2
A
> 3-Amino-4-bromo-5-methylpyrazole hydrobromide, see 5-Amino-4-bromo- mp .............................................................................................................................................................. 196 to 200 °C
3-methylpyrazole hydrobromide Page 99
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
3-Amino-4-bromo-5-methyl-1H-pyrazole hydrobromide, see 5-Amino-4- P338
bromo-3-methylpyrazole hydrobromide Page 99
5-Amino-4-bromo-3-methylpyrazole hydrobromide 8
3-Amino-4-bromo-5-methylpyrazole hydrobromide; 1-Amino-4-bromonaphthalene, 97%
Br CH3
3-Amino-4-bromo-5-methyl-1H-pyrazole hydro- 4-Bromo-1-naphthylamine
N • HBr
bromide H2N N [2298‑07‑9] Beil. 12,1257 H2NC10H6Br FW 222.08
H
[167683‑86‑5] C4H6BrN3 · HBr FW 256.93 mp .............................................................................................................................................................. 102 to 103 °C
mp .............................................................................................................................................................. 166 to 180 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H302
732605-250MG glass btl 250 mg A43405-25G glass btl 25 g
5-Amino-4-bromo-3-methyl-1H-pyrazole, 97% 8 2-Amino-3-bromo-5-nitrobenzonitrile, 97%
[1780‑72‑9] C4H6BrN3 FW 176.01 Br CH3 [17601‑94‑4] H2NC6H2(Br)(NO2)CN FW 242.03
mp .............................................................................................................................................................. 180 to 185 °C
H2N N
7
N Warning H302-H312-H315-H319-H332-H335 P261-P280-P305 + P351
H
+ P338
mp .............................................................................................................................................................. 117 to 122 °C
7
Warning H302
717894-1G glass btl 1g 2-Amino-5-bromo-3-nitropyridine, 97%
2-Amino-3-bromo-5-methylpyridine, 98% [6945‑68‑2] Beil. 22,I,631 C5H4BrN3O2 FW 218.01 Br NO2
[17282‑00‑7] C6H7BrN2 FW 187.04 H3C Br N NH2
N NH2 mp .............................................................................................................................................................. 205 to 208 °C
7
mp .................................................................................................................................................................... 73 to 76 °C Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
543071-5G glass btl 5g 2-Amino-4-bromophenol
2-Amino-5-bromo-3-methylpyridine, 97% [40925‑68‑6] C6H6BrNO FW 188.02 OH
[3430‑21‑5] C6H7BrN2 FW 187.04 Br CH3 Br NH2
N NH2
mp .............................................................................................................................................................. 130 to 135 °C
78
mp .................................................................................................................................................................... 88 to 95 °C Danger H302-H315-H317-H319-H334-H335 P261-P280-P305
+ P351 + P338-P342 + P311
7
Warning H315-H319-H335 P261-P305 + P351 + P338
 ≥98.0% (HPLC)
2-Amino-5-bromo-4-methylpyridine, 98%
[98198‑48‑2] C6H7BrN2 FW 187.04 CH3 708356-5G glass btl 5g
Br
4-Amino-2-bromophenol, 97% 8
N NH2
[16750‑67‑7] C6H6BrNO FW 188.02 OH
mp .............................................................................................................................................................. 148 to 151 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338 H2N Br

≥96.5% (GCF)
shelf life (expiry date on the label)
7
Warning H302-H315-H319 P305 + P351 + P338
6-Amino-3-bromo-2-methylpyridine, 97% 727539-1G glass btl 1g

[42753‑71‑9] C6H7BrN2 FW 187.04 Br > 1-(3-Amino-4-bromophenyl)ethanone, see 3′-Amino-4′-bromoaceto-
phenone Page 96
H2N N CH3
mp .................................................................................................................................................................... 79 to 84 °C

AHB A, 0613, UNP EU
n Aminobromopheny n
3-Amino-5-(4-bromophenyl)isoxazole 3-Amino-3-(3-bromophenyl)propionic acid, 97%

5-(4-Bromophenyl)isoxazol-3-amine NH2 [117391‑50‑1] C9H10BrNO2 FW 244.09
C9H7BrN2O FW 239.07 573450-1G glass btl 1g
N
O
> 3-Amino-4-(4-bromophenyl)-2H-pyrazole, see 5-Amino-4-(4-bromophenyl)
Br pyrazole Page 100
mp .............................................................................................................................................................. 144 to 148 °C
5-Amino-3-(4-bromophenyl)pyrazole, 97%
A 6
Danger H301 P301 + P310
[78583‑82‑1] C9H8BrN3 FW 238.08 Br
5-Amino-4-(4-bromophenyl)isoxazole, 97% 8
N
H2N N
4-(4-Bromophenyl)-isoxazole-5-yl amine Br H
[925007‑32‑5] C9H7BrN2O FW 239.07
mp .............................................................................................................................................................. 172 to 176 °C
H2N N
57
O Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338
mp .............................................................................................................................................................. 143 to 147 °C
6
P338
708399-1G glass btl 1g 5-Amino-4-(4-bromophenyl)pyrazole, 97% 8
5-Amino-4-(4-bromophenyl)-3-methylisoxazole, 97% 3-Amino-4-(4-bromophenyl)-2H-pyrazole; 4-(4-Bromophenyl)-2H-
8
pyrazole-3-yl amine
4-(4-Bromophenyl)-3-methylisoxazole-5-yl amine Br [57999‑08‑3] C9H8BrN3 FW 238.08
[925007‑46‑1] C10H9BrN2O FW 253.10 CH3
mp .............................................................................................................................................................. 164 to 169 °C
57
H2N N Danger H302-H318 P280-P305 + P351 + P338
O
7
Warning H302
2-Amino-5-(4-bromophenyl)-1,3,4-thiadiazole, 97%
708402-1G glass btl 1g [13178‑12‑6] C8H6BrN3S FW 256.12 N N
S NH2
> 3-Amino-4-(4-bromophenyl)-2H-5-methylpyrazole, see 5-Amino-4-(4-
bromophenyl)-3-methylpyrazole Page 100 Br
5-Amino-4-(4-bromophenyl)-3-methylpyrazole, 96% 8 mp .............................................................................................................................................................. 228 to 232 °C

3-Amino-4-(4-bromophenyl)-2H-5-methylpyrazole;
7
Br Warning H315-H319-H335 P261-P305 + P351 + P338
4-(4-Bromophenyl)-5-methyl-2H-pyrazole-3-yl CH3
amine 576034-1G glass btl 1g
N
[955575‑53‑8] C10H10BrN3 FW 252.11 H2N N
H 2-Amino-4-(4-bromophenyl)thiazole, 97%
mp .............................................................................................................................................................. 133 to 138 °C [2103‑94‑8] C9H7BrN2S FW 255.13 Br
57
Danger H302-H318 P280-P305 + P351 + P338
N
S NH2
2-Amino-4-(4-bromophenyl)-5-methylthiazole, 97% 8
mp .............................................................................................................................................................. 183 to 187 °C
[65705‑44‑4] C10H9BrN2S FW 269.16 Br
7
Warning H315-H319-H335 P261-P305 + P351 + P338
N
H3C NH2 534129-5G glass btl 5g
S
2-Amino-6-bromopurine, 95%
mp .............................................................................................................................................................. 148 to 153 °C
[82499‑03‑4] Beil. 26,16,103 C5H4BrN5 FW 214.02
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 + Br
P338 N N
717851-1G glass btl 1g H2N N N

H
5-Amino-1-(4-bromophenyl)-3-phenyl-1H-pyrazole, 8
97% mp ............................................................................................................................................................................ >350 °C
[72411‑50‑8] C15H12BrN3 FW 314.18 475254-1G glass btl 1g

H2 N N > 6-Amino-8-bromopurine riboside, see 8-Bromoadenosine Page 432

N
2-Amino-5-bromopyrazine, 97%
[59489‑71‑3] C4H4BrN3 FW 174.00 Br N
Br
N NH2
mp .............................................................................................................................................................. 164 to 168 °C
5
Danger H318 P280-P305 + P351 + P338 mp .............................................................................................................................................................. 113 to 117 °C


AHB A, 0613, UNP EU
n Aminobromothiad n
Used without prior protection of the amino group in a palladium- 3-Amino-5-bromopyridine, 97%
catalyzed cross-coupling with pyridylboronic acids leading to [13535‑01‑8] C5H5BrN2 FW 173.01 Br NH2
pyrazinylpyridines.1
Lit. cited: 1. J. Org. Chem. 70, 388 (2005) N
57
Danger H302-H315-H317-H318 P280-P305 + P351 + P338
mp ................................................................................................................................................................... 65 to 69 °C
7
2-Amino-3-bromopyridine, 97%
[13534‑99‑1] C5H5BrN2 FW 173.01 Br
667129-1G
667129-10G
glass btl
glass btl
1g
10 g
A
N NH2
[13534‑97‑9] C5H5BrN2 FW 173.01 NH2
mp .................................................................................................................................................................... 63 to 67 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338 Br N
mp ................................................................................................................................................................... 74 to 76 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Amino-4-bromopyridine, 97% 8 552844-1G glass btl 1g
[84249‑14‑9] C5H5BrN2 FW 173.01 552844-5G glass btl 5g

Br
N NH2 2-Bromo-4-pyridinamine NH2
[7598‑35‑8] C5H5BrN2 FW 173.01
mp .............................................................................................................................................................. 142 to 146 °C
N Br
7
Warning H302-H319 P305 + P351 + P338
mp ................................................................................................................................................................... 92 to 96 °C
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
2-Amino-5-bromopyridine, 97% P338
[1072‑97‑5] Beil. 22,V,8,474 C5H5BrN2 FW 173.01 Br
N NH2 654086-25G glass btl 25 g
mp .............................................................................................................................................................. 133 to 138 °C 4-Amino-3-bromopyridine, 97%

Used in a synthesis of polycyclic azaarenes.1 3-Bromo-4-aminopyridine; 3-Bromo-4-pyridinamine NH2
Lit. cited: 1. Tetrahedron Lett. 48, 5039 (2007) [13534‑98‑0] C5H5BrN2 FW 173.01 Br
6
P338 N

57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338
[19798‑81‑3] C5H5BrN2 FW 173.01
Br N NH2
2-Amino-5-bromopyrimidine, 98%
mp .................................................................................................................................................................... 88 to 91 °C [7752‑82‑1] Beil. 25,IV,2125 C4H4BrN3 FW 174.00 Br
Used in the synthesis of anti-HIV agents.1 N
Employed in an efficient one-pot synthesis of 7-azaindoles.2 N NH2

Lit. cited: 1. Farmaco 58, 259-263 (2003)
2. Tetrahedron Lett. 46, 2283 (2005) mp .............................................................................................................................................................. 241 to 243 °C
7 79
Warning H315-H319-H335 P261-P305 + P351 + P338 Warning H302-H319-H400 P273-P305 + P351 + P338

3-Amino-2-bromopyridine, 97% 4-Amino-2-bromopyrimidine-5-carbonitrile, 95%

[39856‑58‑1] C5H5BrN2 FW 173.01 NH2
[94741‑70‑5] C5H3BrN4 FW 199.01
mp ................................................................................................................................................................ 254 °C (dec.)
7
N Br Warning H315-H319-H335 P261-P305 + P351 + P338
mp .................................................................................................................................................................... 76 to 80 °C
Used in a palladium-catalyzed synthesis of indole systems containing
fused medium- and large-ring heterocycles.1 2-Amino-5-bromo-1,3,4-thiadiazole, 97% 8
5-Bromo-[1,3,4]thiadiazol-2-ylamine
56
Danger H301-H315-H318-H335 P261-P280-P301 + P310-P305 N N
+ P351 + P338 [37566‑39‑5] C2H2BrN3S FW 180.03 NH2
Br S
mp ............................................................................................................................................... 178 to 182 °C (dec.)
7

AHB A, 0613, UNP EU
n Aminobromothiaz n
2-Amino-5-bromothiazole monohydrobromide, 97% (R)-(−)-2-Amino-1-butanol, 98%

[61296‑22‑8] C3H3BrN2S · HBr FW 259.95 N [5856‑63‑3] Beil. 4,291; 4,IV,1705 C2H5CH(NH2)CH2OH FW 89.14
mp .......................................................................... −2 °C density ................................. 0.943 g/mL, 20 °C
Br S NH2 • HBr
bp ............................................................... 172-174 °C
mp ................................................................................................................................................................. 165 °C (dec.) D −10°, neat

[α]19
ee (GLC): 96%
7
Warning H302-H319 P305 + P351 + P338
n20
D ...................................................................................................................................................................................... 1.452
A 128023-5G
128023-25G
glass btl
glass btl
5g
25 g 57
Danger H302-H314 P280-P305 + P351 + P338-P310

> 2-Amino-5-bromotoluene, see 4-Bromo-2-methylaniline Page 490
2-Amino-5-bromo-4-(trifluoromethyl)pyridine, 95% 8 (S)-(+)-2-Amino-1-butanol, ≥98%
C6H4BrF3N2 FW 241.01 [5856‑62‑2] Beil. 4,IV,1705 C2H5CH(NH2)CH2OH FW 89.14
CF3
bp ............................................................... 172-174 °C n20
D ....................................................................... 1.4521
Br
density ..................................... 0.944 g/mL, 25 °C
N NH2 [α]20
D +10°, neat
ee (GLC): 96%
mp .................................................................................................................................................................... 66 to 75 °C
57
Danger H302-H314 P280-P305 + P351 + P338-P310
7
Warning H302-H319 P305 + P351 + P338

(R)-(–)-2-Aminobutanamide hydrochloride, 97%
2-Amino-1-butanol-1,1-d2, 97% (CP) 8
(R)-2-Aminobutyramide hydrochloride
[103765‑03‑3] CH3CH2CH(NH2)CONH2 · HCl FW 138.60 C2H5CH(NH2)CD2OH FW 91.15
mp ................................................................................................................................................................................... -2 °C
mp .............................................................................................................................................................. 258 to 262 °C
bp ....................................................................................................................................................................... 172-174 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
 97 atom % D
679380-1G glass btl 1g mol wt 91.09, atom % calculation
density ............................................................................................................................................. 0.964 g/mL, 25 °C
(S)-(+)-2-Aminobutanamide hydrochloride, 97%
5
Danger H314 P280-P305 + P351 + P338-P310
(S)-2-Aminobutyramide hydrochloride
[7682‑20‑4] CH3CH2CH(NH2)CONH2 · HCl FW 138.60 716138
mp .............................................................................................................................................................. 259 to 263 °C
4-Amino-1-butanol, 98%
[α]22
D +24°, c = 1 in H2O
[13325‑10‑5] Beil. 4,IV,1711; 4,291 H2N(CH2)4OH FW 89.14
7
mp ............................................................ 16 to 18 °C density ................................. 0.967 g/mL, 25 °C
bp ......................................................................... 206 °C n20
D ....................................................................... ~1.462
5
Danger H314 P280-P305 + P351 + P338-P310
> 1-Aminobutane, see Butylamine Page 556
(S)-(−)-2-Aminobutane hydrochloride, see (S)-(−)-sec-Butylamine hydro-
chloride Page 557 178330-1G glass btl 1g
(±)-2-Aminobutane, see sec-Butylamine Page 556 178330-5G glass btl 5g
(2R,3R)-2-Amino-1,3-butanediol, see L-Threoninol Page 2434
> 3-Amino-2-butenenitrile, see 3-Aminocrotononitrile Page 111
3-Aminobutanoic acid, 97% 3-Amino-(tert-butoxycarbonyl)-L-alanine, see (N-Boc-β-amino)-Ala-OH
Page 370
(±)-3-Aminobutyric acid; DL-3-Aminobutyric acid Boc-Dap-OH Page 370
[541‑48‑0] Merck 14,429; Beil. 4,IV,2595 CH3CH(NH2)CH2COOH (S)-4-Amino-2-(tert-butoxycarbonylamino)butanoic acid, see Boc-Dab-OH
Page 386
FW 103.12 (S)-3-Amino-2-(tert-butoxycarbonylamino)propanoic acid, see (N-Boc-β-
mp ................................................................................................................................................................. 189 °C (dec.) amino)-Ala-OH Page 370
Boc-Dap-OH Page 370
7
Warning H315-H319-H335 P261-P305 + P351 + P338 3-Amino-4-[(N-tert-butoxycarbonyl)amino]pyridine, see 3-Amino-4-(Boc-
amino)pyridine Page 96
A44207-5G glass btl 5g 4-Amino-1-(tert-butoxycarbonyl)piperidine-4-carboxylic acid, see 1-Boc-4-
aminopiperidine-4-carboxylic acid Page 378
A44207-25G poly btl 25 g {3-[(4-Aminobutyl)-tert-butoxycarbonylamino]propyl}carbamic acid tert-
butyl ester, see N1,N4-Bis-Boc-spermidine Page 298
2-Amino-1-butanol, 97%
[96‑20‑8] Merck 14,427; Beil. 4,291 C2H5CH(NH2)CH2OH FW 89.14 N-(4-Aminobutyl)-N-ethylisoluminol, ≥90%
mp ............................................................................ -2 °C density .................................. 0.943 g/mL, 25 °C ABEI; 4-(N1-Ethyl-4-aminobutylamino) H 3C
bp ............................................................... 176-178 °C n20 D ....................................................................... 1.4510 O
phthalic hydrazide; 6-[N-(4-Aminobutyl)-
N
5
Danger H314 P280-P305 + P351 + P338-P310 N-ethylamino]-2,3-dihydro-1,4-phthal- H 2N NH
azinedione NH
A43804-100ML glass btl 100 mL [66612‑29‑1] C14H20N4O2 FW 276.33 O

mp .............................................................................................................................................................. 259 to 260 °C
store at: 2-8°C
A0156-10MG 10 mg
A0156-100MG 100 mg
> N-(4-Aminobutyl)guanidine sulfate salt, see Agmatine sulfate salt

Page 61

AHB A, 0613, UNP EU
n Aminobutyricaci n
3-Amino-5-tert-butylisoxazole, 97% 1-Amino-3-butyne, 98% 8

[55809‑36‑4] C7H12N2O FW 140.18 NH2 3-Butyn-1-amine; 3-Butynylamine; 4-Amino-1-butyne
HC NH2
H 3C [14044‑63‑4] C4H7N FW 69.11
H 3C N
O
CH3 bp ............................................................... 100-103 °C n20
D .......................................................................... 1.448
density ..................................... 0.844 g/mL, 25 °C
mp .............................................................................................................................................................. 110 to 114 °C
257
Danger H225-H302-H314 P210-P280-P305 + P351 +
Amination of aryl bromides catalyzed by Pd(dba)3 (Aldrich Catalog P338-P310
No. 328774) and Xantphos (Aldrich Catalog No. 526460).1
Lit. cited: 1. Synlett 2331 (2007)
A
> 4-Amino-1-butyne, see 1-Amino-3-butyne Page 103
7
4-Aminobutyraldehyde diethyl acetal, 90%

666580-25G glass btl 25 g 4,4-Diethoxybutylamine
[6346‑09‑4] Beil. 4,IV,1928 H2N(CH2)3CH(OC2H5)2 FW 161.24
1-(4-Aminobutyl)-4-(2-methoxyphenyl)piperazine, 8 bp ......................................................................... 196 °C n20
D .......................................................................... 1.428
97% density ..................................... 0.933 g/mL, 25 °C
4-[4-(2-Methoxyphenyl)-1-piperazinyl]butylamine
[21103‑33‑3] C15H25N3O FW 263.38
NH2  technical grade
N
7
Warning H315-H319-H335 P261-P305 + P351 + P338
N
OCH3 A44150-5G glass btl 5g
≥97.0% (HPLC)
> (R)-2-Aminobutyramide hydrochloride, see (R)-(–)-2-Aminobutanamide
5
Danger H314 P280-P305 + P351 + P338-P310 store at: 2-8°C hydrochloride Page 102
(S)-2-Aminobutyramide hydrochloride, see (S)-(+)-2-Aminobutanamide
728500-1G glass btl 1g hydrochloride Page 102
D-2-Aminobutyric acid, 99%
2-Amino-4-tert-butylphenol, 98% (R)-(−)-2-Aminobutyric acid
[1199‑46‑8] (CH3)3CC6H3(NH2)OH FW 165.23 [2623‑91‑8] Beil. 4,IV,2584 C2H5CH(NH2)CO2H FW 103.12
mp .............................................................................................................................................................. 160 to 163 °C mp ............................................................................................................................................................................ >300 °C
D −21 to −19°, c = 4 in H2O
[α]20
7
+ P338 ee (GLC): 99%
(S)-(+)-2-Amino-2-(4-tert-butylphenyl)ethanol, 97%
> (R)-(−)-2-Aminobutyric acid, see D-2-Aminobutyric acid Page 103
C12H19NO FW 193.29 NH2
OH
L-2-Aminobutyric acid, ≥99% (titration)
H3C
H3C L-α-Aminobutyricacid O
CH3 [1492‑24‑6] C4H9NO2 FW 103.12
H3C OH
NH2
mp .............................................................................................................................................................. 115 to 119 °C
578
Danger H315-H318-H334-H335 P261-P280-P305 +
7
Warning H317 P280
P351 + P338-P342 + P311
666130-250MG glass btl 250 mg A1879-1G glass btl 1g
3-Amino-5-tert-butylpyrazole 8 DL-2-Aminobutyric acid, 99%
5-Amino-3-tert-butyl-1H-pyrazole; 3-Amino-5-tert-butyl- NH2 [2835‑81‑6] Merck 14,428; Beil. 4,IV,2584 C2H5CH(NH2)CO2H
1H-pyrazole FW 103.12
N
[82560‑12‑1] C7H13N3 FW 139.20 t-Bu N mp ................................................................................................................................................................ 291 °C (dec.)
H
162663-25G poly btl 25 g
mp .................................................................................................................................................................... 77 to 83 °C
162663-100G poly btl 100 g
> (S)-3-Aminobutyric acid hydrochloride, see L-β-Homoalanine hydrochloride
> 3-Amino-5-tert-butyl-1H-pyrazole, see 3-Amino-5-tert-butylpyrazole Page 1450
Page 103
5-Amino-3-tert-butyl-1H-pyrazole, see 3-Amino-5-tert-butylpyrazole 4-Aminobutyric acid-15N
Page 103
GABA-15N
2-Amino-5-tert-butyl-1,3,4-thiadiazole, 97% H215N(CH2)3CO2H FW 104.11
[39222‑73‑6] C6H11N3S FW 157.24 mp ................................................................................................................................................................ 195 °C (dec.)
N N
H 3C
H 3C S NH2  98 atom % 15N
CH3 mol wt 104.10, atom % calculation
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 183 to 187 °C
7
Warning H302-H332 609277-500MG glass btl 500 mg
AHB A, 0613, UNP EU
n Aminobutyricaci n
4-Aminobutyric acid-2,2-d2 Lit. cited: 1. Humphries, J.E., et al., Fibrinogenolytic and fibrinolytic activity
of cell-associated plasmin,. Arterioscler. Thromb. 13, 48-55 (1993)
GABA-d2
2. Krishnamurti, C., et al., Inhibitory effects of lysine analogues on t-PA
H2N(CH2)2CD2CO2H FW 105.13 induced whole blood clot lysis. Thromb. Res. 73, 419-430 (1994)
mp ................................................................................................................................................................. 195 °C (dec.)
 powder
 98 atom % D soluble in ......................................................................................................................................... H2O (50 mg/mL)
mol wt 105.09, atom % calculation color .............................................................................................................................................................................. white
A 7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338

4-Aminobutyric acid-2,2,3,3,4,4-d6 A2504-100G poly btl 100 g
GABA-d6
H2N(CD2)3CO2H FW 109.16
mp ................................................................................................................................................................. 195 °C (dec.)
 97 atom % D L-(−)-α-Amino-ε-caprolactam hydrochloride, ≥97.0% (AT)

mol wt 108.98, atom % calculation (S)-3-Amino-hexahydro-2-azepinone hydrochloride;
NH2
L-Lysine lactam hydrochloride
7
Warning H315-H319-H335 P261-P305 + P351 + P338 • HCl
[26081‑07‑2] C6H12N2O · HCl FW 164.63 N
H
O
615587-100MG 100 mg
D −27±2°, c = 1 in H2O
[α]20
α-Amino-γ-butyrolactone hydrobromide, 99%
enantiomeric ratio (HPLC): ≥99:1
(±)-α-Amino-γ-butyrolactone hydrobromide; DL-Homo- NH2 store at: 2-8°C
serine lactone hydrobromide • HBr 21612-1G poly btl 1g
[6305‑38‑0] Beil. 18,I,568 C4H7NO2 · HBr FW 182.02 O O
mp .............................................................................................................................................................. 220 to 225 °C
DL-α-Amino-ε-caprolactam hydrochloride, ≥99.0%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
DL-Lysinelactam hydrochloride; (±)-3-Aminohexa-
NH2
hydro-2H-azepin-2-one hydrochloride; 3-Amino-2- • HCl
oxohexamethyleneimine hydrochloride N
H
O
(R)-(+)-α-Amino-γ-butyrolactone hydrochloride, 97% [29426‑64‑0] C6H12N2O · HCl FW 164.63
7
[104347‑13‑9] C4H7NO2 · HCl FW 137.56 NH2 store at: 2-8°C
• HCl
O 41336-1G-F poly tube 1g
O
> ω-Aminocaprylic acid, see 8-Aminooctanoic acid Page 151
mp .............................................................................................................................................................. 220 to 224 °C
[α]23
D +28°, c = 1 in H2O DL-2-Aminocaprylic acid, 99%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
DL-2-Aminooctanoic acid
[644‑90‑6] Beil. 4,461 CH3(CH2)5CH(NH2)CO2H FW 159.23
mp ................................................................................................................................................................ 260 °C (dec.)
(S)-(−)-α-Amino-γ-butyrolactone hydrobromide, 99%
> 3-Amino-4-carbethoxypyrazole, see Ethyl 3-aminopyrazole-4-carboxylate
L-Homoserine lactone hydrobromide Page 1213
[15295‑77‑9] Beil. 18,IV,7829 C4H7NO2 · HBr FW 182.02
mp ................................................................................................................................................................. 225 °C (dec.)
1-(Aminocarbonyl)-1-cyclopropanecarboxylic acid, 97%
D −21°, c = 1 in H2O
[α]20 [6914‑74‑5] Beil. 9,II,512 H2NC(O)C3H4CO2H FW 129.11
471429-1G glass btl 1g mp ................................................................................................................................................................ 185 °C (dec.)
7
(S)-α-Amino-γ-butyrolactone hydrochloride, 97% 439517-1G glass btl 1g

HSI; L-Homoserine lactone hydrochloride NH2 439517-5G glass btl 5g
[2185‑03‑7] Beil. 18,V,11,314 C4H7NO2 · HCl • HCl
> 5-(Aminocarbonyl)-1H-indole, see 1H-Indole-5-carboxamide Page 1535
FW 137.56 O O
1-[(Aminocarbonyl)methyl]cyclohexaneacetic acid, see 1,1-Cyclohexanedi-
acetic acid monoamide Page 806
mp ............................................................................................................................................... 210 to 220 °C (dec.)
D −27.8°, c = 1 in H2O
[α]20 (+)-[[2Z-[2-[[(2S,3S)-2-[[(Aminocarbonyl)oxy]methyl]-4-oxo-1-
sulfo-3-azetidinyl]amino]-1-(2-amino-4-thiazolyl)-2-oxoethyl-
7
Warning H315-H319-H335 P261-P305 + P351 + P338
idene]amino]oxy]acetic acid disodium salt, 97%
459224-1G glass btl 1g [2S-[2α,3α(Z)]]-[[[2-[[2-[[(Aminocarbo- O
nyl)oxy]methyl]-4-oxo-1-sulfo-3-azeti- O
> (±)-α-Amino-γ-butyrolactone hydrobromide, see α-Amino-γ-butyrolactone O NaO N
hydrobromide Page 104 dinyl]amino]-1-(2-amino-4-thiozolyl)- H
N
(S)-2-Aminocaproic acid, see L-Norleucine Page 1941 2-oxoethylidene]amino]oxy]acetic H2N
O
O N
N O
acid disodium salt; (+)-(Z)-(((1-(2- NaO S O S NH2
6-Aminocaproic acid, ≥99% (titration) Amino-4-thiazolyl)-2-(((2S,3S)-2- O
EACA; 6-Aminohexanoic acid; ε-Aminocaproic acid (carbamoyl-oxymethyl)-4-oxo-1-

[60‑32‑2] Merck 14,432; Beil. 4,IV,2695 H2N(CH2)5CO2H FW 131.17 sulfonate-3-azetidinyl)amino)-2-oxo-
Lysine analog. Promotes rapid dissociation of plasmin, thereby ethylidene)amino)oxy)acetate
inhibiting the activation of plasminogen and subsequent fibri- disodium salt
nolysis.1,2 [86832‑68‑0] Merck 14,1871
mp ............................................................................................................................................... 207 to 209 °C (dec.)
C12H12N6Na2O10S2 FW 510.37

AHB A, 0613, UNP EU
n Aminochlorobenz n
[α]20
D +18°, c = 1 in H2O 2-Amino-4-chlorobenzenethiol, 96%
mp ................................................................................................................................................................. 250 °C (dec.) [1004‑00‑8] H2NC6H3(Cl)SH FW 159.64
7
Warning H315-H319-H335 P261-P305 + P351 + P338 mp ................................................................................................................................................................... 56 to 61 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> 1′-(Aminocarbonyl)-1,2,3,4,5-pentaphenyl-ferrocene, see 1′,2′,3′4′,5′-Penta- 541850-25G glass btl 25 g
phenylferrocene carboxamide Page 1996
3-Aminocarbonylphenylboronic acid 8
2-Amino-3-chlorobenzoic acid, 95% A
3-Chloroanthranilic acid
3-Carbamoylphenylboronic acid [6388‑47‑2] Beil. 14,IV,1071 H2NC6H3(Cl)CO2H FW 171.58
[351422‑73‑6] (H2NCO)C6H4B(OH)2 FW 164.95 mp .............................................................................................................................................................. 189 to 191 °C
mp .............................................................................................................................................................. 221 to 226 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H302
2-Amino-4-chlorobenzoic acid, 98%
4-Aminocarbonylphenylboronic acid
[89‑77‑0] Beil. 14,IV,1072 H2NC6H3(Cl)CO2H FW 171.58
4-Carbamoylphenylboronic acid mp .............................................................................................................................................................. 231 to 233 °C
[123088‑59‑5] (H2NCO)C6H4B(OH)2 FW 164.95
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 229 to 234 °C
7
Warning H302 A45467-25G poly btl 25 g
A45467-100G poly btl 100 g
2-Amino-5-chlorobenzoic acid
> (S)-2-(Aminocarbonyl)-1-pyrrolidinecarboxylic acid, 1,1-dimethylethyl
ester, see 1-Boc-L-prolinamide Page 410 [635‑21‑2] Beil. 14,IV,1075 H2NC6H3(Cl)CO2H FW 171.58
Aminocarbonylsulfamic acid, 3,3,3-trichloroethoxy ester, see N-(2,2,2- mp ............................................................................................................................................... 204 to 206 °C (dec.)
Trichloroethoxysulfonyl)urea Page 2476
7
(cis)-2-Amino-3-carboxybicyclo[2.2.1]heptane hydrochloride, see (cis)-3- Warning H315-H319-H335 P261-P305 + P351 + P338
Aminobicyclo[2.2.1]heptane-2-carboxylic acid hydrochloride Page 95
5-Amino-6-carboxy-2,4-dihydroxypyrimidine, see 5-Aminoorotic acid
Page 151  98%
2-Amino-3-O-(1-carboxyethyl)-2-deoxy-D-glucose, see Muramic acid A45475-10G glass btl 10 g
Page 1878
(S)-N-(5-Amino-1-carboxypentyl)iminodiacetic acid, see Nα,Nα-Bis(carboxy-  90%, technical grade
methyl)-L-lysine hydrate Page 303
378046-25G poly btl 25 g
7-Aminocephalosporanic acid, 98%
7-ACA
H2N H
S 6-Chloroanthranilic acid
[957‑68‑6] Merck 14,434 C10H12N2O5S
FW 272.28 N O CH3
[2148‑56‑3] Beil. 14,III,966 H2NC6H3(Cl)CO2H FW 171.58
O mp .............................................................................................................................................................. 158 to 160 °C
O
O OH
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp ............................................................................................................................................................................ >300 °C
[α]19
D +90°, c = 0.5 in KH2PO4/trace NaOH
8
Danger H317-H334 P261-P280-P342 + P311
[108679‑71‑6] H2NC6H3(Cl)CO2H FW 171.58
> 4-Amino-5-chloro-o-anisic acid, see 4-Amino-5-chloro-2-methoxybenzoic mp .............................................................................................................................................................. 154 to 160 °C
acid Page 107
7
Warning H315-H319-H335 P261-P305 + P351 + P338
4-Amino-6-chloro-1,3-benzenedisulfonamide, 98%
3-Chloroaniline-4,6-disulfonamide; 4-Amino-6-chlorobenzene-1,3-di-
sulfonamide 3-Amino-4-chlorobenzoic acid, ≥98.0% (T)
[121‑30‑2] Merck 14,2076; Beil. 14,IV,2810 H2NC6H2(Cl)(SO2NH2)2 [2840‑28‑0] Beil. 14,IV,1115 H2NC6H3(Cl)CO2H FW 171.58
FW 285.73 mp .............................................................................................................................................................. 214 to 215 °C
mp .............................................................................................................................................................. 257 to 261 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
86
Danger H373-H331-H311 P307+P311-P311-P280-P310
308560-100G glass btl 100 g 4-Amino-2-chlorobenzoic acid, 97%
> 4-Amino-6-chlorobenzene-1,3-disulfonamide, see 4-Amino-6-chloro-1,3-
benzenedisulfonamide Page 105 mp ................................................................................................................................................................ 211 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338

AHB A, 0613, UNP EU
n Aminochlorobenz n
4-Amino-3-chlorobenzoic acid, 97% 4-Amino-3-chlorobenzonitrile, 97%

[2486‑71‑7] C7H6ClNO2 FW 171.58 O [21803‑75‑8] H2NC6H3(Cl)CN FW 152.58
mp .............................................................................................................................................................. 102 to 105 °C
OH
7
Warning H315-H319-H335 P261-P305 + P351 + P338
H2N
Cl
A 7
2-Amino-5-chlorobenzophenone, 98%
691445-1G glass btl 1g 4-Chloro-2-benzoylaniline
691445-5G glass btl 5g [719‑59‑5] Beil. 14,III,214 H2NC6H3(Cl)COC6H5 FW 231.68
mp ................................................................................................................................................................... 96 to 98 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 184 to 188 °C A45564-25G poly btl 25 g
7
Warning H315-H319-H335 P261-P305 + P351 + P338 A45564-100G poly btl 100 g
A45564-500G poly btl 500 g
2-Amino-4-chlorobenzothiazole, 97%
2-Amino-4-chlorobenzonitrile, 99%
[19952‑47‑7] C7H5ClN2S FW 184.65 Cl
5-Chloro-2-cyanoaniline; 4-Chloroanthranilonitrile N
[38487‑86‑4] Beil. 14,III,954 H2NC6H3(Cl)CN FW 152.58 NH2
S
mp .............................................................................................................................................................. 157 to 162 °C
7
7
Warning H315-H319-H335 P261-P305 + P351 + P338
133434-25G poly btl 25 g
2-Amino-5-chlorobenzonitrile, 98%
5-Chloroanthranilonitrile 2-Amino-6-chlorobenzothiazole, 99%
[5922‑60‑1] H2NC6H3(Cl)CN FW 152.58 [95‑24‑9] Beil. 27,II,230 C7H5ClN2S FW 184.65 N
mp .................................................................................................................................................................... 96 to 99 °C NH2
Cl S
bp ........................................................................................................................................... 132-135 °C/0.5 mmHg
7
Warning H302-H312-H315-H319-H332-H335 P261-P280-P305 + P351 mp .............................................................................................................................................................. 199 to 201 °C
+ P338
7
2-Amino-6-chlorobenzonitrile, 96% 136085-5G glass btl 5g
[6575‑11‑7] C7H5ClN2 FW 152.58 CN > 2-Amino-5-chlorobenzotrifluoride, see 4-Chloro-2-(trifluoromethyl)aniline

Cl NH2
Page 746
3-Amino-4-chlorobenzotrifluoride, see 2-Chloro-5-(trifluoromethyl)aniline
Page 746
5-Amino-2-chlorobenzotrifluoride, see 4-Chloro-3-(trifluoromethyl)aniline
mp .............................................................................................................................................................. 134 to 136 °C Page 746
7
Warning H317-H319 P280-P305 + P351 + P338 2-Amino-5-chlorobenzoxazole, 97%
Zoxazolamine Cl
642843-1G glass btl 1g N
[61‑80‑3] Merck 14,10199 C7H5ClN2O NH2
642843-5G glass btl 5g O
FW 168.58
3-Amino-4-chlorobenzonitrile, 96% mp .............................................................................................................................................................. 181 to 184 °C
[53312‑79‑1] ClC6H3(NH2)CN FW 152.58
7
mp .................................................................................................................................................................... 87 to 91 °C + P338
7
Warning H302-H315-H317-H319-H335 P261-P280-P305 + P351 + A45807-1G glass btl 1g
P338 A45807-5G glass btl 5g
2-Amino-5-chlorobenzyl alcohol, 99%
4-Amino-2-chlorobenzonitrile, 99% [37585‑25‑4] H2NC6H3(Cl)CH2OH FW 157.60
3-Chloro-4-cyanoaniline mp .............................................................................................................................................................. 107 to 109 °C
[20925‑27‑3] H2NC6H3(Cl)CN FW 152.58
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 116 to 118 °C
7
Warning H317 P280 339539-5G glass btl 5g
5-Amino-2-chlorobenzyl alcohol, 97%

[89951‑56‑4] H2NC6H3(Cl)CH2OH FW 157.60
mp .............................................................................................................................................................. 119 to 123 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338


AHB A, 0613, UNP EU
n Aminochlorometh n
1-Amino-4-chloro-2-butyne hydrochloride, 90% 5-Amino-2-chloro-3-iodopyridine, 97% 8

[77369‑59‑6] C4H6ClN · HCl FW 140.01 2-Chloro-3-iodo-5-pyridinamine; 6-Chloro-5-iodo-3- H2 N I
mp .............................................................................................................................................................. 128 to 139 °C pyridinamine
[444902‑32‑3] C5H4ClIN2 FW 254.46 N Cl
79
mp .............................................................................................................................................................. 115 to 125 °C
579
Danger H302-H318-H400 P273-P280-P305 + P351 +
4-Amino-2-chloro-6,7-dimethoxyquinazoline, 95% P338
2-Chloro-6,7-dimethoxy-4-quinazolinamine NH2
A
[23680‑84‑4] Beil. 25,13,350 C10H10ClN3O2 H3CO 4-Amino-5-chloro-2-methoxybenzoic acid, 97%
N
FW 239.66
H3CO N Cl 4-Amino-5-chloro-o-anisic acid
[7206‑70‑4] H2NC6H2(Cl)(OCH3)CO2H FW 201.61
mp ............................................................................................................................................... 262 to 268 °C (dec.) mp ................................................................................................................................................................ 206 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338

4-Amino-5-chloro-2,6-dimethylpyrimidine, 96% 340871-25G glass btl 25 g
[2858‑20‑0] C6H8ClN3 FW 157.60 3-Amino-2-chloro-6-methoxypyridine, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338 [34392‑85‑3] C6H7ClN2O FW 158.59 NH2
391387-5G glass btl 5g H3CO N Cl

mp ................................................................................................................................................................... 46 to 50 °C
> 2-Amino-4′-chlorodiphenylamine, see N-(4-Chlorophenyl)-1,2-phenylenedi-
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
amine Page 729
P338
2-Amino-5-chloro-2′-fluorobenzophenone, 98% 681679-1G glass btl 1g
[784‑38‑3] H2NC6H3(Cl)C(O)C6H4F FW 249.67 2-Amino-4-chloro-6-methoxypyrimidine, 95%

mp .................................................................................................................................................................... 95 to 98 °C
[5734‑64‑5] Beil. 25,7 C5H6ClN3O FW 159.57 Cl
7
Warning H315-H319-H335 P261-P305 + P351 + P338
N
397210-25G glass btl 25 g H3CO N NH2
2-Amino-5-chloro-3-fluoropyridine, 97% 8 mp .............................................................................................................................................................. 168 to 171 °C
7
Warning H302
[246847‑98‑3] C5H4ClFN2 FW 146.55 Cl F
mp .................................................................................................................................................................... 91 to 95 °C 2-Amino-5-chloro-3-methylbenzoic acid, 97%

[20776‑67‑4] H2NC6H2(Cl)(CH3)CO2H FW 185.61
69
Danger H301-H311-H319-H331-H400 P261-P273-P280-P301 +
P310-P305 + P351 + P338-P311 mp .............................................................................................................................................................. 239 to 243 °C
7
714631-1G glass btl 1g Warning H317-H319 P280-P305 + P351 + P338
2-Amino-6-chloro-3-formylchromone, 97%
[68301‑77‑9] C10H6ClNO3 FW 223.61 643513-25G glass btl 25 g
7
Warning H315-H319-H335 P261-P305 + P351 + P338
3-Amino-6-(chloromethyl)-2-pyrazinecarbonitrile 4-oxide, 97%
402354-1G glass btl 1g [40127‑89‑7] C6H5ClN4O FW 184.58 O
N NH2
2-Amino-4-chloro-5-formyl-3-thiophenecarbonitrile, 8
90% Cl
N CN
2-Amino-3-cyano-4-chlorothiophene-5-carboxal- Cl CN
dehyde mp .............................................................................................................................................................. 144 to 146 °C
H
7
[104366‑23‑6] C6H3ClN2OS FW 186.62 S NH2 Warning H302-H312-H315-H319-H332-H335 P261-P280-P305 + P351
O + P338
mp .............................................................................................................................................................. 270 to 271 °C
56
Danger H301-H314-H317 P280-P305 + P351 + P338-P310 2-Amino-5-chloro-3-methylpyridine hemihydrate, 97%
C6H7ClN2 · 0.5H2O FW 151.59
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338
3-Amino-2-chloro-5-iodopyridine, 97% 8
2-Chloro-5-iodo-3-pyrimidine I NH2
[426463‑09‑4] C5H4ClIN2 FW 254.46
N Cl
mp .............................................................................................................................................................. 128 to 133 °C
57
Danger H302-H318 P280-P305 + P351 + P338
AHB A, 0613, UNP EU
n Aminochlorometh n
7
3-Amino-2-chloro-4-methylpyridine, 97% 8 Warning H315-H319-H335 P261-P305 + P351 + P338
[133627‑45‑9] C6H7ClN2 FW 142.59 CH3

NH2
N Cl
2-Amino-5-chloro-3-nitropyridine, 97%
mp .................................................................................................................................................................... 65 to 70 °C [5409‑39‑2] C5H4ClN3O2 FW 173.56 Cl NO2
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
A 708135-1G
P338
glass btl 1g
N NH2
mp .............................................................................................................................................................. 193 to 197 °C

7
Warning H315-H319-H335 P261-P305 + P351 + P338
3-Amino-2-chloro-5-methylpyridine, 97% 8
[34552‑13‑1] C6H7ClN2 FW 142.59 594202-5G glass btl 5g
H3C NH2
N Cl
4-Amino-2-chloro-5-nitropyrimidine, 95% 8
mp .................................................................................................................................................................... 86 to 91 °C
[1920‑66‑7] C4H3ClN4O2 FW 174.55 NH2
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 + O2N
P338 N
701882-5G glass btl 5g N Cl
2-Amino-4-chloro-6-methylpyrimidine, 97% mp .............................................................................................................................................................. 221 to 226 °C
78
Danger H302-H315-H319-H334-H335 P261-P305 + P351 +
[5600‑21‑5] Beil. 25,IV,2171 C5H6ClN3 FW 143.57 Cl P338-P342 + P311
N
H3C N NH2 720321-1G glass btl 1g
mp .............................................................................................................................................................. 183 to 186 °C 2-Amino-4-chlorophenol, 97%

122882-5G glass btl 5g 5-Chloro-2-hydroxyaniline
122882-25G glass btl 25 g [95‑85‑2] Beil. 13,IV,878 H2NC6H3(Cl)OH FW 143.57
mp .............................................................................................................................................................. 136 to 141 °C
4-Amino-6-chloro-2-(methylthio)pyrimidine, 97%
7
[1005‑38‑5] Beil. 25,11 C5H6ClN3S FW 175.64 NH2
N C44400-5G glass btl 5g

Cl N SCH3 C44400-100G glass btl 100 g
C44400-500G glass btl 500 g
mp .............................................................................................................................................................. 130 to 132 °C
2-Amino-5-chlorophenol, 97%
A46005-5G glass btl 5g [28443‑50‑7] H2NC6H3(Cl)OH FW 143.57
A46005-25G poly btl 25 g mp .............................................................................................................................................................. 145 to 153 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
1-Amino-4-chloronaphthalene, 98%
4-Chloro-1-naphthylamine 552224-5G glass btl 5g
[4684‑12‑2] Beil. 12,1255 H2NC10H6Cl FW 177.63 552224-25G glass btl 25 g
mp ................................................................................................................................................................. 98 to 100 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[16026‑77‑0] H2NC6H3(Cl)OH FW 143.57
A46404-5G glass btl 5g mp .............................................................................................................................................................. 151 to 154 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> 1-Amino-4-chloro-2-nitrobenzene, see 4-Chloro-2-nitroaniline Page 714
2-Amino-4-chloro-nitrobenzene, see 5-Chloro-2-nitroaniline Page 714
4-Amino-1-chloro-2-nitrobenzene, see 4-Chloro-3-nitroaniline Page 714 552488-1G glass btl 1g
2-Amino-3-chloro-5-nitrobenzonitrile, 97%
2-Cyano-6-chloro-4-nitroaniline
[20352‑84‑5] O2NC6H2(Cl)(NH2)CN FW 197.58 3-Chloro-4-hydroxyaniline
mp .............................................................................................................................................................. 183 to 187 °C [3964‑52‑1] Beil. 13,510 H2NC6H3(Cl)OH FW 143.57
mp .............................................................................................................................................................. 150 to 153 °C
7
7
+ P338
2-Amino-4-chloro-5-nitrophenol, 98% 4-Amino-3-chlorophenol hydrochloride, 98%

[6358‑07‑2] Beil. 13,392 H2NC6H2(Cl)(NO2)OH FW 188.57 2-Chloro-4-hydroxyaniline hydrochloride
mp ................................................................................................................................................................................ 225 °C [52671‑64‑4] Beil. 13,IV,1273 H2NC6H3(Cl)OH · HCl FW 180.03
mp ................................................................................................................................................................ 255 °C (dec.)
7
7
+ P338 Warning H315-H319-H335 P261-P305 + P351 + P338
2-Amino-4-chloro-6-nitrophenol, 97%
[6358‑08‑3] H2NC6H2(Cl)(NO2)OH FW 188.57
mp .............................................................................................................................................................. 158 to 162 °C

AHB A, 0613, UNP EU
n Aminochloropuri n
> (±)-α-Amino-2-chlorophenylacetic acid, see (±)-2-Chlorophenylglycine 5-Amino-1-(2-chlorophenyl)-1H-pyrazole-4-carbonitrile, 97%
Page 727
(±)-α-Amino-4-chlorophenylacetic acid, see (±)-4-Chlorophenylglycine [64096‑89‑5] C10H7ClN4 FW 218.64 NC
Page 727
H2 N N
N
N-(2-Amino-4-chlorophenyl)anthranilic acid, 97% Cl
[67990‑66‑3] H2NC6H3(Cl)NHC6H4CO2H FW 262.69
mp ................................................................................................................................................................. 191 °C (dec.)
A
mp .............................................................................................................................................................. 136 to 140 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
56
Danger H301-H317-H318 P280-P301 + P310-P305 + P351 +
153230-25G glass btl 25 g P338
5-Amino-3-(4-chlorophenyl)isoxazole, 97%
[33866‑48‑7] C9H7ClN2O FW 194.62 Cl
5-Amino-1-(3-chlorophenyl)-1H-pyrazole-4-carbonitrile, 97%
[51516‑68‑8] C10H7ClN4 FW 218.64
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
N
H2N O P338
mp .............................................................................................................................................................. 163 to 167 °C
6
Danger H301 P301 + P310
5-Amino-1-(4-chlorophenyl)-1H-pyrazole-4-carbonitrile, 97%
644943-1G glass btl 1g [51516‑67‑7] C10H7ClN4 FW 218.64
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338
2-Amino-5-(2-chlorophenyl)-1,3,4-oxadiazole, 97%
[2138‑98‑9] C8H6ClN3O FW 195.61 N N
O NH2
2-Amino-5-(4-chlorophenyl)-1,3,4-thiadiazole, 97%
Cl
[28004‑62‑8] C8H6ClN3S FW 211.67 N N
mp .............................................................................................................................................................. 165 to 169 °C
S NH2
6
Danger H301-H315-H319-H335 P261-P301 + P310-P305 + P351 + Cl
P338
7
2-Amino-5-(4-chlorophenyl)-1,3,4-oxadiazole, 95% 573744-1G glass btl 1g

[33621‑61‑3] C8H6ClN3O FW 195.61 N N
2-Amino-4-(4-chlorophenyl)thiazole, 98%
O NH2
Cl [2103‑99‑3] Beil. 27,IV,4953 C9H7ClN2S FW 210.68 Cl
mp ................................................................................................................................................................. 245 °C (dec.)
6
Danger H301-H319 P301 + P310-P305 + P351 + P338 N
S NH2
663387-10G glass btl 10 g mp .............................................................................................................................................................. 169 to 171 °C
6
> 2-Amino-3-(4-chlorophenyl)-1-propanol, see DL-4-Chlorophenylalaninol
P338
Page 724
3-Amino-3-(2-chlorophenyl)propionic acid, 97%
2-Amino-6-chloropurine
[68208‑20‑8] ClC6H4CH(NH2)CH2CO2H FW 199.63
6-Chloroguanine Cl
mp ................................................................................................................................................................. 228 °C (dec.)
[10310‑21‑1] Beil. 26,IV,3561 C5H4ClN5 FW 169.57 N
N
H2N N N
H
3-Amino-3-(4-chlorophenyl)propionic acid, 97%
[19947‑39‑8] ClC6H4CH(NH2)CH2CO2H FW 199.63 mp ............................................................................................................................................................................ >300 °C
mp ................................................................................................................................................................. 223 °C (dec.)
 ≥99%
5-Amino-3-(4-chlorophenyl)pyrazole, 97% 109789-5G glass btl 5g
[78583‑81‑0] C9H8ClN3 FW 193.63 Cl  97%

N
H2N N
H
mp .............................................................................................................................................................. 172 to 176 °C
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338

AHB A, 0613, UNP EU
n Aminochloropuri n
2-Amino-6-chloro-9H-purine-9-acetic acid, 97% 3-Amino-2-chloropyridine, 98%

[149376‑70‑5] C7H6ClN5O2 FW 227.61 Cl [6298‑19‑7] Beil. 22,V,9,88 C5H5ClN2 FW 128.56 NH2
N N
O N Cl
H2N N N
OH
mp ................................................................................................................................................................... 76 to 78 °C
7
mp ............................................................................................................................................................................ >300 °C Warning H315-H319-H335 P261-P305 + P351 + P338
A 7
Warning H315-H319-H335 P261-P305 + P351 + P338
> 6-Amino-2-chloropurine riboside, see 2-Chloroadenosine hemihydrate 3-Amino-4-chloropyridine, 98% 8

Page 648
[20511‑15‑3] C5H5ClN2 FW 128.56 Cl
2-Amino-3-chloropyrazine, 97% 8 NH2
[6663‑73‑6] C4H4ClN3 FW 129.55 N Cl
N
N NH2
mp ................................................................................................................................................................... 58 to 63 °C
56
mp .............................................................................................................................................................. 164 to 169 °C Danger H301-H315-H318-H335 P261-P280-P301 + P310-P305
+ P351 + P338
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
720364-1G glass btl 1g 4-Amino-2-chloropyridine, 97%
2-Amino-3-chloropyridine, 97% 8 [14432‑12‑3] C5H5ClN2 FW 128.56 NH2
[39620‑04‑7] C5H5ClN2 FW 128.56 Cl

N Cl
N NH2
mp ................................................................................................................................................................... 90 to 94 °C
mp .................................................................................................................................................................... 60 to 64 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338
5-Amino-2-chloropyridine, 98%
2-Amino-4-chloropyridine, 97%
[5350‑93‑6] Beil. 22,V,9,94 C5H5ClN2 FW 128.56 H2N
4-Chloro-2-pyridinamine Cl
[19798‑80‑2] C5H5ClN2 FW 128.56 N Cl
N NH2 mp ................................................................................................................................................................... 81 to 83 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 129 to 133 °C
7
676020-25G glass btl 25 g 2-Amino-4-chloropyrimidine, 97%
2-Amino-5-chloropyridine, 98% [3993‑78‑0] C4H4ClN3 FW 129.55 Cl
[1072‑98‑6] Beil. 22,V,8,451 C5H5ClN2 FW 128.56 Cl

N
N NH2
N NH2
mp ............................................................................................................................................... 155 to 160 °C (dec.)
mp .............................................................................................................................................................. 135 to 138 °C Substrate used in a palladium-catalyzed cyanation with zinc(II)
bp ............................................................................................................................................ 127-128 °C/11 mmHg cyanide.1
7
Warning H302 Lit. cited: 1. Org. Lett. 9, 1711 (2007)
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
A46803-25G glass btl 25 g P338
A46803-500G 500 g 661325-5G glass btl 5g
2-Amino-6-chloropyridine, 97% 2-Amino-5-chloropyrimidine, 97%

6-Chloro-2-pyridinamine [5428‑89‑7] C4H4ClN3 FW 129.55 Cl
N
[45644‑21‑1] C5H5ClN2 FW 128.56
Cl N NH2 N NH2
mp .................................................................................................................................................................... 69 to 73 °C mp .............................................................................................................................................................. 235 to 238 °C

Substrate used in a Ni(II)-catalyzed homo-coupling providing
56
Danger H301-H318 P280-P301 + P310-P305 + P351 + P338
diamino-2,2′-bipyridine.1
7

AHB A, 0613, UNP EU
n Aminocrotononit n
4-Amino-2-chloropyrimidine, 97% 2-Amino-3-chloro-5-(trifluoromethyl)pyridine, 97%

[7461‑50‑9] C4H4ClN3 FW 129.55 NH2 [79456‑26‑1] C6H4ClF3N2 FW 196.56 F3C Cl
N
N NH2
N Cl
mp ................................................................................................................................................................... 86 to 90 °C
mp .............................................................................................................................................................. 197 to 205 °C
7
7
Warning H302-H319 P305 + P351 + P338

A
4-Amino-3-chloro-2,5,6-trifluoropyridine, 99%
5-Amino-4-chloropyrimidine, 97% 8 [2693‑57‑4] C5H2ClF3N2 FW 182.53 NH2
[54660‑78‑5] C4H4ClN3 FW 129.55 Cl F Cl
H2N
N F N F
N
mp .............................................................................................................................................................. 120 to 121 °C
7
57
Danger H302-H318 P280-P305 + P351 + P338
6-Aminochrysene, 97%
6-Amino-4-chloropyrimidine, 97% 8 6-Chrysenamine
[5305‑59‑9] C4H4ClN3 FW 129.55 [2642‑98‑0] Merck 14,2254; Beil. 12,1346 C18H13N
Cl
FW 243.30
N
H2N N NH2
mp .............................................................................................................................................................. 212 to 216 °C mp .............................................................................................................................................................. 209 to 211 °C
7
Warning H302
7
732133-1G glass btl 1g A47052-250MG glass btl 250 mg
4-Amino-2-chloropyrimidine-5-carbonitrile, 97% 4-Aminocinnamic acid hydrochloride, 97%

[94741‑69‑2] C5H3ClN4 FW 154.56 [54057‑95‑3] Beil. 14,H,520 H2NC6H4CH=CHCO2H · HCl FW 199.63
NH2
NC mp ............................................................................................................................................... 265 to 270 °C (dec.)
N
N Cl
 predominantly trans
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp ................................................................................................................................................................. 200 °C (dec.)
57
Danger H302-H315-H317-H318-H335 P261-P280-P305 + P351 A47109-1G poly btl 1g
+ P338 A47109-5G poly btl 5g
2-Amino-6-chloro-4-pyrimidinol hydrate, 98% 3-Aminocoumarin, 97%

2-Amino-4-chloro-6-hydroxypyrimidine hydrate OH [1635‑31‑0] C9H7NO2 FW 161.16 NH2
[206658‑81‑3] Beil. 25,IV,3639 C4H4ClN3O · xH2O
N • xH2O
FW 145.55 (Anh) O O
Cl N NH2
mp .............................................................................................................................................................. 135 to 139 °C
mp ................................................................................................................................................................. 252 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> 2-Amino-m-cresol, see 2-Amino-3-methylphenol Page 142
A47028-25G poly btl 25 g 2-Amino-p-cresol, see 2-Amino-4-methylphenol Page 142
3-Amino-o-cresol, see 3-Amino-2-methylphenol Page 143
2-Amino-5-chlorothiazole hydrochloride 4-Amino-m-cresol, see 4-Amino-3-methylphenol Page 143
[55506‑37‑1] C3H3ClN2S · HCl FW 171.05 5-Amino-o-cresol, see 5-Amino-2-methylphenol Page 143
N 6-Amino-m-cresol, see 2-Amino-5-methylphenol Page 142
• HCl
Cl S NH2
3-Aminocrotononitrile
mp ............................................................................................................................................... 164 to 167 °C (dec.)
Diacetonitrile; 3-Iminobutyronitrile; 3-Amino-2-butenenitrile
57
Danger H302-H315-H317-H318-H335 P261-P280-P305 + P351 [1118‑61‑2] Beil. 4,IV,2842 H2N(CH3)=CHCN FW 82.10
+ P338
7
Warning H302
 Lonza quality, ≥96.0% (GC, KF, based on DM)
> 2-Amino-6-chlorotoluene, see 3-Chloro-2-methylaniline Page 699 product of Lonza Ltd
4-Amino-2-chlorotoluene, see 2-Chloro-4-aminotoluene Page 648 mp .................................................................................................................................. 40 to 67 °C (E/Z-Isomers)
690538-10KG steel drum 10 kg
 96%
117641-100G glass btl 100 g
117641-500G glass btl 500 g
AHB A, 0613, UNP EU
n Aminocumene n
> o-Aminocumene, see 2-Isopropylaniline Page 1581 (1R,2R)-trans-2-Aminocyclohexanol hydrochloride, 97.0-103.0%
6-Amino-2-cyanobenzothiazole, 97% (AT)
8
[13374‑31‑7] C6H13NO · HCl FW 151.63 OH
2-Cyano-6-aminobenzothiazole; 6-Amino-2-benzo- N
• HCl
thiazolecarbonitrile CN
NH2
H 2N S
[7724‑12‑1] C8H5N3S FW 175.21
≥96.5% (HPLC) enantiomeric excess: ≥98%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
A 57
Danger H302-H318 P280-P305 + P351 + P338
store at: 2-8°C store at: 2-8°C
713732-100MG glass btl 100 mg 671762-250MG glass btl 250 mg

> 2-Amino-3-cyano-4-chlorothiophene-5-carboxaldehyde, see 2-Amino-4-
chloro-5-formyl-3-thiophenecarbonitrile Page 107 (1S,2S)-trans-2-Aminocyclohexanol hydrochloride, 97.0-103.0%
3-Amino-4-cyano-5-(methylthio)pyrazole, see 3-Amino-5-(methylthio) (AT)
pyrazole-4-carbonitrile Page 146
3-Amino-4-cyanopyrazole, see 3-Aminopyrazole-4-carbonitrile Page 162 (1S,2S)-(+)-2-Aminocyclohexanol hydrochloride OH
2-Amino-3-cyanopyridine, see 2-Amino-3-pyridinecarbonitrile Page 163 [13374‑30‑6] C6H13NO · HCl FW 151.63 • HCl
2-Amino-5-cyanopyridine, see 6-Amino-3-pyridinecarbonitrile Page 163 NH2
5-Amino-2-cyanopyridine, see 5-Amino-2-pyridinecarbonitrile Page 163
2-Amino-5-cyanothiazole, see 2-Aminothiazole-5-carbonitrile Page 168
Aminocyclobutane, see Cyclobutylamine Page 801 enantiomeric excess: ≥98%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
1-Amino-1-cyclobutanecarboxylic acid, 97% store at: 2-8°C
[22264‑50‑2] H2NC4H6CO2H FW 115.13 671959-250MG glass btl 250 mg
7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 > (1S,2S)-(+)-2-Aminocyclohexanol hydrochloride, see (1S,2S)-trans-2-Amino-
cyclohexanol hydrochloride Page 112
trans-2-Aminocyclohexanol hydrochloride, 99%
[5456‑63‑3] Beil. 13,III,708 H2NC6H10OH·HCl FW 151.63
> Aminocyclododecane, see Cyclododecylamine Page 803
Aminocycloheptane, see Cycloheptylamine Page 804 mp .............................................................................................................................................................. 172 to 175 °C
Aminocyclohexane, see Cyclohexylamine Page 813 222577-5G glass btl 5g
1-Aminocyclohexaneacetic acid hydrochloride, see 2-(1-Aminocyclohexyl)
acetic acid hydrochloride Page 112 222577-25G glass btl 25 g
1-Aminocyclohexanecarboxylic acid, 98% trans-4-Aminocyclohexanol hydrochloride, 97%

Homocycloleucine trans-4-Hydroxycyclohexylamine hydrochloride
[2756‑85‑6] Beil. 14,III,845 H2NC6H10CO2H FW 143.18 [50910‑54‑8] Beil. 13,III,720 H2NC6H10OH · HCl FW 151.63
mp .............................................................................................................................................................. 225 to 227 °C
mp ............................................................................................................................................................................ >300 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
cis-2-Aminocyclohexanecarboxylic acid, ≥95.0% (NT) 263761-25G poly btl 25 g

[45743‑49‑5] C7H13NO2 FW 143.18 263761-100G poly btl 100 g
O
OH 3-Amino-2-cyclohexen-1-one, 99%
NH2 [5220‑49‑5] H2NC6H7O FW 111.14
mp .............................................................................................................................................................. 129 to 133 °C
mp ............................................................................................................................................................. ~240 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
trans-2-Aminocyclohexanecarboxylic acid, ≥97.0% 239372-5G glass btl 5g

[5691‑19‑0] Beil. 14,IV,970 C7H13NO2 FW 143.18 O
OH
> (R)-α-Aminocyclohexylacetic acid, see D-α-Cyclohexylglycine Page 814
NH2 2-(1-Aminocyclohexyl)acetic acid hydrochloride, ≥95.0% (AT)

mp ............................................................................................................................................................. ~255 °C (dec.) 1-Aminocyclohexaneacetic acid hydrochloride NH2
OH
[37631‑99‑5] C8H15NO2 · HCl FW 193.67 • HCl
O
cis-4-Aminocyclohexanecarboxylic acid, 95%

7
Warning H315-H319-H335 P261-P305 + P351 + P338
[3685‑23‑2] Beil. 14,IV,981 H2NC6H10CO2H FW 143.18
mp .............................................................................................................................................................. 299 to 301 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> (S)-2-[[[[(1R,2R)-2-Aminocyclohexyl]amino]thioxomethyl]amino]-N-benzyl-
N-3,3-trimethylbutanamide, see (S)-2-[[(1R,2R)-2-Aminocyclohexyl]
404853-1G glass btl 1g thioureido]-N-benzyl-N,3,3-trimethylbutanamide Page 113
(2S)-2-[[[[(1R,2R)-2-Aminocyclohexyl]amino]thioxomethyl]amino]-N-3,3-
(S)-(+)-α-Aminocyclohexanepropionic acid hydrate trimethyl-N-(phenylmethyl)butanamide, see (S)-2-[[(1R,2R)-2-Aminocyclo-
hexyl]thioureido]-N-benzyl-N,3,3-trimethylbutanamide Page 113
3-Cyclohexyl-L-alanine
[307310‑72‑1] C6H11CH2CH(NH2)CO2H · xH2O FW 171.24 (Anh)
mp .............................................................................................................................................................. 234 to 237 °C
 technical grade
[α]21
D +12.0°, c = 1 in 1 M NaOH
7
Warning H302-H319 P305 + P351 + P338

AHB A, 0613, UNP EU
n Aminocyclopropy n
(S)-(+)-2-Amino-3-cyclohexyl-1-propanol hydrochloride, 97% (1R,2S)-cis-2-Aminocyclopentanol hydrochloride, ≥98.0% (TLC)

3-Cyclohexyl-L-alaninol; (S)-2-Amino-3-cyclohexylpropanol hydro- [137254‑03‑6] C5H11NO · HCl FW 137.61 OH
chloride • HCl
[117160‑99‑3] C6H11CH2CH(NH2)CH2OH·HCl FW 193.71 NH2
mp ................................................................................................................................................................. 230 °C (dec.)

[α]20
D +2.6°, c = 1 in methanol 06756-1G-F poly tube 1g
7
Warning H315-H319-H335 P261-P305 + P351 + P338

(1S,2S)-trans-2-Aminocyclopentanol hydrochloride, ≥98.0%
(TLC) A
[68327‑04‑8] C5H11NO · HCl FW 137.61 OH
(S)-2-[[(1R,2R)-2-Aminocyclohexyl]thioureido]-N-benzyl-N,3,3- • HCl
trimethylbutanamide, 95% NH2
(S)-2-[[[[(1R,2R)-2-Aminocyclohexyl]amino]
7
CH3 t-Bu S Warning H302
thioxomethyl]amino]-N-benzyl-N-3,3-tri- N
N N
methylbutanamide; (2S)-2-[[[[(1R,2R)-2- H H
O NH2 06782-1G-F poly tube 1g
Aminocyclohexyl]amino]thioxomethyl]
amino]-N-3,3-trimethyl-N-(phenylmethyl)
butanamide trans-2-Aminocyclopentanol hydrochloride, 97%
[479423‑21‑7] C21H34N4OS FW 390.59 [31775‑67‑4] C5H11NO · HCl FW 137.61 OH
mp .................................................................................................................................................................... 71 to 85 °C
[α]20
D +19.0°, c = 1 in chloroform
• HCl
NH2
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 191 to 196 °C
693413 525863-5G glass btl 5g
> Aminocyclooctane, see Cyclooctylamine Page 820
cis-2- Amino-3-cyclopentene-1-carboxylic acid hydrochloride,
≥97.0% (AT)
cis-2-Amino-1-cyclooctanecarboxylic acid hydrochloride,
≥95.0% [122022‑92‑8] C6H9NO2 · HCl FW 163.60 O OH
• HCl
[350015‑76‑8] C9H17NO2 · HCl FW 207.70 NH2
> Aminocyclopentane, see Cyclopentylamine Page 824

7
Warning H302
1-Aminocyclopentaneacetic acid hydrochloride, see 2-(1-Aminocyclopentyl)
acetic acid hydrochloride Page 113
1-Aminocyclopentanecarboxylic acid, see Cycloleucine Page 817 68602-250MG poly btl 250 mg
cis-2-Amino-1-cyclopentanecarboxylic acid hydrochloride,
≥95.0% (AT) 2-(1-Aminocyclopentyl)acetic acid hydrochloride, ≥95.0% (AT)
cis-β-Cycloleucine hydrochloride 1-Aminocyclopentaneacetic acid hydrochloride O
O
[18414‑30‑7] C6H11NO2 · HCl FW 165.62 C7H13NO2 · HCl FW 179.64
OH OH
H2N
• HCl
• HCl
NH2
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
30249-1G-F poly tube 1g 38965-1G-F poly tube 1g
1-Amino-1-cyclopentanemethanol, 97% > Aminocyclopropane, see Cyclopropylamine Page 826

Cycloleucinol 1-Amino-1-cyclopropanecarbonitrile hydrochloride, 8
[10316‑79‑7] H2NC5H8CH2OH FW 115.17 97%
mp ................................................................................................................................................................................... 20 °C [127946‑77‑4] C4H7ClN2 FW 118.56 CN
bp .................................................................................................................................................. 85-90 °C/10 mmHg • HCl
NH2
Often used building block in medicinal chemistry synthesis.1,2
Lit. cited: 1. J. Med. Chem. 50, 2341 (2007) mp .............................................................................................................................................................. 214 to 220 °C
2. J. Med. Chem. 49, 4409 (2006)
6
7
Warning H315-H319-H335 P261-P305 + P351 + P338

192279-10G glass btl 10 g 1-Aminocyclopropanecarboxylic acid, ≥98% (TLC)
ACPC O
(1R,2R)-trans-2-Aminocyclopentanol hydrochloride, 97%
[22059‑21‑8] Beil. 14,IV,973 C4H7NO2 FW 101.10
OH
[68327‑11‑7] C5H11NO · HCl FW 137.61 OH NH2
• HCl
NH2 NMDA agonist acting at the glycine site
mp .............................................................................................................................................................. 229 to 231 °C
≥96.5% (TLC)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
ee (GC): ≥98.5%
store at: 2-8°C
> (S)-Amino-cyclopropylacetic acid, see L-α-Cyclopropylglycine Page 827

AHB A, 0613, UNP EU
n Aminodeazapurin n
6-Amino-7-deazapurine, 97% 8 4′-Amino-3′,5′-dichloroacetophenone, 97%

4-Amino-7H-pyrrolo[2,3-d]pyrimidine NH2
1-(4-Amino-3,5-dichlorophenyl)-ethanone; 3,5-Dichloro-4-amino-
[1500‑85‑2] C6H6N4 FW 134.14 acetophenone
N
[37148‑48‑4] H2NC6H2(Cl)2C(O)CH3 FW 204.05
N N
H mp .............................................................................................................................................................. 162 to 166 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 257 to 262 °C
A 6
Danger H301 P301 + P310
722332-1G glass btl 1g > 2-Amino-3,5-dichlorobenzoic acid, see 3,5-Dichloroanthranilic acid

Page 910
> 1-Aminodecane, see Decylamine Page 839
(8S,9S)-9-Amino-9-deoxyepiquinine trihydrochloride, see (8α,9S)-6′- 3-Amino-2,5-dichlorobenzoic acid, 95%
Methoxycinchonan-9-amine trihydrochloride Page 1696
2-Amino-2-deoxy-D-galactopyranose hydrochloride, see D-(+)-Galactos- Chloramben
amine hydrochloride Page 1377 [133‑90‑4] H2NC6H2(Cl)2CO2H FW 206.03
2-Amino-2-deoxy-β-D-glucopyranose 1,3,4,6-tetraacetate, see 1,3,4,6-Tetra-
O-acetyl-2-amino-2-deoxy-β-D-glucopyranose hydrochloride Page 2363 mp ............................................................................................................................................... 194 to 197 °C (dec.)
(9R)-9-Amino-9-deoxyquinidine trihydrochloride, see (9R)-6′-Methoxycin-
78
Danger H315-H319-H335-H350 P201-P261-P305 + P351 +
chonan-9-amine trihydrochloride Page 1696 P338-P308 + P313
4′-Aminodibenzo-18-crown-6, ≥98.0% (GC) 152668-5G glass btl 5g
[126531‑26‑8] C20H25NO6 FW 375.42 4-Amino-3,5-dichlorobenzoic acid, 98%

O
O O NH2 [56961‑25‑2] H2NC6H2(Cl)2CO2H FW 206.03
mp .............................................................................................................................................................. 290 to 293 °C
O O
7
O Warning H315-H319-H335 P261-P305 + P351 + P338
7
2-Amino-3,5-dichlorobenzonitrile, 97%
[36764‑94‑0] H2NC6H2(Cl)2CN FW 187.03
> 2-Amino-6H-dibenzo[b,d]pyran-6-one, see 6-Amino-3,4-benzocoumarin
Page 92 642819 Full product information at Aldrich.com
4-Amino-3,5-dichlorobenzonitrile, 97%
2-Amino-3,5-dibromobenzaldehyde, 97%
[78473‑00‑4] H2NC6H2(Cl)2CN FW 187.03
[50910‑55‑9] H2NC6H2(Br)2CHO FW 278.93
mp .............................................................................................................................................................. 130 to 135 °C 642797 Full product information at Aldrich.com
7
Warning H319 P305 + P351 + P338 2-Amino-2′,5-dichlorobenzophenone, 99%
[2958‑36‑3] H2NC6H3(Cl)COC6H4Cl FW 266.12
mp ................................................................................................................................................................... 87 to 89 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> 4-Amino-3,5-dibromobenzenesulfonic acid sodium salt, see 3,5-Dibromo-
sulfanilic acid sodium salt Page 893 105155-10G glass btl 10 g
2-Amino-3,5-dibromobenzonitrile, 97%
[68385‑95‑5] H2NC6H2(Br)2CN FW 275.93 5-Amino-4,6-dichloro-2-methylpyrimidine, 97%
642800-5G glass btl 5g 2-Methyl-4,6-dichloro-5-aminopyrimidine Cl
[39906‑04‑2] C5H5Cl2N3 FW 178.02 H2N
> N-(2-Amino-3,5-dibromobenzyl)-N-methylcyclohexylamine hydrochloride, N
see Bromhexine hydrochloride Page 428 Cl N CH3
2-Amino-3,5-dibromo-N-cyclohexyl-N-methylbenzylamine hydrochloride,
see Bromhexine hydrochloride Page 428
mp ................................................................................................................................................................... 70 to 73 °C
7
2-Amino-3,5-dibromopyrazine, 97% Warning H315-H319-H335 P261-P305 + P351 + P338
[24241‑18‑7] Beil. 25,10,146 C4H3Br2N3 FW 252.89 Br N Br

mp .............................................................................................................................................................. 114 to 117 °C 4-Amino-2,6-dichlorophenol, 98%

[5930‑28‑9] Beil. 13,512 H2NC6H2(Cl)2OH FW 178.02
56
Danger H301-H315-H318-H335 P261-P280-P301 + P310-P305
+ P351 + P338 mp .............................................................................................................................................................. 167 to 170 °C
7
2-Amino-3,5-dibromopyridine, 97%
[35486‑42‑1] Beil. 22,431 C5H4Br2N2 FW 251.91 Br Br
5-Amino-2,4-dichlorophenol, 97%
N NH2 2,4-Dichloro-5-hydroxyaniline
[39489‑79‑7] H2NC6H2(Cl)2OH FW 178.02
mp .............................................................................................................................................................. 104 to 105 °C
mp .............................................................................................................................................................. 133 to 137 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
6
P338
> 4-Amino-2,6-dibromotoluene, see 3,5-Dibromo-4-methylaniline Page 889 655899-5G glass btl 5g

AHB A, 0613, UNP EU
n Aminodifluorobe n
> 1-(4-Amino-3,5-dichlorophenyl)-ethanone, see 4′-Amino-3′,5′-dichloroace- Used to construct pyrimido-oxazepines in a three-step process with
tophenone Page 114
microwave heating at 150°C.1
Lit. cited: 1. Tetrahedron Lett. 48, 1489 (2007)
2-Amino-3,5-dichloropyridine, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[4214‑74‑8] Beil. 22,V,8,466 C5H4Cl2N2 FW 163.00 Cl Cl

N NH2
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Amino-4,6-dichloropyrimidine-5-carboxaldehyde, 97% A
135925-25G poly btl 25 g [5604‑46‑6] C5H3Cl2N3O FW 192.00 O Cl
H N
3-Amino-2,5-dichloropyridine, 97% 8
Cl N NH2
[78607‑32‑6] C5H4Cl2N2 FW 163.00 Cl NH2
mp .............................................................................................................................................................. 208 to 224 °C
N Cl Substrate used in the synthesis of an N-terminal surrogate in amino
mp .............................................................................................................................................................. 124 to 129 °C
acid and peptide analogues.1
56
7
+ P351 + P338
P338
3-Amino-2,6-dichloropyridine, 97% 8 > 2-Amino-3,5-dichlorotoluene, see 2,4-Dichloro-6-methylaniline Page 932
2,6-Dichloro-3-pyridinamine NH2 2-Amino-4,6-dichloro-1,3,5-triazine, ≥96% 8
[62476‑56‑6] C5H4Cl2N2 FW 163.00
Cl N Cl [933‑20‑0] C3H2Cl2N4 FW 164.98 Cl
N N
mp .............................................................................................................................................................. 120 to 124 °C
Cl N NH2
56
Danger H301-H317-H318 P280-P301 + P310-P305 + P351 +
P338
≥96.0% (HPLC)
7
4-Amino-2,6-dichloropyridine, 97%
2,6-Dichloro-4-aminopyridine 711551-1G poly btl 1g
NH2
[2587‑02‑2] C5H4Cl2N2 FW 163.00 711551-5G poly btl 5g
Cl N Cl
2-Amino-N,N-diethylacetamide hydrochloride, 98% 8
[108723‑79‑1] C6H14N2O · HCl FW 166.65 O
mp .............................................................................................................................................................. 169 to 173 °C
H2N
N CH3 • HCl
7
Warning H315-H319-H335 P261-P305 + P351 + P338
CH3

≥98.0% (TLC)
2-Amino-4,6-dichloropyrimidine, 98%
7
Warning H302
[56‑05‑3] Beil. 25,IV,2123 C4H3Cl2N3 FW 163.99
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Amino-5-diethylaminopentane, 97%

N1,N1-Diethyl-1,4-pentanediamine
[140‑80‑7] Merck 14,6723 (C2H5)2N(CH2)3CH(NH2)CH3 FW 158.28
A48601-100G poly btl 100 g
density ............................................................................................................................................. 0.817 g/mL, 25 °C
4-Amino-2,6-dichloropyrimidine, 97% n20
D ................................................................................................................................................................................... 1.4429
5
[10132‑07‑7] C4H3Cl2N3 FW 163.99 NH2
Danger H314 P280-P305 + P351 + P338-P310
N
Cl N Cl
> 4-Amino-N,N-diethylaniline oxalate salt, see N,N-Diethyl-p-phenylenedi-
mp .............................................................................................................................................................. 258 to 267 °C amine oxalate salt Page 982
4-Amino-N,N-diethylaniline sulfate salt, see N,N-Diethyl-p-phenylenedi-
7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 amine sulfate salt Page 983
2-Amino-4,5-difluorobenzoic acid, see 4,5-Difluoroanthranilic acid
2-Amino-4,6-difluorobenzothiazole, 97%
5-Amino-4,6-dichloropyrimidine, 97% [119256‑40‑5] C7H4F2N2S FW 186.18 F
[5413‑85‑4] Beil. 25,IV,2139 C4H3Cl2N3 FW 163.99 Cl N
H2N NH2
N F S
Cl N
mp .............................................................................................................................................................. 216 to 220 °C
7
mp .............................................................................................................................................................. 145 to 148 °C Warning H302-H315-H319-H335 P261-P305 + P351 + P338

AHB A, 0613, UNP EU
n Aminodifluoroph n
2-Amino-4-(2,4-difluorophenyl)thiazole, 97% enantiomeric excess: ≥97.0%

C9H6F2N2S FW 212.22 store at: 2-8°C
F F
N
NH2
(1S,2S)-trans-2-Amino-1,2-dihydro-1-naphthol hydro- 8
S chloride, ≥96%
mp .............................................................................................................................................................. 115 to 119 °C [904930‑22‑9] C10H11NO · HCl FW 197.66
≥96.0% (HPLC)
A 7
683280-1G glass btl 1g store at: 2-8°C
2-Amino-4-(3,4-difluorophenyl)thiazole, 97%
[175135‑32‑7] C9H6F2N2S FW 212.22 3-Amino-4,5-dihydro-1H-1-phenylpyrazole, 97%
F
[3314‑35‑0] C9H11N3 FW 161.20 NH2
F
N
N N
S NH2
mp .............................................................................................................................................................. 121 to 125 °C
7
Warning H302-H319 P305 + P351 + P338 mp .............................................................................................................................................................. 168 to 172 °C
7
Warning H302-H319 P305 + P351 + P338
2-Amino-3,5-difluoro-4-(trifluoromethyl)pyridine, 95% 8 2-Amino-4,6-dihydroxypyrimidine, 98%

[883498‑68‑8] C6H3F5N2 FW 198.09 CF3
2-Amino-4,6-pyrimidinediol OH
F F [56‑09‑7] Beil. 24,468 C4H5N3O2 FW 127.10
N
N NH2 HO N NH2
density ............................................................................................................................................. 1.524 g/mL, 25 °C mp ............................................................................................................................................................................ >300 °C

n20
D ...................................................................................................................................................................................... 1.463
7
Warning H315-H319-H335 P261-P305 + P351 + P338
A50401-100G poly btl 100 g
701033-250MG glass btl 250 mg 2-Amino-4,6-dihydroxypyrimidine disodium salt 8

3-Amino-2,3-dihydrobenzoic acid hydrochloride, ≥98% 2-Amino-4,6-dihydroxypyrimidine sodium salt; ONa
Sodium 2-aminopyrimidine-4,6-bis(olate)
Gabaculine hydrochloride; 5-Amino-1,3-cyclohexa- O OH
N
C4H3N3Na2O2 FW 171.07
diene-1-carboxylic acid hydrochloride NaO N NH2
[59556‑17‑1] C7H9NO2 · HCl FW 175.61 • HCl
H2N mp ............................................................................................................................................................................ >300 °C
7
Warning H315-H319 P305 + P351 + P338
Inhibitor of γ-aminobutyric acid transaminase. Conformationally
constrained analog of GABA. 725013-1G glass btl 1g
store at: 2-8°C
> 2-Amino-4,6-dihydroxypyrimidine sodium salt, see 2-Amino-4,6-dihydrox-
A3539-50MG poly btl 50 mg ypyrimidine disodium salt Page 116
A3539-250MG poly btl 250 mg 4-Amino-2,6-dihydroxypyrimidine, see 6-Aminouracil Page 173
5-Amino-2,4-dihydroxypyrimidine, see 5-Aminouracil Page 172
> 6-Amino-2,3-dihydro-1,3-dioxo-2-hydrazinocarbonylamino-1H-benz[d,e]
isoquinoline-5,8-disulfonic acid dilithium salt, see Lucifer Yellow CH 2-Amino-4,5-dimethoxybenzoic acid, 98%
dilithium salt Page 1629
S-(−)-2-Amino-7,8-dihydro-6-(2-hydroxy-1-oxopropyl)-4(1H)-pteridinone, 4,5-Dimethoxyanthranilic acid; 6-Aminoveratric acid
see Sepiapterin Page 2269 [5653‑40‑7] Beil. 14,III,1623 H2NC6H2(OCH3)2CO2H FW 197.19
mp ............................................................................................................................................... 169 to 173 °C (dec.)
6-Amino-3,4-dihydro-1(2H)-naphthalenone, 96%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
6-Amino-1-tetralone O
[3470‑53‑9] C10H11NO FW 161.20
H2N
3-Amino-2,6-dimethoxypyridine monohydrochloride, 99%
mp .............................................................................................................................................................. 128 to 132 °C [80789‑72‑6] C7H10N2O2 · HCl FW 190.63 NH2
• HCl
6
Danger H301 P301 + P310
H3CO N OCH3
678422-1G glass btl 1g mp ............................................................................................................................................................................... 212 °C

7
Warning H315-H319-H335 P261-P305 + P351 + P338
(1R,2R)-trans-2-Amino-1,2-dihydro-1-naphthol hydro- 8
chloride, ≥96% 143251-1G glass btl 1g
[904316‑35‑4] C10H11NO · HCl FW 197.66 143251-5G glass btl 5g
OH
NH2
• HCl
≥96.0% (HPLC)

AHB A, 0613, UNP EU
n Aminodimethylph n
7
2-Amino-4,6-dimethoxypyrimidine, 98% Warning H302-H312-H332 P280
[36315‑01‑2] Beil. 25,IV,3485 C6H9N3O2 FW 155.15 OCH3
N
H3CO N NH2
2-Amino-6,7-dimethyl-4-hydroxypteridine, 97% dry basis
mp .................................................................................................................................................................... 94 to 96 °C
2-Amino-6,7-dimethyl-4-pteridinol OH
7
Warning H315-H319-H335 P261-P305 + P351 + P338 [611‑55‑2] C8H9N5O FW 191.19 H3C N
A
N
375349-5G glass btl 5g H3C N N NH2

mp ............................................................................................................................................................................ >300 °C
4-Amino-2,6-dimethoxypyrimidine, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[3289‑50‑7] C6H9N3O2 FW 155.15 NH2
N
H3CO N OCH3
2-Amino-5,6-dimethyl-4-hydroxypyrimidine, 96%
[3977‑23‑9] C6H9N3O FW 139.16
mp .............................................................................................................................................................. 149 to 152 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
534617-1G-A glass btl 1g
> 2-Amino-6,7-dimethyl-4-hydroxy-5,6,7,8-tetrahydropteridine, see 6,7-
> 4-Amino-N,N-dimethylaniline, see N,N-Dimethyl-p-phenylenediamine Dimethyl-5,6,7,8-tetrahydropterine hydrochloride Page 1118
Page 1104
4′-Amino-2,3′-dimethylazobenzene, see Fast Garnet GBC base Page 1286 4-Amino-3,5-dimethylisoxazole, 97%
1-Amino-3,5-dimethylbenzene, see 3,5-Dimethylaniline Page 1069
4-Amino-1,2-dimethylbenzene, see 3,4-Dimethylaniline Page 1069 [31329‑64‑3] C5H8N2O FW 112.13 H2N CH3
N
2-Amino-5,6-dimethylbenzimidazole, 97% H3C O
[29096‑75‑1] C9H11N3 FW 161.20 H3C N mp ................................................................................................................................................................... 41 to 46 °C

NH2
7
H3C N Warning H315-H319-H335 P261-P305 + P351 + P338
H
mp ............................................................................................................................................... 220 to 223 °C (dec.) 575069-1G glass btl 1g

7
Warning H315-H319-H335 P261-P305 + P351 + P338
5-Amino-3,4-dimethylisoxazole, 97%
[19947‑75‑2] C5H8N2O FW 112.13 H 3C CH3
2-Amino-5,6-dimethylbenzothiazole, 97% N
H 2N O
[29927‑08‑0] C9H10N2S FW 178.25 H3C N
NH2 mp .............................................................................................................................................................. 118 to 122 °C
S
7
H3C Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 185 to 189 °C

7
Warning H315-H319-H335 P261-P305 + P351 + P338
> (S)-2-Amino-4,4-dimethylpentanoic acid, see L-α-Neopentylglycine
Page 1895
(S)-3-Amino-2,4-dimethyl-2-pentanol hydrochloride, 8
> (R)-2-Amino-3,3-dimethyl-1-butanol, see (R)-(−)-tert-Leucinol Page 1610 97%
(S)-2-Amino-3,3-dimethyl-1-butanol hydrochloride, see L-tert-Leucinol
hydrochloride Page 1610 C7H17NO · HCl FW 167.68
(R)-2-Amino-3,3-dimethylbutyric acid, see D-tert-Leucine Page 1608 mp ................................................................................................................................................................. 98 to 102 °C
(S)-2-Amino-3,3-dimethylbutyric acid, see L-tert-Leucine Page 1608
(±)-2-Amino-3,3-dimethylbutyric acid, see DL-tert-Leucine Page 1609 D −10.0°, c = 0.5 in chloroform
[α]22
(S)-(−)-2-Amino-3,3-dimethyl-1,1-diphenyl-1-butanol, 99%
5-Amino-2,2-dimethylpentanol
[144054‑70‑6] (CH3)3CCH(NH2)C(C6H5)2OH FW 269.38
mp .............................................................................................................................................................. 134 to 137 °C
[13532‑77‑9] C7H17NO FW 131.22
HO NH2
[α]20
D ~−171°, c = 1 in chloroform
H3C CH3
product of Onyx Scientific, U.K.

