SISTEMA ACETONA- AGUA

TEMP(C) 373.15
PRESION(ATM) 1 101.325 Psat(acetona) 373.025555342
Psat(agua) 100.908903621
CONSTANTE DE ANTOINE
A B C Pt 196.149731723
14.71 2976 -34.52 y(acet) 0.66560857985
16.54 3985 -39

Xi yi P T(K) Psat (ac) Psat (H2O

0 0 100.9089 329.4167748 101.324999925 16.749038
0.1 0.291151966 128.12057 334 118.246978766 20.728829
0.2 0.480293814 155.33223 339 139.20657933 25.96285
0.3 0.61304523 182.5439 344 163.019482295 32.279302
0.4 0.711352867 209.75556 349 189.949660891 39.85155
0.5 0.787082577 236.96723 354 220.271946231 48.872084
0.6 0.847211256 264.17889 359 254.271442299 59.553496
0.7 0.896109637 291.39056 364 292.242894189 72.129386
0.8 0.936655242 318.60222 369 334.490016074 86.855205
0.9 0.970819881 345.81389 373.2653387 374.143441926 101.325
1 1 373.02556

1.2

0.8

Colum
0.6 nA
Colum
nB

0.4

0.2

0
1 2 3 4 5 6 7 8 9 10 11
 400
Tsat 329.41677482164
373.26533870352 350

300

250

200
Xi yi
1 1 150
0.8264735 0.9645003684996
0.6654863 0.9142864139975 100
0.5281138 0.8496703060107
0.4095551 0.7677755406046 50
0.3060266 0.6652758308565
0.2145231 0.5383380861845 0
0.1326389 0.3825588562721 0 0.2 0.4 0.6 0.8 1 1

0.058432 0.1928933351366
0 0
380

370

360

350

340

330

320

310

300
0 0.2 0.4 0.6 0.8 1 1.2
 Column
C
Column
C

6 0.8 1 1.2

Column
E
Column
E

0.8 1 1.2
T= 332.05 1. se calculan las presiones de saturacion a la temperatura especifica
P= 101.33 2. La Ki son calculadas por la relacion Psat/P
Z1= 0.3 3. La ecuacion f(y) = Σ(zi*ki/(1+V(ki-1)), se resuelve con funcion objeti
0.7

CONSTANTE DE ANTOINE
A B C
14.7171 2975.95 -34.5228 PSAT1 111.588859
16.4948 3593.39 -35.2249 PSAT2 80.5368329

K1=PSAT/P 1.10124207
K2= 0.79479752

V= 0.9999964036
F.OBJETIVO -5.507814E-07
 la temperatura especificada por el problema.

resuelve con funcion objetivo

 SISTEMA BENCENO- ETIL B

TEMPERATURA
mmHg Kpa
PRESION 586 78.1269 Psat(BEN)
Psat(TOL)
CONSTANTE DE ANTOINE
COMPUESTO A B C Pt
BENCENO 6.03055 1211.033 220.79 y(acet)
Etil benceno 6.08209 1424.255 213.202

Xi yi T
0 0 71.889158
0.1 0.4157666 76.88
0.2 0.6155621 80
0.3 0.7329712 85
0.4 0.8102419 90
0.5 0.8649525 95
0.6 0.9057244 100
0.7 0.9372826 105
0.8 0.9624331 110
0.9 0.9829477 115
1 1 120
126.773722

BENCENO - TOLUENO x Vs y
1.2

0.8

0.6

0.4

0.2

0
0 0.2 0.4 0.6 0.8 1 1.2
0.4

0.2

0
0 0.2 0.4 0.6 0.8 1 1.2
CENO- ETIL BENCENO

78.12690789 Tsat 71.8892

12.19817732 126.774

35.27323302
0.775217223

Psat (ben) Psat(ETILBE xi yi xi P y

78.12690789 12.1981773 1 1 0 12.1982 0
91.65910783 14.8678233 0.824 0.96646 0.1 18.7911 0.41577
101.01261 16.7684811 0.728 0.94169 0.2 25.3839 0.61556
117.5460217 20.2274864 0.595 0.89513 0.3 31.9768 0.73297
136.1200349 24.2495586 0.482 0.8391 0.4 38.5697 0.81024
156.8984157 28.9008241 0.385 0.77235 0.5 45.1625 0.86495
180.0494491 34.2518058 0.301 0.69352 0.6 51.7554 0.90572
205.7454874 40.3773931 0.228 0.60116 0.7 58.3483 0.93728
234.1624863 47.3567878 0.165 0.49369 0.8 64.9412 0.96243
265.4795328 55.2734276 0.109 0.36943 0.9 71.534 0.98295
299.8783694 64.2148889 0.059 0.22659 1 78.1269 1
351.7239022 78.1269079 0 0