57
Danger H302-H317-H318 P280-P305 + P351 + P338
7
+ P338
4-Amino-2,5-dimethylphenol
2-Amino-4,5-dimethyl-3-furancarbonitrile, 95%
4-Amino-2,5-xylenol
[5117‑88‑4] Beil. 18,12,200 C7H8N2O FW 136.15 H3C CN
[3096‑71‑7] Beil. 13,634 H2NC6H2(CH3)2OH FW 137.18
mp .............................................................................................................................................................. 242 to 243 °C
H3C O NH2
 technical grade
mp .............................................................................................................................................................. 163 to 169 °C
7
+ P338

AHB A, 0613, UNP EU
n Aminodimethylph n
> 4-Amino-2,3-dimethyl-1-phenyl-3-pyrazolin-5-one, see 4-Aminoantipyrine 4-Amino-3,5-dinitrobenzotrifluoride, 97%
Page 91
[445‑66‑9] H2NC6H2(NO2)2CF3 FW 251.12
1-Amino-2,6-dimethylpiperidine, 90% mp .............................................................................................................................................................. 144 to 149 °C
7
[39135‑39‑2] C7H16N2 FW 128.22 Warning H315-H319-H335 P261-P305 + P351 + P338
H3C N CH3 559520-5G glass btl 5g

NH2
2-Amino-3,5-dinitrothiophene, 95%
A bp .......................................... 65-80 °C/30 mmHg
density ..................................... 0.865 g/mL, 25 °C
n20
D .......................................................................... 1.465
[2045‑70‑7] C4H3N3O4S FW 189.15 NO2
 technical grade O2N S NH2
27
P280-P305 + P351 + P338 mp .............................................................................................................................................................. 174 to 176 °C
7
5-Amino-1,3-dimethylpyrazole, 97% 521620-5G glass btl 5g

[3524‑32‑1] C5H9N3 FW 111.15 CH3
> (S)-2-Amino-5-(1,3-dioxolan-2-yl)pentanoic acid, see L-Allysine ethylene
N acetal Page 77
H2N N 2-Aminodiphenylamine, see N-Phenyl-o-phenylenediamine Page 2044
CH3 4-Aminodiphenylamine diazonium sulfate, see Variamine Blue RT Salt
Page 2600
mp .................................................................................................................................................................... 65 to 69 °C
(1R,2S)-(−)-2-Amino-1,2-diphenylethanol, 99%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[23190‑16‑1] Beil. 13,IV,2150 C6H5CH(NH2)CH(C6H5)OH FW 213.28
D −7.0°, c = 0.6 in ethanol
[α]25
2-Amino-4,6-dimethylpyridine, 99%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
6-Amino-2,4-lutidine CH3
[5407‑87‑4] C7H10N2 FW 122.17 331899-1G glass btl 1g
H3C N NH2 331899-5G glass btl 5g
mp .................................................................................................................................................................... 63 to 64 °C (1S,2R)-(+)-2-Amino-1,2-diphenylethanol, 99%

bp ................................................................................................................................................................................. 235 °C [23364‑44‑5] Beil. 13,IV,2150 C6H5CH(NH2)CH(C6H5)OH FW 213.28
7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 mp .............................................................................................................................................................. 142 to 144 °C
[α]25
D +7.0°, c = 0.6 in ethanol
7
A51807-5G glass btl 5g Warning H315-H319-H335 P261-P305 + P351 + P338
2-Amino-4,6-dimethylpyrimidine, 95%
Acetylacetoneguanidine CH3
[767‑15‑7] Beil. 25,IV,2205 C6H9N3 FW 123.16 (R,R)-(+)-2-Amino-1,2-diphenylethanol, ≥99.5% (HPLC)
N
H3C N NH2
[88082‑66‑0] C6H5CH(NH2)CH(C6H5)OH FW 213.28
[α]D +124±3°, c = 0.87 in ethanol
mp .............................................................................................................................................................. 151 to 153 °C enantiomeric excess (HPLC): ≥99.0%
mp .............................................................................................................................................................. 116 to 119 °C
7
Warning H302-H319 P305 + P351 + P338
7
Warning H302
2-Amino-4,5-dimethylthiazole hydrochloride, 98%
[71574‑33‑9] C5H8N2S · HCl FW 164.66 (S,S)-(−)-2-Amino-1,2-diphenylethanol, ≥99.5% (HPLC)
H 3C
N [23190‑17‑2] C6H5CH(NH2)CH(C6H5)OH FW 213.28
• HCl
H3C S NH2 [α]D -124±3°, c = 0.87 in ethanol
enantiomeric excess (HPLC): ≥99.0%
mp ............................................................................................................................................... 273 to 274 °C (dec.)
mp .............................................................................................................................................................. 116 to 119 °C
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
7
Warning H302
P338
174408-10G poly btl 10 g
174408-50G poly btl 50 g
> [N-[(1R,2R)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfona-
6-Amino-1,3-dimethyluracil, 98% midato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-
ruthenium, see RuCl(p-cymene)[(R,R)-Ts-DPEN] Page 2256
[6642‑31‑5] Beil. 24,471 C6H9N3O2 FW 155.15 O [N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfona-
H3C midato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-
N
ruthenium, see RuCl(p-cymene)[(S,S)-Ts-DPEN] Page 2256
O N NH2 [N-[(1R,2R)-2-(Amino-κN)-1,2- diphenylethyl]-4-methylbenzenesulfona-
CH3 midato-κN]chloro [(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]-ruthenium, see
RuCl[(R,R)-TsDPEN](mesitylene) Page 2257
mp ................................................................................................................................................................. 295 °C (dec.) [N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfona-
midato-κN]chloro[(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]-ruthenium, see
A52153-100G poly btl 100 g RuCl[(S,S)-TsDPEN](mesitylene) Page 2258
[N-[(1R,2R)-2-(Amino-κN)-1,2-diphenylethyl]-2,3,4,5,6-pentafluorobenzene-
sulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)
benzene]-ruthenium, see RuCl[(R,R)-FsDPEN](p-cymene) Page 2257

AHB A, 0613, UNP EU
n Aminododecanoic n
[((1R,2R)-2-Amino-1,2-diphenylethyl)(p-tosyl)amido](p- 8 (S)-(−)-2-Amino-1,1-diphenyl-1-propanol, 99%

cymene)(pyridine)ruthenium(II) tetrafluoroborate, 97%
1,1-Diphenyl-L-alaninol
RuBF4(p-cymene)(pyridine)[(R,R)-TS- CH3 [78603‑91‑5] Beil. 13,IV,2200 CH3CH(NH2)C(C6H5)2OH FW 227.30
H3C
DPEN] CH3 mp .............................................................................................................................................................. 100 to 102 °C
C36H40BF4N3O2RuS FW 766.66 O
N
H 3C S N
Ru
NH2
[α]20
O BF4- Product of Onyx Scientific, U.K.
7
Ph Ph Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 184 to 190 °C

[α]20
D positive, c = 0.01 in chloroform
549479 A
Sold under license from Kanata Chemical Technologies Inc. for > (R)-2-Amino-3,3-diphenylpropionic acid, see 3,3-Diphenyl-D-alanine
research purposes only. Page 1139
(S)-2-Amino-3,3-diphenylpropionic acid, see 3,3-Diphenyl-L-alanine
7
Warning H315-H319-H335 P261-P305 + P351 + P338 Page 1139
5-Amino-1,3-diphenyl-1H-pyrazole, 97% 8
[5356‑71‑8] C15H13N3 FW 235.28
[((1R,2R)-2-Amino-1,2-diphenylethyl)(p-tosyl)amido](p- 8
cymene)ruthenium(II) tetrafluoroborate, 97%
N
RuBF4(p-cymene)[(R,R)-TS-DPEN] CH3 H2N N
H3C
C31H35BF4N2O2RuS FW 687.56 CH3
O Ru BF4-
H3C S N NH2
O
mp .............................................................................................................................................................. 128 to 132 °C
Ph Ph
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 207 to 212 °C
Sold under license from Kanata Chemical Technologies Inc. for 700118-1G glass btl 1g
research purposes only. 700118-5G glass btl 5g
> 6-Amino-1,3-dipropyl-2,4(1H,3H)-pyrimidinedione, see 6-Amino-1,3-dipro-
> [N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethy]-2,3,4,5,6-pentafluorobenzene- pyluracil Page 119
sulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)
benzene]-ruthenium, see RuCl[(S,S)-FsDPEN](p-cymene) Page 2257 6-Amino-1,3-dipropyluracil, 97%
6-Amino-1,3-dipropyl-2,4(1H,3H)-pyrimidinedione O
2-Amino-4,5-diphenyl-3-furancarbonitrile, 95%
[41862‑14‑0] C10H17N3O2 FW 211.26 CH3
[5503‑73‑1] C17H12N2O FW 260.29 N
7
Warning H302-H312-H332 P280 H2 N N O
CH3

7
Warning H302
Aminodiphenylmethane hydrochloride, 97%
Benzhydrylamine hydrochloride
[5267‑34‑5] Beil. 12,1323 (C6H5)2CHNH2 · HCl FW 219.71 4-Amino-3,5-di-2-pyridyl-4H-1,2,4-triazole, 97%
mp .............................................................................................................................................................. 293 to 295 °C
[1671‑88‑1] C12H10N6 FW 238.25 N N
7
Warning H315-H319-H335 P261-P305 + P351 + P338 N N
N
NH2
176885-25G poly btl 25 g
176885-100G poly btl 100 g mp .............................................................................................................................................................. 182 to 184 °C
7
> α-Aminodiphenylmethane, see Benzhydrylamine Page 231 Warning H315-H319-H335 P261-P305 + P351 + P338
2-Aminodiphenylmethane, see 2-Benzylaniline Page 250
4-Amino-2,6-diphenylphenol, 98% 341525-5G glass btl 5g
[50432‑01‑4] H2NC6H2(C6H5)2OH FW 261.32
4-Amino-3,6-disulfo-1,8-naphthalic anhydride dipotassium salt
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Lucifer Yellow anhydride dipotassium salt O O O
273066-250MG glass btl 250 mg [79539‑35‑8] C12H5K2NO9S2 FW 449.50
273066-1G glass btl 1g O O
S S
KO OK
(R)-(+)-2-Amino-1,1-diphenyl-1-propanol, 99% O H2N O
[78603‑93‑7] C15H17NO FW 227.30 NH2 mp ............................................................................................................................................................................ >300 °C
7
CH3 Warning H315-H319-H335 P261-P305 + P351 + P338
HO
12-Aminododecanoic acid, 95%

mp .............................................................................................................................................................. 102 to 105 °C
[α]20
12-Aminolauric acid
Product of Onyx Scientific, U.K [693‑57‑2] Beil. 4,III,1487 NH2(CH2)11COOH FW 215.33
mp .............................................................................................................................................................. 185 to 187 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
AHB A, 0613, UNP EU
n Aminododecanola n
12-Aminododecanolactam, 98% 3-(2-Aminoethylamino)propyldimethoxymethylsilane, ≥95.0%

Aza-2-cyclotridecanone; Laurolactam; N-[3-(Dimethoxymethylsilyl)propyl] OCH3
Cyclododecanone isooxime ethylenediamine; 3-(2-Aminoethylamino) H3CO Si
N
NH2
O
[947‑04‑6] Beil. 21,V,6,566 C12H23NO FW 197.32 NH propylmethyldimethoxysilane CH3 H
[3069‑29‑2] C8H22N2O2Si FW 206.36

density ............................................................................................................................................. 0.968 g/mL, 20 °C
mp .............................................................................................................................................................. 150 to 153 °C
Silane used for the derivatization of silica with aminoethyl-propylsilyl,
AEAPS, groups. 1
A > 2-Aminoenanthic acid, see 2-Aminoheptanoic acid Page 127
Aminoethane, see Ethylamine solution Page 1210
n20
D ...................................................................................................................................................................................... 1.450
Lit. cited: 1. K.K. Unger, Porous Silica Amsterdam (1979)
2-Aminoethanesulfinic acid, see Hypotaurine Page 1522
57
2-Aminoethanesulfonic acid, see Taurine Page 2356 Danger H317-H318 P280-P305 + P351 + P338
2-Aminoethanethiol, see Cysteamine Page 830
2-Aminoethanol, see Ethanolamine Page 1197 06667-25ML glass btl 25 mL
2-Amino-6-ethoxybenzothiazole N-(2-Aminoethyl)-N′-(3-aminopropyl)ethylenediamine tetrahy-

drochloride, ≥97.0%
[94‑45‑1] C9H10N2OS FW 194.25 N
NH2 [187037‑23‑6] NH2CH2CH2CH2NHCH2CH2NHCH2CH2NH2 · 4HCl
H3 C O S
FW 306.10
 technical grade > 3-(2-Aminoethylamino)propylmethyldimethoxysilane, see 3-(2-Aminoethy-

lamino)propyldimethoxymethylsilane Page 120
7
P338
[3-(2-Aminoethylamino)propyl]trimethoxysilane, ≥80%
N-(2-Aminoethyl)-3-(trimethoxysilyl)propylamine
2-(2-Aminoethoxy)ethanol, 98% [1760‑24‑3] (CH3O)3Si(CH2)3NHCH2CH2NH2 FW 222.36
Diethylene glycolamine liquid
bp ............................................... 146 °C/15 mmHg n20
D .......................................................................... 1.444
[929‑06‑6] Beil. 4,IV,1412 NH2CH2CH2OCH2CH2OH FW 105.14 density ..................................... 1.028 g/mL, 25 °C
bp ....................................................................................................................................................................... 218-224 °C
density ............................................................................................................................................. 1.048 g/mL, 25 °C  Dow Corning® product Z-6020
57
Danger H312-H314 P280-P305 + P351 + P338-P310 technical grade
Repackaged by Aldrich Chemical Company, Inc. Manufactured by
A54059-100G glass btl 100 g Dow Corning Corporation, U.S.A.
57
Danger H315-H317-H318 P280-P305 + P351 + P338
2-Amino-4-ethoxy-6-(methylamino)-1,3,5-triazine, 97%
[62096‑63‑3] C6H11N5O FW 169.18 440302-100ML glass btl 100 mL
O CH3
N N
H3C
N N NH2 > [3-(2-Aminoethylamino)propyl]trimethoxysilane, see N-[3-(Trimethoxysilyl)
H propyl]ethylenediamine Page 120
mp .............................................................................................................................................................. 171 to 174 °C 4-(2-Aminoethyl)aniline, 97%
7
Warning H302
4-Aminophenethylamine
[13472‑00‑9] Beil. 13,IV,278 H2NC6H4CH2CH2NH2 FW 136.19
523003-25G glass btl 25 g mp ............................................................ 28 to 31 °C density ................................. 1.034 g/mL, 25 °C
bp .............................................. 103 °C/0.3 mmHg n20 D .......................................................................... 1.591
N-(2-Aminoethyl)acetamide, 90%
N-Acetylethylenediamine Reagent used in polycondensation reactions.1,2,3
Lit. cited: 1. Macromolecules 27, 1289 (1994)
[1001‑53‑2] Beil. 4,IV,1193 CH3C(O)NHCH2CH2NH2 FW 102.14 2. Polymer J. Tokyo 23, 1511 (1991)
mp ........................................................................... 50 °C density .................................. 1.066 g/mL, 25 °C
3. Chem. Abstr. 116, 106932j (1992)
bp .................................................. 128 °C/3 mmHg n20 D .......................................................................... 1.485
5
Danger H314 P280-P305 + P351 + P338-P310
 technical grade
7
Warning H319 P305 + P351 + P338
397261-25G glass btl 25 g > O-(2-Aminoethyl)-O′-(2-azidoethyl)diethylene glycol, see 11-Azido-3,6,9-
trioxaundecan-1-amine Page 214
> 3-[2-(2-Aminoethylamino)ethylamino]propyltrimethoxysilane, see N
1
-(3-Trimethoxysilylpropyl)diethylenetriamine Page 2530
O-(2-Aminoethyl)-O′-(2-azidoethyl)heptaethylene glycol, ≥90%
2-(2-Aminoethylamino)-5-nitropyridine, 96% (oligomer purity)
[29602‑39‑9] C7H10N4O2 FW 182.18 Azido-PEG-amine (n=8)

O2 N O
[857891‑82‑8] C18H38N4O8 FW 438.52 H2N
8
N3
NH2
N N
7
H Warning H315-H319-H335 P261-P305 + P351 + P338
store at: 2-8°C
mp .............................................................................................................................................................. 126 to 128 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338

AHB A, 0613, UNP EU
n Aminoethylhydro n
O-(2-Aminoethyl)-O′-(2-azidoethyl)nonaethylene glycol, ≥90% O-(2-Aminoethyl)-O′-[2-(Boc-amino)ethyl]octaethylene glycol,

(oligomer purity) ≥90% (oligomer purity)
Azido-PEG-amine (n=10) Boc-PEG-amine (n=9) H
O H2N N
[912849‑73‑1] C22H46N4O10 FW 526.62 H2N
10
N3 [890091‑43‑7] C25H52N2O11 FW 556.69 O Boc
9
7
Warning H315-H319-H335 P261-P305 + P351 + P338
store at: 2-8°C store at: 2-8°C
O-(2-Aminoethyl)-O′-(2-azidoethyl)pentaethylene glycol, ≥90% O-(2-Aminoethyl)-O′-[2-(Boc-amino)ethyl]polyethylene glycol

5000
A
(oligomer purity)
Azido-PEG-amine (n=6) [198227‑38‑2] NH2CH2CH2O(CH2CH2O)nCH2CH2NHCOOC(CH3)3
O
[957486‑82‑7] C14H30N4O6 FW 350.41 H2 N
6
N3 671266-100MG poly btl 100 mg
671266-500MG poly btl 500 mg
7
Warning H315-H319-H335 P261-P305 + P351 + P338
store at: 2-8°C 2-(2-Aminoethyl)-1,3-di-Boc-guanidine, ≥90% (HPLC)
76172-500MG-F poly btl 500 mg 1,3-Di-Boc-2-(2-aminoethyl)guanidine
[203258‑44‑0] C13H26N4O4 FW 302.37
> (R,R)-α-(1-Aminoethyl)benzenemethanol, see (1R,2R)-(−)-Norpseudoephe-
drine Page 1941  technical
Guanidinylation reagent1
4-(2-Aminoethyl)benzenesulfonamide, 99% mp ................................................................................................................................................................... 95 to 98 °C
[35303‑76‑5] Beil. 14,III,2234 H2NCH2CH2C6H4SO2NH2 FW 200.26 Lit. cited: 1. K.C. Nicolaou et al., Bioorg. Med. Chem. 6, 1185 (1998)
mp .............................................................................................................................................................. 150 to 152 °C ship: dry ice store at: −20°C
275247-25G glass btl 25 g 84190-1G-F poly tube 1g
2-(2-Aminoethyl)benzimidazole dihydrochloride, 97%
> 2-Aminoethyl dihydrogen phosphate, see O-Phosphorylethanolamine
1H-Benzimidazole-2-ethanamine; 2-(1H-Benz- N Page 2067
imidazol-2-yl)ethylamine NH2
N
[4499‑07‑4] C9H11N3 · 2HCl FW 234.13 H • 2HCl 2-Aminoethyl diphenylborinate
2-Aminoethyl diphenyl borate; Diphenylboric acid 2-aminoethyl ester;
57
Danger H302-H318 P280-P305 + P351 + P338
2-APB; Diphenylborinic acid
657875-1G glass btl 1g [524‑95‑8] Beil. 16,IV,1642 (C6H5)2BOCH2CH2NH2 FW 225.09
Membrane-permeable modulator of intracellular IP3-induced calcium
4-(2-Aminoethyl)benzoic acid hydrochloride, 97% release.
[60531‑36‑4] H2NCH2CH2C6H4CO2H · HCl FW 201.65 store at: −20°C
mp ............................................................................................................................................................................ >350 °C D9754-1G glass btl 1g
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 + D9754-5G glass btl 5g
P338 D9754-10G glass btl 10 g
656380-1G glass btl 1g D9754-25G glass btl 25 g
656380-5G glass btl 5g > (2-Aminoethyl)diphenylphosphine, see 2-(Diphenylphosphino)ethylamine
656380-25G glass btl 25 g Page 1148
O-(2-Aminoethyl)-O′-[2-(biotinylamino)ethyl]octa- 8 (Rp)-1-[(1S)-(1-Aminoethyl)]-2-(diphenylphosphino)ferrocene,
ethylene glycol, ≥95% (oligomer purity) 97%
O (Rp)-1-(1S)-[(2-Diphenylphosphino)ferrocenyl]ethan-
HN NH
amine
P
H H
H
[607389‑84‑4] C24H24FeNP FW 413.27 NH2
N O
S O NH2 CH3
O 8 Fe
Biotin-PEG amine (n = 8)
mp .............................................................................................................................................................. 131 to 135 °C
[960132‑48‑3] C30H58N4O11S FW 682.87
Sold under license from Kanata Chemical Technologies Inc. for
research purposes only.
O-(2-Aminoethyl)-O′-[2-(Boc-amino)ethyl]decaethylene glycol, 697354-100MG glass btl 100 mg
≥90% (oligomer purity)
> (Sp)-1-[(1R)-(1-Aminoethyl)]-2-(diphenylphosphino)ferrocene, see (R)-1-[(S
Boc-PEG-amine (n=11) H p)-2-(Diphenylphosphino)ferrocenyl]ethylamine Page 1149
H2N N
[890091‑42‑6] C29H60N2O13 FW 644.79 O Boc N-(2-Aminoethyl)ethanolamine, see N-(2-Hydroxyethyl)ethylenediamine
11 Page 1482
2-Aminoethyl ether dihydrochloride, see 2,2′-Oxydiethylamine dihydro-
store at: 2-8°C chloride Page 1967
2-Aminoethyl hydrogen sulfate, ≥98.0% (T)
O-(2-Aminoethyl)-O′-[2-(Boc-amino)ethyl]hexaethylene glycol, Sulfuric acid mono 2-aminoethylester
≥90% (oligomer purity) [926‑39‑6] Beil. 4,IV,1414 NH2CH2CH2OSO3H FW 141.15
Boc-PEG-amine (n=7) H mp ................................................................................................................................................................ 277 °C (dec.)
H2N N
[206265‑98‑7] C21H44N2O9 FW 468.58
7
O Boc Warning H302-H315-H319-H335 P261-P305 + P351 + P338
7

70023-500MG-F poly btl 500 mg 06720-500G glass btl 500 g

AHB A, 0613, UNP EU
n Aminoethylhydro n
> 3-(2-Aminoethyl)-5-hydroxyindole hydrochloride, see Serotonin hydro- Di- to tetrapeptides with this amino acid analogue at the "P-terminal"
chloride Page 2271
3-(2-Aminoethyl)indole, see Tryptamine Page 2584 are bactericides and synergistic potentiators of penicillins and
4-[4-(2-Aminoethyl)-2-iodophenoxy]phenol-d4 hydrochloride, see 3- cephalophorins.1,2,3
Iodothyronamine-(ethylamino-1,1,2,2-d4) hydrochloride Page 1556 Lit. cited: 1. J.G. Allen et al., Nature 272, 56 (1978)
4-Amino-N-ethyl-N-isopropylaniline hydrochloride, see N-Ethyl-N-isopropyl- 2. Antimicrob. Agents Chemother. 16, 306 (1979)
p-phenylenediamine hydrochloride Page 1251 3. F.R. Atherton et al., Antimicrob. Agents Chemother. 15, 677 (1979)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-(2-Aminoethyl)isothiourea dihydrobromide
A
AET; 2-(2-Aminoethyl)-2-thiopseudourea dihydrobromide; S-(2- 06655-1G glass btl 1g
Aminoethyl)isothiouronium bromide hydrobromide
[56‑10‑0] Merck 14,178; Beil. 4,IV,1575
NH2CH2CH2SC(=NH)NH2 · 2HBr FW 281.01 (S)-(+)-1-Aminoethylphosphonic acid, 99%
Inhibits constitutive and inducible NOS. D-Ala(P); D-(+)-1-Aminoethylphosphonic
acid
mp .............................................................................................................................................................. 190 to 196 °C [66068‑76‑6] CH3CH(NH2)P(O)(OH)2 FW 125.06
7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 mp ................................................................................................................................................................ 290 °C (dec.)
[α]20
D +4.8°, c = 5 in H2O
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> S-(2-Aminoethyl)isothiouronium bromide hydrobromide, see 2-(2-Amino- 367559-1G glass btl 1g

ethyl)isothiourea dihydrobromide Page 122
2-Aminoethylphosphonic acid, 99%
N-(2-Aminoethyl)maleimide trifluoroacetate salt, ≥95% (HPLC) 2-AEP
2-Maleimidoethylamine trifluoroacetate salt [2041‑14‑7] Beil. 4,III,1792 H2NCH2CH2P(O)(OH)2 FW 125.06
O
[146474‑00‑2] C6H8N2O2 · C2HF3O2 O N O •
mp ................................................................................................................................................................ 296 °C (dec.)
F3C OH
FW 254.16
7
NH2 Warning H315-H319 P305 + P351 + P338
Heterobifunctional linker for introducing a maleimide function into 268674-250MG glass btl 250 mg
the widely used NOSu-modified fluorescent labels.1,2 268674-1G glass btl 1g
Lit. cited: 1. Y. Arano et al., J. Med. Chem. 39, 3451 (1996)
2. Ch. Boeckler et al., Bioorg. Med. Chem. Lett. 8, 2055 (1998) 1-(2-Aminoethyl)piperazine, 99%
 ≥98% (T) 2-Piperazinoethylamine H
[140‑31‑8] Beil. 23,V,1,257 C6H15N3 FW 129.20 N
7
Warning H315-H319-H335 P261-P305 + P351 + P338
N
56951-250MG-F poly btl 250 mg NH2
bp ............................................................... 218-222 °C vd ............................................................... 4.4 (vs air)
> 3-(2-Aminoethyl)-5-methoxyindole hydrochloride, see O-Methylserotonin density ..................................... 0.985 g/mL, 25 °C vp ......................................... 0.05 mmHg (20 °C)
hydrochloride Page 1844 n20
D .................................................................................... 1.5
3-(2-Aminoethyl)-5-methylindole hydrochloride, see 5-Methyltryptamine
57
hydrochloride Page 1863 Danger H302-H312-H314-H317-H412 P273-P280-P305 + P351
+ P338-P310
2-(2-Aminoethyl)-1-methylpyrrolidine, 97% A55209-100G glass btl 100 g
[51387‑90‑7] C7H16N2 FW 128.22 A55209-500G glass btl 500 g
N NH2
1-(2-Aminoethyl)piperidine, 98%
CH3
2-Piperidinoethylamine
density ............................................................................................................................................. 0.885 g/mL, 25 °C [27578‑60‑5] Beil. 20,V,3,143 C7H16N2 FW 128.22
n20
D ................................................................................................................................................................................... 1.4684
N
NH2
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338
bp ......................................................................... 186 °C n20
D .......................................................................... 1.473
25
Danger H226-H314 P280-P305 + P351 + P338-P310
4-(2-Aminoethyl)morpholine, 99%
2-Morpholinoethylamine O
[2038‑03‑1] Beil. 27,IV,370 C6H14N2O FW 130.19
N > O-(2-Aminoethyl)polyethylene glycol 3,000, see Poly(ethylene glycol),
NH2 Heterobifunctional under Page 2115
2-Aminoethyl-polystyrene, see Polystyrene Microspheres 2-aminoethylated
bp ......................................................................... 205 °C n20
D .......................................................................... 1.476 Page 2145
density ..................................... 0.992 g/mL, 25 °C Polystyrene A-NH2 Page 2145
57
Danger H302-H314-H317 P280-P305 + P351 + P338-P310 N-(2-Aminoethyl)-1,3-propanediamine, 97%
[13531‑52‑7] H2N(CH2)3NHCH2CH2NH2 FW 117.19
density ............................................................................................................................................. 0.928 g/mL, 25 °C
n20
D ................................................................................................................................................................................... 1.4815
5
Danger H314 P280-P305 + P351 + P338-P310
> 4-(2-Aminoethyl)phenol, see Tyramine Page 2588
(R)-(−)-1-Aminoethylphosphonic acid, ≥97.0% (NT)
L-Ala(P); L-(−)-1-Aminoethylphosphonic acid
[60687‑36‑7] Beil. 1,IV,3125 CH3CH(NH2)P(O)(OH)2 FW 125.06
D −4.8±0.5°, c = 5 in H2O
[α]20

AHB A, 0613, UNP EU
n Aminofluorene n
5-Amino-1-ethylpyrazole, 99% 2-Amino-5-(ethylthio)-1,3,4-thiadiazole, 99%

[3528‑58‑3] C5H9N3 FW 111.15 [25660‑70‑2] Beil. 27,II,785 C4H7N3S2 N N
N FW 161.25
H2N N H3C S S NH2
CH3
mp .............................................................................................................................................................. 135 to 137 °C
bp .............................................................................................................................................. 92-94 °C/0.01 mmHg
(2-Aminoethyl)trimethylammonium chloride hydrochloride,
7 A
Warning H315-H319-H335 P261-P305 + P351 + P338
99%

Cholaminchloride hydrochloride
[3399‑67‑5] Beil. 4,II,690 NH2CH2CH2N(Cl)(CH3)3 · HCl FW 175.10
mp ................................................................................................................................................................ 260 °C (dec.)
> 2-(2-Aminoethyl)pyridine, see 2-(2-Pyridyl)ethylamine Page 2225
7
Warning H315-H319-H335 P261-P305 + P351 + P338
3-(2-Aminoethyl)pyridine dihydrobromide, 98%

[307496‑23‑7] C7H10N2 · 2HBr FW 283.99 NH2 284556-5G glass btl 5g
• 2HBr
N > 1-Amino-4-ethynylbenzene, see 4-Ethynylaniline Page 1278
mp .............................................................................................................................................................. 248 to 252 °C 6-Aminoflavone, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[4613‑53‑0] C15H11NO2 FW 237.25
mp .............................................................................................................................................................. 196 to 200 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
4-(1-Aminoethyl)pyridine, 95% 576263-1G glass btl 1g

1-(4-Pyridyl)ethylamine; 1-Pyridin-4-yl-ethylamine H3C NH2 7-Aminoflavone, 97%
[50392‑78‑4] C7H10N2 FW 122.17
[15847‑18‑4] C15H11NO2 FW 237.25 O
H2N O
density .......................................................................................................................................... 1.0190 g/mL, 25 °C
n20
D ................................................................................................................................................................................... 1.5347
56
Danger H301-H315-H318-H335 P261-P280-P301 + P310-P305 mp .............................................................................................................................................................. 184 to 188 °C
+ P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
4-(2-Aminoethyl)pyridine, 96% 3-Aminofluoranthene, 90%
[13258‑63‑4] C7H10N2 FW 122.17 3-Fluoranthenamine
NH2
[2693‑46‑1] C16H11N FW 217.27
N NH2
bp .................................................. 104 °C/9 mmHg n20

D ....................................................................... 1.5380 mp .............................................................................................................................................................. 115 to 117 °C
density .................................. 1.0238 g/mL, 25 °C
79
Warning H302-H319-H411 P273-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338

1-(2-Aminoethyl)pyrrolidine, 98% 1-Aminofluorene, 99%
2-Pyrrolidinoethylamine 1-Fluorenamine
[7154‑73‑6] Beil. 20,V,1,405 C6H14N2 FW 114.19 N [6344‑63‑4] Beil. 12,III,3285 C13H11N FW 181.23
NH2
NH2
bp .......................................... 66-70 °C/23 mmHg n20

D .......................................................................... 1.468
density ..................................... 0.901 g/mL, 25 °C mp .............................................................................................................................................................. 125 to 126 °C
7
25
Danger H226-H314 P280-P305 + P351 + P338-P310
+ P338
A55357-5G glass btl 5g 2-Aminofluorene, 98%
2-Amino-5-ethyl-1,3,4-thiadiazole, 97% 2-Fluorenylamine; 2-Fluorenamine
[153‑78‑6] Beil. 12,IV,3370 C13H11N FW 181.23
[14068‑53‑2] C4H7N3S FW 129.18 N N
H 3C mp .............................................................................................................................................................. 124 to 128 °C
S NH2
mp .............................................................................................................................................................. 200 to 203 °C A55500-25G glass btl 25 g
7
Warning H315-H319-H335 P261-P305 + P351 + P338
9-Aminofluorene hydrochloride, 98%

9-Fluorenamine hydrochloride
[5978‑75‑6] Beil. 12,1331 C13H11N · HCl FW 217.69
mp ............................................................................................................................................... 265 to 270 °C (dec.)
> 2-(2-Aminoethyl)-2-thiopseudourea dihydrobromide, see 2-(2-Aminoethyl)
isothiourea dihydrobromide Page 122 A55608-5G glass btl 5g
AHB A, 0613, UNP EU
n Aminofluorenone n
1-Amino-9-fluorenone, 97% 2-Amino-6-fluorobenzoic acid, 98%

[6344‑62‑3] Beil. 14,113 C13H9NO FW 195.22 6-Fluoroanthranilic acid
[434‑76‑4] H2NC6H3(F)CO2H FW 155.13
NH2 mp .............................................................................................................................................................. 167 to 169 °C
O
Used in the synthesis of a novel benzamide with potent neuroleptic
mp .............................................................................................................................................................. 118 to 120 °C activity.1
Lit. cited: 1. J. Med. Chem. 39, 1172 (1996)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
A 7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Amino-9-fluorenone, 98% 443026-5G glass btl 5g
[3096‑57‑9] Beil. 14,113 C13H9NO FW 195.22
4-Amino-2-fluorobenzoic acid, 97%
NH2
[446‑31‑1] H2NC6H3(F)CO2H FW 155.13
O mp ................................................................................................................................................................ 210 °C (dec.)
57
mp .............................................................................................................................................................. 157 to 160 °C Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
A55802-10G glass btl 10 g 2-Amino-5-fluorobenzonitrile, 97%
4-Amino-9-fluorenone, 95% [61272‑77‑3] H2NC6H3(F)CN FW 136.13
mp ................................................................................................................................................................... 92 to 96 °C
[4269‑15‑2] Beil. 14,113 C13H9NO FW 195.22 H2N
bp ...................................................................................................................................................... 138 °C/15 mmHg
7
Warning H319 P305 + P351 + P338

mp .............................................................................................................................................................. 138 to 140 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338 2-Amino-6-fluorobenzonitrile, 99%
6-Fluoroanthranilonitrile
122947-1G glass btl 1g [77326‑36‑4] H2NC6H3(F)CN FW 136.13
6-Aminofluorescein mp .............................................................................................................................................................. 125 to 128 °C
7
Fluoresceinamine isomer II Warning H319 P305 + P351 + P338
O
[51649‑83‑3] Beil. 19,V,8,713 C20H13NO5 H2N O 429856-1G glass btl 1g
FW 347.32
HO O OH
5-Amino-2-fluorobenzonitrile, 97%
Note: Do not confuse with fluorescamine. 3-Cyano-4-fluoroaniline
mp ................................................................................................................................................................. 285 °C (dec.) [53312‑81‑5] C6H3(F)CN FW 136.13
λmax ............................................................................................................................................................................. 495 nm mp ................................................................................................................................................................... 92 to 96 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
5
Danger H315-H318 P280-P305 + P351 + P338

2-Amino-6-fluorobenzothiazole, 99%
> 2-Amino-4-fluoroanisole, see 5-Fluoro-2-methoxyaniline Page 1309
1-Amino-3-fluorobenzene, see 3-Fluoroaniline Page 1295 [348‑40‑3] Beil. 27,IV,4858 C7H5FN2S FW 168.19 N
1-Amino-4-fluorobenzene, see 4-Fluoroaniline Page 1295 NH2
F S
2-Amino-4-fluorobenzoic acid, 97%

mp .............................................................................................................................................................. 183 to 185 °C
4-Fluoroanthranilic acid
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[446‑32‑2] Beil. 14,IV,1070 H2NC6H3(F)CO2H FW 155.13
mp .............................................................................................................................................................. 192 to 196 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> 2-Amino-3-fluorobenzotrifluoride, see 2-Fluoro-6-(trifluoromethyl)aniline
Page 1331
370169-1G glass btl 1g 2-Amino-5-fluorobenzotrifluoride, see 4-Fluoro-2-(trifluoromethyl)aniline
Page 1331
2-Amino-5-fluorobenzoic acid, 97% 3-Amino-2-fluorobenzotrifluoride, see 2-Fluoro-3-(trifluoromethyl)aniline
Page 1331
5-Fluoroanthranilic acid 3-Amino-4-fluorobenzotrifluoride, see 2-Fluoro-5-(trifluoromethyl)aniline
[446‑08‑2] Beil. 14,IV,1071 H2NC6H3(F)CO2H FW 155.13 Page 1331
mp .............................................................................................................................................................. 181 to 183 °C 5-Amino-2-fluorobenzotrifluoride, see 4-Fluoro-3-(trifluoromethyl)aniline
Page 1331
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Amino-6-fluorobenzylamine, 97%
367982-1G glass btl 1g [175277‑93‑7] NH2C6H3(F)CH2NH2 FW 140.16
5
Danger H314 P280-P305 + P351 + P338-P310

AHB A, 0613, UNP EU
n Aminofluoropyri n
> (±)-2-Amino-4-fluoroglutaric acid, see 4-Fluoro-DL-glutamic acid Page 1304 mp .............................................................................................................................................................. 168 to 172 °C
2-Amino-3-fluoro-3-methylbutyric acid, see 3-Fluoro-DL-valine Page 1335
57
Danger H302-H318 P280-P305 + P351 + P338
(R)-(+)-2-Amino-1-fluoro-3-methyl-1,1-diphenylbutane, 97%
(CH3)2CHCH(NH2)C(C6H5)2F FW 257.35
2-Amino-5-(4-fluorophenyl)-1,3,4-thiadiazole, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
5-(4-Fluorophenyl)-1,3,4-thiadiazol-2-amine N N
551090-500MG glass btl 500 mg [942‑70‑1] C8H6FN3S FW 195.22
A
S NH2
F
(S)-(−)-2-Amino-1-fluoro-3-methyl-1,1-diphenylbutane, 97%
(CH3)2CHCH(NH2)C(C6H5)2F FW 257.35 mp .............................................................................................................................................................. 238 to 243 °C
7 7
Warning H315-H319-H335 P261-P305 + P351 + P338 Warning H302-H319 P305 + P351 + P338

2-Amino-4-fluorophenol, 96%
5-Fluoro-2-hydroxyaniline 2-Amino-3-fluoropyridine, 97% 8
OH
[399‑97‑3] C6H6FNO FW 127.12 [21717‑95‑3] C5H5FN2 FW 112.11 F
F NH2
N NH2
mp .............................................................................................................................................................. 130 to 135 °C
7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 mp ................................................................................................................................................................... 41 to 45 °C
7
Warning H302-H319 P305 + P351 + P338
4-Amino-3-fluorophenylboronic acid hydrochloride 8
C6H8BClFNO2 FW 191.40 2-Amino-5-fluoropyridine, 97%
OH
B [21717‑96‑4] Beil. 22,8,449 C5H5FN2 FW 112.11 F
OH
H2N • HCl N NH2

F
mp ................................................................................................................................................................... 93 to 97 °C
mp .............................................................................................................................................................. 150 to 160 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H302
3-Amino-5-(4-fluorophenyl)isoxazole, 97%
2-Amino-6-fluoropyridine, 98% 8
5-(4-Fluorophenyl) isoxazol-3-amine NH2
C9H7FN2O FW 178.16 [1597‑32‑6] C5H5FN2 FW 112.11
N
O F N NH2
F
mp ................................................................................................................................................................... 57 to 62 °C
mp .............................................................................................................................................................. 102 to 106 °C
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338
7
Warning H302
3-Amino-3-(4-fluorophenyl)propionic acid, 97% 3-Amino-2-fluoropyridine, 95% 8

[325‑89‑3] FC6H4CH(NH2)CH2CO2H FW 183.18 [1597‑33‑7] C5H5FN2 FW 112.11 NH2
N F
5-Amino-3-(4-fluorophenyl)pyrazole, 97%
density ............................................................................................................................................. 1.212 g/mL, 25 °C
[72411‑52‑0] C9H8FN3 FW 177.18 F n20
D ...................................................................................................................................................................................... 1.563
7
Warning H302-H319 P305 + P351 + P338
H 2N N 728675-1G glass btl 1g

N
H
3-Amino-5-fluoropyridine 8
mp .............................................................................................................................................................. 119 to 123 °C
[210169‑05‑4] C5H5FN2 FW 112.11 F NH2
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338 N
mp ................................................................................................................................................................... 85 to 89 °C
7
5-Amino-4-(4-fluorophenyl)-1H-pyrazole, 97%
4-(4-Fluorophenyl)-1H-pyrazol-5-amine 732176-500MG glass btl 500 mg
F
[5848‑05‑5] C9H8FN3 FW 177.18
H2N N
N
H

AHB A, 0613, UNP EU
n Aminofluoropyri n
4-Amino-2-fluoropyridine, 96% 8 mp ...................................................................................................................................................... 115.5 to 119.5 °C

[α]20
[18614‑51‑2] C5H5FN2 FW 112.11 NH2
7
Warning H315-H319-H335 P261-P305 + P351 + P338
N F 545872-500MG glass btl 500 mg
mp .................................................................................................................................................................... 83 to 88 °C (S)-(−)-Aminoglutethimide, 97%
7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 [57288‑03‑6] C13H16N2O2 FW 232.28
A 720232-1G glass btl 1g 7
Warning H315-H319-H335 P261-P305 + P351 + P338
4-Amino-3-fluoropyridine, 97% 545864-500MG glass btl 500 mg

8
[2247‑88‑3] C5H5FN2 FW 112.11 NH2
Aminoguanidine hydrochloride, ≥98%
F Guanylhydrazine hydrochloride
N
[1937‑19‑5] Merck 14,441; Beil. 3,IV,236 NH2NHC(=NH)NH2 · HCl
FW 110.55
mp .................................................................................................................................................................... 71 to 79 °C Inhibits both constitutive and inducible nitric oxide synthetase.
7
Warning H302-H319 P305 + P351 + P338 mp .............................................................................................................................................................. 162 to 166 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
5-Amino-2-fluoropyridine, 97% 8 396494-100G glass btl 100 g
6-Fluoro-3-pyridineamine H2N
[1827‑27‑6] C5H5FN2 FW 112.11 Aminoguanidine bicarbonate, 97%
N F Aminoguanidine hydrogencarbonate; Guanylhydrazine hydrogen-
carbonate
mp .................................................................................................................................................................... 87 to 91 °C
[2582‑30‑1] Beil. 3,III,230 NH2NHC(=NH)NH2 · H2CO3 FW 136.11
57
Danger H315-H318-H335 P261-P280-P305 + P351 + P338
mp ............................................................................................................................................... 170 to 172 °C (dec.)
79
Warning H317-H411 P273-P280
> 4-amino-5-fluoro-2(1H)-pyrimidinone, see 5-Fluorocytosine Page 1302 109266-100G poly btl 100 g
2-Amino-5-fluorotoluene, see 4-Fluoro-2-methylaniline Page 1311
4-Amino-2-fluorotoluene, see 3-Fluoro-4-methylaniline Page 1311 109266-500G poly btl 500 g
5-Amino-2-fluorotoluene, see 4-Fluoro-3-methylaniline Page 1312
Aminoformamidine hydrochloride, see Guanidine hydrochloride Aminoguanidine nitrate, 99%
Page 1405
[10308‑82‑4] Beil. 3,IV,236 H2NNHC(=NH)NH2 · HNO3 FW 137.10
2-Amino-3-formylchromone, 97% mp .............................................................................................................................................................. 145 to 147 °C
37
Danger H272-H315-H319-H335 P220-P261-P305 + P351 +
2-Amino-4-oxo-4H-1-benzopyran-3-carboxaldehyde O O P338
[61424‑76‑8] Beil. 18,11,571 C10H7NO3 FW 189.17 H A56108-5G glass btl 5g
O NH2
> 1-Amino-4-guanidinobutane sulfate salt, see Agmatine sulfate salt
Page 61
mp ................................................................................................................................................................. 249 °C (dec.) (S)-2-Amino-6-guanidinohexanoic acid hydrochloride, see L-Homoarginine
hydrochloride Page 1450
7
Warning H315-H319-H335 P261-P305 + P351 + P338
(R)-2-Amino-5-guanidinopentanoic acid, see D-Arginine Page 197
(S)-2-Amino-5-guanidinopentanoic acid, see L-Arginine Page 197
402028-1G glass btl 1g (±)-2-Amino-5-guanidinopentanoic acid, see DL-Arginine Page 198
1-Aminoheptane, see Heptylamine Page 1419
> 2-Amino-5-formylthiazole, see 2-Aminothiazole-5-carboxaldehyde
Page 169
2-Aminoheptane, 99%
3-Amino-5-(2-furyl)pyrazole, 97% 1-Methylhexylamine; 2-Heptylamine
[96799‑02‑9] C7H7N3O FW 149.15 [123‑82‑0] Merck 14,9802; Beil. 4,III,374 CH3(CH2)4CH(NH2)CH3
NH2
FW 115.22
N bp ............................................................... 142-144 °C n20
D .......................................................................... 1.418
O N
H density ..................................... 0.766 g/mL, 25 °C
27
mp .............................................................................................................................................................. 126 to 130 °C
7
(R)-(−)-2-Aminoheptane
> (R)-2-Aminoglutaric acid, see D-Glutamic acid Page 1386
(±)-2-Aminoglutaric acid, see DL-Glutamic acid monohydrate Page 1387 [6240‑90‑0] CH3(CH2)4CH(NH2)CH3 FW 115.22
3-Aminoglutaric acid hydrochloride, see β-Glutamic acid hydrochloride bp ............................................................... 142-144 °C n20
D .......................................................................... 1.419
Page 1387 density ..................................... 0.766 g/mL, 25 °C
256
(R)-(+)-Aminoglutethimide, 97% Danger H226-H301-H314-H317-H335
[55511‑44‑9] C13H16N2O2 FW 232.28 NH2

 99%
P261-P280-P301 + P310-P305 + P351 + P338-P310
CH3
O N O 462624-1G glass btl 1g
H

AHB A, 0613, UNP EU
n Aminohexanol n
 ChiPros®, produced by BASF, 99% 8 (S)-2-Aminohexane

≥98.5% (GC) (S)-2-Hexylamine
enantiomeric excess: ≥98.5% [70492‑67‑0] C6H15N FW 101.19
P261-P280-P305 + P351 + P338-P310
257
Danger H225-H302-H314 P210-P280-P305 + P351 +
727105-5G glass btl 5g P338-P310
 ≥97.0%
(S)-(+)-2-Aminoheptane enantiomeric ratio (GC): >99.0:1.0
[44745‑29‑1] CH3(CH2)4CH(NH2)CH3 FW 115.22
bp ............................................................... 142-144 °C n20
D .......................................................................... 1.419
A
density ..................................... 0.766 g/mL, 25 °C
 ChiPros®, produced by BASF, 99% 8
≥98.5% (GC)
2569
Danger H226-H301-H314-H317-H400
 99% 727172-25G glass btl 25 g
[α]20
D +7°, neat
P273-P280-P301 + P310-P305 + P351 + P338-P310 > (R)-2-Aminohexanedioic acid, see D-2-Aminoadipic acid Page 90
(S)-2-Aminohexanedioic acid, see L-2-Aminoadipic acid Page 90
462632-1G glass btl 1g (S)-3-Aminohexanedioic acid hydrochloride, see L-β-Homoglutamic acid
 ChiPros®, produced by BASF 8
≥98.5% (GC) 6-Amino-1-hexanethiol hydrochloride 8
enantiomeric excess: ≥99.0% 6-Mercaptohexylamine hydrochloride
NH2CH2(CH2)4CH2SH • HCl
P273-P280-P305 + P351 + P338-P310 [31098‑40‑5] C6H15NS · HCl FW 169.72
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Aminoheptanoic acid, ≥97.0% (NT)
733679
2-Aminoenanthic acid O
[1115‑90‑8] Beil. 4,IV,2789 C7H15NO2 H3C > 2-Aminohexanoic acid, see DL-Norleucine Page 1941
OH
FW 145.20 (S)-(+)-2-Aminohexanoic acid, see L-Norleucine Page 1941
NH2 6-Aminohexanoic acid, see 6-Aminocaproic acid Page 104
mp ............................................................................................................................................................. ~280 °C (dec.)

(R)-(−)-2-Amino-1-hexanol, 97%
D-Norleucinol
[80696‑28‑2] CH3(CH2)3CH(NH2)CH2OH FW 117.19
7-Aminoheptanoic acid, 98% mp ................................................................................................................................................................... 40 to 44 °C
bp ....................................................................................................................................................................... 216-218 °C
7-Aminooenanthic acid
[α]20
[929‑17‑9] Beil. 4,IV,2791 H2N(CH2)6CO2H FW 145.20
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 192 to 195 °C
2-Aminohexadecanoic acid, ≥95% (NT) (S)-(+)-2-Amino-1-hexanol, 97%
2-Aminopalmitic acid O L-Norleucinol
[7769‑79‑1] C16H33NO2 FW 271.44 CH3(CH2)12CH2
OH [80696‑29‑3] CH3(CH2)3CH(NH2)CH2OH FW 117.19
NH2 mp ................................................................................................................................................................... 35 to 40 °C
bp ....................................................................................................................................................................... 216-218 °C
mp ............................................................................................................................................................. ~220 °C (dec.)
[α]20
 technical
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> (S)-3-Amino-hexahydro-2-azepinone hydrochloride, see L-(−)-α-Amino-ε-
caprolactam hydrochloride Page 104
DL-2-Amino-1-hexanol, 90%
(±)-3-Aminohexahydro-2H-azepin-2-one hydrochloride, see DL-α-Amino-ε-
caprolactam hydrochloride Page 104 DL-Norleucinol
1-Aminohexane, see Hexylamine Page 1442
[5665‑74‑7] Beil. 4,III,809 CH3(CH2)3CH(NH2)CH2OH FW 117.19
bp ................................. 190-192 °C/740 mmHg n20 D ....................................................................... 1.4522
(R)-2-Aminohexane
density ..................................... 0.912 g/mL, 25 °C
(R)-2-Hexylamine NH2
[70095‑40‑8] C6H15N FW 101.19 H3C  technical grade
CH3
7
Warning H315-H319-H335 P261-P305 + P351 + P338
256
Danger H226-H301-H311-H314
 ≥97.0% (GC) 237671-10G glass btl 10 g
enantiomeric ratio (GC): >99.0:1.0 6-Amino-1-hexanol, 97%
P280-P301 + P310-P305 + P351 + P338-P310
[4048‑33‑3] Beil. 4,IV,1785 H2N(CH2)6OH FW 117.19
mp ................................................................................................................................................................... 54 to 58 °C
 ChiPros®, produced by BASF, ≥99% 8 bp ............................................................................................................................................ 135-140 °C/30 mmHg
≥99.0% (GC)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
P280-P305 + P351 + P338-P310 A56353-5G glass btl 5g
727164-25G glass btl 25 g A56353-100G glass btl 100 g
AHB A, 0613, UNP EU
n Aminohexynoicac n
7
(R)-3-Amino-5-hexynoic acid hydrochloride, 95% 8 Warning H302-H315-H319-H335 P261-P305 + P351 + P338
[332064‑87‑6] C6H9NO2 · HCl FW 163.60 NH2 O

• HCl
HC OH
> 3-Amino-2-hydroxybenzoic acid, see 3-Aminosalicylic acid Page 166
≥94.5% (TLC)
[α]D -12.0±1°, c = 1 in H2O 3-Amino-4-hydroxybenzoic acid, 97%
[1571‑72‑8] Beil. 14,IV,2090 H2NC6H3(OH)CO2H FW 153.14
7
A mp ................................................................................................................................................................ 208 °C (dec.)
7
711926-250MG glass btl 250 mg Warning H302-H315-H319-H335 P261-P305 + P351 + P338
(S)-3-Amino-5-hexynoic acid hydrochloride, 94% 8 289647-5G glass btl 5g

[332064‑85‑4] C6H9NO2 · HCl FW 163.60 289647-25G glass btl 25 g
≥94.0% (TLC)
> 4-Amino-2-hydroxybenzoic acid, see 4-Aminosalicylic acid Page 166
[α]D +13±1.5°, c = 1 in H2O
7
Warning H315-H319 P305 + P351 + P338 store at: 2-8°C 4-Amino-3-hydroxybenzoic acid, 97%
[2374‑03‑0] Beil. 14,IV,2075 H2NC6H3(OH)CO2H FW 153.14
mp .............................................................................................................................................................. 211 to 215 °C
p-Aminohippuric acid, ≥99%
7
N-(4-Aminobenzoyl)glycine; 4-Aminohippuric acid
[61‑78‑9] Merck 14,442; Beil. 14,IV,1152 NH2C6H4C(O)NHCH2COOH 339598-5G glass btl 5g
FW 194.19 339598-25G glass btl 25 g
mp ............................................................................................................................................... 199 to 200 °C (dec.) > 5-Amino-2-hydroxybenzoic acid, see 5-Aminosalicylic acid Page 166
store at: room temp (R)-(+)-2-Amino-2′-hydroxy-1,1′-binaphthalene, see (R)-(+)-2′-Amino-1,1′-
binaphthalen-2-ol Page 95
(S)-(−)-2-Amino-2′-hydroxy-1,1′-binaphthalene, see (S)-(−)-2′-Amino-1,1′-
A1422-25G poly btl 25 g binaphthalen-2-ol Page 96
A1422-100G poly btl 100 g (±)-2-Amino-3-hydroxybutyric acid, see DL-Threonine Page 2434
(2R,3S)-2-Amino-3-hydroxybutyric acid, see D-Threonine Page 2433
A1422-250G poly btl 250 g (2S,3R)-2-Amino-3-hydroxybutyric acid, see L-Threonine Page 2433
(2S,3S)-2-Amino-3-hydroxybutyric acid, see L-allo-Threonine Page 2433
> 4-Aminohippuric acid, see p-Aminohippuric acid Page 128 (S)-2-Amino-4-hydroxybutyric acid, see L-Homoserine Page 1452
(R)-3-Amino-4-hydroxybutyric acid, see L-β-Homoserine Page 1452
1-Aminohomopiperidine, 95%
N-Aminohexamethyleneimine (S)-(−)-4-Amino-2-hydroxybutyric acid, 96%
[5906‑35‑4] C6H14N2 FW 114.19 [40371‑51‑5] Beil. 4,IV,3170 H2NCH2CH2CH(OH)CO2H FW 119.12
N mp .............................................................................................................................................................. 200 to 203 °C
NH2
Building block for enantiopure 3-hydroxypyrrolidin-2-ones.1
bp ......................................................................... 165 °C n20
D .......................................................................... 1.485 D −30°, c = 1 in H2O
[α]23
density ..................................... 0.984 g/mL, 25 °C Lit. cited: 1. Bentley, J.M. et al., J. Chem. Soc., Chem. Commun. 231 (1995)
27
A56450-5G glass btl 5g 4-Amino-3-hydroxybutyric acid, 98%
1-Aminohydantoin hydrochloride, 98% DL-γ-Amino-β-hydroxybutyric acid
[2827‑56‑7] C3H5N3O2 · HCl FW 151.55 NH2
[924‑49‑2] Beil. 4,II,938 H2NCH2CH(OH)CH2CO2H FW 119.12
N mp ................................................................................................................................................................ 223 °C (dec.)
• HCl
7
O N O Warning H315-H319-H335 P261-P305 + P351 + P338
H
mp .............................................................................................................................................................. 201 to 205 °C A56655-5G glass btl 5g

545953-5G glass btl 5g (S)-(+)-4-Amino-3-hydroxybutyric acid, 97%
[7013‑05‑0] C4H9NO3 FW 119.12 OH O
> 4-Amino-3-hydrazino-5-mercapto-1,2,4-triazole, see Purpald® Page 2210 H2N
OH
3-Amino-4-hydroxybenzenesulfonic acid, 85-95% (T) mp .............................................................................................................................................................. 207 to 212 °C

2-Aminophenol-4-sulfonic acid [α]20
D +20.0°, c = 1.7 in H2O
[98‑37‑3] Beil. 14,IV,2820 H2NC6H3(OH)SO3H FW 189.19 542946-1G glass btl 1g
mp ............................................................................................................................................................................ ≥300 °C 542946-5G glass btl 5g
 technical 1-Amino-4-(2-hydroxyethyl)piperazine, 96%
ign. residue ................................................................................................................................................................. ≤2%
4-Amino-1-piperazineethanol
5
Danger H314 P280-P305 + P351 + P338-P310 OH
[3973‑70‑4] C6H15N3O FW 145.20 N
09180-250G poly btl 250 g N

NH2
> 2-Amino-3-hydroxybenzoic acid, see 3-Hydroxyanthranilic acid Page 1471
mp .............................................................................................................................................................. 105 to 107 °C
2-Amino-5-hydroxybenzoic acid, 98%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
5-Hydroxyanthranilic acid
[394‑31‑0] Beil. 14,IV,2080 HOC6H3(NH2)CO2H FW 153.14 122963-1G glass btl 1g
mp ................................................................................................................................................................. 247 °C (dec.)

AHB A, 0613, UNP EU
n Aminohydroxynit n
(R)-(−)-1-Amino-6-hydroxyindan, 97% 2-Amino-4-hydroxy-6-methylpyrimidine, 98%

C9H11NO FW 149.19 2-Amino-6-methyl-4-pyrimidinol; 6-Methylisocytosine OH
[3977‑29‑5] Beil. 24,343 C5H7N3O FW 125.13 N
HO
NH2
H3C N NH2
mp .............................................................................................................................................................. 195 to 205 °C mp ............................................................................................................................................................................ >300 °C
7
Warning H302

A58003-100G poly btl 100 g
A
4-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid
4-Amino-6-hydroxy-2-mercaptopyrimidine monohydrate, 98% monosodium salt hydrate, 85%
6-Amino-2-thiouracil monohydrate; 6-Amino-2- NH2 H Acid
mercapto-4-pyrimidinol monohydrate [312693‑54‑2] H2NC10H4(OH)(SO3H)SO3Na · xH2O FW 341.29 (Anh)
N • H2O
[65802‑56‑4] Beil. 24,476 C4H5N3OS · H2O mp ............................................................................................................................................................................ >300 °C
HO N SH
FW 161.18
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp ............................................................................................................................................................................ >300 °C
7
Warning H302-H319 P305 + P351 + P338 528765-100G glass btl 100 g
528765-500G glass btl 500 g
4-Amino-3-hydroxy-1-naphthalenesulfonic acid, ≥98%
(+)-2-Amino-N-[(1S,2S)-(2-hydroxy-1-methyl-2-phenyl)ethyl]-N-
methylacetamide, 97% 1-Amino-2-naphthol-4-sulfonic acid
[116‑63‑2] Merck 14,454; Beil. 14,IV,2825 H2NC10H5(OH)SO3H
2-Amino-N-[(2-hydroxy-1-methyl-2-phenyl)ethyl]-N-methylacetamide; FW 239.25
(1S, 2S)-(+)-Pseudoephedrine glycinamide
mp ................................................................................................................................................................ 290 °C (dec.)
[170115‑96‑5] H2NCH2CON(CH3)CH(CH3)CH(OH)C6H5 FW 222.28
[α]20
D +101°, c = 2 in methanol  ACS reagent
mp .................................................................................................................................................................... 76 to 80 °C ign. residue ............................................................................................................................................................. ≤0.1%
sulfate (SO42-) ........................................................................................................................................................ ≤0.2%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
6-Amino-4-hydroxy-2-naphthalenesulfonic acid, ≥90% (T)
> 2-Amino-2-(hydroxymethyl)-1,3-propanediol, see Tris(hydroxymethyl) 7-Amino-1-naphthol-3-sulfonic acid
aminomethane Page 2573 O
Trizma® base Page 2583 [90‑51‑7] Beil. 14,IV,2823 C10H9NO4S S OH
2-Amino-2-(hydroxymethyl-13C)propane-1,3-diol, see FW 239.25 O
Tris(hydroxymethyl-13C)aminomethane Page 2573 H2N
(R)-3-Amino-2-(hydroxymethyl)propanoic acid, see (R)-3-Amino-2-(hydrox- OH
ymethyl)propionic acid Page 129
(S)-3-Amino-2-(hydroxymethyl)propanoic acid, see (S)-3-Amino-2-(hydrox-
ymethyl)propionic acid Page 129  technical
coupling agent ....................................................................................................................................................... ~95%
(R)-3-Amino-2-(hydroxymethyl)propionic acid, ≥96% 8
(TLC)
5
Danger H314 P280-P305 + P351 + P338-P310
(R)-3-Amino-2-(hydroxymethyl)propanoic acid O
C4H9NO3 FW 119.12 08158-250G poly btl 250 g
H2N OH
OH
6-Amino-4-hydroxy-2-naphthalenesulfonic acid monohydrate,
90%
[α]D -6.0±0.5°, c = 1 in 5 M HCl [139123‑65‑2] H2NC10H5(OH)SO3H · H2O FW 257.26
composition
5
Danger H314 P280-P305 + P351 + P338-P310
carbon 39.5‑41.1%
nitrogen 11.2‑12.2% 290793-5G glass btl 5g
store at: 2-8°C
290793-250G glass btl 250 g
7-Amino-4-hydroxy-2-naphthalenesulfonic acid, ≥90% (T)
(S)-3-Amino-2-(hydroxymethyl)propionic acid, ≥96% 8
(TLC) 6-Amino-1-naphthol-3-sulfonic acid; I-Acid O
[87‑02‑5] Beil. 14,IV,2823 C10H9NO4S H2N S OH
(S)-3-Amino-2-(hydroxymethyl)propanoic acid FW 239.25 O
[930784‑11‑5] C4H9NO3 FW 119.12
OH
[α]D -5.0±0.5°, c = 1 in 5 M HCl
composition
carbon 39.5‑41.1%  technical
nitrogen 11.2‑12.2%
5
Danger H314 P280-P305 + P351 + P338-P310
store at: 2-8°C
714127-50MG glass btl 50 mg 08800-100G poly btl 100 g
08800-500G 500 g
> 2-Amino-6-hydroxy-1-methylpurine, see 1-Methylguanine Page 1782
2-Amino-6-hydroxy-7-methylpurine, see 7-Methylguanine Page 1782
2-Amino-6-hydroxy-9-methylpurine, see 9-Methylguanine Page 1782
3-Amino-4-hydroxy-5-nitrobenzenesulfonic acid, 97%
[96‑93‑5] H2NC6H2(OH)(NO2)SO3H FW 234.19
5
Danger H314 P280-P305 + P351 + P338-P310

AHB A, 0613, UNP EU
n Aminohydroxyphe n
(R)-Amino-(4-hydroxyphenyl)acetic acid methyl ester hydro- 5-Amino-8-hydroxyquinoline dihydrochloride, 95%

chloride, 97%
5-Amino-8-quinolinol dihydrochloride NH2
D-p-Hydroxyphenylglycine methyl ester hydro- NH2 • HCl [21302‑43‑2] Beil. 22,IV,5866 C9H8N2O · 2HCl
chloride OCH3 FW 233.09 • 2HCl
N
[57591‑61‑4] C9H11NO3 · HCl FW 217.65 O OH
HO
mp ................................................................................................................................................................ 279 °C (dec.)

mp .............................................................................................................................................................. 187 to 190 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
A 534927-5G glass btl
> (S)-3-Amino-4-(4-hydroxyphenyl)butyric acid hydrochloride, see L-β-

5g

Homotyrosine hydrochloride Page 1452
N-[(2S,3R)-3-Amino-2-hydroxy-4-phenylbutyryl]-L-leucine, 97% 2-Amino-4-hydroxy-6-trifluoromethylpyrimidine, 97%
([2S,3R]-3-Amino-2-hydroxy-4-phenylbutanoyl)-L-leucine [1513‑69‑5] C5H4F3N3O FW 179.10 OH
[58970‑76‑6] Merck 14,9842
N
(CH3)2CHCH2CH[NHCOCH(OH)CH(NH2)CH2C6H5]CO2H FW 308.37
F3C N NH2
mp ................................................................................................................................................................. 245 °C (dec.)
D −11°, c = 1 in 1 M NaOH
[α]20
mp ...................................................................................................................................................... 289.5 to 293.5 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> (±)-2-Amino-3-(3-hydroxyphenyl)propionic acid, see DL-m-Tyrosine
(R)-2-Amino-3-(4-hydroxyphenyl)propionic acid, see D-Tyrosine Page 2588
(S)-2-Amino-3-(4-hydroxyphenyl)propionic acid, see L-Tyrosine Page 2588 > 4-Amino-5-imidazolecarboxamide hydrochloride, see 5-Amino-4-imidazo-
(±)-2-Amino-3-(4-hydroxyphenyl)propionic acid, see DL-Tyrosine lecarboxamide hydrochloride Page 130
Page 2589
(R)-2-Amino-3-hydroxypropionic acid, see D-Serine Page 2270
(S)-2-Amino-3-hydroxypropionic acid, see L-Serine Page 2270 5-Amino-4-imidazolecarboxamide, 95%
(±)-2-Amino-3-hydroxypropionic acid, see DL-Serine Page 2270 [360‑97‑4] C4H6N4O FW 126.12 O
(S)-3-Amino-2-hydroxypropionic acid, see L-Isoserine Page 1592
(±)-3-Amino-2-hydroxypropionic acid, see DL-Isoserine Page 1592 H2 N N
H2N N
4-Amino-4-(3-hydroxypropyl)-1,7-heptanediol, 97% H
Bis-homotris mp .............................................................................................................................................................. 164 to 170 °C

[116747‑79‑6] H2NC(CH2CH2CH2OH)3 FW 205.29
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 108 to 110 °C
bp ........................................................................................................................................... 220-235 °C/0.5 mmHg
7
Warning H315-H319-H335 P261-P305 + P351 + P338
5-Amino-4-imidazolecarboxamide hydrochloride, 98%
361542-1G glass btl 1g AICA; 4-Amino-5-imidazolecarboxamide hydro- H2N
chloride N
> 2-Amino-6-hydroxypurine, see Guanine Page 1406 H2N • HCl
2-Amino-6-hydroxypurine hydrochloride, see Guanine hydrochloride [72‑40‑2] Beil. 25,IV,4329 C4H6N4O · HCl N
O H
Page 1406 FW 162.58
mp ............................................................................................................................................... 250 to 252 °C (dec.)
3-Amino-5-hydroxypyrazole, 98%
[6126‑22‑3] Beil. 25,IV,3516 C3H5N3O FW 99.09 NH2
164968-25G poly btl 25 g
N
HO N 2-Amino-4,5-imidazoledicarbonitrile, 97%
H
[40953‑34‑2] C5H3N5 FW 133.11 NC
mp ................................................................................................................................................................. 214 °C (dec.) N
7
Warning H315-H319-H335 P261-P305 + P351 + P338 NC N NH2
H
331449-5G glass btl 5g mp ................................................................................................................................................................ 270 °C (dec.)

7
2-Amino-3-hydroxypyridine, 98% + P338
2-Amino-3-pyridinol OH
[16867‑03‑1] Beil. 22,V,11,424 C5H6N2O FW 110.11 376744-50G glass btl 50 g
N NH2
2-Aminoimidazole sulfate, 98%
mp .............................................................................................................................................................. 168 to 172 °C 2-Imidazoleamine sulfate N
O
[1450‑93‑7] Beil. 24,I,188 C6H10N6 ·
7
Warning H315-H319-H335 P261-P305 + P351 + P338 N NH2 • 1/2 HO S OH
0.5H2SO4 FW 215.22 H O
122513-25G poly btl 25 g
mp ................................................................................................................................................................ 270 °C (dec.)
122513-100G poly btl 100 g
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> 2-Amino-8-hydroxyquinoline, see 2-Amino-8-quinolinol Page 166
197912-2.5G glass btl 2.5 g
> (±)-2-Amino-3-(4-imidazolyl)propionic acid, see DL-Histidine Page 1448

D-α-Amino-β-(4-imidazolyl)propionic acid monohydrochloride, see D-
Histidine monohydrochloride monohydrate Page 1448
L-α-Amino-β-(4-imidazolyl)propionic acid monohydrochloride, see L-
Histidine monohydrochloride monohydrate Page 1448
13
L-α-Amino-β-(4-imidazolyl)propionic acid- C6 hydrochloride monohy-
drate, see L-Histidine-13C6 hydrochloride monohydrate Page 1448

AHB A, 0613, UNP EU
n Aminoindanol n
3-Aminoimidazo[1,2-a]pyridine, 97% 4-Aminoindan, 97%

[28036‑33‑1] C7H7N3 FW 133.15 NH2 4-Indanamine NH2
N [32202‑61‑2] C9H11N FW 133.19
N
mp .............................................................................................................................................................. 114 to 126 °C bp ..................................................................... 90-92 °C n20

D .......................................................................... 1.592
density ..................................... 0.736 g/mL, 25 °C
7
Warning H302
7
Warning H315-H319-H335 P261-P305 + P351 + P338
A
> N-(Aminoiminomethyl)-4-morpholinecarboximidamide hydrochloride, see
Moroxydine hydrochloride Page 1873
5-Aminoindan, 95%
1-Aminoindan, 98%
5-Indanamine
1-Indanamine
[24425‑40‑9] Beil. 12,I,511 C9H11N FW 133.19
[34698‑41‑4] Beil. 12,III,2798 C9H11N FW 133.19
mp ................................................................................................................................................................... 34 to 36 °C
NH2
bp ......................................................................................................................................... 247-249 °C/745 mmHg
7
mp ........................................................................... 15 °C density .................................. 1.038 g/mL, 25 °C Warning H302-H312-H332 P280
bp ............................................. 96-97 °C/8 mmHg n20 D .......................................................................... 1.561
7
Warning H315-H319-H335 P261-P305 + P351 + P338
A59506-1G glass btl 1g (R)-(−)-1-Aminoindane, 97%
(S)-(+)-1-Aminoindan (R)-(−)-1-Indanamine
(S)-(+)-1-Indanamine [10277‑74‑4] Beil. 12,III,2798 C9H11N FW 133.19
[61341‑86‑4] Beil. 12,III,2798 C9H11N FW 133.19 NH2
bp ............................................. 96-97 °C/8 mmHg n20
D .......................................................................... 1.562
density ..................................... 1.038 g/mL, 25 °C mp ........................................................................... 15 °C density ................................. 1.038 g/mL, 25 °C
bp ............................................. 96-97 °C/8 mmHg n20 D .......................................................................... 1.562
7
D −16.5°, c = 1.5 in methanol
[α]20
79
 97% Warning H315-H319-H335-H411 P261-P273-P305 + P351 +
P338
[α]20
D +16.5°, c = 1.5 in methanol
445355-1G glass btl 1g (R)-(−)-1-Aminoindane, 99% 8
 ChiPros®, produced by BASF, 99% 8 (R)-(−)-1-Indanamine
≥98.5% (GC) [10277‑74‑4] Beil. 12,III,2798 C9H11N FW 133.19
enantiomeric excess: ≥98.5% NH2

727083-25G glass btl 25 g  ChiPros®, produced by BASF
≥98.5% (GC)
2-Aminoindan, 97% enantiomeric excess: ≥98.5%
[2975‑41‑9] Beil. 12,1196 C9H11N FW 133.19
79
NH2 P338
density ............................................................................................................................................. 1.024 g/mL, 25 °C 726737-25G glass btl 25 g
n20
D ...................................................................................................................................................................................... 1.561
(1R,2R)-(−)-trans-1-Amino-2-indanol, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[163061‑73‑2] C9H11NO FW 149.19
OH
479128-5G glass btl 5g NH2
2-Aminoindan hydrochloride, 98% mp .............................................................................................................................................................. 142 to 146 °C
2-Indanamine hydrochloride [α]D -23.0°, c = 1 in ethanol
7
[2338‑18‑3] Beil. 12,III,2798 C9H11N · HCl FW 169.65 Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 245 to 247 °C

Prepared from 2-indanols via azide displacement and subsequent
hydrogenation.1 663336-5G glass btl 5g
Lit. cited: 1. Tetrahedron 61, 6801 (2005) (1R,2S)-(+)-cis-1-Amino-2-indanol, 99%
7
Warning H302
(1R,2S)-(+)-cis-1-Amino-2-hydroxyindane NH2
[136030‑00‑7] C9H11NO FW 149.19
A59522-1G glass btl 1g OH
A59522-25G glass btl 25 g mp .............................................................................................................................................................. 118 to 121 °C
[α]22
ee (GLC): 99%
7
Warning H315-H319-H335 P261-P305 + P351 + P338

AHB A, 0613, UNP EU
n Aminoindanol n
7
(1S,2R)-(−)-cis-1-Amino-2-indanol, 99% Warning H315-H319-H335 P261-P305 + P351 + P338
(1S,2R)-(−)-cis-1-Amino-2-hydroxyindane
[126456‑43‑7] C9H11NO FW 149.19 525022-500MG glass btl 500 mg
mp .............................................................................................................................................................. 118 to 121 °C 5-Aminoindole, 97%
Used to prepare a mannitol-based scaffold in the study of Plasmepsin
5-Indolamine H 2N
II inhibition. Aspartic proteases such as plasmepsins I and II are of
[5192‑03‑0] Beil. 22,V,10,12 C8H8N2 FW 132.16
interest as targets for new, potential anti-malarials.1 N
H
D −61°, c = 0.5 in chloroform
[α]20
A ee (GLC): 99% mp ............................................................................................................................................... 131 to 133 °C (dec.)
Sold under license from Shasun Chemicals and Drugs Limited.
7
Useful chiral ligand for asymmetric synthesis.2
Lit. cited: 1. Bioorg. Med. Chem. 11, 3723 (2003)
2. Aldrichimica Acta 31, 3 (1998)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
6-Aminoindole, 97%
[5318‑27‑4] C8H8N2 FW 132.16
440833-25G glass btl 25 g H2N N
H
(1S,2S)-(+)-trans-1-Amino-2-indanol, 97% mp ................................................................................................................................................................... 75 to 79 °C

[163061‑74‑3] C9H11NO FW 149.19
7
OH

mp .............................................................................................................................................................. 142 to 146 °C
[α]D +23.0°, c = 1 in ethanol 7-Aminoindole, ≥95.0% (HPLC)
7
Warning H315-H319-H335 P261-P305 + P351 + P338 [5192‑04‑1] C8H8N2 FW 132.16
N
663344-1G glass btl 1g H
NH2
5-Aminoindazole, 97% may discolor to brown on storage

mp ................................................................................................................................................................. 96 to 100 °C
[19335‑11‑6] Beil. 25,II,308 C7H7N3 FW 133.15 H 2N
7
Warning H315-H319-H335 P261-P305 + P351 + P338
N
N
H
mp .............................................................................................................................................................. 175 to 178 °C > (S)-3-Amino-4-(3-indolyl)butyric acid hydrochloride, see L-β-Homotryp-
6
Danger H301-H315-H319-H335 P261-P301 + P310-P305 + P351 + tophan hydrochloride Page 1452
P338 (S)-2-Amino-3-(3-indolyl)propionic acid, see L-Tryptophan Page 2584
(±)-2-Amino-3-(3-indolyl)propionic acid, see DL-Tryptophan Page 2584
A59557-25G glass btl 25 g 2-Amino-5-iodobenzoic acid, 97%
6-Aminoindazole, 98% 5-Iodoanthranilic acid
[5326‑47‑6] Beil. 14,373 H2NC6H3(I)CO2H FW 263.03
[6967‑12‑0] Beil. 25,317 C7H7N3 FW 133.15
N
mp ............................................................................................................................................... 219 to 221 °C (dec.)
7
H2N N Warning H315-H319-H335 P261-P305 + P351 + P338
H
mp ............................................................................................................................................... 204 to 206 °C (dec.) A59603-5G glass btl 5g
7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 A59603-25G poly btl 25 g
A59603-100G 100 g
4-Amino-3-iodobenzonitrile
4-Cyano-2-iodoaniline
7-Amino-1H-indazole, 97% 8 [33348‑34‑4] IC6H3(NH2)CN FW 244.03
[21443‑96‑9] C7H7N3 FW 133.15 mp .............................................................................................................................................................. 112 to 115 °C
N Palladium-catalyzed carbonylation of iodoanilines provides ketoa-
N
H mides in the presence of primary and secondary amines.1
NH2
98%
Lit. cited: 1. Tetrahedron 62, 12051 (2006)
mp .............................................................................................................................................................. 157 to 163 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7

4-Aminoindole, 97%
2-Amino-3-iodo-5-nitropyridine, 97%
4-Indolamine NH2 3-Iodo-5-nitro-2-pyridinamine O2N I
[5192‑23‑4] Beil. 22,IV,4296 C8H8N2 FW 132.16
[25391‑56‑4] C5H4IN3O2 FW 265.01
N N NH2
H
mp .............................................................................................................................................................. 231 to 236 °C

mp .............................................................................................................................................................. 106 to 109 °C
Useful starter in azaindole chemistry.1
Lit. cited: 1. Synthesis 15, 2503 (2005)

AHB A, 0613, UNP EU
n Aminoisoxazole n
7
Warning H302-H315-H317-H319-H335 P261-P280-P305 + P351 + DL-3-Aminoisobutyric acid, 98%
P338
α-Methyl-β-alanine
694738-1G glass btl 1g [144‑90‑1] Beil. 4,IV,2624 NH2CH2CH(CH3)COOH FW 103.12
2-Amino-5-iodo-3-nitropyridine, 97% 217794-1G glass btl 1g
[25391‑57‑5] C5H4IN3O2 FW 265.01 217794-5G glass btl 5g
mp .............................................................................................................................................................. 215 to 219 °C 3-Amino-1H-isoindole hydrochloride
7
Warning
P338
H302-H315-H317-H319-H335 P261-P280-P305 + P351 +
[76644‑74‑1] C8H8N2 · HCl FW 168.62 NH2 A
640166-1G glass btl 1g N • HCl

mp ................................................................................................................................................................ 130 °C (dec.)
> 2-Amino-3-(4-iodophenyl)-propanoic acid, see p-Iodo-D-phenylalanine
7
Page 1553 Warning H315-H319-H335 P261-P305 + P351 + P338
2-Amino-3-iodopyridine, 96% 8
[104830‑06‑0] C5H5IN2 FW 220.01 I
> 3-Aminoisonicotinic acid, see 3-Aminopyridine-4-carboxylic acid
N NH2
Page 164
mp .................................................................................................................................................................... 87 to 91 °C 5-Aminoisophthalic acid, 94%

5-Aminobenzene-1,3-dicarboxylic acid
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338 [99‑31‑0] Beil. 14,I,636 H2NC6H3-1,3-(CO2H)2 FW 181.15
704474-1G glass btl 1g mp ............................................................................................................................................................................ >300 °C
7
2-Amino-5-iodopyridine, 98%
186279-25G poly btl 25 g
[20511‑12‑0] Beil. 22,II,334 C5H5IN2 FW 220.01 186279-100G poly btl 100 g
mp .............................................................................................................................................................. 128 to 131 °C
1-Aminoisoquinoline, 99%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[1532‑84‑9] Beil. 22,I,640 C9H8N2 FW 144.17
NH2
5-Amino-2-iodopyridine, 95%
[29958‑12‑1] C5H5IN2 FW 220.01 H2N mp .............................................................................................................................................................. 122 to 124 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
N I

57
+ P338
4-Aminoisoquinoline, 97% 8
[23687‑25‑4] C9H8N2 FW 144.17 NH2
2-Amino-5-iodopyrimidine, 97% 8
[1445‑39‑2] C4H4IN3 FW 221.00 I N
N
N NH2 mp .............................................................................................................................................................. 107 to 113 °C
7
Warning H302-H319 P305 + P351 + P338
mp .............................................................................................................................................................. 218 to 223 °C
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 + 734225-1G glass btl 1g
P338
691844-5G glass btl 5g 5-Aminoisoquinoline, 99%
[1125‑60‑6] Beil. 22,452 C9H8N2 FW 144.17
5-Aminoisatoic anhydride NH2
[169037‑24‑5] C8H6N2O3 FW 178.14 O N

H2N
O
mp .............................................................................................................................................................. 125 to 128 °C
N O
7
H Warning H315-H319-H335 P261-P305 + P351 + P338
mp ............................................................................................................................................................................ >300 °C
56
Danger H301-H315-H317-H318-H335 P261-P280-P301 +
P310-P305 + P351 + P338
560278-1G glass btl 1g 3-Aminoisoxazole, 95%
> α-Aminoisobutyric acid, see 2-Aminoisobutyric acid Page 133 [1750‑42‑1] Beil. 27,IV,4572 C3H4N2O FW 84.08 NH2
N
2-Aminoisobutyric acid, 98% O
α-Aminoisobutyric acid; Aib; 2-Methylalanine bp ............................................................... 226-228 °C n20

D .......................................................................... 1.511
[62‑57‑7] Merck 14,445; Beil. 4,IV,2616 (CH3)2C(NH2)COOH density ..................................... 1.138 g/mL, 25 °C
FW 103.12
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp ............................................................................................................................................................................ ≥300 °C
850993-25G poly btl 25 g 424218-5ML glass btl 5 mL
850993-100G poly btl 100 g 424218-25ML glass btl 25 mL

AHB A, 0613, UNP EU
n Aminoisoxazolid n
> 4-Amino-3-isoxazolidinone, see D-Cycloserine Page 829 (−)-2-Amino-6-mercaptopurine riboside hydrate, 98%
(R)-4-Amino-3-isoxazolidone, see D-Cycloserine Page 829
(S)-4-Amino-3-isoxazolidone, see L-Cycloserine Page 829 Thioguanosine SH
5-Aminolaevulinic acid hydrochloride, see 5-Aminolevulinic acid hydro- [345909‑25‑3] Merck 14,9338 C10H13N5O4S ·
N N
chloride Page 134 xH2O FW 299.31 (Anh) H2 N N
N
5-Aminolevulinic acid hydrochloride, ~98% HO • xH2O
O
δ-Aminolevulinic acid hydrochloride; ALA; 5-Aminolaevulinic acid
hydrochloride; 5-Amino-4-oxopentanoic acid hydrochloride OH OH
A [5451‑09‑2] Merck 14,446; Beil. 4,IV,3265 NH2CH2C(O)CH2CH2COOH ·

HCl FW 167.59 mp ............................................................................................................................................... 230 to 231 °C (dec.)
Intermediate in heme biosynthesis. D −69.9°, c = 1.3 in 0.1 M NaOH

[α]22
store at: −20°C 858412-1G glass btl 1g
A3785-500MG glass btl 500 mg > 4-Amino-2-mercaptopyrimidine, see 2-Thiocytosine Page 2425
A3785-1G glass btl 1g 2-Amino-5-mercapto-1,3,4-thiadiazole, see 5-Amino-1,3,4-thiadiazole-2-thiol
Page 168
A3785-5G glass btl 5g 3-Amino-5-mercapto-1,2,4-triazole, see 3-Amino-1,2,4-triazole-5-thiol
Page 170
5-Aminolevulinic acid-5-13C hydrochloride Aminomethanamidine hydrochloride, see Guanidine hydrochloride
H2N13CH2COCH2CH2CO2H · HCl FW 168.58 Page 1405
 99 atom % 13
C Aminomethanesulfonic acid, 97%
586757-100MG glass btl 100 mg [13881‑91‑9] Beil. 1,IV,3055 NH2CH2SO3H FW 111.12
mp ................................................................................................................................................................ 184 °C (dec.)
5-Aminolevulinic acid-13C5, 15
N hydrochloride, 97% 8
5
(CP) Danger H314 P280-P305 + P351 + P338-P310
H215N13CH213CO(13CH2)213CO2H · HCl FW 173.55
mp ................................................................................................................................................................. 156 °C (dec.) 127442-10G glass btl 10 g
 99 atom % 13C; 98 atom % 15N
mol wt 173.48, atom % calculation 2-Amino-4′-methoxyacetophenone hydrochloride, 90%
711187 [3883‑94‑1] Beil. 14,III,549 CH3OC6H4C(O)CH2NH2 · HCl FW 201.65
mp .............................................................................................................................................................. 190 to 193 °C
> 6-Amino-2,4-lutidine, see 2-Amino-4,6-dimethylpyridine Page 118
 technical
Aminomalononitrile p-toluenesulfonate, 98%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[5098‑14‑6] NH2CH(CN)2 · CH3C6H4SO3H FW 253.28
7
Warning H302-H312-H332 P280 415944-5G glass btl 5g
3-Amino-4-methoxybenzenesulfonic acid, 98%

221147-25G glass btl 25 g 4-Methoxymetanilic acid
[98‑42‑0] Beil. 14,814 H2NC6H3(OCH3)SO3H FW 203.22
5-Amino-2-mercaptobenzimidazole, 96% mp ................................................................................................................................................................ 305 °C (dec.)
[2818‑66‑8] C7H7N3S FW 165.22
57
H2N N Danger H314-H317 P280-P305 + P351 + P338-P310
SH
N
H 157031-25G glass btl 25 g
mp .............................................................................................................................................................. 240 to 244 °C 5-Amino-2-methoxybenzenesulfonic acid, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338 [6470‑17‑3] CH3OC6H3(NH2)SO3H FW 203.22
536067-100G glass btl 100 g 2-Amino-3-methoxybenzoic acid, 98%
6-Amino-2-mercaptobenzothiazole, 97% 3-Methoxyanthranilic acid

[3177‑80‑8] Beil. 14,I,654 H2NC6H3(OCH3)CO2H FW 167.16
6-Amino-2-benzothiazolethiol N mp .............................................................................................................................................................. 169 to 170 °C
[7442‑07‑1] C7H6N2S2 FW 182.27 SH
7
H2N S Warning H315-H319-H335 P261-P305 + P351 + P338
7
454370-1G glass btl 1g 2-Amino-4-methoxybenzoic acid, 97% 8

454370-5G glass btl 5g [4294‑95‑5] C8H9NO3 FW 167.16 O
> 2-Amino-4-mercaptobutyric acid, see DL-Homocysteine Page 1450 OH
DL-2-Amino-4-mercaptobutyric acid 1,4-thiolactone hydrochloride, see DL-
Homocysteine thiolactone hydrochloride Page 1451 H3CO NH2
(R)-2-Amino-3-mercaptopropionic acid, see L-Cysteine Page 830
(S)-2-Amino-3-mercaptopropionic acid, see D-Cysteine Page 830 mp .............................................................................................................................................................. 175 to 180 °C
(±)-2-Amino-3-mercaptopropionic acid, see DL-Cysteine Page 831
7
Warning H302

AHB A, 0613, UNP EU
n Aminomethoxymet n
2-Amino-5-methoxybenzoic acid, 97% 2-Amino-4-methoxybenzothiazole, 96%

[6705‑03‑9] (H2N)C6H3(OCH3)CO2H FW 167.16 [5464‑79‑9] C8H8N2OS FW 180.23 OCH3
mp .............................................................................................................................................................. 148 to 152 °C N
NH2
7
Warning H302-H319 P305 + P351 + P338 S
mp .............................................................................................................................................................. 153 to 155 °C

7
665118-5G glass btl 5g Warning H302-H312-H332 P280
3-Amino-2-methoxybenzoic acid, 96% 138215-1G glass btl 1g A

[861306‑04‑9] C8H9NO3 FW 167.16 O 138215-5G glass btl 5g
OH
OCH3 2-Amino-6-methoxybenzothiazole, 98%

NH2
[1747‑60‑0] Beil. 27,II,334 C8H8N2OS N
mp ................................................................................................................................................................. 98 to 102 °C FW 180.23 NH2
H3CO S
7
Warning H302
mp .............................................................................................................................................................. 165 to 167 °C
7
3-Amino-4-methoxybenzoic acid, ≥98% 162590-50G glass btl 50 g
[2840‑26‑8] Beil. 14,I,657 H2NC6H3(OCH3)CO2H FW 167.16 162590-250G glass btl 250 g
mp .............................................................................................................................................................. 208 to 210 °C 3-Amino-2-methoxydibenzofuran, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338 [5834‑17‑3] Beil. 18,IV,7352 C13H11NO2 OCH3
FW 213.23
186066-10G poly btl 10 g NH2
O
3-Amino-5-methoxybenzoic acid, 97%
mp ................................................................................................................................................................... 92 to 94 °C
[74165‑74‑5] C8H9NO3 FW 167.16
7
H3CO
OH
NH2 264555-100G glass btl 100 g
mp .............................................................................................................................................................. 180 to 185 °C 2-Amino-α-(methoxyimino)-4-thiazoleacetic acid, predomi-

nantly syn, 97%
6
P338 [65872‑41‑5] C6H7N3O3S FW 201.20 O OH
694428-1G glass btl 1g H3CO
N N
S NH2
mp ................................................................................................................................................................ 192 °C (dec.)
[2486‑80‑8] H2NC6H3(OCH3)CO2H FW 167.16
7
mp .............................................................................................................................................................. 149 to 153 °C
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
647624-5G glass btl 5g > 4-Amino-5-methoxy-2-methylbenzanilide diazotated zinc double salt, see
Fast Violet B Salt Page 1287
4-Amino-3-methoxybenzoic acid, 98% 2-Amino-4-methoxy-6-methylpyrimidine, 98%

[2486‑69‑3] Beil. 14,I,654 H2NC6H3(OCH3)CO2H FW 167.16 [7749‑47‑5] Beil. 25,IV,3385 C6H9N3O FW 139.16 OCH3
mp .............................................................................................................................................................. 186 to 188 °C N
Key building block for the efficient synthesis of carbazole alkaloids H3C N NH2
mukonine and mukonidine via oxidative annulation.1
Lit. cited: 1. Tetrahedron 59, 5317 (2003) mp .............................................................................................................................................................. 156 to 158 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338

[3403‑47‑2] C8H9NO3 FW 167.16 O
H2N
OH
OCH3
mp .............................................................................................................................................................. 161 to 166 °C
7
Warning H302

AHB A, 0613, UNP EU
n Aminomethoxymet n
7
(R)-(+)-1-Amino-2-(methoxymethyl)pyrrolidine, 96% Warning H302-H315-H319-H335 P261-P305 + P351 + P338
(R)-1-Amino-2-(methoxymethyl)pyrrolidine; RAMP
[72748‑99‑3] Beil. 21,V,1,80; Fieser 17,15; 12,30 OCH3 644951-1G glass btl 1g
N
C6H14N2O FW 130.19 NH2 644951-5G 5g
2-Amino-5-(4-methoxyphenyl)-1,3,4-oxadiazole, 97%
bp ................................................. 42 °C/1.8 mmHg n20
D .......................................................................... 1.465
density ........................................ 0.97 g/mL, 25 °C [5711‑61‑5] C9H9N3O2 FW 191.19 N N
NH2
A
Reagent for asymmetric synthesis. O
[α]18
D +79°, neat H3CO
ee (GLC): 98%
mp .............................................................................................................................................................. 245 to 249 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
(S)-(−)-1-Amino-2-(methoxymethyl)pyrrolidine, 95%
SAMP
[59983‑39‑0] Beil. 21,V,1,89; Fieser 12,30; 14,22; 17,15; 16,12 (1S,2S)-(+)-2-Amino-3-methoxy-1-phenyl-1-propanol, 98%
C6H14N2O FW 130.19 [51594‑34‑4] Fieser 12,381; 13,17 CH3OCH2CH(NH2)CH(C6H5)OH
bp ................................................. 42 °C/1.8 mmHg n20
D .......................................................................... 1.465 FW 181.23
density ........................................ 0.97 g/mL, 25 °C mp ................................................................................................................................................................... 51 to 53 °C
D −79°, neat
[α]20 [α]18
ee (GLC): 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
281573-1G ampule 1g
2-Amino-4-methoxy-6-methyl-1,3,5-triazine, 97%
[1668‑54‑8] C5H8N4O FW 140.14 OCH3
3-Amino-3-(4-methoxyphenyl)propionic acid, 97%
N N
H 3C NH2
[5678‑45‑5] C10H13NO3 FW 195.22
N
mp .............................................................................................................................................................. 258 to 261 °C
3-Amino-5-(4-methoxyphenyl)pyrazole, 97%
7
[19541‑95‑8] C10H11N3O FW 189.21 NH2
522996-10G glass btl 10 g N
N
H
2-Amino-6-methoxy-3-nitropyridine, 97% 8 H3CO
[73896‑36‑3] C6H7N3O3 FW 169.14 NO2

mp .............................................................................................................................................................. 140 to 144 °C
7
H3CO N NH2 Warning H315-H319-H335 P261-P305 + P351 + P338
78
Danger H302-H315-H319-H334-H335 P261-P305 + P351 +
P338-P342 + P311 2-Amino-5-(4-methoxyphenyl)-1,3,4-thiadiazole, 97%
704598-1G glass btl 1g [1014‑25‑1] C9H9N3OS FW 207.25 N N
704598-5G glass btl 5g S NH2
H3CO
2-Amino-4-methoxyphenol, 95% 8
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Hydroxy-5-methoxyaniline OH
[20734‑76‑3] C7H9NO2 FW 139.15
H3CO NH2
mp .............................................................................................................................................................. 135 to 140 °C
5-Amino-2-methoxypyridine, 95%
7
Warning H302
[6628‑77‑9] Beil. 22,II,408 C6H8N2O FW 124.14 H2N
722367-1G glass btl 1g OCH3

N
5-Amino-2-methoxyphenol, 98%
mp ............................................................ 29 to 31 °C n20
D .......................................................................... 1.575
3-Hydroxy-4-methoxyaniline bp ............................................. 85-90 °C/1 mmHg
[1687‑53‑2] Beil. 13,I,307 H2NC6H3(OCH3)OH FW 139.15
7
mp .............................................................................................................................................................. 130 to 132 °C
7
Warning H302-H312-H315-H319-H332-H335 P261-P280-P305 + P351 A61209-5G glass btl 5g
+ P338
3-Amino-6-methoxypyridine-2-acetonitrile, 97% 8
(3-Amino-6-methoxypyridin-2-yl)acetonitrile NH2
5-Amino-3-(4-methoxyphenyl)isoxazole, 97%
[111796‑01‑1] C8H9N3O FW 163.18
CN
[86685‑98‑5] C10H10N2O2 FW 190.20 OCH3 H3CO N
mp .............................................................................................................................................................. 110 to 115 °C

N
57
H2 N O Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338
mp .............................................................................................................................................................. 135 to 139 °C 709964-500MG glass btl 500 mg

AHB A, 0613, UNP EU
n Aminomethylbenz n
> (3-Amino-6-methoxypyridin-2-yl)acetonitrile, see 3-Amino-6-methoxypyr- 2-Amino-6-methylbenzoic acid, 99%
idine-2-acetonitrile Page 136
6-Methylanthranilic acid
4-Amino-6-methoxypyrimidine, 98% [4389‑50‑8] Beil. 14,IV,1351 H2NC6H3(CH3)CO2H FW 151.16
[696‑45‑7] Beil. 25,IV,3359 C5H7N3O FW 125.13 mp ............................................................................................................................................... 128 to 130 °C (dec.)
NH2
7
Warning H315-H319-H335 P261-P305 + P351 + P338
N
H3CO N
mp .............................................................................................................................................................. 157 to 160 °C 3-(Aminomethyl)benzoic acid hydrochloride, ≥98.0% (HPLC) A
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[876‑03‑9] C8H9NO2 · HCl FW 187.62 O
513245-5G glass btl 5g OH

• HCl
8-Amino-6-methoxyquinoline hydrobromide, 97%

NH2
[312693‑53‑1] C10H10N2O · HBr FW 255.11 H3CO
7
N store at: 2-8°C
NH2 • HBr
mp ................................................................................................................................................................. 238 °C (dec.) 3-Amino-2-methylbenzoic acid, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338 3-Amino-o-toluic acid
[52130‑17‑3] Beil. 14,IV,1348 H2NC6H3(CH3)CO2H FW 151.16
> 1-(Aminomethyl)adamantane, see 1-Adamantanemethylamine Page 56
7
Warning H315-H319-H335 P261-P305 + P351 + P338
4-Amino-N-methylbenzenemethanesulfonamide, see 4-Amino-N-methyl-α-
toluenesulfonamide Page 147
2-Amino-5-methylbenzenesulfonic acid, see 4-Aminotoluene-3-sulfonic acid 334189-50G glass btl 50 g
Page 170
3-Amino-4-methylbenzoic acid, 99%
2-(Aminomethyl)benzimidazole dihydrochloride, 98% 3-Amino-p-toluic acid
[5993‑91‑9] C8H9N3 · 2HCl FW 220.10 [2458‑12‑0] Beil. 14,IV,1361 H2NC6H3(CH3)CO2H FW 151.16
mp ................................................................................................................................................................. 264 °C (dec.) mp .............................................................................................................................................................. 164 to 168 °C
7
2-Amino-1-methylbenzimidazole, 95% A62809-50G poly btl 50 g

[1622‑57‑7] Beil. 25,10,408 C8H9N3 FW 147.18 N A62809-250G poly btl 250 g
NH2
N 4-(Aminomethyl)benzoic acid, 97%
CH3
[56‑91‑7] Beil. 14,IV,1362 H2NCH2C6H4CO2H FW 151.16
7 mp ............................................................................................................................................................................ ≥300 °C
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Aminomethyl-1,4-benzodioxane, 97% 283746-25G poly btl 25 g

283746-100G poly btl 100 g
(2,3-Dihydrobenzo-1,4-dioxin-2-yl)methylamine; 1,4- O
Benzodioxane-2-methylamine; 2,3-Dihydro-1,4- 4-Amino-2-methylbenzoic acid, 95%
NH2
benzodioxin-2-methanamine O
[2486‑75‑1] C8H9NO2 FW 151.16 O
[4442‑59‑5] C9H11NO2 FW 165.19
bp ....................................... 105-110 °C/3 mmHg n20
D ....................................................................... 1.5594 OH
density .................................. 1.1679 g/mL, 25 °C H2N CH3
57
Danger H315-H318-H335 P261-P280-P305 + P351 + P338
mp .............................................................................................................................................................. 160 to 165 °C
7
Warning H302-H319 P305 + P351 + P338
2-Amino-3-methylbenzoic acid, 99% 691437-5G glass btl 5g

3-Methylanthranilic acid 4-Amino-3-methylbenzoic acid, 98%
[2486‑70‑6] Beil. 14,480 H2NC6H3(CH3)CO2H FW 151.16
mp .............................................................................................................................................................. 174 to 177 °C
mp .............................................................................................................................................................. 169 to 171 °C
7
Warning H302
7
Warning H315-H319-H335 P261-P305 + P351 + P338

5-Methylanthranilic acid
5-Amino-o-toluic acid
[2840‑04‑2] H2NC6H3(CH3)CO2H FW 151.16
mp ................................................................................................................................................................. 175 °C (dec.)
mp .............................................................................................................................................................. 194 to 199 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7


AHB A, 0613, UNP EU
n Aminomethylbenz n
2-Amino-4-methylbenzonitrile, 97% 5-Amino-2-methylbenzothiazole dihydrochloride

[26830‑96‑6] Beil. 14,485 H2NC6H3(CH3)CN FW 132.16 [32770‑99‑3] Beil. 27,II,427 C8H8N2S · H2N N
mp .................................................................................................................................................................... 92 to 95 °C 2HCl FW 237.15 CH3 • 2HCl
S
7
+ P338 mp ............................................................................................................................................... 249 to 250 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
A 2-Amino-5-methylbenzonitrile, 97% A63309-5G glass btl
> 2-(Aminomethyl)benzotrifluoride, see 2-(Trifluoromethyl)benzylamine

5g
[5925‑93‑9] H2NC6H3(CH3)CN FW 132.16

Page 2505
mp .................................................................................................................................................................... 59 to 63 °C (S)-α-(Aminomethyl)benzyl alcohol, see (S)-2-Amino-1-phenylethanol
Page 155
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Amino-3-methylbenzyl alcohol, 97%

[57772‑50‑6] H2NC6H3(CH3)CH2OH FW 137.18
2-Amino-6-methylbenzonitrile, ≥97.0% mp ................................................................................................................................................................... 67 to 69 °C
6-Amino-o-tolunitrile
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[56043‑01‑7] Beil. 14,II,290 C8H8N2 FW 132.16
may discolor to brown on storage 334197-5G glass btl 5g
7
Warning H315-H319-H335 P261-P305 + P351 + P338
08419-5G poly btl 5g [34897‑84‑2] H2NC6H3(CH3)CH2OH FW 137.18
08419-25G poly btl 25 g mp .............................................................................................................................................................. 123 to 126 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
4-(Aminomethyl)benzonitrile hydrochloride, 97%
4-Cyanobenzylamine hydrochloride 332984-5G glass btl 5g
[15996‑76‑6] NH2CH2C6H4CN · HCl FW 168.62
mp .............................................................................................................................................................. 274 to 279 °C
631396-5G glass btl 5g [83647‑42‑1] H2NC6H3(CH3)CH2OH FW 137.18
7
Warning H315-H319-H335 P261-P305 + P351 + P338
5-Amino-2-methylbenzonitrile, 97%
[50670‑64‑9] H2NC6H3(CH3)CN FW 132.16 334200-1G glass btl 1g
7

549584-25G glass btl 25 g [81863‑45‑8] Beil. 13,635 H2NC6H3(CH3)CH2OH FW 137.18
mp .............................................................................................................................................................. 107 to 109 °C
2-Amino-4-methylbenzophenone, 99%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[4937‑62‑6] Beil. 14,107 H2NC6H3(CH3)C(O)C6H5 FW 211.26
7
Warning H315-H319-H335 P261-P305 + P351 + P338 335320-25G poly btl 25 g
(R)-2-(Aminomethyl)-1-Boc-pyrrolidine, 98%
(R)-2-(Aminomethyl)-1-(tert-butoxycarbonyl)pyrrolidine;
2-Amino-4-methylbenzothiazole, 97% NH2
tert-Butyl (R)-2-(aminomethyl)-1-pyrrolidinecarboxylate N
[1477‑42‑5] Beil. 27,193 C8H8N2S FW 164.23 CH3 [259537‑92‑3] C10H20N2O2 FW 200.28 Boc
N
NH2 ≥97.5% (GC)
S
[α]D +47.0±2°, c = 1 in chloroform
mp .............................................................................................................................................................. 137 to 139 °C enantiomeric excess: ≥99.0%
57
Danger H302-H314 P280-P305 + P351 + P338-P310
7
Warning H302
store at: 2-8°C

193224-25G glass btl 25 g 672181-500MG glass btl 500 mg
2-Amino-6-methylbenzothiazole, 98% (S)-2-(Aminomethyl)-1-Boc-pyrrolidine, 97%

[2536‑91‑6] Beil. 27,II,241 C8H8N2S FW 164.23 (S)-2-(Aminomethyl)-1-(tert-butoxycarbonyl)pyrrolidine; tert-Butyl (S)-
N
NH2
2-(aminomethyl)-1-pyrrolidinecarboxylate
H3C S [119020‑01‑8] C10H20N2O2 FW 200.28
≥96.5% (GC)
mp .............................................................................................................................................................. 140 to 142 °C 96.5-103.5% (NT)
enantiomeric excess (GC): ≥97.5%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
57
Danger H302-H314 P280-P305 + P351 + P338-P310
288373-25G glass btl 25 g store at: 2-8°C

AHB A, 0613, UNP EU
n Aminomethylcoum n
> (R)-2-Amino-3-methylbutanamide hydrochloride, see D-Valinamide hydro- (S)-(+)-2-Amino-3-methyl-1-butanol, 96%
chloride Page 2596
L-Valinol
(R)-(−)-2-Amino-3-methylbutane [2026‑48‑4] Beil. 4,III,805; Fieser 13,341; 16,380; 12,563
(R)-(−)-3-Methyl-2-butylamine (CH3)2CHCH(NH2)CH2OH FW 103.16
NH2 mp ............................................................ 30 to 32 °C density ................................. 0.926 g/mL, 25 °C
[34701‑33‑2] C5H13N FW 87.16 H3 C
bp .................................................... 81 °C/8 mmHg n20
CH3 D ....................................................................... 1.4548
CH3
[α]25
D +10°, c = 10 in H2O
A
density ................................................................................................................................................ 0.75 g/mL, 20 °C ee (GLC): 95%
7
Warning H319 P305 + P351 + P338
256
Danger H225-H302-H314-H331 P210-P261-P280-P305
+ P351 + P338-P310
 ≥97.0% (GC)
[α]D −5.5±1°, neat 186708-5G glass btl 5g
18241-5G-F glass btl 5g > (S)-2-(Aminomethyl)-1-(tert-butoxycarbonyl)pyrrolidine, see (S)-2-(Amino-
methyl)-1-Boc-pyrrolidine Page 138
 ChiPros®, produced by BASF, 99% 8 (R)-2-(Aminomethyl)-1-(tert-butoxycarbonyl)pyrrolidine, see (R)-2-(Amino-
≥98.5% (GC) 8-(4-Amino-1-methylbutylamino)-6-methoxyquinoline diphosphate salt,
enantiomeric excess: ≥98.5% see Primaquine bisphosphate Page 2186
726907-5G glass btl 5g 3-Amino-3-methyl-1-butyne, see 2-Methyl-3-butyn-2-amine Page 1754
(±)-3-Amino-5-methylcaproic acid, see DL-β-Homoleucine Page 1451
5-(Aminomethyl)-2-chloropyridine, 97%
(S)-(+)-2-Amino-3-methylbutane
[97004‑04‑1] C6H7ClN2 FW 142.59
(S)-(+)-3-Methyl-2-butylamine H2N
[22526‑46‑1] C5H13N FW 87.16 N Cl
density ............................................................................................................................................. 0.746 g/mL, 20 °C
Danger mp ................................................................................................................................................................... 28 to 34 °C
56
Danger H301-H315-H317-H318-H335 P261-P280-P301 +
 ≥98.0% (GC) P310-P305 + P351 + P338
[α]20
D +5.3±0.5°, neat
n20
D ...................................................................................................................................................................................... 1.405
257
H225-H302-H312-H314-H332 P210-P260-P280-P284-
P305 + P351 + P338-P310 7-Amino-2-methylchromone, 95%
91936-1G-F glass btl 1g [30779‑70‑5] C10H9NO2 FW 175.18 O
 ChiPros®, produced by BASF 8 H2N O CH3

≥99.0% (GC)
enantiomeric excess: ≥99% mp ...................................................................................................................................................... 174.5 to 179.5 °C
7
Warning H319 P305 + P351 + P338
2579
H225-H302-H312-H314-H332-H411 P210-P273-
P280-P305 + P351 + P338-P310
726850-25G glass btl 25 g 7-Amino-4-methylcoumarin
> D-2-Amino-3-methylbutanoic acid, see D-Valine Page 2596 Coumarin 120 CH3
L-2-Amino-3-methylbutanoic acid, see L-Valine Page 2596
DL-2-Amino-3-methylbutanoic acid, see DL-Valine Page 2596
[26093‑31‑2] Beil. 18,V,11,445 C10H9NO2
FW 175.18
H 2N O O
2-Amino-3-methyl-1-butanol, 97%
DL-Valinol mp .............................................................................................................................................................. 223 to 226 °C
7
[16369‑05‑4] Beil. 4,II,747 (CH3)2CHCH(NH2)CH2OH FW 103.16 Warning H315-H319-H335 P261-P305 + P351 + P338
bp ............................................. 75-77 °C/8 mmHg n20
D ....................................................................... 1.4543
density ..................................... 0.936 g/mL, 25 °C
 99%
7
Warning H315-H319-H335 P261-P305 + P351 + P338 Suitable as laser dye
Fluorescent labeling reagent for trace determination of enzymes.1
184837-1G glass btl 1g λmax ............................................................................................................................................................................ 354 nm
184837-5G glass btl 5g Lit. cited: 1. Aldrichimica Acta 15, 42 (1982)
store at: 2-8°C
(R)-(−)-2-Amino-3-methyl-1-butanol, 98%
D-Valinol
[4276‑09‑9] Beil. 4,III,805 (CH3)2CHCH(NH2)CH2OH FW 103.16
mp .................................................................................................................................................................... 35 to 36 °C fluorescence ............................................................................ λex 365 nm, λem 440 nm in ethanol(lit.)
D −16°, c = 10 in ethanol
[α]20 store at: 2-8°C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
284483-1G glass btl 1g A9891-1G poly btl 1g
284483-5G glass btl 5g A9891-5G poly btl 5g
AHB A, 0613, UNP EU
n Aminomethylcrow n
2-Aminomethyl-15-crown-5, 95% trans-2-(Aminomethyl)cyclohexanol hydrochloride, 97%

1,4,7,10,13-Pentaoxacyclopentadecane-2-methan- NH2
[24948‑05‑8] C7H15NO · HCl FW 165.66 OH
amine O O • HCl
NH2
[83585‑56‑2] C11H23NO5 FW 249.30 O
O
O 96.5-103.5% (AT)
≥96.5% (GC)
bp ........................................... 115 °C/0.08 mmHg n20
D ............................................................................. 1.48
7
A
density ..................................... 1.134 g/mL, 25 °C
7

cis-2-Amino-2-methylcyclopentanecarboxylic acid hydro-
chloride, ≥98.0% (CHN)
[156292‑34‑1] C7H13NO2 · HCl FW 179.64 O
2-Aminomethyl-18-crown-6, 95%
OH
• HCl
1,4,7,10,13,16-Hexaoxacyclooctadecane-2-methanamine NH2
CH3
[83585‑61‑9] C13H27NO6 FW 293.36
bp ........................................... 135 °C/0.08 mmHg n20
D .......................................................................... 1.479
density ..................................... 1.126 g/mL, 25 °C 39927-500MG-F poly btl 500 mg
7 > (1-Aminomethyl-cyclopentyl)-carbamic acid tert-butyl ester, see 1-(Boc-

+ P338 amino)-1-aminomethyl cyclopentane Page 370
(Aminomethyl)cyclopropane, 97%
Cyclopropanemethylamine
> (Aminomethyl)cyclohexane, see Cyclohexanemethylamine Page 809
Beil. 12,IV,4 C3H5CH2NH2 FW 71.12
cis-2-Amino-2-methylcyclohexanecarboxylic acid hydro- bp ...................................................................................................................................................... 86 °C/758 mmHg
chloride, ≥98.0% density ................................................................................................................................................ 0.82 g/mL, 25 °C
water .............................................................................................................................................................................. ≤15%
[202921‑88‑8] C8H15NO2 · HCl FW 193.67 O
25
Danger H225-H314 P210-P280-P305+P351+P338-P310
OH
NH2 • HCl
CH3 359521-1ML ampule 1 mL
> (Aminomethyl)cyclopropane hydrochloride, see Cyclopropanemethylamine

30254-500MG-F poly btl 500 mg hydrochloride Page 826
(+)-α-(Aminomethyl)-3,4-dihydroxybenzyl alcohol (+)-tartrate (1:1), see (S)-
trans-4-(Aminomethyl)cyclohexanecarboxylic acid, 97% (+)-Norepinephrine L-bitartrate Page 1940
Tranexamic acid; AMCA; AMCHA; HAKU; TAMCHA (R)-(+)-2-Amino-3-methyl-1,1-diphenyl-1-butanol, 95%

[1197‑18‑8] Merck 14,9569; Beil. 14,III,860 H2NCH2C6H10CO2H
FW 157.21 [86695‑06‑9] (CH3)2CHCH(NH2)C(C6H5)2OH FW 255.35
mp ................................................................................................................................................................... 95 to 99 °C
mp ............................................................................................................................................................................ >300 °C
Used as a lysine analogue to characterize binding sites in [α]20
plasminogen.1,2 A Product of Onyx Scientific, U.K.
7
Lit. cited: 1. Biochemistry 33, 3599 (1994) Warning H315-H319-H335 P261-P305 + P351 + P338
2. Biochemistry 32, 10936 (1993)
7
857653-10G poly btl 10 g
(S)-(−)-2-Amino-3-methyl-1,1-diphenyl-1-butanol, 98%
857653-50G poly btl 50 g
857653-250G poly btl 250 g
(S)-2-Amino-1,1-diphenyl-3-methyl-1-butanol; 1,1-Diphenyl-L-valinol
[78603‑95‑9] (CH3)2CHCH(NH2)C(C6H5)2(OH) FW 255.35
1-Aminomethyl-1-cyclohexanol hydrochloride, 98% mp ................................................................................................................................................................... 95 to 99 °C
[19968‑85‑5] H2NCH2C6H10OH · HCl FW 165.66 D −132°, c = 1 in chloroform
[α]20
mp .............................................................................................................................................................. 217 to 219 °C A Product of Onyx Scientific, U.K.
7
(1R,2S)-(−)-trans-2-(Aminomethyl)cyclohexanol, 97% 8 551015-1G glass btl 1g

[133269‑86‑0] C7H15NO FW 129.20 551015-5G glass btl 5g
OH
NH2 (R)-(+)-2-Amino-4-methyl-1,1-diphenyl-1-pentanol, 98%

[161832‑74‑2] (CH3)2CHCH2CH(NH2)C(C6H5)2OH FW 269.38
≥96.5% (GC) mp .............................................................................................................................................................. 144 to 147 °C
 ee (HPLC): 99%
5
Danger H314 P280-P305 + P351 + P338-P310 store at: 2-8°C
[α]20
7
689351-500MG glass btl 500 mg Warning H315-H319-H335 P261-P305 + P351 + P338
(1S,2R)-(+)-trans-2-(Aminomethyl)cyclohexanol, 97% 8 554553-1G glass btl 1g

[133269‑87‑1] C7H15NO FW 129.20 554553-5G glass btl 5g
≥96.5% (GC)
5

AHB A, 0613, UNP EU
n Aminomethylisox n
(S)-(−)-2-Amino-4-methyl-1,1-diphenyl-1-pentanol, 98% 2-Amino-5-methylhexane, ≥99.0% (GC)

[78603‑97‑1] (CH3)2CHCH2CH(NH2)C(C6H5)2OH FW 269.38 1,4-Dimethylpentylamine; 5-Methyl-2-hexylamine
mp .............................................................................................................................................................. 132 to 136 °C [28292‑43‑5] Beil. 4,III,377 (CH3)2CHCH2CH2CH(CH3)NH2 FW 115.22
[α]20 bp ....................................................................................................................................................................... 128-129 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338 density ............................................................................................................................................. 0.760 g/mL, 20 °C
n20
D ...................................................................................................................................................................................... 1.416
25
554561-1G glass btl 1g Danger H226-H314 P280-P305 + P351 + P338-P310
554561-5G
2-(Aminomethyl)-1-ethylpyrrolidine, 97%
glass btl 5g
08490-25ML glass btl 25 mL A
> (3R,4S)-3-Amino-4-methylhexanoic acid hydrochloride, see L-β-Homoiso-
[26116‑12‑1] C7H16N2 FW 128.22 leucine hydrochloride Page 1451
NH2
N (S)-3-Amino-5-methylhexanoic acid hydrochloride, see L-β-Homoleucine
CH3 (±)-3-Amino-5-methylhexanoic acid, see DL-β-Homoleucine Page 1451
DL-α-(Aminomethyl)-4-hydroxy-3-methoxybenzenemethanol hydro-
bp .......................................... 58-60 °C/16 mmHg n20
D .......................................................................... 1.466 chloride, see DL-Normetanephrine hydrochloride Page 1941
density ..................................... 0.884 g/mL, 25 °C 4-(Aminomethyl)-5-hydroxy-6-methyl-3-pyridinemethanol dihydro-
chloride, see Pyridoxamine dihydrochloride Page 2222
27
Warning H226-H315-H319-H335 P261-P305 + P351 + P338 4-(Aminomethyl)-5-hydroxy-6-(methyl-d3)-3-pyridinemethanol dihydro-
chloride, see Pyridoxamine-methyl-d3 dihydrochloride Page 2222
7-Amino-4-methyl-2-hydroxyquinoline, see Carbostyril 124 Page 622
655600-5G glass btl 5g 2-Amino-1-methyl-2-imidazolin-4-one, see Creatinine Page 783
655600-25G glass btl 25 g Creatinine hydrochloride Page 784
(R)-(+)-2-Aminomethyl-1-ethylpyrrolidine, 90% 4-(Aminomethyl)indole, 95% 8

[22795‑97‑7] C7H16N2 FW 128.22 [3468‑18‑6] C9H10N2 FW 146.19 H2N
NH2
N
CH3
N
H
bp ....................................... 50-52 °C/760 mmHg n20
D .......................................................................... 1.467
density ..................................................... 0.929 g/mL mp .............................................................................................................................................................. 130 to 135 °C
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
257
Danger H226-H302-H315-H318-H335 P261-P280-P305
+ P351 + P338 P338
(S)-(−)-2-Aminomethyl-1-ethylpyrrolidine, 96% 5-(Aminomethyl)indole, 95%

[22795‑99‑9] C7H16N2 FW 128.22 C9H10N2 FW 146.19
H2N
bp ..................................................................... 50-52 °C n20
D ....................................................................... 1.4670 N
density ..................................... 0.919 g/mL, 25 °C H
[α]D −109.0 to −95.0°, c = 1 in methanol mp .............................................................................................................................................................. 114 to 118 °C
27 7
Warning H226-H315-H319-H335 P261-P305 + P351 + P338 Warning H302-H315-H319-H335 P261-P305 + P351 + P338

(2S,4S,5R)-2-Aminomethyl-5-ethylquinuclidine, ≥95.0% (GC) 5-Amino-2-methylindole, 97%

(2S,4S,5R)-5-Ethyl-2-quinuclidinyl-methylamine [7570‑49‑2] C9H10N2 FW 146.19 H2N
H3C
[475160‑59‑9] C10H20N2 FW 168.28 CH3
N N
H
H2N
mp .............................................................................................................................................................. 153 to 157 °C
7
diastereometric excess 98% (against (2R,4S,5R)-2-Aminomethyl-5- Warning H315-H319-H335 P261-P305 + P351 + P338
ethylquinuclidine)
57
Danger H302-H315-H318 P280-P305 + P351 + P338
store at: 2-8°C
5-Amino-3-methyl-isothiazole hydrochloride
[52547‑00‑9] Beil. 27,IV,4683 C4H6N2S · HCl FW 150.63
mp ............................................................................................................................................................................... 300 °C
> 4-Amino-10-methylfolic acid, see (±)Amethopterin hydrate Page 88 NH4Cl ............................................................................................................................................................................. ~10%
4-Amino-10-methylfolic acid hydrate, see L-Amethopterin hydrate
2-Aminomethylfuran, see Furfurylamine Page 1373 155640-25G glass btl 25 g
2-Amino-6-methylheptane, 99% 3-Amino-5-methylisoxazole, ≥98%

6-Methyl-2-heptylamine; 1,5-Dimethylhexylamine [1072‑67‑9] Beil. 27,IV,4685 C4H6N2O FW 98.10 NH2
[543‑82‑8] Merck 14,6757; Beil. 4,IV,764 (CH3)2CH(CH2)3CH(CH3)NH2
N
FW 129.24 H3C O
bp ............................................................... 154-156 °C n20
D .......................................................................... 1.422
density ..................................... 0.767 g/mL, 25 °C mp ................................................................................................................................................................... 59 to 61 °C
27
Warning H226-H302-H315-H319-H335 P261-P305 + P351 + 232270-50G poly btl 50 g
P338
D161292-25G glass btl 25 g
D161292-100G glass btl 100 g

AHB A, 0613, UNP EU
n Aminomethylisox n
5-Amino-3-methylisoxazole, 98% 2-Amino-4-methyl-5-nitropyridine, 98%

[14678‑02‑5] Beil. 27,157 C4H6N2O FW 98.10 CH3
[21901‑40‑6] Beil. 22,IV,4180 C6H7N3O2 FW 153.14 CH3
O2N
H2N N
O
N NH2
mp .................................................................................................................................................................... 85 to 87 °C
mp .............................................................................................................................................................. 223 to 225 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
A 304271-1G glass btl 1g

> 6-Amino-1-methyl-5-nitroso-1H-pyrimidine-2,4-dione, see 6-Amino-1-
(R)-2-(Aminomethyl)-3-methylbutyric acid hydro- 8 methyl-5-nitrosouracil Page 142
chloride, ≥97% (TLC)
2 6-Amino-1-methyl-5-nitrosouracil, 97%
(R)-β -Homovaline hydrochloride CH3 O
C6H13NO2 · HCl FW 167.63 • HCl 6-Amino-1-methyl-5-nitroso-1H-pyrimidine-2,4-dione O
H3C OH
[6972‑78‑7] C5H6N4O3 FW 170.13 HN
NO
NH2
O N NH2
[α]D +12.0±1.0°, c = 1 in DMF CH3
composition
carbon 42.1‑43.9% mp ............................................................................................................................................................................ >300 °C
7
nitrogen 8.1‑8.6% Warning H315-H319-H335 P261-P305 + P351 + P338
(S)-2-(Aminomethyl)-3-methylbutyric acid hydro- 8
chloride, ≥97% (TLC) > DL-2-Amino-3-methylpentanoic acid, see DL-Isoleucine Page 1574
(2R,3S)-2-Amino-3-methylpentanoic acid, see D-allo-Isoleucine Page 1574
(S)-β2-Homovaline hydrochloride (2S,3S)-2-Amino-3-methylpentanoic acid, see L-Isoleucine Page 1574
[925704‑47‑8] C6H13NO2 · HCl FW 167.63 (2RS,3SR)-2-Amino-3-methylpentanoic acid, see DL-allo-Isoleucine
Page 1574
[α]D -12.0±1.0°, c = 1 in DMF (R)-2-Amino-4-methylpentanoic acid, see D-Leucine Page 1608
composition (S)-2-Amino-4-methylpentanoic acid, see L-Leucine Page 1608
carbon 42.1‑43.9% (R)-3-Amino-4-methylpentanoic acid hydrochloride, see L-β-Leucine
nitrogen 8.1‑8.6% (±)-3-Amino-4-methylpentanoic acid, see DL-β-Leucine Page 1609
714143-100MG glass btl 100 mg (±)-Amino-4-methylpentanoic acid, see DL-Leucine Page 1608
(2S,3S)-2-Amino-3-methyl-1-pentanol, see (S)-(+)-Isoleucinol Page 1574
2-(Aminomethyl)-2-methyl-1,3-propanediamine trihydro- (S)-2-Amino-4-methyl-1-pentanol, see (S)-(+)-Leucinol Page 1610
chloride, ≥95.0% (NT) 4-Amino-4-methyl-2-pentanone hydrogenoxalate, see Diacetonamine
hydrogenoxalate Page 855
1,1,1-Tris(aminomethyl)ethane trihydrochloride; (R)-2-Amino-2-methyl-4-pentenoic acid, see (R)-(+)-α-Allylalanine
H2N NH2 Page 67
Ethylidintris(methylamine) trihydrochloride H3C NH2
• 3HCl
(S)-2-Amino-2-methyl-4-pentenoic acid, see (S)-(−)-α-Allylalanine
C5H15N3 · 3HCl FW 226.58 Page 67
mp ................................................................................................................................................................. 270 °C (dec.)
2-Amino-3-methylphenol, 96%
57
Danger H302-H314 P280-P305 + P351 + P338-P310
2-Amino-m-cresol
690023-1G glass btl 1g [2835‑97‑4] Beil. 13,589 H2NC6H3(CH3)OH FW 123.15
> 1-(Aminomethyl)naphthalene, see 1-Naphthylmethylamine Page 1891 mp .............................................................................................................................................................. 149 to 152 °C
1-Amino-2-methylnaphthalene, see 2-Methyl-1-naphthylamine Page 1806
7
Warning H315-H319-H335 P261-P305 + P351 + P338
6-Amino-2-methylnicotinonitrile, see 6-Amino-2-methylpyridine-3-carbon-
itrile Page 145
2-Amino-3-methyl-5-nitropyridine, 97% 8 336572-25G glass btl 25 g
[18344‑51‑9] C6H7N3O2 FW 153.14 O2N CH3
N NH2 2-Amino-p-cresol; 3-Amino-4-hydroxytoluene; 2-Hydroxy-5-methyl-
aniline
mp .............................................................................................................................................................. 256 to 260 °C
[95‑84‑1] Beil. 13,IV,1712 H2NC6H3(CH3)OH FW 123.15
57
Danger H302-H318 P280-P305 + P351 + P338
mp .............................................................................................................................................................. 133 to 136 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Amino-4-methyl-3-nitropyridine, 98%
2-Amino-3-nitro-4-picoline CH3
6-Amino-m-cresol; 4-Amino-3-hydroxytoluene; 2-Hydroxy-4-methyl-
[6635‑86‑5] Beil. 22,V,9,343 C6H7N3O2 FW 153.14 NO2
aniline
N NH2 [2835‑98‑5] Beil. 13,III,1552 H2NC6H3(CH3)OH FW 123.15
mp .............................................................................................................................................................. 159 to 162 °C
mp .............................................................................................................................................................. 136 to 140 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338


AHB A, 0613, UNP EU
n Aminomethylphos n
3-Amino-2-methylphenol, 95% > (R)-(+)-2-Amino-2-methyl-3-phenylpropionic acid, see α-Methyl-D-phenyl-

alanine Page 1823
3-Amino-o-cresol (S)-(−)-2-Amino-2-methyl-3-phenylpropionic acid, see α-Methyl-L-phenyl-
[53222‑92‑7] Beil. 13,579 H2NC6H3(CH3)OH FW 123.15 alanine Page 1823
(±)-2-Amino-2-methyl-3-phenylpropionic acid, see α-Methyl-DL-phenylala-
mp .............................................................................................................................................................. 129 to 130 °C nine Page 1823
7
Warning H315-H319-H335 P261-P305 + P351 + P338
5-Amino-3-methyl-1-phenylpyrazole, 97%
225061-1G glass btl 1g [1131‑18‑6] C10H11N3 FW 173.21 CH3
H2N N
N A
2-Amino-5-hydroxytoluene; 4-Hydroxy-2-methylaniline; 4-Amino-m-
cresol
mp .............................................................................................................................................................. 176 to 179 °C mp .............................................................................................................................................................. 114 to 117 °C
7 7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 Warning H315-H319-H335 P261-P305 + P351 + P338

5-Amino-2-methylphenol, 97% 5-Amino-3-(4-methylphenyl)pyrazole, 97%

3-Hydroxy-4-methylaniline; 5-Amino-o-cresol; 4-Amino-2-hydroxy- [78597‑54‑3] C10H11N3 FW 173.21 CH3
toluene
mp .............................................................................................................................................................. 160 to 162 °C
N
7
Warning H315-H319-H335 P261-P305 + P351 + P338 H2N N
H

mp .............................................................................................................................................................. 148 to 151 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
5-Amino-2-methylphenylboronic acid pinacol ester, 8
97% 549207-5G glass btl 5g
[882670‑69‑1] C13H20BNO2 FW 233.11 H 3C 2-Amino-5-(4-methylphenyl)-1,3,4-thiadiazole, 97%
O CH3
CH3 2-Amino-5-(p-tolyl)-1,3,4-thiadiazole; 5-(p-Tolyl)- N N
H 2N B
O 1,3,4-thiadiazol-2-amine
CH3 NH2
S
CH3 [26907‑54‑0] C9H9N3S FW 191.25 H3C
mp .................................................................................................................................................................... 82 to 86 °C mp .............................................................................................................................................................. 218 to 222 °C
7
7
Warning H315-H319 P305 + P351 + P338

> (2-Aminomethyl-phenyl)-carbamic acid tert-butyl ester, see 2-(Boc-amino) 2-Amino-5-methyl-4-phenylthiazole, 97%

benzylamine Page 370
5-Methyl-4-phenyl-2-thiazolamine
5-Amino-3-(4-methylphenyl)-1-phenylpyrazole, 97% [30709‑67‑2] C10H10N2S FW 190.26
N
[90012‑40‑1] C16H15N3 FW 249.31 CH3 H3C S NH2
mp .............................................................................................................................................................. 122 to 126 °C

N
57
H2N N Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338
mp .............................................................................................................................................................. 173 to 176 °C
4-Amino-3-methyl-6-phenyl-1,2,4-triazin-5-one, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[41394‑05‑2] Merck 14,5924 C10H10N4O NH2
549169-1G glass btl 1g FW 202.21 O N CH3

N
(S)-(+)-2-Amino-N-methyl-3-phenyl-propionamide 8
hydrochloride, ≥97.0%
mp .............................................................................................................................................................. 167 to 170 °C
L-Phenylalanine methylamide hydrochloride; H- O
79
Phe-NHMe N
CH3
[17186‑56‑0] C10H14N2O · HCl FW 214.69 NH2
H
• HCl 559806-25G glass btl 25 g
≥97.0% (HPLC) (Aminomethyl)phosphonic acid, 99%

97.0-103.0% (AT) AMPA
[α]D +67.0±2.0°, c = 3 in methanol [1066‑51‑9] Beil. 1,IV,3070 NH2CH2P(O)(OH)2 FW 111.04
7
Warning H317 P280
5
Danger H314 P280-P305 + P351 + P338-P310

AHB A, 0613, UNP EU
n Aminomethylphth n
4-Amino-N-methylphthalimide, 97%  200-400 mesh, loading: 4.0 mmol/g, 2% cross-linked

[2307‑00‑8] Beil. 22,535 C9H8N2O2 FW 176.17 O 473677-5G glass btl 5g
N CH3
H2N 473677-100G glass btl 100 g
O
 macroporous, 30-60 mesh, loading: 1.5-3.0 mmol/g
mp .............................................................................................................................................................. 246 to 248 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
A
564095-100G glass btl 100 g
1-Amino-4-methylpiperazine, 97%  macroporous, 70-90 mesh, loading: 1.5-3.0 mmol/g

[6928‑85‑4] Beil. 23,IV,376 C5H13N3 FW 115.18 CH3
N
> (Aminomethyl)polystyrene, macrobeads, see Polystyrene AM-NH2
N Page 2143
NH2 1-Amino-2-methylpropane, see Isobutylamine Page 1569
2-Amino-2-methylpropane, see tert-Butylamine Page 556
bp ............................................................... 172-175 °C n20
D .......................................................................... 1.485 2-Amino-2-methylpropane hydrochloride, see tert-Butylamine hydro-
density ..................................... 0.957 g/mL, 25 °C chloride Page 557
7
+ P338
2-Amino-2-methyl-1,3-propanediol, ≥99%
255688-25G glass btl 25 g AMPD; Ammediol
[115‑69‑5] Merck 14,448; Beil. 4,IV,1881 (HOCH2)2C(NH2)CH3
2-(Aminomethyl)piperidine, 97% FW 105.14
[22990‑77‑8] C6H14N2 FW 114.19 pKa (25 °C) ................................................................ 8.8 useful pH range .................................. 7.8 - 9.7
mp ...................................................... 100 to 110 °C vd ............................................................. 3.63 (vs air)
NH2
N bp ............................................... 151 °C/10 mmHg vp ....................................... ~10 mmHg (152 °C)
H
7
Warning H315-H319-H335 P261-P305 + P351 + P338
density .......................................................................................................................................... 0.9406 g/mL, 25 °C
n20
D ................................................................................................................................................................................... 1.4854 A9754-25G 25 g
5
Danger H314 P280-P305 + P351 + P338-P310 A9754-100G 100 g
A9754-500G 500 g
2-Amino-2-methyl-1-propanol
4-(Aminomethyl)piperidine, 96%
β-Aminoisobutyl alcohol; AMP; AMP 100; AMP 75; AMP 90
4-AMP NH2 [124‑68‑5] Merck 14,449; Beil. 4,IV,1740; Fieser 1,37; 3,14; 6,20
[7144‑05‑0] Beil. 22,V,8,120 C6H14N2 FW 114.19 (CH3)2C(NH2)CH2OH FW 89.14
pKa (25 °C) ................................................................ 9.7 n20
D ....................................................................... 1.4455
N mp ............................................................ 24 to 28 °C useful pH range ............................... 9.0 - 10.5
H
bp ......................................................................... 165 °C vd ................................................................... 3 (vs air)
mp ........................................................................... 25 °C n20
D ............................................................................. 1.49
density ..................................... 0.934 g/mL, 25 °C vp ............................................. <1 mmHg (25 °C)
bp ......................................................................... 200 °C
7
Warning H315-H319-H412 P273-P305 + P351 + P338
5
Danger H314 P280-P305 + P351 + P338-P310
 95%
A65158-5G-A glass btl 5g Used to derivatize carboxylic acids for GC analysis1 and to synthesize
2-oxazolines2 for further transformations.3
(Aminomethyl)polystyrene
Used in an efficient synthesis of 2-oxazolidinones via carbonylation
AM-polystyrene; Benzylamine polymer-bound; Polystyrene crosslinked with CO in the presence of salen-cobalt catalysts.4
with divinylbenzene, aminomethylated; Poly(styrene-co-divinylben- monomethyl aminomethyl propanol ...................................................................................................... <5%
zene), aminomethylated; Poly(styrene-co-vinylbenzylamine-co-divinyl- Lit. cited: 1. J. Chromatogr. A. 673, 101 (1994)
benzene 2. Tetrahedron 49, 9353 (1993)
Scavenges acids, acid chlorides, anhydrides, aldehydes and other 3. J. Am. Chem. Soc. 114, 1010 (1992)
electrophiles 4. Tetrahedron Lett. 48, 929 (2007)
 50-100 mesh, loading: 2.0 mmol/g, 1% cross-linked A65182-25ML glass btl 25 mL

Product of Varian A65182-500ML glass btl 500 mL
A65182-1L glass btl 1L
A65182-2.5L 2.5 L
 70-90 mesh, loading: 1.0-1.5 mmol/g N, 1% cross-linked
 technical, ≥90% (GC)
515620-100G glass btl 100 g
(1R)-(+)-(1-Amino-2-methylpropyl)phosphonic acid, 98%
 100-200 mesh, loading: 1.0 mmol/g N, 1% cross-linked
Product of Polymer Laboratories Ltd. [66254‑56‑6] (CH3)2CHCH(NH2)P(O)(OH)2 FW 153.12
[α]20
D +1.0°, c = 1 in 1 M NaOH
 100-200 mesh, loading: 0.5-1.0 mmol/g N, 1% cross-linked
7
Warning H315-H319-H335 P261-P305 + P351 + P338

AHB A, 0613, UNP EU
n Aminomethylpyri n
57
4-Amino-1-methyl-3-n-propyl-5-pyrazolecarboxamide, 96% Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338
4-Amino-2-methyl-5-propyl-2H-pyrazole-3- H2N
CH3 662690-250MG glass btl 250 mg
carboxylic acid amide
[139756‑02‑8] C8H14N4O FW 182.22 H2N N 662690-1G glass btl 1g
N
O CH3
3-Amino-4-methylpyridine, 97%
mp ................................................................................................................................................................. 98 to 101 °C [3430‑27‑1] C6H8N2 FW 108.14 CH3
NH2
7
Warning H315-H319-H335 P261-P305 + P351 + P338

N A
mp .............................................................................................................................................................. 102 to 107 °C
> 4-Amino-2-methyl-5-propyl-2H-pyrazole-3-carboxylic acid amide, see 4-
57
Amino-1-methyl-3-n-propyl-5-pyrazolecarboxamide Page 145 Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338
3-(Aminomethyl)-PROXYL 697141-5G glass btl 5g
3-(Aminomethyl)-2,2,5,5-tetramethyl-1-pyrrolidinyloxy NH2 697141-25G glass btl 25 g
[54606‑49‑4] C9H19N2O FW 171.26 H3C CH3
3-Amino-5-methylpyridine, 97%
H3C N CH3
O [3430‑19‑1] C6H8N2 FW 108.14 H3C NH2
Useful spin label for studying biological systems.1,2 Used to study N

molecular diffusion into horse spleen ferritin3 and has been shown to
mp ................................................................................................................................................................... 59 to 63 °C
be an effective nonthiol radioprotector.4
57
bp ............................................................................................................................................ 128-131 °C/13 mmHg Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
Lit. cited: 1. Pou, S,, A fluorophore-containing nitroxide as a probe to P338
detect superoxide and hydroxyl radical generated by stimulated neutro- 684856-250MG glass btl 250 mg
phils. Anal. Biochem. 212, 85 (1993) 684856-1G glass btl 1g
2. Int. J. Pharm. 98, 131 (1993)
3. Yang, X., Chasteen, N. D., Molecular diffusion into horse spleen ferritin: a 4-(Aminomethyl)pyridine, 98%
nitroxide radical spin probe study. Biophys. J. 71, 1587 (1996)
4-Picolylamine NH2
4. Hahn, S. M., Identification of nitroxide radioprotectors. Radiat. Res. 132, 87
(1992)
[3731‑53‑1] Beil. 22,V,9,345 C6H8N2 FW 108.14
7
+ P338 N

mp .......................................................................... −8 °C density ................................. 1.065 g/mL, 25 °C
270180-25MG glass btl 25 mg bp ......................................................................... 230 °C n20
D .......................................................................... 1.552
>
5
10
DL-4-Amino-N -methylpteroylglutamic acid, see (±)Amethopterin hydrate Danger H314 P280-P305 + P351 + P338-P310
Page 88
6-Amino-7-methylpurine, see 7-Methyladenine Page 1729
3-Amino-5-methylpyrazole, 97% A65603-25G glass btl 25 g
5-Methyl-3-pyrazolamine NH2 4-Amino-2-methylpyridine, 97%

[31230‑17‑8] Beil. 25,IV,2033 C4H7N3 FW 97.12 [18437‑58‑6] C6H8N2 FW 108.14
N NH2
H3 C N
H
N CH3
mp .................................................................................................................................................................... 45 to 47 °C
bp ....................................................................................................................................................... 213 °C/14 mmHg
mp ................................................................................................................................................................... 93 to 97 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338
340200-100G glass btl 100 g
> 2-(Aminomethyl)pyridine, see 2-Picolylamine Page 2071
2-Amino-3-methylpyridine, see 2-Amino-3-picoline Page 158 5-Amino-2-methylpyridine, 97%
2-Amino-4-methylpyridine, see 2-Amino-4-picoline Page 158
2-Amino-5-methylpyridine, see 6-Amino-3-picoline Page 158
[3430‑14‑6] C6H8N2 FW 108.14 H2N
2-Amino-6-methylpyridine, 98% N CH3
6-Amino-2-picoline mp ................................................................................................................................................................... 95 to 99 °C
[1824‑81‑3] Beil. 22,V,9,210 C6H8N2 FW 108.14
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
mp .................................................................................................................................................................... 40 to 44 °C P338
bp ....................................................................................................................................................................... 208-209 °C
6
Danger H301-H310-H315-H319-H335 P261-P280-P301 + P310-P302 + 662704-1G glass btl 1g
P350-P305 + P351 + P338-P310
A75706-100G glass btl 100 g 6-Amino-2-methylpyridine-3-carbonitrile, 97%
A75706-500G glass btl 500 g 6-Amino-2-methylnicotinonitrile CN
[183428‑90‑2] C7H7N3 FW 133.15
> 3-(Aminomethyl)pyridine, see 3-Picolylamine Page 2071
H2N N CH3
3-Amino-2-methylpyridine, 97% mp .............................................................................................................................................................. 162 to 166 °C

3-Amino-2-picoline
57
NH2 Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
[3430‑10‑2] C6H8N2 FW 108.14 P338
N CH3
mp .............................................................................................................................................................. 114 to 119 °C

AHB A, 0613, UNP EU
n Aminomethylpyri n
2-Amino-4-methylpyrimidine, 97% 2-(Aminomethyl)thiazole, 97% 8

[108‑52‑1] Beil. 24,84 C5H7N3 FW 109.13 CH3 (2-Thiazolyl)methylamine N
N [55661‑33‑1] C4H6N2S FW 114.17 NH2
S
N NH2
density ............................................................................................................................................. 1.204 g/mL, 25 °C
mp .............................................................................................................................................................. 158 to 160 °C n20
D ...................................................................................................................................................................................... 1.569
7 57
Warning H315-H319-H335 P261-P305 + P351 + P338 Danger H302-H314 P280-P305 + P351 + P338-P310
A A65700-10G poly btl 10 g 721522-1G glass btl 1g

A65700-100G poly btl 100 g
2-Amino-4-methylthiazole, 98%
> 2-Amino-4-methylpyrimidine-5-carboxylic acid ethyl ester, see Ethyl 2-
amino-4-methylpyrimidine-5-carboxylate Page 1212 [1603‑91‑4] Merck 14,450; Beil. 27,159 C4H6N2S H3 C
FW 114.17 N
4-Amino-N-(4-methyl-2-pyrimidinyl)benzenesulfonamide, see Sulfamer-
azine Page 2345 S NH2
Sulfamerazine sodium salt Page 2345
1-([4-Amino-2-methyl]-5-pyrimidylmethyl)-2-methyl-3-(β-hydroxyethyl)
pyridinium bromide, see Pyrithiamine hydrobromide Page 2228 mp ................................................................................................................................................................... 44 to 47 °C
bp ....................................................................................................................................................................... 231-232 °C
7
(S)-(+)-2-(Aminomethyl)pyrrolidine, 97% Warning H315-H319-H335 P261-P305 + P351 + P338
[69500‑64‑7] Beil. 22,IV,3761 C5H12N2 FW 100.16
NH2 A66006-5G glass btl 5g
N
H A66006-25G glass btl 25 g
bp .................................................. 65 °C/11 mmHg n20

D .......................................................................... 1.482 2-Amino-5-methylthiazole, 98%
density ..................................... 0.933 g/mL, 25 °C
[7305‑71‑7] Beil. 27,IV,4741 C4H6N2S FW 114.17 N
[α]20
D +20°, c = 1 in chloroform H3C NH2
S
27
mp ................................................................................................................................................................... 93 to 98 °C
79
3-Amino-2-methyl-4(3H)quinazolinone, 98% 380563-5G glass btl 5g

[1898‑06‑2] C9H9N3O FW 175.19
2-Amino-4-methylthiazole-5-carboxylic acid, 95% 8
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[67899‑00‑7] C5H6N2O2S FW 158.18 H3C

555797 N
HO NH2
> 4-Amino-2-methylquinoline, see 4-Aminoquinaldine Page 165 S
O
5-Amino-6-methylquinoline, 97%
mp .............................................................................................................................................................. 166 to 170 °C
6-Methylquinolin-5-ylamine; 6-Methyl-5-aminoquino-
7
NH2 Warning H315-H319-H335 P261-P305 + P351 + P338
line H 3C
[50358‑35‑5] C10H10N2 FW 158.20
mp .............................................................................................................................................................. 133 to 137 °C
Useful aminoquinoline for further quinoline chemistry modifica- > D-2-Amino-4-(methylthio)butanoic acid, see D-Methionine Page 1687
L-2-Amino-4-(methylthio)butanoic acid, see L-Methionine Page 1687
tions.1,2 DL-2-Amino-4-(methylthio)butanoic acid, see DL-Methionine Page 1687
Lit. cited: 1. Chem. Ber. 3655 (1890) (±)-3-Amino-5-(methylthio)pentanoic acid, see DL-β-Homomethionine
2. J. Chem. Soc. 2350 (1953) Page 1451
R-3-Amino-5-(methylthio)pentanoic acid hydrochloride, see L-β-Homome-
56
Danger H301-H318 P280-P301 + P310-P305 + P351 + P338
thionine hydrochloride Page 1451
(1S,2S)-(+)-2-Amino-1-[4-(methylthio)phenyl]-1,3-propanediol, see (1S,2S)-
685526-1G glass btl 1g (+)-Thiomicamine Page 2427
3-Amino-5-(methylthio)-1H-pyrazole-4-carbonitrile, see 3-Amino-5-
> 7-Amino-4-methyl-2(1H)-quinolinone, see Carbostyril 124 Page 622 (methylthio)pyrazole-4-carbonitrile Page 146
DL-2-Amino-4-(methylsulfonyl)butanoic acid, see DL-Methionine sulfone
Page 1687 3-Amino-5-(methylthio)pyrazole-4-carbonitrile 8
(R)-2-(Aminomethyl)tetrahydrofuran, see (R)-(−)-Tetrahydrofurfurylamine
Page 2388
3-Amino-4-cyano-5-(methylthio)pyrazole; 3-Amino-5- N C NH2
3-(Aminomethyl)-2,2,5,5-tetramethyl-1-pyrrolidinyloxy, see 3-(Amino- (methylthio)-1H-pyrazole-4-carbonitrile
N
methyl)-PROXYL Page 145 [72760‑85‑1] C5H6N4S FW 154.19 H3CS N
H
2-Amino-5-methyl-1,3,4-thiadiazole, 97%
mp .............................................................................................................................................................. 146 to 152 °C
[108‑33‑8] C3H5N3S FW 115.16
7
N N Warning H302
H3C S NH2
mp .............................................................................................................................................................. 223 to 228 °C
2-Amino-5-(methylthio)-1,3,4-thiadiazole, 99%
7
[5319‑77‑7] Beil. 27,I,609 C3H5N3S2 FW 147.22 N N
686166-5G glass btl 5g H3CS NH2
S
mp .............................................................................................................................................................. 178 to 181 °C


AHB A, 0613, UNP EU
n Aminonaphthalen n
3-Amino-5-methylthio-1H-1,2,4-triazole, 98% > 1-Aminonaphthalene, see 1-Naphthylamine Page 1888
[45534‑08‑5] C3H6N4S FW 130.17 NH2 4-Amino-1-naphthalenecarbonitrile, 97%

N
N 4-Cyano-1-naphthylamine
H3CS N
H [58728‑64‑6] Beil. 14,533 H2NC10H6CN FW 168.19
mp .............................................................................................................................................................. 130 to 133 °C mp ...................................................................................................................................................... 174.5 to 176.5 °C
7
190683-25G glass btl 25 g Warning H302-H312-H332 P280
4-Amino-N-methyl-α-toluenesulfonamide, 97% 122432-1G glass btl 1g A

4-Amino-N-methylbenzenemethanesulfon- H2N
O 2-Amino-1-naphthalenesulfonic acid, 98%
amide
S CH3
[109903‑35‑7] C8H12N2O2S FW 200.26 N 2-Naphthylamine-1-sulfonic acid; Tobias acid
O H
[81‑16‑3] Merck 14,6406; Beil. 14,IV,2792 H2NC10H6SO3H
mp .............................................................................................................................................................. 140 to 142 °C FW 223.25
6
Danger H301-H317-H319 P280-P301 + P310-P305 + P351 + P338 291137-250G glass btl 250 g
4-Amino-1-naphthalenesulfonic acid, 97%
1-Naphthylamine-4-sulfonic acid; Naphthionic acid
(1R,3S)-3-Aminomethyl-3,5,5-trimethylcyclohexyl- 8 [84‑86‑6] Merck 14,6403; Beil. 14,IV,2793 H2NC10H6SO3H
amine O,O′-dibenzoyl-L-tartrate salt, ≥97.0% FW 223.25
(1R,3S)-Isophorone diamine (2R,3R)-O, O mp ............................................................................................................................................................................ ≥300 °C
O′-dibenzoyl tartrate salt; cis-IPDA; H 3C
5
NH3 Ph O O Danger H314 P280-P305 + P351 + P338-P310
(1S,3R)-5-Amino-1,3,3-trimethyl-cyclo- H3C O
O
hexanemethylamine (2R,3R)-2,3-bis NH3
H 3C O O Ph
(benzoyloxy)butanedioate
O 250619-100G glass btl 100 g
[918963‑28‑7] C28H36N2O8
FW 528.59 4-Amino-1-naphthalenesulfonic acid sodium salt hydrate
≥97.0% (GC) Sodium 4-amino-1-naphthalenesulfonate; Naphthionic acid sodium
ee: ≥99.0% salt; 1-Naphthylamine-4-sulfonic acid sodium salt
water ............................................................................................................................................................................. ≤5.0%
[123333‑48‑2] Beil. 14,III,2241 H2NC10H6SO3Na · xH2O
711616-500MG glass btl 500 mg FW 245.23 (Anh)
> (Aminomethyl)trimethylsilane, see (Trimethylsilyl)methylamine Page 2551 mp ................................................................................................................................................................ 280 °C (dec.)
 technical
6-Amino-1-methyluracil, 97% water .............................................................................................................................................................................. ~25%
[2434‑53‑9] Beil. 24,470 C5H7N3O2 FW 141.13
7
NH
H2N N O 70862-250G poly btl 250 g

CH3 70862-1KG poly btl 1 kg
5-Amino-1-naphthalenesulfonic acid, ≥90% (T)

7
1-Naphthylamine-5-sulfonic acid; Laurent’s acid OH
346799-25G glass btl 25 g [84‑89‑9] Merck 14,6404; Beil. 14,IV,2800 C10H9NO3S O S O
> (±)-3-Amino-4-methylvaleric acid, see DL-β-Leucine Page 1609 FW 223.25
4-Aminomorpholine, 97% NH2

[4319‑49‑7] Beil. 27,8 C4H10N2O FW 102.14 NH2
N  technical
57
Danger H312-H314-H332 P280-P305 + P351 + P338-P310
O
bp ......................................................................... 168 °C n20

D ....................................................................... 1.4772 70800-100G poly btl 100 g
density ..................................... 1.059 g/mL, 25 °C
5-Amino-2-naphthalenesulfonic acid, ≥95%
27
P280-P305 + P351 + P338 [119‑79‑9] Merck 14,2350; Beil. 14,758 H2NC10H6SO3H FW 223.25
> 2-Amino-1-morpholinoethanone hydrochloride, see 2-Amino-1-(4-morpho- 8-Amino-2-naphthalenesulfonic acid, ≥97%

linyl)ethanone hydrochloride Page 147
1-Naphthylamine-7-sulfonic acid; Cleves acid-1,7
2-Amino-1-(4-morpholinyl)ethanone hydrochloride, 8 [119‑28‑8] Merck 14,2351; Beil. 14,IV,2805 H2NC10H6SO3H
98%
FW 223.25
4-(Aminoacetyl)morpholine hydrochloride; 2-Amino-1- O mp ............................................................................................................................................................................ ≥300 °C
NH2
morpholinoethanone hydrochloride; 4-Glycylmorpho-
5
N Danger H314 P280-P305 + P351 + P338-P310
line hydrochloride • HCl
[24152‑96‑3] C6H12N2O2 · HCl FW 180.63 O
≥98.0% (TLC) A7782-100G glass btl 100 g
7
Warning H319 P305 + P351 + P338
AHB A, 0613, UNP EU
n Aminonaphthalic n
7
4-Amino-1,8-naphthalic anhydride, 95% Warning H315-H319-H335 P261-P305 + P351 + P338
[6492‑86‑0] Beil. 18,II,469 C12H7NO3 FW 213.19 NH2
536911-500G glass btl 500 g
> 1-Amino-2-naphthol-4-sulfonic acid, see 4-Amino-3-hydroxy-1-naphthale-

O O O nesulfonic acid Page 129
6-Amino-1-naphthol-3-sulfonic acid, see 7-Amino-4-hydroxy-2-naphthale-
DMF .................................................................................................................................................................................. 1-2% nesulfonic acid Page 129
A 78 Danger H302-H312-H315-H319-H332-H335-H350
P280-P305 + P351 + P338-P308 + P313
P201-P261- 7-Amino-1-naphthol-3-sulfonic acid, see 6-Amino-4-hydroxy-2-naphthale-
nesulfonic acid Page 129
2-Aminonicotinamide, see 2-Aminopyridine-3-carboxamide Page 164
6-Aminonicotinamide, 99%
3-Amino-2-naphthoic acid, 80%
6-Aminopyridine-3-carboxamide O
[5959‑52‑4] Merck 14,452; Beil. 14,III,1341 H2NC10H6CO2H [329‑89‑5] Beil. 22,V,13,618 C6H7N3O FW 137.14 NH2
FW 187.19
H2N N
mp ............................................................................................................................................... 212 to 215 °C (dec.)
 technical grade mp .............................................................................................................................................................. 245 to 248 °C
7 8
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 Danger H360 P201-P308 + P313
A66804-5G glass btl 5g A68203-1G glass btl 1g

A66804-25G 25 g A68203-5G glass btl 5g
6-Amino-2-naphthoic acid, 90% > 2-Aminonicotinic acid, see 2-Aminopyridine-3-carboxylic acid Page 164
[116668‑47‑4] Beil. 14,II,324 H2NC10H6CO2H FW 187.19 4-Amino-nicotinic acid, ≥97.0% (HPLC)

mp .............................................................................................................................................................. 206 to 209 °C
4-Amino-3-pyridinecarboxylic acid NH2 O
5-amino-2-naphthoic acid .................................................................................................................................... 3%
[7418‑65‑7] C6H6N2O2 FW 138.12
6-hydroxy-2-naphthoic acid ................................................................................................................................ 5% OH
7
Warning H315-H319-H335 P261-P305 + P351 + P338 N
water ............................................................................................................................................................................. ≤1.0%

mp .............................................................................................................................................................. 307 to 312 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
1-Amino-2-naphthol hydrochloride, 90%
[1198‑27‑2] Beil. 13,666 H2NC10H6OH · HCl FW 195.65 11585-5G-F poly btl 5g
mp ................................................................................................................................................................. 250 °C (dec.) > 5-Aminonicotinic acid, see 5-Aminopyridine-3-carboxylic acid Page 164
6-Aminonicotinic acid, see 6-Aminopyridine-3-carboxylic acid Page 164
 technical grade 5-Aminonicotinic acid methyl ester, see Methyl 5-aminopyridine-3-
carboxylate Page 1736
78
P280-P305 + P351 + P338 6-Aminonicotinonitrile, see 6-Amino-3-pyridinecarbonitrile Page 163
4-Amino-3-nitroanisole, see 4-Methoxy-2-nitroaniline Page 1709
3-Amino-5-nitrobenzisothiazole, 97%
3-Amino-2-naphthol, 97%
[84987‑89‑3] C7H5N3O2S FW 195.20 NH2
[5417‑63‑0] Beil. 13,681 H2NC10H6OH FW 159.18 O2N
mp .............................................................................................................................................................. 229 to 230 °C N
S
78
P280-P305 + P351 + P338 mp ................................................................................................................................................................ 250 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
4-Amino-1-naphthol hydrochloride, 90%
[5959‑56‑8] Beil. 13,667 H2NC10H6OH · HCl FW 195.65 2-Amino-3-nitrobenzoic acid, 96%
mp ................................................................................................................................................................. 273 °C (dec.) [606‑18‑8] O2NC6H3(NH2)CO2H FW 182.13
7
Warning H302
7
Warning H315-H319-H335 P261-P305 + P351 + P338

133485-25G poly btl 25 g 663476-10G glass btl 10 g
5-Amino-1-naphthol, 97% 2-Amino-5-nitrobenzoic acid

[83‑55‑6] Beil. 13,670 H2NC10H6OH FW 159.18 5-Nitroanthranilic acid
mp ................................................................................................................................................................. 190 °C (dec.) [616‑79‑5] Beil. 14,IV,1088 O2NC6H3(NH2)CO2H FW 182.13
mp ................................................................................................................................................................ 270 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
376469-100G glass btl 100 g  95%
8-Amino-2-naphthol, 97%
[118‑46‑7] H2NC10H6OH FW 159.18
mp .............................................................................................................................................................. 206 to 210 °C  technical grade, 90%

AHB A, 0613, UNP EU
n Aminonitropheny n
4-Amino-3-nitrobenzoic acid, 97% 2-Amino-4-nitrophenol

[1588‑83‑6] H2NC6H3(NO2)CO2H FW 182.13 2-Hydroxy-5-nitroaniline
mp ................................................................................................................................................................. 280 °C (dec.) [99‑57‑0] Beil. 13,IV,896 H2NC6H3(NO2)OH FW 154.12
7
7
Warning H315-H319-H335 P261-P305 + P351 + P338
5-Amino-2-nitrobenzoic acid  ≥99.0% (NT)

[13280‑60‑9] Beil. 14,III,1021 H2NC6H3(NO2)CO2H FW 182.13
mp .............................................................................................................................................................. 143 to 145 °C
A
mp .............................................................................................................................................................. 236 to 238 °C
564613-5G glass btl 5g  96%
2-Amino-5-nitrobenzonitrile, 95%
2-Cyano-4-nitroaniline; 5-Nitroanthranilonitrile
[17420‑30‑3] Beil. 14,III,980 O2NC6H3(NH2)CN FW 163.13
mp .............................................................................................................................................................. 200 to 207 °C 2-Amino-5-nitrophenol
153494-5G glass btl 5g 2-Hydroxy-4-nitroaniline
153494-100G poly btl 100 g [121‑88‑0] Beil. 13,IV,903 H2NC6H3(NO2)OH FW 154.12
153494-500G poly btl 500 g mp ............................................................................................................................................... 198 to 202 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
4-Amino-3-nitrobenzonitrile, 98%
[6393‑40‑4] Beil. 14,IV,1287 H2NC6H3(NO2)CN FW 163.13 303585-25G glass btl 25 g
7
Warning H315-H319-H335 P261-P305 + P351 + P338
4-Amino-2-nitrophenol, 97%
324698-5G glass btl 5g 4-Hydroxy-3-nitroaniline
[119‑34‑6] Beil. 13,520 H2NC6H3(NO2)OH FW 154.12
2-Amino-5-nitrobenzophenone, ≥98%
mp .............................................................................................................................................................. 125 to 127 °C
[1775‑95‑7] Beil. 14,79 H2NC6H3(NO2)C(O)C6H5 FW 242.23
7
Warning H302
mp .............................................................................................................................................................. 166 to 168 °C
7
147214-100G glass btl 100 g
211737-100G glass btl 100 g 4-Amino-3-nitrophenol, 98%
4-Hydroxy-2-nitroaniline
2-Amino-6-nitrobenzothiazole, ≥97%
[610‑81‑1] Beil. 13,III,1203 H2NC6H3(NO2)OH FW 154.12
[6285‑57‑0] Beil. 27,II,232 C7H5N3O2S FW 195.20 N mp .............................................................................................................................................................. 150 to 154 °C
NH2
7
O2N S Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H302-H312-H315-H319-H332-H335 P261-P280-P305 + P351 249319-100G glass btl 100 g
+ P338
190241-25G poly btl 25 g
4-Amino-3-nitrophenylboronic acid, 90%
190241-100G poly btl 100 g [89466‑07‑9] C6H7BN2O4 FW 181.94 OH
B
> 2-Amino-3-nitrobenzotrifluoride, see 2-Nitro-6-(trifluoromethyl)aniline OH
Page 1930 H2N
2-Amino-5-nitrobenzotrifluoride, see 4-Nitro-2-(trifluoromethyl)aniline NO2
Page 1930
4-Amino-3-nitrobenzotrifluoride, see 2-Nitro-4-(trifluoromethyl)aniline
Page 1930 Contains varying amounts of anhydride
5-Amino-2-nitrobenzotrifluoride, see 4-Nitro-3-(trifluoromethyl)aniline mp ............................................................................................................................................... 215 to 225 °C (dec.)
Page 1930
 technical grade
4-Amino-4′-nitrodiphenyl sulfide, 98% 651621-1G glass btl 1g
[101‑59‑7] H2NC6H4SC6H4NO2 FW 246.29
4-Amino-3-nitrophenylboronic acid pinacol ester, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Nitro-4-(4,4,5,5-tetramethyl-1,3,2-dioxa- H 3C

borolan-2-yl)aniline O CH3
[833486‑94‑5] C12H17BN2O4 FW 264.09 B CH3
O
> 1-Amino-4-nitronaphthalene, see 4-Nitro-1-naphthylamine Page 1918 CH3
H 2N
2-Amino-3-nitrophenol, 98% NO2
2-Hydroxy-6-nitroaniline mp ...................................................................................................................................................... 157.1 to 172.4 °C

[603‑85‑0] Beil. 13,IV,895 H2NC6H3(NO2)OH FW 154.12
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 212 to 213 °C
7

AHB A, 0613, UNP EU
n Aminonitropheny n
2-Amino-5-(4-nitrophenyl)-1,3,4-oxadiazole, 97% 2-Amino-5-nitropyridine, 97%

[51891‑79‑3] C8H6N4O3 FW 206.16 N N [4214‑76‑0] Beil. 22,V,8,495 C5H5N3O2 FW 139.11 O2N
O NH2
O2N N NH2
mp .............................................................................................................................................................. 245 to 249 °C mp .............................................................................................................................................................. 186 to 188 °C
7 7
Warning H302-H319 P305 + P351 + P338 Warning H315-H319-H335 P261-P305 + P351 + P338
A 663417-1G
663417-10G
glass btl
glass btl
1g
10 g
4-Amino-3-nitropyridine, 97%
(1R,2R)-(−)-2-Amino-1-(4-nitrophenyl)-1,3-propanediol, 99% [1681‑37‑4] C5H5N3O2 FW 139.11 NH2
D-(−)-threo-2-Amino-1-(p-nitrophenyl)-1,3-propanediol; Chloramphe- NO2
nicol base
N
[716‑61‑0] Beil. 13,III,2267 HOCH2CH(NH2)CH(C6H4NO2)OH
FW 212.20 mp .............................................................................................................................................................. 203 to 207 °C
7
mp .............................................................................................................................................................. 163 to 165 °C Warning H302-H315-H319-H335 P261-P305 + P351 + P338
D −30°, c = 1 in 6 M HCl
[α]25
7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 646962-1G glass btl 1g
2-Amino-3-nitropyridine-5-boronic acid pinacol ester, 8
97%
(1S,2S)-(+)-2-Amino-1-(4-nitrophenyl)-1,3-propanediol, 99% 3-Nitro-5-(4,4,5,5-tetramethyl-1,3,2-dioxa- H3C CH
3
L-(+)-threo-2-Amino-1-(4-nitrophenyl)-1,3-propanediol borolan-2-yl)pyridin-2-amine; 6-Amino-5-nitro- O CH3
[2964‑48‑9] Beil. 13,III,2267 O2NC6H4CH(OH)CH(NH2)CH2OH pyridine-3-boronic acid pinacol ester O2N B
O CH3
FW 212.20 [1032758‑80‑7] C11H16BN3O4 FW 265.07
H2N N
mp .............................................................................................................................................................. 163 to 166 °C
[α]23
D +31°, c = 1 in 6 M HCl mp .............................................................................................................................................................. 169 to 174 °C
7
3-Amino-3-(4-nitrophenyl)propionic acid, 95%
[35005‑61‑9] C9H10N2O4 FW 210.19 NH2 O
> 6-Amino-5-nitropyridine-3-boronic acid pinacol ester, see 2-Amino-3-
OH nitropyridine-5-boronic acid pinacol ester Page 150
O2N
2-Amino-5-nitropyrimidine, 98%
mp ................................................................................................................................................................. 215 °C (dec.) [3073‑77‑6] Beil. 24,I,231 C4H4N4O2 FW 140.10 O2N
N
N NH2
2-Amino-5-(4-nitrophenyl)-1,3,4-thiadiazole
mp .............................................................................................................................................................. 235 to 237 °C
[833‑63‑6] C8H6N4O2S FW 222.22
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Amino-4-(4-nitrophenyl)thiazole, 96% A70836-250MG glass btl 250 mg

[2104‑09‑8] C9H7N3O2S FW 221.24 O2N
N
5-Amino-6-nitroquinoline, 97%
S NH2
[35975‑00‑9] C9H7N3O2 FW 189.17 NH2
mp .............................................................................................................................................................. 283 to 287 °C O2N
7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 N
658499-10G glass btl 10 g mp ............................................................................................................................................... 272 to 273 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> 2-Amino-3-nitro-4-picoline, see 2-Amino-4-methyl-3-nitropyridine
Page 142
2-Amino-3-nitropyridine, 99% 145025-5G glass btl 5g
[4214‑75‑9] Beil. 22,V,8,484 C5H5N3O2 FW 139.11 2-Amino-5-nitrothiazole, 97%
mp .............................................................................................................................................................. 163 to 165 °C
[121‑66‑4] Merck 14,457; Beil. 27,IV,4675 C3H3N3O2S N
7
Warning H315-H319-H335 P261-P305 + P351 + P338
FW 145.14
O2N S NH2

mp ............................................................................................................................................... 195 to 200 °C (dec.)
7
133507-25G poly btl 25 g

133507-100G poly btl 100 g

AHB A, 0613, UNP EU
n Aminopalmiticac n
> 4-Amino-2-nitro-toluene, see 4-Methyl-3-nitroaniline Page 1807 (S)-2-Aminooctane
4-Amino-3-nitrotoluene, see 4-Methyl-2-nitroaniline Page 1807
1-Aminononane, see Nonylamine Page 1937 (S)-2-Octylamine NH2
(R)-2-Aminononane [34566‑04‑6] C8H19N FW 129.24 H3C

8 CH3
(R)-2-Nonylamine NH2 Danger

[74069‑74‑2] C9H21N FW 143.27
CH3(CH2)5CH2 CH3  ≥97.0%
 ChiPros®, produced by BASF
≥98.5%  ChiPros®, produced by BASF, ≥99.0% 8 A
ee: ≥98.0% ≥99.0% (GC)
56
Danger H301-H310-H314-H330 P260-P280-P284-P301 +
2579
P310-P302 + P350-P305 + P351 + P338 H226-H302-H314-H400 P273-P280-P305 + P351
+ P338-P310
(S)-2-Aminononane, 99% 8 > DL-2-Aminooctanoic acid, see DL-2-Aminocaprylic acid Page 104
(S)-2-Nonylamine
[869278‑88‑6] C9H21N FW 143.27 8-Aminooctanoic acid, 99%
 ChiPros®, produced by BASF ω-Aminocaprylic acid
≥98.5% (GC) [1002‑57‑9] Beil. 4,IV,2802 NH2(CH2)7COOH FW 159.23
enantiomeric excess: ≥98.5% mp ................................................................................................................................................................ 194 °C (dec.)
579
Danger H302-H312-H314-H332-H400 P273-P280-P305 855294-1G glass btl 1g
+ P351 + P338-P310 855294-5G glass btl 5g
> 8-Aminooctanoic acid lactam, see 2-Azacyclononanone Page 207
727342-25G glass btl 25 g 7-Aminooenanthic acid, see 7-Aminoheptanoic acid Page 127
2-Aminonorbornane hydrochloride, 99%
5-Aminoorotic acid, 99%
2-Norbornanamine hydrochloride
5-Amino-2,6-dioxo-1,2,3,6-tetrahydro-4-pyrimidine- O
[14370‑45‑7] Beil. 12,III,160 C7H13N · HCl FW 147.65 • HCl carboxylic acid; 5-Amino-6-carboxy-2,4-dihydroxy- H2N
NH
NH2 pyrimidine HO
N O
[7164‑43‑4] Beil. 25,264 C5H5N3O4 FW 171.11 H
mp ................................................................................................................................................................. 295 °C (dec.) O
133515-1G glass btl 1g mp ............................................................................................................................................................................ >300 °C

7
Warning H315-H319-H335 P261-P305 + P351 + P338
exo-2-Aminonorbornane, 99%
191213-50G poly btl 50 g
exo-2-Norbornanamine
[7242‑92‑4] Beil. 12,III,160 C7H13N FW 111.18 NH2
3-Aminooxetane-3-carboxylic acid, 95% 8
[138650‑24‑5] C4H7NO3 FW 117.10 O
bp .................................................. 49 °C/10 mmHg n20
D ....................................................................... 1.4807
H2N
density ..................................... 0.938 g/mL, 25 °C OH
27
Warning H226-H315-H319-H335 P261-P305 + P351 + P338 O
mp .............................................................................................................................................................. 205 to 210 °C

7
Warning H302-H319 P305 + P351 + P338
> 1-Aminooctadecane, see Octadecylamine Page 1944
(R)-2-Aminooctane
> (S)-3-Amino-2-oxetanone tetrafluoroborate salt, see L-Serine β-lactone
(R)-2-Octylamine tetrafluoroborate salt Page 2270
[34566‑05‑7] CH3(CH2)5CH(NH2)CH3 FW 129.24 Aminooxoacetic acid, see Oxamic acid Page 1960
Danger P273-P280-P305 + P351 + P338-P310 2-Amino-4-oxo-4H-1-benzopyran-3-carboxaldehyde, see 2-Amino-3-
formylchromone Page 126
 ≥98.0% (GC) 1-Amino-4-oxocyclohexanecarboxylic acid ethylene 8
enantiomeric ratio (GC): >99.0:1.0 ketal, 95%
579
H302-H314-H400
[54621‑18‑0] C9H15NO4 FW 201.22 O
93786-1G-F glass btl 1g OH

O NH2
 ChiPros®, produced by BASF, 98% 8 O
≥98.5% (GC) mp .............................................................................................................................................................. 275 to 280 °C

57
Danger H302-H318 P280-P305 + P351 + P338
2579
H226-H302-H314-H400

726893-25G glass btl 25 g > 1-(2-Amino-2-oxoethyl)cyclohexaneacetic acid, see 1,1-Cyclohexanediacetic
acid monoamide Page 806
3-Amino-2-oxohexamethyleneimine hydrochloride, see DL-α-Amino-ε-
caprolactam hydrochloride Page 104
2-Aminopalmitic acid, see 2-Aminohexadecanoic acid Page 127
AHB A, 0613, UNP EU
n Aminopenicillan n
(+)-6-Aminopenicillanic acid, 96% DL-2-Amino-1-pentanol, 97%

6-APA; (2S,5R,6R)-6-Amino-3,3-dimethyl-7-oxo-4-thia- H [4146‑04‑7] Beil. 4,III,794 CH3CH2CH2CH(NH2)CH2OH FW 103.16
H2N
1-azabicyclo[3.2.0]heptane-2-carboxylic acid S CH3 bp ............................................................... 194-195 °C n20
D ....................................................................... 1.4511
[551‑16‑6] Merck 14,458; Beil. 27,IV,5858 N CH3 density ..................................... 0.922 g/mL, 25 °C
O
C8H12N2O3S FW 216.26
7
O OH Warning H315-H319-H335 P261-P305 + P351 + P338

[α]22
D +276.3°, c = 1.2 in 0.1 M HCl
A 8 Danger H317-H334 P261-P280-P342 + P311
5-Amino-1-pentanol, 95%
[2508‑29‑4] Beil. 4,IV,1750 NH2(CH2)5OH FW 103.16
A70909-10G glass btl 10 g mp ............................................................ 33 to 35 °C density ................................. 0.949 g/mL, 25 °C
bp .................................... 120-122 °C/16 mmHg n20 D ....................................................................... 1.4615
57
Danger H302-H314 P280-P305 + P351 + P338-P310
> 1-Aminopentane, see Amylamine Page 187
123048-10G poly btl 10 g

2-Aminopentane, 97%
123048-50G poly btl 50 g
2-Amylamine; 1-Methylbutylamine
[63493‑28‑7] CH3CH(NH2)CH2CH2CH3 FW 87.16 5-Amino-1-pentanol solution
bp ............................................................. 90.5-91.5 °C n20
D ....................................................................... 1.4020 [2508‑29‑4] NH2(CH2)5OH FW 103.16
density ..................................... 0.736 g/mL, 25 °C
bp ...................................................................................................................................................... 122 °C/16 mmHg
25
Danger H226-H314 P280-P305 + P351 + P338-P310 density ................................................................................................................................................ 0.99 g/mL, 20 °C
 50% in H2O
57
Danger H302-H314 P280-P305 + P351 + P338-P310
> 3-Aminopentane, see 1-Ethylpropylamine Page 1270
(R)-2-Aminopentanedioic acid, see D-Glutamic acid Page 1386
(S)-2-Aminopentanedioic acid, see L-Glutamic acid Page 1386 11318-100G poly btl 100 g
L-Glutamic acid monosodium salt monohydrate Page 1387
(±)-2-Aminopentanedioic acid, see DL-Glutamic acid monohydrate (S)-(−)-2-Amino-4-pentenoic acid, 98%
Page 1387
L-2-Amino-4-pentenoic acid; L-Allylglycine
(R)-(−)-2-Aminopentanoic acid, see D-Norvaline Page 1941
(S)-(+)-2-Aminopentanoic acid, see L-Norvaline Page 1941 [16338‑48‑0] Beil. 4,IV,2852 H2C=CHCH2CH(NH2)CO2H FW 115.13
mp ................................................................................................................................................................ 283 °C (dec.)
(R)-3-Aminopentanoic acid, 98% D −36°, c = 4 in H2O
[α]20
7
(R)-3-Amino-valeric acid OH Warning H315-H319-H335 P261-P305 + P351 + P338
H3C
[131347‑76‑7] C5H9NO2 FW 115.13
H2N O
≥97.5% (GC) > (±)-2-Amino-4-pentenoic acid, see DL-2-Allylglycine Page 72
[α]D -43.0±2.0°, c = 0.5 in H2O
enantiomeric excess: ≥99.0% 4-Amino-3-penten-2-one, 97%
670944-250MG poly btl 250 mg Acetylacetonamine CH3 O
670944-1G poly btl 1g [1118‑66‑7] C5H9NO FW 99.13
H2N CH3
(S)-3-Aminopentanoic acid, 98%

≥96.5% (GC)
(S)-3-Amino-valeric acid
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[14389‑77‑6] C5H9NO2 FW 115.13
≥97.5% (GC)
[α]D +43.0±2.0°, c = 0.5 in H2O
enantiomeric excess: ≥99.0% > 1-Amino-4-pentyne, see 4-Pentyn-1-amine Page 2000
5-Amino-1-pentyne, see 4-Pentyn-1-amine Page 2000
670715-250MG poly btl 250 mg
670715-1G poly btl 1g 2-Aminoperimidine hydrobromide hydrate, 98%
> 5-Aminopentanoic acid, see 5-Aminovaleric acid Page 173 [313223‑13‑1] C11H9N3 · HBr · xH2O FW 264.12 NH2
5-Aminovaleric acid hydrochloride Page 173 (Anh) N NH
• HBr
(R)-(−)-2-Amino-1-pentanol, 97% • xH2O
D-Norvalinol
[80696‑30‑6] CH3(CH2)2CH(NH2)CH2OH FW 103.16 mp ............................................................................................................................................................................... 297 °C
mp .................................................................................................................................................................... 44 to 48 °C
[α]20
9-Aminophenanthrene, 96%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
9-Phenanthrenamine NH2
534579-1G glass btl 1g [947‑73‑9] Beil. 12,1338 C14H11N FW 193.24
(S)-(+)-2-Amino-1-pentanol, 97%
L-Norvalinol
mp .............................................................................................................................................................. 137 to 139 °C
[22724‑81‑8] CH3(CH2)2CH(NH2)CH2OH FW 103.16
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .................................................................................................................................................................... 44 to 48 °C
[α]20
7
Warning H315-H319-H335 P261-P305 + P351 + P338

AHB A, 0613, UNP EU
n Aminophenylbenz n
2-Aminophenethyl alcohol, 97% mp ................................................................................................................................................................ 294 °C (dec.)
[5339‑85‑5] Beil. 13,III,1679 H2NC6H4CH2CH2OH FW 137.18 D −1.4°, c = 1 in H2O

[α]20
bp .................................... 147-148 °C/3.5 mmHg n20
7
D .......................................................................... 1.588 Warning H315-H319-H335 P261-P305 + P351 + P338
density ..................................... 1.045 g/mL, 25 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> (±)-α-Aminophenylacetic acid, see 2-Phenylglycine Page 2037
192600-5G glass btl 5g R-(−)-α-Aminophenylacetic acid, see D−(−)-α-Phenylglycine Page 2037
A
3-Aminophenylacetic acid, 97%
4-Aminophenethyl alcohol, 98%
[14338‑36‑4] Beil. 14,456 H2NC6H4CH2CO2H FW 151.16
2-(4-Aminophenyl)ethanol mp .............................................................................................................................................................. 147 to 150 °C
[104‑10‑9] Beil. 13,IV,1833 H2NC6H4CH2CH2OH FW 137.18
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 107 to 110 °C
7
4-Aminophenylacetic acid, 98%
[1197‑55‑3] Merck 14,463; Beil. 14,III,1182 H2NC6H4CH2CO2H
2-Aminophenol, 99% FW 151.16
[95‑55‑6] Merck 14,461; Beil. 13,IV,805 H2NC6H4OH FW 109.13 mp ................................................................................................................................................................ 201 °C (dec.)
mp .............................................................................................................................................................. 170 to 175 °C
78
Warning H302-H332-H341 P281 A71352-100G poly btl 100 g
> 2-Aminophenylacetonitrile, see 2-Aminobenzyl cyanide Page 94

4-Aminophenylacetonitrile, see 4-Aminobenzyl cyanide Page 94
A71301-500G glass btl 500 g 4-Amino-L-phenylalanine hydrochloride, ≥96.0% (AT)
3-Aminophenol, 98% [62040‑55‑5] Beil. 14,IV,1687 C9H12N2O2 · O
HCl FW 216.66
[591‑27‑5] Merck 14,460; Beil. 13,IV,952 H2NC6H4OH FW 109.13 OH • HCl
NH2
mp .............................................................................................................................................................. 120 to 124 °C H2N
bp ....................................................................................................................................................... 164 °C/11 mmHg
[α]20
D +8.7±0.5°, c = 1 in acetic acid: water (4:1)
79
> 4-Aminophenylarsonic acid, see p-Arsanilic acid Page 199
100242-100G glass btl 100 g 4-Aminophenyl azide hydrochloride, see 4-Azidoaniline hydrochloride
100242-500G glass btl 500 g Page 209
2,2′-[4-(4-Aminophenylazo)phenylimino]diethanol, see Disperse Black 9
4-Aminophenol Page 1161
4-Hydroxyaniline 2-(2-Aminophenyl)-1H-benzimidazole, 97%

[123‑30‑8] Merck 14,462; Beil. 13,IV,1014 H2NC6H4OH FW 109.13
[5805‑39‑0] C13H11N3 FW 209.25 H 2N
mp .............................................................................................................................................................. 185 to 189 °C
N
789
Warning H302-H332-H341-H410 P273-P281-P501
N
H
 ≥99% (HPLC) mp .............................................................................................................................................................. 211 to 215 °C

mp .............................................................................................................................................................. 186 to 188 °C
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
60034-250G-R 250 g P338
60034-1KG-R 1 kg 642681-5G glass btl 5g
60034-50KG-R 50 kg 642681-25G glass btl 25 g
 ≥98% 3-(4-Aminophenyl)benzonitrile, 97%

A71328-5G glass btl 5g 4′-Aminobiphenyl-3-carbonitrile; 4′-Amino-[1,1′-biphenyl]-3-carbo-
A71328-100G glass btl 100 g nitrile
A71328-500G glass btl 500 g [443998‑73‑0] C13H10N2 FW 194.23
A71328-1KG glass btl 1 kg mp .............................................................................................................................................................. 128 to 132 °C
579
4-Aminophenol-d7 Danger H302-H312-H318-H332-H400 P273-P280-P305
+ P351 + P338
[285132‑88‑9] D2NC6D4OD FW 116.17
mp .............................................................................................................................................................. 188 to 190 °C
 98 atom % D
mol wt 116.03, atom % calculation 4-(3-Aminophenyl)benzonitrile, 97%
491519-1G glass btl 1g 3′-Aminobiphenyl-4-carbonitrile; 3′-Amino-[1,1′- H2N
biphenyl]-4-carbonitrile
> (R)-(+)-2-Amino-2-phenylacetamide hydrochloride, see D-2-Amino-2- [149505‑72‑6] C13H10N2 FW 194.23 CN
phenylacetamide hydrochloride Page 153
N-(4-Aminophenyl)acetamide, see 4′-Aminoacetanilide Page 89
mp .............................................................................................................................................................. 119 to 123 °C
59
D-2-Amino-2-phenylacetamide hydrochloride, 97% Danger H318-H400 P273-P280-P305 + P351 + P338
(R)-(+)-2-Amino-2-phenylacetamide hydrochloride NH2

[63291‑39‑4] C8H10N2O · HCl FW 186.64 NH2 • HCl

AHB A, 0613, UNP EU
n Aminophenylbenz n
4-(4-Aminophenyl)benzonitrile, 95% mp ................................................................................................................................................................... 63 to 68 °C
7
4′-Aminobiphenyl-4-carbonitrile; 4′-Amino- Warning H315-H319-H335 P261-P305 + P351 + P338
[1,1′-biphenyl]-4-carbonitrile H2N CN
[4854‑84‑6] C13H10N2 FW 194.23 576557-1G glass btl 1g

579
Danger H302-H312-H318-H332-H400 P273-P280-P305
+ P351 + P338 3-Aminophenylboronic acid pinacol ester, 97%
3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline
A
644048-1G glass btl 1g H 3C
[210907‑84‑9] C12H18BNO2 FW 219.09 O CH3
2-(2-Aminophenyl)benzothiazole, 97% B CH3
O
CH3
[29483‑73‑6] C13H10N2S FW 226.30 N
S NH2
H2N
mp ................................................................................................................................................................... 90 to 94 °C
mp .............................................................................................................................................................. 126 to 130 °C Product of Boron Molecular
6 7
Danger H301-H315-H319 P301 + P310-P305 + P351 + P338 Warning H315-H319-H335 P261-P305 + P351 + P338

2-Aminophenylboronic acid hydrochloride 8
4-Aminophenylboronic acid pinacol ester, 97%
[863753‑30‑4] NH2C6H4B(OH)2 · HCl FW 173.41
mp .............................................................................................................................................................. 145 to 156 °C 4-Aminophenylboronic acid, pinacol cyclic
H3C CH3
ester; 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan- O
7
Warning H302 H3C
2-yl)aniline H3C O
B
[214360‑73‑3] C12H18BNO2 FW 219.09

mp .............................................................................................................................................................. 165 to 169 °C
3-Aminophenylboronic acid monohydrate, 98% Arylboronic ester used in Suzuki cross-coupling to iodoflavonoids.1
3-Aminobenzeneboronic acid Lit. cited: 1. J. Med. Chem. 49, 3973 (2006)
7
[206658‑89‑1] Beil. 16,III,1284 H2NC6H4B(OH)2 · H2O FW 154.96 Warning H315-H319-H335 P261-P305 + P351 + P338
mp .................................................................................................................................................................... 93 to 96 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
287512-1G glass btl 1g > 3-Aminophenylboronic acid, polymer-bound, see Boric acid gel
2-Aminophenyl (4-bromophenyl)methanone, see 2-Amino-4′-bromoben-
3-Aminophenylboronic acid hemisulfate salt, ≥95% zophenone Page 97
3-Amino-1-phenylbutane, see 1-Methyl-3-phenylpropylamine Page 1826
3-Aminobenzeneboronic acid hemisulfate salt
[66472‑86‑4] H2NC6H4B(OH)2 · 0.5H2SO4 FW 185.98 2-Amino-2-phenylbutyric acid, 96%
mp ............................................................................................................................................................................ ≥300 °C [5438‑07‑3] C6H5C(NH2)(CO2H)C2H5 FW 179.22
7
Warning H315-H319-H335 P261-P305 + P351 + P338 mp ............................................................................................................................................... 276 to 280 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
A71751-25G poly btl 25 g 530255-5G glass btl 5g
3-Aminophenylboronic acid hydrochloride, 98% > (±)-2-Amino-4-phenylbutyric acid, see DL-Homophenylalanine Page 1451
(S)-3-Amino-4-phenylbutyric acid hydrochloride, see L-β-Homophenyla-
3-Aminobenzeneboronic acid hydrochloride lanine hydrochloride Page 1451
[85006‑23‑1] H2NC6H4B(OH)2 · HCl FW 173.41 (±)-3-Amino-4-phenylbutyric acid, see DL-β-Homophenylalanine
Page 1451
7
Warning H315-H319-H335 P261-P305 + P351 + P338
4-(4-Aminophenyl)butyric acid, 95%
[15118‑60‑2] Beil. 14,III,1279 H2NC6H4(CH2)3CO2H FW 179.22
mp .............................................................................................................................................................. 121 to 124 °C
4-Aminophenylboronic acid hydrochloride 8
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[80460‑73‑7] C6H8BNO2 · HCl FW 173.41
mp .............................................................................................................................................................. 195 to 200 °C
May contain varying amounts of anhydride
7
Warning H302 (S)-(+)-2-Amino-4-phenylbutyric acid ethyl ester hydrochloride,
97%
708887-250MG glass btl 250 mg [90891‑21‑7] C6H5(CH2)2CH(NH2)CO2C2H5 · HCl FW 243.73
2-Aminophenylboronic acid pinacol ester [α]20

2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline H3C CH3
[191171‑55‑8] C12H18BNO2 FW 219.09 O CH3
B
O CH3 > (2-Aminophenyl)-carbamic acid tert-butyl ester, see N-Boc-1,2-phenyl-
enediamine Page 406
NH2

AHB A, 0613, UNP EU
n Aminophenyloxad n
2-Aminophenyl disulfide, 97% 5-Amino-3-phenylisoxazole, 97%

2,2′-Dithiodianiline; Bis(2-aminophenyl) disulfide; 2,2′-Diamino- [4369‑55‑5] C9H8N2O FW 160.17
diphenyl disulfide
[1141‑88‑4] Beil. 13,IV,920 (H2NC6H4)2S2 FW 248.37 N
H2N O
mp .................................................................................................................................................................... 91 to 92 °C
569
Danger H301-H318-H410 P273-P280-P301 + P310- mp .............................................................................................................................................................. 110 to 114 °C
P305 + P351 + P338-P501
7
Warning H302
166766-10G
4-Aminophenyl disulfide, 98%

glass btl 10 g
A
4,4′-Dithiodianiline
[722‑27‑0] Beil. 13,536 (H2NC6H4S-)2 FW 248.37 4-Aminophenylmercuric acetate, ≥90% (titration)
mp .................................................................................................................................................................... 77 to 78 °C 4-(Acetoxymercurio)aniline; APMA
7
Warning H315-H319-H335 P261-P305 + P351 + P338 [6283‑24‑5] Beil. 16,IV,1754 CH3CO2HgC6H4NH2 FW 351.75
An organomercurial activator of matrix metalloproteinases.
369462-25G glass btl 25 g solubility (10 mg/mL in DMSO) ............................................................................................................. soluble
> 1-(4-Aminophenyl)ethanol, see 4-(1-Hydroxyethyl)aniline Page 1481 solubility (5 mM in H2O) ............................................................................................................................. soluble
solubility (50 mg/mL in glacial acetic acid) ................................................................................. soluble
689
2-Amino-1-phenylethanol, 98% Danger H300-H310-H330-H373-H410 P260-P264-
P273-P280-P284-P301 + P310
α-(Aminomethyl)benzyl alcohol; Phenylethanolamine; DL-β-Hydroxy-
phenethylamine A9563-5G glass btl 5g
[7568‑93‑6] Merck 14,7287; Beil. 13,IV,1801 NH2CH2CH(OH)C6H5 A9563-25G glass btl 25 g
FW 137.18 > N-(3-Aminophenyl)methanesulfamide, see N-(3-Aminophenyl)methanesul-
mp .................................................................................................................................................................... 56 to 58 °C fonamide Page 155
bp ....................................................................................................................................................... 160 °C/17 mmHg
N-(3-Aminophenyl)methanesulfonamide
7
Warning H315-H319-H335 P261-P305 + P351 + P338
N-(3-Aminophenyl)methanesulfamide O
H
A72405-10G poly btl 10 g [37045‑73‑1] C7H10N2O2S FW 186.23 N S CH3
O
NH2
(R)-(−)-2-Amino-1-phenylethanol, 97%
(R)-α-(Aminomethyl)benzyl alcohol mp .............................................................................................................................................................. 117 to 121 °C
[2549‑14‑6] Beil. 13,IV,1801 H2NCH2CH(C6H5)OH FW 137.18
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .................................................................................................................................................................... 59 to 65 °C
[α]22
D −39°, c = 2 in ethanol 548278-5G glass btl 5g
57
Danger H302-H314 P280-P305 + P351 + P338-P310 548278-25G glass btl 25 g
> (4S)-4-[(4-Aminophenyl)methyl]-2-oxazolidinone, see (S)-4-(4-Amino-

494577-1G glass btl 1g benzyl)-2(1H)-oxazolidinone Page 94
(S)-2-Amino-1-phenylethanol, ≥97.0% (GC, sum of enantiomers)
4-(3-Aminophenyl)-2-methylthiazole, 97%
(S)-α-(Aminomethyl)benzyl alcohol
2-Methyl-4-(3-aminophenyl)thiazole
[56613‑81‑1] Beil. 13,IV,1801 C8H11NO FW 137.18 H 2N
C10H10N2S FW 190.26
[α]20
D +43±2°, c = 2 in ethanol
N
57
Danger H302-H314 P280-P305 + P351 + P338-P310
S CH3
09222-500MG glass btl 500 mg mp .............................................................................................................................................................. 102 to 106 °C

> (R)-2-Amino-2-phenylethanol, see (R)-(−)-2-Phenylglycinol Page 2037
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
2-(4-Aminophenyl)ethanol, see 4-Aminophenethyl alcohol Page 153 P338
2-Aminophenyl ether, see 2,2′-Oxydianiline Page 1967
(2-Amino-1-phenyl-ethyl)carbamic acid tert-butyl ester, see α-(Boc-amino) 642630-1G glass btl 1g
phenethylamine Page 377 642630-5G glass btl 5g
1-(4-Aminophenyl)-1H-imidazole, see 4-(1H-Imidazol-1-yl)aniline
Page 1525 2-Amino-5-phenyl-1,3,4-oxadiazole, 97%
[1612‑76‑6] C8H7N3O FW 161.16 N N
2-(2-Aminophenyl)indole, 97%
O NH2
[32566‑01‑1] Beil. 22,IV,5017 C14H12N2 FW 208.26 H2N
N mp .............................................................................................................................................................. 237 to 242 °C

H
7
mp .............................................................................................................................................................. 154 to 155 °C
7
5-(4-Aminophenyl)-1,3,4-oxadiazole-2-thiol, 97%
[32058‑82‑5] C8H7N3OS FW 193.23
7
AHB A, 0613, UNP EU
n Aminophenyloxad n
> 2-(4-Aminophenyl)-1,3,4-oxadiazole-5-thione, see 5-(4-Aminophenyl)-1,3,4- (1R,2S)-2-Amino-1-phenyl-1-propanol, see (1R,2S)-(−)-Norephedrine
oxadiazole-2-thiol Page 155 Page 1940
5-(4-Aminophenyl)-1,3,4-oxadiazole-2(3H)-thione, see 5-(4-Aminophenyl)- (1S,2R)-2-Amino-1-phenyl-1-propanol, see (1S,2R)-(+)-Norephedrine
1,3,4-oxadiazole-2-thiol Page 155 Page 1940
(1S,2S)-2-Amino-1-phenyl-1-propanol, see (1S,2S)-(+)-Norpseudoephedrine
2-Amino-4-phenylphenol, 90% Page 1941
DL-erythro-2-Amino-1-phenyl-1-propanol hydrochloride, see DL-Norephe-
[1134‑36‑7] Beil. 13,II,419 H2NC6H3(C6H5)OH FW 185.22 drine hydrochloride Page 1940
mp .............................................................................................................................................................. 198 to 202 °C
(R)-(+)-2-Amino-3-phenyl-1-propanol, 98%
A  technical grade
D-Phenylalaninol
7
[5267‑64‑1] Beil. 13,IV,1920 C6H5CH2CH(NH2)CH2OH FW 151.21
mp ................................................................................................................................................................... 93 to 95 °C
[α]D +22.8°, c = 1.2 in 1 M HCl
> 2-Aminophenyl phenyl sulfide, see 2-(Phenylthio)aniline Page 2054
5
Danger H314 P280-P305 + P351 + P338-P310
2-Aminophenyl phenyl sulfone, see 2-(Phenylsulfonyl)aniline Page 2052
1-(4-Aminophenyl)piperazine, 97% 284491-1G glass btl 1g

[67455‑41‑8] C10H15N3 FW 177.25 H
N (S)-(−)-2-Amino-3-phenyl-1-propanol, 98%
N L-Phenylalaninol
[3182‑95‑4] Beil. 13,IV,1921 C6H5CH2CH(NH2)CH2OH FW 151.21
mp ................................................................................................................................................................... 92 to 94 °C
NH2  ee (HPLC): 99%
D −22.8°, c = 1.2 in 1 M HCl
[α]22
mp .............................................................................................................................................................. 119 to 123 °C
5
Danger H314 P280-P305 + P351 + P338-P310
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338
N-(4-Aminophenyl)piperidine, 97% > (R)-2-Amino-3-phenylpropionic acid, see D-Phenylalanine Page 2020
[2359‑60‑6] C11H16N2 FW 176.26 (S)-2-Amino-3-phenylpropionic acid, see L-Phenylalanine Page 2020
(R)-3-Amino-2-phenylpropionic acid, ≥98% (HPLC) 8
N
(R)-2-Phenyl-β-alanine O
C9H11NO2 FW 165.19
H2N OH
NH2
mp .................................................................................................................................................................... 26 to 29 °C
n20
D ................................................................................................................................................................................... 1.5937
[α]D -8.5±1.0°, c = 1 in 0.1 M HCl
7
Warning H315-H319-H335 P261-P305 + P351 + P338
composition
carbon 64.1‑66.7%
556629-1G glass btl 1g nitrogen 8.2‑8.7%
78
N-(3-Aminophenyl)propanamide, 97% Danger H315-H317-H319-H334-H335 P261-P280-P305 + P351
+ P338-P342 + P311
[22987‑10‑6] H2NC6H4NHC(O)CH2CH3 FW 164.20
mp .................................................................................................................................................................... 92 to 96 °C
> ±-3-Amino-3-phenylpropionic acid, see DL-β-Phenylalanine Page 2020
7
Warning H315-H319-H335 P261-P305 + P351 + P338
3-(4-Aminophenyl)propionic acid, 97%

3-(4-Aminophenyl)propanoic acid
> 1-Amino-2-phenylpropane, see β-Methylphenethylamine Page 1821
[2393‑17‑1] H2NC6H4CH2CH2CO2H FW 165.19
(1R,2R)-(−)-2-Amino-1-phenyl-1,3-propanediol, 98% mp .............................................................................................................................................................. 133 to 137 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[46032‑98‑8] Beil. 13,IV,2697; Fieser 13,18
C6H5CH(OH)CH(NH2)CH2OH FW 167.21
mp .............................................................................................................................................................. 112 to 118 °C
D −37°, c = 1 in 1 M HCl
[α]23
7
Warning H315-H319-H335 P261-P305 + P351 + P338 (1S,2S)-(2-Amino-1-phenylpropyl)diphenylphosphine
(1S,2S)-(2-Diphenylphosphino)-1-methyl-2-phenyl-
248886-1G glass btl 1g ethylamine
C21H22NP FW 319.38
P
CH3
(1S,2S)-(+)-2-Amino-1-phenyl-1,3-propanediol, 97%
L-(+)-threo-2-Amino-1-phenyl-1,3-propanediol
[28143‑91‑1] Beil. 13,IV,2697; Fieser 13,18; 12,32
C6H5CH(OH)CH(NH2)CH2OH FW 167.21 mp .............................................................................................................................................................. 100 to 105 °C
mp .............................................................................................................................................................. 109 to 113 °C  kanata purity
[α]25
D +37°, c = 1 in 1 M HCl [α]22
7
Warning H315-H319-H335 P261-P305 + P351 + P338 Sold under license from Kanata Chemical Technologies Inc. for
research purposes only.
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> (1R,2R)-2-Amino-1-phenyl-1-propanol, see (1R,2R)-(−)-Norpseudoephedrine
Page 1941 697583-100MG glass btl 100 mg

AHB A, 0613, UNP EU
n Aminophenylthia n
7
3-(4-Aminophenyl)pyrazole 8 Warning H302-H319 P305 + P351 + P338
4-(1H-Pyrazol-3-yl)aniline; 3-(4-Aminophenyl)-1H- NH2

pyrazole
[89260‑45‑7] C9H9N3 FW 159.19 1-(2-Aminophenyl)pyrrole, ≥98%
N
N
H [6025‑60‑1] C10H10N2 FW 158.20
N
mp .............................................................................................................................................................. 110 to 115 °C
NH2
A
3-Amino-4-phenyl-1H-pyrazole, 97% 8 mp ................................................................................................................................................................... 96 to 98 °C
[5591‑70‑8] C9H9N3 FW 159.19
7
NH2 + P338
N
H 196940-10G glass btl 10 g
mp .............................................................................................................................................................. 176 to 180 °C 3-Amino-2-phenyl-4(3H)-quinazolinone, 97%
7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 [1904‑60‑5] C14H11N3O FW 237.26
7
> 3-(4-Aminophenyl)-1H-pyrazole, see 3-(4-Aminophenyl)pyrazole 634999-1G glass btl 1g

Page 157
3-Aminophenyl sulfone, 97%
3-Amino-5-phenylpyrazole, 98% 3,3′-Sulfonyldianiline
[1572‑10‑7] Beil. 24,148 C9H9N3 FW 159.19 NH2
[599‑61‑1] Beil. 13,426 (H2NC6H4)2SO2 FW 248.30
mp .............................................................................................................................................................. 170 to 173 °C
N
7
N Warning H315-H319-H335 P261-P305 + P351 + P338
H

mp .............................................................................................................................................................. 124 to 127 °C
4-Aminophenyl sulfone, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Dapsone; Bis(4-aminophenyl) sulfone; 4,4′-Diaminodiphenyl sulfone;
393797-1G glass btl 1g 4,4′-Sulfonyldianiline; DDS
393797-5G glass btl 5g [80‑08‑0] Merck 14,2822; Beil. 13,IV,1306; 13,536 (H2NC6H4)2SO2
FW 248.30
5-Amino-1-phenylpyrazole-4-carbonitrile, 96%
mp .............................................................................................................................................................. 175 to 177 °C
[5334‑43‑0] C10H8N4 FW 184.20
7
NC Warning H302
H2N N
N
A74807-100G poly btl 100 g
A74807-500G poly btl 500 g
> N-(4-Aminophenylsulfonyl)acetamide sodium salt, see Sulfacetamide

mp .............................................................................................................................................................. 132 to 137 °C sodium salt hydrate Page 2345
7
Warning H302-H312-H315-H319-H332-H335 P261-P280-P305 + P351 2-Amino-5-phenyl-1,3,4-thiadiazole, 96%
+ P338
[2002‑03‑1] C8H7N3S FW 177.23 N N
389595-5G glass btl 5g S NH2
5-Amino-1-phenyl-1H-pyrazole-4-carboxylic acid, 97%

[51649‑80‑0] C10H9N3O2 FW 203.20 mp .............................................................................................................................................................. 223 to 227 °C
O
7
Warning H315-H319-H335 P261-P305 + P351 + P338
HO
N
H2N N
2-Amino-5-phenyl-1,3,4-thiadiazole sulfate salt, 97%

[340169‑03‑1] (C8H7N3S)2 · H2SO4 FW 354.45 (FB)
mp ............................................................................................................................................... 183 to 188 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H317-H319 P280-P305 + P351 + P338

639818-5G glass btl 5g 2-Amino-4-phenylthiazole, 97%
[2010‑06‑2] C9H8N2S FW 176.24
2-Amino-4-phenylpyrimidine, 97% 8
4-Phenylpyrimidin-2-amine N
[2305‑87‑5] C10H9N3 FW 171.20
S NH2
N
mp .............................................................................................................................................................. 149 to 153 °C
N NH2
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338
mp .............................................................................................................................................................. 162 to 164 °C

AHB A, 0613, UNP EU
n Aminophenylthia n
2-Amino-4-phenylthiazole hydrobromide monohydrate, 99% 3-Aminophthalimide, 97%

[52253‑69‑7] C9H8N2S · HBr · H2O FW 275.17 [2518‑24‑3] C8H6N2O2 FW 162.15 NH2 O
NH
2-(4-Aminophenylthio)acetic acid, ≥98.0% O
[104‑18‑7] C8H9NO2S FW 183.23
mp ...................................................................................................................................................... 268.5 to 273.5 °C
68
Danger H301-H319-H334 P261-P301 + P310-P305 + P351 +
7
A
P338-P342 + P311
> S-(4-Aminophenyl)thioglycolic acid, see 2-(4-Aminophenylthio)acetic acid 524794-10G glass btl 10 g
Page 158
4-Aminophthalonitrile, 98%
4-Amino-5-phenyl-4H-1,2,4-triazole-3-thiol, 97%
3,4-Dicyanoaniline
[22706‑11‑2] C8H8N4S FW 192.24 [56765‑79‑8] Beil. 14,III,1399 H2NC6H3-1,2-(CN)2 FW 143.15
7
Aminophylline, ≥98%
> 3-Aminophthalhydrazide, see Luminol Page 1632
3,7-Dihydro-1,3-dimethyl-1H-purine-
O
4-Aminophthalhydrazide 2,6-dione, cmpd. with 1,2-ethanedi- H3C
H
N N
Isoluminol; 6-Amino-2,3-dihydro-1,4-phthalazine- amine (2:1); (Theophylline)2 · H 2N
O NH2
Ethylenediamine; Theophylline hemi O N N
dione NH
(ethylenediamine) complex CH 3
[3682‑14‑2] Beil. 25,IV,4199 C8H7N3O2 FW 177.16 NH 2
H2N [317‑34‑0] Merck 14,465 C7H8N4O2 ·
O
0.5C2H8N2 FW 210.21
Features and Benefits Non-selective phosphodiesterase (PDE) inhibitor. Antiepileptic drug
Produces chemiluminescence.1  powder
mp ................................................................................................................................................................................ 300 °C solubility in alcohol ..................................................................................................................................... insoluble
Lit. cited: 1. Aldrichimica Acta 16, 59 (1983) soluble in ........................................................................................................................................ H2O (3.7 mg/mL)
7
Warning H315-H319-H335 P261-P305 + P351 + P338 color ............................................................................................................................................... white to off-white
store at: −20°C
6
Danger H301 P301 + P310
A8264-5G glass btl 5g A1755-25G poly btl 25 g
A8264-10G glass btl 10 g A1755-100G poly btl 100 g
3-Aminophthalic acid, 90% > 4-Aminopiazthiole, see 4-Amino-2,1,3-benzothiadiazole Page 93
[5434‑20‑8] Beil. 14,552 H2NC6H3-1,2-(CO2H)2 FW 181.15 2-Amino-3-picoline, 95%

mp .............................................................................................................................................................. 180 to 185 °C
2-Amino-3-methylpyridine CH3
 technical grade [1603‑40‑3] Beil. 22,V,9,272 C6H8N2 FW 108.14
7
Warning H315-H319-H335 P261-P305 + P351 + P338 N NH2
mp ............................................................ 29 to 31 °C density ................................. 1.073 g/mL, 25 °C

335347-1G glass btl 1g bp ............................................................... 221-222 °C n20
D ....................................................................... 1.5823
68
4-Aminophthalic acid, 97%
[5434‑21‑9] H2NC6H3-1,2-(CO2H)2 FW 181.15 A75633-100G glass btl 100 g
mp ................................................................................................................................................................. 344 °C (dec.) A75633-500G glass btl 500 g
7
Warning H315-H319-H335 P261-P305 + P351 + P338 2-Amino-4-picoline, 99%
2-Amino-4-methylpyridine
[695‑34‑1] Merck 14,466; Beil. 22,V,9,325 C6H8N2 FW 108.14
mp ................................................................................................................................................................... 96 to 99 °C
524716-10G glass btl 10 g bp ................................................................................................................................................................................. 230 °C
68
N-Aminophthalimide, 90% Danger H301-H311-H331-H373 P261-P280-P301 + P310-P311
N,N-Phthaloylhydrazine, unsym. O
123080-100G glass btl 100 g
[1875‑48‑5] Beil. 21,V,11,122; Fieser 1,38; 5,14
N NH2
C8H6N2O2 FW 162.15 > 3-Amino-2-picoline, see 3-Amino-2-methylpyridine Page 145
O 6-Amino-2-picoline, see 2-Amino-6-methylpyridine Page 145
mp .............................................................................................................................................................. 200 to 202 °C 6-Amino-3-picoline, 99%

 technical grade 2-Amino-5-methylpyridine
Remainder phthalhydrazide [1603‑41‑4] Beil. 22,V,9,289 C6H8N2 FW 108.14
78
Danger H315-H317-H319-H334-H335 P261-P280-P305 + P351 mp ................................................................................................................................................................... 76 to 77 °C
+ P338-P342 + P311 bp ................................................................................................................................................................................. 227 °C
6
178314-5G glass btl 5g Danger H301-H311-H315-H319-H331-H335 P261-P280-P301 + P310-
178314-25G poly btl 25 g P305 + P351 + P338-P311

AHB A, 0613, UNP EU
n Aminopropanol n
57
1-Aminopiperidine, 97% Danger H302-H314 P280-P305 + P351 + P338-P310
[2213‑43‑6] Beil. 20,89 C5H12N2 FW 100.16
N
09267-25G poly btl 25 g
NH2
(S)-3-Amino-1,2-propanediol, 98%
bp ............................................ 146 °C/730 mmHg n20
D .......................................................................... 1.475
density ..................................... 0.928 g/mL, 25 °C [61278‑21‑5] Beil. 4,I,447 H2NCH2CH(OH)CH2OH FW 91.11
bp ................................... 117-119 °C/0.4 mmHg n20 D .......................................................................... 1.483
A
remainder piperidine density ..................................... 1.175 g/mL, 25 °C
27
D −12±2° (neat or melt)
[α]23
total impurities ............................................................................................................................................... <0.5 mol
5
Danger H314 P280-P305 + P351 + P338-P310
3-Aminopiperidine dihydrochloride, 97%
(±)-3-Amino-1,2-propanediol, 97%
[138060‑07‑8] Beil. 22,IV,3743 C5H12N2 · 2HCl NH2
[616‑30‑8] Beil. 4,IV,1865 NH2CH2CH(OH)CH2OH FW 91.11
FW 173.08 • 2HCl bp ................................. 264-265 °C/739 mmHg n20 D .......................................................................... 1.492
N
H density ..................................... 1.175 g/mL, 25 °C
5
mp ................................................................................................................................................................. 230 °C (dec.)
Danger H314 P280-P305 + P351 + P338-P310
7
Warning H315-H319-H335 P261-P305 + P351 + P338
3-Amino-1-propanesulfonic acid, 97%
(R)-(−)-3-Aminopiperidine dihydrochloride, 97%
Tramiprosate; Homotaurine; 3APS
(R)-3-Piperidinamine dihydrochloride NH2
[334618‑23‑4] C5H12N2 · 2HCl FW 173.08 [3687‑18‑1] Merck 14,10218 H2N(CH2)3SO3H FW 139.17
• 2HCl
N mp ................................................................................................................................................................ 293 °C (dec.)
H
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 190 to 195 °C
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 + A76109-5G glass btl 5g
P338
3-Amino-1-propanethiol hydrochloride
(3-Mercaptopropyl)ammonium chloride
[7211‑54‑3] C3H10ClNS FW 91.18 (FB)
(S)-(+)-3-Aminopiperidine dihydrochloride, 96%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[334618‑07‑4] C5H12N2 · 2HCl FW 173.08
mp .............................................................................................................................................................. 205 to 209 °C 739294
674109-250MG glass btl 250 mg > 3-Amino-1,1,3-propanetricarboxylic acid, see γ-Carboxy-DL-glutamic acid
4-Aminopiperidine (R)-(−)-1-Amino-2-propanol, 98%

[13035‑19‑3] C5H10NNH2 FW 100.16 (−)-Isopropanolamine
density ............................................................................................................................................. 0.945 g/mL, 25 °C [2799‑16‑8] Beil. 4,IV,1664 CH3CH(OH)CH2NH2 FW 75.11
n20
D ................................................................................................................................................................................... 1.4910 mp ............................................................ 24 to 26 °C vd ............................................................... 2.6 (vs air)
bp ......................................................................... 160 °C vp ............................................. <1 mmHg (20 °C)
25
Danger H226-H314 P280-P305 + P351 + P338-P310
n20
D ........................................................................... 1.4482
561479-25G glass btl 25 g D −23.5°, c = 1 in methanol
[α]20
ee (GLC): 98%
4-Amino-2-(1-piperidinyl)pyrimidine-5-carbonitrile, 97%
5
Danger H314 P280-P305 + P351 + P338-P310
[90973‑23‑2] C10H13N5 FW 203.24
7
(S)-(+)-1-Amino-2-propanol, 98%
> Aminopolyethylene glycol monomethyl ether, see Methoxypolyethylene (+)-Isopropanolamine
glycol amine Page 1718
1-Aminopropane, see Propylamine Page 2198 [2799‑17‑9] Beil. 4,IV,1665 CH3CH(OH)CH2NH2 FW 75.11
1-Aminopropane hydrochloride, see Propylamine hydrochloride mp ............................................................ 24 to 26 °C n20 D ....................................................................... 1.4437
Page 2198 bp ......................................................................... 160 °C vd ............................................................... 2.6 (vs air)
2-Aminopropane, see Isopropylamine Page 1580 density ..................................... 0.954 g/mL, 25 °C vp ............................................. <1 mmHg (20 °C)
2-Aminopropane-d6, see Isopropyl-1,1,1,3,3,3-d6-amine Page 1580
2-Amino-1,3-propanediol, see Serinol Page 2271 [α]20
D +18°, c = 1.8 in H2O
Serinol hydrochloride Page 2271
5
Danger H314 P280-P305 + P351 + P338-P310
(R)-3-Amino-1,2-propanediol, ≥98.0% (T)
[66211‑46‑9] Beil. 4,I,447 C3H9NO2 FW 91.11 H2N OH 238864-5G glass btl 5g
OH
> (±)-1-Amino-2-propanol, see Amino-2-propanol Page 160
[α]20
D +28±1°, c = 4 in 5 M HCl
AHB A, 0613, UNP EU
n Aminopropanol n
Amino-2-propanol, 93% 3-Aminopropionitrile fumarate salt

(±)-1-Amino-2-propanol; (±)-Isopropanolamine [2079‑89‑2] Beil. 4,IV,2530 NH2CH2CH2CN · ½ (HO2CCH=CHCO2H)
[78‑96‑6] Beil. 4,III,754 CH3CH(OH)CH2NH2 FW 75.11 FW 128.13
mp .......................................................................... −2 °C n20
D ....................................................................... 1.4478 mp ................................................................................................................................................................ 177 °C (dec.)
bp ......................................................................... 160 °C vd ................................................................ 2.6 (vs air)
8
Danger H360 P201-P308 + P313
density ..................................... 0.973 g/mL, 25 °C vp ............................................. <1 mmHg (20 °C)
2-amino-1-propanol .................................................................................................................................................. 7%
A 5
Danger H314 P280-P305 + P351 + P338-P310 A3134-10G poly btl 10 g
> 3-Aminopropyl alcohol, see 3-Amino-1-propanol Page 160
(R)-(−)-2-Amino-1-propanol, 98% 2-(3-Aminopropylamino)ethanol, ≥98.0% (GC)

D-Alaninol N-(2-Hydroxyethyl)trimethylenediamine
[35320‑23‑1] Beil. 4,IV,1614 CH3CH(NH2)CH2OH FW 75.11 [4461‑39‑6] Beil. 4,IV,1562 NH2CH2CH2CH2NHCH2CH2OH
bp ............................................................... 166-168 °C n20
D ....................................................................... 1.4493 FW 118.18
density ..................................... 0.963 g/mL, 20 °C bp ....................................................................................................................................................................... 250-252 °C
D −18°, neat
[α]19 density ............................................................................................................................................. 1.007 g/mL, 20 °C
ee (GLC): 97% Inhibitor of the mammalian glycogen debranching enzyme1; Photo-
graphic development accelerator.
5
Danger H314 P280-P305 + P351 + P338-P310
n20
D ...................................................................................................................................................................................... 1.486
Lit. cited: 1. B.K. Gillard, T.E. Nelson, Biochemistry 16, 3978 (1977)
5
Danger H314 P280-P305 + P351 + P338-P310
(S)-(+)-2-Amino-1-propanol, 98% 09293-500ML glass btl 500 mL

L-Alaninol > N-(3-Aminopropyl)-1,4-butanediamine trihydrochloride, see Spermidine
[2749‑11‑3] Beil. 4,IV,1615 CH3CH(NH2)CH2OH FW 75.11 trihydrochloride Page 2328
bp .......................................... 72-73 °C/11 mmHg n20
D ....................................................................... 1.4498
{4-[(3-Aminopropyl)-tert-butoxycarbonylamino]butyl}carbamic acid tert-
density ..................................... 0.965 g/mL, 25 °C butyl ester, see N1,N5-Bis-Boc-spermidine Page 298
3-Aminopropyl tert-butyl ether hydrochloride, see 3-(tert-Butoxy)propyl-
[α]20
D +18°, neat
amine hydrochloride Page 555
N-(3-Aminopropyl)-1,4-diaminobutane, see Spermidine Page 2328
ee (GLC): 97%
5
Danger H314 P280-P305 + P351 + P338-P310 3-Aminopropyl(diethoxy)methylsilane, 97%
3-Aminopropyl-methyl-diethoxysilane; 3-(Diethoxymethylsilyl)propyl-
amine
[3179‑76‑8] Beil. 4,IV,4201 CH3Si(OC2H5)2(CH2)3NH2 FW 191.34
> (±)-2-Amino-1-propanol, see DL-Alaninol Page 64 liquid
bp ............................................. 85-88 °C/8 mmHg n20
D .......................................................................... 1.426
3-Amino-1-propanol density ..................................... 0.916 g/mL, 25 °C
3-Aminopropyl alcohol
5
Danger H314 P280-P305 + P351 + P338-P310
[156‑87‑6] Beil. 4,IV,1623 HO(CH2)3NH2 FW 75.11
mp ............................................................ 10 to 12 °C vd ............................................................. 2.59 (vs air) 371890-50ML glass btl 50 mL
bp ............................................................... 184-187 °C vp ............................................. 2.1 mmHg (20 °C) 371890-250ML glass btl 250 mL
n20
D ........................................................................... 1.4598 > (3-Aminopropyl)diphenylphosphine, see 3-(Diphenylphosphino)-1-propyl-
amine Page 1152
5
Danger H314 P280-P305 + P351 + P338-P310
3-Aminopropyl functionalized silica
 ≥99%
NH2
239844-10G glass btl 10 g Si
 99%  nanoparticles, particle size ~100 nm (DLS), dispersion, 3 % (w/v)

in ethanol
Nanoparticle building block for self-assembly.1
A76400-500G glass btl 500 g bp ............................................................................................................................................................................ 75-78 °C
> 3-Amino-1-propene, see Allylamine Page 67 density ............................................................................................................................................. 0.836 g/mL, 25 °C
3-Amino-15N-1-propene-13C3, see Allyl-13C3-amine-15N Page 67 Lit. cited: 1. Gallow, T.H. et al., Adv. Mater. 12, 576 (2000)
3-Aminopropene-13C3,15N hydrochloride, see Allyl-13C3-amine-15N hydro-
28
Danger H225-H371 P210-P260
chloride Page 68
2-Amino-1,1,3-propenetricarbonitrile, 97% 660442-25ML glass btl 25 mL
2-Amino-1,1-3-tricyanopropene; Malononitrile dimer 3-Aminopropyl-functionalized silica gel

[868‑54‑2] Merck 14,480; Beil. 4,IV,3109 (NC)2C=C(NH2)CH2CN
FW 132.12 Si
NH2
mp .............................................................................................................................................................. 171 to 173 °C
7
Warning H302
 40-63 μm, loading: ~1 mmol/g NH2
For low- and medium-pressure reversed-phase liquid chromatog-
raphy.
> L-α-Aminopropionic acid, see L-Alanine Page 61 extent of labeling ................................................................................................................ ~9% functionalized
(R)-2-Aminopropionic acid, see D-Alanine Page 61 particle platform ............................................................................................................................ irregular silica
(S)-2-Aminopropionic acid, see L-Alanine Page 61
phase ................................................................................................................................................................................. NH2
(±)-2-Aminopropionic acid, see DL-Alanine Page 62
3-Aminopropionic acid, see β-Alanine Page 62

AHB A, 0613, UNP EU
n Aminopropylpyrr n
surface area .................................................................................................................................................... 550 m2/g 3-Aminopropyl(3-oxobutanoic acid) functionalized silica

mean pore size ......................................................................................................................................................... 60 Å
Carboxylic acid-functionalized silica colloid O
7
N
Si OH
O
364258-50G glass btl 50 g bp ....................................................................................................................................................................... 143-153 °C
364258-250G glass btl 250 g  nanoparticles, particle size ~15 nm (DLS), dispersion, 2.5 % (w/v)
A
1-(3-Aminopropyl)imidazole, 98% in DMF
Dispersion may settle. Shake well before use.
[5036‑48‑6] Beil. 23,IV,577 C6H11N3 FW 125.17 N Used for the self-assembly of nano-scale monolayers.1
N density ............................................................................................................................................. 0.927 g/mL, 25 °C
NH2
Lit. cited: 1. Galow, T.H. et al., Adv. Mater. 12, 576 (2000)
density ............................................................................................................................................. 1.049 g/mL, 25 °C
n20
D ...................................................................................................................................................................................... 1.519
(1S)-(+)-(1-Aminopropyl)phosphonic acid, 98%
5
Danger H314 P280-P305 + P351 + P338-P310 [98048‑99‑8] C2H5CH(NH2)P(O)(OH)2 FW 139.09
mp .............................................................................................................................................................. 265 to 269 °C
272264-50G glass btl 50 g [α]20
D +16.5°, c = 2 in 1 M NaOH
7
O-(2-Aminopropyl)-O′-(2-methoxyethyl)polypropylene glycol
Jeffamine® M-600; Polypropylene glycol 500 mono-2-aminoethyl
mono-2-methoxyethyl ether 3-Aminopropylphosphonic acid, 98%
[77110‑54‑4] CH3OCH2CH2O[CH(CH3)CH2O]nCH2CH(NH2)CH3 [13138‑33‑5] Beil. 4,III,1793 H2N(CH2)3P(O)(OH)2 FW 139.09
density ................................................................................................................................................ 0.98 g/mL, 25 °C GABAB receptor agonist; antagonist of basal prolactin secretion.
n20
D ...................................................................................................................................................................................... 1.445 mp ................................................................................................................................................................ 294 °C (dec.)
 average Mn ~600
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
422118-100ML glass btl 100 mL N-(3-Aminopropyl)-2-pipecoline, 96%
[25560‑00‑3] C9H20N2 FW 156.27
O-(2-Aminopropyl)-O′-(2-methoxyethyl)polypropylene glycol
500 N CH3
NH2
Jeffamine® M-600; Polypropylene glycol 500 mono-2-aminoethyl
mono-2-methoxyethyl ether bp .......................................... 96-97 °C/15 mmHg n20
D ....................................................................... 1.4765
[77110‑54‑4] CH3OCH2CH2O[CH(CH3)CH2O]nCH2CH(NH2)CH3 density ..................................... 0.889 g/mL, 25 °C
7
5
Danger H314 P280-P305 + P351 + P338-P310
09303-500ML glass btl 500 mL 186112-5G glass btl 5g

1-(3-Aminopropyl)-4-(2-methoxyphenyl)piperazine, 8 N-(3-Aminopropyl)piperidine, 95%
97% 8
3-[4-(2-Methoxyphenyl)-1-piperazinyl]propylamine 3-Piperidinopropylamine
NH2
[20529‑23‑1] C14H23N3O FW 249.35 [3529‑08‑6] C8H18N2 FW 142.24
N N
NH2
N
OCH3
density ............................................................................................................................................. 0.895 g/mL, 25 °C
n20
D ...................................................................................................................................................................................... 1.476
57
Danger H302-H314 P280-P305 + P351 + P338-P310
≥97.0% (HPLC)
5
Danger H314 P280-P305 + P351 + P338-P310 store at: 2-8°C 694134-5G glass btl 5g
728497-1G glass btl 1g N-(3-Aminopropyl)-2-pyrrolidinone

728497-5G glass btl 5g [7663‑77‑6] C7H14N2O FW 142.20
N O
1-(3-Aminopropyl)-2-methyl-1H-imidazole, 96% 8
NH2
3-(2-Methyl-1H-imidazol-1-yl)propylamine N
[2258‑21‑1] C7H13N3 FW 139.20 CH3 bp ....................................... 120-123 °C/1 mmHg n20D ................................................................................ 1.5
N
density ..................................... 1.014 g/mL, 25 °C
NH2
 technical grade
density ............................................................................................................................................. 1.028 g/mL, 25 °C
Contains varying amounts of 1,5-diazabicyclo[4.3.0]non-5-ene (cat. no.
n20
D ...................................................................................................................................................................................... 1.517
136581)
57
Danger H302-H314 P280-P305 + P351 + P338-P310 2-pyrrolidinone ............................................................................................................................................................. 2%
5
Danger H314 P280-P305 + P351 + P338-P310
> 4-(3-Aminopropyl)morpholine, see 3-Morpholinopropylamine Page 1875 136565-5G glass btl 5g

136565-100G glass btl 100 g

AHB A, 0613, UNP EU
n Aminopropyltrie n
(3-Aminopropyl)triethoxysilane 3-Amino-2-pyrazinecarboxylic acid, ≥99%

3-Triethoxysilylpropylamine; APTES [5424‑01‑1] Beil. 25,IV,4412 C5H5N3O2 FW 139.11 N NH2
[919‑30‑2] Beil. 4,IV,4273 H2N(CH2)3Si(OC2H5)3 FW 221.37 OH
N
bp .................................................................................................................................................... 217 °C/760 mmHg
O
density ............................................................................................................................................. 0.946 g/mL, 25 °C
57
Danger H302-H314 P280-P305 + P351 + P338-P310 mp ............................................................................................................................................... 205 to 210 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
A  Dow Corning® product Z-6011

99% A76982-5G glass btl 5g
Forms aminopropyl derivative of glass, an adsorbent for affinity A76982-25G poly btl 25 g
chromatography. Used to prepare positively charged slides suitable
3-Aminopyrazole, 98%
for use with various immunohistochemical and in situ hybridization
procedures.1 Recently (3-Aminopropyl)triethoxysilane has been used 3-Pyrazolamine; 3-AP NH2
to prepare dye-doped silica nanoparticles with minimal aggregation [1820‑80‑0] Beil. 25,IV,2028 C3H5N3 FW 83.09
N
and minimal nonspecific binding with biomolecules.2 N
H
Used in a preparation of a series of tenary composite films of
polyimide/SiO/polydiphenylsiloxane with good optical transparency.3 mp ................................................................................................................................................................... 34 to 37 °C
Manufactured by Dow Corning Corporation, U.S.A. Repackaged by bp .................................................................................................................................................... 218 °C/122 mmHg
Aldrich Chemical Company, Inc. Employed in a one-pot synthesis of pyrazolopyrimidines.1
®Registered trademark of Dow Corning Corporation, U.S.A. Used in the preparation of heterocyclic compounds of pharma-
Lit. cited: 1. Weetall, H.H.,, Biochim. Biophys. Acta 212, 1 (1970) ceutical interest.2
2. Bagwe, R.P. et al., Langmuir 22, 4357 (2006) Lit. cited: 1. Tetrahedron Lett. 47, 2611 (2006)
3. Polym. Int. 55, 1277 (2006) 2. Trends Heterocycl. Chem. 2, 97 (1991)
57
Danger H302-H314 P280-P305 + P351 + P338-P310
 packaged for use in deposition systems, 99% 8

160644-2.5G glass btl 2.5 g
liquid
706493-20ML ss cyl 20 mL
4-Aminopyrazole, 95% 8
(3-Aminopropyl)trimethoxysilane, 97%
3-(Trimethoxysilyl)propylamine [28466‑26‑4] C3H5N3 FW 83.09 H2N
[13822‑56‑5] H2N(CH2)3Si(OCH3)3 FW 179.29 N

N
liquid H
bp .......................................... 91-92 °C/15 mmHg n20
D .......................................................................... 1.424
density ..................................... 1.027 g/mL, 25 °C mp ................................................................................................................................................................... 77 to 82 °C
7
7
Warning H315-H319 P305 + P351 + P338

281778-100ML glass btl 100 mL 3-Aminopyrazole-4-carbonitrile, 97%
3-Amino-4-cyanopyrazole NC NH2
(3-Aminopropyl)tris(trimethylsiloxy)silane, ≥95% (GC) [16617‑46‑2] Beil. 25,IV,4323 C4H4N4 FW 108.10
N
N
3-[Tris(trimethylsiloxy)silyl]propylamine TMS H
O
[25357‑81‑7] C12H35NO3Si4 FW 353.75 H2N
Si O mp .............................................................................................................................................................. 172 to 174 °C
TMS
O
TMS Building block used in the synthesis of a variety of heterocycles.1,2
Lit. cited: 1. Synlett 65 (2006)
density ............................................................................................................................................. 0.891 g/mL, 20 °C 2. Helv. Chim. Acta 89, 30 (2006)
n20
D ...................................................................................................................................................................................... 1.413
 technical 153044-25G glass btl 25 g
7
Warning H315-H319-H335 P261-P305 + P351 + P338
3-Amino-4-pyrazolecarboxamide hemisulfate salt
09329-5ML glass btl 5 mL [27511‑79‑1] C4H6N4O · 0.5H2SO4 FW 175.16
09329-25ML glass btl 25 mL mp ................................................................................................................................................................ 224 °C (dec.)
> 3-Amino-1-propyne, see Propargylamine Page 2193
3-Amino-1-propyne hydrochloride, see Propargylamine hydrochloride
Page 2193
3-Amino-4-pyrazolecarboxylic acid, 95%
6-Aminopurine, see Adenine Page 58 [41680‑34‑6] C4H5N3O2 FW 127.10 O
2-Amino-6-purinethiol, see 6-Thioguanine Page 2427 NH2
HO
Aminopyrazine, 98% N
N
H
Pyrazinamine N
[5049‑61‑6] Beil. 25,IV,2139 C4H5N3 FW 95.10 mp ................................................................................................................................................................ 135 °C (dec.)
N NH2
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 118 to 120 °C
Substrate in a four-component synthesis of imidazolidines.1 A77407-1G glass btl 1g
Lit. cited: 1. Synth. Commun. 37, 247 (2007) A77407-5G glass btl 5g
7
Warning H315-H319-H335 P261-P305 + P351 + P338


AHB A, 0613, UNP EU
n Aminopyridineca n
4-Aminopyrazolo[3,4-d]pyrimidine, 98% mp .............................................................................................................................................................. 155 to 158 °C

bp ................................................................................................................................................................................. 273 °C
[20289‑44‑5] C5H5N5 FW 135.13 NH2
6
N + P338
N
N N
H  ≥99%
mp ............................................................................................................................................................................ >325 °C
6
A77806-1G
P305 + P351 + P338-P311
glass btl 1g
 98% A
A78403-100G poly btl 100 g
> (S)-2-Amino-3-(1-pyrazolyl)propionic acid, see 3-(1-Pyrazolyl)-L-alanine
Page 2212 2-Aminopyridine-5-boronic acid pinacol ester, 97%
2-Amino-5-(4,4,5,5-tetramethyl-1,3,2-dioxa- CH3
1-Aminopyrene, 97% H3C
borolan-2-yl)pyridine; 6-Aminopyridine-3- H3C O
1-Pyrenamine; 3-Aminopyrene NH2
boronic acid pinacol ester H3C O
B
[1606‑67‑3] Beil. 12,IV,3460 C16H11N FW 217.27 [827614‑64‑2] C11H17BN2O2 FW 220.08

N NH2
mp .............................................................................................................................................................. 131 to 135 °C

mp .............................................................................................................................................................. 115 to 117 °C Substrate used in a microwave-assisted, four-component coupling
process leading to amino substituted imidazopyridines.1
7
7
Warning H315-H319-H335 P261-P305 + P351 + P338
3-Aminopyridazine, 97% 8 640379-1G glass btl 1g

Pyridazin-3-amine NH2
[5469‑70‑5] C4H5N3 FW 95.10 > 6-Aminopyridine-3-boronic acid pinacol ester, see 2-Aminopyridine-5-
N
N boronic acid pinacol ester Page 163
mp .............................................................................................................................................................. 168 to 172 °C 2-Amino-3-pyridinecarbonitrile, 97%
7
Warning H302-H319 P305 + P351 + P338
2-Amino-3-cyanopyridine
[24517‑64‑4] C5H3NNH2CN FW 119.12
mp .............................................................................................................................................................. 132 to 136 °C
57
2-Aminopyridine Danger H302-H318 P280-P305 + P351 + P338
2-Pyridylamine; 2-Pyridinamine; 2-AP
[504‑29‑0] Merck 14,473; Beil. 22,V,8,280; Fieser 9,18 697133-1G glass btl 1g
N NH2 697133-5G glass btl 5g
C5H6N2 FW 94.11
mp .................................................................................................................................................................... 54 to 58 °C 5-Amino-2-pyridinecarbonitrile, 96%
bp ....................................................................................................................................................................... 204-210 °C
5-Amino-2-cyanopyridine H2N
6
Danger H301-H311-H315-H319-H335 P261-P280-P301 + P310-P305 + [55338‑73‑3] Beil. 22,13,587 C6H5N3 FW 119.12
P351 + P338-P312 N CN
 ≥99% mp .............................................................................................................................................................. 148 to 152 °C

7
A77989-100G glass btl 100 g + P338
 99%
538906-100G glass btl 100 g
A77997-100G glass btl 100 g 6-Amino-3-pyridinecarbonitrile, 97%
A77997-500G glass btl 500 g 2-Amino-5-cyanopyridine; 6-Aminonicotinonitrile
3-Aminopyridine, 99% [4214‑73‑7] C5H3NNH2CN FW 119.12
mp .............................................................................................................................................................. 159 to 163 °C
3-Pyridinamine NH2
6
Danger H301-H312-H332 P280-P301 + P310
[462‑08‑8] Merck 14,473; Beil. 22,V,9,3 C5H6N2 FW 94.11
N
bp ................................................................................................................................................................................. 248 °C
2-Amino-3-pyridinecarboxaldehyde, 97%
68
P301 + P310-P305 + P351 + P338-P311 [7521‑41‑7] C6H6N2O FW 122.12 O
A78209-25G glass btl 25 g H
A78209-100G glass btl 100 g N NH2
mp ................................................................................................................................................................. 98 to 102 °C
4-Aminopyridine
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Fampridine; 4-Pyridylamine; 4-Pyridinamine; 4AP NH2
[504‑24‑5] Merck 14,3933; Beil. 22,V,9,106 C5H6N2 FW 94.11 639109-1G glass btl 1g
N
AHB A, 0613, UNP EU
n Aminopyridineca n
7
2-Aminopyridine-3-carboxamide, 97% 8 Warning H302-H315-H319-H335 P261-P305 + P351 + P338
2-Aminonicotinamide O
[13438‑65‑8] C6H7N3O FW 137.14
NH2
2-Amino-5-(4-pyridinyl)-1,3,4-thiadiazole, 97%
N NH2
[2002‑04‑2] C7H6N4S FW 178.21 N N
mp .............................................................................................................................................................. 194 to 200 °C NH2
S
A 6
Danger H301-H317-H319 P280-P301 + P310-P305 + P351 + P338 N
7
> 6-Aminopyridine-3-carboxamide, see 6-Aminonicotinamide Page 148
2-Aminopyridine-3-carboxylic acid, 98% 663573-1G glass btl 1g
2-Aminonicotinic acid; 2-Aminopyridine-3-carboxylic acid 663573-10G glass btl 10 g

O
[5345‑47‑1] Beil. 22,V,13,592 C6H6N2O2 FW 138.12 OH > (R)-2-Amino-3-(2-pyridyl)propionic acid, see 3-(2-Pyridyl)-D-alanine
Page 2223
N NH2 (S)-2-Amino-3-(2-pyridyl)propionic acid, see 3-(2-Pyridyl)-L-alanine
Page 2223
mp ............................................................................................................................................... 295 to 297 °C (dec.) (S)-2-Amino-3-(3-pyridyl)propionic acid, see 3-(3-Pyridyl)-L-alanine
Page 2223
A68300-5G glass btl 5g (R)-2-Amino-3-(4-pyridyl)propionic acid, see 3-(4-Pyridyl)-D-alanine
A68300-25G glass btl 25 g Page 2223
(S)-2-Amino-3-(4-pyridyl)propionic acid, see 3-(4-Pyridyl)-L-alanine
3-Aminopyridine-4-carboxylic acid, 95% Page 2223
8
3-Aminoisonicotinic acid O OH 4-Amino-5-(4-pyridyl)-4H-1,2,4-triazole-3-thiol, 97%
[7579‑20‑6] C6H6N2O2 FW 138.12 [36209‑51‑5] Beil. 26,IV,2129 C7H7N5S FW 193.23
NH2 N N
N SH
N
N NH2
mp .............................................................................................................................................................. 305 to 310 °C
mp .............................................................................................................................................................. 250 to 254 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> 4-Amino-3-pyridinecarboxylic acid, see 4-Amino-nicotinic acid Page 148
5-Aminopyridine-3-carboxylic acid, 97% 2-Aminopyrimidine, 97%

5-Aminonicotinic acid O 2-Pyrimidinamine
N
[24242‑19‑1] C6H6N2O2 FW 138.12 H2N [109‑12‑6] Beil. 25,IV,2071 C4H5N3 FW 95.10
OH
N NH2
N
mp .............................................................................................................................................................. 122 to 126 °C
7
7
Warning H315-H319-H335 P261-P305 + P351 + P338
672513-1G poly tube 1g

A78608-100G poly btl 100 g
A78608-500G poly btl 500 g
6-Aminopyridine-3-carboxylic acid, 97%
4-Aminopyrimidine, 98%
6-Aminonicotinic acid
[591‑54‑8] Beil. 24,81 C4H5N3 FW 95.10 NH2
[3167‑49‑5] Merck 14,456; Beil. 22,IV,6726 C6H6N2O2 FW 138.12
mp ............................................................................................................................................................................ >300 °C N

mp .............................................................................................................................................................. 154 to 156 °C
1-Aminopyridinium iodide, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[6295‑87‑0] Beil. 20,V,5,382 C5H7IN2 FW 222.03
N I
NH2
2-Aminopyrimidine-5-boronic acid 8
mp .............................................................................................................................................................. 159 to 161 °C
[936250‑22‑5] C4H6BN3O2 FW 138.92
7
Warning H315-H319-H335 P261-P305 + P351 + P338 OH
B
HO N
441503-10G glass btl 10 g N NH2
> (3-Aminopyridin-4-yl)-carbamic acid tert-butyl ester, see 3-Amino-4-(Boc-

amino)pyridine Page 96 mp .............................................................................................................................................................. 206 to 211 °C
May contain varying amounts of anhydride
2-Amino-4-pyridinylmethanol, 97% 8
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Amino-4-(hydroxymethyl)pyridine OH
[105250‑17‑7] C6H8N2O FW 124.14 706221-250MG glass btl 250 mg
N NH2
mp .................................................................................................................................................................... 80 to 84 °C

AHB A, 0613, UNP EU
n Aminoquinoline n
4-Amino-5-pyrimidinecarbonitrile, 96% 4-Aminoquinaldine, 98%

[16357‑69‑0] Beil. 25,IV,4411 C5H4N4 FW 120.11 NH2 4-Amino-2-methylquinoline NH2
NC
N
[6628‑04‑2] Beil. 22,V,10,347 C10H10N2 FW 158.20
N N CH3
mp .............................................................................................................................................................. 251 to 255 °C mp .............................................................................................................................................................. 162 to 166 °C
57
Danger H302-H312-H315-H317-H318-H332-H335 P261-P280- bp ................................................................................................................................................................................. 333 °C
A
P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> 5-Amino-2,4-pyrimidinediol, see 5-Aminouracil Page 172 A79000-25G poly btl 25 g

6-Amino-2,4-pyrimidinediol, see 6-Aminouracil Page 173
4-Amino-N-(2-pyrimidinyl)benzenesulfonamide, see Sulfadiazine 3-Amino-4(3H)-quinazolinone, 97%
Page 2345 [14663‑46‑8] C8H7N3O FW 161.16
Aminopyrine-4-(dimethylamino-13C2), see
7
4-(Dimethyl-13C2-amino)antipyrine Page 1059 Warning H302-H315-H319 P305 + P351 + P338
1-Aminopyrrolidine hydrochloride 634980-1G glass btl 1g

[63234‑71‑9] C4H10N2 · HCl FW 122.60
2-Aminoquinoline, 97% 8
N
NH2 • HCl 2-Quinolinamine
[580‑22‑3] C9H8N2 FW 144.17
mp .............................................................................................................................................................. 109 to 126 °C N NH2

May contain varying amounts of dihydrochloride
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
7
Warning H315-H319-H335 P261-P305 + P351 + P338 P338
3-Aminoquinoline, 98%
3-Quinolinamine; 3-AQ NH2
3-Aminopyrrolidine dihydrochloride, 98% [580‑17‑6] Beil. 22,V,10,233 C9H8N2 FW 144.17
[103831‑11‑4] C4H10N2 · 2HCl FW 159.06 N
mp ............................................................................................................................................................................ >300 °C mp ................................................................................................................................................................... 91 to 92 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319 P305 + P351 + P338

(R)-(+)-3-Aminopyrrolidine, 98%
5-Quinolinamine NH2
[116183‑82‑5] C4H10N2 FW 86.14 NH2 [611‑34‑7] Beil. 22,V,10,297 C9H8N2 FW 144.17
N N
H
mp .............................................................................................................................................................. 106 to 109 °C
bp ............................................................... 164-165 °C n20
D .......................................................................... 1.489 bp ................................................................................................................................................................................. 310 °C
density ..................................... 0.984 g/mL, 25 °C
7
Warning H315-H319 P305 + P351 + P338
[α]D +20°, neat
7
Warning H315-H319-H335 P261-P305 + P351 + P338 A79205-1G glass btl 1g
(S)-(−)-3-Aminopyrrolidine, 98%
6-Quinolinamine
[128345‑57‑3] C4H10N2 FW 86.14 [580‑15‑4] Beil. 22,V,10,303 C9H8N2 FW 144.17
bp ............................................................... 164-165 °C n20
D .......................................................................... 1.488
mp .............................................................................................................................................................. 115 to 119 °C
density ..................................... 0.967 g/mL, 25 °C
bp ..................................................................................................................................................... 146 °C/0.3 mmHg
[α]20 −20°, neat
7
D Warning H315-H319 P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> 4-Amino-7H-pyrrolo[2,3-d]pyrimidine, see 6-Amino-7-deazapurine 8-Aminoquinoline, 98%
Page 114
8-Quinolinamine
[578‑66‑5] Beil. 22,V,10,316 C9H8N2 FW 144.17
mp ................................................................................................................................................................... 60 to 65 °C
bp ...................................................................................................................................................... 174 °C/26 mmHg
7
Warning H315-H319 P305 + P351 + P338


AHB A, 0613, UNP EU
n Aminoquinolinol n
2-Amino-8-quinolinol, ≥98.0% (GC) 3-Aminosalicylic acid, 97%

2-Amino-8-hydroxyquinoline 3-Amino-2-hydroxybenzoic acid
[70125‑16‑5] Beil. 22,IV,5860 C9H8N2O [570‑23‑0] Beil. 14,IV,1963 H2NC6H3-2-(OH)CO2H FW 153.14
FW 160.17 N NH2 mp ................................................................................................................................................................ 240 °C (dec.)
7
OH Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 157 to 160 °C

A 7
Warning H315-H319-H335 P261-P305 + P351 + P338
08128-1G glass btl 1g 4-Aminosalicylic acid, 99%

08128-5G glass btl 5g 4-Amino-2-hydroxybenzoic acid; PAS
6-Aminoquinoxaline, 95% [65‑49‑6] Merck 14,477; Beil. 14,IV,1967 H2NC6H3-2-(OH)CO2H
8
FW 153.14
Quinoxalin-6-amine H2N N mp .............................................................................................................................................................. 135 to 145 °C
[6298‑37‑9] C8H7N3 FW 145.16
7
N
Warning H319 P305 + P351 + P338
7
Warning H302-H315-H319 P305 + P351 + P338 A79604-100G glass btl 100 g
5-Aminosalicylic acid, 95%

Mesalamine; 5-AS; 5-Amino-2-hydroxybenzoic acid
3-Aminoquinuclidine dihydrochloride, 98% [89‑57‑6] Merck 14,5904; Beil. 14,IV,2058 H2NC6H3-2-(OH)CO2H
[6530‑09‑2] Beil. 22,IV,3816 C7H14N2 · 2HCl FW 153.14
FW 199.12 NH2
mp ............................................................................................................................................... 275 to 280 °C (dec.)
N • 2HCl
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp ............................................................................................................................................... 321 to 323 °C (dec.)
100358-25G poly btl 25 g A79809-100G poly btl 100 g
> 13 15
L-a-Amino-ß-(4-imidazolyl)propionic acid - C6, N3, see L
(R)-(+)-3-Aminoquinuclidine dihydrochloride, 98% -Histidine-13C6,15N3 hydrochloride monohydrate Page 1449
[123536‑14‑1] C7H14N2 · 2HCl FW 199.12 (R)-(−)-2-Aminosuccinamic acid, see D-Asparagine monohydrate
NH2 Page 201
N • 2HCl
(S)-(+)-2-Aminosuccinamic acid, see L-Asparagine monohydrate Page 201
(S)-(+)-Aminosuccinic acid, see L-Aspartic acid Page 201
(R)-2-Aminosuccinic acid, see D-Aspartic acid Page 201
mp ............................................................................................................................................................................ >300 °C
(±)-2-Aminosuccinic acid, see DL-Aspartic acid Page 202
[α]20
D +24°, c = 1 in H2O (R)-2-Aminosuccinic acid 4-amide, see D-Asparagine Page 201
D-Asparagine monohydrate Page 201
7
Warning H315-H319-H335 P261-P305 + P351 + P338
(S)-2-Aminosuccinic acid 4-amide, see L-Asparagine Page 201
DL-2-Amino-4-sulfobutyric acid, see DL-Homocysteic acid Page 1450
415715-1G glass btl 1g (S)-5-Aminosulfonyl-N-[(1-ethyl-2-pyrrolidinyl)methyl]-2-methoxyben-
zamide, see (S)-(−)-Sulpiride Page 2352
(S)-(−)-3-Aminoquinuclidine dihydrochloride, 98% 2-Amino-5-([4-sulfophenyl]azo)benzenesulfonic acid, see 4-Amino-1,1′-
azobenzene-3,4′-disulfonic acid sodium salt Page 91
[119904‑90‑4] C7H14N2 · 2HCl FW 199.12 4-Amino-TEMPO, see 4-Amino-TEMPO, free radical Page 166
D −24°, c = 1 in H2O
[α]20
4-Amino-TEMPO, free radical
7
Warning H315-H319-H335 P261-P305 + P351 + P338
4-Amino-2,2,6,6-tetramethylpiperidine-1-oxyl; 4- NH2
415723-250MG glass btl 250 mg Amino-2,2,6,6-tetramethylpiperidinyloxy, free radical;
415723-1G glass btl 1g 4-Amino-TEMPO H3C CH3
H3C N CH3
[14691‑88‑4] C9H19N2O FW 171.26
4-Aminoresorcinol hydrochloride, 97% O
2,4-Dihydroxyaniline hydrochloride mp .................................................................................................................................................................................. ~0 °C

[34781‑86‑7] Beil. 13,783 H2NC6H3-1,3-(OH)2 · HCl FW 161.59
 for ESR-spectroscopy
mp ................................................................................................................................................................. 220 °C (dec.)
97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
3-Aminorhodanine, 99% 163945-1G glass btl 1g

[1438‑16‑0] Beil. 27,245 C3H4N2OS2 FW 148.21 O NH2
N 2-Aminoterephthalic acid, 99%
S S
[10312‑55‑7] Beil. 14,I,630 H2NC6H3-1,4-(CO2H)2 FW 181.15
mp .............................................................................................................................................................. 100 to 103 °C mp ................................................................................................................................................................ 324 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
6
Danger H300-H310 P264-P280-P301 + P310-P302 + P350-P310

AHB A, 0613, UNP EU
n Aminotetrahydro n
2-Amino-3,4,5,6-tetrafluorobenzoic acid, 98% 1-Amino-5,6,7,8-tetrahydronaphthalene, see 5,6,7,8-Tetrahydro-1-naphthyl-

amine Page 2391
3,4,5,6-Tetrafluoroanthranilic acid 2-Amino-5,6,7,8-tetrahydronaphthalene, see 5,6,7,8-Tetrahydro-2-naphthyl-
[1765‑42‑0] H2NC6F4CO2H FW 209.10 amine Page 2392
6-Amino-1,2,3,4-tetrahydronaphthalene, see 5,6,7,8-Tetrahydro-2-naphthyl-
mp .............................................................................................................................................................. 141 to 143 °C amine Page 2392
7
Warning H315-H319-H335 P261-P305 + P351 + P338
(R)-2-Amino-1,2,3,4-tetrahydronaphthalene-2-carboxylic acid,
≥99.0% (HPLC)
A
(R)-2-Amino-1,2,3,4-tetrahydro-2-naphthoic acid; (R)- O
4-Amino-2,3,5,6-tetrafluorobenzoic acid, 99% 2-Aminotetralin-2-carboxylic acid
OH
[944‑43‑4] H2NC6F4CO2H FW 209.10 [104974‑44‑9] C11H13NO2 FW 191.23 NH2
mp .............................................................................................................................................................. 185 to 187 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338 [α]D -4.7±0.5°, c = 0.5 in 0.3% HCl
ee: ≥98%
247936-1G glass btl 1g water .............................................................................................................................................................................. ≤10%
7
Warning H302
4-Amino-2,3,5,6-tetrafluorobenzonitrile, 99%
670383-100MG poly btl 100 mg
[17823‑38‑0] H2NC6F4CN FW 190.10
670383-500MG poly btl 500 mg
mp .................................................................................................................................................................... 96 to 98 °C
(S)-2-Amino-1,2,3,4-tetrahydro-2-naphthalenecarboxylic acid,
7
+ P338 ≥99.0% (HPLC)
247944-5G glass btl 5g (S)-2-Amino-1,2,3,4-tetrahydro-2-naphthoic acid; (S)-2-Aminotetralin-
2-carboxylic acid
4-Amino-2,3,5,6-tetrafluoropyridine, 98% [104974‑45‑0] C11H13NO2 FW 191.23
[1682‑20‑8] C5H2F4N2 FW 166.08 NH2 [α]D +4.7±0.5°, c = 0.5 in 0.3 M HCl
F F ee: ≥98%
water .............................................................................................................................................................................. ≤10%
F N F
7
Warning H302
mp .................................................................................................................................................................... 85 to 87 °C
7
Warning H302-H312-H315-H319-H332-H335 P261-P280-P305 + P351 670499-100MG poly btl 100 mg
+ P338 670499-500MG poly btl 500 mg
> (R)-2-Amino-1,2,3,4-tetrahydro-2-naphthoic acid, see (R)-2-Amino-1,2,3,4-
9-Amino-1,2,3,4-tetrahydroacridine hydrochloride hydrate, tetrahydronaphthalene-2-carboxylic acid Page 167
≥99% (S)-2-Amino-1,2,3,4-tetrahydro-2-naphthoic acid, see (S)-2-Amino-1,2,3,4-
tetrahydro-2-naphthalenecarboxylic acid Page 167
Tetrahydroaminacrine hydrochloride hydrate; NH2 (1R,2R)-trans-2-Amino-1,2,3,4-tetrahydro-1-naphthol
THA hydrochloride hydrate; Tacrine hydro- 8
• HCl hydrochloride, ≥96.0%
chloride • xH2O
N (1R,2R)-2-Amino-1-tetralol hydrochloride OH
Merck 14,9024; Beil. 22,IV,4911 C13H14N2 · HCl
[115563‑64‑9] C10H13NO · HCl FW 199.68 NH2
· xH2O FW 234.72 (Anh)
mp .............................................................................................................................................................. 284 to 286 °C • HCl
68
P301 + P310-P305 + P351 + P338-P311 ≥96.0% (HPLC)
7
2-Amino-4,5,6,7-tetrahydrobenzothiazole, 97% 714038-250MG glass btl 250 mg

4,5,6,7-Tetrahydrobenzothiazoyl-2-ylamine N (1R,2S)-cis-2-Amino-1,2,3,4-tetrahydro-1-naphthol 8
[2933‑29‑1] C7H10N2S FW 154.23 NH2
S
(1R,2S)-2-Amino-1-tetralol hydrochloride OH
mp .................................................................................................................................................................... 86 to 90 °C
[29365‑56‑8] C10H13NO · HCl FW 199.68 NH2
7

≥96.0% (HPLC)
> (R)-(+)-3-Aminotetrahydrofuran p-toluenesulfonate salt, see (R)-(+)-Tetra- enantiomeric excess: ≥97.0%
hydro-3-furylamine p-toluenesulfonate salt Page 2389
7
Warning H302 store at: 2-8°C
5-Amino-1,2,3,4-tetrahydroisoquinoline, 98%
1,2,3,4-Tetrahydro-5-aminoisoquinoline NH2
[115955‑90‑3] C9H12N2 FW 148.20 (1S,2R)-cis-2-Amino-1,2,3,4-tetrahydro-1-naphthol 8
NH
(1S,2R)-2-Amino-1-tetralol hydrochloride OH
mp .............................................................................................................................................................. 153 to 155 °C [29365‑58‑0] C10H13NO · HCl FW 199.68 NH2
7
596825-1G glass btl 1g ≥96.0% (HPLC)

596825-5G glass btl 5g enantiomeric excess: ≥97.0%
7
> N-(4-Amino-1,2,3,6-tetrahydro-1-methyl-2,6-dioxo-5-pyrimidinyl)
acetimide-13C4,15N3(ring-13C4,15N2,amino-15N), see 5-Acetylamino-6-
amino-3-methyluracil-ring-13C4,15N2,amino-15N Page 32 714054-250MG glass btl 250 mg
AHB A, 0613, UNP EU
n Aminotetrahydro n
(1S,2S)-trans-2-Amino-1,2,3,4-tetrahydro-1-naphthol 8 5-Aminotetrazole, 97%

[4418‑61‑5] CH3N5 FW 85.07 N N
(1S,2S)-2-Amino-1-tetralol hydrochloride N
H2N N
[115563‑63‑8] C10H13NO · HCl FW 199.68 H
≥96.0% (HPLC)
enantiomeric excess: ≥97.0% mp .............................................................................................................................................................. 201 to 205 °C
7
7
A 714046-250MG glass btl 250 mg 550728-100G

550728-500G
poly btl
poly btl
100 g
500 g
2-Amino-4-(5,6,7,8-tetrahydro-2-naphthyl)thiazole, 8
97% 5-Aminotetrazole monohydrate, 97%
4-(1,2,3,4-Tetrahydronaphthalen-6-yl)thiazol-2- Tetrazol-5-amine N N
amine [15454‑54‑3] Beil. 26,IV,3469 CH3N5 · H2O H2N N • H2O
N N
[87999‑04‑0] C13H14N2S FW 230.33 FW 103.08 H
S NH2
mp ............................................................................................................................................... 198 to 204 °C (dec.)
mp .............................................................................................................................................................. 105 to 110 °C
7
7
Warning H315-H319-H335 P261-P305 + P351 + P338
4-Aminotetrahydropyran, 97% 8 > (S)-2-Amino-3-(2-tetrazolyl)propionic acid, see 3-(2-Tetrazolyl)-L-alanine
Page 2417
Tetrahydro-2H-pyran-4-amine NH2
[38041‑19‑9] C5H11NO FW 101.15 2-Amino-1,3,4-thiadiazole, 97%
O 1,3,4-Thiadiazol-2-amine N N
[4005‑51‑0] Beil. 27,IV,8053 C2H3N3S FW 101.13 NH2
density ........................................................................................................................................... 0.977 g/cm3, 25 °C S
n20
D ...................................................................................................................................................................................... 1.463
mp ............................................................................................................................................... 188 to 191 °C (dec.)
25
Danger H226-H318 P280-P305 + P351 + P338
7

> (R)-(−)-1-AminoTetralin, see (R)-(−)-1,2,3,4-Tetrahydro-1-naphthylamine 258881-5G glass btl 5g
Page 2391
(S)-(+)-1-AminoTetralin, see (S)-(+)-1,2,3,4-Tetrahydro-1-naphthylamine 5-Amino-1,3,4-thiadiazole-2-thiol, 98%
Page 2391
6-Aminotetralin, see 5,6,7,8-Tetrahydro-2-naphthylamine Page 2392 2-Amino-5-mercapto-1,3,4-thiadiazole N N
(R)-2-Aminotetralin-2-carboxylic acid, see (R)-2-Amino-1,2,3,4-tetrahydro- [2349‑67‑9] Beil. 27,IV,8185 C2H3N3S2 FW 133.20 H2N SH
naphthalene-2-carboxylic acid Page 167 S
(S)-2-Aminotetralin-2-carboxylic acid, see (S)-2-Amino-1,2,3,4-tetrahydro-2-
naphthalenecarboxylic acid Page 167 mp ................................................................................................................................................................ 235 °C (dec.)
(R)-(−)-1-Aminotetraline, see (R)-(−)-1,2,3,4-Tetrahydro-1-naphthylamine
7
Page 2391
(S)-(+)-1-Aminotetraline, see (S)-(+)-1,2,3,4-Tetrahydro-1-naphthylamine
Page 2391 127906-50G poly btl 50 g
(1R,2R)-2-Amino-1-tetralol hydrochloride, see (1R,2R)-trans-2-Amino-1,2,3,4-
tetrahydro-1-naphthol hydrochloride Page 167 2-Aminothiazole, 97%
(1R,2S)-2-Amino-1-tetralol hydrochloride, see (1R,2S)-cis-2-Amino-1,2,3,4-
tetrahydro-1-naphthol hydrochloride Page 167 2-Thiazolamine N
(1S,2R)-2-Amino-1-tetralol hydrochloride, see (1S,2R)-cis-2-Amino-1,2,3,4- [96‑50‑4] Merck 14,479; Beil. 27,IV,4574; Fieser 4,19 NH2
tetrahydro-1-naphthol hydrochloride Page 167 S
C3H4N2S FW 100.14
(1S,2S)-2-Amino-1-tetralol hydrochloride, see (1S,2S)-trans-2-Amino-1,2,3,4-
tetrahydro-1-naphthol hydrochloride Page 168 mp ................................................................................................................................................................... 91 to 93 °C
6-Amino-1-tetralone, see 6-Amino-3,4-dihydro-1(2H)-naphthalenone Used in a mild Ulmann coupling with 2-chlorobenzoic acids
Page 116
2-Amino-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine, see 2-
mediated by ultrasonic irradiation.1
Aminopyridine-5-boronic acid pinacol ester Page 163 Lit. cited: 1. Synth. Commun. 37, 1853 (2007)
7
Warning H302-H319 P305 + P351 + P338
4-Amino-2,2,6,6-tetramethylpiperidine, 98%
[36768‑62‑4] Beil. 22,V,8,162 C9H20N2 FW 156.27 123129-5G glass btl 5g
NH2
123129-100G poly btl 100 g
H3C CH3 123129-500G poly btl 500 g
H3C N CH3
H
2-Amino-4-thiazoleacetic acid, 95%
mp ............................................................ 16 to 18 °C density .................................. 0.912 g/mL, 25 °C [29676‑71‑9] Beil. 27,336 C5H6N2O2S FW 158.18 HO
N
bp ............................................................... 188-189 °C n20
D .......................................................................... 1.470
O
S NH2
57
Danger H302-H314-H412 P273-P280-P305 + P351 + P338-
P310
mp ................................................................................................................................................................ 130 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
> 4-Amino-2,2,6,6-tetramethylpiperidine-1-oxyl, see 4-Amino-TEMPO, free 249696-25G glass btl 25 g

radical Page 166
4-Amino-2,2,6,6-tetramethylpiperidinyloxy, free radical, see 4-Amino- 2-Aminothiazole-5-carbonitrile, 97% 8
TEMPO, free radical Page 166
2-Amino-5-cyanothiazole N
[51640‑52‑9] C4H3N3S FW 125.15 N C NH2
S

AHB A, 0613, UNP EU
n Aminotoluene n
mp .............................................................................................................................................................. 204 to 208 °C DL-α-Amino-2-thiopheneacetic acid, 97%
57
Danger H302-H318 P280-P305 + P351 + P338 DL-α-Amino-2-thienylacetic acid; DL-2-(2-Thienyl)glycine O
[21124‑40‑3] Beil. 18,V,12,184 C6H7NO2S FW 157.19 OH
S
2-Aminothiazole-5-carboxaldehyde, 95%
mp .............................................................................................................................................................. 208 to 210 °C
2-Amino-5-formylthiazole N 188808-1G glass btl 1g
[1003‑61‑8] C4H4N2OS FW 128.15 H
A
S NH2 188808-5G glass btl 5g
O
2-Aminothiophene-3-carbonitrile, 97%
mp .............................................................................................................................................................. 122 to 132 °C
The presence of different functional groups allows differential [4651‑82‑5] C5H4N2S FW 124.16 CN
attachment of an azo linkage and benzoxazolium salt providing

NH2
cationic, delocalized azo dyes.1 S

mp .............................................................................................................................................................. 104 to 108 °C
7
57
P338 Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338
2-Amino-4-thiazolecarboxylic acid hydrobromide, 90% 681067-5G glass btl 5g
[112539‑08‑9] C4H4N2O2S · HBr FW 225.06 3-Aminothiophene-2-carboxamide, 97%
7
Warning H319 P305 + P351 + P338
[147123‑47‑5] C5H6N2OS FW 142.18 NH2
636282-250MG glass btl 250 mg NH2

S
O
2-Amino-2-thiazoline hydrochloride, 98%
[3882‑98‑2] Beil. 27,136 C3H6N2S · HCl FW 138.62 mp .............................................................................................................................................................. 120 to 124 °C
N
• HCl
6
S NH2

263729-250G glass btl 250 g 2-Aminothiophenol
> (R)-2-Amino-3-(2-thiazolylthio)propionic acid, see S-(2-Thiazolyl)-L-cysteine 2-Aminophenyl mercaptan; 2-Aminobenzenethiol; 2-Mercaptoaniline
Page 2422 [137‑07‑5] Beil. 13,IV,910 H2NC6H4SH FW 125.19
2-Amino-3-(2-thienyl)propionic acid, see 3-(2-Thienyl)-DL-alanine mp ............................................................ 16 to 20 °C density .................................... 1.17 g/mL, 25 °C
Page 2422
(S)-2-Amino-3-(2-thienyl)propionic acid, see 3-(2-Thienyl)-L-alanine bp ......................................... 70-72 °C/0.2 mmHg n20 D .......................................................................... 1.642
Page 2422
579
Danger H302-H314-H410 P273-P280-P305 + P351 +
P338-P310-P501
5-Amino-3-(2-thienyl)pyrazole, 96%
 99%
[96799‑03‑0] C7H7N3S FW 165.22
S
N 274240-100G glass btl 100 g
H2N N
H
 technical grade, 90%
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338 3-Aminothiophenol, 96%
586269-5G glass btl 5g 3-Aminobenzenethiol
[22948‑02‑3] Beil. 13,425 H2NC6H4SH FW 125.19
> 2-Aminothioanisole, see 2-(Methylthio)aniline Page 1851
density ............................................................................................................................................. 1.179 g/mL, 25 °C
3-Aminothioanisole, see 3-(Methylthio)aniline Page 1851
n20
D ...................................................................................................................................................................................... 1.656
4-Aminothiobenzamide, 97% 8
57
Danger H302-H312-H314-H332 P280-P305 + P351 + P338-
4-Aminobenzothioamide; 4-Aminobenzenecarbo- S
P310
thioamide NH2
[4714‑67‑4] C7H8N2S FW 152.22 143480-25G glass btl 25 g
H2N
4-Aminothiophenol, 97%
mp .............................................................................................................................................................. 185 to 190 °C
4-Mercaptoaniline; 4-Aminophenyl mercaptan; 4-Aminobenzenethiol
7
Warning H302-H317-H319 P280-P305 + P351 + P338
[1193‑02‑8] Beil. 13,IV,1289 H2NC6H4SH FW 125.19
mp ................................................................................................................................................................... 37 to 42 °C
bp ............................................................................................................................................ 140-145 °C/16 mmHg
2-Amino-6-thiocyanatobenzothiazole, 96%
5
Danger H314 P280-P305 + P351 + P338-P310
[7170‑77‑6] C8H5N3S2 FW 207.28 N
N C S S
mp .............................................................................................................................................................. 194 to 197 °C > 6-Amino-2-thiouracil monohydrate, see 4-Amino-6-hydroxy-2-mercaptopyr-
imidine monohydrate Page 129
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Aminotoluene, see o-Toluidine Page 2453
4-Aminotoluene, see p-Toluidine Page 2453

AHB A, 0613, UNP EU
n Aminotoluenesul n
4-Aminotoluene-3-sulfonic acid, 99% mp ............................................................................................................................................................................... 182 °C
7
2-Amino-5-methylbenzenesulfonic acid; 4-Methylaniline-2-sulfonic Warning H315-H319-H335 P261-P305 + P351 + P338
acid
[88‑44‑8] Beil. 14,III,2213 H2NC6H3(CH3)SO3H FW 187.22 282073-25G glass btl 25 g
DuPont product 5-Amino-1H-[1,2,4]-triazole-3-carboxylic acid methyl ester, 96%
5
Danger H314 P280-P305 + P351 + P338-P310
[3641‑14‑3] C4H6N4O2 FW 142.12 O
OCH3
A
218766-250G glass btl 250 g N
N
> 3-Amino-p-toluic acid, see 3-Amino-4-methylbenzoic acid Page 137 H2N N
H
5-Amino-o-toluic acid, see 5-Amino-2-methylbenzoic acid Page 137
6-Amino-o-tolunitrile, see 2-Amino-6-methylbenzonitrile Page 138
2-Amino-5-(p-tolyl)-1,3,4-thiadiazole, see 2-Amino-5-(4-methylphenyl)-1,3,4- mp .............................................................................................................................................................. 218 to 222 °C
thiadiazole Page 143
7
Warning H317 P280
2-Amino-4-(p-tolyl)thiazole, 96%
4-(4-Methylphenyl)-2-thiazolamine H3C
[2103‑91‑5] C10H10N2S FW 190.26 3-Amino-1,2,4-triazole-5-thiol, 95%
3-Amino-5-mercapto-1,2,4-triazole NH2
N [16691‑43‑3] Beil. 26,IV,1351 C2H4N4S FW 116.14 N
NH2 HS N
S N
H
mp .............................................................................................................................................................. 132 to 136 °C
mp ............................................................................................................................................................................ >300 °C
7
7
Warning H315-H319-H335 P261-P305 + P351 + P338
140260-10G poly btl 10 g
> (S)-2-Amino-3-(1,2,4-triazol-1-yl)propionic acid, see 3-(1,2,4-Triazol-1-yl)-L-
3-Amino-1,2,4-triazine, 97% alanine Page 2462
[1120‑99‑6] C3H4N4 FW 96.09 3-Amino-4,4,4-trifluorobutanoic acid methyl ester hydrochloride, see
N NH2
Methyl 3-amino-4,4,4-trifluorobutyrate hydrochloride Page 1737
N
N
2-Amino-5-(trifluoromethoxy)benzoic acid, 97%
mp .............................................................................................................................................................. 174 to 177 °C [83265‑56‑9] C8H6F3NO3 FW 221.13 O
7
Warning H315-H319-H335 P261-P305 + P351 + P338 F3CO
OH
NH2
100625-10G poly btl 10 g
100625-50G poly btl 50 g mp .............................................................................................................................................................. 138 to 142 °C
6
> 2-Amino-1,3,5-triazine-4,6-dione-13C3, see Ammelide-13C3 Page 173 Danger H301-H317-H319 P280-P301 + P310-P305 + P351 + P338
4-Amino-1,3,5-triazin-2-one, see 5-Azacytosine Page 207
3-Amino-1,2,4-triazole, ~95% (TLC)
1,2,4-Triazol-3-amine; 3-AT; Amitrol NH2
4-Amino-6-(trifluoromethyl)benzene-1,3-disulfonamide, ≥96%
N (HPLC)
[61‑82‑5] Merck 14,489; Beil. 26,IV,1073 C2H4N4 FW 84.08
N
N 5-Amino-α,α,α-trifluorotoluene-2,4-disulfonamide NH2
H
[654‑62‑6] Beil. 14,IV,2811 C7H8F3N3O4S2 O S O
mp .............................................................................................................................................................. 150 to 153 °C FW 319.28 F3C
Reagent for the determination of tryptophan in proteins. O
S
store at: −20°C
89
Warning H361d-H373-H411 P273-P281 NH2
H2N O

 technical
ign. residue ................................................................................................................................................................ ≤2%
mp .............................................................................................................................................................. 241 to 246 °C
7
4-Amino-4H-1,2,4-triazole, 99% Warning H315-H319-H335 P261-P305 + P351 + P338
4H-1,2,4-Triazol-4-amine N N
[584‑13‑4] Beil. 26,IV,40 C2H4N4 FW 84.08 09575-50G poly btl 50 g
N
NH2 09575-250G 250 g
mp .................................................................................................................................................................... 84 to 86 °C
2-Amino-4-(trifluoromethyl)benzenethiol hydrochloride, 97%
[4274‑38‑8] H2NC6H3(CF3)SH · HCl FW 229.65
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 196 to 198 °C
7
A81803-5G glass btl 5g Warning H302-H312-H315-H319-H332-H335 P261-P280-P305 + P351
A81803-25G glass btl 25 g + P338
3-Amino-1,2,4-triazole-5-carboxylic acid hydrate, 98%
[304655‑78‑5] Beil. 26,311 C3H4N4O2 · xH2O 5-Amino-2-(trifluoromethyl)benzimidazole, 96%
NH2
FW 128.09 (Anh) N [3671‑66‑7] C8H6F3N3 FW 201.15 H2N N
HO N
N • xH2O CF3
O H N
H
mp .............................................................................................................................................................. 185 to 189 °C

AHB A, 0613, UNP EU
n Aminotrifluorom n
6
Danger H301-H315-H319-H335 P261-P301 + P310-P305 + P351 + 2-Amino-3-(trifluoromethyl)pyridine, 97% 8
P338
3-(Trifluoromethyl)-2-pyridinamine CF3
[183610‑70‑0] C6H5F3N2 FW 162.11
N NH2
2-Amino-3-(trifluoromethyl)benzoic acid, 98%
3-(Trifluoromethyl)anthranilic acid mp ................................................................................................................................................................... 66 to 71 °C
[313‑12‑2] Beil. 14,IV,1356 CF3C6H3-2-(NH2)CO2H FW 205.13
6
mp .............................................................................................................................................................. 157 to 160 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338 728683-1G glass btl 1g A
2-Amino-4-(trifluoromethyl)pyridine, 97%
[106447‑97‑6] C6H5F3N2 FW 162.11 CF3
3-Amino-5-(trifluoromethyl)benzoic acid, 97%
[328‑68‑7] C8H6F3NO2 FW 205.13
N NH2
mp .............................................................................................................................................................. 141 to 146 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338 mp ................................................................................................................................................................... 70 to 74 °C
6
Danger H300-H315-H317-H319-H335 P261-P264-P280-P301 + P310-
579513-1G glass btl 1g P305 + P351 + P338
4-Amino-2-(trifluoromethyl)benzonitrile, 97%
4-Cyano-3-trifluoromethylaniline
[654‑70‑6] NCC6H3(CF3)NH2 FW 186.13 2-Amino-5-(trifluoromethyl)pyridine, 97%
mp .............................................................................................................................................................. 141 to 145 °C [74784‑70‑6] C6H5F3N2 FW 162.11 F3C
7
N NH2

mp ................................................................................................................................................................... 45 to 49 °C
6
2-Amino-6-(trifluoromethyl)benzothiazole, 96% P338
6-(Trifluoromethyl)-1,3-benzothiazol-2-ylamine 684716-250MG glass btl 250 mg

N
[777‑12‑8] C8H5F3N2S FW 218.20 NH2 684716-1G glass btl 1g
F 3C S
mp .............................................................................................................................................................. 120 to 124 °C [34486‑24‑3] C6H5F3N2 FW 162.11
6
+ P338 F3C N NH2

mp ................................................................................................................................................................... 85 to 89 °C
7-Amino-4-(trifluoromethyl)coumarin, ≥99% Substrate used in a one-pot synthesis of the corresponding 7-aza-
indole.1
Coumarin 151 CF3 Lit. cited: 1. Tetrahedron Lett. 46, 2283 (2005)
[53518‑15‑3] C10H6F3NO2 FW 229.16
6
Danger H300-H315-H317-H319-H335 P261-P264-P280-P301 + P310-
P305 + P351 + P338
H2N O O
Suitable as laser dye
λmax ............................................................................................................................................................................. 207 nm
[387824‑61‑5] C6H5F3N2 FW 162.11
7
Warning H315-H319-H335 P261-P305 + P351 + P338 NH2
CF3
248924-250MG glass btl 250 mg N

mp ................................................................................................................................................................. 98 to 102 °C
> 1-Amino-1-(trifluoromethyl)cyclopentane hydrochloride, see (±)-1-(Trifluor-
6
omethyl)cyclopentanamine hydrochloride Page 2507 Danger H300-H315-H317-H319-H335 P261-P264-P280-P301 + P310-
P305 + P351 + P338
2-Amino-5-(trifluoromethyl)-1,3,4-oxadiazole, 97% 8 661090-100MG glass btl 100 mg
[768‑29‑6] C3H2F3N3O FW 153.06 N N 661090-500MG glass btl 500 mg
F3C O NH2
mp .............................................................................................................................................................. 155 to 160 °C [106877‑33‑2] C6H5F3N2 FW 162.11 NH2
6
Danger H301 P301 + P310
F3C N

> (±)-2-Amino-4-(trifluoromethyl)pentanoic acid, see 5,5,5-Trifluoro-DL-leucine Employed in a covenient, one-pot, synthesis of azaindoles.1
Page 2498 Lit. cited: 1. Tetrahedron Lett. 46, 2283 (2005)
(±)-2-Amino-2-[3-(trifluoromethyl)phenyl]acetic acid, see 3-(Trifluoro-
6
methyl)-DL-phenylglycine Page 2511 + P338
(S)-2-Amino-2-[4-(trifluoromethyl)phenyl]acetic acid, see 4-(Trifluoro-
methyl)-L-phenylglycine Page 2511 640107-1G glass btl 1g
(S)-2-Amino-3-[3-(trifluoromethyl)phenyl]propionic acid, see 3-(Trifluoro-
methyl)-L-phenylalanine Page 2510
(R)-2-Amino-3-[4-(trifluoromethyl)phenyl]propionic acid, see 4-(Trifluoro-
methyl)-D-phenylalanine Page 2510
(S)-2-Amino-3-[4-(trifluoromethyl)phenyl]propionic acid, see 4-(Trifluoro-
methyl)-L-phenylalanine Page 2510
AHB A, 0613, UNP EU
n Aminotrifluorom n
2-Amino-4-(trifluoromethyl)pyrimidine, 97% 8 (S)-(−)-2-Amino-1,1,2-triphenylethanol, 97%

[16075‑42‑6] C5H4F3N3 FW 163.10 CF3
[129704‑13‑8] C6H5CH(NH2)C(OH)(C6H5)2 FW 289.37
mp .............................................................................................................................................................. 128 to 132 °C
N
[α]20
N NH2
mp .............................................................................................................................................................. 174 to 178 °C
(R)-(+)-2-Amino-1,1,3-triphenyl-1-propanol, 98%
A 689
Danger H300-H319-H334-H400 P261-P264-P273-P301
+ P310-P305 + P351 + P338-P342 + P311 [86906‑05‑0] C6H5CH2CH(NH2)C(C6H5)2OH FW 303.40
7
2-Amino-5-trifluoromethyl-1,3,4-thiadiazole, 97% 554472-1G glass btl 1g

[10444‑89‑0] C3H2F3N3S FW 169.13 N N 554472-5G glass btl 5g
F3C S NH2 (S)-(−)-2-Amino-1,1,3-triphenyl-1-propanol, 98%
mp .............................................................................................................................................................. 225 to 227 °C [79868‑78‑3] C6H5CH2CH(NH2)C(C6H5)2OH FW 303.40
mp .............................................................................................................................................................. 139 to 144 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[α]20
7
2-Amino-4-(trifluoromethyl)thiazole-5-carboxylic acid, 97% 3-Amino-L-tyrosine dihydrochloride monohydrate, 98%

[239135‑55‑8] C5H3F3N2O2S FW 212.15 [23279‑22‑3] Beil. 14,622 H2NC6H3-4-(OH)CH2CH(NH2)CO2H · 2HCl ·
F3 C
N H2O FW 287.14
HO mp ............................................................................................................................................... 158 to 160 °C (dec.)
S NH2
O D −1.6°, c = 2 in H2O
[α]22
mp ............................................................................................................................................... 232 to 236 °C (dec.)
> 11-Aminoundecanethiol hydrochloride, see 11-Amino-1-undecanethiol

7
11-Amino-1-undecanethiol hydrochloride, 99%
11-Aminoundecanethiol hydrochloride; 11-Mercaptoundecylamine;
> 5-Amino-α,α,α-trifluorotoluene-2,4-disulfonamide, see 4-Amino-6-(trifluoro- MUAM
methyl)benzene-1,3-disulfonamide Page 170
[143339‑58‑6] HSCH2(CH2)9CH2NH2 · HCl FW 239.85
5-Amino-2,4,6-triiodoisophthalic acid, 95% mp .............................................................................................................................................................. 120 to 170 °C
AUT
[35453‑19‑1] Beil. 14,IV,1903 H2NC6I3-1,3-(CO2H)2 FW 558.84
Creating SAMs containing amino functionalized sites.1 This molecule
mp .............................................................................................................................................................. 265 to 270 °C
is used to modify gold surfaces with amine groups. The amine group
water ................................................................................................................................................................................. <5%
is usually modified using amine-reactive materials, such as proteins or
7
Warning H317 P280 biomaterials, to further functionalize the gold surface. This material
has also been self-assembled onto gold electrodes for a study on the
444367-50G glass btl 50 g effect of the terminal groups on the redox responses of ferrocene
derivatives using the voltammetric method.2 Tanahashi and co-
2-Amino-3,4,5-trimethoxybenzoic acid, 97%
workers modified a gold surface with SAMs of several kinds of
[61948‑85‑4] C10H13NO5 FW 227.21 O functionalized alkanethiols.3
H3CO
OH
Lit. cited: 1. Belser T. et al., J. Am. Chem. Soc. 127(24), 8720-8731 (2005)
2. Takehara, K.; Takemura, H.; Ide, Y., Electrochim. Acta 39, 817 (1994)
H3CO NH2 3. Tanahashi, M.; Matsuda, T., J. Biomed. Mater. Res. 34, 305 (1994)
OCH3
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 137 to 141 °C
7
Warning H317-H319 P280-P305 + P351 + P338
11-Aminoundecanoic acid, 97%
[2432‑99‑7] Beil. 4,IV,2823 NH2(CH2)10CO2H FW 201.31
mp .............................................................................................................................................................. 188 to 191 °C
> (1S,3R)-5-Amino-1,3,3-trimethyl-cyclohexanemethylamine (2R,3R)-2,3-bis A82605-100G poly btl 100 g
(benzoyloxy)butanedioate, see (1R,3S)-3-Aminomethyl-3,5,5-trimethylcy-
clohexylamine O,O′-dibenzoyl-L-tartrate salt Page 147 A82605-500G poly btl 500 g
5-Amino-1,3,3-trimethylcyclohexanemethylamine, mixture of 5-Aminouracil, 98%

cis and trans, ≥99% 5-Amino-2,4-pyrimidinediol; 5-Amino-2,4-dihydroxy- O
Isophorone diamine pyrimidine H2N
NH
[2855‑13‑2] H2NC6H7(CH3)3CH2NH2 FW 170.30 [932‑52‑5] Beil. 25,IV,4126 C4H5N3O2 FW 127.10
N O
mp ........................................................................... 10 °C density .................................. 0.922 g/mL, 25 °C H
bp ......................................................................... 247 °C n20
D .......................................................................... 1.488
mp ............................................................................................................................................................................ >300 °C
57
7
+ P338-P310 Warning H302

855286-25G poly btl 25 g
> 2-Amino-2,4,4-trimethylpentane, see tert-Octylamine Page 1952

AHB A, 0613, UNP EU
n Ammonia n
6-Aminouracil, 97%  anhydrous

4-Amino-2,6-dihydroxypyrimidine; 6-Amino-2,4-pyrimi- O
Reagent for chemical vapor deposition of TiN.1
dinediol Stainless steel control valves Z146951, Z187224 or either of stainless
NH
[873‑83‑6] Beil. 25,IV,4107 C4H5N3O2 FW 127.10 steel regulators Z148504 and Z148512 and a "T"-purge valve Z151661
H2N N
H
O is recommended.
Lit. cited: 1. Weiller, B.H., J. Am. Chem. Soc. 118, 4975 (1996)
mp ............................................................................................................................................................................ ≥360 °C
4569
Danger H221-H280-H314-H331-H400 P210-
P261-P273-P280-P305 + P351 + P338-P310
7
Warning H302
A50606-100G poly btl 100 g

294993-170G steel cyl 170 g
A
Ammonia solution
> N-Aminourea hydrochloride, see Semicarbazide hydrochloride Page 2269 [7664‑41‑7] Merck 14,492 NH3 FW 17.03
(R)-2-Amino-5-ureidopentanoic acid, see D-Citrulline Page 765
(S)-2-Aminovaleric acid, see L-Norvaline Page 1941  0.5 M in dioxane
(R)-3-Amino-valeric acid, see (R)-3-Aminopentanoic acid Page 152 density ..................................... 1.023 g/mL, 25 °C vp ................................................. 11.73 psi (55 °C)
(S)-3-Amino-valeric acid, see (S)-3-Aminopentanoic acid Page 152
vp ....................................................... 4.16 psi (20 °C)
278
5-Aminovaleric acid, 97% Danger H225-H319-H335-H351-EUH019-EUH066
P210-P261-P281-P305 + P351 + P338
Homopiperidinic acid; 5-Aminopentanoic acid
[660‑88‑8] Beil. 4,IV,2636 NH2(CH2)4CO2H FW 117.15
mp .............................................................................................................................................................. 158 to 161 °C
123188-5G glass btl 5g  2.0 M in ethanol
123188-25G glass btl 25 g bp .................................................................................................................................................................................... 60 °C
density ............................................................................................................................................. 0.785 g/mL, 25 °C
5-Aminovaleric acid hydrochloride, 99%
25
Danger H225-H315-H318 P210-P280-P305 + P351 + P338
5-Aminopentanoic acid
[627‑95‑2] Beil. 4,418 H2N(CH2)4CO2H · HCl FW 153.61 392685-100ML Sure/Seal™ 100 mL
mp .................................................................................................................................................................... 95 to 97 °C 392685-800ML Sure/Seal™ 800 mL
 2.0 M in isopropanol
bp ............................................................................ 50 °C vp .................................................... 6.34 psi (20 °C)
> 6-Aminoveratric acid, see 2-Amino-4,5-dimethoxybenzoic acid Page 116 density ..................................... 0.773 g/mL, 25 °C vp ................................................. 20.22 psi (55 °C)
4-Aminoveratrole, see 3,4-Dimethoxyaniline Page 1036
257
Danger H225-H315-H318-H336 P210-P261-P280-P305
Aminoxy-tert-butyldimethylsilane, see O-(tert-Butyldimethylsilyl)hydroxyl-
+ P351 + P338
amine Page 569
4-Amino-o-xylene, see 3,4-Dimethylaniline Page 1069 392693-100ML Sure/Seal™ 100 mL
5-Amino-m-xylene, see 3,5-Dimethylaniline Page 1069
4-Amino-2,5-xylenol, see 4-Amino-2,5-dimethylphenol Page 117 392693-800ML Sure/Seal™ 800 mL
Aminoxytrimethylsilane, see O-(Trimethylsilyl)hydroxylamine Page 2550
Ammediol, see 2-Amino-2-methyl-1,3-propanediol Page 144  2.0 M in methanol
density ............................................................................................................................................. 0.787 g/mL, 25 °C
Ammelide-13C3, 95% (CP) 8
2568
13
Danger H225-H301-H311-H314-H331-H370
2-Amino-1,3,5-triazine-4,6-dione- C3 NH2 P210-P260-P280-P301 + P310-P305 + P351 +
13
C3H4N4O2 FW 131.07 13C
P338-P310
N N 341428-100ML Sure/Seal™ 100 mL
13C 13C 341428-800ML Sure/Seal™ 800 mL
HO N OH 341428-2L glass btl 2L
mp ................................................................................................................................... 320 to 330 °C (Sublimes)  7 N in methanol

store at: 20-25°C water ............................................................................................................................................. ≤0.1% (Karl Fischer)
 99 atom % C 13 density ............................................................................................................................................. 0.779 g/mL, 25 °C
2568
mol wt 131.04, atom % calculation Danger H225-H301-H311-H314-H331-H370
P210-P260-P280-P301 + P310-P305 + P351 +
7
Warning H302-H319 P305 + P351 + P338
P338-P310
708984
Ammeline-13C3, 95% (CP) 8
 0.4 M in THF 8
4,6-Diamino-2-hydroxy-1,3,5-triazine-13C3 NH2 density ............................................................................................................................................. 0.881 g/mL, 25 °C
13
C3H5N5O FW 130.08 13C
N N 718939-100ML glass btl 100 mL
13C 13C
H2N N OH Ammonia-15N
15
[13767‑16‑3] NH3 FW 18.02
 99 atom % C 13 mp ....................................................................... −78 °C density ................................. 0.814 g/mL, 25 °C
bp ......................................................................... −33 °C vd ............................................................... 0.6 (vs air)
4569
Danger H221-H280-H314-H331-H400 P210-
7
Warning H302-H319 P305 + P351 + P338
P261-P273-P280-P305 + P351 + P338-P310
709263  98 atom % N 15

> Ammoidin, see 8-Methoxypsoralen Page 1720
299227-1L cylinder 1L
Ammonia, ≥99.99% 299227-10L cylinder 10 L
[7664‑41‑7] Merck 14,492; Fieser 5,15 NH3 FW 17.03  10 atom % 15
N
mp ....................................................................... −78 °C vp ................................................. 8.75 atm (21 °C)
bp ......................................................................... −33 °C ait ...................................................................... 1203 °F 487953 Full product information at Aldrich.com
vd ................................................................... 0.6 (vs air)

AHB A, 0613, UNP EU
n Ammonia n
Ammonia-d3  reagent grade, ≥98%

[13550‑49‑7] ND3 FW 20.05 store at: 2-8°C
mp ....................................................................... −78 °C vd ................................................................ 0.6 (vs air) A7262-500G poly btl 500 g
bp ......................................................................... −33 °C A7262-2.5KG poly btl 2.5 kg
 99 atom % D
mol wt 20.02, atom % calculation Ammonium-15N acetate
Stainless steel control valves Z146951, Z187224 or either of stainless
[86451‑35‑6] CH3CO215NH4 FW 78.08
A steel regulators Z148504 and Z148512 and a "T"-purge valve Z151661
is recommended.
mp ............................................................................................................................................... 110 to 112 °C (dec.)
vp ............................................................................................................................................... 4802 mmHg (15.5 °C)  98 atom % 15N

ait .................................................................................................................................................................................. 1203 °F mol wt 78.06, atom % calculation
4569 7
Danger H221-H314-H331-H400 P210-P261- Warning H315-H319-H335 P261-P305 + P351 + P338
P273-P280-P305 + P351 + P338-P310
422975-10L steel cyl 10 L 363006-1G glass btl 1g
Ammonium-15Nacetate-13C2
Ammonia-15N,d3 13
CH313CO215NH4 FW 80.06
15
[22364‑56‑3] ND3 FW 21.04  99 atom % 13
C; 98 atom % 15
N
mp ............................................................................................................................................................................... −76 °C
bp ................................................................................................................................................................................. −33 °C
 98 atom % N; 99 atom % D 15 Ammonium acetate-d3

mol wt 20.99, atom % calculation CD3CO2NH4 FW 80.10
Stainless steel control valves Z146951, Z187224 or either of stainless  98 atom % D
steel regulators Z148504 and Z148512 and a "T"-purge valve Z151661
is recommended.
485373-1L steel cyl 1L Ammonium-d4 acetate
> Ammonia water, see Ammonium hydroxide solution Page 179 ND4CO2CH3 FW 81.11
mp ............................................................................................................................................... 110 to 112 °C (dec.)
Ammonium solution
 98 atom % D
Ammonium chloride solution mol wt 81.03, atom % calculation
[12125‑02‑9] Merck 14,509 NH4Cl FW 53.49 613991-10G glass btl 10 g
density ............................................................................................................................................. 0.995 g/mL, 25 °C
Ammonium acetate-d7
 volumetric standard, in H2O
Visit our Titration Center to learn more. [194787‑05‑8] CD3CO2ND4 FW 84.13
mp ............................................................................................................................................... 110 to 112 °C (dec.)
318639-100ML poly btl 100 mL
318639-500ML poly btl 500 mL  98 atom % D
Ammonium acetate
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[631‑61‑8] Merck 14,495; Beil. 2,IV,121; Fieser 1,38; 7,11 CH3CO2NH4
FW 77.08 440485-1G glass btl 1g
solid 440485-5G glass btl 5g
mp ............................................................................................................................................... 110 to 112 °C (dec.)
> Ammonium alum, see Ammonium aluminum sulfate dodecahydrate
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Page 174
 99.999% trace metals basis Ammonium aluminum sulfate dodecahydrate

crystalline Ammonium alum; Aluminum ammonium sulfate dodecahydrate
372331-10G poly btl 10 g [7784‑26‑1] Merck 14,327 AlNH4(SO4)2 · 12H2O FW 453.33
372331-100G poly btl 100 g mp .............................................................................................................................................................................. 93.5 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Meets ACS reagent specifications.
insolubles ............................................................................................................................................................. ≤0.005%  99.999% trace metals basis
total metallic impurities ....................................................................................................................... <100 ppm crystals and lumps
pH range ...................................................... 6.7 - 7.3 sulfate (SO42-) ...................................... ≤0.001% 202568-25G poly btl 25 g
chloride (Cl-) ............................................. ≤5 ppm Fe ................................................................... ≤5 ppm
nitrate (NO3-) ........................................... ≤0.001% heavy metals ........................................ ≤5 ppm  ACS reagent, ≥98%
98.0-102.0% (ACS specification)
431311-50G poly btl 50 g
insolubles ............................................................................................................................................................. ≤0.005%
431311-250G poly btl 250 g chloride (Cl-) ............................................. ≤0.001% heavy metals (as Pb) ..................... ≤0.001%
Ca ........................................................................ ≤0.05% K ....................................................................... ≤0.05%
 ACS reagent, ≥97% Fe ..................................................................... ≤0.001% Na .................................................................... ≤0.01%
insolubles ............................................................................................................................................................. ≤0.005%
ign. residue .................................................. ≤0.01% sulfate (SO42-) ...................................... ≤0.001% 402818-250G poly btl 250 g
pH ............................................... 6.7-7.3, 5% (25 °C) Fe ................................................................... ≤5 ppm
chloride (Cl-) ............................................. ≤5 ppm heavy metals ........................................ ≤5 ppm  ReagentPlus®, ≥99% (titration)
nitrate (NO3-) ........................................... ≤0.001% A2140-500G poly btl 500 g
238074-25G poly btl 25 g A2140-1KG poly btl 1 kg
238074-500G poly btl 500 g
238074-2.5KG poly btl 2.5 kg

AHB A, 0613, UNP EU
n Ammoniumcarbona n
Ammonium benzoate, 98%  ACS reagent, ≥99.0%

Benzoic acid ammonium salt insolubles ............................................................................................................................................................. ≤0.005%
[1863‑63‑4] Merck 14,496; Beil. 9,IV,273 C6H5COONH4 FW 139.15 ign. residue .................................................. ≤0.01% sulfate (SO42-) ...................................... ≤0.005%
pH ............................................... 4.5-6.0, 5% (25 °C) Ba .................................................................. ≤0.002%
mp ............................................................................................................................................... 192 to 198 °C (dec.)
bromate (BrO3-) ..................................... ≤0.002% Fe .................................................................. ≤5 ppm
7 chloride (Cl-) .................................................. ≤0.2% heavy metals (as Pb) ...................... ≤5 ppm
iodide (I-) .................................................... ≤0.005%
183334-250G poly btl 250 g
213349-500G glass btl 500 g
183334-1KG
Ammonium biborate tetrahydrate, 98.9-101.2% B2O3 basis

poly btl 1 kg
213349-2.5KG glass btl 2.5 kg A
Ammonium-15N bromide
Ammonium tetraborate tetrahydrate 15
[39466‑31‑4] NH4Br FW 98.94
[12228‑87‑4] (NH4)2B4O7 · 4H2O FW 263.38
pH ..................................................................... ~8.8 solution (over a wide range of concentrations)  98 atom % 15
N
7
Warning H315-H319-H335 P261-P305 + P351 + P338 412651 Full product information at Aldrich.com
Ammonium-d4 bromide
[12265‑06‑4] ND4Br FW 101.97
Ammonium bicarbonate, ≥99.0%
 98 atom % D
Ammonium hydrogen carbonate
[1066‑33‑7] Merck 14,497 NH4HCO3 FW 79.06
vd ........................................................................................................................................................................... 2.7 (vs air) Ammonium carbamate, 99%
 ReagentPlus ® Carbamic acid ammonium salt
[1111‑78‑0] Merck 14,507; Beil. 3,IV,37 H2NCO2NH4 FW 78.07
7
Warning H302
vp .................................................................................................................................................. 100 mmHg (26.7 °C)
A6141-25G poly btl 25 g powder
7
A6141-500G poly btl 500 g Warning H302
Ammonium bisulfate, ≥98.0% (T) 292834-100G glass btl 100 g
Ammonium sulfate monobasic; Ammonium hydrogen sulfate 292834-500G glass btl 500 g
[7803‑63‑6] Merck 14,500 (NH4)HSO4 FW 115.11
Ammonium carbonate
 purum p.a.
chloride (Cl-) ...................................... ≤50 mg/kg K ........................................................... ≤500 mg/kg
Hartshorn salt
Ca .............................................................. ≤50 mg/kg Na ....................................................... ≤100 mg/kg [506‑87‑6] (NH4)2CO3 FW 96.09
Cd .............................................................. ≤50 mg/kg Ni ............................................................ ≤50 mg/kg vd ........................................................................................................................................................................... 2.7 (vs air)
Co .............................................................. ≤50 mg/kg Pb .......................................................... ≤50 mg/kg
7
Warning H302
Cu .............................................................. ≤50 mg/kg Zn .......................................................... ≤50 mg/kg
Fe ............................................................... ≤50 mg/kg
A mixture of ammonium bicarbonate and ammonium carbamate.
5 composition
Danger H314 P280-P305 + P351 + P338-P310
ammonia ≥30%
09848-1KG poly btl 1 kg May solidify on storage
Ammonium bromide
[12124‑97‑9] Merck 14,505; Fieser 6,473 NH4Br FW 97.94
mp ........................................................................ 452 °C vp .......................................... 1 mmHg (198.3 °C)
density ........................................ 2.43 g/mL, 25 °C
 mixture of variable proportions of ammonium bicarbonate and
7
Warning H319 P305 + P351 + P338 ammonium carbamate, 99.999% trace metals basis
379999-10G poly btl 10 g
 99.999% trace metals basis 379999-50G poly btl 50 g
powder
 ACS reagent, ≥30.0% NH3 basis
Mixture of variable proportions of ammonium bicarbonate and
380008-25G poly btl 25 g
ammonium carbamate
 ≥99.99% trace metals basis insolubles ............................................................................................................................................................. ≤0.005%
powder and chunks nonvolatiles ............................................................................................................................................................... ≤0.01
insolubles ............................................................................................................................................................. ≤0.005% chloride (Cl-) ............................................. ≤5 ppm Fe .................................................................. ≤5 ppm
sulfate (SO42-) .......................................... ≤0.002% heavy metals (as Pb) ...................... ≤5 ppm
total metallic impurities ....................................................................................................................... <100 ppm
ign. residue .................................................. ≤0.01% sulfate (SO42-) ...................................... ≤0.005%
207861-25G poly btl 25 g
pH range ...................................................... 4.5 - 6.0 Ba .................................................................. ≤0.002%
bromate (BrO3-) ..................................... ≤0.002% Fe ................................................................... ≤5 ppm
207861-500G poly btl 500 g
chloride (Cl-) ................................................... ≤0.2% heavy metals ........................................ ≤5 ppm 207861-2.5KG poly btl 2.5 kg
iodide (I-) ..................................................... ≤0.005%
 NF
467731-50G poly btl 50 g testing & handling conforms to Pharmacopeia
467731-250G poly btl 250 g 68392-1KG-F 1 kg
AHB A, 0613, UNP EU
n Ammoniumceriumn n
Ammonium cerium(IV) nitrate Ammonium cerium(IV) sulfate hydrate, ≥99.99% trace metals
basis
Ceric ammonium nitrate
[16774‑21‑3] Merck 14,1992; Fieser 3,44; 14,74; 16,66; 1,120; 2,63; 4,71; Ce(NH4)4(SO4)4 · xH2O FW 596.52 (Anh)
5,101; 13,67; 15,70; 6,99; 9,99 Ce(NH4)2(NO3)6 FW 548.22 chunks
granular
37
Danger P220-P261-P305 + P351 + P338
powder
7
Warning H315-H319-H335 P261-P305 + P351 + P338
 semiconductor grade PURANAL™ (Honeywell 17732)
A specification on request
H272-H315-H319-H335
483680-25G poly btl 25 g
40206-1KG 1 kg Ammonium chloride

40206-5KG 5 kg Salmiac
[12125‑02‑9] Merck 14,509 NH4Cl FW 53.49
mp ........................................................ 340 °C (subl.) vp ......................................... 1 mmHg (160.4 °C)
crystalline vd ................................................................... 1.9 (vs air)
H272-H315-H319-H335
7
Warning H302-H319 P305 + P351 + P338
229547-10G poly btl 10 g
229547-50G poly btl 50 g
 99.998% trace metals basis
229547-250G poly btl 250 g
powder
 ACS reagent, ≥98.5% 254134-5G poly btl 5g
insol. dil. H2SO4 .................................................................................................................................................. ≤0.05% 254134-25G poly btl 25 g
chloride (Cl-) ................................................ ≤0.01% Fe .................................................................. ≤0.005% 254134-100G poly btl 100 g
phosphate (PO43-) ................................... ≤0.02%
H272-H302-H315-H319-H335  99.99% trace metals basis
215473-50G poly btl 50 g
crystalline
215473-250G poly btl 250 g 326372-25G poly btl 25 g
215473-1KG 1 kg 326372-100G poly btl 100 g
326372-500G poly btl 500 g
 ≥98% (titration)
H272-H315-H319-H335  ACS reagent, ≥99.5%
C3654-250G glass btl 250 g insolubles ............................................................................................................................................................. ≤0.005%
ign. residue .................................................. ≤0.01% Ca ................................................................. ≤0.001%
Ammonium cerium(IV) nitrate on silica gel pH ............................................... 4.5-5.5, 5% (25 °C) Fe .................................................................. ≤2 ppm
phosphate (PO43-) ................................ ≤2 ppm heavy metals (as Pb) ...................... ≤5 ppm
Ce(NH4)2(NO3)6 · (SiO2)x sulfate (SO42-) .......................................... ≤0.002% Mg ................................................................ ≤5 ppm
213330-25G poly btl 25 g
Ammonium cerium(IV) sulfate dihydrate 213330-500G poly btl 500 g
Ceric ammonium sulfate; Cerium(IV) ammonium sulfate 213330-1KG 1 kg
[10378‑47‑9] Fieser 7,56; 8,80; 12,107 Ce(NH4)4(SO4)4 · 2H2O 213330-2.5KG poly btl 2.5 kg
FW 632.55
mp ................................................................................................................................................................................ 130 °C  ReagentPlus®, ≥99.5%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
 ACS reagent, ≥94%
insol. dil. H2SO4 .................................................................................................................................................. ≤0.05% > Ammonium chloride solution, see Ammonium solution Page 174
phosphate (PO43-) ........................................................................................................................................... ≤0.03%
Fe ................................................................................................................................................................................ ≤0.01% Ammonium-15N chloride
15
383090-100G poly btl 100 g [39466‑62‑1] NH4Cl FW 54.48
383090-500G poly btl 500 g mp ............................................................................................................................................................... 340 °C (subl.)
 ≥99%  98 atom % 15N

heavy metals (as Pb) ................................................................................................................................... ≤0.005% mol wt 54.47, atom % calculation
7
insoluble in acid ............................................................................................................................................. ≤0.005% Warning H302-H319 P305 + P351 + P338
chloride (Cl-) ...................................... ≤10 mg/kg Fe ........................................................... ≤50 mg/kg
phosphate (PO43-) ......................... ≤50 mg/kg 299251-250MG glass btl 250 mg
31173-100G-R 100 g
299251-10G 10 g
31173-50KG-R 50 kg
powder 299251-50G 50 g
composition
Ce(IV) ≥22% Ammonium-d4 chloride
221759-100G poly btl 100 g [12015‑14‑4] ND4Cl FW 57.52
221759-500G poly btl 500 g mp ............................................................................................................................................................... 340 °C (subl.)
vp ..................................................................................................................................................... 1 mmHg (160.4 °C)
 98 atom % D
7
Warning H302-H319 P305 + P351 + P338


AHB A, 0613, UNP EU
n Ammoniumfluorid n
Ammonium-15N,d4 chloride Ammonium cobalt(II) sulfate hexahydrate, 99%

15
[99011‑95‑7] ND4Cl FW 58.51 [13586‑38‑4] (NH4)2Co(SO4)2 · 6H2O FW 395.23
mp ................................................................................................................................................................ 340 °C (subl.) mp ................................................................................................................................................................ 120 °C (dec.)
density ............................................................................................................................................. 1.902 g/mL, 25 °C
 98 atom % 15N; 99 atom % D
crystals and lumps
7
7
Warning H302-H319 P305 + P351 + P338
+ P338
A
Ammonium-d4 deuteroxide solution
Ammonium chloride-ammonium hydroxide buffer solution
[12168‑30‑8] ND4OD/D2O soln. FW 56.08
NH4Cl / NH4OH
 25 wt. % in D2O, 99 atom % D
 in H2O density ............................................................................................................................................. 1.056 g/mL, 25 °C
composition n20
D ...................................................................................................................................................................................... 1.334
NH4Cl 1 wt. % 176702-5G glass btl 5g
NH4OH 4 wt. % (pH 10 to 11) 176702-50G glass btl 50 g
density ................................................................................................................................................ 0.99 g/mL, 25 °C
176702-100G glass btl 100 g
pH ..................................................................................................................................................................................... 10-11
Ammonium dichromate
59
Danger H315-H318-H400 P273-P280-P305 + P351 + P338
Ammonium bichromate
318604-500ML poly btl 500 mL [7789‑09‑5] Merck 14,515 (NH4)2Cr2O7 FW 252.06
318604-2L poly btl 2L mp ................................................................................................................................................................ 170 °C (dec.)
vd ........................................................................................................................................................................... 8.7 (vs air)
Ammonium chromate, 98%
[7788‑98‑9] Merck 14,510 (NH4)2CrO4 FW 152.07  99.999% trace metals basis
density ................................................................................................................................................ 1.91 g/mL, 25 °C
crystalline
needles 450138-25G poly btl 25 g
3589
Danger H272-H314-H334-H350i-H400 P201-
P220-P261-P273-P280-P305 + P351 + P338
insolubles ............................................................................................................................................................. ≤0.005%
216038-100G poly btl 100 g LOD ........................................................................ ≤3.0% Ca ................................................................. ≤0.002%
216038-500G poly btl 500 g chloride (Cl-) ............................................. ≤0.005% Fe .................................................................. ≤0.002%
sulfate (SO42-) ............................................. ≤0.01% Na ................................................................. ≤0.005%
Ammonium citrate dibasic, 98%
35689
Danger H272-H301-H312-H314-H317-
Citric acid ammonium salt; Diammonium hydrogen citrate; H330-H334-H340-H350-H360-H372-H410
Ammonium hydrogencitrate P201-P220-P260-P273-P280-P284
[3012‑65‑5] Merck 14,512; Beil. 3,H,553 HOC(CO2H)(CH2CO2NH4)2 402826-100G poly btl 100 g
FW 226.18 402826-500G poly btl 500 g
vd ........................................................................................................................................................................... 1.8 (vs air)
Ammonium diethyldithiocarbamate
 ACS reagent
98.0-103.0% (ACS specification) Diethyldithiocarbamic acid ammonium salt
insolubles ............................................................................................................................................................. ≤0.005%
[21124‑33‑4] Beil. 4,III,224 (C2H5)2NC(S)SSNH4 FW 166.31
oxalate ............................................................................................................................ passes test (lim ~0.05%) mp ................................................................................................................................................................... 80 °C (dec.)
ign. residue .................................................. ≤0.01% sulfate (SO42-) ...................................... ≤0.005%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
chloride (Cl-) ............................................. ≤0.001% Fe .................................................................. ≤0.001%
phosphate (PO43-) ................................ ≤5 ppm heavy metals (as Pb) ...................... ≤5 ppm
7
Warning H319-H335 P261-P305 + P351 + P338
Ammonium dihydrogenphosphate, 99.999% trace metals basis
247561-100G poly btl 100 g prim-Ammonium phosphate; Ammonium dihydrogenphosphate;
247561-500G poly btl 500 g mono-Ammonium phosphate; Ammonium phosphate monobasic
247561-2.5KG poly btl 2.5 kg [7722‑76‑1] Merck 14,543 NH4H2PO4 FW 115.03
mp ................................................................................................................................................................ 190 °C (dec.)
Ammonium citrate tribasic, ≥97% (titration) crystalline
Citric acid triammonium salt 204005-25G poly btl 25 g
[3458‑72‑8] Beil. 3,I,190 HOC(CO2NH4)(CH2CO2NH4)2 FW 243.22 204005-100G poly btl 100 g
mp ......................................................... 185 °C (dec.) density ........................................... 1 g/mL, 25 °C
204005-500G poly btl 500 g
bp ......................................................................... 100 °C
> Ammonium dodecyl sulfate, see Ammonium lauryl sulfate solution
 anhydrous Page 181
Ammonium ferric oxalate, see Ammonium iron(III) oxalate trihydrate
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Page 181
A1332-100G poly btl 100 g Ammonium fluoride

A1332-500G poly btl 500 g [12125‑01‑8] Merck 14,522 NH4F FW 37.04
6
Danger H301-H311-H331 P261-P280-P301 + P310-P311

crystals and lumps
338869-25G poly btl 25 g
338869-100G poly btl 100 g

AHB A, 0613, UNP EU
n Ammoniumfluorid n
Ammonium fluoride (continued) Ammonium heptafluorotantalate(V), 99.99% trace metals basis
[12022‑02‑5] (NH4)2TaF7 FW 350.01
crystalline
insolubles ............................................................................................................................................................. ≤0.005%
57
Danger H302-H312-H314-H332 P280-P305 + P351 + P338-
ign. residue .................................................. ≤0.01% Fe ................................................................... ≤5 ppm
P310
chloride (Cl-) ............................................. ≤0.001% heavy metals (as Pb) ...................... ≤5 ppm
sulfate (SO42-) .......................................... ≤0.005% 332526-5G poly btl 5g
216011-100G poly btl 100 g Ammonium hexachloroiridate(III) monohydrate, 99.99% trace

A 216011-500G
216011-6X500G
poly btl
6 × 500 g
500 g
metals basis
Iridium(III)-ammonium chloride
[29796‑57‑4] (NH4)3IrCl6 · H2O FW 477.07
Ammonium fluoride solution
7
Warning H315-H319 P305 + P351 + P338
[12125‑01‑8] Merck 14,522 NH4F FW 37.04
 0.5 M in methanol 229431-1G glass btl 1g
bp ................................................................................................................................................................................ 64.6 °C
Ammonium hexachloroiridate(IV)
density ............................................................................................................................................. 0.802 g/mL, 25 °C
Iridium(IV)-ammonium chloride
[16940‑92‑4] (NH4)2IrCl6 FW 441.01
powder
 semiconductor grade VLSI PURANAL™ (Honeywell 17600) density ................................................................................................................................................ 2.86 g/mL, 25 °C
7
specification on request Warning H302-H312-H332 P280
6
40292-5L 5L 203475-1G glass btl 1g
 semiconductor grade PURANAL™ (Honeywell 17767)  98%

specification on request
6
Ammonium hexachloroosmate(IV)
40208-5L 5L Osmium(IV)-ammonium chloride
Ammonium fluoride – hydrofluoric acid mixture [12125‑08‑5] Merck 14,536 (NH4)2OsCl6 FW 439.02
powder
[70456‑74‑5] NH4F · HF
mp ............................................................................................................................................................... 170 °C (subl.)
 AF 875-125, etching mixture, semiconductor grade PURANAL™ density ................................................................................................................................................ 2.93 g/mL, 25 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
56
Danger H301-H310-H314-H330 P260-P280-P284-P301 +
P310-P302 + P350-P305 + P351 + P338
40207-2.5L 2.5 L
Ammonium formate
 reagent grade
Formic acid ammonium salt
209074-2.5G glass btl 2.5 g
[540‑69‑2] Merck 14,523; Beil. 2,IV,18; Fieser 1,38 HCO2NH4
FW 63.06 Ammonium hexachloropalladate(IV), 99.99% trace metals basis
mp .............................................................................................................................................................. 119 to 121 °C Palladium(IV)-ammonium chloride
density ................................................................................................................................................ 1.26 g/mL, 25 °C [19168‑23‑1] (NH4)2PdCl6 FW 355.21
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H302-H315-H319 P305 + P351 + P338
 ≥99.995% trace metals basis 323535-1G glass btl 1g

Phenolic benzyl protecting groups are quickly removed by
ammonium formate and microencapsulated palladium(0) under Ammonium hexachloroplatinate(IV), 99.999% trace metals
basis
microwave irradiation.1
crystalline Platinum(IV)-ammonium chloride
Lit. cited: 1. Tetrahedron Lett. 48, 1241 (2007) [16919‑58‑7] Merck 14,548; Fieser 1,890 (NH4)2PtCl6 FW 443.87
516961-100G poly btl 100 g Features and Benefits
Reacts with Cu(OAc)2 and H2S to form Cu2PtIIPt3IVS8 which has
 reagent grade, 97% applications in diamagnetic materials and semiconductors.1,2
156264-100G poly btl 100 g density ................................................................................................................................................ 3.07 g/mL, 25 °C
156264-500G poly btl 500 g Lit. cited: 1. Gross, P.J.; Jansen, M., Z. Anorg. Allg. Chem. 620, 1909 (1994)
156264-1KG poly btl 1 kg 2. Gross, P.J., Jansen, M., Z. Anorg. Allg. Chem. 619, 1431 (1993)
568
Danger H301-H317-H318-H334 P261-P280-P301 +
Ammonium formate solution 8 P310-P305 + P351 + P338-P342 + P311
[540‑69‑2] Merck 14,523 HCOONH4 FW 63.06 204021-1G glass btl 1g
 10 mM in H2O, CHROMASOLV®, for HPLC

density ............................................................................................................................................. 0.998 g/mL, 25 °C

AHB A, 0613, UNP EU
n Ammoniumhydroxi n
Ammonium hexachlororhodate(III) Ammonium hexafluorotitanate, 99.99% trace metals basis

Rhodium(III)-ammonium chloride [16962‑40‑6] (NH4)2TiF6 FW 197.93
[15336‑18‑2] (NH4)3RhCl6 FW 369.74
7
 reagent grade
powder 204749-10G poly btl 10 g
204749-50G poly btl 50 g
204749-250G poly btl 250 g
A
Ammonium hexachlororuthenate(IV)
> Ammonium hydrogencitrate, see Ammonium citrate dibasic Page 177
Ruthenium(IV)-ammonium chloride
[18746‑63‑9] (NH4)2RuCl6 FW 349.86 Ammonium hydrogen difluoride
powder Etching powder; Ammonium bifluoride
6
Danger H301-H311-H331 P261-P280-P301 + P310-P311 [1341‑49‑7] Merck 14,498 NH4HF2 FW 57.04
mp ............................................................................................................................................................................... 125 °C
56
Danger H301-H314 P280-P301 + P310-P305 + P351 + P338-
Ammonium hexafluorogermanate(IV), 99.99% trace metals P310
basis  99.999% trace metals basis
[16962‑47‑3] (NH4)2GeF6 FW 222.71 crystalline
203378 Full product information at Aldrich.com 455830-25G poly btl 25 g
455830-100G poly btl 100 g
Ammonium hexafluorophosphate
[16941‑11‑0] Merck 14,526 NH4PF6 FW 163.00  reagent grade, 95%
density ................................................................................................................................................ 2.18 g/mL, 25 °C 224820-25G poly btl 25 g
224820-500G poly btl 500 g
5
Danger H314 P280-P305 + P351 + P338-P310
224820-2.5KG poly btl 2.5 kg
 99.99% trace metals basis Ammonium hydrogenoxalate hydrate, 99.999% trace metals
crystalline basis
216593-5G poly btl 5g (NH4)HC2O4 · xH2O FW 107.07 (Anh)
216593-25G poly btl 25 g mp ................................................................................................................................................................ 210 °C (dec.)
216593-100G poly btl 100 g 573876-25G poly btl 25 g
 ≥98.0% (gravimetric, as NH4PF6) > Ammonium hydrogen sulfate, see Ammonium bisulfate Page 175
09820-25G poly btl 25 g
Ammonium hydrogensulfate, 99.99% trace metals basis
09820-100G poly btl 100 g Ammonium sulfate monobasic
[7803‑63‑6] Merck 14,500 (NH4)HSO4 FW 115.11
 ≥95% mp ...................................................... 121 to 145 °C density .................................... 1.79 g/mL, 25 °C
201138-25G poly btl 25 g bp .......................................................... 350 °C (dec.)
201138-100G poly btl 100 g crystalline
5
201138-500G poly btl 500 g Danger H314 P280-P305 + P351 + P338-P310
Ammonium hexafluorosilicate
455849-25G poly btl 25 g
[16919‑19‑0] Merck 14,527 (NH4)2SiF6 FW 178.15
455849-100G poly btl 100 g
density ................................................................................................................................................ 2.01 g/mL, 25 °C
6
Danger H301-H311-H331 P261-P280-P301 + P310-P311
Losing Time Calculating

204331-10G poly btl 10 g Concentrations by Hand?
204331-50G poly btl 50 g Add Aldrich’s Normality and
204331-250G poly btl 250 g Molarity Calculator.
 98% Aldrich.com/calculator
372579-500G poly btl 500 g
Ammonium hexafluorostannate, 99.999% trace metals basis

Ammonium hydroxide solution
[16919‑24‑7] (NH4)2SnF6 FW 266.76
crystalline Ammonia aqueous; Ammonia water
[1336‑21‑6] Merck 14,494; Fieser 5,15 NH4OH FW 35.05
7
Warning H315-H319-H335 P261-P305 + P351 + P338
density ................................................................................................................................................... 0.9 g/mL, 25 °C
457183-5G poly btl 5g  28% in H2O, ≥99.99% trace metals basis

457183-25G poly btl 25 g density ................................................................................................................................................... 0.9 g/mL, 25 °C
579
Danger H314-H335-H400 P261-P273-P280-P305 +
P351 + P338-P310
AHB A, 0613, UNP EU
n Ammoniumhydroxi n
Ammonium hydroxide (continued)
 ≥25% in H2O, TraceSELECT®, for trace analysis
concentration .................................................................................................................... ≥25% NH3 in H2O (T)
 ACS reagent, 28.0-30.0% NH3 basis density ........................................ 0.91 g/mL, 20 °C Cu ................................................... ≤0.001 mg/kg
CO2 ............................................................................................................................................................................ ≤0.002% bromide (Br-) ................................. ≤0.05 mg/kg Fe .................................................... ≤0.002 mg/kg
MnO4- reducers ........................................................................................................................................ passes test carbonate (CO2) .............................. ≤10 mg/kg Ga ................................................... ≤0.001 mg/kg
ign. residue ............................................... ≤0.002% phosphate (PO43-) ............................. ≤2 ppm chloride (Cl-) ..................................... ≤0.5 mg/kg Hg ................................................... ≤0.001 mg/kg
vd ................................................................... 1.2 (vs air) sulfate (SO42-) ....................................... ≤2 ppm fluoride (F-) ........................................ ≤0.1 mg/kg In ..................................................... ≤0.001 mg/kg
vp .............................................. 115 mmHg (20 °C) Fe ............................................................... ≤0.2 ppm iodide (I-) .......................................... ≤0.05 mg/kg K ....................................................... ≤0.005 mg/kg
chloride (Cl-) ....................................... ≤0.05 ppm heavy metals (as Pb) .................. ≤0.5 ppm nitrate (NO3-) ................................... ≤0.5 mg/kg Li ...................................................... ≤0.001 mg/kg
A nitrate (NO3-) ............................................ ≤2 ppm nitrite (NO2-) ..................................... ≤0.1 mg/kg Mg .................................................. ≤0.001 mg/kg
phosphate (PO43-) ..................... ≤0.05 mg/kg Mn .................................................. ≤0.001 mg/kg
59
Danger H314-H400 P273-P280-P305 + P351 + P338-P310
sulfate (SO42-) .................................. ≤0.1 mg/kg Mo .................................................. ≤0.001 mg/kg
Ag ....................................................... ≤0.001 mg/kg Na ...................................................... ≤0.01 mg/kg
320145-500ML PVC coated 500 mL Al ......................................................... ≤0.005 mg/kg Ni ..................................................... ≤0.001 mg/kg
320145-1L 1L As ........................................................ ≤0.001 mg/kg Pb .................................................... ≤0.001 mg/kg
320145-2.5L PVC coated 2.5 L Au ....................................................... ≤0.001 mg/kg Pt ..................................................... ≤0.001 mg/kg
Ba ........................................................ ≤0.001 mg/kg Rb .................................................... ≤0.001 mg/kg
 ACS reagent, 28.0-30.0% NH3 basis Be ........................................................ ≤0.001 mg/kg Sn .................................................... ≤0.001 mg/kg
ACS specifications same for product 320145 Bi ......................................................... ≤0.001 mg/kg Sr ..................................................... ≤0.001 mg/kg
Ca .......................................................... ≤0.01 mg/kg Ti ...................................................... ≤0.001 mg/kg
579
Danger H302-H314-H400 P273-P280-P305 + P351 +
Cd ....................................................... ≤0.001 mg/kg Tl ...................................................... ≤0.001 mg/kg
P338-P310
Co ....................................................... ≤0.001 mg/kg V ....................................................... ≤0.001 mg/kg
221228-25ML-A glass btl 25 mL Cr ........................................................ ≤0.001 mg/kg Zn ................................................... ≤0.001 mg/kg
221228-100ML-A glass btl 100 mL Cs ........................................................ ≤0.001 mg/kg Zr ..................................................... ≤0.001 mg/kg
221228-12X100ML-A glass btl 12 × 100 mL
59
Danger H314-H400 P273-P280-P305 + P351 + P338-P310
221228-500ML-A poly btl 500 mL store at: 2-8°C
221228-6X500ML-A poly btl 6 × 500 mL 09857-100ML poly btl 100 mL
221228-1L-A glass btl 1L 09857-500ML poly btl 500 mL
221228-2L-A glass btl 2L
 ≥25% NH3 in H2O, semiconductor grade PURANAL™ (Honeywell
221228-6X2.5L-A poly btl 6 × 2.5 L
17814)
221228-385LB-A 385 lb
 ≥25% NH3 in H2O (T), TraceSELECT® Ultra, for trace analysis 40205-5L 5L
density ........................................ 0.91 g/mL, 20 °C K .................................................................. ≤1 μg/kg
bromide (Br-) ................................. ≤0.05 mg/kg La ......................................................... ≤0.01 μg/kg  ≥25% NH3 in H2O, semiconductor grade VLSI PURANAL™
carbonate (CO2) .............................. ≤10 mg/kg Li ........................................................... ≤0.01 μg/kg (Honeywell 17605)
chloride (Cl-) ..................................... ≤0.5 mg/kg Lu ......................................................... ≤0.01 μg/kg specification on request
fluoride (F-) ........................................ ≤0.1 mg/kg Mg .......................................................... ≤0.1 μg/kg
579
Danger H314-H335-H400 P261-P273-P280-P305 +
iodide (I-) .......................................... ≤0.05 mg/kg Mn .......................................................... ≤0.1 μg/kg
P351 + P338-P310
nitrate (NO3-) .................................... ≤0.5 mg/kg Mo ....................................................... ≤0.05 μg/kg
nitrite (NO2-) ..................................... ≤0.1 mg/kg Na ............................................................... ≤1 μg/kg 40291-2.5L 2.5 L
phosphate (PO43-) ..................... ≤0.05 mg/kg Nd ....................................................... ≤0.01 μg/kg
sulfate (SO42-) .................................. ≤0.1 mg/kg Ni ............................................................ ≤0.1 μg/kg  ≥25% NH3 in H2O, semiconductor grade SLSI PURANAL™
Ag ............................................................ ≤0.01 μg/kg Pb ........................................................ ≤0.02 μg/kg (Honeywell 17301)
Al ................................................................ ≤0.2 μg/kg Pd ........................................................ ≤0.01 μg/kg specification on request
As ............................................................... ≤0.5 μg/kg Pr .......................................................... ≤0.01 μg/kg 40321-5L 5L
Au ............................................................ ≤0.01 μg/kg Pt .......................................................... ≤0.01 μg/kg
Ba ............................................................. ≤0.01 μg/kg Rb ........................................................ ≤0.01 μg/kg  5.0 N in H2O
Be ............................................................ ≤0.01 μg/kg Re ......................................................... ≤0.01 μg/kg Visit our Titration Center to learn more.
Bi .............................................................. ≤0.01 μg/kg Rh ........................................................ ≤0.01 μg/kg
concentration ....................................................................... 4.90-5.10 N (Exact value stated on label)
Ca ................................................................... ≤1 μg/kg Ru ........................................................ ≤0.01 μg/kg
density ............................................................................................................................................. 0.965 g/mL, 25 °C
Cd ............................................................ ≤0.01 μg/kg Sb ........................................................... ≤0.1 μg/kg
579
Ce ............................................................ ≤0.01 μg/kg Sm ....................................................... ≤0.01 μg/kg Danger H314-H335-H400 P261-P273-P280-P305 +
Co ............................................................ ≤0.01 μg/kg Sn ........................................................... ≤0.1 μg/kg P351 + P338-P310
Cr ............................................................. ≤0.05 μg/kg Sr .......................................................... ≤0.01 μg/kg 318612-500ML poly btl 500 mL
Cs ............................................................. ≤0.01 μg/kg Tb ......................................................... ≤0.01 μg/kg 318612-2L poly btl 2L
Cu ............................................................... ≤0.5 μg/kg Te ......................................................... ≤0.01 μg/kg
Dy ............................................................ ≤0.01 μg/kg Th ......................................................... ≤0.01 μg/kg  0.1 N in H2O
Er .............................................................. ≤0.01 μg/kg Ti ........................................................... ≤0.05 μg/kg Visit our Titration Center to learn more.
Eu ............................................................ ≤0.01 μg/kg Tl ........................................................... ≤0.01 μg/kg
concentration ................................................................. 0.095-0.105 N (Exact value stated on label)
Fe ................................................................ ≤0.5 μg/kg Tm ....................................................... ≤0.01 μg/kg
density ............................................................................................................................................. 0.995 g/mL, 25 °C
Ga ............................................................ ≤0.01 μg/kg U ........................................................... ≤0.01 μg/kg
Gd ........................................................... ≤0.01 μg/kg V ............................................................ ≤0.05 μg/kg 318620-500ML poly btl 500 mL
Ge ............................................................ ≤0.05 μg/kg W .......................................................... ≤0.01 μg/kg 318620-2L poly btl 2L
Hf ............................................................. ≤0.01 μg/kg Y ............................................................ ≤0.01 μg/kg
Hg .............................................................. ≤0.5 μg/kg Yb ........................................................ ≤0.01 μg/kg Ammonium-15N hydroxide solution
Ho ........................................................... ≤0.01 μg/kg Zn ........................................................... ≤0.5 μg/kg 15
[62948‑80‑5] NH4OH/H2O soln. FW 36.04
In .............................................................. ≤0.01 μg/kg Zr .......................................................... ≤0.01 μg/kg
Ir ............................................................... ≤0.01 μg/kg  ~14 N in H2O, 98 atom % 15N
59
Danger H314-H400 P273-P280-P305 + P351 + P338-P310
store at: 2-8°C 609390-5G glass btl 5g
16748-250ML-F PFA/FEP btl 250 mL
16748-1L-F PFA/FEP btl 1L

AHB A, 0613, UNP EU
n Ammoniummagnesi n
Ammonium hypophosphite, ≥97.0%  ACS reagent, 99%

Ammonium phosphinate 98.5-101.5%
[7803‑65‑8] Merck 14,528 NH4H2PO2 FW 83.03 insolubles ................................................................................................................................................................ ≤0.01%
Not NH4OH pptd. ............................................................................................................................................. ≤0.05%
heavy metals (as Pb) ................................................................................................................................... ≤0.001%
phosphate (PO43-) ................................ ≤0.003% Mg ................................................................... 0.002%
chloride (Cl-) ................................... ≤100 mg/kg As .............................................................. ≤5 mg/kg
Ca ......................................................................... 0.005% Mn .................................................................. ≤0.01%
phosphite (H3PO3) ......................................... ≤1% Ca ........................................................ ≤500 mg/kg
Cu ..................................................................... ≤0.003% Na ....................................................................... 0.02%
sulfate (SO42-) ................................. ≤100 mg/kg Fe ........................................................... ≤10 mg/kg
Fe3+ .................................................................... ≤0.01% Zn ................................................................. ≤0.003%
7 A
Warning H315-H319-H335 P261-P305 + P351 + P338 K ............................................................................ 0.002%
04401-1KG 1 kg 215406-100G glass btl 100 g

04401-6X1KG 6 × 1 kg 215406-500G glass btl 500 g
04401-25KG-H 25 kg  ReagentPlus®, ≥98%
Ammonium iodide F3754-500G poly btl 500 g
[12027‑06‑4] Merck 14,529 NH4I FW 144.94 F3754-1KG poly btl 1 kg
vp ..................................................................................................................................................... 1 mmHg (210.9 °C) F3754-5KG poly drum 5 kg
7
Warning H315-H319-H335 P261-P305 + P351 + P338 Ammonium iron(III) sulfate dodecahydrate
Ammonium ferric sulfate dodecahydrate
 99.999% trace metals basis [7783‑83‑7] Merck 14,518 NH4Fe(SO4)2 · 12H2O FW 482.19
crystalline mp ................................................................................................................................................................... 39 to 41 °C
203467-10G amber poly 10 g
7
Warning H315-H319 P305 + P351 + P338
203467-50G amber poly 50 g
 ACS reagent, ≥99%  ACS reagent, 99%

insolubles ............................................................................................................................................................. ≤0.005% 98.5-102.0% (ACS specification)
ign. residue .................................................. ≤0.05% Ba .................................................................. ≤0.002% insolubles ................................................................................................................................................................ ≤0.01%
Cl- and Br- .................................................. ≤0.005% Fe ................................................................... ≤5 ppm not NH4OH pptd. ............................................................................................................................................. ≤0.05%
phosphate (PO43-) ................................ ≤0.001% heavy metals (as Pb) ...................... ≤0.001% chloride (Cl-) ............................................. ≤0.001% Fe2+ ..... passes test (limit about 0.001%)
sulfate (SO42-) ............................................. ≤0.05% nitrate (NO3-) .............................................. ≤0.01% Zn ................................................................. ≤0.003%
Cu ..................................................................... ≤0.003%
221937-100G glass btl 100 g
221260-500G glass btl 500 g
Ammonium iron(III) citrate 221260-2.5KG glass btl 2.5 kg
Ferric ammonium citrate; Ammonium ferric citrate
[1185‑57‑5] Merck 14,4017; Beil. 3,III,1103 C6H8O7 ·xFe3+ · yNH3  ≥99%
store at: 2-8°C
 reagent grade, powder F3629-250G poly btl 250 g
composition
F3629-500G poly btl 500 g
Iron 16.5‑18.5%
7
Warning H315-H319-H335 P261-P305 + P351 + P338 Ammonium lactate solution
[515‑98‑0] Merck 14,530; Beil. 3,I,107 CH3CH(OH)CO2NH4
F5879-100G poly btl 100 g FW 107.11
F5879-500G poly btl 500 g
 technical grade, 20 wt. % in H2O
Ammonium iron(III) oxalate trihydrate, ≥98% lactic acid lactate, ammonium salt ........................................................................................................... 2-3%
density ............................................................................................................................................. 1.054 g/mL, 25 °C
Iron ammonium oxalate; Ammonium ferric oxalate
n20
D ...................................................................................................................................................................................... 1.363
[13268‑42‑3] (NH4)3[Fe(C2O4)3] · 3H2O FW 428.06
density ................................................................................................................................................ 1.78 g/mL, 25 °C 377228-100ML glass btl 100 mL
chloride (Cl-) .............................................................................................................................................. ≤50 mg/kg Ammonium lauryl sulfate solution
sulfate (SO42-) ...................................................................................................................................... ≤1000 mg/kg
Ammonium dodecyl sulfate; Dodecyl sulfate ammonium salt
7
[2235‑54‑3] CH3(CH2)11OSO3NH4 FW 283.43
79
Warning H315-H319-H411 P273-P305 + P351 + P338
Ammonium iron(II) sulfate hexahydrate  ~30% in H2O (T)

Ammonium iron(II) sulfate; Mohr’s salt; Ammonium ferrous sulfate anionic
hexahydrate density ................................................................................................................................................ 1.02 g/mL, 20 °C
[7783‑85‑9] Merck 14,521 (NH4)2Fe(SO4)2 · 6H2O FW 392.14 n20
D ......................................................................................................................................................................................... 1.37
mp ................................................................................................................................................................. 100 °C (dec.) 09887-250ML 250 mL
7
Warning H315-H319-H335 P261-P305 + P351 + P338 09887-1L 1L
 ~30% in H2O
density ................................................................................................................................................ 1.02 g/mL, 25 °C
crystalline n20
D ...................................................................................................................................................................................... 1.374
203505-25G poly btl 25 g
203505-100G poly btl 100 g Ammonium magnesium phosphate hydrate, 99.999% trace
metals basis
Phosphoric acid ammonium magnesium salt hydrate
(NH4)MgPO4 · xH2O FW 137.31 (Anh)

AHB A, 0613, UNP EU
n Ammoniummetatun n
Ammonium metatungstate hydrate Features and Benefits

[12333‑11‑8] (NH4)6H2W12O40 · xH2O FW 2956.30 (Anh) Meets A.C.S. reagent specificatons.
mp ................................................................................................................................................................. 100 °C (dec.) insolubles ............................................................................................................................................................. ≤0.005%
nitrate (NO3-) ...................................... passes test Mg and allied cations ...................... ≤0.01%
57
Danger H302-H318 P280-P305 + P351 + P338
heavy metals ........................................... ≤0.001%
 ≥85% WO3 basis (gravimetric)
431346-50G poly btl 50 g
water-insoluble matter ............................................................................................................................... ≤0.005%
A LOI .................................................................................................................................................................................... ≤15% 431346-250G poly btl 250 g
10035-100G poly btl 100 g  ACS reagent, 81.0-83.0% MoO3 basis

10035-500G poly btl 500 g Insoluble matter ............................................................................................................................................. ≤0.005%
arsenate, phosphate, and silicate (as heavy metals (as Pb) ..................... ≤0.001%
 99.99% trace metals basis SiO2) ........................................................... ≤0.001% Mg and allied cations ...................... ≤0.02%
powder -
nitrate (NO3 ) ........ passes test (limit about
0.003%)
463922-25G poly btl 25 g
store at: room temp
 ≥66.5% (W)
crystalline
358975-100G glass btl 100 g
A7302-6X500G 6 × 500 g
Ammonium metavanadate A7302-1KG poly btl 1 kg
[7803‑55‑6] Merck 14,568; Fieser 1,1057 NH4VO3 FW 116.98 A7302-2.5KG poly drum 2.5 kg
density .............................................................................................................................................. 2.32 g/cm3, 25 °C Ammonium nickel(II) sulfate hexahydrate
6
Danger H301-H315-H319-H330-H335 P260-P284-P301 + P310-P305 + Nickel ammonium sulfate
P351 + P338-P310
[7785‑20‑8] Merck 14,6501 (NH4)2Ni(SO4)2 · 6H2O FW 394.99
 99.999% mp ................................................................................................................................................................... 85 to 89 °C
powder
789
Danger H302-H317-H332-H334-H341-H350i-H360-
573884-5G glass btl 5g H372-H410 P201-P261-P273-P280-P308 + P313-P501
 99.99% trace metals basis  99.999% trace metals basis

crystalline crystals and lumps
 ACS reagent, ≥99.0%  ≥98%

solubility in NH4OH ................................................................................................................................ passes test A1827-100G glass btl 100 g
carbonate (CO32-) ........................... passes test sulfate (SO42-) ......................................... ≤0.05% A1827-500G glass btl 500 g
chloride (Cl-) ................................................... ≤0.2%
Ammonium niobate(V) oxalate hydrate, 99.99% trace metals
398128-50G poly btl 50 g basis
398128-250G poly btl 250 g C4H4NNbO9 · xH2O FW 302.98 (Anh)
mp ................................................................................................................................................................ 122 °C (dec.)
 99%
powder
205559-250G poly btl 250 g
525839-250G glass btl 250 g
Ammonium molybdate, 99.98% trace metals basis
Ammonium nitrate
[13106‑76‑8] (NH4)2MoO4 FW 196.01
[6484‑52‑2] Merck 14,534; Fieser 1,39 NH4NO3 FW 80.04
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp ............................................................................................................................................................................... 169 °C
bp ................................................................................................................................................................................. 210 °C
37
277908-20G poly btl 20 g P338
277908-100G poly btl 100 g
 ≥99.0%
Ammonium molybdate tetrahydrate A9642-500G poly btl 500 g
Molybdic acid ammonium salt tetrahydrate; Ammonium hepta- A9642-2.5KG poly drum 2.5 kg
molybdate tetrahydrate
[12054‑85‑2] Merck 14,533 (NH4)6Mo7O24 · 4H2O FW 1235.86  99.999% trace metals basis
81.0-83.0% MoO3 basis crystals and lumps
density ..................................... 2.498 g/mL, 25 °C phosphate (PO43-) ............................. ≤5 ppm 256064-25G poly btl 25 g
chloride (Cl-) ............................................. ≤0.002% sulfate (SO42-) ......................................... ≤0.02% 256064-100G poly btl 100 g
7
Warning H315-H319-H335 P261-P305 + P351 + P338
insolubles ............................................................................................................................................................. ≤0.005%
 99.98% trace metals basis ign. residue .................................................. ≤0.01% phosphate (PO43-) ............................. ≤5 ppm
Reagent used for oxidation of sulfides to sulfonyls.1 pH ............................................... 4.5-6.0, 5% (25 °C) sulfate (SO42-) ...................................... ≤0.002%
chloride (Cl-) ............................................. ≤5 ppm Fe .................................................................. ≤2 ppm
nitrite (NO2-) .... passes test (lim. ~5 ppm) heavy metals (as Pb) ...................... ≤5 ppm
221244-500G poly btl 500 g

221244-2.5KG poly btl 2.5 kg

AHB A, 0613, UNP EU
n Ammoniumperrhen n
Ammonium-15N nitrate Ammonium oxalate monohydrate

15
[31432‑48‑1] NH4NO3 FW 81.04 Oxalic acid diammonium salt
mp ................................................................................................................................................................................ 169 °C [6009‑70‑7] Merck 14,537; Beil. 2,IV,1846 (NH4)2C2O4 · H2O
bp ................................................................................................................................................................................. 210 °C FW 142.11
37
Warning H272-H315-H319-H335 P220-P261-P305 + P351 + mp ................................................................................................................................................................ 133 °C (dec.)
P338
7
 10 atom % 15N
powder A
Hydration may vary slightly
 60 atom % 15N 379743-5G poly btl 5g
379743-25G poly btl 25 g
 98 atom % 15N 99.0-101.0% (ACS specification)
mol wt 81.02, atom % calculation insolubles ............................................................................................................................................................. ≤0.005%
299278 ign. residue .................................................. ≤0.02% Fe .................................................................. ≤2 ppm
Ammonium nitrate-15N sulfate (SO42-) .......................................... ≤0.002%
[31432‑46‑9] NH415NO3 FW 81.04
221716-100G poly btl 100 g
mp ................................................................................................................................................................................ 169 °C
221716-500G poly btl 500 g
bp ................................................................................................................................................................................. 210 °C
221716-2.5KG poly drum 2.5 kg
37
P338 Ammonium pentaborate octahydrate, ≥99%
 10 atom % 15N [12046‑03‑6] (NH4)2B10O16 · 8H2O FW 544.30
7
Warning H315-H319-H335 P261-P305 + P351 + P338
 98 atom % 15N
A4505-2.5KG poly drum 2.5 kg
366536-1G glass btl 1g > Ammonium pentadecafluorooctanoate, see Pentadecafluorooctanoic acid
ammonium salt Page 1985
> Ammonium-15Nnitrate-15N solution, see NMR
Standard/66.67mg/mL15NH415NO3(98%)/D2O(99.0%) Page 1933 Ammonium perchlorate
Ammonium nitrate-15N2 [7790‑98‑9] Merck 14,540 NH4ClO4 FW 117.49

density ................................................................................................................................................ 1.95 g/mL, 25 °C
Ammonium-15Nnitrate-15N
3
Danger H271-EUH044 P220
[43086‑60‑8] 15NH415NO3 FW 82.03
mp ................................................................................................................................................................................ 169 °C
bp ................................................................................................................................................................................. 210 °C  99.999% trace metals basis
 5 atom % 15N
mol wt 80.14, atom % calculation  99.8% trace metals basis
37
Warning H272-H315-H319-H335 P220-P261-P305 + P351 + 208507-250G glass btl 250 g
P338
488070-100G poly btl 100 g
Ammonium perchlorate solution
 10 atom % 15N
[7790‑98‑9] Merck 14,540 NH4ClO4 FW 117.49
 ~1 M in H2O
37
3
P338 Warning H272 P220
 60 atom % 15N 09911-2.5L glass btl 2.5 L
488062-5G glass btl 5g Ammonium perrhenate
[13598‑65‑7] NH4ReO4 FW 268.24
 98 atom % 15N density ................................................................................................................................................ 3.97 g/mL, 25 °C
37
Danger H272-H315-H319-H335 P220-P261-P305 + P351 +
37
P338
Ammonium nitrate- N2 solution 14

 ≥99%
14 crystalline
NH414NO3 FW 80.04
 99.95 atom % 14
N
AHB A, 0613, UNP EU
n Ammoniumpersulf n
Ammonium persulfate  ACS reagent, ≥98%

AP; Ammonium peroxodisulfate; APS; PER; Ammonium peroxy- insolubles ............................................................................................................................................................. ≤0.005%
disulfate NH4OH pptd. ..................................................................................................................................................... ≤0.005%
pH ............................................... 3.8-4.4, 5% (25 °C) Fe .................................................................. ≤0.001%
[7727‑54‑0] Merck 14,541; Fieser 6,20; 5,5; 12,33; 1,952; 3,238; 2,348;
chloride (Cl-) ............................................. ≤5 ppm heavy metals (as Pb) ...................... ≤5 ppm
5,15 (NH4)2S2O8 FW 228.20
nitrate (NO3-) ........................................... ≤0.001% K .................................................................... ≤0.005%
Catalyst for acrylamide gel polymerization. sulfate (SO42-) ............................................. ≤0.01% Mg ................................................................... 0.005%
vd ........................................................................................................................................................................... 7.9 (vs air) Ca ......................................................................... 0.001% Na ................................................................. ≤0.005%
A 378
Danger H272-H302-H315-H317-H319-H334-H335
P220-P261-P280-P305 + P351 + P338-P342 + P311 216003-100G poly btl 100 g
216003-500G poly btl 500 g
216003-2.5KG poly btl 2.5 kg
insolubles ............................................................................................................................................................. ≤0.005%
Titr. acid ...................................................................................................................................................... ≤0.04 meq/g  ReagentPlus®, ≥98.5%
ign. residue .................................................. ≤0.05% heavy metals (as Pb) ...................... ≤0.005%
Cl- and ClO4- ............................................ ≤0.001% Mn ............................................................ ≤0.5 ppm
Fe ...................................................................... ≤0.001% A1645-500G poly btl 500 g
A1645-2.5KG poly btl 2.5 kg
248614-100G poly btl 100 g
248614-500G poly btl 500 g > Ammonium phosphate monobasic, see Ammonium dihydrogenphosphate
Page 177
248614-2.5KG poly btl 2.5 kg Ammonium phosphinate, see Ammonium hypophosphite Page 181
 reagent grade, 98% Ammonium phosphomolybdate hydrate

Free radical initiator
Phosphomolybdic acid ammonium salt hydrate; Molybdophosphoric
215589-100G poly btl 100 g acid ammonium salt; Ammonium-12-molybdophosphate
215589-500G poly btl 500 g [54723‑94‑3] (NH4)3PMo12O40 · xH2O FW 1876.35 (Anh)
Ammonium phosphate dibasic powder
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Diammonium hydrogenphosphate; di-Ammonium hydrogenphos-
phate (sec); Ammonium hydrogenphosphate
[7783‑28‑0] Merck 14,542 (NH4)2HPO4 FW 132.06
342165-250G glass btl 250 g
mp ................................................................................................................................................................. 155 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338 Ammonium pyrrolidinedithiocarbamate, ~99%
APDC; PDTC; Ammonium pyrrolidinecarbodithioate; PDC; 1-
 ≥99.99% trace metals basis Pyrrolidinecarbodithioic acid ammonium salt
crystalline [5108‑96‑3] Beil. 20,V,1,331 C5H9NS2 · NH3 FW 164.29
379980-25G poly btl 25 g mp .............................................................................................................................................................. 153 to 155 °C
379980-100G poly btl 100 g Prevents induction of nitric oxide synthetase by inhibiting translation
of NOS mRNA; induces apoptosis in rat smooth muscle cells and
 ACS reagent, ≥98% inhibits apoptosis in leukemia HL-60 cells.
insolubles ............................................................................................................................................................. ≤0.005%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
NH4OH pptd. ..................................................................................................................................................... ≤0.005% store at: 2-8°C
pH ............................................... 7.7-8.1, 5% (25 °C) Fe .................................................................. ≤0.001%
chloride (Cl-) ............................................. ≤0.001% heavy metals (as Pb) ...................... ≤0.001% P8765-1G glass btl 1g
nitrate (NO3-) ........................................... ≤0.003% K ..................................................................... ≤0.005% P8765-5G glass btl 5g
sulfate (SO42-) ............................................. ≤0.01% Mg ................................................................ 0.0005% P8765-25G glass btl 25 g
Ca ......................................................................... 0.001% Na ................................................................. ≤0.005% P8765-100G glass btl 100 g
215996-100G poly btl 100 g > Ammonium rhodanide, see Ammonium thiocyanate Page 186
215996-500G poly btl 500 g Ammonium sodium hydrogen phosphate, see Ammonium sodium
phosphate dibasic tetrahydrate Page 184
215996-2.5KG poly btl 2.5 kg
Ammonium sodium phosphate dibasic tetrahydrate, ≥99%
 reagent grade, ≥98.0%
Ammonium sodium hydrogen phosphate; sec-Sodium ammonium
phosphate; Sodium ammonium hydrogen phosphate
[7783‑13‑3] NaNH4HPO4 · 4H2O FW 209.07
A5764-2.5KG poly btl 2.5 kg S9506-100G poly btl 100 g
S9506-500G poly btl 500 g
Ammonium phosphate monobasic S9506-1KG poly btl 1 kg
prim-Ammonium phosphate; Ammonium dihydrogenphosphate;
Ammonium sulfamate, ≥98.0%
mono-Ammonium phosphate
[7722‑76‑1] Merck 14,543 NH4H2PO4 FW 115.03 [7773‑06‑0] Merck 14,554 NH4SO3NH2 FW 114.12
mp ................................................................................................................................................................. 190 °C (dec.) mp .............................................................................................................................................................. 131 to 135 °C
 ≥99.99% trace metals basis  ACS reagent

insolubles ............................................................................................................................................................. ≤0.005% insolubles ................................................................................................................................................................ ≤0.02%
total metallic impurities ....................................................................................................................... <100 ppm ign. residue .......................................................................................................................................................... ≤0.10%
pH range ...................................................... 3.8 - 4.4 Fe .................................................................. ≤0.001% heavy metals .................................................................................................................................................... ≤5 ppm
chloride (Cl-) ............................................. ≤5 ppm heavy metals ........................................ ≤5 ppm
7
Warning H302
nitrate (NO3-) ........................................... ≤0.001% K ..................................................................... ≤0.005%
sulfate (SO42-) ............................................. ≤0.01% Mg ................................................................ 0.0005%
228745-100G poly btl 100 g
Ca ......................................................................... 0.001% Na ................................................................. ≤0.005%
467782-50G poly btl 50 g
467782-250G poly btl 250 g

AHB A, 0613, UNP EU
n Ammoniumtetrach n
Ammonium sulfate Ammonium-14N2 sulfate

[7783‑20‑2] Merck 14,555 (NH4)2SO4 FW 132.14 (14NH4)2SO4 FW 132.13
May be used for the precipitation or fractionation of proteins or for mp ............................................................................................................................................................. >280 °C (dec.)
purification of antibodies. Useful for crystallographic analysis of
 99.99 atom % 14N
nucleic acids and proteins. 15
N depleted
mp ............................................................................................................................................................. >280 °C (dec.)
density ................................................................................................................................................ 1.77 g/mL, 25 °C
crystals and lumps > Ammonium sulfate monobasic, see Ammonium bisulfate Page 175 A
204501-50G poly btl 50 g Ammonium sulfide solution
204501-250G poly btl 250 g
[12135‑76‑1] Merck 14,556 (NH4)2S FW 68.14
 ACS reagent, ≥99.0% Danger EUH029
Insoluble matter .............................................................................................................................................. ≤0.005%  20% in H2O
ign. residue ............................................... ≤0.005% phosphate (PO43-) ............................. ≤5 ppm
59
H314-H400 P273-P280-P305 + P351 + P338-P310
pH ............................................... 5.0-6.0, 5% (25 °C) Fe ................................................................... ≤5 ppm
chloride (Cl-) ............................................. ≤5 ppm heavy metals (as Pb) ...................... ≤5 ppm
nitrate (NO3-) ........................................... ≤0.001% A1952-25ML glass btl 25 mL
store at: room temp A1952-500ML glass btl 500 mL
A4915-25G poly btl 25 g  40-48 wt. % in H2O

A4915-500G poly btl 500 g bp ............................................................................ 40 °C n20
D .......................................................................... 1.467
A4915-6X500G 6 × 500 g density ............................................... 1 g/mL, 25 °C
259
A4915-1KG poly btl 1 kg H225-H314-H400 P210-P273-P280-P305 + P351 + P338-
A4915-2.5KG poly drum 2.5 kg P310
A4915-4X2.5KG 4 × 2.5 kg 515809-100ML glass btl 100 mL

A4915-5KG poly drum 5 kg 515809-500ML glass btl 500 mL
A4915-12KG poly drum 12 kg Ammonium sulfite monohydrate, 92%
[7783‑11‑1] Merck 14,557 (NH4)2SO3 · H2O FW 134.16
density ................................................................................................................................................ 1.41 g/mL, 25 °C
 ReagentPlus®, ≥99.0%
7
Warning H315-H319-H335-EUH031 P261-P305 + P351 + P338
A5132-1KG poly btl 1 kg 358983-500G glass btl 500 g
A5132-5KG poly drum 5 kg 358983-2.5KG glass btl 2.5 kg
 technical, ≥99% Ammonium sulfite solution, 34%

heavy metals (as Pb) ................................................................................................................................... ≤0.003% [17026‑44‑7] (NH4)2SO3 FW 116.14
chloride (Cl-) ........................................................................................................................................... ≤100 mg/kg
 technical
Fe ....................................................................................................................................................................... ≤50 mg/kg
concentration ........................................................................................................................................ ~34% in H2O
11226-5KG 5 kg
11229-2.5L glass btl 2.5 L
> Ammonium sulfate monobasic, see Ammonium hydrogensulfate
Page 179 Ammonium tetrachloroaurate(III) hydrate, 99.99% trace metals
basis
Ammonium-15N2 sulfate [13874‑04‑9] NH4AuCl4 · xH2O FW 372.82 (Anh)
[43086‑58‑4] (15NH4)2SO4 FW 134.13 203386-1G glass btl 1g
mp ............................................................................................................................................................. >280 °C (dec.)
Ammonium tetrachloropalladate(II)
 5 atom % 15N
Palladium(II)-ammonium chloride
[13820‑40‑1] Fieser 3,81 (NH4)2PdCl4 FW 284.31
488089-250G glass btl 250 g
 10 atom % N 15
Reacts with creatinine (cat. no. 859702) to form various Pd-creatinine
mol wt 132.34, atom % calculation complexes with applications in semiconductors, catalysis, mixed
348473-5G glass btl 5g oxidation state studies, and electron conductivity.1
348473-25G glass btl 25 g density ................................................................................................................................................ 2.17 g/mL, 25 °C
Lit. cited: 1. Gencheva, G. et al., Polyhedron 11, 2357 (1992)
 60 atom % N 15
7
mol wt 133.34, atom % calculation + P338
488097-5G glass btl 5g  ≥99.995% trace metals basis
 98 atom % 15N
mol wt 134.09, atom % calculation  97%

AHB A, 0613, UNP EU
n Ammoniumtetrach n
Ammonium tetrachloroplatinate(II), 99% Ammonium thiocyanate

Platinum(II)-ammonium chloride Ammonium rhodanide
[13820‑41‑2] Merck 14,549 (NH4)2PtCl4 FW 372.97 [1762‑95‑4] Merck 14,561; Beil. 3,IV,319 NH4SCN FW 76.12
Features and Benefits mp .............................................................................................................................................................. 152 to 154 °C
79
Reacts with creatinine (cat. no. 859702) to form various complexes Warning H302-H312-H332-H410-EUH032 P273-P280-P501
such as [Pt4(creat)2Cl14]7- and [Pt4(creat)6]2- with applications in
semiconductors, catalysis, mixed oxidation state studies, and electron  99.99% trace metals basis
A
conductivity.1
mp ................................................................................................................................................................. 140 °C (dec.)
Meets ACS reagent specifications.
density ............................................................................................................................................. 2.936 g/mL, 25 °C
insolubles ............................................................................................................................................................. ≤0.005%
Lit. cited: 1. Gencheva, G. et al., Polyhedron 11, 2357 (1992)
I2 consumers ....................................................................................................................................... ≤0.004 meq/g
568
Danger H301-H315-H317-H318-H334 P261-P280-P301 ign. residue ............................................... ≤0.025% sulfate (SO42-) ...................................... ≤0.005%
+ P310-P305 + P351 + P338-P342 + P311
pH range ...................................................... 4.5 - 6.0 Fe .................................................................. ≤3 ppm
206105-1G glass btl 1g chloride (Cl-) ............................................. ≤0.005% heavy metals ........................................ ≤5 ppm
431354-50G poly btl 50 g
Ammonium tetrafluoroborate 431354-250G poly btl 250 g
Ammonium fluoroborate
[13826‑83‑0] Fieser 5,17; 6,132 NH4BF4 FW 104.84
insolubles ............................................................................................................................................................. ≤0.005%
crystalline I2 consumers ....................................................................................................................................... ≤0.004 meq/g
density ............................................................................................................................................. 1.871 g/mL, 25 °C ign. residue ............................................... ≤0.025% sulfate (SO42-) ...................................... ≤0.005%
pH ................................... 4.5-6.0, 5% H2O (25 °C) Fe .................................................................. ≤3 ppm
221988-100G poly btl 100 g
202843-10G poly btl 10 g 221988-2.5KG poly drum 2.5 kg
202843-50G poly btl 50 g
 powder
 ≥97% color .............................................................................................................................................................................. white
223727-100G poly btl 100 g A7149-100G glass btl 100 g
223727-500G poly btl 500 g A7149-500G glass btl 500 g
Ammonium tetraphenylborate, 99% Ammonium-d4 thiocyanate
Tetraphenylboron ammonium [36700‑77‑3] ND4SCN FW 80.15
[14637‑34‑4] Beil. 16,IV,1624 NH4B(C6H5)4 FW 337.27
 99 atom % D
mp ................................................................................................................................................................. 220 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Ammonium thioglycolate solution
Thioglycolic acid ammonium salt
> Ammonium tetrarhodanatodiamminechromate(III), see Reinecke salt [5421‑46‑5] HSCH2COONH4 FW 109.15
Page 2244
 ~60% in H2O
Ammonium tetrathiomolybdate, 99.97% trace metals basis 10010-1L glass btl 1L
[15060‑55‑6] Merck 14,560 (NH4)2MoS4 FW 260.28 Ammonium thiosulfate, 98%
mp ............................................................................................................................................................................ >300 °C
[7783‑18‑8] Merck 14,562 (NH4)2S2O3 FW 148.21
Acts as a chelator in vivo to reduce copper levels. Tetrathiomolybdate
density ............................................................................................................................................. 1.679 g/mL, 25 °C
interferes with angiogenesis and reduces tumor growth. Its
mechanism may involve inhibition of NF-κB and downstream crystals and lumps
cytokines.2 336726-500G glass btl 500 g
Ring opening of aziridines leading to sulfides and disulfides.1 336726-2.5KG glass btl 2.5 kg
crystalline
Lit. cited: 1. J. Org. Chem. 72, 2106 (2007) Ammonium titanyl oxalate monohydrate, 99.998% trace metals
basis
2. Brewer, G.J., Curr. Cancer Drug Targets 5, 195 (2005)
323446-1G glass btl 1g Ammonium bis(oxalato)oxotitanate(IV)
[10580‑03‑7] (NH4)2TiO(C2O4)2 · H2O FW 294.00
crystals and lumps
7
Ammonium tetrathiotungstate, ≥99.9% trace metals basis + P338
[13862‑78‑7] (NH4)2WS4 FW 348.18 229989-10G poly btl 10 g
density ................................................................................................................................................ 2.71 g/mL, 25 °C 229989-100G poly btl 100 g
crystalline > Ammonium triflate, see Ammonium trifluoromethanesulfonate Page 187
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Ammonium trifluoroacetate, 98%
336734-5G glass btl 5g Trifluoroacetic acid ammonium salt
336734-25G glass btl 25 g [3336‑58‑1] Beil. 2,II,186; Fieser 11,557 CF3CO2NH4 FW 131.05
mp .............................................................................................................................................................. 123 to 125 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338

238732-100G glass btl 100 g

AHB A, 0613, UNP EU
n Amylamine n
Ammonium trifluoromethanesulfonate, 99% Ampicillin trihydrate, 96.0-100.5%

Ammonium triflate D-(−)-α-Aminobenzylpenicillin
O
[38542‑94‑8] Beil. 3,IV,34 CF3SO3NH4 FW 167.11 [7177‑48‑2] Merck 14,586 C16H19N3O4S · H
N S CH3
mp .............................................................................................................................................................. 224 to 226 °C 3H2O FW 403.45 H
NH2 N CH3
crystals and lumps O
• 3H2O O OH
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp ............................................................................................................................................... 198 to 200 °C (dec.)

345865-10G
345865-50G
poly btl
poly btl
10 g
50 g
Used to select for ampicillin resistance in mutated and transformed
cells.
A
78
Ammonium tungstate, 99.99% trace metals basis Danger H315-H317-H319-H334-H335 P261-P280-P305 + P351
+ P338-P342 + P311 store at: 2-8°C
[11140‑77‑5] (NH4)10H2(W2O7)6
A6140-5G 5g
Soluble form
powder A6140-25G 25 g
Purity excludes ~2000 ppm Mo. A6140-100G 100 g
7
Warning H315-H319-H335 P261-P305 + P351 + P338 Ampicillin sodium salt
D-(−)-α-Aminobenzylpenicillin
sodium salt NH2
322385-10G glass btl 10 g H H
[69‑52‑3] Merck 14,586 C16H18N3NaO4S N S
322385-50G glass btl 50 g CH3
FW 371.39 O N CH3
O
Ammonium (para)tungstate hydrate, 99.99% trace metals basis
O ONa
[11120‑25‑5] Merck 14,564 (NH4)10H2(W2O7)6 · xH2O
FW 3060.46 (Anh) mp ................................................................................................................................................................ 215 °C (dec.)
mp ............................................................................................................................................................................ >300 °C Used to select for ampicillin resistance in mutated and transformed
density ................................................................................................................................................... 2.3 g/mL, 25 °C cells.
powder soluble in ......................................................................................................................................... H2O (50 mg/mL)
color ..................................................................................................................... white with slight yellow cast
7
Warning H315-H319-H335 P261-P305 + P351 + P338
8
Danger H317-H334 P261-P280-P342 + P311 store at: 2-8°C
510114-25G poly btl 25 g
510114-100G poly btl 100 g A9518-5G poly btl 5g
Ammonium zirconium(IV) carbonate solution A9518-100G poly btl 100 g
 in H2O, contains 1-2% tartaric acid as stabilizer > AM-polystyrene, see (Aminomethyl)polystyrene Page 144
mp .................................................................................................................................................................................. −4 °C Amsonic acid, see 4,4′-Diamino-2,2′-stilbenedisulfonic acid Page 868
density ................................................................................................................................................ 1.38 g/mL, 25 °C Amyl acetate, see Pentyl acetate Page 1998
464597-250ML glass btl 250 mL Amyl acetate, mixture of isomers, 99%

Amojell™ Pentyl acetate O
Excellent saturated-hydrocarbon-based, low-melting lubricant for C7H14O2 FW 130.18 CH3

H3C O
precision glass stirrer shafts and bearings. In contrast to glycerine and O
silicone-based lubricants, this material is highly inert and unreactive H3C O CH3
toward most organic reaction mixtures. CH3
color ............................................................................................................................................................... snow-white
density ................................................................................................................................................ 0.84 g/mL, 25 °C density ............................................................................................................................................. 0.876 g/mL, 25 °C
n20
D ...................................................................................................................................................................................... 1.402
230855
 Mixture of 2-methylbutyl acetate and n-pentyl acetate
> AMP, see 2-Amino-2-methyl-1-propanol Page 144
27
5′-AMP, see Adenosine 5′-monophosphate monohydrate Page 58 Warning H226-H315-H319-H335 P261-P305 + P351 + P338
AMP 75, see 2-Amino-2-methyl-1-propanol Page 144
AMP 90, see 2-Amino-2-methyl-1-propanol Page 144
AMP 100, see 2-Amino-2-methyl-1-propanol Page 144 227471-1L glass btl 1L
AMPA, see (Aminomethyl)phosphonic acid Page 143 227471-2.5L glass btl 2.5 L
AMPD, see 2-Amino-2-methyl-1,3-propanediol Page 144
> n-Amyl alcohol, see 1-Pentanol Page 1995
Ampicillin, 96.0-100.5% (anhydrous basis) tert-Amyl alcohol, see 2-Methyl-2-butanol Page 1751
tert-Amyl alcohol sodium salt, see Sodium tert-pentoxide Page 2315
D-(−)-α-Aminobenzylpenicillin Sodium tert-pentoxide solution Page 2315
O
[69‑53‑4] Merck 14,586 C16H19N3O4S HO O
O Amylamine, 99%
FW 349.40 N
H3C
H3C N Pentylamine; 1-Aminopentane; n-Amylamine
S H H
NH2
[110‑58‑7] Merck 14,598; Beil. 4,IV,674 CH3(CH2)4NH2 FW 87.16
mp ....................................................................... −50 °C n20D .......................................................................... 1.411
mp ................................................................................................................................................................. 208 °C (dec.)
bp ......................................................................... 104 °C vd ............................................................. 3.01 (vs air)
 anhydrous density ..................................... 0.752 g/mL, 25 °C
suitable for 1694 per US EPA May darken in storage.
soluble in ...................................................................................................................... 1 M NH4OH (50 mg/mL)
256
Danger H225-H302-H312-H314-H331 P210-P261-
78
Danger H315-H317-H319-H334-H335 P261-P280-P305 + P351 P280-P305 + P351 + P338-P310
+ P338-P342 + P311 store at: 2-8°C
A9393-5G 5g 171409-50ML glass btl 50 mL
A9393-25G 25 g 171409-250ML glass btl 250 mL
> n-Amylamine, see Amylamine Page 187
AHB A, 0613, UNP EU
n Amylamine n
tert-Amylamine, 98% 4-tert-Amylphenol, 99%

1,1-Dimethylpropylamine; tert-Pentylamine [80‑46‑6] Merck 14,7142; Beil. 6,548 C2H5C(CH3)2C6H4OH
[594‑39‑8] C2H5C(CH3)2NH2 FW 87.16 FW 164.24
bp ............................................................................ 77 °C n20
D ....................................................................... 1.3996 mp ................................................................................................................................................................... 88 to 89 °C
density ..................................... 0.746 g/mL, 25 °C bp ................................................................................................................................................................................. 255 °C
256 57
Danger H225-H301-H314 P210-P280-P305 + P351 + Danger H302-H312-H314 P280-P305 + P351 + P338-P310
P338-P310
A
> 2-Amylamine, see 2-Aminopentane Page 152 153842-100G poly btl 100 g
> 4-Amylphenyl 4′-methoyxbenzoate, see 4-Pentylphenyl 4-methoxybenzoate

Amylamines, mixture of isomers, ≥98% Page 2000
C5H11NH2 FW 87.16
Anabasine
Neonicotine; 2-(3-Pyridyl)piperidine
> n-Amyl bromide, see 1-Bromopentane Page 507 [13078‑04‑1] Beil. 23,IV,1027 C10H14N2 FW 162.23
tert-Amyl bromide, see 2-Bromo-2-methylbutane Page 493 N
H
N
tert-Amyl-tert-butylamine, 96%
[2085‑66‑7] C2H5C(CH3)2NHC(CH3)3 FW 143.27 bp .................................................. 96 °C/12 mmHg n20
D .......................................................................... 1.544
bp ......................................................................... 144 °C n20 density ..................................... 1.046 g/mL, 25 °C

D .......................................................................... 1.421
6
density ........................................ 0.77 g/mL, 25 °C Danger H300-H315-H319-H335 P261-P264-P301 + P310-P305 + P351
+ P338
25
Danger H225-H314 P210-P280-P305 + P351 + P338-P310
> Amyl chloride, see 1-Chloropentane Page 720 (R,R)-ANDEN-Phenyl Trost Ligand 8
tert-Amyl chloride, see 2-Chloro-2-methylbutane Page 702
(11R,12R)-N,N′-(9,10-Dihydro-9,10- Ph Ph
O
α-Amylcinnamaldehyde, 97% ethanoanthracene-11,12-diyl)bis[2- P
O
Ph
P
Ph
[122‑40‑7] Beil. 7,II,310 C6H5CH=C[(CH2)4CH3]CHO FW 202.29 (diphenylphosphino)]benzamide; HN

NH
bp ............................................................... 287-290 °C n20
D .......................................................................... 1.557
(+)-(11R,12R)Bis[2′-(diphenylphosphino)
density ........................................ 0.97 g/mL, 25 °C benzamido]-9,10-dihydro-9,10-ethano-
anthracene
 mixture of cis and trans [152140‑65‑3] C54H42N2O2P2
FW 812.87
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 125 to 130 °C
288993-100ML glass btl 100 mL Asymmetric allylic alkylation ligand.1,2,3,4
[α]22
D -100°, c = 1 in chloroform
> 2-tert-Amyl-6-(diphenylphosphino)pyridine, see 2-(1,1-Dimethylpropyl)-6- Sold in collaboration with Dr. Reddy′s Laboratories for research
(diphenylphosphino)pyridine Page 1110
Amylene, see 2-Methyl-2-butene Page 1752 purposes only. US Patent 5739396 applies.
Amyl ether, see Dipentyl ether Page 1137 Lit. cited: 1. Trost, B.M. et al., Chem. Rev. 96, 395 (1996)
Amyl fluoride, see 1-Fluoropentane Page 1319 2. Trost, B.M. et al., Chem. Rev. 103, 2921 (2003)
n-Amyl iodide, see 1-Iodopentane Page 1552 3. Trost, B.M. et al., J. Am. Chem. Soc. 124, 11616 (2004)
Amyllithium, see Pentyllithium solution Page 1999 4. Trost, B.M. et al., Aldrichimica Acta 40, 59 (2007)
Amyl mercaptan, see 1-Pentanethiol Page 1995
tert-Amyl methyl ether, 97% 697591-500MG glass btl 500 mg
Methyl 2-methyl-2-butyl ether; Methyl tert-pentyl ether; 1,1- (S,S)-ANDEN-Phenyl Trost Ligand 8
Dimethylpropyl methyl ether; TAME
[994‑05‑8] Merck 14,612; Beil. 1,IV,1671 C2H5C(CH3)2OCH3 (11S,12S)-N,N′-(9,10-Dihydro-9,10- Ph Ph
Ph Ph O P
FW 102.17 ethanoanthracene-11,12-diyl)bis[2- P O
(diphenylphosphino)]benzamide; NH
bp ..................................................................... 85-86 °C n20
D .......................................................................... 1.389 HN
density ........................................ 0.77 g/mL, 25 °C (+)-(11S,12S)Bis[2′-(diphenylphosphino)
benzamido]-9,10-dihydro-9,10-ethano-
27
Danger H225-H302-H336 P210-P261
anthracene
[138517‑65‑4] C54H42N2O2P2
FW 812.87
mp .............................................................................................................................................................. 123 to 128 °C
Asymmetric allylic alkylation ligand.1,2,3,4
Amylose from potato [α]22
Sold in collaboration with Dr. Reddy′s Laboratories for research
[9005‑82‑7] (C6H10O5)n
purposes only. US Patent 5739396 applies.
A substrate for serum amylase. Lit. cited: 1. Trost, B. M. et al., Chem. Rev. 96, 395 (1996)
amylopectin ....................................................................................................................................... essentially free 2. Trost, B. M. et al., Chem. Rev. 103, 2921 (2003)
butanol ............................................................................................................................................................................ ≤2% 3. Trost, B. M. et al., J. Am. Chem. Soc. 124, 11616 (2004)
ethanol .......................................................................................................................................................................... ≤10% 4. Trost, B. M. et al., Aldrichimica Acta 40, 59 (2007)
7
Warning H319 P305 + P351 + P338 697605-100MG glass btl 100 mg

AHB A, 0613, UNP EU
n Aniline n
Andrographolide, 98% 1,6-Anhydro-β-D-glucose, 99%

[5508‑58‑7] Merck 14,633; Beil. 18,IV,2357 O Levoglucosan O
C20H30O5 FW 350.45 HO O [498‑07‑7] Beil. 19,V,3,498 C6H10O5 FW 162.14 O
OH
H3 C OH
OH
CH2
H
HO mp .............................................................................................................................................................. 182 to 184 °C
D −66°, c = 1 in H2O
[α]18
A
H3C OH

Diterpenoid lactone with anti-inflammatory properties. It blocks T-cell
proliferation to allogenic stimuli and the chemotactic migration of Aniline
macrophages induced by complement. Blocks the proliferation of [62‑53‑3] Merck 14,659; Beil. 12,IV,223; Fieser 6,21 C6H5NH2
several cancer cell lines in vitro. FW 93.13
mp .............................................................................................................................................................. 229 to 232 °C The acute toxicity of aniline involves its activation in vivo to 4-
D −126°, c = 1.5 in acetic acid
[α]20 hydroxyaniline and the formation of adducts with hemoglobin. In
365645-100MG glass btl 100 mg erythrocytes, this is associated with the release of iron and the
365645-500MG glass btl 500 mg accumulation of methemoglobin and the development of hemolytic
anemia and inflammation of the spleen. Tumor formation is often
> 5-Androsten-3ß-ol-17-one-d6, see Dehydroepiandrosterone-2,2,3,4,4,6-d6
Page 842 observed in the spleen on prolonged administration.
5-Androsten-3β-ol-17-one sulfate sodium salt dihydrate, see Dehydroi- Material darkens in storage to reddish-brown with no loss in purity.
soandrosterone 3-sulfate sodium salt dihydrate Page 842 APHA color .......................................................... ≤250 n20
D .......................................................................... 1.586
12-Ane-S4, see 1,4,7,10-Tetrathiacyclododecane Page 2417 mp .......................................................................... −6 °C vd .......................................... 3.22 (185 °C, vs air)
14-Ane-S4, see 1,4,8,11-Tetrathiacyclotetradecane Page 2417 bp ......................................................................... 184 °C vp ............................................ 0.7 mmHg (25 °C)
16-Ane-S4, see 1,5,9,13-Tetrathiacyclohexadecane Page 2417
density ..................................... 1.022 g/mL, 25 °C ait ...................................................................... 1139 °F
5689
trans-Anethole, 99% Danger H301-H311-H317-H318-H331-H341-
H351-H372-H400 P261-P273-P280-P301 + P310-
trans-1-Methoxy-4-(1-propenyl)benzene; 4-Propenylanisole P305 + P351 + P338-P311
[4180‑23‑8] Merck 14,643; Beil. 6,566; 6,IV,3796
CH3CH=CHC6H4OCH3 FW 148.20  ACS reagent, ≥99.5%
chlorobenzene .................................................................................................................................................... ≤0.01%
Naturally occurring phenylpropene derivative that is estrogenic at
Hydrocarbons ............................................................................................................................................ passes test
lower concentrations and cytotoxic at higher concentrations to
Nitrobenzene ......................................................................................................... passes test (lim. ~0.001%)
cancer cell lines. The cytotoxicity is related to the metabolism of trans-
ign. residue ....................................................................................................................................................... ≤0.005%
anethole to 4-hydroxy-1-propenylbenzene.
mp ............................................................ 20 to 21 °C density .................................. 0.988 g/mL, 25 °C 242284-5ML 5 mL
bp ............................................................... 234-237 °C n20
D .......................................................................... 1.561 242284-100ML 100 mL
7
Warning H317 P280 242284-250ML 250 mL
242284-500ML 500 mL
117870-25ML glass btl 25 mL 242284-1L 1L
242284-100G glass btl 100 g
> Aneurine hydrochloride, see Thiamine hydrochloride Page 2420
Aneurine hydrochloride, Vitamin B1, hydrochloride, see 242284-500G glass btl 500 g
Thiamine-(4-methyl-13C-thiazol-5-yl-13C3) hydrochloride Page 2420
α-Angelica lactone, 98% 132934-500ML 500 mL
4-Hydroxy-3-pentenoic acid γ-lactone; 5-Methyl-2(3H)- 132934-1L 1L
furanone H3C O O 132934-2.5L 2.5 L
[591‑12‑8] Beil. 17,V,9,120 C5H6O2 FW 98.10 132934-18L 18 L
Plant-derived cancer chemopreventive agent. Increases the synthesis 132934-500G glass btl 500 g
of glutathione and the activity of glutathione-S-transferase and UDP- 132934-2KG glass btl 2 kg
glucunonosyltransferase detoxification enzymes in esophagus,
stomach, intestine, and liver. Aniline hydrochloride
mp ............................................................ 13 to 17 °C density .................................. 1.092 g/mL, 25 °C [142‑04‑1] Merck 14,659; Beil. 12,IV,232 C6H5NH2 · HCl FW 129.59
bp .......................................... 55-56 °C/12 mmHg n20 D .......................................................................... 1.448 The acute toxicity of aniline involves its activation in vivo to 4-
hydroxyaniline and the formation of adducts with hemoglobin. In
erythrocytes, this is associated with the release of iron and the
accumulation of methemoglobin and the development of hemolytic
> 1,5-Anhydro-2-deoxy-D-lyxo-hex-1-enitol, see D-Galactal Page 1377 anemia and inflammation of the spleen. Tumor formation is often
observed in the spleen on prolonged administration.
1,4-Anhydroerythritol, 95% mp .............................................................................................................................................................. 196 to 198 °C
[4358‑64‑9] Beil. 17,153 C4H8O3 FW 104.10 HO OH vd ........................................................................................................................................................................ 4.46 (vs air)
5689
Danger H301-H311-H317-H318-H331-H341-
O H351-H372-H400 P261-P273-P280-P301 + P310-
P305 + P351 + P338-P311
density ................................................................................................................................................ 1.27 g/mL, 25 °C A8524-5G poly btl 5g
n20
D ...................................................................................................................................................................................... 1.477

AHB A, 0613, UNP EU
n Aniline n
Aniline-15N Anilinium hypophosphite, 97%

[7022‑92‑6] Beil. 12,III,240 C6H515NH2 FW 94.12 [82395‑88‑8] C6H10NO2P FW 159.12 NH3
mp .......................................................................... −6 °C n20
D .......................................................................... 1.586
O
bp ......................................................................... 184 °C O P H
H
 98 atom % 15N mp .............................................................................................................................................................. 113 to 115 °C

5689
Danger H301-H311-H317-H318-H331-H341-
density ............................................................................................................................................. 1.033 g/mL, 25 °C H351-H372-H400 P261-P273-P280-P301 + P310-
A 5689 Danger H301-H311-H317-H318-H331-H341-
H351-H372-H400 P261-P273-P280-P301 + P310- 654116-25G glass btl
P305 + P351 + P338-P311
25 g
P305 + P351 + P338-P311
488100-1G glass btl 1g > 4-Anilinoazobenzene, see 4-(Phenylazo)diphenylamine Page 2022
2-Anilinoethanol, see N-(2-Hydroxyethyl)aniline Page 1481
Aniline-1-13C
13 N-[(3-(Anilinomethylene)-2-chloro-1-cyclohexen-1-yl)
[18960‑62‑8] CC5H7N FW 94.12 methylene]aniline monohydrochloride, 97%
 99 atom % 13
C [63857‑00‑1] C20H19ClN2 · HCl FW 359.29
491799 Full product information at Aldrich.com mp ................................................................................................................................................................ 224 °C (dec.)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Aniline-2,3,4,5,6-d5
[4165‑61‑1] C6D5NH2 FW 98.16 407232-5G glass btl 5g
mp ............................................................................ -6 °C vd .......................................... 3.22 (184 °C, vs air)
bp ......................................................................... 184 °C vp ............................................. 0.7 mmHg (25 °C) (R)-(−)-2-(Anilinomethyl)pyrrolidine, 97%
n20
D ........................................................................... 1.5836
[68295‑45‑4] C11H16N2 FW 176.26
H
 98 atom % D N N
H
density ............................................................................................................................................. 1.076 g/mL, 25 °C
bp ................................ 111-112 °C/0.55 mmHg n20 D .......................................................................... 1.574
789
Warning H302-H312-H332-H351-H400 P273-P280
density ..................................... 1.046 g/mL, 25 °C
175692-1G ampule 1g D −19°, c = 1 in ethanol

[α]20
57
175692-5G ampule 5g Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
P338
Aniline-13C6
13
[100849‑37‑4] C6H5NH2 FW 99.08
mp .......................................................................... −6 °C n20
D .......................................................................... 1.586
(S)-(+)-2-(Anilinomethyl)pyrrolidine, 96%
bp ......................................................................... 184 °C [64030‑44‑0] Fieser 9,19 C11H16N2 FW 176.26
bp ........................................................................................................................................ 111-112 °C/0.55 mmHg
 99 atom % 13C
density ............................................................................................................................................. 1.046 g/mL, 25 °C
[α]20
D +19°, c = 1 in ethanol
density ............................................................................................................................................. 1.087 g/mL, 25 °C
5
Danger H314 P280-P305 + P351 + P338-P310
5689
Danger H301-H311-H317-H318-H331-H341-
H351-H372-H400 P261-P273-P280-P301 + P310-
P305 + P351 + P338-P311 374911-1G glass btl 1g
485497-250MG ampule 250 mg 8-Anilino-1-naphthalenesulfonic acid
Aniline-d7 ANSA; N-Phenyl peri acid; ANS
[14545‑23‑4] C6D5ND2 FW 100.17 [82‑76‑8] Merck 14,661; Beil. 14,753 C6H5NHC10H6SO3H FW 299.34
mp ............................................................................ -6 °C n20
D ....................................................................... 1.5824 mp ............................................................................................................................................... 215 to 217 °C (dec.)
bp ......................................................................... 184 °C A1028-5G glass btl 5g
 98 atom % D
mol wt 100.03, atom % calculation A1028-100G glass btl 100 g
density ............................................................................................................................................. 1.098 g/mL, 25 °C 8-Anilino-1-naphthalenesulfonic acid ammonium salt hydrate,
97%
5689
Danger H301-H311-H317-H318-H331-H341-
H351-H372-H400 P261-P273-P280-P301 + P310- [206659‑00‑9] C6H5NHC10H6SO3NH4 · xH2O FW 316.37 (Anh)
P305 + P351 + P338-P311
mp .............................................................................................................................................................. 242 to 244 °C
175706-1G ampule 1g
175706-5G ampule 5g
216909-250G poly btl 250 g
Aniline sulfate, 98%
2-Anilinophenylacetic acid
[542‑16‑5] Merck 14,659; Beil. 12,117 (C6H5NH2)2 · H2SO4
FW 284.33 2-Phenylaminophenylacetic acid
[70172‑33‑7] C6H5NHC6H4CH2CO2H FW 227.26
mp ................................................................................................................................................................... 89 to 93 °C
Aniline-2-sulfonic acid, 95%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Orthanilic acid; 2-Aminobenzenesulfonic acid; o-Sulfanilic acid
[88‑21‑1] Merck 14,6882; Beil. 14,IV,2638 H2NC6H4SO3H FW 173.19 533769-25G glass btl 25 g
5 > anionic lithium carboxylate fluorosurfactant, see Zonyl® FSA fluorosur-

Danger H314 P280-P305 + P351 + P338-P310
factant Page 2639
anionic phosphate surfactant, see Zonyl® FSJ fluorosurfactant Page 2639
A86805-100G glass btl 100 g p-Anisalacetone, see trans-4-(4-Methoxyphenyl)-3-buten-2-one Page 1714
o-Anisaldehyde, see 2-Methoxybenzaldehyde Page 1689

AHB A, 0613, UNP EU
n Anisotropicsili n
m-Anisaldehyde, 97% > p-Anisidine-3-sulfonic acid, see 5-Amino-2-methoxybenzenesulfonic acid

Page 134
3-Methoxybenzaldehyde p-Anisoin, see 4,4′-Dimethoxybenzoin Page 1038
[591‑31‑1] Beil. 8,IV,241 CH3OC6H4CHO FW 136.15
bp ............................................... 143 °C/50 mmHg n20
D .......................................................................... 1.553 Anisole
density ..................................... 1.117 g/mL, 20 °C
Methoxybenzene; Methyl phenyl ether
7
Warning H315-H319-H335 P261-P305 + P351 + P338 [100‑66‑3] Merck 14,669; Beil. 6,IV,548; Fieser 1,41 CH3OC6H5
FW 108.14
mp ....................................................................... −37 °C vd ............................................................... 3.7 (vs air)
A
129658-100G glass btl 100 g bp ......................................................................... 154 °C vp ......................................... 10 mmHg (42.2 °C)
Anisaldehyde dimethyl acetal, ≥98.5% (GC) n20
D .............................................................................. 1.516
4-Methoxybenzaldehyde dimethyl acetal; α,α,4-Trimethoxytoluene

2
Warning H226
[2186‑92‑7] Beil. 8,H,74 C10H14O3 FW 182.22
bp ................................................................................................................................................. 85-87 °C/0.1 mmHg  anhydrous, 99.7%
density ................................................................................................................................................ 1.07 g/mL, 20 °C water ....................................................................................................................................................................... <0.002%
Protecting group reagent for diols, used e.g. in carbohydrate water ..................................................................................................................................... <0.005% (100 mL pkg)
chemistry; the acetal protection can be selectively cleaved under mild evapn. residue ............................................................................................................................................. <0.0003%
conditions1,2,3 296295-100ML Sure/Seal™ 100 mL
n20
D ...................................................................................................................................................................................... 1.505 296295-1L Sure/Seal™ 1L
Lit. cited: 1. M. Kloosterman et al., Rec. Trav. Chim. 103, 243 (1984)
2. R. Johansson, B. Samuelsson, J. Chem. Soc. Perkin Trans. I 2371 (1984)
3. U. Peters et al., Tetrahedron 43, 3803 (1987)
25
Danger H260-H314-EUH014 P223 - P231 + P232 - P280 - P305
+ P351 + P338 - P370 + P378 - P422 store at: 2-8°C 123226-250ML 250 mL
10445-50ML-F glass btl 50 mL
123226-2.5L 2.5 L
> p-Anisamide, see 4-Methoxybenzamide Page 1689 123226-20L steel drum 20 L
o-Anisic acid, see 2-Methoxybenzoic acid Page 1690
m-Anisic acid, see 3-Methoxybenzoic acid Page 1690 Anisole-2,3,4,5,6-d5
p-Anisic acid, see 4-Methoxybenzoic acid Page 1690
C6D5OCH3 FW 113.17
m-Anisic hydrazide, 98%
 98 atom % D
[5785‑06‑8] CH3OC6H4CONHNH2 FW 166.18 616753 Full product information at Aldrich.com
Anisole-2,4,6-d3
o-Anisidine, ≥99% [2567‑25‑1] C7D3H5O FW 111.16
2-Aminoanisole; 2-Methoxyaniline
 98 atom % D
[90‑04‑0] Beil. 13,IV,806 CH3OC6H4NH2 FW 123.15
mp .................................................................. 3 to 6 °C density .................................. 1.092 g/mL, 25 °C 579882 Full product information at Aldrich.com
bp ......................................................................... 225 °C n20
D .......................................................................... 1.574
Anisole-d8
68
P310-P311 Methoxybenzene-d8
[54887‑54‑6] C6D5OCD3 FW 116.19
mp ....................................................................... −37 °C n20
D ....................................................................... 1.5145
A88182-100G glass btl 100 g bp ......................................................................... 154 °C
 98 atom % D
m-Anisidine, 97% mol wt 116.03, atom % calculation
3-Aminoanisole; 3-Methoxyaniline density ............................................................................................................................................. 1.068 g/mL, 25 °C
27
Warning H226-H315-H319 P305 + P351 + P338
mp .............................................................. −1 to 1 °C density .................................. 1.096 g/mL, 25 °C
bp ......................................................................... 251 °C n20
D .......................................................................... 1.581
448818-1G ampule 1g
79
Warning H302-H315-H319-H335-H410 P261-P273-P305 +
P351 + P338-P501 Anisole-methyl-d3
A88204-1L 1L [4019‑63‑0] C6H5OCD3 FW 111.16
A88204-5G glass btl 5g  99 atom % D
A88204-1KG glass btl 1 kg Anisotropic Silicon <100> Etchant
p-Anisidine, 99% Silicon Preferential Etch; Silicon 100 Etch; Preferential Silicon Etchant
bp ...................................................................... >240 °C n20
D .......................................................................... 1.484
4-Aminoanisole; 4-Methoxyaniline density ..................................... 1.001 g/mL, 25 °C
Etch rate ~80microns/hour at @ 100 °C. Etches cleanly with only a
mp ............................................................ 56 to 59 °C ait ......................................................................... 959 °F
bp ............................................................... 240-243 °C
deionized water rinse needed. Will not etch Au or Ta.
Ethylenediamine based - for < 100 > crystal orientation
689
Danger H300-H310-H330-H350-H373-H400 P201-
578
Danger H302-H312-H314-H317-H334 P261-P280-P305
P260-P264-P273-P280-P284
+ P351 + P338-P310
A88255-100G poly btl 100 g
AHB A, 0613, UNP EU
n Anisotropicsili n
7
Anisotropic Silicon <110> Etchant Warning H302-H312-H332 P280
Silicon Preferential Etch; Preferential Silicon Etchant; Silicon 110 Etch
Etch rate 1 mil/3 min at @ 100 °C. Etches cleanly with only a deionized 152765-5G glass btl 5g
water rinse needed. Will not etch Au or SiO2 152765-25G glass btl 25 g
Alkali based - for < 110 > crystal orientation - etches with vertical 9-Anthracenecarboxaldehyde, 97%
walls.
9-Anthraldehyde
667455-500ML poly btl 500 mL
[642‑31‑9] Beil. 7,IV,1738 C15H10O FW 206.24
A > o-Anisoyl chloride, see 2-Methoxybenzoyl chloride Page 1691
m-Anisoyl chloride, see 3-Methoxybenzoyl chloride Page 1691
mp .............................................................................................................................................................. 103 to 105 °C
p-Anisoyl chloride, see 4-Methoxybenzoyl chloride Page 1691
o-Anisyl alcohol, see 2-Methoxybenzyl alcohol Page 1691 278688-25G poly btl 25 g
p-Anisylchlorodiphenylmethane, see 4-Methoxytriphenylmethyl chloride
Page 1727 278688-100G poly btl 100 g
ANSA, see 8-Anilino-1-naphthalenesulfonic acid Page 190
9-Anthracenecarboxylic acid, 99%
Anthracene 9-Anthroic acid
[120‑12‑7] Merck 14,682; Beil. 5,IV,2281 C14H10 [723‑62‑6] Beil. 9,IV,2671 C15H10O2 FW 222.24
FW 178.23 mp .............................................................................................................................................................. 213 to 217 °C
λmax, ethanol ......................................................................................................................................... 254 nm, 0.1%
mp ...................................................... 210 to 215 °C vp .............................................. 1 mmHg (145 °C) A89405-5G poly btl 5g
bp ......................................................................... 340 °C ait ...................................................................... 1004 °F
vd ................................................................ 6.15 (vs air)
9,10-Anthracenediboronic acid bis(pinacol) ester, 97% 8
79
P338-P501
9,10-Bis(4,4,5,5-tetramethyl[1.3.2]dioxaborolan-2-yl)an- H3C CH3
 ReagentPlus®, 99% thracene H3C CH3
color .................................................................................................................................. blue-violet fluorescence [863992‑56‑7] C26H32B2O4 FW 430.15 O
B
O

141062-25G poly btl 25 g
141062-100G poly btl 100 g B
O O
 reagent grade, 97% H3C CH3
H3C CH3
A89200-100G poly btl 100 g
A89200-500G poly btl 500 g mp ............................................................................................................................................................................ >300 °C
solid
 sublimed grade, ≥99%
TGA/DSC Lot specific traces available upon request
LOH ....................................................................................................................... 0.5 wt. %, 155°C (typical, TGA) 9,10-Anthracenedicarbonitrile, 97%
694959-5G glass btl 5g 9,10-Dicyanoanthracene
694959-25G glass btl 25 g [1217‑45‑4] Beil. 9,IV,3660 C16H8N2 FW 228.25
Anthracene-d10 mp ............................................................................................................................................................................... 340 °C
[1719‑06‑8] C14D10 FW 188.29 459852-1G glass btl 1g
mp .............................................................................................................................................................. 210 to 215 °C > 9,10-Anthracenedicarboxylic acid, see Metal Organic Frameworks and
bp ................................................................................................................................................................................. 340 °C Linkers under Page 1673
 98 atom % D 9-Anthracenemethanol, 97%

9-(Hydroxymethyl)anthracene
79
P338
[1468‑95‑7] C15H12O FW 208.26
mp .............................................................................................................................................................. 162 to 164 °C
187240-10G poly btl 10 g
9-Anthraceneboronic acid 187240-50G poly btl 50 g
9-Anthrylboronic acid; 9-Anthracenylboronic acid HO OH > Anthracene-9-thiol, see 9-Mercaptoanthracene Page 1660
[100622‑34‑2] C14H11BO2 FW 222.05 B
9(10H)-Anthracenone, see Anthrone Page 194
1-(2-Anthracenyl)acetone, see 2-Acetylanthracene Page 33
9-Anthracenylboronic acid, see 9-Anthraceneboronic acid Page 192
mp .............................................................................................................................................................. 203 to 250 °C 9-Anthracenylmethyl acrylate, 98%
6
Danger H301 P301 + P310 [31645‑34‑8] C18H14O2 FW 262.30
Fluorescent monomer
684600-250MG glass btl 250 mg λmax ............................................................................................................................................................................ 251 nm
9-Anthracenecarbonitrile, 97% N-(9-Anthracenylmethyl)cinchonindinium chloride, 85%
9-Cyanoanthracene CN [199588‑80‑2] C34H33ClN2O FW 521.09
[1210‑12‑4] Beil. 9,I,304 C15H9N FW 203.24 mp .............................................................................................................................................................. 158 to 161 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 173 to 177 °C


AHB A, 0613, UNP EU
n Anthraquinonesu n
9-Anthracenylmethyl methacrylate, 95% Anthranilic acid, ≥98%

[31645‑35‑9] C19H16O2 FW 276.33 CH3 2-Aminobenzoic acid; 2-AA
O
CH2
[118‑92‑3] Merck 14,422; Beil. 14,IV,1004 2-(H2N)C6H4CO2H
O FW 137.14
Used for non-selective, efficient fluorescent labeling of glycans.
mp .............................................................................................................................................................. 144 to 148 °C
vd ........................................................................................................................................................................... 4.7 (vs air)
mp .................................................................................................................................................................... 80 to 85 °C
λmax ............................................................................................................................................................................. 249 nm
 reagent grade
A
7
Warning H319 P305 + P351 + P338
5
Danger H318 P280-P305 + P351 + P338
A89855-500G poly btl 500 g
Anthraflavic acid, 90%
2,6-Dihydroxyanthraquinone; Anthraflavine O
13
[84‑60‑6] Beil. 8,463 C14H8O4 FW 240.21 OH Anthranilic acid-ring- C6, 98% (CP) 8
HO 2-Aminobenzoic acid-13C6; 2-AA-13C6 O
13
O C6CH7NO2 FW 143.09 13
C
13 13
C C OH
mp ............................................................................................................................................................................ >320 °C
13C 13C
 technical grade 13
C NH2
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 144 to 148 °C
A89502-5G glass btl 5g  99 atom % 13C

> Anthraflavine, see Anthraflavic acid Page 193
7
9-Anthraldehyde, see 9-Anthracenecarboxaldehyde Page 192 Warning H315-H319-H335 P261-P305 + P351 + P338
9-Anthraldehyde oxime, predominantly syn, 99% 709530

[34810‑13‑4] Beil. 7,III,2528 C15H11NO FW 221.25 N OH > Anthranilic acid amide, see Anthranilamide Page 193
Anthranilonitrile, see 2-Aminobenzonitrile Page 93
Anthraquinone, 97%
[84‑65‑1] Merck 14,687; Beil. 7,IV,2556; O
mp .............................................................................................................................................................. 162 to 164 °C
7,781; Fieser 4,20 C14H8O2 FW 208.21
7
Warning H315-H319-H335 P261-P305 + P351 + P338
O
301612-10G poly btl 10 g
> 1-Anthramine, see 1-Aminoanthracene Page 90 mp ...................................................... 284 to 286 °C vd ............................................................. 7.16 (vs air)
bp ............................................................... 379-381 °C vp ............................................. 1 mmHg (190 °C)
Anthranil, 99%
7
2,1-Benzisoxazole
[271‑58‑9] Beil. 27,39 C7H5NO FW 119.12 O A90004-50G poly btl 50 g
N
A90004-250G poly btl 250 g
bp ..................................... 101-102 °C/15 mmHg n20 D .......................................................................... 1.584
density ..................................... 1.183 g/mL, 25 °C
Anthraquinone-2-carboxylic acid, 98%
9,10-Dihydro-9,10-dioxo-2-anthracenecarboxylic
7
Warning H302 O O
acid OH
[117‑78‑2] Beil. 10,835 C15H8O4 FW 252.22
144517-10G glass btl 10 g O
Anthranilamide, ≥98% mp .............................................................................................................................................................. 287 to 289 °C
Anthranilic acid amide; 2-Aminobenzamide; 2-AB 252727-1G glass btl 1g

[88‑68‑6] Beil. 14,IV,1010 2-(H2N)C6H4CONH2 FW 136.15 252727-5G glass btl 5g
Used for non-selective, efficient fluorescent labeling of glycans.
Anthraquinone-2-sulfonic acid sodium salt monohydrate, 97%
Slightly less sensitive than anthranilic acid (2-AA) for glycan labeling.
mp .............................................................................................................................................................. 111 to 113 °C 9,10-Dihydro-9,10-dioxo-2-anthracenesulfonic O O
Fluorescently labels glycans containing a free reducing terminus.1,2 acid sodium salt monohydrate; Sodium an- S ONa
fluorescence ....................................................................................................... λex 330 nm, λem 420 nm(lit.)

thraquinone-2-sulfonate O
• H 2O
Lit. cited: 1. Harvey, D.J., Electrospray mass spectrometry and fragmen- [153277‑35‑1] C14H7NaO5S FW 310.26
O
tation of N-linked carbohydrates derivatized at the reducing terminus. J. Am.
Soc. Mass Spectrom. 11, 900-15 (2000) water ........................................................................................................................................ 4.0-6.0% (Karl Fischer)
2. Bigge J.C., et al., Nonselective and efficient fluorescent labeling of glycans
7
Warning H315-H319-H335 P261-P305 + P351 + P338
using 2-amino benzamide and anthranilic acid. Anal. Biochem. 230, 229-238
(1995)
123242-100G poly btl 100 g
7
P338 123242-1KG poly btl 1 kg


AHB A, 0613, UNP EU
n Anthrarufin n
Anthrarufin, 85%
1,5-Dihydroxyanthraquinone O OH
Ion Standard Solutions
[117‑12‑4] Merck 14,689; Beil. 8,IV,3268 C14H8O4
FW 240.21 We offer a wide range of standards for
OH O
calibration of ICP-MS, ICP-OES, AAS and IC.
mp ................................................................................................................................................................. 279 °C (dec.)
vd ........................................................................................................................................................................... 8.3 (vs air)
sigma-aldrich.com/tracecert
A  technical grade
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Antimony(III) acetate, 99.99% trace metals basis
340014-100G glass btl 100 g [6923‑52‑0] (CH3CO2)3Sb FW 298.89
solid
> 9-Anthroic acid, see 9-Anthracenecarboxylic acid Page 192
mp .............................................................................................................................................................. 126 to 131 °C
density ................................................................................................................................................ 1.22 g/mL, 25 °C
Anthrone, 97%
79
9(10H)-Anthracenone O
[90‑44‑8] Merck 14,691; Beil. 6,IV,4930 C14H10O
483265-100G glass btl 100 g
FW 194.23
Antimony(III) butoxide solution
mp .............................................................................................................................................................. 154 to 157 °C [2155‑74‑0] Sb(OC4H9)3 FW 341.10
 ACS reagent Features and Benefits
Reagent used in formation studies of poly(ethylene terephthalate).1
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Lit. cited: 1. J. Polym. Sci., A: Polym. Chem. 27, 3535 (1989)
319899-25G poly btl 25 g  65 wt. % in toluene
319899-100G poly btl 100 g density ..................................... 1.225 g/mL, 25 °C vp ........................................ 1.1 mmHg (54.4 °C)
n20
D ................................................................................. 1.48
> 9-Anthrylboronic acid, see 9-Anthraceneboronic acid Page 192
25789
Danger H226-H302-H304-H315-H318-
(R)-(−)-1-(9-Anthryl)-2,2,2-trifluoroethanol, ≥98% H332-H335-H336-H361d-H373-H411
P261-P273-P280-P301 + P310-P305 + P351
(R)-(−)-α-(Trifluoromethyl)anthracene-9-methanol; (R)- HO CF3 + P338-P331
(−)-2,2,2-Trifluoro-1-(9-anthryl)ethanol 376922-50ML glass btl 50 mL
[53531‑34‑3] C16H11F3O FW 276.25 376922-250ML glass btl 250 mL
Antimony(III) chloride
mp .............................................................................................................................................................. 132 to 135 °C
Antimony trichloride
D −30°, c = 6.0 in chloroform
[α]25
ee (HPLC): 98% [10025‑91‑9] Merck 14,707; 14,708; Fieser 8,19 SbCl3 FW 228.12
mp ....................................................................... 73.4 °C vp ................................................ 1 mmHg (49 °C)
7
Warning H315-H319-H335 P261-P305 + P351 + P338 vd ................................................................... 7.9 (vs air)
59
Danger H314-H411 P273-P280-P305 + P351 + P338-P310
(S)-(+)-1-(9-Anthryl)-2,2,2-trifluoroethanol, ≥98%  ≥99.99% trace metals basis

(S)-(+)-α-(Trifluoromethyl)anthracene-9-methanol; (S)-(+)-2,2,2- crystalline
Trifluoro-1-(9-anthryl)ethanol 337374-10G glass btl 10 g
[60646‑30‑2] C16H11F3O FW 276.25
mp .............................................................................................................................................................. 132 to 135 °C  ACS reagent, ≥99.0%
insol. CHCl3 ............................................................................................................................................................ ≤0.05%
[α]25
sulfate (SO42-) .......................................... ≤0.005% Fe .................................................................. ≤0.002%
ee (HPLC): 98%
As ........................................................................ ≤0.02% K ....................................................................... ≤0.01%
7
Warning H315-H319-H335 P261-P305 + P351 + P338 Ca ..................................................................... ≤0.005% Na .................................................................... ≤0.02%
Cu ..................................................................... ≤0.001% Pb ................................................................. ≤0.005%
311375-100G glass btl 100 g
> Antifolan hydrate, see L-Amethopterin hydrate Page 88 311375-500G glass btl 500 g
Antimony  ReagentPlus®, 99%

[7440‑36‑0] Merck 14,692 Sb FW 121.76 215783-500G glass btl 500 g
resistance .................................................................................................................................................... 41.7 μΩ-cm 215783-2KG glass btl 2 kg
mp ........................................................................ 630 °C density .................................... 6.69 g/mL, 25 °C
bp ....................................................................... 1950 °C Antimony(V) chloride
Antimony pentachloride
 beads, 1-5 mm, low oxide, 99.999% trace metals basis [7647‑18‑9] Merck 14,695; Fieser 1,42; 5,18; 17,17; 4,21; 6,22; 7,12
452343-10G ampule 10 g SbCl5 FW 299.03
452343-50G ampule 50 g mp .......................................................................... 2.8 °C vd ......................................................... >10.2 (vs air)
bp .................................................. 92 °C/30 mmHg vp .................................................... 0.13 psi (55 °C)
 powder, −100 mesh, 99.5% trace metals basis density ........................................ 2.36 g/mL, 25 °C
9
H411 P273
59
Danger H314-H411 P273-P280-P305 + P351 + P338-P310
266329-250G glass btl 250 g

 anhydrous, ≥99.999% trace metals basis
451673-1G ampule 1g
451673-10G ampule 10 g

AHB A, 0613, UNP EU
n Antimonysulfate n
 ≥99.99% trace metals basis Antimony(III) oxide

338877-5G glass btl 5g [1309‑64‑4] Merck 14,711 Sb2O3 FW 291.52
338877-25G glass btl 25 g mp ............................................................................................................................................................................... 655 °C
bp .............................................................................................................................................................................. 1550 °C
 99%
8
Warning H351 P281
215171-250G glass btl 250 g
A
215171-1KG glass btl 1 kg powder
Antimony(V) chloride solution 202649-10G poly btl 10 g
[7647‑18‑9] Merck 14,695 SbCl5 FW 299.03 202649-50G poly btl 50 g
 1.0 M in methylene chloride  99.99% trace metals basis

density ............................................................................................................................................. 1.442 g/mL, 25 °C powder
249858-100ML Sure/Seal™ 100 mL 379255-50G poly btl 50 g
Antimony(III) ethoxide  nanopowder, particle size <250 nm (TEM), ≥99.9% trace metals
[10433‑06‑4] Fieser 17,204 Sb(OC2H5)3 FW 256.94 basis
bulk density .............................................................................................................................................. 0.5‑0.6 g/mL
density ............................................................................................................................................. 1.513 g/mL, 25 °C
spec. surface area ................................................................................................................ 15.6 m2/g (typical)
n20
D ...................................................................................................................................................................................... 1.495
279
Warning H226-H302-H332-H411 P273
637173-100G glass btl 100 g
Antimony(III) fluoride, 99.8% trace metals basis  powder, 5 μm, ReagentPlus®, 99%
Antimony trifluoride 230898-100G poly btl 100 g
[7783‑56‑4] Merck 14,709; Fieser 6,553; 5,526 SbF3 FW 178.76 230898-1KG poly btl 1 kg
mp ................................................................................................................................................................. 235 °C (dec.)
 ≥99%
density ................................................................................................................................................ 4.38 g/mL, 25 °C chloride (Cl-) ................................... ≤500 mg/kg Fe ........................................................... ≤20 mg/kg
 powder sulfate (SO42-) ................................ ≤100 mg/kg Na ....................................................... ≤100 mg/kg
Contains lead As ............................................................... ≤20 mg/kg Pb ....................................................... ≤100 mg/kg
Ca ........................................................... ≤100 mg/kg Zn .......................................................... ≤20 mg/kg
69
Danger H301-H311-H331-H411 P261-P273-P280-P301 + Cu ................................................................. ≤3 mg/kg
P310-P311
381292-100G poly btl 100 g 11115-500G-R poly btl 500 g
381292-500G poly btl 500 g
Antimony(V) oxide, 99.995% trace metals basis
Antimony(V) fluoride Antimony pentoxide
Antimony pentafluoride [1314‑60‑9] Merck 14,698 Sb2O5 FW 323.52
[7783‑70‑2] Merck 14,696; Fieser 9,20; 6,23; 5,19 SbF5 FW 216.75 mp ................................................................................................................................................................ 380 °C (dec.)
mp .............................................................................. 7 °C vd ................................................................ 2.2 (vs air) density ................................................................................................................................................ 3.78 g/mL, 25 °C
bp ............................................................... 148-150 °C vp .............................................. 10 mmHg (25 °C)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
density ..................................... 2.993 g/mL, 25 °C
79
Warning H302-H332-H411 P273 255998-10G poly btl 10 g
255998-50G poly btl 50 g
> Antimony potassium tartrate, see Potassium antimony(III) tartrate hydrate
481017-5G 5g Page 2158
 99% Antimony(III) propoxide, 98%

175129-5G poly btl 5g [4292‑34‑6] Sb(OC3H7)3 FW 299.02
175129-25G poly btl 25 g
Antimony(III) iodide, 98% Antimony(III) selenide, 99.99% trace metals basis
Antimony triiodide [1315‑05‑5] Merck 14,712 Sb2Se3 FW 480.40
[7790‑44‑5] Merck 14,710 SbI3 FW 502.47 Used to prepare the large Zintl ion (Sb12Se20)4-.1
mp ........................................................................ 170 °C density .................................... 4.92 g/mL, 25 °C
bp ......................................................................... 401 °C
solid
Lit. cited: 1. Martin, T.M. et al., Inorg. Chem. 33, 1587 (1994)
crystalline
6
79
Warning H302-H332-H411 P273 P305 + P351 + P338-P311
> Antimony sesquitelluride, see Antimony(III) telluride Page 196
Antimony(III) isopropoxide, 98%
Antimony(III) sulfate, ≥95.0%
[18770‑47‑3] Sb(OCH(CH3)2)3 FW 299.02
liquid [7446‑32‑4] Merck 14,704 Sb2(SO4)3 FW 531.71
79
bp .............................................................................................................................................. 53-54 °C/0.25 mmHg Warning H302-H332-H411 P273
density ............................................................................................................................................. 1.307 g/mL, 25 °C
10783-10G poly btl 10 g
7
Warning H315-H319-H335 P261-P305 + P351 + P338
10783-50G poly btl 50 g
AHB A, 0613, UNP EU
n Antimonysulfide n
Antimony(III) sulfide > Antiscorbutic factor, see L-Ascorbic acid Page 200
AOT, see Dioctyl sulfosuccinate sodium salt Page 1131
[1345‑04‑6] Merck 14,713 Sb2S3 FW 339.72 2-AP, see 2-Aminopyridine Page 163
mp ................................................................................................................................................................................ 550 °C 3-AP, see 3-Aminopyrazole Page 162
6-APA, see (+)-6-Aminopenicillanic acid Page 152
density ................................................................................................................................................ 4.64 g/mL, 25 °C
P-APAC, see 4-Ethynylaniline Page 1278
79
Warning H302-H332-H411 P273 APAP, see 4-Acetamidophenol Page 18
2-APB, see 2-Aminoethyl diphenylborinate Page 121
 99.995% trace metals basis Apiezon® M

A 229466-5G
229466-50G
poly btl
poly btl
5g
50 g  grease
all pressure lubricant; similar to Apiezon L, but higher wax content
 powder and higher vapor pressure
244562-100G poly btl 100 g 10802-1EA 100 g
244562-500G poly btl 500 g
Apiezon® N
Antimony(V) sulfide, ≥60% Sb basis
 grease (consistency similar to rubber)
Antimony pentasulfide polymer hydrocarbon with higher molecular weight ...................................................... contains
[1315‑04‑4] Merck 14,697 Sb2S5 FW 403.85
10803-1EA 25 g
 technical
Apiezon® T
279
Danger H228-H302-H332-H411 P210-P273
[9064‑45‑3]
11133-500G-R poly btl 500 g mp ............................................................................................................................................................................... 125 °C
density ............................................................................................................................................. 0.912 g/mL, 25 °C
> Antimony telluride, see Antimony(III) telluride Page 196
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Antimony(III) telluride, 99.96% trace metals basis 8
Antimony sesquitelluride; Antimony telluride; Diantimony tritelluride 380873-25G 25 g
[1327‑50‑0] Sb2Te3 FW 626.32 > APMA, see 4-Aminophenylmercuric acetate Page 155
density ................................................................................................................................................... 6.5 g/mL, 25 °C Apocynin, see 4′-Hydroxy-3′-methoxyacetophenone Page 1491
 powder, −325 mesh R-(−)-Apomorphine hydrochloride hemihydrate, ≥98.5%

mp ................................................................................................................................................................................ 629 °C
[41372‑20‑7] Merck 14,746 C17H17NO2 · HCl · 1/2H2O FW 312.79
79
mp .............................................................................................................................................................. 285 to 287 °C
733490-1G glass btl 1g  calcined

Nonselective dopamine agonist; causes nausea and emesis.
Antimony tin oxide, ≥99.5% trace metals basis soluble in ...................................................................................................................................... H2O (~10 mg/mL)
ATO color .......................................................................................................................................................... white to gray
6
Merck 14,8778; 14,698 Danger H301 P301 + P310
 nanopowder, particle size <50 nm

composition A4393-100MG glass btl 100 mg
antimony pentoxide 7‑11% A4393-250MG glass btl 250 mg
tin(IV) oxide 89‑93% A4393-1G glass btl 1g
surface area ....................................................................................................................................................... 47 m2/g A4393-5G glass btl 5g
7
Warning H315-H319 P305 + P351 + P338 > 3APS, see 3-Amino-1-propanesulfonic acid Page 159
APTES, see (3-Aminopropyl)triethoxysilane Page 162
549541-5G glass btl 5g 3-AQ, see 3-Aminoquinoline Page 165
549541-25G glass btl 25 g (+)-Arabinogalactan

Antipyrine Polyarabinogalactan
2,3-Dimethyl-1-phenyl-3-pyrazolin-5-one; Phenazone CH3
[9036‑66‑2]
[60‑80‑0] Merck 14,716; Beil. 24,IV,75 C11H12N2O Dietary fiber that enhances immune system function by stimulating
N CH natural killer (NK) cell activity.
FW 188.23 O N 3
mp ............................................................................................................................................................. >200 °C (dec.)
 from larch wood

mp .............................................................................................................................................................. 109 to 111 °C
water .............................................................................................................................................................................. ≤15%
7
P338 10830-25G glass btl 25 g
10830-100G glass btl 100 g
A5882-100G poly btl 100 g D-(−)-Arabinose, ≥98%
A5882-500G poly btl 500 g [10323‑20‑3] Merck 14,761; Beil. 1,IV,4215 C5H10O5 O
4-Antipyrinecarboxaldehyde, 97% FW 150.13 HO OH
HO
Antipyraldehyde; 2,3-Dimethyl-5-oxo-1-phenyl-3-pyrazoline-4- OH
carboxaldehyde
mp .............................................................................................................................................................. 162 to 164 °C
[950‑81‑2] Beil. 24,IV,1317 C12H12N2O2 FW 216.24
mp .............................................................................................................................................................. 162 to 165 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338

AHB A, 0613, UNP EU
n Arginine n
L-(+)-Arabinose, 98% > Arachidic acid-20,20,20-d3, see Eicosanoic acid-20,20,20-d3 Page 1183
Arachidic acid methyl ester, see Methyl arachidate Page 1738
[5328‑37‑0] Merck 14,761; Beil. 1,IV,4217; 31,32 C5H10O5 OH Arachidinic acid-20,20,20-d3, see Eicosanoic acid-20,20,20-d3 Page 1183
FW 150.13 O
OH OH
Arachidonic acid
OH
Eicosa-5Z,8Z,11Z,14Z-tetraenoic acid; cis,cis,cis,cis-5,8,11,14-Eicosatetra-
mp .............................................................................................................................................................. 160 to 163 °C enoic acid
[α]20
D +103°, c = 1 in H2O [506‑32‑1] Merck 14,765; Beil. 2,H,469
A
A91906-1G-A glass btl 1g CH3(CH2)4(CH=CHCH2)4CH2CH2CO2H FW 304.47
Arachidonic acid and its metabolites play important roles in a variety
of biological processes, including signal transduction, smooth muscle
A91906-100G-A poly btl 100 g
contraction, chemotaxis, cell proliferation and differentiation, and
13
D-Arabinose-1- C apoptosis.
13 mp ....................................................................... −49 °C density ................................. 0.922 g/mL, 25 °C
[70849‑23‑9] CC4H10O5 FW 151.12 bp ................................ 169-171 °C/0.15 mmHg n20 D ....................................................................... 1.4872
 99 atom % 13
C EUH019
 from porcine liver, ≥99% (GC), liquid
D-(+)-Arabitol, ≥99% soluble in ............................................................................................................................. ethanol (≥10 mg/mL)
color ....................................................................................................... clear colorless to very faintly yellow
[488‑82‑4] Beil. 1,IV,2832 C5H12O5 FW 152.15 CH2OH ship: dry ice store at: −20°C
HO H
H OH A9673-10MG ampule 10 mg
H OH A9673-50MG ampule 50 mg
CH2OH
A9673-100MG ampule 100 mg
A9673-500MG ampule 500 mg
Used to produce xylitol via biotransformation.1
A9673-1G ampule 1g
sweetness ............................................................................................................................................... 0.7 × sucrose
Lit. cited: 1. Suzuki, S. et al., Novel enzymatic method for the production of  >95.0% (GC)
xylitol from D-arabitol by Gluconobacter oxydans. Biosci. Biotechnol. ship: dry ice store at: −20°C
Biochem. 66, 2614-2620 (2002)
A3381-250G poly btl 250 g D-Arginine, ≥98% (TLC)
L-(−)-Arabitol, ≥98% (R)-2-Amino-5-guanidinopentanoic acid

[157‑06‑2] Beil. 4,IV,2648 H2NC(=NH)NH(CH2)3CH(NH2)CO2H
L-Arabinitol CH2OH FW 174.20
[7643‑75‑6] Beil. 1,IV,2832 C5H12O5 FW 152.15 H OH
mp ................................................................................................................................................................ 226 °C (dec.)
HO H
7
HO H Warning H319 P305 + P351 + P338
CH2OH

mp .............................................................................................................................................................. 101 to 104 °C
A3506-100G poly btl 100 g L-Arginine, ≥98% (TLC)
> Arachic acid-20,20,20-d3, see Eicosanoic acid-20,20,20-d3 Page 1183 (S)-2-Amino-5-guanidinopentanoic acid
[74‑79‑3] Merck 14,780; Beil. 4,IV,2648
Arachidic acid H2NC(=NH)NH(CH2)3CH(NH2)CO2H FW 174.20
Arachic acid; Arachidinic acid; Eicosanoic acid Substrate of nitric oxide synthase, which is converted to citrulline and
[506‑30‑9] Merck 14,764; Beil. 2,IV,1275 CH3(CH2)18COOH nitric oxide (NO). Induces insulin release by a nitric oxide-dependent
FW 312.53 mechanism.
mp ................................................................................................................................................................ 222 °C (dec.)
mp .................................................................................................................................................................... 74 to 76 °C
 ≥99%  reagent grade, powder

Arachidic acid is a saturated fatty acid with a 20 carbon chain.
color .............................................................................................................................................................................. white
Arachidic acid occurs naturally in fish and vegetable oils. Diets rich in
saturated fats like arachidic acid are associated with increased levels A5006-100G poly btl 100 g
of serum low density lipoproteins. A5006-500G poly btl 500 g
store at: −20°C A5006-1KG poly btl 1 kg
 synthetic, ≥99.0% (GC)


AHB A, 0613, UNP EU
n Arginine n
L-Arginine monohydrochloride, ≥98% (TLC) L-Arginine methyl ester dihydrochloride, ≥98.0% (AT)
S-(+)-2-Amino-5-[(aminoiminomethyl)amino]pentanoic acid mono- [26340‑89‑6] Beil. 4,IV,2640 HN=C(NH2)NH(CH2)3CH(NH2)COOCH3 ·
hydrochloride 2HCl FW 261.15
[1119‑34‑2] Merck 14,780 C6H14N4O2 · HCl FW 210.66 [α]20
D +21±1°, c = 2.5 in methanol
Substrate of nitric oxide synthase, which is converted to citrulline and mp ............................................................................................................................................................. ~190 °C (dec.)
nitric oxide (NO). Induces insulin release by a nitric oxide-dependent 11030-5G glass btl 5g
mechanism.
Argininosuccinic acid disodium salt hydrate, ≥80%
A  reagent grade, powder
O
O OH
NH O
color .............................................................................................................................................................................. white
NaO N N ONa • xH2O
7
Warning H315-H319 P305 + P351 + P338 H H
NH2
A5131-10G poly btl 10 g C10H16N4Na2O6 · xH2O FW 334.24 (Anh)

A5131-25G poly btl 25 g store at: −20°C
> H-Arg(MTR)-OH, see Nω-(4-Methoxy-2,3,6-trimethylbenzenesulfonyl)-L-
DL-Arginine, ≥97.0% (NT) arginine Page 1726
(±)-2-Amino-5-guanidinopentanoic acid
Argon
[7200‑25‑1] Beil. 4,III,1359 HN=C(NH2)NH(CH2)3CH(NH2)COOH
FW 174.20 [7440‑37‑1] Merck 14,783 Ar FW 39.95
mp .................................................................. -189.2 °C vd ............................................. 1.38 (21 °C, vs air)
7
Warning H319 P305 + P351 + P338 bp .................................................................... -185.7 °C
11020-5G glass btl 5g  ≥99.998%

11020-25G glass btl 25 g filling pressure at 15°C; 11 bar, content (15°C, 1 bar) 11 L
15 Sales restrictions may apply
L-Arginine- N4 hydrochloride, 97% (CP)
00752-1EA 1L
H215NC(15NH)15NH(CH2)3C(15NH2)CO2H · HCl FW 214.64
mp ............................................................................................................................................... 226 to 230 °C (dec.)  ≥99.998%
Brass control valve Z146943 or either of brass regulators Z146706 and
 99 atom % 15N
Z146714 is recommended.
[α]20
D +22°, c = 12 in 10% HCl
oxygen .................................................................................................................................................................... ≤3 ppm
water ........................................................................................................................................................................ ≤3 ppm
13
L-Arginine- C6 hydrochloride, 95% (CP)
H-Arg(Pbf)-HMPB-ChemMatrix® resin 8
H2N13C(NH)NH13CH2(13CH2)213CH(NH2)13CO2H · HCl FW 216.62
mp ............................................................................................................................................... 226 to 230 °C (dec.) O
O OCH3
N NH2 O CH3
 99 atom % 13C H
O
H
N
H
N S
[α]20
D +22°, c = 12 in 10% HCl O
CH3
O NH CH3
mol wt 216.51, atom % calculation H3C O
CH3
13 15
L-Arginine- C6, N4 hydrochloride, 95% (CP) 4-{3-Methoxy-4-{[Nω-(2,2,4,6,7-pentamethyldihydrobenzofuran-5-
H215N13C(15NH)15NH(13CH2)313CH(15NH2)13CO2H · HCl FW 220.59 sulfonyl)-L-arginyloxy]methyl}phenoxy}butyric acid, polymer-bound to
mp ............................................................................................................................................... 226 to 230 °C (dec.)
ChemMatrix® resin
 99 atom % 13C; 99 atom % 15N, 97% (L)  35-100 mesh (wet sieved), loading: 0.20-0.45 mmol/g
[α]20
D +22°, c = 12 in 10% HCl
mol wt 220.40, atom % calculation 727849-5G glass btl 5g
composition
Arkopal® N 100
L-isomer 97%
608033
4-Nonylphenyl-polyethylene glycol
[9016‑45‑9] O
OH
15
L-Arginine-guanidineimino- N2 hydrochloride n
C9H19
H215NC(15NH)NH(CH2)3C(NH2)CO2H · HCl FW 212.65
mp ............................................................................................................................................... 226 to 230 °C (dec.) average mol wt 680
cloud point ................................................................................................................................................... 45 ‑ 50 °C
 98 atom % 15N
CMC ............................................................................................................................................ 0.059 mM (20‑25°C)
[α]20
D +22°, c = 12 in 10% HCl
viscosity 350-450 mPa.s (20 °C)
water ............................................................................................................................................................................. ≤1.0%
609080-1G glass btl 1g density ................................................................................................................................................ 1.06 g/mL, 20 °C
579
Danger H302-H318-H335-H400 P261-P273-P280-P305
+ P351 + P338

AHB A, 0613, UNP EU
n Arsenicoxide n
> Armstrong’s acid, see 1,5-Naphthalenedisulfonic acid tetrahydrate Arsenazo III
Page 1884
(−)-allo-Aromadendrene, see (−)-Alloaromadendrene Page 66 2,7-Bis(2-arsonophenylazo)chromotropic acid; 2,2′-(1,8-Dihydroxy-3,6-
disulfonaphthylene-2,7-bisazo)bisbenzenearsonic acid
(+)-Aromadendrene, ≥97.0% (GC, sum of enantiomers) [1668‑00‑4] Beil. 16,IV,1194 (HO)2C10H2(SO3H)2(N=NC6H4AsO3H2)2
(1R,2S,8R,11R)-7-Methylene-3,3,11-trimethyltricyclo CH3
FW 776.37
H3C
[6.3.0.02.4]undecane H
H
CH3 mp ............................................................................................................................................................................ >320 °C
[489‑39‑4] Beil. 5,IV,1187 C15H24 FW 204.35 H Suitable for the determination of calcium. (per Clin. Chem. Vol 39,
H
A
1608-1612 (1993))
H2C λmax ............................................................................................................................................................................ 530 nm
Ca .................................................................................................................................................................................... <0.1%
bp ....................................................................................................................................................................... 261-263 °C
69
Danger H301-H331-H410 P261-P273-P301 + P310-P311-P501
density ............................................................................................................................................. 0.912 g/mL, 20 °C
[α]20
D +12±1°, neat
Chiral building block1,2
n20
D ...................................................................................................................................................................................... 1.497
Lit. cited: 1. C.G.J.M. Seelen et al., Tetrahedron 46, 7237 (1990) A92775-10G glass btl 10 g
2. H.J.M. Gijsen et al., Tetrahedron 50, 4745 (1994) Arsenic
store at: 2-8°C
[7440‑38‑2] Merck 14,794 As FW 74.92
resistivity ..................................................................................................................................................... 33.3 μΩ-cm
Aromadendrene oxide 2, ≥95.0% mp ........................................................................ 817 °C density ................................. 5.727 g/mL, 25 °C
bp ......................................................................... 613 °C
[85710‑39‑0] C15H24O FW 220.35
69
> ARPYPHOS, see 2-(Diphenylphosphino)-6-(2,4,6-triphenylphenyl)pyridine  pieces, 99.999% trace metals basis

Page 1152
Arquad® 2HT-75
 powder, ≥99.997% trace metals basis
Di(hydrogenated tallow)dimethylammo- H 3C CH3 267961-10G glass btl 10 g
nium chloride; Quaternium-18; O N O Cl
Dimethyldioctadecylammonium chloride, H 3C O O CH3
mixture of homologs n n
[61789‑80‑8] Ion Standard Solutions

Consists mainly of C18 and C16
water ............................................................................................................................................................................. 8-12% We offer a wide range of standards for
pH .......................................................................................................................... 6-9, 5% isopropanol/water 1:1 calibration of ICP-MS, ICP-OES, AAS and IC.
259
Danger H226-H318-H400 P273-P280-P305 + P351 +
P338
64402-250G-F poly btl 250 g
o-Arsanilic acid, 98%

2-Aminobenzenearsonic acid Arsenic(III) chloride, 99.99% trace metals basis
[2045‑00‑3] Beil. 16,I,463 H2NC6H4AsO3H2 FW 217.05 [7784‑34‑1] Merck 14,801 AsCl3 FW 181.28
mp .............................................................................................................................................................. 154 to 155 °C mp ....................................................................... −16 °C density .................................... 2.15 g/mL, 25 °C
bp ..................................................................... 130.2 °C
69
69
p-Arsanilic acid
4-Aminophenylarsonic acid; 4-Aminobenzenearsonic acid; OH
4-Arsanilic acid O As OH Arsenic(III) iodide
[98‑50‑0] Merck 14,792; Beil. 16,IV,1105 C6H8AsNO3 [7784‑45‑4] Merck 14,803 AsI3 FW 455.64
FW 217.05 density ................................................................................................................................................ 4.69 g/mL, 25 °C
68
NH2 Danger H302-H330-H334 P260-P284-P310
mp ............................................................................................................................................................................ ≥300 °C 401145-5G glass btl 5g
69
Danger H301-H331-H410 P261-P273-P301 + P310-P311-P501 401145-25G glass btl 25 g
A9258-100G poly btl 100 g Arsenic(III) oxide

Arsenous acid; Arsenic trioxide
> 4-Arsanilic acid, see p-Arsanilic acid Page 199
[1327‑53‑3] Merck 14,804 As2O3 FW 197.84
5689
Danger H300-H314-H350-H410

powder
P201-P264-P273-P280-P305 + P351 + P338-P310
202673-25G poly btl 25 g
AHB A, 0613, UNP EU
n Arsenicoxide n
Arsenic(III) oxide (continued) Artemisinin, 98%
Arteannuin; Qinghaosu
 ACS reagent (primary standard) [63968‑64‑9] Merck 14,817; Beil. 19,11,690
H 3C
H H
powder C15H22O5 FW 282.33 O
CH3
99.95-100.05% O
OH O O
solubility (≤0.01% in dilute HCl) ........................................................................................................ insoluble H 3C
ign. residue .................................................. ≤0.02% Fe ................................................................... ≤5 ppm
S2- ........................... passes test (lim. ~0.001%) Pb ................................................................. ≤0.002% mp .............................................................................................................................................................. 156 to 157 °C
A
chloride (Cl-) ............................................. ≤0.005% Sb .................................................................... ≤0.05%
[α]20
D +76°, c = 0.5 in methanol
P201-P264-P273-P280-P301 + P310-P305 + P351 + P338 361593-100MG glass btl 100 mg
311383-125G glass btl 125 g
> Arzene, see Phenylarsine oxide Page 2022
 ReagentPlus®, ≥99.0% 5-AS, see 5-Aminosalicylic acid Page 166
ASA, see Acetylsalicylic acid Page 45
Very potent agent against acute promyelocytic leukemia (APL). Asaronaldehyde, see 2,4,5-Trimethoxybenzaldehyde Page 2526
Causes skin, lung and bladder cancer.
P201-P264-P273-P280-P305 + P351 + P338-P310 α-Asarone, 98%
A1010-25G glass btl 25 g trans-1,2,4-Trimethoxy-5-(1-propenyl)benzene; trans-1-Propenyl-2,4,5-
A1010-100G glass btl 100 g trimethoxybenzene
A1010-250G glass btl 250 g [2883‑98‑9] Beil. 6,IV,7476 (CH3O)3C6H2CH=CHCH3 FW 208.25
A1010-1KG glass btl 1 kg mp ................................................................................................................................................................... 57 to 61 °C
bp ................................................................................................................................................................................. 296 °C
Arsenic(V) oxide, 99%
7
Warning H302
[1303‑28‑2] Merck 14,798 As2O5 FW 229.84
mp ............................................................................................................................................................................ >300 °C 231282-1G glass btl 1g
689
Danger H301-H331-H350-H410 P201-P261-P273-P301
+ P310-P311-P501 > β-Asarone, see cis-2,4,5-Trimethoxy-1-propenylbenzene Page 2529
Asaronic acid, see 2,4,5-Trimethoxybenzoic acid Page 2526
483257
Ascarite®
Arsenic(V) oxide hydrate
[1310‑73‑2] Merck 14,9961; 14,8627; Fieser 4,21
[12044‑50‑7] As2O5 · xH2O FW 229.84 (Anh)
5
Danger H314 P280-P305 + P351 + P338-P310
density ................................................................................................................................................ 4.32 g/mL, 25 °C
689
Danger H301-H331-H350-H410 P201-P261-P273-P301
+ P310-P311-P501  Sodium hydroxide-coated silica, 8-20 mesh
223913-100G poly btl 100 g
 ≥99.99%
composition 223913-500G poly btl 500 g
Degree of hydration 2‑5  Sodium hydroxide-coated silica, 20-30 mesh
363456-25G ampule 25 g
223921-100G poly btl 100 g
 98% 223921-500G poly btl 500 g
powder L-Ascorbic acid
composition
Degree of hydration ~3 Antiscorbutic factor; L-Threoascorbic acid; Vitamin C HO OH
[50‑81‑7] Merck 14,830; Beil. 18,V,5,26 C6H8O6 H
255459-100G glass btl 100 g
FW 176.12 HO O O
Arsenic(II) sulfide, 95% OH
[1303‑32‑8] Merck 13,804 As2S2 FW 213.97 mp ............................................................................................................................................... 190 to 194 °C (dec.)
69
[α]25
D +20.5 to +21.5° in H2O
519111-25G poly btl 25 g ign. residue ..................................................... <0.1% heavy metals (as Pb) ..................... ≤0.002%
Fe ..................................................................... ≤0.001%
Arsenic(V) sulfide, 99.99%
[1303‑34‑0] Merck 14,797 As2S5 FW 310.17 255564-5G glass btl 5g
mp ............................................................................................................................................................................ >300 °C 255564-100G poly btl 100 g
255564-500G poly btl 500 g
69
 99%
519103-25G 25 g [α]25
D +23.6°, c = 1 in H2O
Arsenobetaine, ≥95.0% (NMR) A92902-25G poly btl 25 g
2-(Trimethylarsonio)acetate A92902-100G poly btl 100 g
CH3 O
[64436‑13‑1] C5H11AsO2 FW 178.06 H3C
As+
A92902-500G poly btl 500 g
O-
H3C A92902-2KG poly drum 2 kg
> Ascorbic acid 6-palmitate, see 6-O-Palmitoyl-L-ascorbic acid Page 1976

 purum p.a. L-Ascorbyl palmitate, see 6-O-Palmitoyl-L-ascorbic acid Page 1976
69

AHB A, 0613, UNP EU
n Asparticacid n
15
Asiatic acid L-Asparagine- N2,d8, 98% (CP)
[464‑92‑6] C30H48O5 FW 488.70 D215NCOCD2CD(15ND2)CO2D FW 142.15
mp .............................................................................................................................................................. 325 to 330 °C mp ................................................................................................................................................................ 232 °C (dec.)
546712-500MG glass btl 500 mg  98 atom % 15N; 98 atom % D
D-Asparagine, 99% mol wt 141.95, atom % calculation
(R)-2-Aminosuccinic acid 4-amide; (R)-2-Aminosuccinamic acid; D-
13
A
Aspartic acid 4-amide L-Asparagine- C4 monohydrate, 95% (CP)
[2058‑58‑4] Merck 14,837; Beil. 4,IV,3004 H2NCOCH2CH(NH2)CO2H H2N13CO13CH213CH(NH2)13CO2H · H2O FW 154.10
FW 132.12 [α]25
D +31.5°, c = 1 in 1 M HCl
mp ................................................................................................................................................................. 280 °C (dec.) mp .............................................................................................................................................................. 233 to 235 °C
D −35°, c = 5 in 5 M HCl
[α]20
 98 atom % 13
C
D-Asparagine monohydrate, ≥99% (TLC) 13
L-Asparagine-4- C monohydrate
(D)-Aspartic acid 4-amide; (R)-2-Aminosuccinic acid 4-amide; (R)-(−)-2-
Aminosuccinamic acid [286437‑12‑5] H2N13COCH2CH(NH2)CO2H · H2O FW 151.13
[5794‑24‑1] Merck 14,837; Beil. 4,IV,3004 NH2COCH2CH(NH2)COOH ·  99 atom % 13
C
H2O FW 150.13 579866 Full product information at Aldrich.com
mp ................................................................................................................................................................. 275 °C (dec.)
13 15
L-Asparagine- C4, N2, 95% (CP)
H215N13CO13CH213CH(15NH2)13CO2H FW 138.08
L-Asparagine, ≥98% (TLC) mp ................................................................................................................................................................ 232 °C (dec.)
L-Asparticacid 4-amide; (S)-2-Aminosuccinic acid 4-amide
 98 atom % 13C; 98 atom % 15N
[70‑47‑3] Merck 14,837; Beil. 4,IV,3005 H2NCOCH2CH(NH2)CO2H
FW 132.12
store at: −20°C
mp ................................................................................................................................................................. 235 °C (dec.)
13 15
A0884-25G poly btl 25 g L-Asparagine- C4, N2,d8, 95% (CP)
A0884-100G poly btl 100 g D215N13CO13CD213CD(15ND2)13CO2D FW 146.12
 98 atom % 13
C; 98 atom % 15
N; 98 atom % D
L-Asparagine monohydrate, ≥99% (TLC)
L-Asparagine (amide-15N) monohydrate
(S)-2-Aminosuccinic acid 4-amide; L-Aspartic acid 4-amide; (S)-(+)-2-
[204451‑47‑8] H215NCOCH2CH(NH2)CO2H · H2O FW 151.13
Aminosuccinamic acid
[5794‑13‑8] Merck 14,837; Beil. 4,IV,3005 NH2COCH2CH(NH2)COOH ·  98 atom % 15
N
H2O FW 150.13 485896 Full product information at Aldrich.com
mp .............................................................................................................................................................. 233 to 235 °C
L-Asparagine tert-butyl ester hydrochloride, ≥98.0% (TLC)
[63094‑81‑5] NH2COCH2CH(NH2)COOC(CH3)3 · HCl FW 224.69
[α]D +11.5±1.0°, c = 1 in methanol
DL-Asparagine monohydrate, ≥99.0% (NT) 75136-1G poly tube 1g
(±)-2-Aminosuccinic acid 4-amide; DL-Aspartic acid 4-amide
> Aspartame, see Asp-Phe methyl ester Page 203
[3130‑87‑8] Beil. 4,IV,3005 NH2COCH2CH(NH2)COOH · H2O
FW 150.13 D-Aspartic acid, 99%
mp ................................................................................................................................................................. 220 °C (dec.)
(R)-2-Aminosuccinic acid; (R)-(−)-Aminosuccinic acid
11180-100G glass btl 100 g [1783‑96‑6] Merck 14,840; Beil. 4,IV,2998 HO2CCH2CH(NH2)CO2H
11180-500G glass btl 500 g FW 133.10
15 mp ............................................................................................................................................................................ >300 °C
L-Asparagine- N2, 98% (CP)
D −24°, c = 2.3 in 6 M HCl
[α]20
[748757‑99‑5] H215NCOCH2CH(15NH2)CO2H FW 134.10 ee (GLC): 98%
mp ................................................................................................................................................................. 232 °C (dec.)
219096-25G poly btl 25 g
 98 atom % 15N 219096-100G poly btl 100 g
L-Aspartic acid, ≥98%
(S)-(+)-Aminosuccinic acid; (S)-Aminobutanedioic acid
15
L-Asparagine- N2 monohydrate, 98% (CP) [56‑84‑8] Merck 14,840; Beil. 4,IV,2998 HO2CCH2CH(NH2)CO2H
[287484‑32‑6] H215NCOCH2CH(15NH2)CO2H·H2O FW 150.13 FW 133.10
mp .............................................................................................................................................................. 233 to 235 °C Principal neurotransmitter for fast synaptic excitation.
mp ............................................................................................................................................................. >300 °C (dec.)
 98 atom % 15N
[α]20
D +25°, c = 8 in 5 M HCl
[α]20
D +31.5°, c = 1 in 1 M HCl
ee (GLC): 98%
7
Warning H319 P305 + P351 + P338
A93100-2.5G glass btl 2.5 g

A93100-100G poly btl 100 g
A93100-500G poly btl 500 g

AHB A, 0613, UNP EU
n Asparticacid n
acid potassium Magnesium salt, ≥95.0% (NT, calc.

L-Aspartic DL-Aspartic acid-2-13C,15N
based on dry substance)
[98532‑13‑9] HO2CCH213CH(15NH2)CO2H FW 135.09
Potassium magnesium L-aspartate mp ............................................................................................................................................................. >300 °C (dec.)
[67528‑13‑6] [HOOCCH(NH2)CH2COO]4K2Mg FW 630.88
 99 atom % 13C; 98 atom % 15N
 powder mol wt 135.07, atom % calculation
[α]20
D +20±1°, c = 2 in 6 M HCl 492353-250MG glass btl 250 mg
magnesium salt ........................................................................................................................................... ~50% (KT)
A
potassium salt .......................................................................................................................................... ~50% (AAS) L-Aspartic acid-2,3,3-d3
LOD ................................................................................................................................................................. ~5%, 110 °C
[3842‑25‑9] HO2CCD2CD(NH2)CO2H FW 136.12
11250-100G poly btl 100 g mp ............................................................................................................................................................. >300 °C (dec.)
L-Aspartic acid sodium salt monohydrate, ≥99.0% (NT)  98 atom % D

Sodium L-aspartate; (S)-2-Aminobutanedioic acid sodium salt [α]25
D +25.0°, c = 2 in 5 M HCl
[323194‑76‑9] Beil. 4,H,478 HO2CCH2CH(NH2)CO2Na · H2O mol wt 136.07, atom % calculation

FW 173.10 489980
Principal neurotransmitter for fast synaptic excitation. L-Aspartic acid-15N,2,3,3-d3
D −14±1°, c = 1 in H2O
[α]20
mp ............................................................................................................................................................. ~140 °C (dec.) HO2CCD2CD(15NH2)CO2H FW 137.11
11195-100G poly btl 100 g  98 atom % 15
N; 98 atom % D
11195-500G poly btl 500 g 572519 Full product information at Aldrich.com
L-Aspartic acid-15N L-Aspartic acid-3-13C

[3715‑16‑0] HO2CCH2CH(15NH2)CO2H FW 134.10 HO2C13CH2CH(NH2)CO2H FW 134.10
mp ............................................................................................................................................................. >300 °C (dec.)
 99 atom % 13
C
 98 atom % 15N 617539 Full product information at Aldrich.com
[α]25
D +25.0°, c = 2 in 5 M HCl
mol wt 134.09, atom % calculation DL-Aspartic acid-3-13C
[202326‑56‑5] HO2C13CH2CH(NH2)CO2H FW 134.10
7
Warning H319 P305 + P351 + P338
 99 atom % 13
C
DL-Aspartic acid, ≥99% (TLC)
L-Aspartic acid-13C4, 95% (CP)
(±)-2-Aminosuccinic acid
HO213C13CH213CH(NH2)13CO2H FW 137.07
[617‑45‑8] Beil. 4,IV,3000 HOOCCH2CH(NH2)COOH FW 133.10
[α]25
D +25.0°, c = 2 in 5 M HCl
mp ............................................................................................................................................................................ >300 °C
mp ............................................................................................................................................................. >300 °C (dec.)
 98 atom % 13C
7
Warning H319 P305 + P351 + P338
DL-Aspartic acid magnesium salt, ≥98.0%
Magnesium DL-aspartate 604852-250MG 250 mg
[7018‑07‑7] [HOOCCH(NH2)CH2COO]2Mg · 4H2O FW 360.56 L-Aspartic acid-4-13C
11270-250G poly btl 250 g [81201‑98‑1] HO213CCH2CH(NH2)CO2H FW 134.10
DL-Aspartic acid potassium salt hemihydrate, ≥98.0% (NT)  99 atom % 13
C
Potassium DL-aspartate 489999 Full product information at Aldrich.com
[394208‑50‑5] HOOCCH(NH2)CH2COOK · 0.5H2O FW 180.20
L-Aspartic acid-13C4,15N, 95% (CP)
11240-100G poly btl 100 g
[202468‑27‑7] HO213C13CH213CH(15NH2)13CO2H FW 138.07
11240-500G 500 g
mp ............................................................................................................................................................. >300 °C (dec.)
L-Aspartic acid-1-13C
 98 atom % 13C; 98 atom % 15N
[81201‑97‑0] HO2CCH2CH(NH2)13CO2H FW 134.10 [α]25
D +25.0°, c = 2 in 5 M HCl
mp ............................................................................................................................................................. >300 °C (dec.) mol wt 137.97, atom % calculation
 99 atom % 13C 607835-250MG glass btl 250 mg
[α]25
D +25.0°, c = 2 in 5 M HCl
DL-Aspartic acid-4-13C
[68315‑35‑5] HO213CCH2CH(NH2)CO2H FW 134.10
8
Warning H351 P281
 99 atom % 13
C
489972-100MG glass btl 100 mg 488968 Full product information at Aldrich.com
DL-Aspartic acid-1-13C > (D)-Aspartic acid 4-amide, see D-Asparagine monohydrate Page 201
[137168‑39‑9] HO2CCH2CH(NH2)13CO2H FW 134.10
 99 atom % 13
C

AHB A, 0613, UNP EU
n Atropine n
L-Aspartic acid 4-tert-butyl ester, ≥98.0% (TLC) > Astradiamant green GX, see Brilliant Green Page 428
[3057‑74‑7] C8H15NO4 FW 189.21 CH3 O Astrazon Orange G

H3C O
OH Basic Orange 21
CH3
O NH2
[3056‑93‑7] C22H23ClN2 FW 350.88
Metachromatic dye
D −9±2°, c = 2 in methanol: water (4:1)
[α]20
λmax ............................................................................................................................................................................ 490 nm
7
L-Aspartic
acid 4-tert-butyl-1-methyl ester hydrochloride,
≥95.0% (TLC) 274216-100G
P338
glass btl 100 g
A
[2673‑19‑0] (CH3)3COCOCH2CH(NH2)COOCH3 · HCl FW 239.70
(R)-(+)-Atenolol, 99%
(+)-4-[2-Hydroxy-3-[(1-methylethyl)amino]propoxy]benzeneacet-
L-Aspartic acid dibenzyl ester p-toluenesulfonate salt, 98% amide
[2886‑33‑1] Beil. 6,IV,2529 C6H5CH2OCOCH2CH(NH2)COOCH2C6H5 · [56715‑13‑0] (CH3)2CHNHCH2CH(OH)CH2OC6H4CH2CONH2
C7H8O3S FW 485.55 FW 266.34
mp .............................................................................................................................................................. 157 to 160 °C mp .............................................................................................................................................................. 148 to 152 °C
[α]24
[α]25
D +16°, c = 1 in 1 M HCl
459887-25G glass btl 25 g 330884-100MG glass btl 100 mg
L-Aspartic acid dimethyl ester hydrochloride, 97% (S)-(−)-Atenolol

[32213‑95‑9] Beil. 4,IV,3001 CH3O2CCH2CH(NH2)CO2CH3 · HCl (−)-4-[2-Hydroxy-3-[(1-methylethyl)amino]propoxy]benzeneacet-
FW 197.62 amide
mp .............................................................................................................................................................. 115 to 117 °C [93379‑54‑5] (CH3)2CHNHCH2CH(OH)CH2OC6H4CH2CONH2
FW 266.34
mp .............................................................................................................................................................. 148 to 152 °C
 solid
> L-Aspartyl-L-phenylalanine, see Asp-Phe Page 203
N-(L-α-Aspartyl)-L-phenylalanine methyl ester, see Asp-Phe methyl ester β1-Adrenergic receptor antagonist; active enantiomer of atenolol.
Page 203 D −10.5°, c = 0.5 in H2O (lit.)
[α]23
Aspirin, see Acetylsalicylic acid Page 45 solubility in H2O ............................................................................................................................................ insoluble
soluble in ......... 0.1 M HCl, 45% (w/v) aq 2-hydroxypropyl-β-cyclodextrin (>6 mg/mL),
Asp-Phe, 96% ethanol
Aspartame acid; L-Aspartyl-L-phenylalanine color ..................................................................................................................................................................... pale pink
[13433‑09‑5] HOOCCH2CH(NH2)CONHCH(CH2C6H5)CO2H A143-10MG 10 mg
FW 280.28 A143-100MG 100 mg
mp .............................................................................................................................................................. 236 to 239 °C
> ATP disodium salt hydrate, see Adenosine 5′-triphosphate disodium salt
[α]20
D +12.5°, c = 1 in 0.5 M HCl hydrate Page 58
421669-100MG glass btl 100 mg ATP-15N5 sodium salt solution, see Adenosine-15N5 5′-triphosphate sodium
salt solution Page 58
421669-250MG glass btl 250 mg ATP-13C10 sodium salt solution, see Adenosine-13C10 5′-triphosphate sodium
salt solution Page 59
Asp-Phe methyl ester, ≥98% ATRA, see Retinoic acid Page 2247
Atrazine-ethylamino-15N1, see
Aspartame; Asp-Phe-OMe; N-(L-α-Aspartyl)-L-phenylalanine methyl 2-Chloro-4-ethylamino-15N-6-isopropylamino-1,3,5-triazine Page 674
ester Atrol, see 2-Dimethylaminoethanol (+)-bitartrate salt Page 1062
[22839‑47‑0] Merck 14,839
HOOCCH2CH(NH2)CONHCH(CH2C6H5)COOCH3 FW 294.30 Atropine sulfate salt monohydrate, ≥97% (TLC)
First generation synthetic sugar alternative that has been studied for Tropine tropate; α-(Hydroxymethyl)benzeneacetic acid 8-methyl-8-
its carcinogenic potential. azabicyclo[3.2.1]oct-3-yl ester
sweetness ................................................................................................................................... 160-200 × sucrose [5908‑99‑6] Merck 14,875; Beil. 21,IV,183; 21,27 (C17H23NO3)2 · H2SO4
store at: 2-8°C · H2O FW 694.83
A5139-1G poly btl 1g Competitive nonselective antagonist at central and peripheral
A5139-5G poly btl 5g muscarinic acetylcholine receptors.
A5139-25G poly btl 25 g mp ..................................................................................................................................................... 189 to 192 °C (A)
β-Asp-Phe methyl ester, 96%  crystalline

soluble in ............................... H2O (2.5 g/mL), ethanol (200 mg/mL), glycerol (400 mg/mL)
N-β-L-Aspartyl-L-phenylalanine methyl ester color .............................................................................................................................................................................. white
[22839‑61‑8] HO2CCH(NH2)CH2CONHCH(CH2C6H5)CO2CH3
6
Danger H300-H330 P260-P264-P284-P301 + P310-P310
FW 294.30
mp ............................................................................................................................................... 201 to 204 °C (dec.)
[α]20
D +6°, c = 1 in H2O
water ................................................................................................................................................................................. <4%
AHB A, 0613, UNP EU
n Atrpinitiators n
ATRP Initiators
Name Structure Description H&P Prod. No.

Bis[2-(2′-bromoisobutyr- CH3
Atom Transfer Radical Polymerization GHS07 Warning H315-H319- 723169-1G
O
yloxy)ethyl]disulfide H3C S O Br (ATRP) initiator for the preparation of H335 P261-P305 + P351 + 723169-5G
O S biodegradable polymers as well as P338
Br CH3
CH3 O
polymers that adhere to gold surfaces.
A Dipentaerythritol hexakis
(2-bromoisobutyrate)
RO OR O
Atom Transfer Radical Polymerization
(ATRP) initiator for the creation of
GHS07 Warning H315-H319-
H335 P261-P305 + P351 +
723207-1G
723207-5G
RO O OR CH3
R=*
Br CH3
hexafunctional polymers. P338
RO OR
Dodecyl 2-bromoisobu- Atom Transfer Radical Polymerization GHS05, GHS07 Danger H302- 723223-1G
O
tyrate H3C
CH2(CH2)10CH3
(ATRP) initiator for the creation of H315-H318-H335 P261-P280- 723223-5G
Br
O dodecyl functionalized telechelic P305 + P351 + P338
CH3 polymers.
Ethylene bis(2-bromoiso- O
Atom Transfer Radical Polymerization GHS05, GHS07 Danger H302- 723177-1G
H3C
butyrate) O
CH3 (ATRP) initiator for the creation of H318 P280-P305 + P351 + 723177-5G
Br O
H3C Br difunctional polymers. P338
O CH3
2-Hydroxyethyl 2- Atom Transfer Radical Polymerization GHS05, GHS07 Danger H302- 723150-1G
O
bromoisobutyrate H3 C OH
(ATRP) initiator for the creation of H318 P280-P305 + P351 + 723150-5G
Br
O hydroxy functionalized telechelic P338
CH3 polymers. Can be used to modify
carboxylate- or isocyanate- modified
surfaces, particles or biomolecules.
Octadecyl 2-bromoisobu- O
tyrate H3C
(ATRP) initiator for the creation of stearyl H335 P261-P305 + P351 + 723231-5G
OCH2(CH2)16CH3 functionalized telechelic polymers. P338
Br CH3
Pentaerythritol tetrakis(2- CH3

bromoisobutyrate) O Br
(ATRP) initiator for the creation of H335 P261-P305 + P351 + 723193-5G
CH3 tetrafunctional polymers. P338
O
O O
H3C CH3
O O Br
Br CH3
CH3 O
H3C
O
Br
CH3
1,1,1-Tris(2-bromoisobu- Atom Transfer Radical Polymerization GHS07 Warning H302-H315- 723185-1G

Br CH3 CH3 Br CH3
tyryloxymethyl)ethane O O
(ATRP) initiator for the creation of H319-H335 P261-P305 + P351 723185-5G
H3C CH3 trifunctional polymers. + P338
O O O
CH3
O
Br CH3
10-Undecenyl 2-bromoi- O
sobutyrate H3 C
(ATRP) initiator that reacts with surfaces H319-H335 P261-P305 + P351 723215-5G
OCH2(CH2)8CH CH2 containing S-H bonds. Precursor of + P338
Br CH3
various silane-containing polymers and
initiators. Hydrosilation with Cl3SiH yields
an initiator that reacts with glass
surfaces.

AHB A, 0613, UNP EU
n Azabenzimidazol n
ATRP Ligands
Name Structure H&P Prod. No.

4,4′-Dinonyl-2,2′-dipyridyl GHS07 Warning H315-H319-H335 P261-P305 482250-1G
CH3(CH2)7CH2 CH2(CH2)7CH3 + P351 + P338 482250-5G
A
N N
N,N,N′,N′′,N′′-Pentamethyldiethylenetriamine GHS05, GHS06 Danger H302-H311-H314 369497-250ML

CH3 CH3
P280-P305 + P351 + P338-P310 369497-1L
N N
H3C N CH3
CH3
Tris[2-(dimethylamino)ethyl]amine GHS05 Danger H314 P280-P305 + P351 + 723142-1ML

H3C CH3
N P338-P310
H3C N CH3
N N
CH3 CH3
Tris(2-pyridylmethyl)amine GHS07 Warning H302 723134-250MG

723134-1G
N
N
N N
Auramine O AW Standard Super-Cel® NF

Basic Yellow 2; Pyoctaninum aureum; 4,4′-(Imidocarbonyl)bis(N,N- Diatomaceous earth, calcined
dimethylaniline) monohydrochloride [91053‑39‑3]
[2465‑27‑2] Beil. 14,IV,256 C17H21N3 · HCl FW 303.83 Free of organic matter
Certified for use by fluorescence microscopy in Churukian′s Suitable for most filtrations
modification of Truant′s fluorescent method for acid fast bacilli on Acid washed
paraffin sections. ®Registered trademark of Johns-Manville Corp.
mp ............................................................................................................................................................. >250 °C (dec.) limit ............................................................................................................................. (0.30) (Permeability(Darcy))
68 78
Danger H302-H311-H351 P280-P312 Warning H319-H335-H373 P261-P305 + P351 + P338
 Dye content: 85%, certified by the Biological Stain Commission 221791-250G poly btl 250 g
λmax ............................................................................................................................................................................. 370 nm 221791-1KG poly drum 1 kg
λmax .............................................................................................................................................................. 434 nm (2nd)
2-Azaadamantane-N-oxyl, 96% 8
AZADO
 Dye content: ≥80%, certified by the Biological Stain Commission [57625‑08‑8] C9H14NO FW 152.21
N
A9655-25G glass btl 25 g O
> Aurin, see p-Rosolic acid Page 2253 mp ..................................................................................................................................................... 182 to 189 °C (D)
7
Aurintricarboxylic acid ammonium salt Warning H302
Aluminon; Ammonium aurintricarboxylate; ATA

[569‑58‑4] Merck 14,322 C22H14O9 · 3NH3 FW 473.43
May contain a substantial amount of polymeric material.
mp ............................................................................................................................................... 220 to 225 °C (dec.) 4-Azabenzimidazole, 99%
7
Warning H315-H319 P305 + P351 + P338 1H-Imidazo[4,5-b]pyridine N N
[273‑21‑2] C6H5N3 FW 119.12
N
 powder H
mp .............................................................................................................................................................. 148 to 151 °C
 ACS reagent
7
Warning H302
Reagent for aluminum
λmax ............................................................................................................................................................................. 450 nm A93607-1G glass btl 1g
λmax .............................................................................................................................................................. 522 nm (2nd) A93607-5G glass btl 5g
insolubles ................................................................................................................................................................... ≤0.1%
ign. residue ............................................................................................................................................................. ≤0.2% 5-Azabenzimidazole, 97%
A36883-25G glass btl 25 g [272‑97‑9] C6H5N3 FW 119.12 N
N
N
H
> AUT, see 11-Amino-1-undecanethiol hydrochloride Page 172
mp .............................................................................................................................................................. 168 to 172 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338

AHB A, 0613, UNP EU
n Azabenzotriazol n
(7-Azabenzotriazol-1-yloxy)tripyrrolidinophosphonium hexa- (1R)-(−)-2-Azabicyclo[2.2.1]hept-5-en-3-one, ≥98%

fluorophosphate, 96%
[79200‑56‑9] C6H7NO FW 109.13
PyAOP N NH
[156311‑83‑0] C17H27F6N7OP2 FW 521.38 N
N N N O
O P PF6-
N N mp ................................................................................................................................................................... 94 to 97 °C
[α]20
ee (HPLC): 99%
A mp .............................................................................................................................................................. 163 to 168 °C
Sold under agreement with PE Biosystems 57
Danger H302-H317-H318 P280-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
535303-5G poly btl 5g (1S)-(+)-2-Azabicyclo[2.2.1]hept-5-en-3-one, ≥98%
O-(7-Azabenzotriazol-1-yl)-N,N,N′,N′-tetramethyluronium hexa- [130931‑83‑8] C6H7NO FW 109.13
fluorophosphate mp ................................................................................................................................................................... 94 to 97 °C
HATU; N,N,N′,N′-Tetramethyl-O-(7-azabenzotri- [α]20

CH3
azol-1-yl)uronium hexafluorophosphate
N
PF6 ee (HPLC): 99%
N N CH3
7
[148893‑10‑1] Merck 14,10421 C10H15F6N6OP N N Warning H315-H319-H335 P261-P305 + P351 + P338
O N CH3
FW 380.23 CH3
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Azabicyclo[2.2.1]hept-5-en-3-one, 98%
(±)-2-Azabicyclo[2.2.1]hept-5-en-3-one; 4-Amino-2-cyclo-
 97% O
pentene-1-carboxylic acid lactam
Peptide coupling reagent.1,2,3 N
[49805‑30‑3] Beil. 21,V,7,211 C6H7NO FW 109.13 H
Preparation of N-arylsulfonamide-linked peptides by solid-phase
synthesis.4 mp ................................................................................................................................................................... 54 to 58 °C
Lit. cited: 1. J. Prakt. Chem./Chem.-Ztg. 340, 581-583 (1998)
bp ........................................................................................................................................ 102-106 °C/0.25 mmHg
2. Lett. Pept. Sci. 9, 119-123 (2003)
7
3. Proc. Eur. Pept. Symp., ed. U. Ragnarrson 27, 272-273 (2002) Warning H302-H317 P280
4. Org. Lett. 8, 2483 (2006)
445460-25G poly btl 25 g > (±)-2-Azabicyclo[2.2.1]hept-5-en-3-one, see 2-Azabicyclo[2.2.1]hept-5-en-3-
one Page 206
 ≥98.0% (CHN)
Recent studies show that crystal as well as solution structure of this cis-3-Azabicyclo[3.1.0]hexane-2-carboxylic acid, 98%
coupling agent is a guanidinium N-oxide and not an uronium [22255‑16‑9] C6H9NO2 FW 127.14
compound;1 Advantageous coupling reagent for solid-phase peptide
mp .............................................................................................................................................................. 252 to 256 °C
synthesis2.
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp ............................................................................................................................................... 183 to 188 °C (dec.)
Lit. cited: 1. L.A. Carpino et al., Angew. Chem. Int. Ed. Engl. 41, 441 (2002)
2. L. Carpino et al., J. Chem. Soc., Chem. Commun. 201 (1994) 391190-250MG glass btl 250 mg
store at: 2-8°C > 1-Azabicyclo[2.2.2]octane, see Quinuclidine Page 2241
11373-1G poly btl 1g (S,S,S)-2-Azabicyclo-[3,3,0]-octane carboxylic acid benzylester hydro-
chloride, see Benzyl (S,S,S)-2-azabicyclo[3.3.0]octane-3-carboxylate hydro-
11373-5G poly btl 5g chloride Page 250
11373-25G poly btl 25 g 1-Azabicyclo[2.2.2]octan-3-ol, see 3-Quinuclidinol Page 2241
1-Azabicyclo[2.2.2]octan-3-one hydrochloride, see 3-Quinuclidone hydro-
O-(7-Azabenzotriazol-1-yl)-N,N,N′,N′-tetramethyluronium hexa- chloride Page 2242
fluorophosphate, ChemDose™ tablets
ChemDose™ O-(7-Azabenzotriazol-1-yl)-N,N,N′, 1-Aza-12-crown-4, ≥97.0%
CH3
N
N′-tetramethyluronium hexafluorophosphate N N CH3
PF6 1,4,7-Trioxa-10-azacyclododecane
tablets; N,N,N′,N′-Tetramethyl-O-(7-azabenzotri- N N
O N CH3
[41775‑76‑2] C8H17NO3 FW 175.23 O O
azol-1-yl)uronium hexafluorophosphate CH3

NH O
impregnated tablets; HATU impregnated
tablets; O-(7-Azabenzotriazol-1-yl)-N,N,N′,N
′-tetramethyluronium hexafluorophosphate mp ................................................................................................................................................................... 54 to 58 °C
impregnated tablets bp ........................................................................................................................................... 58-62 °C/0.005 mmHg
Merck 14,10421 C10H15F6N6OP FW 380.23 Synthesis of lariat ether derivatives1,2
mp ................................................................................................................................................................... 54 to 58 °C
 Loading: 0.02mmol per tablet Lit. cited: 1. K.A. Arnold et al., J. Org. Chem. 53, 5652 (1988)
base material ....................................................................................... magnesium aluminometasilicate 2. G.W. Gokel and J.E. Trafton, Y. Inoue and G.W. Gokel, eds., Cation Binding
by Macrocycles New York, 1990, p. 253
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
685739-100TAB 100 tablets
685739-10TAB 10 tablets 11378-1G glass btl 1g
11378-5G 5g
> O-(7-Azabenzotriazol-1-yl)-N,N,N′,N′-tetramethyluronium hexafluorophos-
phate impregnated tablets, see O-(7-Azabenzotriazol-1-yl)-N,N,N′,N′-tetra-
methyluronium hexafluorophosphate, ChemDose™ tablets Page 206

AHB A, 0613, UNP EU
n Azaindolecarbox n
1-Aza-15-crown-5, 97% mp ............................................................................................................................................................................ >300 °C
7
1,4,7,10-Tetraoxa-13-azacyclopentadecane Warning H302
[66943‑05‑3] C10H21NO4 FW 219.28 NH O

O O
O > 6-Aza-2,4-dihydroxypyrimidine, see 6-Azauracil Page 208
AZADO, see 2-Azaadamantane-N-oxyl Page 205
mp .................................................................................................................................................................... 35 to 37 °C
7-Azaindole, 98%
7 A
Warning H315-H319-H335 P261-P305 + P351 + P338
1H-Pyrrolo(2,3-b)pyridine
364096-1G glass btl 1g [271‑63‑6] C7H6N2 FW 118.14
N N
H
1-Aza-18-crown-6, ≥98.0% (NT)
1,4,7,10,13-Pentaoxa-16-azacyclooctadecane mp .............................................................................................................................................................. 105 to 107 °C
[33941‑15‑0] C12H25NO5 FW 263.33
N
H Starting material in a recent synthesis of azaserotonin.1
O O
A heterocyclic molecule that can be utilized as a pharmaceutical
O O building block2
O Lit. cited: 1. J. Am. Chem. Soc. 128, 14426 (2006)
2. Wang, Xin; et al., J. Org. Chem. 71, 4021-4023 (2006)
57
mp .................................................................................................................................................................... 46 to 49 °C Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
Building block for the synthesis of bis-crown ethers, lariat ethers and P338
other monofunctionalized macrocycles1 A95502-1G glass btl 1g
Lit. cited: 1. G.W. Gokel and J.E. Trafton, Y. Inoue and G.W. Gokel, eds., A95502-5G glass btl 5g
Cation Binding by Macrocycles New York, 1990, p. 253
7-Azaindole-3-carbonitrile, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
3-Cyano-1H-pyrrolo[2,3-b]pyridine; 3-Cyano-7-azaindole CN
11382-5G glass btl 5g N N
H
> Aza-2-cycloheptanone, see ε-Caprolactam Page 612
mp .............................................................................................................................................................. 258 to 262 °C
2-Azacyclononanone, 98%
57
Caprylolactam; 8-Aminooctanoic acid lactam; Aza-2-cyclo- + P351 + P338
nonanone 702323-1G glass btl 1g
[935‑30‑8] Beil. 21,V,6,516 C8H15NO FW 141.21 N
H O 7-Azaindole-4-carbonitrile, 97% 8
4-Cyano-7-azaindole; 1H-Pyrrolo[2,3-b]pyridine-4-carbo- CN
mp .................................................................................................................................................................... 74 to 76 °C
nitrile
N N
H
> Azacyclooctane, see Heptamethyleneimine Page 1415
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
1-Aza-2-cyclooctanone, 98% P338
Oenantholactam; 2-Azocanone; Hexahydro-2(1H)- 706426-250MG glass btl 250 mg
azocinone; 2-Oxo-heptamethyleneimine; Enantholactam; 2-
Azacyclooctanone N
7-Azaindole-3-carboxaldehyde, 97%
H O
[673‑66‑5] Beil. 21,V,6,494 C7H13NO FW 127.18 1H-Pyrrolo[2,3-b]pyridine-3-carbaldehyde O
mp .................................................................................................................................................................... 35 to 38 °C [4649‑09‑6] C8H6N2O FW 146.15
H
bp ............................................................................................................................................ 148-150 °C/10 mmHg
N N
7
Warning H302 H
mp .............................................................................................................................................................. 216 to 220 °C

Useful starter in 7-azaindole chemistry1,2,3
5-Azacytidine, ≥98% (HPLC) Lit. cited: 1. J. Med. Chem. 15, 149 (1972)
2. Bioorg. Med. Chem. 12, 5505 (2004)
Ladakamycin; 4-Amino-1-(β-D-ribofuranosyl)-1,3,5-triazin-2(1H)-one 3. J. Am. Chem. Soc. 77, 457 (1995)
[320‑67‑2] Merck 14,890 C8H12N4O5 FW 244.20
7
Potent growth inhibitor and cytotoxic agent; inhibits DNA methyl- P338
transferase. 694681-1G glass btl 1g
mp ............................................................................................................................................... 226 to 232 °C (dec.)
Causes DNA demethylation or hemi-demethylation. 7-Azaindole-3-carboxylic acid, 95%
store at: −20°C
78
Danger H302-H350 P201-P308 + P313 1H-Pyrrolo[2,3-b]pyridine-3-carboxylic acid O
[156270‑06‑3] C8H6N2O2 FW 162.15
OH
A2385-250MG poly btl 250 mg N N
H
mp .............................................................................................................................................................. 205 to 209 °C
5-Azacytosine
7
4-Amino-1,3,5-triazin-2-one NH2
[931‑86‑2] Beil. 26,IV,1355 C3H4N4O FW 112.09 692530-1G glass btl 1g
N N
N O
H
AHB A, 0613, UNP EU
n Azaindoleoxide n
7-Azaindole N-oxide hemihydrate, 97%  98%

1H-Pyrrolo[2,3-b]pyridine, 7-oxide 246379-25G poly btl 25 g
C7H6N2O · 0.5H2O FW 143.14 • ½ H2O
246379-100G poly btl 100 g
N N
H
O  technical grade, 80%
7
Warning H319 P305 + P351 + P338
mp .............................................................................................................................................................. 102 to 118 °C
57
Danger H302-H318 P280-P305 + P351 + P338
A 696838-1G glass btl 1g Azelaic acid dichloride, 98%
7-Azaindole N-oxide 3-chlorobenzoate, 95% Nonanedioyl dichloride; Nonanedioyl chloride; Azelaoyl chloride
[123‑98‑8] Beil. 2,III,1789 ClOC(CH2)7COCl FW 225.11
7-Hydroxy-1H-pyrrolo[2,3-b]pyridinium 3- O bp ............................................... 166 °C/18 mmHg n20
D .......................................................................... 1.467
chlorobenzoate density ..................................... 1.143 g/mL, 25 °C
O-
C14H11ClN2O3 FW 290.70
5
N+ N Danger H314 P280-P305 + P351 + P338-P310
H
OH Cl

mp .............................................................................................................................................................. 143 to 147 °C
Easily handled form of 7-azaindole N-oxide. > Azelaic acid monomethyl ester, see mono-Methyl azelate Page 1738
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Azetidine, 98%
693588-1G glass btl 1g Trimethylene imine

[503‑29‑7] Beil. 20,V,1,136 C3H7N FW 57.09 N
H
1-Aza-2-methoxy-1-cycloheptene, 99%
O-Methylcaprolactim bp ..................................................................... 61-62 °C n20
D .......................................................................... 1.432
[2525‑16‑8] C7H13NO FW 127.18 density ..................................... 0.847 g/mL, 25 °C
N OCH3
Employed in a high yielding palladium-catalyzed cross-coupling with
bp .......................................... 52-53 °C/18 mmHg n20 aryl bromides.1 Also used in a Ullmann type coupling with
D .......................................................................... 1.463
density ..................................... 0.887 g/mL, 25 °C iodonitroflourenes.2
2
Warning H226 2. Synthesis 3245 (2006)
25
Danger H225-H314 P210-P280-P305 + P351 + P338-P310
A95804-25G glass btl 25 g 281069-250MG ampule 250 mg
> 2′-Aza-D-phenylalanine, see 3-(2-Pyridyl)-D-alanine Page 2223 281069-1G ampule 1g
2′-Aza-L-phenylalanine, see 3-(2-Pyridyl)-L-alanine Page 2223
3-Azaspiro[4.5]decan-2-one, see 4,4-Pentamethylene-2-pyrrolidinone Azetidine hydrochloride, 97%
Page 1993
Trimethyleneimine hydrochloride
• HCl
6-Aza-2-thiothymine, 99% [36520‑39‑5] Beil. 20,2 C3H7N · HCl FW 93.56 N
H
3,4-Dihydro-6-methyl-3-thioxo-1,2,4-triazin-5(2H)-one; 2-Thio-6-aza-
mp ............................................................................................................................................................................ >300 °C
thymine
[615‑76‑9] Beil. 26,IV,559 C4H5N3OS FW 143.17 Basic building block for synthesizing azetidines.1,2
Lit. cited: 1. Bioorg. Med. Chem. Lett. 13, 2899-2901 (2003)
mp .............................................................................................................................................................. 218 to 221 °C
2. Org. Lett. 4, 1859-1862 (2002)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
4-Azatricyclo[4.3.1.13,8]undecan-5-one, 98%
[22607‑75‑6] Beil. 21,7,272 C10H15NO FW 165.23 O 414336-5G glass btl 5g
NH
L-Azetidine-2-carboxylic acid, ≥99%
(S)-Azetidine-2-carboxylic acid O
mp .............................................................................................................................................................. 316 to 318 °C [2133‑34‑8] Beil. 22,V,1,15 C4H7NO2 FW 101.10
N OH
7
403164-1G glass btl 1g L-Azetidine-2-carboxylic acid is an inhibitor of collagen synthesis that

is anti-angiogenic.
6-Azauracil, ≥98%
3,5-Dihydroxy-1,2,4-triazine; 6-Aza-2,4-dihydroxypyrimidine; O A0760-100MG poly btl 100 mg
1,2,4-Triazine-3,5(2H,4H)-dione NH A0760-250MG poly btl 250 mg
[461‑89‑2] Beil. 26,IV,554 C3H3N3O2 FW 113.07 N A0760-1G poly btl 1g
N O
H
> (S)-Azetidine-2-carboxylic acid, see L-Azetidine-2-carboxylic acid Page 208
mp .............................................................................................................................................................. 274 to 275 °C
3-Azetidinecarboxylic acid, 98%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[36476‑78‑5] Beil. 22,1,23 C4H7NO2 FW 101.10 O OH
Azelaic acid N
H
Nonanedioic acid
[123‑99‑9] Merck 14,905; Beil. 2,IV,2055 HO2C(CH2)7CO2H mp ................................................................................................................................................................ 286 °C (dec.)
FW 188.22 391131-250MG glass btl 250 mg
mp ...................................................... 109 to 111 °C vd ................................................................ 6.5 (vs air)
bp ............................................ 286 °C/100 mmHg vp ............................................. <1 mmHg (20 °C)

AHB A, 0613, UNP EU
n Azidobocaminohe n
2-Azetidinone, 98%  ~0.5 M in tert-butyl methyl ether

2-Azacyclobutanone; β-Propiolactam water ............................................................................................................................................................................. ≤2.0%
O
store at: −20°C
27
[930‑21‑2] Beil. 21,V,6,312 C3H5NO FW 71.08 N Danger H225-H315-H317 P210-P280
H
mp .................................................................................................................................................................... 74 to 76 °C 727431-10ML glass btl 10 mL

bp ....................................................................................................................................................... 106 °C/15 mmHg 727431-50ML glass btl 50 mL
5 > Azido-Asp(tBu)-OH (dicyclohexylammonium) salt, see (S)-(−)-4-tert-Butyl

Danger H314 P280-P305 + P351 + P338-P310

hydrogen 2-azidosuccinate (dicyclohexylammonium) salt Page 574
Azidobenzene solution, ≥95.0% 8
A
Phenyl azide solution N3
Azide exchange resin, azide on Amberlite® IRA-400 [622‑37‑7] C6H5N3 FW 119.12
 16-50 mesh
Used to replace activated and nonactivated alkyl halides at room  ~0.5 M in tert-butyl methyl ether
temperature. ≥95.0% (GC)
capacity ........................................................................................................................................................ 3.8 mmol/g water ............................................................................................................................................................................. ≤2.0%
store at: −20°C
6 278
Danger H301-H311-H315-H319-H331-H335-EUH032 P261-P280-P301 Danger H225-H315-H373 P210
+ P310-P305 + P351 + P338-P311
> Azide terminated poly(methyl acrylate), see Poly(methyl acrylate), azide
terminated Page 2131 > (S)-α-Azidobenzenepropanoic acid (dicyclohexylammonium) salt, see (S)-2-
Azide terminated polystyrene, see Polystyrene, azide terminated Azido-3-phenylpropionic acid (dicyclohexylammonium) salt Page 213
Page 2144 o-Azidobenzoic acid solution, see 2-Azidobenzoic acid solution Page 209
L-Azidoalanine cyclohexylammonium salt, see (S)-2-Azido-propionic acid
cyclohexylammonium salt Page 213 2-Azidobenzoic acid solution, ≥95.0% (HPLC) 8
4-Azidoaniline hydrochloride, 97% o-Azidobenzoic acid solution O
[31162‑13‑7] C7H5N3O2 FW 163.13
4-Aminophenyl azide hydrochloride OH
[91159‑79‑4] Beil. 12,IV,1741 N3C6H4NH2 · HCl FW 170.60 N3

mp ................................................................................................................................................................. 165 °C (dec.)
 ~0.25 M in tert-butyl methyl ether
6
P305 + P351 + P338-P311 water ............................................................................................................................................................................. ≤2.0%
27
Danger H225-H315-H319 P210-P305 + P351 + P338
359556-1G glass btl 1g store at: −20°C
2-Azidoanisole solution, ≥95% (HPLC) 8
1-Azido-2-methoxybenzene solution; 2-Methoxyphenyl (4S)-4-[(1R)-2-Azido-1-(benzyloxy)ethyl]-2,2-dimethyl-1,3-
OCH3
dioxolane
azide
[20442‑97‑1] C7H7N3O FW 149.15 N3 C14H19N3O3 FW 277.32 N3
 0.5 M in tert-butyl methyl ether O

O O
water ............................................................................................................................................................................. ≤2.0%
H3C CH3
278
Danger H225-H315-H319-H372 P210-P305 + P351 +
P338-P314 store at: −20°C
[α]20
D +13°, neat
779261-10ML glass btl 10 mL density ............................................................................................................................................. 1.116 g/mL, 25 °C
779261-50ML glass btl 50 mL n20
D ................................................................................................................................................................................... 1.5090
7
3-Azidoanisole solution, ≥97% (HPLC) Warning H302
8
1-Azido-3-methoxybenzene solution; 3-Methoxyphenyl OCH3 573213-1G glass btl 1g
azide solution
[3866‑16‑8] C7H7N3O FW 149.15 > (S)-4-Azido-2-(Boc-amino)butyric acid (dicyclohexylammonium) salt, see N-
N3 Boc-4-azido-L-homoalanine (dicyclohexylammonium) salt Page 382
(S)-2-Azido-6-(Boc-amino)caproic acid (dicyclohexylammonium) salt, see
(S)-(−)-2-Azido-6-(Boc-amino)hexanoic acid (dicyclohexylammonium) salt
 0.5 M in tert-butyl methyl ether Page 209
water ............................................................................................................................................................................. ≤2.0% (S)-(−)-2-Azido-6-(Boc-amino)hexanoic acid (dicyclo- 8
hexylammonium) salt, ≥97%
278
Danger H225-H315-H319-H372 P210-P305 + P351 +
O
H
778729-10ML glass btl 10 mL N •
Boc OH
778729-50ML glass btl 50 mL N
N3 H
4-Azidoanisole solution, ≥90.0% (HPLC) 8 (S)-2-Azido-6-(Boc-amino)caproic acid (dicyclohexylammonium) salt;

1-Azido-4-methoxybenzene solution; 4-Methoxy- N3 N3-Lys(Boc)-OH (dicyclohexylammonium) salt
phenyl azide solution C11H20N4O4 · C12H23N FW 453.62
[2101‑87‑3] C7H7N3O FW 149.15 H3CO
≥97.0% (HPLC)
[α]D -13.5±1.0°, c = 1 in ethanol

AHB A, 0613, UNP EU
n Azidobocaminohe n
> (S)-6-Azido-2-(Boc-amino)hexanoic acid (dicyclohexylammonium) salt, see 1-Azido-3-chlorobenzene solution, ≥97% (HPLC)
N-Boc-6-azido-L-norleucine (dicyclohexylammonium) salt Page 382
8
(S)-5-Azido-2-(Boc-amino)pentanoic acid (dicyclohexylammonium) salt, 3-Chlorophenyl azide solution N3
see N-Boc-5-azido-L-norvaline (dicyclohexylammonium) salt Page 382 [3296‑06‑8] C6H4ClN3 FW 153.57
(S)-3-Azido-2-(Boc-amino)propionic acid (dicyclohexylammonium) salt, see
Boc-3-azido-Ala-OH (dicyclohexylammonium) salt Page 382
Cl
4-Azido-α-bromoacetophenone, see 4-Azidophenacyl bromide Page 213
4′-Azido-2-bromoacetophenone, see 4-Azidophenacyl bromide Page 213
1-Azido-4-bromobenzene solution, ≥95.0% (GC)  0.5 M in tert-butyl methyl ether
8
water ................................................................................................................................................................................. ≤2%
A 4-Bromophenyl azide solution
[2101‑88‑4] C6H4BrN3 FW 198.02
N3
278
Danger H225-H315-H319-H372
P210-P305 + P351 +
Br
 ~0.5 M in tert-butyl methyl ether 779938-50ML glass btl 50 mL

water ............................................................................................................................................................................. ≤2.0% 1-Azido-4-chlorobenzene solution, ≥95.0% (GC) 8
278
Danger H225-H315-H319-H372 P210-P305 + P351 +
P338-P314 store at: −20°C 4-Chlorophenyl azide solution N3
[3296‑05‑7] C6H4ClN3 FW 153.57
779377-10ML glass btl 10 mL Cl
> (S)-2-Azidobutanedioic acid 4-tert-butyl ester (dicyclohexylammonium)  ~0.5 M in tert-butyl methyl ether
salt, see (S)-(−)-4-tert-Butyl hydrogen 2-azidosuccinate (dicyclohexylam- water ............................................................................................................................................................................. ≤2.0%
monium) salt Page 574
store at: −20°C
27
Danger H225-H302-H315 P210
(S)-2-Azido-3-(4-tert-butoxyphenyl)propionic acid 8
cyclohexylammonium salt, ≥98% (TLC)
O 727482-50ML glass btl 50 mL
OH NH2
CH3 • 6-Azido-6-deoxy-1,2:3,4-di-O-isopropylidene-α-D- 8
N3
H3C O galactopyranose, ≥96% (HPLC)
CH3
[4711‑00‑6] C12H19N3O5 FW 285.30 CH3 N3
L-Azidotyrosine tert-butyl ether cyclohexylammonium salt; H3C O
O
N3-Tyr(OtBu)-OH CHA salt O
O
C13H17N3O3 · C6H13N FW 362.47 O
CH3
[α]D -48.0±2.0°, c = 1 in methanol CH3
composition
carbon 62.3‑63.6% [α]D -92.0±3.0°, c = 1 in ethyl acetate
78
P280-P305 + P351 + P338 store at: 2-8°C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
store at: 2-8°C 712736-100MG glass btl 100 mg
1-Azido-1-deoxy-β-D-galactopyranoside, 97%
(S)-2-Azido-3-tert-butoxypropionic acid cyclohexylam- 8 [35899‑89‑9] C6H11N3O5 FW 205.17
monium salt, ≥98% (TLC) HO
HO N3
O
N3-Ser(OtBu)-OH CHA salt; L-Azido- O OH
CH3
serine tert-butyl ether cyclohexylam- NH2
H3C O OH
monium salt • OH
CH3 N3
C7H13N3O3 ·C6H13N FW 286.37
mp ................................................................................................................................................................ 150 °C (dec.)
[α]D +3.7±0.3°, c = 1 in methanol [α]20
D +23°, c = 1 in DMSO
composition
carbon 54.0‑55.0%
nitrogen 19.1‑19.9% 1-Azido-1-deoxy-β-D-galactopyranoside tetraacetate, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338 [13992‑26‑2] C14H19N3O9 FW 373.32
store at: 2-8°C
mp ................................................................................................................................................................... 96 to 99 °C
[α]25
1-Azido-2-chlorobenzene solution, ≥97% (HPLC) 8 513970-1G glass btl 1g
2-Chlorophenyl azide solution N3 6-Azido-6-deoxy-D-galactose, ≥98.0% (HPLC) 8

[3296‑07‑9] C6H4ClN3 FW 153.57
Cl [66927‑03‑5] C6H11N3O5 FW 205.17 N3
HO O
OH OH
 0.5 M in tert-butyl methyl ether
water ................................................................................................................................................................................. ≤2% OH
278
Danger H225-H315-H319-H372 P210-P305 + P351 +
[α]D 59.0±2.0°, c = 1 in H2O
7

AHB A, 0613, UNP EU
n Azidofluorobenz n
1-Azido-1-deoxy-β-D-glucopyranoside > 2-Azido-2-deoxy-3,4,6-tri-O-acetyl-D-galactopyranosyl acetate, see 2-Azido-

D-galactose tetraacetate Page 212
[20379‑59‑3] C6H11N3O5 FW 205.17 HO 2-Azido-2-deoxy-3,4,6-tri-O-acetyl-β-D-glucopyranosyl acetate, see 2-Azido-
N3 β-D-glucose tetraacetate Page 212
O 2-{2-[2-(2-Azidoethoxy)ethoxy]ethoxy}ethylamine, see 11-Azido-3,6,9-triox-
OH
aundecan-1-amine Page 214
HO
OH
1-{2-[2-(2-Azidoethoxy)ethoxy]ethoxy}-2-methoxyethane, see O-(2-
Azidoethyl)-O′-methyl-triethylene glycol Page 211
mp .................................................................................................................................................................... 60 to 65 °C
O-(2-Azidoethyl)-O-[2-(diglycolyl-amino)ethyl]heptaethylene
514004-500MG
1-Azido-1-deoxy-β-D-glucopyranoside tetraacetate
glass btl 500 mg glycol, ≥90% (oligomer purity)
O O
A
N3 O O
[13992‑25‑1] C14H19N3O9 FW 373.32 O N OH
H
[α]D -29°, c = 1 in H2O 7
[α]D -30°, c = 1 in chloroform

mp .............................................................................................................................................................. 127 to 131 °C
Azido-PEG-acid (n=8)
[846549‑37‑9] C22H42N4O12 FW 554.59
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Azido-2-deoxy-D-glucose, ≥98.0% (HPLC) 8 store at: 2-8°C
71613-500MG-F poly tube 500 mg
[56883‑39‑7] C6H11N3O5 FW 205.17 HO
O O-(2-Azidoethyl)heptaethylene glycol 8
OH OH
OH
Azido-PEG (n=7)
O
N3 [352439‑36‑2] C16H33N3O8 FW 395.45 N3 OH
7
[α]D 22.5±1.0°, c = 1 in H2O

≥95% (oligomer purity)
7
7
Warning H315-H319-H335 P261-P305 + P351 + P338
6-Azido-6-deoxy-D-glucose, ≥98% (HPLC) 8
> O-(2-Azidoethyl)-O′-methylpolyethylene glycol, see Methoxypolyethylene
C6H11N3O5 FW 205.17 N3 glycol azide Page 1718
Poly(ethylene glycol) methyl ether azide Page 1718
O
OH OH O-(2-Azidoethyl)-O′-methyl-triethylene glycol, ≥90% 8
HO (NMR)
OH
13-Azido-2,5,8,11-tetraoxatridecane; H3CO O N3
O O
[α]D +59.0±3.0°, c = 1 in H2O 1-{2-[2-(2-Azidoethoxy)ethoxy]
composition ethoxy}-2-methoxyethane
carbon 34.4‑35.8% [606130‑90‑9] C9H19N3O4
nitrogen 20.0‑21.0% FW 233.26
7
Warning H302
7
712760-100MG glass btl 100 mg 712590-100MG glass btl 100 mg
1-Azido-1-deoxy-β-D-lactopyranoside, 97% O-(2-Azidoethyl)-O′-methyl-undecaethylene glycol, 8

≥90% (NMR)
[69266‑16‑6] C12H21N3O10 FW 367.31 HO
C25H51N3O12 FW 585.69
N3 O
O H3CO
HO OH N3
11
HO O
O
OH OH
store at: 2-8°C
OH 712604-100MG glass btl 100 mg
[α]20
D +14.8°, c = 1 in DMSO
O-(2-Azidoethyl)nonadecaethylene glycol, ≥95% 8
mp ................................................................................................................................................................................ 120 °C
(oligomer purity)
Azido-PEG (n=19)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
C40H81N3O20 FW 924.08 O
N3 OH
19
3′-Azido-3′-deoxythymidine, ≥98% (HPLC) store at: 2-8°C
AZT; Azidothymidine; Zidovudine; ZDV 726249-250MG glass btl 250 mg

[30516‑87‑1] Merck 14,10123 C10H13N5O4 FW 267.24 1-Azido-2-fluorobenzene solution, ≥95% (GC) 8
Reverse transcriptase inhibitor active against HIV-1 virus.
mp .............................................................................................................................................................. 113 to 115 °C 2-Fluorophenyl azide solution N3
[3296‑04‑6] C6H4FN3 FW 137.11
F
store at: −20°C
8
Warning H351 P281
A2169-25MG poly btl 25 mg water ............................................................................................................................................................................. ≤2.0%
278
Danger H225-H315-H319-H372 P210-P305 + P351 +
A2169-250MG glass btl 250 mg P338-P314 store at: −20°C
A2169-1G glass btl 1g 778842-10ML glass btl 10 mL
AHB A, 0613, UNP EU
n Azidofluorobenz n
1-Azido-3-fluorobenzene solution, ≥95% (GC) 8 (S)-2 Azido-3-(3-indolyl)propionic acid cyclohexylam- 8

monium salt, ≥98% (HPLC)
3-Fluorophenyl azide solution N3
L-Azidotryptophan cyclohexylam-
[3296‑03‑5] C6H4FN3 FW 137.11 O
monium salt; N3-Trp-OH CHA salt
OH NH2
F C11H10N4O2 · C6H13N FW 329.40 N3 •
N
H
water ............................................................................................................................................................................. ≤2.0% [α]D -45.0±2.0°, c = 1 in methanol
A 278 Danger H225-H315-H319-H372
P210-P305 + P351 + composition
carbon 60.7‑63.2%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
1-Azido-4-fluorobenzene solution, ≥95.0% (GC) 8
4-Fluorophenyl azide solution 714259-250MG glass btl 250 mg
N3
[3296‑02‑4] C6H4FN3 FW 137.11 1-Azido-2-iodobenzene solution, ≥97% (HPLC)
F 8
2-Iodophenyl azide solution N3
 ~0.5 M in tert-butyl methyl ether [54467‑95‑7] C6H4IN3 FW 245.02
I
water ............................................................................................................................................................................. ≤2.0%
278
Danger H225-H315-H319-H372 P210-P305 + P351 +
P338-P314 store at: −20°C  ~0.25 M in tert-butyl methyl ether
water ............................................................................................................................................................................. ≤2.0%
278
779253-50ML glass btl 50 mL Danger H225-H315-H319-H372 P210-P305 + P351 +
(S)-5-Azido-2-(Fmoc-amino)pentanoic acid, ≥97.0% 8 779059-25ML glass btl 25 mL
(HPLC)
Fmoc-Orn(N2)-OH; Fmoc-5-azido-L-norvaline; Fmoc- 1-Azido-3-iodobenzene solution, ≥97.0% (HPLC) 8
O
L-δ-azidoornithine 3-Iodophenyl azide solution N3
N3 OH
[1097192‑04‑5] C20H20N4O4 FW 380.40 NH [54467‑96‑8] C6H4IN3 FW 245.02
Fmoc
I
[α]D 3.5±0.3°, c = 1 in ethyl acetate
composition  ~0.5 M in tert-butyl methyl ether
carbon 62.5‑63.9%
water ............................................................................................................................................................................. ≤2.0%
278
Danger H225-H315-H319-H372 P210-P305 + P351 +
7
Warning H315-H319-H335 P261-P305 + P351 + P338 P338-P314 store at: −20°C
store at: 2-8°C
> (S)-3-Azido-2-(Fmoc-amino)propionic acid, see Fmoc-β-azido-Ala-OH

1-Azido-4-iodobenzene solution, ≥95% (HPLC) 8
Page 1341 4-Iodophenyl azide solution N3
2-Azido-D-galactose tetraacetate, ≥97% (HPLC) 8 [53694‑87‑4] C6H4IN3 FW 245.02
I
1,3,4,6-Tetra-O-acetyl-2-azido-2-deoxy-D- RO
galactopyranose; 2-Azido-2-deoxy-3,4,6-tri- RO
OR
O
O  0.5 M in tert-butyl methyl ether
O-acetyl-D-galactopyranosyl acetate; 1,3,4,6- OR
R= * water ............................................................................................................................................................................. ≤2.0%
Tetra-O-acetyl-2-azido-2-deoxy-D-galactose CH3
278
N3 Danger H225-H315-H319-H372 P210-P305 + P351 +
[84278‑00‑2] C14H19N3O9 FW 373.32
[α]D +110.0±4.0°, c = 1 in ethyl acetate 779482-10ML glass btl 10 mL
composition
carbon 44.1‑45.9%
nitrogen 10.9‑11.6% > L-Azidomethionin cyclohexylammonium salt, see (S)-2-Azido-4-(methylthio)
butanoic acid cyclohexylammonium salt Page 213
78
Warning H302-H312-H315-H319-H332-H335-H341 P261- 1-Azido-2-methoxybenzene solution, see 2-Azidoanisole solution
P280-P305 + P351 + P338 Page 209
712809-250MG glass btl 250 mg 1-Azido-3-methoxybenzene solution, see 3-Azidoanisole solution
Page 209
2-Azido-β-D-glucose tetraacetate, ≥98% (HPLC) 8
1-Azido-4-methoxybenzene solution, see 4-Azidoanisole solution
Page 209
1,3,4,6-Tetra-O-acetyl-2-azido-2-deoxy-β-D- 1-Azido-2-methylbenzene solution, see 2-Azidotoluene solution
RO
OR Page 214
glucopyranose; 2-Azido-2-deoxy-3,4,6-tri-O- O
O 1-Azido-3-methylbenzene solution, see 3-Azidotoluene solution
OR
acetyl-β-D-glucopyranosyl acetate Page 214
R= * CH3
[80321‑89‑7] C14H19N3O9 FW 373.32 RO 1-Azido-4-methylbenzene solution, see 4-Azidotoluene solution
N3 Page 214
[α]D +2.9±0.4°, c = 1 in chloroform (R)-2-(Azidomethyl)-1-Boc-pyrrolidine, ≥95% (HPLC) 8
78
Warning H302-H312-H315-H319-H332-H335-H341 P261- (R)-2-(Azidomethyl)-1-(tert-butoxycarbonyl)pyrrolidine; tert-
N3
P280-P305 + P351 + P338 store at: 2-8°C Butyl (R)-2-(azidomethyl)-1-pyrrolidinecarboxylate N
712787-100MG glass btl 100 mg [259537‑91‑2] C10H18N4O2 FW 226.28 Boc
> Azido-Glu(OtBu)-OH (dicyclohexylammonium) salt, see (S)-5-tert-Butyl enantiomeric excess (HPLC): ≥99%
hydrogen 2-azidoglutarate (dicyclohexylammonium) salt Page 574
(S)-2-Azidoglutaric acid 5-tert-butyl ester (dicyclohexylammonium) salt, see store at: 2-8°C
(S)-5-tert-Butyl hydrogen 2-azidoglutarate (dicyclohexylammonium) salt 670006-100MG glass btl 100 mg
Page 574
11-Azido-1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadecafluoroundecane, see 670006-500MG glass btl 500 mg
4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoroundecyl azide
Page 1413

AHB A, 0613, UNP EU
n Azidotetraoxatr n
(S)-2-(Azidomethyl)-1-Boc-pyrrolidine, ≥95% (HPLC) 8 5-Azidopentanoic acid, ≥97.0% 8

(S)-2-(Azidomethyl)-1-(tert-butoxycarbonyl)pyrrolidine; tert-Butyl (S)-2- 5-Azidovalerianic acid O
(azidomethyl)-1-pyrrolidinecarboxylate [79583‑98‑5] C5H9N3O2 FW 143.14 N3 OH
[168049‑26‑1] C10H18N4O2 FW 226.28
[α]D -48.5±1°, c = 1 in chloroform 97.0-103.0% (T, calc. on dry substance)
enantiomeric excess (HPLC): ≥98% ≥97.0% (TLC)
store at: 2-8°C LOD ................................................................................................................................................................................. ≤10%
669881-100MG
669881-500MG
glass btl
glass btl
100 mg
500 mg 8
Warning H351 P281
A
> (R)-2-(Azidomethyl)-1-(tert-butoxycarbonyl)pyrrolidine, see (R)-2-(Azido- 712256-250MG glass btl 250 mg
(S)-2-(Azidomethyl)-1-(tert-butoxycarbonyl)pyrrolidine, see (S)-2-(Azido- 4-Azidophenacyl bromide
methyl)-1-Boc-pyrrolidine Page 213 4′-Azido-2-bromoacetophenone; 4-Azido-α-bromo- O
(S)-2-Azido-3-methylbutyric acid cyclohexylam- 8 acetophenone Br
monium salt, ≥98% (TLC) [57018‑46‑9] C8H6BrN3O FW 240.06
N3
L-Azidovaline
cyclohexylammonium salt; CH3 O
N3-Val-OH CHA salt NH2
C5H9N3O2·C6H13N FW 242.32
H3C OH •
 powder
N3
Photoactive, heterobifunctional cross-linking reagent. Typically, the
[α]D -34.0±2.0°, c = 1 in methanol initial reaction couples to sulfhydryl in the pH range 7.0-8.0. Second
composition bonding occurs during UV irradiation (250 nm) via reactive nitrene.
carbon 53.4‑55.6% The latter bonding is rapid and non-specific.
nitrogen 22.5‑23.7% Reducing agents such as thiols may reduce the azide to amine and
should be avoided. Initial manipulations and coupling should be
7
Warning H315-H319-H335 P261-P305 + P351 + P338
store at: 2-8°C performed under reduced light.
soluble in ............................................................................................................................ methanol (50 mg/mL)
color ............................................................................................................................................................................ yellow
> (S)-2-Azido-4-(methylmercapto)butyric acid cyclohexylammonium salt, see
258
Danger H228-H314-H317-H334 P210-P261-P280-P305
(S)-2-Azido-4-(methylthio)butanoic acid cyclohexylammonium salt + P351 + P338-P310 store at: 2-8°C
Page 213
Azidomethyl phenyl sulfide, 95%
4-Azidophenyl isothiocyanate, 97%
Phenylthiomethyl azide
[74261‑65‑7] N3C6H4NCS FW 176.20
[77422‑70‑9] Fieser 10,14; 12,37; 17,286 C6H5SCH2N3 FW 165.22
mp ................................................................................................................................................................... 65 to 68 °C
bp ....................................... 104-105 °C/5 mmHg n20D ....................................................................... 1.5904
278
density ..................................... 1.168 g/mL, 25 °C Danger H228-H302-H312-H315-H317-H319-H332-H334-
H335 P210-P261-P280-P305 + P351 + P338-P342 +
EUH044 P311
(S)-2-Azido-4-(methylthio)butanoic acid cyclohexylam- 8 (S)-2-Azido-3-phenylpropionic acid (dicyclohexylam-
monium salt, ≥98% (TLC) 8
monium) salt, ≥98%
(S)-2-Azido-4-(methylmercapto)butyric O (S)-α-Azidobenzenepropanoic acid O
acid cyclohexylammonium salt; N3- H3CS NH2
OH • (dicyclohexylammonium) salt
OH •
Met-OH CHA salt; L-Azidomethionin N3 [79410‑36‑9] C9H9N3O2 · C12H23N N
N3 H
cyclohexylammonium salt FW 372.50
C5H9N3O2S · C6H13N FW 274.38
≥98.0% (HPLC)
[α]D -115.0±3.0°, c = 1 in methanol
98.0-102.0% (T, with NaOH)
composition
[α]D -44±2°, c = 1 in ethanol
carbon 47.6‑48.6%
nitrogen 20.0‑20.8% 690767-1G glass btl 1g
7
Warning H315-H319-H335 P261-P305 + P351 + P338
store at: 2-8°C
(S)-2-Azido-propionic acid cyclohexylammonium salt, 8
714267-100MG glass btl 100 mg ≥98% (TLC)
> Azido-PEG-acid (n=8), see O-(2-Azidoethyl)-O-[2-(diglycolyl-amino)ethyl] L-Azidoalaninecyclohexylammonium salt; O
heptaethylene glycol Page 211 N3-Ala-OH CHA salt H3C NH2
Azido-PEG-amine (n=10), see O-(2-Aminoethyl)-O′-(2-azidoethyl) OH •
nonaethylene glycol Page 121
C3H5N3O2 · C6H13N FW 214.26 N3
Azido-PEG-amine (n=6), see O-(2-Aminoethyl)-O′-(2-azidoethyl)penta-
ethylene glycol Page 121 [α]D +12.0±1.0°, c = 1 in methanol
Azido-PEG-amine (n=8), see O-(2-Aminoethyl)-O′-(2-azidoethyl)hepta-
ethylene glycol Page 120 composition
Azido-PEG (n=19), see O-(2-Azidoethyl)nonadecaethylene glycol Page 211 carbon 49.9‑51.0%
Azido-PEG (n=7), see O-(2-Azidoethyl)heptaethylene glycol Page 211 nitrogen 25.6‑26.7%
(S)-2-Azido-pentanedioic acid 5-tert-butyl ester (dicyclohexylammonium)
7
salt, see (S)-5-tert-Butyl hydrogen 2-azidoglutarate (dicyclohexylammonium) Warning H315-H319-H335 P261-P305 + P351 + P338
salt Page 574 store at: 2-8°C
> L-Azidoserine tert-butyl ether cyclohexylammonium salt, see (S)-2-Azido-3-

tert-butoxypropionic acid cyclohexylammonium salt Page 210
(S)-2-Azidosuccinic acid 4-tert-butyl ester (dicyclohexylammonium) salt,
see (S)-(−)-4-tert-Butyl hydrogen 2-azidosuccinate (dicyclohexylammonium)
salt Page 574
4-(Azidosulfonyl)benzoic acid, see 4-Carboxybenzenesulfonazide
Page 623
13-Azido-2,5,8,11-tetraoxatridecane, see O-(2-Azidoethyl)-O′-methyl-
triethylene glycol Page 211

AHB A, 0613, UNP EU
n Azidotoluene n
2-Azidotoluene solution, ≥90% (GC) 8 Azidotrimethyltin(IV), 97%

1-Azido-2-methylbenzene solution; o-Tolyl azide solution; [1118‑03‑2] (CH3)3SnN3 FW 207.85
CH3
2-Methylphenyl azide solution mp .............................................................................................................................................................. 117 to 120 °C
[31656‑92‑5] C7H7N3 FW 133.15
69
N3 Danger H300-H310-H330-H410 P260-P264-P273-P280-P284-
P301 + P310
 ~0.5 M in tert-butyl methyl ether 349488-1G glass btl 1g
water ............................................................................................................................................................................. ≤2.0% 349488-5G glass btl 5g
A 278 Danger H225-H315-H319-H372

P210-P305 + P351 +
11-Azido-3,6,9-trioxaundecan-1-amine, ≥90% (GC)

1-Amino-11-azido-3,6,9-trioxaundec- O O
H2N O N3
ane; O-(2-Aminoethyl)-O′-(2-azido-
ethyl)diethylene glycol; 2-{2-[2-(2-
3-Azidotoluene solution, ≥95.0% (GC) 8 Azidoethoxy)ethoxy]ethoxy}ethyl-
amine
1-Azido-3-methylbenzene solution; m-Tolyl azide solution; CH3 [134179‑38‑7] C8H18N4O3
3-Methylphenyl azide solution
FW 218.25
[4113‑72‑8] C7H7N3 FW 133.15 density ................................................................................................................................................ 1.10 g/mL, 20 °C
N3
 technical
 ~0.5 M in tert-butyl methyl ether Bifunctional, hydrophilic linker1,2
water ............................................................................................................................................................................. ≤2.0% n20
D ...................................................................................................................................................................................... 1.470
Lit. cited: 1. C.R. Bertozzi, M.D. Bednarski, J. Org. Chem. 56, 4326 (1991)
278
Danger H225-H315-H319-H372 P210-P305 + P351 +
P338-P314 store at: −20°C 2. A.W. Schwabacher et al., J. Org. Chem. 63, 1727 (1998)
5
Danger H314 P280-P305 + P351 + P338-P310
4-Azidotoluene solution, ≥95.0% (GC) 8 17758-5ML glass btl 5 mL
1-Azido-4-methylbenzene solution; 4-Methylphenyl N3 > L-Azidotryptophan cyclohexylammonium salt, see (S)-2 Azido-3-(3-indolyl)
azide solution; p-Tolyl azide solution propionic acid cyclohexylammonium salt Page 212
L-Azidotyrosine tert-butyl ether cyclohexylammonium salt, see (S)-2-Azido-
[2101‑86‑2] C7H7N3 FW 133.15 H3C
3-(4-tert-butoxyphenyl)propionic acid cyclohexylammonium salt
Page 210
 ~0.5 M in tert-butyl methyl ether 11-Azido-1-undecanethiol, 96% 8
water ............................................................................................................................................................................. ≤2.0%
[668420‑70‑0] N3CH2(CH2)9CH2SH FW 229.39
27
Danger H225-H315-H319 P210-P305 + P351 + P338
store at: −20°C density ............................................................................................................................................. 0.962 g/mL, 25 °C
n20
D ...................................................................................................................................................................................... 1.482
> 5-Azidovalerianic acid, see 5-Azidopentanoic acid Page 213
Azidotributyltin(IV), 98% L-Azidovaline cyclohexylammonium salt, see (S)-2-Azido-3-methylbutyric
[17846‑68‑3] [CH3(CH2)3]3SnN3 FW 334.09 acid cyclohexylammonium salt Page 213

L-Aziridine-2-carboxylic acid lithium salt, see Lithium L-aziridine-2-
density ............................................................................................................................................. 1.212 g/mL, 25 °C carboxylate Page 1616
689
Danger H301-H312-H315-H319-H372-H410 P273-
P280-P301 + P310-P305 + P351 + P338-P314-P501 Azobenzene, 98%
349453-1G glass btl 1g [103‑33‑3] Merck 14,917; Beil. 16,IV,8 C6H5N=NC6H5 FW 182.22
349453-5G glass btl 5g mp ............................................................ 65 to 68 °C vp ............................................. 1 mmHg (104 °C)
bp ......................................................................... 293 °C ait ......................................................................... 890 °F
> 9-Azido-1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorononane, see density ........................................ 1.09 g/mL, 25 °C
4,4,5,5,6,6,7,7,8,8,9,9,9-Tridecafluorononyl azide Page 2481
789
Danger H302-H332-H341-H350-H373-H410 P201-
1-Azido-4-(trifluoromethoxy) benzene solution, ≥97% 8 P273-P281-P308 + P313-P501
(GC)
[876012‑82‑7] C7H4F3N3O FW 203.12 N3 424633-25G glass btl 25 g
F3CO > 4,4′-Azobis(4-cyanopentanoic acid), see 4,4′-Azobis(4-cyanovaleric acid)

Page 214
 0.25 M in tert-butyl methyl ether 4,4′-Azobis(4-cyanovaleric acid)

water ............................................................................................................................................................................. ≤2.0%
4,4′-Azobis(4-cyanopentanoic acid); ACVA; ABCVA
278
Danger H225-H315-H319-H372 P210-P305 + P351 +
[2638‑94‑0] Beil. 4,IV,3382
HOCOCH2CH2C(CH3)(CN)N=NC(CH3)(CN)CH2CH2COOH FW 280.28
mp ............................................................................................................................................... 118 to 125 °C (dec.)
2
Azidotrimethylsilane, 95% Danger H228 P210
Trimethylsilyl azide
[4648‑54‑8] Fieser 5,719; 7,394; 1,1236; 3,316; 6,632; 16,17; 9,21; 10,14;  ≥98.0% (T)
11,32; 12,37; 14,25; 13,24; 15,342; 17,23 (CH3)3SiN3 FW 115.21 Radical initiator, half live at 69°: 10 hrs (water)
bp ....................................... 52-53 °C/175 mmHg n20
D .......................................................................... 1.414 water ................................................................................................................................................................................. ≤1%
density ..................................... 0.868 g/mL, 25 °C store at: 2-8°C
26
Danger H225-H301-H311-H331 P210-P261-P280-P301 + 11590-25G glass btl 25 g
P310-P311
11590-100G poly btl 100 g

AHB A, 0613, UNP EU
n Azomycin n
 ≥75% 1,1′-(Azodicarbonyl)dipiperidine, 99%

Free radical initiator Azodicarboxylic acid dipiperidide; ADD O
Radical initator in polymer synthesis.1 [10465‑81‑3] Beil. 20,V,2,500; Fieser 9,22; 8,19 N
remainder water C12H20N4O2 FW 252.31 N N
Lit. cited: 1. J. Polym. Sci., A: Polym. Chem. 45, 1143 (2007) N
O
Widely used reagent for the Mitsunobu reaction1,2
1,1′-Azobis(cyclohexanecarbonitrile), 98%
VAZO™ catalyst 88 free radical source; 1,1′-Azobis(cyanocyclohexane);
Used in a study of the copper-catalyzed addition of aryboronic acids
to azodicarboxyl derivatives providing aryl-substituted hydrazides.3
A
ACHN Lit. cited: 1. Sato, H.; et al., Bioorg. Med. Chem. 10, 1595 (2002)
[2094‑98‑6] Merck 14,10454; Beil. 16,IV,328; Fieser 14,25 2. Dougherty, J.M.; et al., Tetrahedron 61, 6218 (2005)
NCC6H10N=NC6H10CN FW 244.34 3. J. Org. Chem. 70, 8631 (2005)
7
A more efficient radical initiator than AIBN has been employed to
initiate primary radical reactions.1 255920-5G glass btl 5g
DuPont product 255920-25G poly btl 25 g
Azodicarboxamide, 97%
27
Danger H242-H315-H319-H335 P261-P305 + P351 + P338
[123‑77‑3] Merck 14,919; Beil. 3,IV,246 NH2CON=NCONH2
380210-25G poly btl 25 g
FW 116.08
mp ............................................................................................................................................... 220 to 225 °C (dec.)
380210-100G poly btl 100 g
8
Danger H334 P261-P342 + P311
2,2′-Azobis(2-methylpropane), 97%
Di-tert-butyldiazene; Azo-tert-butane A96606-100G poly btl 100 g
[927‑83‑3] Beil. 4,IV,3371 (CH3)3CN=NC(CH3)3 FW 142.24 A96606-500G poly btl 500 g
bp ............................................. 47-48 °C/8 mmHg n20
D .......................................................................... 1.397
density ..................................... 0.756 g/mL, 25 °C > Azodicarboxylic acid bis(2-methoxyethyl ester), see Di-2-methoxyethyl
azodicarboxylate Page 1045
n-pentane ...................................................................................................................................................................... <3% Azodicarboxylic bismorpholide, see Azodicarboxylic dimorpholide
Page 215
27
+ P351 + P338
Azodicarboxylic dimorpholide, ≥98.0% (N)
Azodicarboxylic bismorpholide
O O
2,2′-Azobis(2-methylpropionamidine) dihydrochloride, 97% [10465‑82‑4] C10H16N4O4 FW 256.26 N
N
N N
α,α′-Azodiisobutyramidine dihydrochloride; AAPH O O
[2997‑92‑4] Beil. 4,IV,3379 [=NC(CH3)2C(=NH)NH2]2·2HCl
FW 271.19 Reagent for the formation of symmetric and unsymmetric disulfides
mp .............................................................................................................................................................. 175 to 177 °C in polar solvents (e.g. water)1
 granular mp .............................................................................................................................................................. 141 to 143 °C
Free radical initiator. Lit. cited: 1. L. Moroder et al., Hoppe Seyler's Z. Physiol. Chem. 370, 365
Polymerization initiator for acrylic, vinyl and allyl monomers. (1989)
t1/2(56 °C) 10 hr 11628-5G glass btl 5g
solubility in acetone, dioxane, methanol, ethanol, DMSO and water ..................... soluble
> 2,2′-Azodiphenol, see 2,2′-Dihydroxyazobenzene Page 1015
27
Danger H242-H302-H317 P280 Azoic Diazo No. 4, see Fast Garnet GBC sulfate salt Page 1286
Azoic Diazo No. 22, see Variamine Blue RT Salt Page 2600
Azoic Diazo No. 24, see Fast Blue RR Page 1286
440914-25G poly btl 25 g Azoic Diazo No. 39, see Fast Corinth V zinc chloride double salt Page 1286
440914-100G poly btl 100 g Azoic Diazo No. 37, see 4-Nitrobenzenediazonium tetrafluoroborate
Page 1909
2,2′-Azobis(2-methylpropionitrile), 98% α,α,′-Azoisobutyronitrile solution, see 2,2′-Azobis(2-methylpropionitrile)
solution Page 215
AIBN; α,α′-Azoisobutyronitrile; Azobisisobutyronitrile
[78‑67‑1] Merck 14,918; Beil. 4,IV,3377 (CH3)2C(CN)N=NC(CH3)2CN Azomethine-H monosodium salt hydrate, 90%
FW 164.21 4-Hydroxy-5-(salicylideneamino)-2,7-naph- HO3S SO3–
mp ............................................................................................................................................... 102 to 104 °C (dec.) thalenedisulfonic acid monosodium salt; 4-
Free radical initiator1 Hydroxy-5-(2-hydroxybenzylideneamino)-naph-
Lit. cited: 1. Tetrahedron Lett. 48, 5585 (2007) thalene-2,7-disulfonic acid monosodium salt N OH Na+
27
Danger H242-H302-H332-H412 P273 hydrate HO
• xH2O
[206752‑32‑1] C17H12NNaO8S2 · xH2O
441090-25G poly btl 25 g FW 445.40 (Anh)
441090-100G poly btl 100 g Degree of hydration varies
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2,2′-Azobis(2-methylpropionitrile) solution 8
AIBN solution; α,α,′-Azoisobutyronitrile solution H3C CH3 285196-5G glass btl 5g
[78‑67‑1] Merck 14,918 C8H12N4 FW 164.21 N C N
N C N
H3C CH3
> Azomycin, see 2-Nitroimidazole Page 1915
 0.2 M in toluene
density ............................................................................................................................................. 0.858 g/mL, 25 °C
n20
D ...................................................................................................................................................................................... 1.495
278
Danger H225-H304-H315-H336-H361d-H373 P210-
P261-P281-P301 + P310-P331
AHB A, 0613, UNP EU
n Azopyridine n
4,4′-Azopyridine 8 Azure A eosinate

[2632‑99‑7] C10H8N4 FW 184.20 [62298‑43‑5]
N N N N λmax .............................................................................................................................................................. 522 nm (2nd)
λmax ............................................................................................................................................................................ 628 nm
mp ................................................................................................................................................................. 96 to 101 °C 200212-25G glass btl 25 g
6
P338 Azure B eosinate
A
705055-1G glass btl 1g [62298‑42‑4]
705055-5G glass btl 5g λmax .............................................................................................................................................................. 523 nm (2nd)
λmax ............................................................................................................................................................................ 636 nm
> Azorubin S, see Amaranth Page 86
Azoviolet, see 4-(4-Nitrophenylazo)resorcinol Page 1921 200239-25G glass btl 25 g
AZT, see 3′-Azido-3′-deoxythymidine Page 211
Azure II
Azulene, 99% [37247‑10‑2] C16H18N3S · C15H16N3S ·2 Cl FW 625.68
Bicyclo[5.3.0]decapentaene  powder
[275‑51‑4] Merck 14,926; Beil. 5,IV,1636 C10H8 mixture of Azure B and Methylene Blue in equal amounts.
FW 128.17
λmax ............................................................................................................................................................................ 657 nm
mp ................................................................................................................................................................. 98 to 100 °C
bp ................................................................................................................................................................................. 242 °C
Azure II eosinate
9
H411 P273
O
A97203-100MG glass btl 100 mg N Cl
O
A97203-1G glass btl 1g H3C CH3 Br Br
N S N
Azure B R CH3
NaO O ONa
Methyleneazure; N,N,N′-Trimethylthionin; Azure I R = H or CH3, 1:1 mix Br Br
[531‑55‑5] Merck 14,928; Beil. 27,IV,5151 C15H16ClN3S FW 305.83

mp ............................................................................................................................................... 205 to 210 °C (dec.)
[53092‑85‑6]
 certified by the Biological Stain Commission
Chief ingredient of Giemsa Stain.
Certified for use in Lillie′s modified Nocht′s method for paraffin
λmax .............................................................................................................................................................. 524 nm (2nd)
sections and the NCCLS method for blood smears.
λmax ............................................................................................................................................................................ 647 nm
composition
5
Danger H318 P280-P305 + P351 + P338
Dye content ≥89%
200220-100G glass btl 100 g
 prepared by direct synthesis Azure B tetrafluoroborate
λmax ............................................................................................................................................................................. 648 nm
[79288‑94‑1] C15H16BF4N3S FW 357.18
mp ................................................................................................................................................................ 244 °C (dec.)
227935-100G glass btl 100 g
Azure C λmax ............................................................................................................................................................................ 637 nm
N-Methylthionine
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[531‑57‑7] Merck 14,929 C13H12ClN3S FW 277.77
 Dye content: 40% 302619-5G glass btl 5g
Biological stain > BA, see 6-Benzylaminopurine Page 249
λmax ............................................................................................................................................................................. 616 nm
242187-5G glass btl 5g Baccatin III, ≥95% (HPLC)
242187-25G glass btl 25 g [27548‑93‑2] C31H38O11 FW 586.63 O
Azure A chloride H3C O O

CH3 OH
H3C CH3
O H
CH3
H
N
O HO O
O2N NO2
CH3 OH O O
H2N S N
CH3
CH3 O O O O
O
Br Br
2
Precursor to paclitaxel
78
Danger H315-H319-H335-H350 P201-P261-P305 + P351 +
[531‑53‑3] Merck 14,927; Beil. 27,IV,5151 C14H14ClN3S FW 291.80
P338-P308 + P313 store at: 2-8°C
mp ................................................................................................................................................................. 290 °C (dec.)
B8154-5MG glass btl 5 mg
 Dye content: ~80%
BACH-EI™ hydroboration reagent solution
A6270-50G glass btl 50 g Borane N-ethyl-N-isopropylaniline complex
[180840‑34‑0] C6H5N(C2H5)CH(CH3)2·BH3 FW 177.09
 2.0 M in THF
bp ............................................................................................................................................................................ 65-67 °C
density ............................................................................................................................................. 0.904 g/mL, 25 °C

AHB A, 0613, UNP EU
n Bariumacetate n
Baicalein, 98% mp ............................................................................................................................................ 248 to 252 °C ((dec.))
5,6,7-Trihydroxyflavone OH O  99 atom % 13C; 98 atom % 15N

[491‑67‑8] Merck 14,942; Beil. 18,V,4,569 HO mol wt 133.97, atom % calculation
C15H10O5 FW 270.24 705101-5MG 5 mg
HO O
Barium
mp .............................................................................................................................................................. 256 to 271 °C [7440‑39‑3] Merck 14,964 Ba FW 137.33
The flavonoid component of Nepalese and Sino-Japanese crude resistivity ........................................................................................................................................ 50.0 μΩ-cm, 20°C
drugs.1,2 Baicalein, a major flavone of Scutellariae baicalensis, inhibits mp ........................................................................ 725 °C density ....................................... 3.6 g/mL, 25 °C
the 12-lipoxygenase (12-LOX) pathway of arachidonic acid metab- bp ...................................................................... 1640 °C
27
olism, which inhibits cancer cell proliferation and induces apoptosis. Danger H261-H315-H319-H335 P231 + P232-P261-P305 +
Lit. cited: 1. Chem. Pharm. Bull. 39, 1051 (1991) P351 + P338-P422
2. Chem. Pharm. Bull. 38, 3488 (1990)
 dendritic pieces, purified by distillation, 99.99% trace metals
7
Warning H315-H319-H335 P261-P305 + P351 + P338 basis
Catalyst for the formation of graphitic nanofilaments.1
465119-100MG glass btl 100 mg Lit. cited: 1. Liang, C.H., et al., Nanotech. in Catalysis 2, 543 (2004)
465119-500MG glass btl 500 mg 474711-5G
474711-25G
ampule
ampule
5g
25 g
B
Baicalin, 95%
[21967‑41‑9] C21H18O11 FW 446.36 OH O  dendritic pieces, purified by distillation, 99.9% trace metals basis
HO Catalyst for the formation of graphitic nanofilaments.1
HO O Lit. cited: 1. Liang, C.H., et al., Nanotech. in Catalysis 2, 543 (2004)
O O
O 441880-5G ampule 5g
OH
441880-25G ampule 25 g
OH OH
 pieces, under oil, 99%
mp ............................................................................................................................................... 202 to 205 °C (dec.)
 pieces, 1 cm, 99% trace metals basis
D −85°, c = 1 in DMSO
[α]20 strontium ....................................................................................................................................................................... 0.5%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
572667-1G glass btl 1g  rod, diam. 2 cm, ≥99% trace metals basis
572667-5G glass btl 5g 2-ethylhexyl dihydrogenphosphate and tris(2-ethylhexyl) phosphate .......................... ≤2%
strontium ....................................................................................................................................................................... 0.5%
Baicalin hydrate
237094-25G poly btl 25 g
Baicalein 7-β-D-glucopyranosiduronate
[206752‑33‑2] Beil. 18,IV,5154 C21H18O11 · xH2O FW 446.36 (Anh)
mp .............................................................................................................................................................. 231 to 233 °C
D −120°, c = 1 in 50% pyridine
[α]23 Ion Standard Solutions
7
Warning H315-H319-H335 P261-P305 + P351 + P338
We offer a wide range of standards for
375756-100MG glass btl 100 mg calibration of ICP-MS, ICP-OES, AAS and IC.
> BAL, see 2,3-Dimercapto-1-propanol Page 1035

BAlq, see Bis(8-hydroxy-2-methylquinoline)-(4-phenylphenoxy)aluminum
Page 336
BAL tributyrate, see 2,3-Dimercapto-1-propanol tributyrate Page 1035
BAO, see 2,5-Bis-(4-aminophenyl)-1,3,4-oxadiazole Page 292 Barium acetate
6-BAP, see 6-Benzylaminopurine Page 249
[543‑80‑6] Merck 14,965; Beil. 2,IV,114 (CH3COO)2Ba FW 255.42
7
Barbituric acid, 99% Warning H302-H332
2,4,6-Trihydroxypyrimidine; Malonylurea O
[67‑52‑7] Merck 14,963; Beil. 24,IV,1873 C4H4N2O3 NH
FW 128.09 255912-10G poly btl 10 g
O N O
H 255912-50G poly btl 50 g
mp ............................................................................................................................................... 248 to 252 °C (dec.)  ACS reagent, 99%

 ReagentPlus ® 99.0-102.0% (ACS specification)
insolubles ................................................................................................................................................................ ≤0.01%
185698-25G poly btl 25 g
oxidizers ................................................................................................................................................................ ≤0.005%
185698-100G poly btl 100 g chloride (Cl-) ............................................. ≤0.001% K .................................................................... ≤0.003%
185698-500G poly btl 500 g Ca ........................................................................ ≤0.05% Na ................................................................. ≤0.005%
Fe ..................................................................... ≤0.001% Sr ......................................................................... ≤0.2%
> Barbituric acid sodium salt, see Sodium barbiturate Page 2292
heavy metals (as Pb) .......................... ≤5 ppm
Barbituric acid-13C4,15N2, 97% (CP) 8
243671-100G poly btl 100 g
2,4,6-Trihydroxypyrimidine-13C4,15N2 O 243671-500G poly btl 500 g
13
C4H415N2O3 FW 134.04 13C
13C 15
NH
13 13
C C
O 15N O
H

AHB A, 0613, UNP EU
n Bariumacetylace n
Barium acetylacetonate hydrate Hydration may vary slightly

Barium 2,4-pentanedionate; Ba(acac)2
379
Danger H271-H302-H332-H411 P220-P273
Beil. 1,782 Ba(C5H7O2)2 · xH2O FW 335.54 (Anh)
244554-500G glass btl 500 g
7
Warning H302-H332
Barium chloride
[10361‑37‑2] Merck 14,971 BaCl2 FW 208.23
339059-250G glass btl 250 g
mp ............................................................................................................................................................................... 963 °C
Barium bis(2,2,6,6-tetramethyl-3,5-heptanedionate) hydrate density ............................................................................................................................................. 3.856 g/mL, 25 °C
6
Ba(TMHD)2 Danger H301-H332 P301 + P310
Ba(OCC(CH3)3CHCOC(CH3)3)2 · xH2O FW 503.86 (Anh)
solid  anhydrous, beads, −10 mesh, 99.999% trace metals basis
mp .............................................................................................................................................................. 175 to 180 °C 449644-5G ampule 5g
composition 449644-25G ampule 25 g
Degree of hydration ~1
 anhydrous, beads, −10 mesh, 99.95% trace metals basis
B 6
P305 + P351 + P338-P311 449652-10G ampule 10 g
Barium bromide, 99.999% trace metals basis powder and chunks
[10553‑31‑8] Merck 14,968 BaBr2 FW 297.14 202738-5G poly btl 5g
202738-25G poly btl 25 g
 anhydrous, beads, −10 mesh
202738-100G poly btl 100 g
7
Warning H302-H332
413607-5G ampule 5g powder
Barium tert-butoxide, 85% 342920-10G poly btl 10 g
8
342920-50G poly btl 50 g
Barium di-t-butoxide CH3 CH3
342920-250G poly btl 250 g
[24363‑36‑8] C8H18BaO2 FW 283.55 H3C O O CH3
Ba
CH3 CH3 Barium chloride dihydrate
mp ............................................................................................................................................................................ >200 °C [10326‑27‑9] Merck 14,971 BaCl2 · 2H2O FW 244.26
6
Danger H301-H332 P301 + P310
257
Danger H228-H314-H335-EUH014 P210-P261-P280-
P305 + P351 + P338-P310
715468-1G glass btl 1g  ≥99%
715468-10G glass btl 10 g B0750-100G poly btl 100 g
B0750-500G poly btl 500 g
Barium carbonate
B0750-1KG poly btl 1 kg
[513‑77‑9] Merck 14,969 BaCO3 FW 197.34
7
Warning H302
powder
powder and chunks
202711-25G poly btl 25 g
insolubles ............................................................................................................................................................. ≤0.005%
202711-100G poly btl 100 g oxidizers ................................................................................................................................................................ ≤0.005%
LOD .............................................................. 14.0-16.0% heavy metals (as Pb) ...................... ≤5 ppm
 99.98% trace metals basis pH ............................................... 5.2-8.2, 5% (25 °C) K .................................................................. ≤0.0025%
powder Ca ........................................................................ ≤0.05% Na ................................................................. ≤0.005%
329436-25G poly btl 25 g Fe ...................................................................... ≤2 ppm Sr ......................................................................... ≤0.1%
329436-100G poly btl 100 g
217565-100G poly btl 100 g
 ACS reagent, ≥99% 217565-500G poly btl 500 g
99.0-101.0% (ACS specification) 217565-2.5KG poly btl 2.5 kg
insol. dil. HCl ...................................................................................................................................................... ≤0.015%
Barium chromate
oxidizers ................................................................................................................................................................ ≤0.005%
water-soluble titr. base ................................................................................................................ ≤0.002 meq/g [10294‑40‑3] Merck 14,972 BaCrO4 FW 253.32
chloride (Cl-) ............................................. ≤0.002% heavy metals (as Pb) ...................... ≤0.001% powder
S2- ..................................................................... ≤0.001% K ..................................................................... ≤0.005% mp ................................................................................................................................................................ 210 °C (dec.)
Ca ........................................................................ ≤0.05% Na .................................................................... ≤0.02% density ................................................................................................................................................... 4.5 g/mL, 25 °C
Fe ...................................................................... ≤0.002% Sr ......................................................................... ≤0.7%
237108-500G poly btl 500 g
237108-1KG 1 kg
237108-2.5KG poly btl 2.5 kg  ≥98%
3789
Danger H272-H302-H317-H332-H350i-H410
Barium chlorate monohydrate, 98% P201-P220-P273-P280-P308 + P313-P501
[10294‑38‑9] Ba(ClO3)2·H2O FW 322.24 401056-250G glass btl 250 g
mp ................................................................................................................................................................................ 414 °C 401056-1KG glass btl 1 kg
density ................................................................................................................................................ 3.18 g/mL, 25 °C
> Barium 2-cyanoethyl phosphate, see 2-Cyanoethyl phosphate barium salt
dihydrate Page 793

AHB A, 0613, UNP EU
n Bariumiodate n
Barium 2-cyanoethylphosphate hydrate  99.99% trace metals basis

2-Cyanoethyl phosphate barium salt hydrate
7
Warning H302-H332
[207121‑42‑4] Fieser 1,172 NCCH2CH2OPO3Ba · xH2O
FW 286.37 (Anh) 202746-20G poly btl 20 g
Contains barium acetate
 powder, ≤5 μm, 98%
7
Warning H302-H332
7
Warning H302-H332

236101-500G poly btl 500 g
> Barium di-t-butoxide, see Barium tert-butoxide Page 218
Barium hydroxide, ~95%
Barium diphenylamine-4-sulfonate [17194‑00‑2] Merck 14,977 Ba(OH)2 FW 171.34
4-(Phenylamino)benzenesulfonic acid barium salt; Diphenylamine-4- mp ............................................................................................................................................................................ >300 °C
sulfonic acid barium salt density ................................................................................................................................................... 2.2 g/mL, 25 °C
[6211‑24‑1] Merck 14,7313; Beil. 14,IV,2691 (C12H10NO3S)2Ba  technical grade
FW 633.88 powder
 for redox titration
Visit our Titration Center to learn more. 7
Warning H302-H332
B
≥95% 433373-250G poly btl 250 g
7
Warning H302-H332 433373-1KG poly btl 1 kg
Barium hydroxide monohydrate, 98%

D4130-5G poly btl 5g
D4130-25G poly btl 25 g [22326‑55‑2] Merck 14,977; Fieser 12,38 Ba(OH)2 · H2O FW 189.36
D4130-50G poly btl 50 g density ............................................................................................................................................. 3.743 g/mL, 25 °C
7
Warning H302-H332
> Barium dodecairon nonadecaoxide, see Barium ferrite Page 219
Barium 2-ethylhexanoate, 98% 342386-25G poly btl 25 g

342386-500G poly btl 500 g
[2457‑01‑4] Beil. 2,349 [CH3(CH2)3CH(C2H5)CO2]2Ba FW 423.73
Barium hydroxide octahydrate
7
Warning H302-H332
[12230‑71‑6] Merck 14,977; Fieser 12,38 Ba(OH)2 · 8H2O FW 315.46
361704-5G glass btl 5g Catalyzes the β-elimination of phosphoserine residues.
Barium ferrite, 98% mp .................................................................................................................................................................................. 78 °C
[11138‑11‑7] BaFe12O19 FW 1111.46  ACS reagent, ≥98%

barium carbonate ................................................................................................................................................ ≤2.0%
 −325 mesh insol. dil. HCl ........................................................................................................................................................ ≤0.01%
May contain varying amounts of oxide. chloride (Cl-) ............................................. ≤0.001% heavy metals (as Pb) ...................... ≤5 ppm
powder S2- ..................................................................... ≤0.001% K ....................................................................... ≤0.01%
Ca ........................................................................ ≤0.05% Na .................................................................... ≤0.01%
7
Warning H302-H332
Fe ..................................................................... ≤0.001% Sr ......................................................................... ≤0.8%
57
383295-250G glass btl 250 g Danger H302-H314-H332 P280-P305 + P351 + P338-P310
217573-100G poly btl 100 g
Barium ferrite, >97% trace metals basis
217573-500G poly btl 500 g
Barium dodecairon nonadecaoxide; Barium iron oxide 217573-2.5KG poly btl 2.5 kg
[12047‑11‑9] BaFe12O19 FW 1111.46
 ≥98%
 nanopowder, particle size <100 nm (BET)
7
Warning H302-H332
7
Warning H302

Barium fluoride B2507-1KG poly btl 1 kg
[7787‑32‑8] Merck 14,974 BaF2 FW 175.32 Barium hydroxide hydrate, 99.995% trace metals basis
Features and Benefits [40226‑30‑0] Merck 14,977 Ba(OH)2 · xH2O FW 171.34 (Anh)
Primary glass modifier in fluorozirconate glasses.1
mp .................................................................................................................................................................................. 78 °C
bp .............................................................................................................................................................................. 2260 °C
density ................................................................................................................................................ 2.18 g/mL, 25 °C
density ................................................................................................................................................ 4.89 g/mL, 25 °C
crystalline
Lit. cited: 1. Konishi, A. et al., J. Mater. Sci. 29, 1584 (1994)
composition
 anhydrous, powder, 99.999% trace metals basis Degree of hydration ~8
7 7
Warning H302-H332 Warning H302-H332
449660-10G glass btl 10 g 450170-5G poly btl 5g

450170-25G poly btl 25 g
 precipitated, 99.999% trace metals basis
powder Barium iodate monohydrate, 98%
density ............................................................................................................................................. 4.830 g/mL, 25 °C
[7787‑34‑0] Ba(IO3)2 · H2O FW 505.15
652458-25G poly btl 25 g
444162-100G glass btl 100 g
652458-100G poly btl 100 g
AHB A, 0613, UNP EU
n Bariumiodide n
Barium iodide, 99.995% trace metals basis Barium oxide

[13718‑50‑8] Merck 14,980 BaI2 FW 391.14 [1304‑28‑5] Merck 14,986; Fieser 9,23 BaO FW 153.33
mp ................................................................................................................................................................................ 740 °C Features and Benefits
density ................................................................................................................................................ 5.15 g/mL, 25 °C Used in the synthesis of the high-κ material BST (barium strontium
 anhydrous, beads, −10 mesh titanate).1 Used in the study of NOX storage.1,2
density ................................................................................................................................................ 5.72 g/mL, 25 °C
7
Warning H302-H332
Lit. cited: 1. Im, J. et al., Thin Solid Films 413, 243 (2002)
2. Stone P. et al., Surface Science 537, 197 (2003)
413615-5G ampule 5g
56
Danger H301-H314-H332 P280-P301 + P310-P305 + P351 +
413615-25G ampule 25 g P338-P310
Barium iodide dihydrate  99.99% trace metals basis
[7787‑33‑9] Bal2 · 2H2O FW 427.17 powder
density ................................................................................................................................................ 5.15 g/mL, 25 °C 554847-5G glass btl 5g
 98% 554847-25G glass btl 25 g
566268-25G amber poly 25 g  97%

B  ≥95%
powder
adsorbed H2O/CO2 ............................................................................................................................................... 1-4%
powder and chunks
7
288497-250G glass btl 250 g
223808-50G glass btl 50 g  technical grade, 90%
Barium isopropoxide powder and chunks
[24363‑37‑9] Ba(OCH(CH3)2)2 FW 255.50 223603-500G glass btl 500 g
solid 223603-2KG glass btl 2 kg
mp ................................................................................................................................................................. 200 °C (dec.) Barium perchlorate
27
Warning H252-H302-H332 P235 + P410
[13465‑95‑7] Merck 14,987 Ba(ClO4)2 FW 336.23
mp ............................................................................................................................................................................... 505 °C
 powder, 99.9% trace metals basis density ................................................................................................................................................... 3.2 g/mL, 25 °C
37
449679-2G glass btl 2g Danger H271-H302-H332 P220
 technical grade  99.999%

339148-25G glass btl 25 g  97%
Barium manganate, 90% Effective desiccant
241733-100G glass btl 100 g
[7787‑35‑1] Merck 14,981; Fieser 10,16; 8,21; 12,38; 15,18; 9,23
BaMnO4 FW 256.26 Barium perchlorate hydrate, 98%
density ................................................................................................................................................ 4.85 g/mL, 25 °C [15318‑52‑2] Ba(ClO4)2 · xH2O FW 336.23 (Anh)
 technical grade crystals
37
powder and chunks Danger H271-H302-H332 P220
37
Danger H272-H302-H332 P220
342394-250G glass btl 250 g
Barium phosphate dibasic
210196-100G glass btl 100 g
Barium hydrogenphosphate
[10048‑98‑3] Merck 14,990 BaHPO4 FW 233.31
Barium nitrate
7
Warning H302-H332
[10022‑31‑8] Merck 14,983 Ba(NO3)2 FW 261.34
mp ................................................................................................................................................................. 592 °C (dec.)
Barium strontium titanium oxide, >99 wt. % trace metals basis
7
Warning H302-H332 (Ba, Sr, and Ti)
(BaTiO3)(SrTiO3) FW 416.68
 99.999% trace metals basis density ................................................................................................................................................ 4.91 g/mL, 25 °C
water ................................................................................................................................................................................. ≤3%
Sr ............................................................................................................................................................................... <5 ppm  nanopowder, particle size <100 nm
7
202754-25G poly btl 25 g Warning H315-H319-H335 P261-P305 + P351 + P338
202754-100G poly btl 100 g

 ACS reagent, ≥99% 633828-100G glass btl 100 g
insolubles ................................................................................................................................................................ ≤0.01%
pH ............................................... 5.0-8.0, 5% (25 °C) heavy metals (as Pb) ...................... ≤5 ppm Barium sulfate
chloride (Cl-) ............................................. ≤5 ppm K ..................................................................... ≤0.005% Baryte
Ca ........................................................................ ≤0.05% Na ................................................................. ≤0.005% [7727‑43‑7] Merck 14,994 BaSO4 FW 233.39
Fe ...................................................................... ≤2 ppm Sr ......................................................................... ≤0.1%
 99.998%
217581-100G poly btl 100 g
202762-20G poly btl 20 g
217581-500G poly btl 500 g
202762-100G poly btl 100 g

AHB A, 0613, UNP EU
n Basicfuchsin n
 ReagentPlus®, 99% Barium tungstate, 99.9% trace metals basis

243353-100G poly btl 100 g [7787‑42‑0] BaWO4 FW 385.16
243353-500G poly btl 500 g density ................................................................................................................................................ 5.04 g/mL, 25 °C
243353-1KG poly btl 1 kg  −100 mesh
Barium sulfide, 99.9% powder
7
Warning H302-H332
[21109‑95‑5] Merck 14,995 BaS FW 169.39
density ................................................................................................................................................ 4.25 g/mL, 15 °C
343137-50G poly btl 50 g
79
Warning H302-H332-H400-EUH031 P273
Barium zirconate
523437-10G glass btl 10 g [12009‑21‑1] BaZrO3 FW 276.55
523437-50G glass btl 50 g density ................................................................................................................................................ 5.52 g/mL, 25 °C
7
Barium thiocyanate hydrate Warning H302-H332
[336879‑43‑7] Ba(SCN)2 · xH2O FW 253.49 (Anh)

 nanopowder, particle size <50 nm, 98.5% trace metals basis
7
Warning H302-H312-H332-H412-EUH032 P273-P280

631884-25G poly btl 25 g
B
 powder, <10 μm
Barium thiosulfate, 98% 383309-250G poly btl 250 g
[35112‑53‑9] Merck 14,999 BaS2O3 FW 249.46 Basacryl Red GL
7
Warning H302-H332
Basic Red 29
H 3C N
[42373‑04‑6] C19H17ClN4S FW 368.88
437417-250G poly btl 250 g S
N N Cl
Barium titanate(IV)
[12047‑27‑7] Merck 14,1000 BaTiO3 FW 233.19 N
CH3
density ................................................................................................................................................ 6.08 g/mL, 25 °C
7
Warning H302-H332
λmax ............................................................................................................................................................................ 511 nm
 powder, 99.995% trace metals basis
7
Warning H315-H319-H335 P261-P305 + P351 + P338
256552-10G poly btl 10 g
 nanopowder (cubic crystalline phase), particle size <100 nm 306525-25G glass btl 25 g
(BET), ≥99% trace metals basis Basic Blue 3
Some agglomeration of nanoparticles may occur during the drying
process, yielding particle sizes of up to 75 microns. These N
agglomerates can be broken up through ultrasonication, ball milling,
H3 C N O N CH3
or dispersion in solution with a surfactant.
H3 C CH3 Cl
dielectric constant ..................................................................................................................................................... 150
467634-25G poly btl 25 g
[33203‑82‑6] C20H26ClN3O FW 359.89
467634-100G poly btl 100 g
mp ................................................................................................................................................................ 205 °C (dec.)
 pieces, 3-12 mm, 99.9% trace metals basis  Dye content: 25%
sintered λmax ............................................................................................................................................................................ 654 nm
 powder, <2 μm, 99.9% trace metals basis > Basic Blue 9, see Methylene blue Page 1773
Basic Blue 17, see Toluidine Blue O Page 2453
338842-100G poly btl 100 g Basic blue 24, see New Methylene Blue N zinc chloride double salt
338842-500G poly btl 500 g Page 1896
Basic Blue 12, see Nile Blue A Page 1903
 powder, <3 μm, 99% Basic Brown 1, see Bismarck Brown Y Page 338
Basic Brown 4, see Bismarck Brown R Page 338
208108-500G poly btl 500 g
208108-2KG poly btl 2 kg Basic Fuchsin
> Barium triflate, see Barium trifluoromethanesulfonate Page 221 Paramagenta hydrochloride; Pararosaniline hydrochloride; Pararos-
aniline chloride; Magenta™ O; Basic Red 9; Basic Parafuchsin;
Barium trifluoromethanesulfonate, 98% Parafuchsin hydrochloride
Barium triflate; Trifluoromethanesulfonic acid barium salt [569‑61‑9] Beil. 12,IV,2290; 13,IV,2283 C19H17N3 · HCl FW 323.82
[2794‑60‑7] Beil. 3,IV,30 (CF3SO3)2Ba FW 435.47 mp ............................................................................................................................................... 268 to 270 °C (dec.)
mp ............................................................................................................................................................................ >300 °C  Dye content: >88%, certified by the Biological Stain Commission
7
Warning H302-H332 Certified for use for acid-fast staining with carbol-fuchsin, as ENDO
medium, and as Schiff′s reagent in the Periodic Acid Schiff (PAS) and
419087-5G glass btl 5g Feulgen techniques.
419087-25G glass btl 25 g λmax ............................................................................................................................................................................ 544 nm
pH range .......................................................................................................................... 1.0 - 3.1, purple to red
8
Danger H350 P201-P308 + P313

857343-100G glass btl 100 g

AHB A, 0613, UNP EU
n Basicgreen n
> Basic Green 1, see Brilliant Green Page 428 Basolite® A100
Basic Green 4, see Malachite Green oxalate salt Page 1646
Basic Green 5, see Methylene Green zinc chloride double salt Page 1776 Aluminum terephthalate; MIL 53
Basic Orange 2, see Chrysoidine G Page 761 C8H5AlO5 FW 208.10
Basic Orange 14, see Acridine Orange hemi(zinc chloride) salt Page 48
Basic Orange 21, see Astrazon Orange G Page 203  produced by BASF
Basic Red 1, see Rhodamine 6G Page 2248 MOF (metal organic framework)
Basic Red 2, see Safranin O Page 2261
Basic Red 5, see Neutral Red Page 1896 can be reactivated at 200°C (vacuum)
Basic Red 9, see Basic Fuchsin Page 221 bulk density .................................................................................................................................................... 0.4 g/cm3
Basic Red 29, see Basacryl Red GL Page 221 BET surf. area ................................................................................................................................ 1100-1500 m2/g
Basic Violet 1, see Methyl violet 2B Page 1865
Basic Violet 3, see Crystal Violet Page 788 particle size distribution .......................................................................................................... 31.55 μm (D50)
78
Basic Violet 10, see Rhodamine B Page 2248 Danger H319-H360D P201-P305 + P351 + P338-P308 + P313
Basic Yellow 2, see Auramine O Page 205
Basic Yellow 1, see Thioflavin T Page 2426
Basionics®, see 1-Propyl-3-methylimidazolium bis(trifluoromethylsulfonyl) 688738-10G poly btl 10 g
imide Page 2202 688738-100G poly btl 100 g
Basionics® AC 09, see 1-Ethyl-3-methylimidazolium tetrachloroaluminate
Page 1258 688738-500G poly btl 500 g
Basionics® AC 25, see 1-Ethyl-3-methylimidazolium hydrogen sulfate
Page 1257 Basolite® Z1200
B Basionics® AC 39, see 1-Methylimidazolium hydrogen sulfate Page 1790
Basionics® AC 75, see 1-Methylimidazolium chloride Page 1790
Basionics® BC 01, see 1-Ethyl-3-methylimidazolium acetate Page 1255
2-Methylimidazole zinc salt; ZIF 8
[59061‑53‑9] C8H12N4Zn FW 229.60
Basionics® BC 02, see 1-Butyl-3-methylimidazolium acetate Page 582
Basionics® EE 03, see 1-Ethyl-3-methylimidazolium tetrafluoroborate  produced by BASF
Page 1258 Metal organic framework (MOF)
Basionics® EE 04, see 1-Butyl-3-methylimidazolium tetrafluoroborate Zinc imidazolate frameworks (ZIF)
Page 584
Basionics® FS 01, see Tris(2-hydroxyethyl)methylammonium methylsulfate can be activated at 100°C (vacuum)
Page 2573 bulk density ................................................................................................................................................. 0.35 g/cm3
Basionics® HP 02, see 1-Butyl-3-methylimidazolium bis(trifluoromethylsul- BET surf. area ................................................................................................................................ 1300-1800 m2/g
fonyl)imide Page 582 particle size ............................................................................................................................................. 4.9 μm (D50)
Basionics® LQ 01, see 1-Ethyl-3-methylimidazolium ethyl sulfate Page 1257
57
Basionics® LQ 02, see 1-Butyl-3-methylimidazolium methyl sulfate Danger H302-H314 P280-P305 + P351 + P338-P310
Page 584
Basionics® LQ 11, see 1-Ethyl-3-methylimidazolium diethyl phosphate
Page 1257 691348-10G poly btl 10 g
Basionics® ST 35, see 1-Ethyl-3-methylimidazolium methanesulfonate 691348-100G poly btl 100 g
Page 1258
691348-500G poly btl 500 g
Basionics® ST 62, see Tributylmethylammonium methyl sulfate Page 2467
Basionics® ST 67, see 1-Ethyl-2,3-dimethylimidazolium ethyl sulfate
Page 1230 Basosiv™ M050 8
Basionics® ST 70, see 1-Butyl-3-methylimidazolium chloride Page 582
Basionics® ST 78, see 1-Butyl-3-methylimidazolium methanesulfonate
Magnesium formate O O
Page 583 [557‑39‑1] Merck 14,5666 C2H2MgO4 FW 114.34 Mg
H O O H
Basionics® ST 80, see 1-Ethyl-3-methylimidazolium chloride Page 1256
Basionics® ST 99, see 1,2,3-Trimethylimidazolium methyl sulfate Page 2538
Basionics® ST 33, see 1,2,4-Trimethylpyrazolium methylsulfate Page 2545  produced by BASF
Basionics® VS 01, see 1-Ethyl-3-methylimidazolium thiocyanate Page 1259
Basionics® VS 02, see 1-Butyl-3-methylimidazolium thiocyanate Page 584
MOF (metal organic framework)
Basionics® VS 03, see 1-Ethyl-3-methylimidazolium dicyanamide Page 1256 bulk density ...................................................................................................................................... 0.30‑0.40 g/cm3
Basionics® VS 11, see 1-Ethyl-3-methylimidazolium trifluoromethanesulfonate BET surf. area ...................................................................................................................................... 400-600 m2/g
Page 1259
Basionics® VS 12, see 1-Butyl-3-methylimidazolium trifluoromethanesulfonate 713716-10G poly btl 10 g
Page 585 713716-100G poly btl 100 g
713716-500G poly btl 500 g
Basolite® C 300
Copper benzene-1,3,5-tricarboxylate; Cu-BTC MOF Bathocuproine
C18H6Cu3O12 FW 604.87 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline; BCP
[4733‑39‑5] Merck 14,10212; Beil. 23,IV,2160 C26H20N2 FW 360.45
 produced by BASF
mp .............................................................................................................................................................. 279 to 283 °C
MOF (metal organic framework)
7
can be reactivated at 200°C (vacuum) Warning H302-H413
bulk density .................................................................................................................................................. 0.35 g/cm3
BET surf. area ................................................................................................................................ 1500-2100 m2/g  96%
particle size distribution ........................................................................................................... 15.96 μm (D50) λmax, methanol .................................................................................................................................................. 280 nm
69
Danger H301-H315-H319-H400-H411 P273-P301 + P310-P305 140910-500MG glass btl 500 mg
+ P351 + P338
688614-100G glass btl 100 g  sublimed grade, 99.99% trace metals basis 8
688614-500G glass btl 500 g Organic electronic material useful as OLED electron transporter and
hole blocker.
TGA/DSC Lot specific traces available upon request
fluorescence ............................................................................................................................ λem 386 nm in THF
λmax ............................................................................................................................................................................ 277 nm
mp ................................................................................................................................................................ 285 °C (DSC)

AHB A, 0613, UNP EU
n Behenoylchlorid n
Bathocuproinedisulfonic acid disodium salt hydrate 9-BBN triflate solution

C26H18N2Na2O6S2 · xH2O FW 564.54 9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate solution; 9-BBN
(Anh) triflate solution
O O [62731‑43‑5] C9H14BF3O3S FW 270.08
O S S O
Na O N N O Na  0.5 M in hexanes
H3C CH3 density ............................................................................................................................................. 0.733 g/mL, 25 °C
O
H H
2789
Danger H225-H304-H315-H319-H336-H361f-
mp ................................................................................................................................................................................ 300 °C H373-H411 P210-P261-P273-P281-P301 + P310-
1 2 P305 + P351 + P338
Reagent used for determination of Cu and Cu-protein complexes.
Lit. cited: 1. J. Electroanal. Chem. (Lausanne Switz) 356, 43 (1993) 253138-100ML Sure/Seal™ 100 mL
2. Clin. Chim. Acta 216, 103 (1993)
> BBOT, see 2,5-Bis(5-tert-butyl-benzoxazol-2-yl)thiophene Page 300
146625-1G glass btl 1g BCA, see 2-Butoxyethyl acetate Page 554
146625-5G glass btl 5g BCDC, see (8S,9R)-(−)-N-Benzylcinchonidinium chloride Page 253
BCIP®, see 5-Bromo-4-chloro-3-indolyl phosphate disodium salt Page 447
Bathophenanthroline, 97% BCP, see Bathocuproine Page 222
I-BCP, see 1-Bromo-3-chloropropane Page 448
4,7-Diphenyl-1,10-phenanthroline; BPhen Bct, see Biocytin Page 284
[1662‑01‑7] Beil. 23,V,10,274 C24H16N2
FW 332.40
BDG, see Diethylene glycol butyl ether Page 973
Diethylene glycol monobutyl ether Page 975
BDM, see 2,3-Butanedione monoxime Page 544
B
BDMA, see N,N-Dimethylbenzylamine Page 1072
N N
mp .............................................................................................................................................................. 218 to 220 °C BDPA complex with benzene(1:1), free radical

Used as a bidentate ligand1,2 and for the determination of iron.3 α,γ-Bisdiphenylene-β-phenylallyl
Lit. cited: 1. J. Org. Chem. 58, 7421 (1993) [35585‑94‑5] Fieser 1,57 C39H27
2. Inorg. Chem. 32, 3836 (1993) FW 495.63
3. Anal. Chim. Acta 268, 351 (1992)
•
> Bathophenanthrolinedisulfonic acid disodium salt trihydrate, see Batho-

phenanthrolinedisulfonic acid disodium salt hydrate Page 223 mp ................................................................................................................................................................ 210 °C (dec.)
Bathophenanthrolinedisulfonic acid disodium salt hydrate Page 223
Bathophenanthrolinedisulfonic acid disodium salt hydrate, 98% > (BDP)Cu(H), see Copper hydride (CuH) solution Page 776
(S,S)-BDPP, see (2S,4S)-2,4-Bis(diphenylphosphino)pentane Page 329
BDT, see Biphenyl-4,4′-dithiol Page 287
O
BDTF, see 1,3-Benzodithiolylium tetrafluoroborate Page 234
S ONa Bedford Catalyst, see 2-[Bis(2,4-di-tert-butyl-phenoxy)phosphinooxy]-3,5-di
O • 3H2O (tert-butyl)phenyl-palladium(II) chloride dimer Page 309
O BEDT-TTF, see Bis(ethylenedithio)tetrathiafulvalene Page 332
S ONa Beechwood creosote, see Creosote from beechwood tar Page 784
N N
O
Beeswax
Disodium bathophenanthrolinedisulfonate trihydrate; Bathophenan- Cera alba
throlinedisulfonic acid disodium salt trihydrate; 4,7-Diphenyl-1,10- [8012‑89‑3] Merck 14,1020
phenanthroline-disulfonic acid disodium salt trihydrate
mp ................................................................................................................................................................... 61 to 65 °C
C24H14N2Na2O6S2 · 3H2O FW 590.53
mp ................................................................................................................................................................................ 300 °C  bleached
color .............................................................................................................................................................................. white
146617-5G glass btl 5g 243221-500G poly btl 500 g
Batyl alcohol, 99%  refined

color ............................................................................................................................................................................ yellow
DL-3-Octadecyloxy-1,2-propanediol; rac-Glycerol 1-octadecyl ether; 1-
O-Octadecyl-rac-glycerol 243248-100G poly btl 100 g
[544‑62‑7] Merck 14,1011; Beil. 1,IV,2758 243248-500G poly btl 500 g
CH3(CH2)17OCH2CH(OH)CH2OH FW 344.57
Behenic acid, 99%
mp .................................................................................................................................................................... 71 to 73 °C
Docosanoic acid
B402-1G glass btl 1g
[112‑85‑6] Merck 14,1023; Beil. 2,IV,1290 CH3(CH2)20COOH
> Baysilone®, see Silicone grease Bayer Page 2277 FW 340.58
BB1, see trans-2-Bromovinylboronic acid MIDA ester Page 538 mp ................................................................................................................................................................... 72 to 80 °C
BBBPY, see 4,4′-Di-tert-butyl-2,2′-dipyridyl Page 900
BBDI, see Boc-1-tert-butoxy-1,2-dihydroisoquinoline Page 384 216941-5G poly btl 5g
BBL, see Poly(benzimidazobenzophenanthroline) Page 2091
9-BBN, see 9-Borabicyclo[3.3.1]nonane solution Page 419 Behenic-d43 acid
9-Borabicyclo[3.3.1]nonane dimer Page 419
[29823‑26‑5] CD3(CD2)20CO2H FW 383.85
 98 atom % D
Behenoyl chloride, ≥99.0% (GC)

Docosanoyl chloride
[21132‑76‑3] Beil. 2,III,1076 CH3(CH2)20COCl FW 359.03
5
Danger H314 P280-P305 + P351 + P338-P310
AHB A, 0613, UNP EU
n Behpmehppv n
> BEHP-co-MEH-PPV, see Poly{[2-[2′,5′-bis(2″-ethylhexyloxy)phenyl]-1,4-phenyl- Benzaldehyde-18O
enevinylene]-co-[2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylenevinylene]}
8
Page 2093 C7H618O FW 108.12 18O
BEHP-PPV, see Poly[2-(2′,5′-bis(2″-ethylhexyloxy)phenyl)-1,4-phenylenevi-
nylene] Page 2092 H
BEMP on polystyrene, see 2-tert-Butylimino-2-diethylamino-1,3-dimethyl-
perhydro-1,3,2-diazaphosphorine on polystyrene Page 576
BEMP resin, see 2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-
bp ....................................................................................................................................................................... 178-179 °C
diazaphosphorine, polymer-bound Page 576
 95 atom % 18O
Bengal Rose B bound to Polystyrene mol wt 108.06, atom % calculation
Rose bengal B bound to polystyrene Cl density ............................................................................................................................................. 1.064 g/mL, 25 °C
7
Cl Cl Warning H302
ONa
Cl
O
707465
I I
Benzaldehyde-α-13C
O O O Benzaldehyde-carbonyl-13C
I I
[10383‑90‑1] C6H513CHO FW 107.11
B mp ....................................................................... −26 °C n20
bp ............................................................... 178-179 °C
D .......................................................................... 1.545
 200-400 mesh, loading: ~0.1 mmol/g

Sales restrictions may apply  99 atom % 13C
Heterogenous photo-sensitizer for the generation of singlet oxygen mol wt 107.11, atom % calculation
used in photooxygenation reactions1,2,3,4 density ............................................................................................................................................. 1.055 g/mL, 25 °C
matrix ........................................................................................................................... crosslinked with 1% DVB
488127-500MG ampule 500 mg
Lit. cited: 1. N.V. Shinkarenko, V.B. Aleskovskii, Russ. Chem. Rev. 50, 220
(1981) Benzaldehyde-α-d1
2. J.J. Lamberts, D.C. Neckers, J. Am. Chem. Soc. 105, 7465 (1983)
3. R.S. Handley et al., Tetrahedron Lett. 26, 3183 (1985) Benz(aldehyde-d)
4. A.P. Schaap et al., Tetrahedron Lett. 28, 1159 (1987) [3592‑47‑0] Beil. 7,III,825 C6H5CDO FW 107.13
mp ....................................................................... −26 °C n20
D .......................................................................... 1.545
bp ............................................................... 178-179 °C
> Benomyl, see Methyl 1-(butylcarbamoyl)-2-benzimidazolecarbamate
Page 1753  98 atom % D
Bentonite density ............................................................................................................................................. 1.055 g/mL, 25 °C
Montmorillonite 488135-1G ampule 1g
Al2O3 • 4SiO2 • H2O
[1302‑78‑9] Merck 14,1056; 14,1055
Benzaldehyde-α-13C,α-d1
285234-500G poly btl 500 g
[155638‑70‑3] C6H513CDO FW 108.12
285234-2.5KG poly drum 2.5 kg
 99 atom % 13
C; 99 atom % D
> Benz[e]acephenanthrylene-d12, see Benzo[b]fluoranthene-d12 Page 235
Benzacylic acid sodium salt, see 2-Hydroxybenzo[a]carbazole-3-carboxylic 491829 Full product information at Aldrich.com
acid sodium salt Page 1473
Benzalacetone, see 4-Phenyl-3-buten-2-one Page 2026 Benzaldehyde-2,3,4,5,6-d5
Benzalacetophenone, see 1,3-Diphenyl-2-propenone Page 1153 [14132‑51‑5] C6D5CHO FW 111.15
trans-Benzalacetophenone oxide, see trans-1,3-Diphenyl-2,3-epoxypropan-1-
one Page 1141 mp ....................................................................... −26 °C n20
D .......................................................................... 1.545
Benzal bromide, see α,α-Dibromotoluene Page 894 bp ............................................................... 178-179 °C

Benzal chloride, see α,α-Dichlorotoluene Page 949
 99 atom % D
Benzaldehyde mol wt 111.11, atom % calculation
Artificial essential oil of almond density ............................................................................................................................................. 1.094 g/mL, 25 °C
[100‑52‑7] Merck 14,1058; Beil. 7,IV,505; Fieser 1,46; 6,26 C6H5CHO 488119-5G ampule 5g
FW 106.12
mp ....................................................................... −26 °C vd ................................................................ 3.7 (vs air) Benzaldehyde-d6
bp ............................................................... 178-179 °C vp ................................................ 4 mmHg (45 °C) [17901‑93‑8] C6D5CDO FW 112.16
density ................................... 1.044 g/cm3, 20 °C ait ......................................................................... 374 °F mp ....................................................................... −26 °C n20
D .......................................................................... 1.545
n20
D .............................................................................. 1.545 bp ............................................................... 178-179 °C
7
Warning H302
 98 atom % D
 purified by redistillation, ≥99.5% density ............................................................................................................................................. 1.103 g/mL, 25 °C
7
Warning H302
 ReagentPlus®, ≥99% 485551-5G ampule 5g

Chlorine-free Benz-13C6-aldehyde
B1334-2ML 2 mL Benzaldehyde-(phenyl-13C6)
B1334-250ML 250 mL 13
C6H5CHO FW 112.08
B1334-1L 1L mp ................................................................................................................................................................................ -26 °C
B1334-2.5L 2.5 L bp ....................................................................................................................................................................... 178-179 °C
B1334-18KG steel drum 18 kg
 99 atom % 13C
density ............................................................................................................................................. 1.103 g/mL, 25 °C

AHB A, 0613, UNP EU
n Benzamide n
7
Warning H302 Benzaldehyde semicarbazone, 97%
[1574‑10‑3] C6H5CH=NNHC(O)NH2 FW 163.18
586412-500MG ampule 500 mg
> Benzaldehyde N-(tert-butoxycarbonyl)imine, see tert-Butyl (phenyl- 568449-1G glass btl 1g
methylene)carbamate Page 590
> Benzaldehyde-2-sulfonic acid sodium salt, see 2-Formylbenzenesulfonic
2-(Benzaldehyde diethylacetal)magnesium bromide 8 acid sodium salt Page 1363
solution 2-Formylbenzenesulfonic acid sodium salt hydrate Page 1363
C11H15BrMgO2 FW 283.44 MgBr
Benzalkonium chloride
O CH3
Alkyldimethylbenzylammonium chloride; Alkylbenzyldimethylammo-
O CH3
nium chloride
[63449‑41‑2] Merck 14,1059 C6H5CH2N(CH3)2RCl (R=C8H17 to
 1 M in THF C18H37)
density ............................................................................................................................................. 1.049 g/mL, 25 °C Predominantly C12H25N(CH3)2C7H7Cl.
Also contains C14 and C16 homologs.
257
Danger H225-H314-H335-EUH019-EUH014 P210-
P261-P280-P305 + P351 + P338-P310
579
Danger H302-H312-H314-H400 P273-P280-P305 +
234427-5G
P351 + P338-P310
glass btl 5g
B
3-(Benzaldehyde diethylacetal)magnesium bromide 8
solution 234427-100G glass btl 100 g
C11H15BrMgO2 FW 283.44
O CH3
Benzalkonium chloride solution, ≥50% (ex Cl)
O CH3
Alkylbenzyldimethylammonium chloride Cl CH3
MgBr
[63449‑41‑2] N CH2(CH2)nCH3
CH3
density ............................................................................................................................................. 1.006 g/mL, 25 °C
 1 M in THF  50% in H2O
257
579
Danger H302-H314-H400 P273-P280-P305 + P351 +
P261-P280-P305 + P351 + P338-P310 P338-P310
732729-50ML Sure/Seal™ 50 mL 63249-500ML 500 mL
63249-2.5L 2.5 L
4-(Benzaldehyde diethylacetal)magnesium bromide 8
solution 63249-4X2.5L 4 × 2.5 L
63249-25KG 25 kg
C11H15BrMgO2 FW 283.44 MgBr
H3C O Benzalphthalide
H3C O 3-Benzylidenephthalide
[575‑61‑1] Beil. 17,376 C15H10O2 FW 222.24 O
 1 M in THF O
density ............................................................................................................................................. 1.013 g/mL, 25 °C
mp ................................................................................................................................................................. 99 to 102 °C
257
P261-P280-P305 + P351 + P338-P310 B1806-100G poly btl 100 g
732737-50ML Sure/Seal™ 50 mL Benzamide
Benzaldehyde dimethyl acetal Benzoic acid amide
α,α-Dimethoxytoluene [55‑21‑0] Merck 14,1060; Beil. 9,IV,725 C6H5CONH2 FW 121.14
[1125‑88‑8] Beil. 7,IV,513 C6H5CH(OCH3)2 FW 152.19 Inhibits poly(ADP-ribose) polymerase (PARP).
bp .......................................... 87-89 °C/18 mmHg n20
D .......................................................................... 1.493
mp .............................................................................................................................................................. 125 to 128 °C
7
density ..................................... 1.014 g/mL, 25 °C Warning H302
7
 purified by sublimation, ≥99.5%
 99% 399337-5G glass btl 5g
226076-100G glass btl 100 g
 99%
226076-500G glass btl 500 g
 95% 135828-100G poly btl 100 g
Benzamide-15N
> Benzaldehyde 2,4-disulfonic acid disodium salt, see 4-Formylbenzene-1,3- [31656‑62‑9] C6H5CO15NH2 FW 122.13
disulfonic acid disodium salt hydrate Page 1363
mp .............................................................................................................................................................. 125 to 128 °C
(E)-Benzaldehyde oxime, 97%  98 atom % 15N
[622‑31‑1] Beil. 7,218 C6H5CH=NOH FW 121.14 mol wt 122.12, atom % calculation
mp ............................................................ 34 to 36 °C n20
7
D .......................................................................... 1.591 Warning H302
bp .................................................. 104 °C/6 mmHg
7
Benzamide-α-13C
245674-50G glass btl 50 g [88058‑12‑2] C6H513CONH2 FW 122.13
 99 atom % 13
C

AHB A, 0613, UNP EU
n Benzamideoxime n
Benzamide oxime, 97% 8  98%

N-Hydroxybenzamide OH
N
[613‑92‑3] C7H8N2O FW 136.15 B2403-500MG glass btl 500 mg
NH2 B2403-1G glass btl 1g
 sublimed grade, 99.99% trace metals basis

mp .................................................................................................................................................................... 74 to 78 °C p-Type organic conductor and OLED dopant. Sublimed grade for
6
Danger H301-H315-H319-H335 P261-P301 + P310-P305 + P351 + organic electronic device applications.
P338 TGA/DSC Lot specific traces available upon request
717436-1G glass btl 1g fluorescence .......................................................................... λem 481, 514 nm in dichloromethane-d2
λmax ............................................................................................................................................................................ 277 nm
Benzamidine, ≥95.0% (NT) LOH ............................................................................................................... 0.5 wt. %, 216.14°C (typical, TGA)
[618‑39‑3] Beil. 9,IV,898 C6H5C(=NH)NH2 FW 120.15 698415-1G glass btl 1g
mp .................................................................................................................................................................... 65 to 70 °C
> 2,3-Benzanthracene, see Benz[b]anthracene Page 226
7
Warning H302-H319 P305 + P351 + P338
Benz[a]anthracene-d12
B
1,2-Benzanthracene-d12; Tetraphene-d12
[1718‑53‑2] C18D12 FW 240.36
Benzamidine hydrochloride, 99% mp .............................................................................................................................................................. 157 to 159 °C
[1670‑14‑0] C6H5C(=NH)NH2 · HCl FW 156.61  98 atom % D
mp .............................................................................................................................................................. 169 to 173 °C mol wt 240.13, atom % calculation
7 89
Warning H315-H319-H335 P261-P305 + P351 + P338 Danger H350-H410 P201-P273-P308 + P313-P501

Benzene
Benzamidine hydrochloride hydrate, ≥99% [71‑43‑2] Merck 14,1066; Beil. 5,IV,583 C6H6 FW 78.11
Amidinobenzene hydrochloride; Benzamidinium chloride; Benzene-
carboximidamide hydrochloride
[206752‑36‑5] Beil. 9,IV,898 C6H5C(=NH)NH2 · HCl · xH2O mp .......................................................................... 5.5 °C vd ............................................................. 2.77 (vs air)
FW 156.61 (Anh) bp ............................................................................ 80 °C vp ......................................... 74.6 mmHg (20 °C)
mp .................................................................................................................................................................... 86 to 88 °C density ..................................... 0.874 g/mL, 25 °C vp ....................................... 166 mmHg (37.7 °C)
n20
D .............................................................................. 1.501 ait ...................................................................... 1043 °F
7
Warning H315-H319-H335 P261-P305 + P351 + P338
278
store at: 2-8°C Danger H225-H304-H315-H319-H340-H350-H372
P201-P210-P301 + P310-P305 + P351 + P338-P308 +
B6506-5G glass btl 5g P313-P331
B6506-25G glass btl 25 g
Environmental carcinogen; hematoxin that is linked to increased
> Benzamidinium chloride, see Benzamidine hydrochloride hydrate incidence of leukemia in humans.
Page 226 water .......................................................................................................................................................................... ≤0.02%
Benzamidomethanol, see N-(Hydroxymethyl)benzamide Page 1495
evapn. residue ..................................... <0.0005% 300 nm ............................................................. 0.06
λ ............................................................................ vs H2O 330 nm ............................................................. 0.02
Benzanilide, 98%
280 nm .................................................................... 1.0 350-400 nm ................................................... 0.01
N-Benzoylaniline; N-Phenylbenzamide 290 nm ................................................................. 0.15
[93‑98‑1] Merck 14,1061; Beil. 12,IV,417 C6H5CONHC6H5 FW 197.23
mp .............................................................................................................................................................. 161 to 163 °C
270709-2.5L 2.5 L
bp ....................................................................................................................................................... 117 °C/10 mmHg
270709-4X2.5L 4 × 2.5 L
108227-100G poly btl 100 g  anhydrous, 99.8%
water ....................................................................................................................................................................... <0.001%
Benz[a]anthracene, 99%
water ..................................................................................................................................... <0.005% (100 mL pkg)
1,2-Benzanthracene; Tetraphene evapn. residue ............................................................................................................................................. <0.0005%
[56‑55‑3] Merck 14,1062; Beil. 5,IV,2549 C18H12 401765-100ML Sure/Seal™ 100 mL
FW 228.29
mp .............................................................................................................................................................. 157 to 159 °C 401765-10L ss drum 10 L
bp ............................................................................................................................................................................. 437.6 °C
89
Danger H350-H410 P201-P273-P308 + P313-P501
S compounds ................................................................................................................................................... ≤0.005%
B2209-500MG glass btl 500 mg H2SO4 ................................................................................................................................... passes test (darkened)
thiophene ................................................................................................................. passes test (limit ∼1ppm)
Water .......................................................................................................................................................................... ≤0.05%
Benz[b]anthracene APHA color .................................................................................................................................................................... ≤10
evapn. residue ................................................................................................................................................ ≤0.001%
Tetracene; 2,3-Benzanthracene; Naphthacene
[92‑24‑0] Merck 14,6369; Beil. 5,IV,2545 C18H12 676985-1L alum btl 1L
FW 228.29 676985-4L alum btl 4L
mp ............................................................................................................................................................................ >300 °C

AHB A, 0613, UNP EU
n Benzenecarboxim n
 ≥99.0%, ACS reagent  "100%", 99.96 atom % D

S compounds ................................................................................................................................................... ≤0.005% pk = 10 × 0.5 mL
H2SO4 ................................................................................................................................... passes test (darkened) 236977-1PAK ampule 1 pkg
thiophene ................................................................................................................. passes test (limit ∼1ppm)
water ........................................................................................................................................................................... ≤0.05%  "100%", 99.96 atom % D
APHA color .................................................................................................................................................................... ≤10 pk = 10 × 0.75 mL
evapn. residue ................................................................................................................................................ ≤0.001% 549118-1PAK ampule 1 pkg
 "100%", 99.96 atom % D
pk = 10 × 1 mL
319953-4X2L 4×2L 434515-1PAK ampule 1 pkg
319953-20L steel drum 20 L  "100%", 99.96 atom % D, contains 0.03 % (v/v) TMS
Benzene-d1 561509-10X.75ML ampule 10 × 0.75 mL
[119516‑83‑5] C6H5D FW 79.12  99.6 atom % D
mp .......................................................................... 5.5 °C n20
D .......................................................................... 1.498
151815-5G ampule 5g
B
bp ............................................................................ 80 °C
151815-10G ampule 10 g
 98 atom % D 151815-25G glass btl 25 g
density ............................................................................................................................................. 0.885 g/mL, 25 °C 151815-100G Sure/Seal™ 100 g
278
Danger H225-H304-H315-H319-H340-H350-H372
P201-P210-P301 + P310-P305 + P351 + P338-P308 +  99.6 atom % D
P313-P331 522104-10G glass btl 10 g
175722-1G ampule 1g
175722-5G ampule 5g  99.6 atom % D 8
13 718262-10X0.5ML ampule 10 × 0.5 mL
Benzene- C1
718262-10X0.6ML ampule 10 × 0.6 mL
13
[6998‑50‑1] CC5H6 FW 79.10
mp .......................................................................... 5.5 °C n20
D .......................................................................... 1.501  99.6 atom % D
bp ............................................................................ 80 °C pk = 10 × 0.75 mL
 99 atom % 13C
mol wt 79.10, atom % calculation  99.6 atom % D
density ............................................................................................................................................. 0.885 g/mL, 25 °C pk = 10 × 1 mL
278
Danger H225-H304-H315-H319-H340-H350-H372 236888-1PAK ampule 1 pkg
P201-P210-P301 + P310-P305 + P351 + P338-P308 +
P313-P331  99.6 atom % D, contains 0.03 % (v/v) TMS
485632-100MG ampule 100 mg 364940-5G 5g
Benzene-1,3,5-d3 364940-10G ampule 10 g
[1684‑47‑5] Beil. 5,III,518 C6H3D3 FW 81.13
mp .......................................................................... 5.5 °C n20
D .......................................................................... 1.499
bp ............................................................................ 80 °C
 99.6 atom % D, contains 1 % (v/v) TMS
 98 atom % D 233358-10G ampule 10 g
density ............................................................................................................................................. 0.908 g/mL, 25 °C 233358-50G glass btl 50 g
278
Danger H225-H304-H315-H319-H340-H350-H372
P201-P210-P301 + P310-P305 + P351 + P338-P308 +  99 atom % D
P313-P331 175978-10G ampule 10 g
343765-500MG ampule 500 mg 175978-50G glass btl 50 g
Benzene-d5  anhydrous, 99.6 atom % D

[13657‑09‑5] C6HD5 FW 83.14 water ..................................................................................................................................................................... <10 ppm
 99 atom % D
Benzene-12C6
278
Danger H225-H304-H315-H319-H340-H350-H372
P201-P210-P301 + P310-P305 + P351 + P338-P308 + 12
P313-P331 C6H6 FW 78.05
485330-5G ampule 5g  99.9 atom % 12
C
Benzene-d6
Hexadeuterobenzene > Benzeneboronic acid, see Phenylboronic acid Page 2024
Benzene-1-boronic acid-4-boronic acid MIDA ester, see Benzene-1,4-
[1076‑43‑3] Beil. 5,IV,630 C6D6 FW 84.15 diboronic acid mono-MIDA ester Page 228
mp .......................................................................... 6.8 °C density .................................. 0.950 g/mL, 25 °C Benzenecarboximidamide hydrochloride, see Benzamidine hydrochloride
bp ........................................... 79.1 °C/760 mmHg n20 D .......................................................................... 1.497 hydrate Page 226
278
Danger H225-H304-H315-H319-H340-H350-H372
P201-P210-P301 + P310-P305 + P351 + P338-P308 +
P313-P331
 "100%", 99.96 atom % D
175870-5G ampule 5g
AHB A, 0613, UNP EU
n Benzenechromium n
Benzene-chromium(0) tricarbonyl, 98% 1,3-Benzenedimethanethiol, 95%

Benzene-tricarbonylchromium(0) [41563‑69‑3] Beil. 6,914 C6H4(CH2SH)2 FW 170.30
[12082‑08‑5] Beil. 5,IV,625; Fieser 6,27; 13,19 (C6H6)Cr(CO)3 bp .................................... 168-170 °C/25 mmHg n20 D ....................................................................... 1.6207
FW 214.14 density ........................................ 1.15 g/mL, 25 °C
7
7
119318-1G glass btl 1g 1,4-Benzenedimethanethiol, 98%
[105‑09‑9] Beil. 6,919 C6H4(CH2SH)2 FW 170.30
Benzenecyclopentadienyliron(II) hexafluorophosphate mp ................................................................................................................................................................... 45 to 46 °C
[12176‑31‑7] C11H11F6FeP FW 344.01 bp ...................................................................................................................................................... 156 °C/12 mmHg
7
Warning H315-H319-H335 P261-P305 + P351 + P338
PF6
Fe
B solid
mp ................................................................................................................................................................. 268 °C (dec.)
1,2-Benzenedimethanol, 97%
1,2-Bis(hydroxymethyl)benzene; Phthalyl alcohol; o-Xylene-α,α′-diol
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[612‑14‑6] Beil. 6,IV,5953; Fieser 16,18 C6H4(CH2OH)2 FW 138.16
mp ................................................................................................................................................................... 63 to 65 °C
594334-1G 1g
> 1,3-Benzenediamine, see m-Phenylenediamine Page 2031
Benzene-1,4-diboronic acid 1,3-Benzenedimethanol, 98%
p-Phenylenediboronic acid; Benzene-1,4-diboronic acid m-Xylene-α,α′-diol
[4612‑26‑4] C6H4[B(OH)2]2 FW 165.75 [626‑18‑6] Beil. 6,914 C6H4(CH2OH)2 FW 138.16
Contains varying amounts of anhydride mp ................................................................................................................................................................... 56 to 60 °C
mp ............................................................................................................................................................................ >350 °C bp ............................................................................................................................................ 154-159 °C/13 mmHg
1,4-Phenylenebisboronic acid 196533-10G glass btl 10 g
7
Warning H302
1,4-Benzenedimethanol, 99%
417130-5G glass btl 5g p-Phenylene dicarbinol; p-Xylylene dialcohol; p-Xylene-α,α′-diol
417130-25G glass btl 25 g [589‑29‑7] Beil. 6,IV,5971 C6H4(CH2OH)2 FW 138.16
mp .............................................................................................................................................................. 114 to 118 °C
1,4-Benzenediboronic acid bis(pinacol) ester, 97%
bp ............................................................................................................................................... 138-143 °C/1 mmHg
1,4-Benzenediboronic acid dipinacol H3C CH3
O O
B3000
ester; 1,4-Bis(4,4,5,5-Tetramethyl-1,3,2- H3C CH3
B B
dioxaborolan-2-yl)benzene H3C O O CH3 > 1,2-Benzenediol, see 1,2-Dihydroxybenzene Page 1015
[99770‑93‑1] C18H28B2O4 FW 330.03 H3C CH3 Pyrocatechol Page 1015
1,3-Benzenediol, see Resorcinol Page 2246
mp .............................................................................................................................................................. 241 to 245 °C Benzene-1,2-disulfonic acid dipotassium salt, see Potassium benzene-1,2-
disulfonate Page 2159
663816-5G glass btl 5g Benzene-1,3-disulfonic acid disodium salt, see Sodium benzene-1,3-
disulfonate Page 2292
> 1,4-Benzenediboronic acid dipinacol ester, see 1,4-Benzenediboronic acid
bis(pinacol) ester Page 228
Benzene-1,2-disulfonyl chloride, ≥97.0% (AT)
Benzene-1,4-diboronic acid mono-MIDA ester 8 [6461‑76‑3] Beil. 11,II,112 C6H4Cl2O4S2 FW 275.13 O
Benzene-1-boronic acid-4-boronic acid MIDA H3C S Cl
ester N O
O
[1104665‑01‑1] C11H13B2NO6 FW 276.85 B
O S Cl
O O
HO O O
B
OH
mp .............................................................................................................................................................. 140 to 146 °C
5
mp .............................................................................................................................................................. 170 to 175 °C Danger H314 P280-P305 + P351 + P338-P310
> Benzene-1,2-dicarboxaldehyde, see Phthaldialdehyde Page 2068 Benzene-1,3-disulfonyl chloride, 97%

Benzene-1,3-dicarboxaldehyde, see Isophthalaldehyde Page 1576 [585‑47‑7] Beil. 11,IV,553 C6H4(SO2Cl)2 FW 275.13
Benzene-1,4-dicarboxaldehyde, see Terephthalaldehyde Page 2361
1,2-Benzenedicarboxylic acid, see Phthalic acid Page 2068 mp ................................................................................................................................................................... 57 to 60 °C
Benzene-1,3-dicarboxylic acid, see Isophthalic acid Page 1576
58
Danger H314-H317-H334 P261-P280-P305 + P351 + P338-
P310
1,2-Benzenedimethanethiol, 95%
[2388‑68‑3] Beil. 6,910 C6H4(CH2SH)2 FW 170.30 444642-10G glass btl 10 g
mp .................................................................................................................................................................... 43 to 45 °C
bp ....................................................................................................................................................... 160 °C/20 mmHg Benzene-1,2-dithiol, 96%
7
Warning H315-H319-H335 P261-P305 + P351 + P338 1,2-Dimercaptobenzene
[17534‑15‑5] Beil. 6,IV,5651 C6H4(SH)2 FW 142.24
306738-1G glass btl 1g mp ............................................................ 22 to 24 °C density ................................. 1.236 g/mL, 25 °C
bp .................................... 119-120 °C/17 mmHg

AHB A, 0613, UNP EU
n Benzenesulfonyl n
Benzene-1,3-dithiol, 99% Benzenesulfonamide, ≥98%

1,3-Dimercaptobenzene [98‑10‑2] Beil. 11,IV,50 C6H5SO2NH2 FW 157.19
[626‑04‑0] Beil. 6,IV,5705 C6H4(SH)2 FW 142.24 mp .............................................................................................................................................................. 149 to 152 °C
7
mp .................................................................................................................................................................... 24 to 25 °C Warning H302
bp ............................................................................................................................................ 128-129 °C/16 mmHg
57
Danger H315-H318-H335 P261-P280-P305 + P351 + P338 108146-5G glass btl 5g
108146-100G poly btl 100 g
Benzenesulfonamide-13C6, 98% (CP) 8
> Benzenehexacarboxylic acid, see Mellitic acid Page 1657 13
Benzene, 1-methyl-4-(1-methylethyl)-, ruthenium complex, see Dichloro(p- C6H5SO2NH2 FW 163.15
cymene)ruthenium(II) dimer Page 922 mp .............................................................................................................................................................. 149 to 152 °C
Benzeneruthenium(II) chloride dimer  99 atom % 13C

[37366‑09‑9] Ru2(C6H6)2Cl4 FW 500.18
7
Warning H302
7
Warning H315-H319-H335 P261-P305 + P351 + P338

719285 B
341568-5G glass btl 5g Benzenesulfonic acid
A product of Umicore. [98‑11‑3] Merck 14,1070; Beil. 11,IV,27 C6H5SO3H FW 158.18
56
Danger H301-H315-H318 P280-P301 + P310-P305 + P351 +
P338
 98.0% (T)
> Benzeneselenenyl chloride, see Phenylselenyl chloride Page 2052 water ............................................................................................................................................................................. ≤1.0%
Benzeneseleninic acid, 99% 12635-25G-F glass btl 25 g

12635-100G-F glass btl 100 g
[6996‑92‑5] Beil. 11,IV,708; Fieser 10,22; 8,28; 9,32 C6H5SeO2H
12635-500G-F glass btl 500 g
FW 189.07
12635-1KG-F glass btl 1 kg
mp .............................................................................................................................................................. 121 to 124 °C
689  technical grade, 90%

Danger H301-H331-H373-H410 P261-P273-P301 +
P310-P311-P501
135070-100G glass btl 100 g
Benzeneseleninic acid anhydride, 70% Benzenesulfonic acid monohydrate, 97%
[17697‑12‑0] Beil. 11,H,422; Fieser 13,28; 6,240; 9,32; 10,22; 15,18; 8,29; [26158‑00‑9] Beil. 11,26 C6H5SO3H · H2O FW 176.19
7,139 C6H5SeOOSeOC6H5 FW 360.13
mp ................................................................................................................................................................... 42 to 49 °C
mp .............................................................................................................................................................. 165 to 170 °C
57
Danger H302-H312-H314-H332 P280-P305 + P351 + P338-
benzeneseleninic acid ....................................................................................................................................... <30% P310
689
Danger H301-H330-H373-H410 P260-P273-P284-P301
+ P310-P310-P501
448737-250G glass btl 250 g
213012-5G glass btl 5g > Benzenesulfonic acid, 3′, 3′′, 3′′′-phosphinidynetris[4,6-dimethyl-trisodium
salt], see Tris(2,4-dimethyl-5-sulfophenyl)phosphine trisodium salt
Benzeneselenol, 97% Page 2571
[645‑96‑5] Beil. 6,IV,1777; Fieser 8,447; 6,28; 10,412; 9,35; 11,537 Benzenesulfonyl azide, polymer-bound
C6H5SeH FW 157.07
bp .......................................... 71-72 °C/18 mmHg n20
D .......................................................................... 1.616  macroporous, 50-100 mesh, loading: ~1.5 mmol/g
density ..................................... 1.479 g/mL, 25 °C Polymer-supported diazo transfer agent.1
Lit. cited: 1. Green, G.M. et al., J. Org. Chem. 66, 2509 (2001)
689
Danger H301-H331-H373-H410 P261-P273-P301 +
P310-P311-P501 572977-5G glass btl 5g
> 1-Benzenesulfonyl-3-bromo-1H-indole, see 3-Bromo-(1-phenylsulfonyl)
indole Page 517
Benzenesulfinic acid sodium salt, 98%
Sodium benzenesulfinate Benzenesulfonyl chloride
[873‑55‑2] Beil. 11,IV,3; Fieser 6,526 C6H5SO2Na FW 164.16 [98‑09‑9] Merck 14,1072; Beil. 11,IV,49; Fieser 1,46; 5,22 C6H5SO2Cl
mp ............................................................................................................................................................................ >300 °C FW 176.62
Substrate used for the synthesis of aryl sulfones via copper-catalyzed mp ............................................................ 13 to 15 °C n20D .......................................................................... 1.551
cross-coupling with boronic acids1 and vinyl sulfones via reaction bp ............................................................... 251-252 °C vp ......................................... 0.04 mmHg (20 °C)
with vicinal dibromides.2 density ..................................... 1.384 g/mL, 25 °C
578
Danger H302-H314-H317-H332-H334 P261-P280-P305
2. Synthesis 1465 (2007) + P351 + P338-P310
123579-25G poly btl 25 g
 99%
123579-100G poly btl 100 g Useful reagent for preparing α-disulfones.1
123579-500G poly btl 500 g Lit. cited: 1. Synthesis 490 (1993)
108138-100G glass btl 100 g
108138-500G glass btl 500 g

AHB A, 0613, UNP EU
n Benzenesulfonyl n
Benzenesulfonyl chloride (continued) 1,2,4,5-Benzenetetramine tetrahydrochloride
1,2,4,5-Tetraaminobenzene tetrahydrochloride
 96%
[4506‑66‑5] Beil. 13,H,337 C6H2(NH2)4·4HCl FW 284.01
108111-25G glass btl 25 g mp ............................................................................................................................................................................ ≥300 °C
 technical grade
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Benzenesulfonyl cyanide, ≥98.0% (HPLC)
Phenylsulfonyl cyanide O
[24224‑99‑5] C7H5NO2S FW 167.19 S CN 305065-5G glass btl 5g
O
Benzenethionosulfonic acid sodium salt, 85%
density ............................................................................................................................................. 1.274 g/mL, 20 °C [1887‑29‑2] Beil. 11,87 C6H5S(=S)(=O)ONa FW 196.22
mp ................................................................................................................................................................ 275 °C (dec.)
 technical
n20
D ...................................................................................................................................................................................... 1.531  technical grade
B 6
Danger H301-H311-H331 P261-P280-P301 + P310-P311 385891-25G glass btl 25 g
Benzene-1,3,5-triacetic acid, ≥97.0% (T)

1,3,5-Tris(carboxymethyl)benzene O
Benzenesulfonyl fluoride, 99% [4435‑67‑0] C12H12O6 FW 252.22 OH
[368‑43‑4] Beil. 11,II,23; Fieser 11,40 C6H5SO2F FW 160.17
O O
bp ............................................................... 207-208 °C n20
D .......................................................................... 1.492
density ..................................... 1.333 g/mL, 25 °C HO OH
56
Danger H302-H312-H314-H331 P261-P280-P305 + P351 +
P338-P310
Building block and core molecule for generating diverse libraries in
combinatorial chemistry1; preparation of giant propeller molecules2,3,4
282332-5G glass btl 5g Lit. cited: 1. T. Carell et al., Chem. Biol. 2, 171 (1995)
2. S. Brandl et al., J. Prakt. Chem. 338, 451 (1996)
Benzenesulfonyl hydrazide, 98%
3. L. Tong et al., J. Am. Chem. Soc. 119, 7291 (1997)
BSH; Porofor BSH; Benzenesulfonylhydrazine 4. J.S. Bradshaw, K.E. Krakowiak, J. Heterocycl. Chem. 35, 519 (1998)
[80‑17‑1] Merck 14,7598; Beil. 11,IV,94; Fieser 7,13 C6H5SO2NHNH2
7
Warning H315-H319-H335 P261-P305 + P351 + P338
FW 172.20
mp .............................................................................................................................................................. 101 to 103 °C 17383-500MG poly tube 500 mg
2
Danger H242
1,3,5-Benzenetricarbonyl trichloride, 98%
B3809-25G glass btl 25 g Trimesic acid trichloride; Benzene-1,3,5-tricarbonyl chloride; Trimesoyl
chloride
[4422‑95‑1] Beil. 9,IV,3748 C6H3(COCl)3 FW 265.48
Benzenesulfonyl isocyanate, 95% mp ............................................................ 32 to 38 °C density ................................. 1.487 g/mL, 25 °C
bp ............................................... 180 °C/16 mmHg
[2845‑62‑7] Beil. 11,H,45; Fieser 1,48 C6H5SO2NCO FW 183.18
bp .................................................. 130 °C/9 mmHg n20
D .......................................................................... 1.536 Starting material for two tritopic amides derived from 3- and 4-
density ..................................... 1.369 g/mL, 25 °C methylaminopyridine which self-assembled into nanoballs on
treatment with palladium(II) nitrate in DMSO.1
78
+ P351 + P338-P342 + P311 Lit. cited: 1. J. Org. Chem. 71, 8412 (2006)
57
232297-10G glass btl 10 g Danger H302-H314-EUH014 P280-P305 + P351 + P338-P310
> Benzenesulfonylnitromethane, see Nitromethyl phenyl sulfone Page 1918

(Benzenesulfonylphenylmethyl)carbamic acid tert-butyl ester, see N-Boc-α- 147532-10G poly btl 10 g
(phenylsulfonyl)benzylamine Page 406 147532-25G poly btl 25 g
1,2,4,5-Benzenetetracarbonitrile, see 1,2,4,5-Tetracyanobenzene Page 2376
147532-100G poly btl 100 g
1,2,4,5-Benzenetetracarboxamide, 97% 147532-500G poly btl 500 g

147532-12X500G poly btl 12 × 500 g
[6183‑35‑3] C6H2(CONH2)4 FW 250.21
472115-5G glass btl 5g 1,2,3-Benzenetricarboxylic acid hydrate, 98%
Hemimellitic acid
1,2,4,5-Benzenetetracarboxylic acid, 96%
[732304‑21‑1] Beil. 9,976 C6H3(CO2H)3·xH2O FW 210.14 (Anh)
Pyromellitic acid mp ............................................................................................................................................... 190 to 192 °C (dec.)
[89‑05‑4] Merck 14,8004; Beil. 9,997 C6H2(CO2H)4 FW 254.15
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .......................................................................................................................................................... 281 to 284.5 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338 B4201-1G glass btl 1g
B4007-100G-A poly btl 100 g
B4007-500G-A poly btl 500 g 1,2,3-Benzenetricarboxylic acid hydrate, ≥98.0% (T, calc. based
on dry substance)
> Benzene-1,2,4,5-tetracarboxylic dianhydride, see Pyromellitic dianhydride
Page 2228
Hemimellitic acid hydrate OH
O
[732304‑21‑1] Beil. 9,IV,3745 C9H6O6 · xH2O OH
1,2,4,5-Benzenetetracarboxylic dianhydride-d2, 98% (CP) FW 210.14 (Anh) O

OH
[106426‑63‑5] C10D2O6 FW 220.13
O
 98 atom % D
456330 Full product information at Aldrich.com mp ............................................................................................................................................................. ~195 °C (dec.)
may contain up to 2 mol water
> Benzene-1,2,4,5-tetracarboxylic diimide, see Pyromellitic diimide
Page 2228

AHB A, 0613, UNP EU
n Benzidine n
7
Warning H315-H319-H335 P261-P305 + P351 + P338 Benzhydrazide, 98%
Benzoic acid hydrazide; Benzoylhydrazine
51520-5G glass btl 5g [613‑94‑5] Beil. 9,IV,922 C6H5CONHNH2 FW 136.15
> Benzene-1,2,4-tricarboxylic acid, see 1,2,4-Benzenetricarboxylic acid mp .............................................................................................................................................................. 112 to 114 °C
Page 231
6
P338
1,2,4-Benzenetricarboxylic acid, ≥99%
Benzene-1,2,4-tricarboxylic acid; Trimellitic acid B13071-100G glass btl 100 g
[528‑44‑9] Merck 14,9702; Beil. 9,IV,3746 C6H3(CO2H)3 FW 210.14
mp ............................................................................................................................................... 229 to 231 °C (dec.) > Benzhydrol, see Diphenylmethanol Page 1144
7
Warning H315-H319-H335 P261-P305 + P351 + P338 Benzhydroxamic acid, 99%
N-Hydroxybenzamide
[495‑18‑1] Beil. 9,IV,912 C6H5CONHOH FW 137.14
mp .............................................................................................................................................................. 126 to 130 °C
1,2,4-Benzenetricarboxylic anhydride, 97% 412260-5G glass btl 5g
Trimellitic anhydride; Benzene-1,2,4-tricarboxylic
anhydride
HO
O O Benzhydrylamine, 97% B
[552‑30‑7] Merck 14,9703; Beil. 18,V,8,562 C9H4O5 O α-Aminodiphenylmethane
FW 192.13 O
[91‑00‑9] Merck 14,1076; Beil. 12,IV,3282 (C6H5)2CHNH2 FW 183.25
mp ........................................................................... 12 °C density ................................. 1.063 g/mL, 25 °C
mp ...................................................... 163 to 166 °C vp ...................................... <0.01 mmHg (20 °C) bp ......................................................................... 295 °C n20
D .......................................................................... 1.595
vd ................................................................... 6.6 (vs air)

7
578
Danger H317-H318-H334-H335 P261-P280-P305 +
P351 + P338-P342 + P311 A53605-5G glass btl 5g
B4600-25G poly btl 25 g A53605-25G glass btl 25 g
B4600-500G poly btl 500 g A53605-100G glass btl 100 g
> Benzhydrylamine hydrochloride, see Aminodiphenylmethane hydrochloride
> Benzene-1,2,4-tricarboxylic anhydride, see 1,2,4-Benzenetricarboxylic Page 119
anhydride Page 231 Benzhydryl bromide, see Bromodiphenylmethane Page 461
Benzene-1,2,4-tricarboxylic 1,2-anhydride 4-chloride, see Trimellitic Benzhydryl chloride, see Chlorodiphenylmethane Page 672
anhydride chloride Page 2525
Benzhydryl isothiocyanate, 97%
1,2,4-Benzenetriol, 99% [3550‑21‑8] (C6H5)2CHNCS FW 225.31
Hydroxyhydroquinone mp ................................................................................................................................................................... 57 to 61 °C
[533‑73‑3] Merck 14,1073; Beil. 6,1087 C6H3(OH)3 FW 126.11
78
mp ................................................................................................................................................................ 140 °C (subl.) P305 + P351 + P338-P342 + P311
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 + 591696-1G glass btl 1g
> 1-Benzhydrylpiperazine, see 1-(Diphenylmethyl)piperazine Page 1145
> 9,10-o-Benzeno-9,10-dihydroanthracene, see Triptycene Page 2565 ((S)-2-Benzhydrylpyrrolidin-1-yl)((2S,4R)-4-hydroxypyrrolidin-2-

Benzerythrene, see p-Quaterphenyl Page 2236 yl)-methanone, 99% (HPLC)
Benzethonii chloridum, see Benzethonium chloride Page 231 C22H26N2O2 FW 350.45 HO
Benzethonium chloride N
N
H O
H3C CH3
Cl
O
H3C CH3 O N
CH3 H3C CH3 [α]D -63±3°, c = 1 in methylene chloride
Phemerol chloride; (Diisobutylphenoxyethoxyethyl)dimethylbenzyl- 671622-500MG glass btl 500 mg
ammonium chloride solution
[121‑54‑0] Merck 14,1074; Beil. 12,IV,2187 C27H42ClNO2 FW 448.08 Benzidine-rings-d8
cationic 4,4′-Diamino(biphenyl-d8) D D D D
mp .............................................................................................................................................................. 162 to 164 °C C12D8H4N2 FW 192.29
H2N NH2
569
Danger H301-H314-H400
D D D D
 Benzethonii chloridum mp .............................................................................................................................................................. 127 to 128 °C

USP
testing & handling conforms to Pharmacopeia  98 atom % D
P273-P280-P301 + P310-P305 + P351 + P338-P310 mol wt 192.13, atom % calculation
789
Danger H302-H350-H410 P201-P273-P308 + P313-
70585-250G-F 250 g
P501
70585-1KG-F 1 kg
617490-100MG 100 mg
 ≥97% (titration), ≥99% (TLC)
P273-P280-P305 + P351 + P338-P310
AHB A, 0613, UNP EU
n Benzil n
Benzil, 98% 5-Benzimidazolecarboxylic acid, 96%

Diphenylethanedione; Dibenzoyl [15788‑16‑6] Beil. 25,IV,817 C8H6N2O2 FW 162.15 O
[134‑81‑6] Merck 14,1078; Beil. 7,IV,2502 C6H5COCOC6H5 HO N
FW 210.23
N
mp .................................................................................................................................................................... 94 to 95 °C H
vp ..................................................................................................................................................... 1 mmHg (128.4 °C)
mp ............................................................................................................................................................................ >300 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
7
Warning H315-H319-H335 P261-P305 + P351 + P338
B5151-5G-A glass btl 5g

> 1H-Benzimidazole-2-ethanamine, see 2-(2-Aminoethyl)benzimidazole
> Benzil α,α-dimethyl acetal, see 2,2-Dimethoxy-2-phenylacetophenone dihydrochloride Page 121
Page 1050
2-Benzimidazolemethanol, 97%
Benzilic acid, ≥99%
[4856‑97‑7] Beil. 23,I,113 C8H8N2O FW 148.16 N
Diphenylglycolic acid
B [76‑93‑7] Merck 14,1080; Beil. 10,IV,1256 (C6H5)2C(OH)COOH
FW 228.24
N
H
OH
mp .............................................................................................................................................................. 149 to 151 °C mp .............................................................................................................................................................. 171 to 175 °C
7 7
Warning H302 Warning H302-H312-H315-H319-H332-H335 P261-P280-P305 + P351
+ P338
B5194-5G glass btl 5g 158356-1G glass btl 1g
B5194-100G poly btl 100 g 158356-5G glass btl 5g
Benzimidazole, 98% 2-Benzimidazolepropionic acid, 97%

1,3-Benzodiazole; BZI N [23249‑97‑0] Merck 14,7762; Beil. 25,133 C10H10N2O2 FW 190.20
[51‑17‑2] Merck 14,1081; Beil. 23,V,6,196 C7H6N2 mp ............................................................................................................................................... 229 to 231 °C (dec.)
N
FW 118.14 H
7
+ P338
mp .............................................................................................................................................................. 169 to 171 °C
194123-100G poly btl 100 g
194123-500G poly btl 500 g 1H-Benzimidazole-2-sulfonic acid, 98%
[40828‑54‑4] C7H6N2O3S FW 198.20 N O
1H-Benzimidazole-5-boronic acid pinacol ester, 97% 8 S OH
N O
C13H17BN2O2 FW 244.10 CH3 H
H3C
O
H3C B
mp .............................................................................................................................................................. 116 to 119 °C
O N
5
H3C Danger H314 P280-P305 + P351 + P338-P310
N
H
mp .............................................................................................................................................................. 202 to 206 °C
> 2-(1H-Benzimidazole-2-yl)phenol, see 2-(2-Hydroxyphenyl)-1H-benzimi-
708879-250MG glass btl 250 mg dazole Page 1507
708879-1G glass btl 1g 2(1H)-Benzimidazolone, see 2-Hydroxybenzimidazole Page 1472
1H-Benzimidazole-2-carboxylic acid monohydrate, 8 (2-Benzimidazolyl)acetonitrile, 97%

97%
2-Cyanomethylbenzimidazole
[849776‑47‑2] C8H6N2O2 · H2O FW 180.16 N
OH • H2O
[4414‑88‑4] Beil. 25,IV,820 C9H7N3 FW 157.17
N mp ............................................................................................................................................... 200 to 205 °C (dec.)
H O
7
+ P338
5
Danger H318 P280-P305 + P351 + P338
2-(2-Benzimidazolylamino)-1-ethanol, 97%
[57262‑38‑1] C9H11N3O FW 177.20 N
1H-Benzimidazole-4-carboxylic acid, 97% 8 N
OH
N H
[46006‑36‑4] C8H6N2O2 FW 162.15 O OH
H
N solid
N mp .............................................................................................................................................................. 184 to 188 °C
H
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 326 to 330 °C
7
Warning H319 P305 + P351 + P338 572721-1G glass btl 1g
> 3-(2-Benzimidazolyl)-7-(diethylamino)coumarin, see Coumarin 7

709697-250MG glass btl 250 mg Page 782
2-(1H-Benzimidazol-2-yl)ethylamine, see 2-(2-Aminoethyl)benzimidazole
dihydrochloride Page 121

AHB A, 0613, UNP EU
n Benzodioxancarb n
2-Benzimidazolylurea, 98% Benzocyclobutene, 98%

[24370‑25‑0] C8H8N4O FW 176.18 H Bicyclo[4.2.0]octa-1,3,5-triene
N N NH2
[694‑87‑1] C8H8 FW 104.15
N O bp ............................................ 150 °C/748 mmHg n20
D .......................................................................... 1.541
H
density ..................................... 0.957 g/mL, 25 °C
mp ............................................................................................................................................................................ >300 °C
2
Warning H226
> 1H-Benz[g]indole, see 1H-Benzo[g]indole Page 237
1-Benzocyclobutenecarbonitrile, 97%
Benz[cd]indol-2(1H)-one
[6809‑91‑2] C9H7N FW 129.16
[130‑00‑7] Beil. 21,328 C11H7NO FW 169.18
7
+ P338
N O 324892-250MG glass btl 250 mg

H
mp .............................................................................................................................................................. 173 to 178 °C
B
1-Benzocyclobutenecarboxylic acid, 99%
 technical grade [14381‑41‑0] Beil. 9,IV,2053 C9H8O2 FW 148.16 O
7
Warning H302
OH

mp ................................................................................................................................................................... 75 to 77 °C
1,2-Benzisothiazol-3(2H)-one, 97%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[2634‑33‑5] C7H5NOS FW 151.19 O
NH 324884-250MG glass btl 250 mg

S 324884-1G glass btl 1g
mp .............................................................................................................................................................. 154 to 158 °C > 1,4-Benzodiazine, see Quinoxaline Page 2240

1H-1,3-Benzodiazol-6-amine, see 6-Aminobenzimidazole Page 92
579
Danger H302-H315-H317-H318-H400 P273-P280-P305
1,4-Benzodioxan, see Benzo-1,4-dioxane Page 234
+ P351 + P338
561487-5G glass btl 5g 1,4-Benzodioxan-6-amine, 99%
561487-25G glass btl 25 g 6-Amino-1,4-benzodioxan H 2N O
1,2-Benzisoxazole, ≥95.0% [22013‑33‑8] C8H9NO2 FW 151.16
O
[271‑95‑4] Beil. 27,IV,1067 C7H5NO FW 119.12
N mp ............................................................ 29 to 31 °C n20
D .......................................................................... 1.599
O
density ..................................................... 1.231 g/mL
7
bp .......................................... 90-92 °C/15 mmHg n20
D .......................................................................... 1.561 Warning H302-H312-H315-H319-H332-H335 P261-P280-P305 + P351
density ..................................... 1.174 g/mL, 25 °C + P338
n20
D ...................................................................................................................................................................................... 1.563 193232-10G glass btl 10 g
store at: 2-8°C 193232-50G glass btl 50 g
12255-5ML-F glass btl 5 mL > 1,4-Benzodioxan-6-boronic acid, see 1,4-Benzodioxane-6-boronic acid
Page 234
> 2,1-Benzisoxazole, see Anthranil Page 193 1,4-Benzodioxane-6-boronic acid Page 234
Benzo-15-crown-5, 98% 1,4-Benzodioxan-6-carboxaldehyde, 98%

[14098‑44‑3] C14H20O5 FW 268.31 [29668‑44‑8] Beil. 19,128 C9H8O3 FW 164.16 O
O O
O
H
O O
O O
mp ................................................................................................................................................................... 50 to 52 °C
mp .................................................................................................................................................................... 78 to 80 °C
bp ...................................................................................................................................................... 105 °C/15 mmHg
Benzo-18-crown-6, 98% 264598-5G glass btl 5g
[14098‑24‑9] Beil. 19,V,12,618 C16H24O6 1,4-Benzodioxan-2-carboxylic acid, 97%
O
FW 312.36 O O [3663‑80‑7] C9H8O4 FW 180.16 O
O
O O OH
O
O
mp .................................................................................................................................................................... 42 to 45 °C mp .............................................................................................................................................................. 126 to 130 °C

1,4-Benzodioxan-5-carboxylic acid, 98%
> (Benzo-15-crown-5)-4′-carboxylic acid, see 4′-Carboxybenzo-15-crown-5
Page 623 [4442‑53‑9] C9H8O4 FW 180.16
(Benzo-15-crown-5)-4′-ylamine, see 4′-Aminobenzo-15-crown-5 Page 92 mp ................................................................................................................................................................... 90 to 94 °C
(Benzo-18-crown-6)-4′-ylamine, see 4′-Aminobenzo-18-crown-6 Page 92
7
Warning H315-H319-H335 P261-P305 + P351 + P338

AHB A, 0613, UNP EU
n Benzodioxane n
Benzo-1,4-dioxane, 97% mp ................................................................................................................................................................... 65 to 70 °C
5
1,2-Ethylenedioxybenzene; 2,3-Dihydro-1,4-benzodioxin; O
Danger H314 P280-P305 + P351 + P338-P310
1,4-Benzodioxan
[493‑09‑4] Beil. 19,V,1,439 C8H8O2 FW 136.15 O 724254-1G glass btl 1g
bp .................................................. 103 °C/6 mmHg n20

D .......................................................................... 1.549 > 6-(1,4-Benzodioxanyl)boronic acid, see 1,4-Benzodioxane-6-boronic acid
density ..................................... 1.142 g/mL, 25 °C Page 234
1,4-Benzodioxane-6-boronic acid Page 234
1,4-Benzodioxan-6-yl methyl ketone, 98%
1,4-Benzodioxane-6-acetic acid, 97% 8 [2879‑20‑1] C10H10O3 FW 178.18
[17253‑11‑1] C10H10O4 FW 194.18 HO O mp ................................................................................................................................................................... 80 to 82 °C
O 179027-10G glass btl 10 g
O
1,3-Benzodioxole, 99%
mp .................................................................................................................................................................... 73 to 78 °C
1,2-(Methylenedioxy)benzene
7
Warning H302-H319 P305 + P351 + P338 O
[274‑09‑9] Beil. 19,V,1,434 C7H6O2 FW 122.12
O
B 731927-1G glass btl 1g

bp ............................................................... 172-173 °C n20
D .......................................................................... 1.539
1,4-Benzodioxane-6-boronic acid density ..................................... 1.064 g/mL, 25 °C vp ............................................. 12 mmHg (25 °C)
1,4-Benzodioxan-6-boronic acid; 6-(1,4-Benzodioxa-
7
OH
Warning H302-H332
nyl)boronic acid B O
HO
[164014‑95‑3] C8H9BO4 FW 179.97 159166-50G glass btl 50 g
O
> 1,3-Benzodioxole-4-carboxaldehyde, see 2,3-(Methylenedioxy)benzaldehyde
Contains varying amounts of anhydride Page 1775
1,3-Benzodioxole-5-propanoic acid, see 3-(3,4-Methylenedioxyphenyl)
7
Warning H315-H319-H335 P261-P305 + P351 + P338 propionic acid Page 1775
6-(Benzo[1,3]dioxol-5-yl)pyridine-2-carbaldehyde, see 6-(1,3-Benzodioxol-5-
yl)-2-pyridinecarboxaldehyde Page 234
635995-5G glass btl 5g 6-(1,3-Benzodioxol-5-yl)-2-pyridinecarboxaldehyde, 97%
(R)-1,4-Benzodioxane-2-carboxylic acid, ≥97.0% (GC, sum of 6-(Benzo[1,3]dioxol-5-yl)pyridine-2-carbaldehyde
enantiomers) [834884‑78‑5] C13H9NO3 FW 227.22
O H
N
(R)-2,3-Dihydro-1,4-benzodioxin-2-carboxylic acid O O
O
[70918‑53‑5] C9H8O4 FW 180.16 O
OH
mp .............................................................................................................................................................. 117 to 122 °C
O
7
Warning H315-H319-H335 P261-P305 + P351 + P338
[α]20
D +83±2°, c = 1.5 in chloroform
enantiomeric ratio: ≥99.0:1.0 655813-1G glass btl 1g
7
Warning H315-H319-H335 P261-P305 + P351 + P338
1,2-Benzodiphenylene sulfide, 99%

Benzo[b]naphtho[2,1-d]thiophene
[239‑35‑0] Beil. 17,IV,712 C16H10S FW 234.32
(S)-1,4-Benzodioxane-2-carboxylic acid, ≥97.0% (GC, sum of S
enantiomers)
[70918‑54‑6] C9H8O4 FW 180.16 mp .............................................................................................................................................................. 188 to 190 °C
Rare constituent of coal tar.
7
Warning H315-H319-H335 P261-P305 + P351 + P338
3H-1,2-Benzodithiol-3-one, 97%
1,4-Benzodioxane-6-carboxylic acid, 97% [1677‑27‑6] Beil. 19,V,4,215 C7H4OS2 FW 168.24 O
[4442‑54‑0] C9H8O4 FW 180.16 O S
O S
HO
O mp ................................................................................................................................................................... 74 to 77 °C
mp .............................................................................................................................................................. 134 to 138 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338 1,3-Benzodithiolylium tetrafluoroborate, 98%
BDTF S
658375-5G glass btl 5g BF4-
[57842‑27‑0] Beil. 19,1,535 C7H5BF4S2 FW 240.05
S
> 1,4-Benzodioxane-2-methylamine, see 2-Aminomethyl-1,4-benzodioxane mp ................................................................................................................................................................ 150 °C (dec.)

Page 137
7
Warning H315-H319-H335 P261-P305 + P351 + P338
1,4-Benzodioxan-6-sulfonyl chloride, 95% 8
2,3-Dihydro-1,4-benzodioxine-6-sulfonyl chloride O
[63758‑12‑3] C8H7ClO4S FW 234.66 Cl S O
O
O

AHB A, 0613, UNP EU
n Benzofuranylmet n
Benzo[b]fluoranthene, 98% > 2-Benzofuranboronic acid, see 2-Benzofuranylboronic acid Page 235
2-Benzofuranboronic acid MIDA ester, see 2-Benzofuranylboronic acid MIDA
3,4-Benzofluoranthene ester Page 235
[205‑99‑2] Beil. 5,III,2516 C20H12 FW 252.31 Benzofuran-2-carbonyl chloride, 97% 8
[41717‑28‑6] C9H5ClO2 FW 180.59
Cl
mp .............................................................................................................................................................. 163 to 165 °C O
O
89
Danger H350-H410 P201-P273-P308 + P313-P501
mp ................................................................................................................................................................... 53 to 57 °C
7
275336-25MG glass btl 25 mg Warning H319 P305 + P351 + P338
Benzo[k]fluoranthene, 98%
[207‑08‑9] Beil. 5,IV,2686 C20H12 FW 252.31 2-Benzofurancarboxaldehyde, 97%
[4265‑16‑1] Beil. 17,IV,5062 C9H6O2 FW 146.14 O
H
O
mp .............................................................................................................................................................. 215 to 217 °C

bp ............................................... 135 °C/18 mmHg n20
D .......................................................................... 1.633 B
89
Danger H350-H410 P201-P273-P308 + P313-P501 density ..................................... 1.206 g/mL, 25 °C

Benzo[b]fluoranthene-d12
Benzofuran-2-carboxylic acid, 99%
Benz[e]acephenanthrylene-d12
[93951‑98‑5] C20D12 FW 264.38 Coumarone-2-carboxylic acid; Coumarilic acid O
mp .............................................................................................................................................................. 163 to 165 °C [496‑41‑3] Merck 14,2561; Beil. 18,V,6,419 C9H6O3

O OH
FW 162.14
 98 atom % D mp .............................................................................................................................................................. 193 to 196 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
89
Danger H350-H410 P201-P273-P308 + P313-P501

Benzofuran-3(2H)-one, ≥98.0% (HPLC)
> 1,2-Benzofluorene, see 11H-Benzo[a]fluorene Page 235
3-Coumaranone O
2,3-Benzofluorene, 98% [7169‑34‑8] Beil. 17,V,4,180 C8H6O2 FW 134.13
11H-Benzo[b]fluorene; Isonaphthofluorene O
[243‑17‑4] Beil. 5,IV,2472 C17H12 FW 216.28
mp .............................................................................................................................................................. 101 to 103 °C
mp .............................................................................................................................................................. 211 to 213 °C
2-Benzofuranylboronic acid
> 11H-Benzo[b]fluorene, see 2,3-Benzofluorene Page 235
2-Benzofuranboronic acid; Benzofuran-2-ylboronic OH
11H-Benzo[a]fluorene, ≥98.0% acid B
[98437‑24‑2] Beil. 18,V,12,587 C8H7BO3 FW 161.95 O OH
Chrysofluorene; 1,2-Benzofluorene
[238‑84‑6] Beil. 5,IV,2473 C17H12 FW 216.28 Contains varying amounts of anhydride
mp .............................................................................................................................................................. 114 to 116 °C
mp .............................................................................................................................................................. 185 to 190 °C
12490-100MG-F 100 mg
2-Benzofuranylboronic acid MIDA ester, 97% 8
2,3-Benzofuran, 99%
2-Benzofuranboronic acid MIDA ester; 2-(Benzo- H3C
Coumarone
furan-2-yl)-6-methyl-1,3,6,2-dioxazaborocane-4,8- N
[271‑89‑6] Merck 14,1088; Beil. 17,V,2,3 C8H6O
O dione B O
FW 118.13 O O
O
[1104637‑65‑1] C13H12BNO5 FW 273.05 O
bp ............................................................... 173-175 °C n20
D .......................................................................... 1.566
density ..................................... 1.072 g/mL, 25 °C mp .............................................................................................................................................................. 198 to 202 °C
28
> 2-(Benzofuran-2-yl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione, see 2-
B8002-5G glass btl 5g Benzofuranylboronic acid MIDA ester Page 235
2-Benzofuranyl methyl ketone, 99%
Benzofuran-3-acetonitrile, 95%
2-Acetylbenzofuran O
[52407‑43‑9] C10H7NO FW 157.17 [1646‑26‑0] C10H8O2 FW 160.17
CN
O CH3
O
mp ................................................................................................................................................................... 70 to 72 °C
mp .................................................................................................................................................................... 38 to 42 °C bp ............................................................................................................................................... 110-113 °C/3 mmHg
bp ...................................................................................................................................................... 120 °C/0.5 mmHg
154377-25G poly btl 25 g
7
Warning H302-H319 P305 + P351 + P338
154377-100G poly btl 100 g
AHB A, 0613, UNP EU
n Benzofurazan n
Benzofurazan, 97% Benzoic-1-13C acid

13
[273‑09‑6] C6H4N2O FW 120.11 [55320‑26‑8] CC5H5CO2H FW 123.11
7
Warning H302  99 atom % 13
C
Benzoic acid-2,3,4,5,6-d5
5-Benzofurazanboronic acid MIDA ester 8
Benzoic-d5 acid (phenyl-d5)
2-(Benzo[c][1,2,5]oxadiazol-5-yl)-6-methyl-1,3,6,2- H3 C [1079‑02‑3] C6D5CO2H FW 127.15
dioxazaborocane-4,8-dione; Benzo[c][1,2,5] N
mp .............................................................................................................................................................. 121 to 125 °C
oxadiazol-5-yl-5-boronic acid MIDA ester B O
bp ................................................................................................................................................................................. 249 °C
O O
C11H10BN3O5 FW 275.03 O
N  99 atom % D
O N mol wt 127.11, atom % calculation
ait ................................................................................................................................................................................. 1061 °F
mp .............................................................................................................................................................. 258 to 263 °C
578
Danger H302-H315-H317-H318-H334-H335 P261-
P280-P305 + P351 + P338-P342 + P311
B > Benzoguanamine, see 2,4-Diamino-6-phenyl-1,3,5-triazine Page 866
217158-1G
Benzoic acid-12C7
glass btl 1g
12
5,6-Benzo-4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8] [65‑85‑0] C6H512CO2H FW 122.05
hexacos-5-ene solution
 99.9 atom % 12
C
[31250‑18‑7] C22H36N2O6 FW 424.53
 Kryptofix® 222B
50 wt. % in toluene Benzoic acid-13C7
13
C6H513CO2H FW 129.07
7
Warning H315-H319-H335 P261-P305 + P351 + P338
mp .............................................................................................................................................................. 121 to 125 °C
308579-100MG ampule 100 mg bp ................................................................................................................................................................................. 249 °C
Benzoic acid  99 atom % 13C

[65‑85‑0] Merck 14,1091; Beil. 9,IV,273; Fieser 1,49 C6H5COOH
578
Danger H302-H315-H317-H318-H334-H335 P261-
FW 122.12
P280-P305 + P351 + P338-P342 + P311
mp ...................................................... 121 to 125 °C vp ........................................... 10 mmHg (132 °C)
bp ......................................................................... 249 °C ait ...................................................................... 1061 °F 586234-100MG 100 mg
vd ................................................................ 4.21 (vs air)
Benzoic acid-ring-13C6
7
Warning H302-H319 P305 + P351 + P338 13
[125945‑98‑4] C6H5CO2H FW 128.08
mp .............................................................................................................................................................. 121 to 125 °C
bp ................................................................................................................................................................................. 249 °C
CH3OH insol. ...................................................................................................................................................... ≤0.005%
S compounds ................................................................................................................................................... ≤0.002%  99 atom % 13C
MnO4- reducers ........................................................................................................................................ passes test mol wt 128.02, atom % calculation
ign. residue ............................................... ≤0.005% heavy metals (as Pb) ...................... ≤5 ppm
578
Danger H302-H315-H317-H318-H334-H335 P261-
chloride (Cl-) ............................................. ≤0.005% P280-P305 + P351 + P338-P342 + P311
242381-25G poly btl 25 g 485691-500MG glass btl 500 mg

242381-100G poly btl 100 g > Benzoic acid benzyl ester, see Benzyl benzoate Page 250
242381-500G poly btl 500 g Benzoic acid N-hydroxy-tert-butylamine ester hydrochloride, see N-tert-
Butyl-O-benzoylhydroxylamine hydrochloride Page 560
242381-3KG poly drum 3 kg Benzoic acid N-hydroxymethylamine ester hydrochloride, see N-Methyl-O-
benzoylhydroxylamine hydrochloride Page 1742
 purified by sublimation, ≥99% Benzoic acid phenyl ester, see Phenyl benzoate Page 2023
Benzoic anhydride, ≥95%
427608-10G poly btl 10 g
[93‑97‑0] Merck 14,1092; Beil. 9,IV,550 (C6H5CO)2O FW 226.23
 ReagentPlus®, 99% mp ................................................................................................................................................................... 38 to 42 °C
109479-500G poly btl 500 g density ............................................................................................................................................. 1.199 g/mL, 25 °C
57
109479-1KG 1 kg Danger H315-H318-H335 P261-P280-P305 + P351 + P338
109479-3KG poly drum 3 kg
385980-100G glass btl 100 g
> Benzoic acid ammonium salt, see Ammonium benzoate Page 175
Benzoic acid potassium salt, see Potassium benzoate Page 2159 385980-500G glass btl 500 g
13 > o-Benzoic sulfimide, see Saccharin Page 2261

Benzoic acid-α- C 3H-Benzoimidazol-5-ylamine, see 6-Aminobenzimidazole Page 92
Benzoic acid-carboxy-13C
[3880‑99‑7] Beil. 9,III,380 C6H513CO2H FW 123.11 Benzoin
mp .............................................................................................................................................................. 121 to 125 °C α-Hydroxy-α-phenylacetophenone; α-Hydroxybenzyl phenyl ketone;
bp ................................................................................................................................................................................. 249 °C 2-Hydroxy-2-phenylacetophenone
 99 atom % 13C [119‑53‑9] Merck 14,1093 C6H5CH(OH)COC6H5 FW 212.24
mol wt 123.11, atom % calculation mp .............................................................................................................................................................. 134 to 138 °C
bp ...................................................................................................................................................... 194 °C/12 mmHg
578
Danger H302-H315-H317-H318-H334-H335 P261-
P280-P305 + P351 + P338-P342 + P311  purified by sublimation, ≥99.5%

AHB A, 0613, UNP EU
n Benzooxazolylam n
 98% α-Benzoin oxime, 98%

B8681-100G poly btl 100 g Cuprone
B8681-500G poly btl 500 g [441‑38‑3] Merck 14,1094; Beil. 8,IV,1282 C6H5CH(OH)C(=NOH)C6H5
FW 227.26
(R)-(−)-Benzoin, 98%
mp .............................................................................................................................................................. 153 to 155 °C
(R)-2-Hydroxy-2-phenylacetophenone
7
Warning H319 P305 + P351 + P338
[5928‑66‑5] Beil. 8,167 C6H5CH(OH)COC6H5 FW 212.24
mp .............................................................................................................................................................. 135 to 137 °C B8908-25G poly btl 25 g
D −115°, c = 1.5 in acetone
[α]24
ee (HPLC): 99% > Benzo[b]naphtho[2,1-d]thiophene, see 1,2-Benzodiphenylene sulfide
Page 234
Benzonitrile
(S)-(+)-Benzoin, 99%
Phenyl cyanide
(S)-2-Hydroxy-2-phenylacetophenone
[100‑47‑0] Merck 14,1097; Beil. 9,IV,892 C6H5CN FW 103.12
[5928‑67‑6] Beil. 8,167; Fieser 6,34 C6H5CH(OH)COC6H5 FW 212.24 mp ....................................................................... −13 °C n20
D .......................................................................... 1.528
mp .............................................................................................................................................................. 135 to 137 °C bp ......................................................................... 191 °C
Chiral starting material.
[α]19
D +115°, c = 1.5 in acetone 7
Warning H302-H312 B
ee (HPLC): 99%
 anhydrous, ≥99%
water ....................................................................................................................................................................... <0.003%
1H-Benzo[g]indole, 97% water ..................................................................................................................................... <0.005% (100 mL pkg)
evapn. residue ............................................................................................................................................. <0.0003%
1H-Benz[g]indole
[233‑34‑1] C12H9N FW 167.21 294098-100ML Sure/Seal™ 100 mL
N 294098-1L Sure/Seal™ 1L
H
 CHROMASOLV®, for HPLC, 99.9%
mp .............................................................................................................................................................. 180 to 184 °C
purified by glass distillation
Useful fused indole as a starter in indole chemistry.1 water .......................................................................................................................................................................... ≤0.03%
Lit. cited: 1. Org. Biomolecular Chem. 2, 160 (2004)
evapn. residue ..................................... <0.0005% 310 nm ............................................................. 0.40
56
Danger H301-H318 P280-P301 + P310-P305 + P351 + P338 λ .......................................................................... vs H2O 335 nm ............................................................. 0.03
300 nm .................................................................... 1.0 360-400 nm ................................................... 0.01
1H-Benzo[g]indole-3-carboxaldehyde, 97% 270318-1L Sure/Seal™ 1L
3-Formyl-1H-benzo[g]indole O
[51136‑18‑6] C13H9NO FW 195.22
H P280
N B8959-500ML Sure/Seal™ 500 mL
H
B8959-1L 1L
mp .............................................................................................................................................................. 231 to 236 °C B8959-2.5L 2.5 L
1
Useful starter in indole and natural product synthesis B8959-20L steel drum 20 L
Lit. cited: 1. J. Chem. Soc. Perkin Trans. I 2450 (1973)
Benzonitrile-d5
7
Phenyl-d5 cyanide
694010-1G glass btl 1g [2102‑15‑0] C6D5CN FW 108.15
mp ....................................................................... −13 °C n20
D .......................................................................... 1.528
Benzoin ethyl ether, 97% bp ......................................................................... 191 °C
2-Ethoxy-2-phenylacetophenone; α-Ethoxy-α-phenylacetophenone
[574‑09‑4] Beil. 8,III,1279 C6H5COCH(OC2H5)C6H5 FW 240.30  99 atom % D
mp .................................................................................................................................................................... 59 to 61 °C
density ............................................................................................................................................. 1.059 g/mL, 25 °C
79
Warning H317-H400 P273-P280
491896-1G ampule 1g
172006-50G poly btl 50 g > Benzonitrile, palladium complex, see Bis(benzonitrile)palladium(II) chloride
Page 293
Benzoin methyl ether
2-Methoxy-2-phenylacetophenone; α-Methoxy-α-phenylacetophen- Benzo[c][1,2,5]oxadiazole-5-boronic acid pinacol ester, 97%
one C12H15BN2O3 FW 246.07 H3C CH3
[3524‑62‑7] Beil. 8,IV,1280 C6H5CH(OCH3)COC6H5 FW 226.27 O
CH3
mp ............................................................................................................................................................ 47.5 to 48.5 °C N B
O CH3
O
6
Danger H301 P301 + P310 N
mp ................................................................................................................................................................... 87 to 91 °C
 99%
powder 677779-1G glass btl 1g
479314-25G glass btl 25 g > Benzo[c][1,2,5]oxadiazol-5-yl-5-boronic acid MIDA ester, see 5-Benzofur-
azanboronic acid MIDA ester Page 236
 96% 2-(Benzo[c][1,2,5]oxadiazol-5-yl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-
Photoinitiator. dione, see 5-Benzofurazanboronic acid MIDA ester Page 236
Benzooxazol-2-ylamine, see 2-Aminobenzoxazole Page 94
remainder benzoin

AHB A, 0613, UNP EU
n Benzoperylene n
Benzo[ghi]perylene, 98% Benzophenone hydrazone, 96%

1,12-Benzoperylene Diphenyldiazomethane precursor
[191‑24‑2] Beil. 5,IV,2766 C22H12 FW 276.33 [5350‑57‑2] Beil. 7,IV,1370 (C6H5)2C=NNH2 FW 196.25
mp ................................................................................................................................................................... 95 to 98 °C
bp ............................................................................................................................................ 225-230 °C/55 mmHg
mp .............................................................................................................................................................. 277 to 279 °C B9602-500G glass btl 500 g
bp .............................................................................................................................................................................. >500 °C
1 Benzophenone imine, 95%
An n-channel organic semiconductor.
Lit. cited: 1. Newman, C.R., et al., Chem. Mater. 16, 4436 (2004) [1013‑88‑3] Merck 14,10235; Beil. 7,IV,1365 (C6H5)2C=NH
FW 181.23
9
Warning H410 P273-P501
bp .................................... 151-153 °C/10 mmHg n20 D .......................................................................... 1.618
density ........................................ 1.08 g/mL, 25 °C
B9009-25MG-A glass btl 25 mg
B9009-100MG-A glass btl 100 mg Useful in the preparation of nitrile ylide dimers.1
> Benzo[def]phenanthrene, see Pyrene Page 2212
7
Warning H315-H319-H335 P261-P305 + P351 + P338
B
9,10-Benzophenanthrene, see Triphenylene Page 2559
Benzo[def]phenanthrene-13C16, see Pyrene-13C16 Page 2213
Benzophenone 293733-25G glass btl 25 g
Diphenyl ketone > Benzophenone-4-maleimide, see 4-(N-Maleimido)benzophenone
[119‑61‑9] Merck 14,1098; Beil. 7,IV,1357; 7,411 (C6H5)2CO Page 1647
FW 182.22
mp ............................................................ 47 to 51 °C vp .............................................. 1 mmHg (108 °C) Benzophenone-3,3′,4,4′-tetracarboxylic dianhydride
bp ......................................................................... 305 °C
4,4′-Carbonyldiphthalic anhydride O O O
7
Warning H315-H319-H335 P261-P305 + P351 + P338 [2421‑28‑5] C17H6O7 FW 322.23
O O
 purified by sublimation, ≥99% O O

mp ...................................................... 218 to 222 °C vp ............................................ <0.1 mmHg (0 °C)
427551-10G poly btl 10 g vd ................................................................... 1.4 (vs air) ait ......................................................................... 975 °F
7
Warning H319-H335 P261-P305 + P351 + P338
B9300-500G-A poly btl 500 g  purified by sublimation, 96%
B9300-1KG-A poly btl 1 kg 262463-5G glass btl 5g
B9300-2KG-A poly btl 2 kg 262463-25G glass btl 25 g
Benzophenone-2,3,4,5,6-d5  96%
[2694‑78‑2] C6H5COC6D5 FW 187.25 B9750-100G glass btl 100 g
 98 atom % D
393983 Full product information at Aldrich.com > Benzopinacol, see 1,1,2,2-Tetraphenyl-1,2-ethanediol Page 2414
Benzopinacolone, see 2,2,2-Triphenylacetophenone Page 2558
Benzophenone-d10 1-Benzopyran-2-one, see Coumarin Page 782
1-Benzopyran-4-one, see Chromone Page 760
[22583‑75‑1] (C6D5)2CO FW 192.28 Benzopyrazine, see Quinoxaline Page 2240
mp .................................................................................................................................................................... 47 to 51 °C 1,2-Benzopyrazole, see Indazole Page 1527
bp ................................................................................................................................................................................. 305 °C
Benzo[e]pyrene, 99%
 99 atom % D 1,2-Benzpyrene; 4,5-Benzpyrene
mol wt 192.08, atom % calculation [192‑97‑2] Merck 14,1104; Beil. 5,IV,2689 C20H12
9
Warning H400 P273 FW 252.31

mp .............................................................................................................................................................. 177 to 180 °C
Benzophenone-carbonyl-13C
89
Danger H350-H410 P201-P273-P308 + P313-P501
13
[32488‑48‑5] (C6H5)2 CO FW 183.21
mp .................................................................................................................................................................... 47 to 51 °C B10102-25MG glass btl 25 mg
bp ................................................................................................................................................................................. 305 °C B10102-100MG glass btl 100 mg
 99 atom % 13C Benzo[a]pyrene-7-d, 97%
[68041‑22‑5] C20DH11 FW 253.32
9
Warning H400 P273
789
Danger H317-H340-H350-H360-H410 P201-P273-
P280-P308 + P313-P501
> Benzophenone-2-carboxylic acid, see 2-Benzoylbenzoic acid Page 244 409375-500MG glass btl 500 mg
Benzophenone-4-carboxylic acid, see 4-Benzoylbenzoic acid Page 244
Benzophenone dichloride, see α,α-Dichlorodiphenylmethane Page 924 Benzo[a]pyrene-7,8-d2, 98% (CP)
3,4-Benzopyrene-7,8-d2
[206752‑38‑7] C20D2H10 FW 254.32
mp .............................................................................................................................................................. 177 to 180 °C
bp ................................................................................................................................................................................. 495 °C

AHB A, 0613, UNP EU
n Benzothiazinone n
 98 atom % D p-Benzoquinone dioxime, ≥90% (TLC)

mol wt 254.28, atom % calculation [105‑11‑3] Beil. 7,IV,2074 C6H4(=NOH)2 FW 138.12
789
Danger H317-H340-H350-H360-H410 P201-P273- mp ................................................................................................................................................................ 243 °C (dec.)
P280-P308 + P313-P501
 technical
7
Warning H302
Benzo[a]pyrene-8-d, 98% (CP)
[206752‑39‑8] C20DH11 FW 253.32 12320-250G poly btl 250 g
 98 atom % D 1-Benzosuberone, 99%

410624 Full product information at Aldrich.com 6,7,8,9-Tetrahydro-5-benzocycloheptenone O
[826‑73‑3] Beil. 7,IV,1029 C11H12O FW 160.21
Benzo[a]pyrene-d12
3,4-Benzopyrene-d12
[63466‑71‑7] C20D12 FW 264.38 bp ......................................................................... 270 °C n20
D .......................................................................... 1.564
mp .............................................................................................................................................................. 177 to 180 °C density ..................................... 1.071 g/mL, 25 °C
 98 atom % D
B10587-5G
B10587-25G
glass btl
glass btl
5g
25 g
B
bp ................................................................................................................................................................................. 495 °C
> Benzo[c]-1,2,3-thiadiazol-4,7-diyl-4,7-diboronic acid dipinacol ester, see
789
Danger H317-H340-H350-H360-H410 P201-P273-
P280-P308 + P313-P501 2,1,3-Benzothiadiazole-4,7-bis(boronic acid pinacol ester) Page 239
451797-10MG glass btl 10 mg 2,1,3-Benzothiadiazole, 98%

Benzo[e]pyrene-d12 Piazthiole N
4,5-Benzopyrene-d12 [273‑13‑2] Beil. 27,IV,7118 C6H4N2S FW 136.17 S

N
C20D12 FW 264.38
mp ................................................................................................................................................................... 42 to 44 °C
mp .............................................................................................................................................................. 177 to 180 °C
bp ................................................................................................................................................................................. 206 °C
 98 atom % D
89
Danger H350-H410 P201-P273-P308 + P313-P501
616664-10MG glass btl 10 mg 2,1,3-Benzothiadiazole-4,7-bis(boronic acid pinacol 8

ester), 95%
> Benzopyrimidine, see Quinazoline Page 2237
1H-Benzo[b]pyrrole, see Indole Page 1534 Benzo[c]-1,2,3-thiadiazol-4,7-diyl-4,7-diboronic acid H3C CH3
Benzo[c]quinoline, see Phenanthridine Page 2011 dipinacol ester H3C CH3
C18H26B2N2O4S FW 388.10 O
B
O
Benzo[h]quinoline, 97%
N
1-Naphthoquinoline; 7,8-Benzoquinoline S
N
[230‑27‑3] Beil. 20,V,8,215 C13H9N FW 179.22
B
N O O
H3C CH3
mp .................................................................................................................................................................... 48 to 50 °C H3C CH3
bp .................................................................................................................................................... 338 °C/719 mmHg
mp .............................................................................................................................................................. 207 to 212 °C
p-Benzoquinone, ≥98% Benzo[c][1,2,5]thiadiazol-5-ylboronic acid pinacol 8

ester, 97%
Quinone
[106‑51‑4] Merck 14,8074; Beil. 7,IV,2065; Fieser 7,55; 1,49 C6H4(=O)2 C12H15BN2O2S FW 262.14 CH3
H3C
FW 108.09 H3C O
mp ...................................................... 113 to 115 °C vp ............................................. 0.1 mmHg (25 °C) H3C B N
O
S
vd ................................................................ 3.73 (vs air) ait ......................................................................... 815 °F N
 reagent grade mp ................................................................................................................................................................... 81 to 86 °C

Free radical inhibitor
7
Warning H315-H319-H335 P261-P305 + P351 + P338
69
+ P310-P305 + P351 + P338-P311
B10358-100G glass btl 100 g 2H-1,4-Benzothiazin-3(4H)-one, 97%
B10358-500G glass btl 500 g [5325‑20‑2] Beil. 27,192 C8H7NOS FW 165.21 H
N O
B10358-1KG glass btl 1 kg
S
p-Benzoquinone-d4
1,4-Benzoquinone-d4 mp .............................................................................................................................................................. 176 to 178 °C
[2237‑14‑1] C6D4O2 FW 112.12 175277-25G glass btl 25 g
mp .............................................................................................................................................................. 113 to 115 °C
 98 atom % D
> 1,4-Benzoquinone-d4, see p-Benzoquinone-d4 Page 239
AHB A, 0613, UNP EU
n Benzothiazole n
Benzothiazole, 96% Benzo[b]thien-2-ylboronic acid

[95‑16‑9] Merck 14,1107; Beil. 27,IV,1069; Fieser 15,20 N Benzothiophen-2-ylboronic acid; 1-Benzothiophene- OH
C7H5NS FW 135.19 2-boronic acid; Thianaphthene-2-boronic acid B
S S OH
[98437‑23‑1] Beil. 18,12,587 C8H7BO2S FW 178.02
mp .............................................................................. 2 °C n20
D .......................................................................... 1.642
bp ......................................................................... 231 °C vd ............................................................. 4.66 (vs air)
density ..................................... 1.238 g/mL, 25 °C vp ........................................... 34 mmHg (131 °C) mp .............................................................................................................................................................. 200 to 206 °C
7
Warning H302-H319 P305 + P351 + P338
101338-5G glass btl 5g Benzo[b]thien-3-ylboronic acid
101338-100G glass btl 100 g
Thianaphthene-3-boronic acid HO
101338-500G glass btl 500 g
[113893‑08‑6] C8H7BO2S FW 178.02 B OH
2-Benzothiazoleacetonitrile, 98%
S
[56278‑50‑3] Beil. 27,IV,4056 C9H6N2S FW 174.22 N

B
S CN
mp .............................................................................................................................................................. 225 to 230 °C
mp ................................................................................................................................................................. 98 to 101 °C
7
+ P338 512117-25G glass btl 25 g
443042-1G glass btl 1g > Benzo[b]thien-2-yltributylstannane, see 2-Tributylstannylbenzo[b]thiophene

Benzo[b]thiophene, see Thianaphthene Page 2420
Benzothiazole-2-carbonyl chloride, 95% 8 Benzo[b]thiophene-2-carbonitrile, 97%
[67748‑61‑2] C8H4ClNOS FW 197.64 N
Cl
Thianaphthene-2-carbonitrile; 2-Cyanobenzothiophene
S [55219‑11‑9] C9H5NS FW 159.21 CN
O S
mp .............................................................................................................................................................. 114 to 118 °C mp ................................................................................................................................................................... 24 to 28 °C

bp ..................................................................................................................................................... 140 °C/0.5 mmHg
7
Warning H312-H319-H332 P280-P305 + P351 + P338
Useful starter in benzothiophene chemistry.1
Lit. cited: 1. J. Med. Chem. 49, 1693 (2006)
7
Warning H302-H319 P305 + P351 + P338
Benzothiazole-2-carboxaldehyde, 97% 8 686727-1G glass btl 1g
[6639‑57‑2] C8H5NOS FW 163.20 N O Benzo[b]thiophene-3-carbonitrile, 97%

S H 3-Cyanobenzo[b]thiophene CN
[24434‑84‑2] C9H5NS FW 159.21
mp .................................................................................................................................................................... 72 to 76 °C
S
78
Danger H302-H319-H334 P261-P305 + P351 + P338-P342 +
P311 mp ................................................................................................................................................................... 71 to 75 °C
7
Benzothiazole-6-carboxylic acid, 96%

[3622‑35‑3] C8H5NO2S FW 179.20 N
Benzo[b]thiophene-2-carboxaldehyde, 97%
HO S
O
Thianaphthene-2-carboxaldehyde O
[3541‑37‑5] C9H6OS FW 162.21
S H
mp .............................................................................................................................................................. 245 to 251 °C
Basic starter on benzothiazole synthesis.1 mp ................................................................................................................................................................... 32 to 36 °C
Lit. cited: 1. Pest Mgmt Sci. 59, 25-35 (2003)
Preparation of the corresponding vinyl benzyl ether using Julia
7
Warning H315-H319-H335 P261-P305 + P351 + P338 olefination.1
Lit. cited: 1. Org. Lett. 5, 4851 (2003)
7
Warning H319 P305 + P351 + P338
> 2-Benzothiazolecarboxylic acid, ethyl ester, see Ethyl benzothiazole-2-
carboxylate Page 1215 674540-5G glass btl 5g
2(3H)-Benzothiazolone, see 2-Hydroxybenzothiazole Page 1473
3-(2-Benzothiazolyl)-7-(diethylamino)coumarin, see Coumarin 6 > Benzo[b]thiophene-2-carboxylic acid methyl ester, see Methyl benzo[b]
Page 782 thiophene-2-carboxylate Page 1741
Benzo[b]thiophene-2,3-dione, ≥97% (GC) 8
2-(2-Benzothiazolylthio)ethanol, 95%
[4665‑63‑8] Beil. 24,IV,1843 C9H9NOS2 Thioisatin O
N
FW 211.30 S [493‑57‑2] C8H4O2S FW 164.18
S O
S
OH
57
mp .................................................................................................................................................................... 50 to 55 °C Danger H317-H318 P280-P305 + P351 + P338
7
+ P338 727636-1G glass btl 1g

AHB A, 0613, UNP EU
n Benzotriazolylb n
Benzothiophene-2-methanol, 97% Benzotriazole-1-carboxamide

2-(Hydroxymethyl)benzo[b]thiophene; Benzo[b] OH [5933‑29‑9] C7H6N4O FW 162.15 N
thiophen-2-yl-methanol N
S N
[17890‑56‑1] C9H8OS FW 164.22
O
H 2N
mp ................................................................................................................................................................. 99 to 103 °C
7
Warning H319 P305 + P351 + P338 mp .............................................................................................................................................................. 170 to 175 °C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Benzo[b]thiophene-2-propionic acid, 97% 596485-1G glass btl 1g
[42768‑60‑5] C11H10O2S FW 206.26 Benzotriazole-5-carboxylic acid, 99%
7
Warning H315-H319-H335 P261-P305 + P351 + P338 [23814‑12‑2] Beil. 26,290 C7H5N3O2 FW 163.13 O
HO N
N
H
Benzothiophene sulfone-2-methanol, 97%
[134996‑50‑2] C9H8O3S FW 196.22
7
Warning H315-H319-H335 P261-P305 + P351 + P338
B
> 1-Benzo[b]thiophen-2-yl-ethanone, see 2-Acetylbenzothiophene
Page 34 1H-Benzotriazole-1-methanol, 98%
Benzo[b]thiophen-2-yl-methanol, see Benzothiophene-2-methanol
Page 241 [28539‑02‑8] Beil. 26,IV,104 C7H7N3O FW 149.15 N
3-(Benzo[b]thiophen-2-yl)propionic acid, see Benzo[b]thiophene-2- N
propionic acid Page 241 N OH
2-(Benzo[b]thiophen-2-yl)pyridine, see 2-(2-Pyridyl)benzothiophene
Page 2224 mp .............................................................................................................................................................. 150 to 152 °C
Safe reagent for the in situ generation of anhydrous formaldehyde in
1,2,3-Benzotriazin-4(3H)-one, 98% organic solvents.1
[90‑16‑4] C7H5N3O FW 147.13 Lit. cited: 1. Org. Lett. (2007)
7 7
Warning H302-H315-H319-H335 P261-P305 + P351 + P338 Warning H315-H319-H335 P261-P305 + P351 + P338

Benzotriazole, 99% 1H-Benzotriazole-4-sulfonic acid, 97%

1,2,3-Benzotriazole; 1H-Benzotriazole N [26725‑50‑8] C6H5N3O3S FW 199.19 OH
[95‑14‑7] Merck 14,1108; Beil. 26,IV,93; Fieser 16,21; 13,262 N O S O
N
C6H5N3 FW 119.12 H N
N
N
mp ............................................................ 97 to 99 °C vp .......................................... 0.04 mmHg (20 °C) H
vd ................................................................... 4.1 (vs air)
mp ................................................................................................................................................................ 285 °C (dec.)
 ReagentPlus ®
7
Warning H302-H319 P305 + P351 + P338
7
B11400-100G poly btl 100 g
> Benzotriazol-1-yl allyl carbonate, polymer-bound, see Alloc protecting
B11400-500G poly btl 500 g group introducing reagent, polymer-bound Page 66
B11400-750G poly btl 750 g
2-(2H-Benzotriazol-2-yl)-4,6-bis(1-methyl-1-phenylethyl)phenol
1H-Benzotriazole-1-acetonitrile, 95%
[70321‑86‑7] C30H29N3O FW 447.57
[111198‑08‑4] C8H6N4 FW 158.16 H3C CH3
N HO
N N
N CN N
N
mp .................................................................................................................................................................... 84 to 89 °C H3C
CH3
7
+ P338
mp .............................................................................................................................................................. 139 to 143 °C
 powder
Low volatile benzotriazole UV light absorber and stabilizer.
solubility (<0.04 ppm in H2O, 20 °C) ............................................................................................. insoluble
soluble in .. chloroform (35 wt. %), methylene chloride (34 wt. %), toluene (20 wt. %)
volat. ...................................................................................................................................................... 1.0 wt. %, 264°C
7
Warning H315-H319-H335 P261-P305 + P351 + P338
535753-100G glass btl 100 g

AHB A, 0613, UNP EU
n Benzotriazolylb n
O-(Benzotriazol-1-yl)-N,N,N′,N′-bis(tetramethylene)uronium 2-[3-(2H-Benzotriazol-2-yl)-4-hydroxyphenyl]ethyl methacryl-

hexafluorophosphate, ≥98.0% ate, 99%
HBPyU; (Benzotriazol-1-yloxy)dipyrrolidinocarbe- N [96478‑09‑0] C18H17N3O3 HO
nium hexafluorophosphate N FW 323.35 N
N N N O
[105379‑24‑6] C15H20F6N5OP FW 431.32 O PF6 N CH2
N O
CH3
mp ................................................................................................................................................................... 96 to 98 °C
mp ................................................................................................................................................................. 176 °C (dec.)
Recent studies show that crystal and solution structure of this Copolymerizable free radical stabilizer
7
coupling agent is a guanidinium N-oxide and not an uronium Warning H315-H319-H335 P261-P305 + P351 + P338
compound1; Non-hygroscopic, extremely reactive reagent for peptide
coupling giving low racemization. Reaction by-products are non- 413437-25G glass btl 25 g
cytotoxic2 413437-100G glass btl 100 g
soluble in ............................................................................................................................. acetonitrile (0.1 g/mL) 413437-500G glass btl 500 g
Lit. cited: 1. P. Henklein et al., Proc. 24th Eur. Pept. Symp.: Peptides 1996 ,
Mayflower Scientific (Kingswinford, UK: 1998), 465 1H-Benzotriazol-1-ylmethyl isocyanide, 94%
B 2. S. Chen, J. Xu, Tetrahedron Lett. 33, 647 (1992) 1-(Isocyanomethyl)-1H-benzotriazole N
7
Warning H315-H319-H335 P261-P305 + P351 + P338 [87022‑42‑2] C8H6N4 FW 158.16 N
N N C
store at: 2-8°C
12809-5G-F glass btl 5g mp ................................................................................................................................................................... 80 to 84 °C
12809-25G-F 25 g
7
+ P338
1H-Benzo[d][1,2,3]triazol-5-ylboronic acid pinacol 8
ester, 97% 367990-1G glass btl 1g
5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)- CH3 2-(2H-Benzotriazol-2-yl)-4-methyl-6-(2-propenyl)phenol, 99%
H3C
1H-benzo[d][1,2,3]triazole O
H3C 2-(3-Allyl-2-hydroxy-5-methylphenyl)-2H- HO
C12H16BN3O2 FW 245.09 H3C O
B N CH2
N benzotriazole; 2-Allyl-6-(2H-benzotriazol-2- N
N
N
H
yl)-p-cresol N
[2170‑39‑0] C16H15N3O FW 265.31 CH3
mp .............................................................................................................................................................. 142 to 146 °C
Covalently bondable UV light stabilizer.
7
Warning H315-H319-H335 P261-P305 + P351 + P338
solubility in H2O ............................................................................................................................................ insoluble
715557-250MG glass btl 250 mg transition temp ............................................................................................................................................... >270 °C
mp ................................................................................................................................................................. 98 to 101 °C
2-(2H-Benzotriazol-2-yl)-4,6-di-tert-pentylphenol, 98% density ................................................................................................................................................... 1.3 g/mL, 25 °C
[25973‑55‑1] Beil. 26,1,469 C22H29N3O H3C CH3 559857-5G glass btl 5g
HO
FW 351.49 CH3
N > (Benzotriazol-1-yloxy)dipyrrolidinocarbenium hexafluorophosphate, see O-
N (Benzotriazol-1-yl)-N,N,N′,N′-bis(tetramethylene)uronium hexafluorophos-
N
CH3 phate Page 242
H3C CH3
(Benzotriazol-1-yloxy)tripyrrolidinophosphonium hexafluoro-
mp .................................................................................................................................................................... 80 to 83 °C phosphate, 98%
UV absorber PyBOP®
7
Warning H315-H319-H335-H413 P261-P305 + P351 + P338 [128625‑52‑5] C18H28N6OP · PF6 FW 520.39
Analogue of the BOP coupling reagent which does not form
422746-50G poly btl 50 g carcinogenic HMPA as by-product.1,2
mp ............................................................................................................................................... 154 to 156 °C (dec.)
2-(2H-Benzotriazol-2-yl)-6-dodecyl-4-methylphenol
Lit. cited: 1. J. Coste, Tetrahedron Lett. 31, 205 (1990)
[125304‑04‑3] C25H35N3O FW 393.56 HO C12H25 2. D. Seebach, Helv. Chim. Acta 77, 1313 (1994)
N
7
N
Warning H315-H319-H335 P261-P305 + P351 + P338
N
CH3
mp .................................................................... >350 °C n20
D .......................................................................... 1.574
density ..................................... 0.911 g/mL, 25 °C
(Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexa-
Low volatile liquid benzotriazole UV light absorber/stabilizer. fluorophosphate, 97%
Imparts outstanding light stability and protection efficiency without BOP Reagent; BOP; Castros reagent N
imparting any yellowness to the protected substrate. [56602‑33‑6] Fieser 7,14; 6,34 C12H22F6N6OP2 N PF6-
Dodecyl chain is branched and linear. N
FW 442.28 H 3C O CH3
solubility (<0.01 ppm in H2O, 20 °C) ............................................................................................. insoluble N P N
H 3C CH3
soluble in ........ acetone, chloroform, ethyl acetate, n-hexane, methylene chloride, and N
H 3C CH3
toluene (50 wt. %)
9
H411 P273 mp ............................................................................................................................................................. >130 °C (dec.)
Peptide coupling agent.1
535788-100G glass btl 100 g Lit. cited: 1. Synthesis 2677 (2006)
27
> Benzotriazol-1-yl 9-fluorenylmethyl carbonate, polymer-bound, see Fmoc Danger H228-H315-H335-EUH044 P210-P261
protecting group introducing reagent, polymer-bound Page 1355

AHB A, 0613, UNP EU
n Benzoylacetone n
2-(2H-Benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol, > 1-Benzotriazol-1-yl-2,2,2-trifluoroethanone, see 1-(Trifluoromethyl)acetyl-

98% benzotriazole Page 2503
Benzotrichloride, see α,α,α-Trichlorotoluene Page 2479
Octrizole HO Benzotrifluoride, see α,α,α-Trifluorotoluene Page 2518
[3147‑75‑9] C20H25N3O FW 323.43 N α,α,α-Trifluorotoluene solution Page 2518
N
N CH3
2,1,3-Benzoxadiazole-5-carboxylic acid, 97%
H3C CH3
CH3 CH3 [19155‑88‑5] C7H4N2O3 FW 164.12 O
HO N
mp .............................................................................................................................................................. 106 to 108 °C O
N
UV absorber
7
322806-100G glass btl 100 g
> Benzoxanthene Yellow H 2495, see Hoechst 2495 Page 1449
O-(Benzotriazol-1-yl)-N,N,N′,N′-tetramethyluronium hexafluoro- 2,1-Benzoxathiol-3-one-1,1-dioxide, see 2-Sulfobenzoic acid cyclic anhydride
phosphate, ≥98.0% (T) Page 2347
HBTU; N,N,N′,N′-Tetramethyl-O-(1H-benzotriazol-1- N 2H-1,3-Benzoxazine-2,4(3H)-dione, 98%
B
CH3
yl)uronium hexafluorophosphate N
N N CH3 [2037‑95‑8] Beil. 27,262 C8H5NO3 FW 163.13
[94790‑37‑1] Merck 14,10422 C11H16F6N5OP O
O
FW 379.24 PF6 N CH3 NH
H3C
O O
Recent studies show that crystal as well as solution structure of this mp .............................................................................................................................................................. 228 to 232 °C
coupling agent is a guanidinium N-oxide and not an uronium
7
Warning H302
compound;1 Coupling reagent for peptide synthesis; advantages are:
very low racemization, simple reaction conditions, very short reaction
time, and high yields.2,3
mp ................................................................................................................................................................. 200 °C (dec.) 466174-25G glass btl 25 g
Lit. cited: 1. I. Abdelmoty, Lett. Pept. Sci. 1, 57 (1994) > 3,1-Benzoxazine-2,4(1H)-dione, see Isatoic anhydride Page 1567
2. L.A. Carpino etal., Angew. Chem. Int. Ed. Engl. 41, 441 (2001)
3. R. Knorr, Tetrahedron Lett. 30, 1927 (1989) 2H-1,4-Benzoxazin-3(4H)-one, 99%
soluble in ............................................................................................................................. acetonitrile (0.1 g/mL)
[5466‑88‑6] Beil. 27,190 C8H7NO2 FW 149.15 H
7
Warning H315-H319-H335 P261-P305 + P351 + P338 N O
store at: 2-8°C
O
12804-5G-F glass btl 5g mp .............................................................................................................................................................. 173 to 175 °C
7
12804-25G-F glass btl 25 g Warning H315-H319-H335 P261-P305 + P351 + P338
O-Benzotriazol-1-yl-N,N,N′,N′-tetramethyluronium hexafluoro-
phosphate polymer bound 383503-5G glass btl 5g
HBTU polymer bound
> 2-Benzoxazolamine, see 2-Aminobenzoxazole Page 94
 100-300 mesh, loading: ~1 mmol/g
matrix ............................................................................................ polystyrene, crosslinked with 2% DVB
Benzoxazole, 98%
[273‑53‑0] Beil. 27,42 C7H5NO FW 119.12 N
O
O-(Benzotriazol-1-yl)-N,N,N′,N′-tetramethyluronium tetrafluoro-
borate, ≥97.0% (N) mp ................................................................................................................................................................... 27 to 30 °C
TBTU; N,N,N′,N′-Tetramethyl-O-(benzotriazol-1-yl)uronium tetrafluoro- bp ................................................................................................................................................................................. 182 °C
7
borate Warning H302-H315-H319-H335 P261-P305 + P351 + P338
[125700‑67‑6] Fieser 12,44 C11H16N5O · BF4 FW 321.08
Coupling reagent which is ideally suited for solid-phase peptide B11702-25G poly btl 25 g
synthesis.
2-Benzoxazolinone, 98%
mp ................................................................................................................................................................. 205 °C (dec.)
Recent studies show that crystal as well as solution structure of this 2-Hydroxybenzoxazole H
[59‑49‑4] Beil. 27,IV,2677 C7H5NO2 FW 135.12 N
coupling agent is a guanidinium N-oxide and not an uronium O
compound1; Coupling reagent which is ideally suited for solid-phase O
peptide synthesis.2 mp .............................................................................................................................................................. 137 to 139 °C

soluble in ............................................................................................................................. acetonitrile (0.1 g/mL)
7
Lit. cited: 1. I. Abdelmoty et al., Lett. Pept. Sci. 1, 57 (1994)
2. S. Zimmer et al., C.H. Schneider and A.N. Eberle, eds., Proc. 22nd Eur. Pept.
Symp.: Peptides 1992 , ESCOM Sci. Publ. (Leiden 1993, p. 393) 157058-25G poly btl 25 g
157058-100G poly btl 100 g
7
Warning H315-H319-H335 P261-P305 + P351 + P338
store at: 2-8°C
2-Benzoylacetanilide, 98%
[959‑66‑0] Beil. 12,522 C6H5COCH2CONHC6H5 FW 239.27
12806-25G-F glass btl 25 g
mp .............................................................................................................................................................. 106 to 108 °C
12806-100G-F glass btl 100 g
12806-250G-F glass btl 250 g 123625-5G glass btl 5g
12806-1KG-F glass btl 1 kg 123625-25G glass btl 25 g
> Benzoylacetone, see 1-Phenyl-1,3-butanedione Page 2025
AHB A, 0613, UNP EU
n Benzoylacetonit n
Benzoylacetonitrile, 99% Benzoyl bromide, 97%

β-Oxohydrocinnamonitrile [618‑32‑6] Beil. 9,IV,724 C6H5COBr FW 185.02
[614‑16‑4] Beil. 10,680 C6H5COCH2CN FW 145.16 bp ............................................................... 218-219 °C n20
D .......................................................................... 1.589
density ........................................ 1.57 g/mL, 25 °C
mp .................................................................................................................................................................... 82 to 83 °C
57
bp ....................................................................................................................................................... 160 °C/10 mmHg Danger H314-H335-EUH014 P261-P280-P305 + P351 + P338-
P310
7
+ P338 139726-50G glass btl 50 g
N-Benzoyladenosine, 97% > 4-Benzoylbutyric acid, see 5-Oxo-5-phenylvaleric acid Page 1965
[4546‑55‑8] C17H17N5O5 FW 371.35 O Benzoyl chloride

NH [98‑88‑4] Merck 14,1112; Beil. 9,IV,721; Fieser 8,240; 5,24; 1,50
N N C6H5COCl FW 140.57
N mp .......................................................................... −1 °C vd ............................................................. 4.88 (vs air)
HO N
bp ......................................................................... 198 °C vp ................................................ 1 mmHg (32 °C)
O
density ..................................... 1.211 g/mL, 25 °C ait ...................................................................... 1056 °F
B OH OH
n20
D .............................................................................. 1.553
57
Danger H302-H312-H314-H317-H332 P280-P305 + P351 +
[α]20
D -49°, c = 1 in DMSO P338-P310
mp .............................................................................................................................................................. 141 to 145 °C
 ACS reagent, 99%
586846-1G glass btl 1g 98.0-100.5% (ACS specification)
> (Benzoylamino)hydroxyacetic acid, see α-Hydroxyhippuric acid Page 1486 freezing point ....................................................................................................................................... −2.0 ‑ 0.0 °C
4-Benzoylamino-2-methoxy-5-methylbenzenediazonium chloride hemi P compounds ................................................................................................................................................... ≤0.002%
(zinc chloride) salt, see Fast Violet B Salt Page 1287 ign. residue ............................................... ≤0.005% heavy metals (as Pb) ..................... ≤0.001%
N-Benzoylaniline, see Benzanilide Page 226 Fe ..................................................................... ≤0.001%
2-Benzoylaniline, see 2-Aminobenzophenone Page 93
3-Benzoylaniline, see 3-Aminobenzophenone Page 93 259950-5ML glass btl 5 mL
4-Benzoylaniline, see 4-Aminobenzophenone Page 93
2-Benzoylbenzoic acid, 98% 259950-1L glass btl 1L
Benzophenone-2-carboxylic acid  ReagentPlus®, 99%

[85‑52‑9] Beil. 10,IV,2977 C6H5COC6H4CO2H FW 226.23 B12695-25ML glass btl 25 mL
mp .............................................................................................................................................................. 126 to 129 °C
B12695-1L-CB PVC coated 1L
bp ....................................................................................................................................................................... 257-265 °C
B12695-1L glass btl 1L
7
Warning H315-H319-H335 P261-P305 + P351 + P338
B12695-2L glass btl 2L
B12695-2.5L 2.5 L
B12385-500G poly btl 500 g Benzoyl chloride polymer bound
 (Chlorocarbonyl)polystyrene
3-Benzoylbenzoic acid, 99% 100-300 mesh, loading: ~1.5 mmol/g
[579‑18‑0] Beil. 10,752 C6H5COC6H4CO2H FW 226.23 Support for SPOS of polyheterocyclic isoxazoles1; Scavenger for
removing excess amines2
mp .............................................................................................................................................................. 164 to 166 °C
matrix .......................................................................................................................... crosslinked with 2% DVB
7
Warning H315-H319-H335 P261-P305 + P351 + P338
Lit. cited: 1. E.J. Kantorowski, M.J. Kurth, J. Org. Chem. 62, 6797 (1997)
2. S.W. Kaldor et al., Tetrahedron Lett. 37, 7193 (1996)
Benzoyl chloride-α-13C
4-Benzoylbenzoic acid, 99%
Benzoyl chloride-carbonyl-13C
Benzophenone-4-carboxylic acid [52947‑05‑4] C6H513COCl FW 141.56
[611‑95‑0] Beil. 10,III,3305 C6H5COC6H4CO2H FW 226.23 mp .......................................................................... −1 °C n20
D .......................................................................... 1.553
mp .............................................................................................................................................................. 198 to 200 °C bp ......................................................................... 198 °C
 99 atom % 13C
density ............................................................................................................................................. 1.219 g/mL, 25 °C
> 2-Benzoylbenzonitrile, see 2-Cyanobenzophenone Page 791 279323-250MG 250 mg
4-Benzoylbenzonitrile, see 4-Cyanobenzophenone Page 791
279323-1G ampule 1g
1-Benzoyl-1H-benzotriazole Benzoyl chloride-d5
[4231‑62‑3] C13H9N3O FW 223.23 Pentadeuterobenzoyl chloride
7
Warning H315-H319-H335 P261-P305 + P351 + P338 [43019‑90‑5] C6D5COCl FW 145.60
mp ............................................................................ -1 °C n20
D .......................................................................... 1.552
596590-1G glass btl 1g bp ......................................................................... 198 °C
4-Benzoylbiphenyl, 99%  99 atom % D

4-Phenylbenzophenone mol wt 145.55, atom % calculation
[2128‑93‑0] Beil. 7,521 C6H5C6H4COC6H5 FW 258.31 density ............................................................................................................................................. 1.254 g/mL, 25 °C
57
mp ................................................................................................................................................................. 99 to 101 °C Danger H302-H312-H314-H317-H332 P280-P305 + P351 +
bp ....................................................................................................................................................................... 419-420 °C P338-P310
B12601-5G glass btl 5g 366048-1G glass btl 1g

AHB A, 0613, UNP EU
n Benzoylisothioc n
Benzoyl cyanide, 98% Benzoyleneurea, 97%

Phenylglyoxylonitrile 2,4(1H,3H)-Quinazolinedione O
[613‑90‑1] Beil. 10,IV,2743; Fieser 6,35 C6H5COCN FW 131.13 [86‑96‑4] Beil. 24,373 C8H6N2O2 FW 162.15 NH
mp ............................................................ 28 to 31 °C density .................................. 1.106 g/mL, 25 °C
N O
bp ......................................................................... 206 °C H
6
Danger H300 P264-P301 + P310
mp ............................................................................................................................................................................... 300 °C

> Benzoylcyclohexane, see Cyclohexyl phenyl ketone Page 816 Benzoylferrocene, ≥98%
[1272‑44‑2] C17H14FeO FW 290.14
2-Benzoylcyclohexanone, 98%
[3580‑38‑9] C6H5COC6H9(=O) FW 202.25
mp .................................................................................................................................................................... 88 to 91 °C Benzoyl fluoride, 99%
461229-5G glass btl 5g [455‑32‑3] Beil. 9,181 C6H5COF FW 124.11
mp ....................................................................... −28 °C density .................................... 1.14 g/mL, 25 °C
461229-25G glass btl
> Benzoylcyclopropane, see Cyclopropyl phenyl ketone Page 828

25 g
bp ............................................................... 159-161 °C n20 D .......................................................................... 1.496 B
25
Danger H226-H314 P280-P305 + P351 + P338-P310
N4-Benzoylcytidine, 99%
[13089‑48‑0] C16H17N3O6 FW 347.32 O
> Benzoylformic acid, see Phenylglyoxylic acid Page 2037
NH
N (+)-N-Benzoylglutamic acid, 97%

O N [58094‑18‑1] HO2CCH2CH2CH(NHCOC6H5)CO2H FW 251.24
HO
O  synthetic
7
Warning H315-H319-H335 P261-P305 + P351 + P338
OH OH

[α]27
D +55°, c = 0.1 in methanol > N-Benzoylglycine, see Hippuric acid Page 1447
326151-100MG 100 mg N-Benzoyl-Gly-His-Leu, see N-Hippuryl-His-Leu hydrate Page 1448
5-Benzoyl-4-hydroxy-2-methoxybenzenesulfonic acid, ≥97.0%
N4-Benzoylcytosine, 98% (HPLC)
[26661‑13‑2] Beil. 25,IV,3658 C11H9N3O2 Sulisobenzone; HMBS O OH
O NH
FW 215.21 [4065‑45‑6] Merck 14,8983 C14H12O6S
N N O FW 308.31
H OCH3
O S O
mp ............................................................................................................................................................. >300 °C (dec.) OH
7
Warning H302-H315-H319-H332-H335 P261-P305 + P351 + P338 water .............................................................................................................................................................................. ≤10%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2′-Benzoyl-2,4′-dichloroacetanilide, 97% 09649-10G poly btl 10 g
[4016‑85‑7] C6H5COC6H3(Cl)NHCOCH2Cl FW 308.16 Benzoyl isocyanate, 90%

mp .............................................................................................................................................................. 119 to 123 °C
[4461‑33‑0] Beil. 9,222 C6H5CONCO FW 147.13
5 bp .......................................... 94-96 °C/21 mmHg n20
Danger H314 P280-P305 + P351 + P338-P310 D ....................................................................... 1.5514
density ..................................... 1.171 g/mL, 25 °C
 technical grade
N4-Benzoyl-5′-O-(4,4′-dimethoxytrityl)-2′-deoxycytidine, 95%
7
Bz-DMT-dC + P338
O
[67219‑55‑0] C37H35N3O7 FW 633.69 308188-1G glass btl 1g
NH
N
O N Benzoyl isothiocyanate, 98%

H3CO O [532‑55‑8] Merck 14,1114; Beil. 9,IV,777; Fieser 1,50 C6H5CONCS
O
FW 163.20
OH bp .................................... 128-131 °C/15 mmHg n20 D ....................................................................... 1.6354
OCH3 density ..................................... 1.214 g/mL, 25 °C
56
Danger H301-H317-H318-EUH032 P280-P301 + P310-P305 +
78
Danger H315-H319-H335-H340-H350 P201-P261-P305 + P351 P351 + P338 store at: 2-8°C
+ P338-P308 + P313

AHB A, 0613, UNP EU
n Benzoylnaphthol n
6-Benzoyl-2-naphthol, ≥98% Benzoyl peroxide blend with dicyclohexyl phthalate, ~50% (T)
6-Hydroxy-2-naphthyl phenyl ketone Merck 14,1116 C14H10O4 FW 242.23
[52222‑87‑4] C6H5COC10H6OH FW 248.28  technical
mp .............................................................................................................................................................. 161 to 162 °C water ............................................................................................................................................................................. ≤0.5%
7
Warning H315-H319-H335 P261-P305 + P351 + P338
27
P351 + P338-P410-P411 + P235 store at: 2-8°C
190608-250MG glass btl 250 mg 00213-100G poly btl 100 g
Benzoylnitromethane, 98% 4-Benzoylphenylboronic acid
α-Nitroacetophenone [268218‑94‑6] C6H5COC6H4B(OH)2 FW 226.04
[614‑21‑1] Beil. 7,289 C6H5COCH2NO2 FW 165.15 Contains varying amounts of anhydride
mp .............................................................................................................................................................. 105 to 107 °C mp .............................................................................................................................................................. 204 to 212 °C
7
+ P338
308080-5G glass btl 5g > 4-Benzoyl-o-phenylenediamine, see 3,4-Diaminobenzophenone
B 2-Benzoyloxazole
Page 860
N-Benzoyl-N-phenylhydroxylamine, 98%
[174150‑58‑4] C10H7NO2 FW 173.17
N N-Hydroxy-N-phenylbenzamide; N-Phenylbenzohydroxamic acid
O [304‑88‑1] Beil. 15,IV,7 C6H5CON(OH)C6H5 FW 213.23
O
mp .............................................................................................................................................................. 118 to 120 °C
7
Warning H302-H315-H317-H319-H335 P261-P280-P305 + P351 + 274852-5G glass btl 5g
P338
N-Benzoyl-(2R,3S)-3-phenylisoserine, 98%
[132201‑33‑3] C6H5CONHCH(C6H5)CH(OH)CO2H FW 285.29
[3aR(3aα,4α,5β,6aα)]-(−)-5-(Benzoyloxy)hexahydro-2-oxo-2H- mp .............................................................................................................................................................. 169 to 172 °C
cyclopenta[b]furan-4-carboxaldehyde, 95%
D −40°, c = 1.0 in ethanol
[α]20
[39746‑01‑5] C15H14O5 FW 274.27
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-(Benzoyloxymethyl)benzoic acid, ≥98.0% (T) > trans-2-Benzoyl-3-phenyloxirane, see trans-1,3-Diphenyl-2,3-epoxypropan-1-

one Page 1141
[58249‑83‑5] C15H12O4 FW 256.25 (S)-2-(3-Benzoylphenyl)propionic acid, see (S)-(+)-Ketoprofen Page 1598
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-(3-Benzoylphenyl)propionitrile, 95%
13030-10G glass btl 10 g [42872‑30‑0] CH3CH(C6H4COC6H5)CN FW 235.28
mp ................................................................................................................................................................... 47 to 53 °C
2-(Benzoyloxymethyl)benzoyl chloride, ≥97.0% (AT)
7
2-(Hydroxymethyl)benzoyl chloride benzoate Cl O
[58249‑87‑9] C15H11ClO3 FW 274.70 O
O
1-Benzoylpiperazine, 97%
[13754‑38‑6] C11H14N2O FW 190.24
contains ~1% CaCO3 as stabilizer
Reagent for a novel amine protection which gives amides the lability O
of esters1 N
mp .................................................................................................................................................................... 59 to 61 °C
Lit. cited: 1. B.F. Cain, J. Org. Chem. 41, 2029 (1976) N
H
5
mp ................................................................................................................................................................... 61 to 64 °C
13032-5G glass btl 5g bp ................................................................................................................................................... 145 °C/0.05 mmHg
7
Warning H315-H319-H335 P261-P305 + P351 + P338
5-Benzoylpentanoic acid, 97%
5-Benzoylvaleric acid 571083-1G glass btl 1g
[4144‑62‑1] C6H5CO(CH2)4CO2H FW 206.24 571083-5G glass btl 5g
mp .................................................................................................................................................................... 75 to 79 °C
1-Benzoylpiperazine hydrochloride, 97%
7
Warning H319 P305 + P351 + P338
[56227‑55‑5] C11H14N2O · HCl FW 226.70
663166-1G glass btl 1g 592714 Full product information at Aldrich.com
> Benzoyl peroxide, see Luperox® A70S, Benzoyl peroxide Page 1634
Luperox® A75, Benzoyl peroxide Page 1634
Luperox® A75FP, Benzoyl peroxide, 75% remainder water Page 1634
Luperox® A98, Benzoyl peroxide Page 1634
Benzoyl peroxide, blend in dibutyl phthalate, see Luperox® AFR40, Benzoyl
peroxide solution Page 1634
Benzoyl peroxide, blend in tricresyl phosphate, see Luperox® ATC50,
Benzoyl peroxide Page 1634

AHB A, 0613, UNP EU
n Benzyladenine n
1-Benzoyl-4-piperidone, 97% Benzyl-2-acetamido-4,6-O-benzylidene-2-deoxy-α-D-gluco-

pyranoside, ≥99.0% (HPLC, sum of enantiomers)
[24686‑78‑0] C12H13NO2 FW 203.24 O
[13343‑63‑0] Beil. 19,V,11,243
N
C22H25NO6 FW 399.44 O
O O
O O
mp .................................................................................................................................................................... 55 to 59 °C
HO NH
bp ........................................................................................................................................... 158-160 °C/0.2 mmHg
O
3-Benzoylpropionic acid, 99% [α]20

D +115±3°, c = 1 in pyridine
4-Oxo-4-phenylbutyric acid Carbohydrate building block; used for the synthesis of N-acetyl
[2051‑95‑8] Beil. 10,IV,2772; Fieser 3,19; 2,26 C6H5COCH2CH2COOH muramic acid and similar compounds;1,2 preparation of derivatives of
FW 178.18 2,3-diamino-2,3-dideoxy-glucopyranoside.3
mp .............................................................................................................................................................. 114 to 117 °C mp ............................................................................................................................................... 256 to 261 °C (dec.)
Lit. cited: 1. T. Osawa, R.W. Jeanloz, J. Org. Chem. 30, 448 (1965)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2. M. Imoto et al., Bull. Chem. Soc. Jpn. 59, 3207 (1986)
B
3. W. Meyer-Reckendorf, Chem. Ber. 102, 4207 (1969)
B13802-100G poly btl 100 g
Benzyl acetate, ≥99%
> β-Benzoylpropionitrile, see 4-Oxo-4-phenylbutanenitrile Page 1964
3-Benzoylpropionitrile, see 4-Oxo-4-phenylbutanenitrile Page 1964 Acetic acid benzyl ester
[140‑11‑4] Merck 14,1123; Beil. 6,IV,2262 CH3COOCH2C6H5
2-Benzoylpyridine, ≥99% FW 150.17
Phenyl 2-pyridyl ketone mp ....................................................................... −51 °C n20D .......................................................................... 1.502
[91‑02‑1] Beil. 21,V,8,566 C12H9NO FW 183.21 bp ......................................................................... 206 °C vp .......................................... 23 mmHg (110 °C)
N density ..................................... 1.054 g/mL, 25 °C ait ......................................................................... 862 °F
O
79
mp .................................................................................................................................................................... 41 to 43 °C P338
bp ................................................................................................................................................................................. 317 °C B15805-100G glass btl 100 g
7
Warning H315-H319-H335 P261-P305 + P351 + P338 B15805-1KG glass btl 1 kg
Benzyl acetoacetate
B14000-100G glass btl 100 g Acetoacetic acid benzyl ester
[5396‑89‑4] Beil. 6,IV,2480 CH3COCH2COOCH2C6H5 FW 192.21
3-Benzoylpyridine, 97% bp .................................... 156-159 °C/10 mmHg n20 D .......................................................................... 1.512
[5424‑19‑1] Beil. 21,331 C12H9NO FW 183.21 density ..................................... 1.112 g/mL, 25 °C

O
 97%
N 295892-100G glass btl 100 g
295892-500G glass btl 500 g
mp .................................................................................................................................................................... 36 to 40 °C
bp ................................................................................................................................................................................. 307 °C  AC-benzyl
Wacker quality, ≥96% (GC)
7
Warning H315-H319-H335 P261-P305 + P351 + P338
product of Wacker Chemie AG
B14205-1G glass btl 1g prices for bulk quantities on request
B14205-5G glass btl 5g 10898-1KG glass btl 1 kg
10898-25KG 25 kg
3-Benzoylpyridine-2-carboxylic acid, 98%
> Benzyl acrylate polymer-bound, see REM resin Page 2244
[64362‑32‑9] Beil. 22,318 C13H9NO3 FW 227.22 O
3-Benzyladenine, 95%
OH
N 3-Benzyl-3H-purin-6-amine NH2
O [7280‑81‑1] C12H11N5 FW 225.25
N N
mp .............................................................................................................................................................. 151 to 155 °C N
N
7
Warning H315-H319-H335 P261-P305 + P351 + P338

mp .............................................................................................................................................................. 268 to 275 °C
2-Benzoylthiophene, 98%
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
[135‑00‑2] Beil. 17,348 C11H8OS FW 188.25 P338
S
O 691941-500MG glass btl 500 mg
mp .................................................................................................................................................................... 56 to 58 °C > N6-Benzyladenine, see 6-Benzylaminopurine Page 249

bp ................................................................................................................................................................................. 300 °C
> 5-Benzoylvaleric acid, see 5-Benzoylpentanoic acid Page 246

2-Benzoylvinyl chloride, see 3-Chloro-1-phenyl-2-propen-1-one Page 730
AHB A, 0613, UNP EU
n Benzyladenosine n
N6-Benzyladenosine, ≥99.0% Benzyl alcohol-α,α-d2

[4294‑16‑0] Beil. 26,IV,3682 C17H19N5O4 [21175‑64‑4] C6H5CD2OH FW 110.15
NH
FW 357.36 mp ........................................................ -16 to -13 °C n20 D ....................................................................... 1.5388
N N
bp ............................................................... 203-205 °C
N N
HO O  98 atom % D
OH OH
density ............................................................................................................................................. 1.065 g/mL, 25 °C
7
mp .............................................................................................................................................................. 184 to 186 °C Warning H302-H332
store at: 2-8°C
13155-1G glass btl 1g 461059-1G ampule 1g
> N-Benzyl-β-alanine ethyl ester, see Ethyl 3-(benzylamino)propionate Benzyl alcohol-α-13C-α,α-d2

Page 1217
2-Benzyl-β-alanine methyl ester hydrochloride, see Methyl (RS)-2-(amino-
[285977‑71‑1] C6H513CD2OH FW 110.15
methyl)-3-phenylpropionate hydrochloride Page 1734  99 atom % 13
C; 98 atom % D
Benzyl alcohol 491926 Full product information at Aldrich.com
B Benzenemethanol Benzyl-2,3,4,5,6-d5 alcohol

[100‑51‑6] Merck 14,1124; Beil. 6,IV,2222 C6H5CH2OH FW 108.14 [68661‑10‑9] C6D5CH2OH FW 113.17
mp ..................................................... −16 to −13 °C vd ................................................................ 3.7 (vs air) mp ........................................................ -16 to -13 °C n20 D .......................................................................... 1.539
bp ............................................................... 203-205 °C vp .......................................... 3.75 mmHg (77 °C) bp ............................................................... 203-205 °C
density ..................................... 1.045 g/mL, 25 °C vp ....................................... 13.3 mmHg (100 °C)
n20
D .............................................................................. 1.539 ait ......................................................................... 817 °F  98 atom % D
7
Warning H302-H332 mol wt 113.07, atom % calculation
density ............................................................................................................................................. 1.094 g/mL, 25 °C
 anhydrous, 99.8%
7
Warning H302-H332
water ........................................................................................................................................................................ <0.003%
water ..................................................................................................................................... <0.005% (100 mL pkg) 362999-250MG ampule 250 mg
305197-100ML Sure/Seal™ 100 mL 362999-1G ampule 1g
305197-1L Sure/Seal™ 1L Benzyl-d7 alcohol
[71258‑23‑6] C6D5CD2OH FW 115.18
 ACS reagent, ≥99.0% mp ........................................................ -16 to -13 °C n20 D .......................................................................... 1.537
bp ............................................................... 203-205 °C
Acetophenone (C6H5COCH3) ................................................................................................................... ≤0.02%
Benzaldehyde (C6H5CHO) ........................................................................................................................... ≤0.01%
 98 atom % D
APHA color .................................................................................................................................................................... ≤20
ign. residue ....................................................................................................................................................... ≤0.005%
density ............................................................................................................................................. 1.113 g/mL, 25 °C
386472-1G ampule 1g
402834-1L glass btl 1L Benzyl alcohol-ring-13C6
402834-2L glass btl 2L 13
C6H5CH2OH FW 114.09
 99 atom % 13
C
 ReagentPlus®, ≥99% 586927 Full product information at Aldrich.com
108006-100ML glass btl 100 mL > Benzyl alcohol polymer-bound, see (Hydroxymethyl)polystyrene
108006-500ML glass btl 500 mL Page 1500
108006-2.5L 2.5 L
Benzylamine
108006-20L steel drum 20 L α-Aminotoluene
[100‑46‑9] Merck 14,1125; Beil. 12,IV,2155; Fieser 1,51; 10,26
Benzyl alcohol, polymer-bound C6H5CH2NH2 FW 107.15
Hydroxymethyl polystyrene; (Hydroxymethyl)poly- mp ........................................................................... 10 °C density ................................. 0.981 g/mL, 25 °C
OH
styrene; Benzyl alcohol polymer-bound; Polystyrene bp ............................................................... 184-185 °C n20 D .......................................................................... 1.543
cross-linked with divinylbenzene, hydroxymethylated

57
Danger H302-H312-H314 P280-P305 + P351 + P338-P310
 70-90 mesh, loading: 2.0-3.0 mmol, 1% cross-linked  purified by redistillation, ≥99.5%

499226-5G glass btl 5g purified by glass distillation
499226-25G glass btl 25 g 407712-100ML Sure/Seal™ 100 mL
 100-200 mesh, loading: 1.0-2.0 mmol/g, 1% cross-linked with
divinylbenzene  ReagentPlus®, 99%
Benzyl alcohol-α-13C 185701-500G glass btl 500 g
[54522‑91‑7] C6H513CH2OH FW 109.13

 99 atom % 13
C

AHB A, 0613, UNP EU
n Benzylaminopyrr n
Benzylamine hydrochloride > 3-(Benzylamino)propionic acid ethyl ester, see Ethyl 3-(benzylamino)
propionate Page 1217
Phenylmethylamine
[3287‑99‑8] Beil. 12,1017 C6H5CH2NH2·HCl FW 143.61 3-(Benzylamino)propionitrile, 97%
mp .............................................................................................................................................................. 262 to 263 °C [706‑03‑6] C6H5CH2NHCH2CH2CN FW 160.22
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 + density ............................................................................................................................................. 1.024 g/mL, 25 °C
P338 n20
D ................................................................................................................................................................................... 1.5308
7
B5136-100G poly btl 100 g + P338
Benzylamine-15N 185167-25G glass btl 25 g

185167-100G glass btl 100 g
[42927‑57‑1] C6H5CH215NH2 FW 108.15
mp ........................................................................... 10 °C n20
D .......................................................................... 1.543 > Benzyl N-(3-aminopropyl)carbamate hydrochloride, see N-Z-1,3-Propanedi-
bp ............................................................... 184-185 °C amine hydrochloride Page 2626
 98 atom % 15N 6-Benzylaminopurine, ≥99.0% (HPLC)

mol wt 108.15, atom % calculation BA; N6-Benzyladenine; 6-BAP
NH
B
density ............................................................................................................................................. 0.990 g/mL, 25 °C [1214‑39‑7] Beil. 26,IV,3575 C12H11N5 FW 225.25 H
N N
57
Danger H302-H312-H314 P280-P305 + P351 + P338-P310
N N
488208-1G ampule 1g
ign. residue .......................................................................................................................................................... ≤0.05%
> Benzylamine polymer-bound, see (Aminomethyl)polystyrene Page 144 mp .............................................................................................................................................................. 230 to 233 °C
Benzyl N-(4-aminobutyl)carbamate hydrochloride, see N-Z-1,4-Butanedi-
7
Warning H315-H319-H335 P261-P305 + P351 + P338
2-Benzylaminoethanol, 95% 13151-1G-F glass btl 1g

N-Benzylethanolamine
[104‑63‑2] Beil. 12,IV,2184 C6H5CH2NHCH2CH2OH FW 151.21 13151-25G-F glass btl 25 g
bp ..................................... 153-156 °C/12 mmHg n20 D .......................................................................... 1.543 2-Benzylaminopyridine, 98%
density ..................................... 1.065 g/mL, 25 °C
[6935‑27‑9] C12H12N2 FW 184.24
57
Danger H302-H315-H318-H335 P261-P280-P305 + P351 +
B22003-500G glass btl 500 g P338
> Benzyl N-(6-aminohexyl)carbamate hydrochloride, see N-Z-1,6-hexanedi- 195057-50G poly btl 50 g

1-Benzyl-3-aminopyrrolidine, 95%
Benzyl α-aminoisobutyrate hydrochloride, ≥98% 8
(HPLC) 1-Benzyl-3-pyrrolidinamine NH2
[18471‑40‑4] C11H16N2 FW 176.26
Benzyl 2-amino-2-methylpropionate hydro- O
N
chloride; 2-Methylalanine benzyl ester H3C
O
hydrochloride; H-Aib-OBzl • HCl
H2N CH3
[60421‑20‑7] C11H15NO2 · HCl FW 229.70
composition density ............................................................................................................................................. 1.024 g/mL, 25 °C
carbon 56.7‑58.3% n20

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2012–2014

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1 (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3- 8 Dimethyl carbonate

7 Reagent used in the enantioselective allylation of aldehydes1

15 B13802-25G poly btl 25 g 33.00

> β-Benzoylpropionitrile, see 4-Oxo-4-phenylbutanenitrile Page 1964

1 Substance name 10 Index references

2 Substance synonyms 11 Hazard pictograms

3 CAS 12 Hazard and precautionary codes

4 Molecular formula 13 Product grade or special quality

5 Linear formula 14 Product physical data and analytical

8 Substance physical property data: 17 Packaging description

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mp ............................................................ 90 to 94 °C vd ............................................................. 5.32 (vs air)

L-Abrine, 99%  99 atom % D

> p-ABSA, see 4-Acetamidobenzenesulfonyl azide Page 16

> ABT, see 1-Aminobenzotriazole Page 94

14 • For Certificate of Analysis and MSDS information, visit Aldrich.com/searchcenter •

A201-25G-A poly btl 25 g  ≥99.0% (GC)

A9758-25G poly btl 25 g

> Acetal, see Acetaldehyde diethyl acetal Page 16

• For additional products and custom pack sizes, visit Aldrich.com/cpr • 15

Acetaldehyde ammonia trimer, ≥96.0% (NT) Acetamide-15N

Acetaldoxime mp .............................................................................................................................................................. 154 to 158 °C

Acetamide  technical grade

16 • PEFC certified paper sourced from sustainably managed forests •

3-Acetamidobenzoic acid, ≥98.0% (HPLC) 2-Acetamido-2-deoxy-β-D-glucopyranosyl azide 3,4,6-triacetate,

4′-Acetamido-3′-bromoacetophenone, 97% mp ............................................................................................................................................................. >214 °C (dec.)

722065-5G glass btl 5g mp .............................................................................................................................................................. 134 to 136 °C