Chart Title
1.2

0.8

0.6

0.4

0.2

0
70 80 90 100 110 120 130
Column J Column K

1.2
1.2
 BENCENO -ETILBENCENO P Vs x,y
90

80

70

60

50

40

30

20

10

0
0 0.2 0.4 0.6 0.8 1 1.2
1.2
 SISTEMA BENCENO- TOLUENO

PRESION 1 760 Tsat(BEN 80.1037313

Tsat(tol) 110.428842
CONSTANTE DE ANTOINE
A B C
6.9056 1211.033 220.79
6.95334 1343.143 219.377

T Psat (ben) psat (tol) Ptotal xi yi

80.1 759.9126622 294.0206834108 760 1 1
83 830.204422 324.6322812749 760 0.86114 0.9406857
86 908.1694791 358.9459518314 760 0.73022 0.87258367
89 991.7307138 396.1114321349 760 0.61094 0.79722303
92 1081.153477 436.2959635563 760 0.50198 0.71409848
95 1176.707599 479.6717245239 760 0.40217 0.62268261
98 1278.667132 526.4157307045 760 0.31051 0.52242566
101 1387.31008 576.7097262729 760 0.22612 0.41275523
104 1502.918133 630.7400667465 760 0.1482 0.29307616
107 1625.776394 688.6975938715 760 0.07609 0.16277035
110.4 1774.144508 759.3769591026 760 0 0

Alimentacion 0.45 0 0 0
0.45 0.45 1 1

Destilado X(ben) 0.95 0

0.95 1

Reciduo 0.1 0
0.1 1

q 1.195

mq 6.128205128

x 0.539748954
y 1
2
linea q 0.45 0.45
0.539748954 1

LOE(MIN) 0.95 0.95

0 0.44
 LOA(MIN) 0.1 0.1
0.49 0.705

m(LOEMIN) 0.536842105 0.536842105263

Rmin 1.159090909
RRO 4.636363636

0.822580645 b 0.16855

Y2=b 0.168548387

LOER 0.95 0.95

0 0.168548387097

LOAR 0.1 0.1

0.47 0.555

a)Teflujo total 5.8 etapas c) Numero de platos teoricos 7.2

b) reflujo minimo 1.159090909 d) plato donde se introduce la alimentacion 5

1.2

0.8

0.6
0.6

0.4

Column I Column I Colum

0.2

0
0 0.2 0.4 0.6
1.2

1
f(x) = 6.12820512820513 x − 2.30769230769231

f(x) = 0.82258064516129 x + 0.168548387096774

0.8

0.6

0.44
0.6

0.44

0.4

0.2 Column I Column I Column F Column F

Linear (0.45 0.539748953974895) Column D Column D Column D

0
0 0.2 0.4 0.6 0
Column I Column F Column F

0.6 0.8 1 1.2

0513 x − 2.30769230769231
0.95
 Column F Column F ZB 0.45 0.539748953974895

Column D Column D Linear (Column D) Column D

.6 0.8 1 1.2
 SISTEMA METANOL-ACETATO DE METILO

TEMPERATURA mmHg Kpa P(Sat) MET 77.3269736842

PRESION 580 77.3269737 P(Sat)ACETATO 1.04393330374

CONSTANTE DE ANTONIE
A B C PT 27.7429974369
Metanol 7.1973 1574.99 238.87 Y 0.97554133619
Acetato 4.1862 1156.43 219.69

Xi Yi T Psat (metanol)
0 0 58.0458 78.1267092993
0.1 0.89166118 62 91.730595338
0.2 0.94876571 70 125.342885754
0.3 0.96946141 80 181.14001431
0.4 0.98015157 90 255.978803425
0.5 0.98667958 100 354.429178829
0.6 0.99108012 150 1403.23042225
0.7 0.99424746 175 2464.79814739
0.8 0.99663629 200 4060.32444527
0.9 0.99850222 225 6338.31360465
1 1 250 9453.77084237
284.5527 15426.9048768
Chart Title
1.2

0.8

0.6

0.4

0.2

0
1 2 3 4 5 6 7 8 9 10 11
Column C Column D
 Tsat Metanol 57.7958882
Tsat Acetato 283.571938

Psat(acetato de metilo) Xi Yi Xi P Y
1.05298641929307 0.98962376 0.9998587 0 1.0439333 0
1.20467929836421 0.84088952 0.99752121 0.1 8.67223734 0.89166118
1.56402280255513 0.61208311 0.99215396 0.2 16.3005414 0.94876571
2.12542582979583 0.42008614 0.98406036 0.3 23.9288454 0.96946141
2.83169511533149 0.29427663 0.97415658 0.4 31.5571495 0.98015157
3.7055437404577 0.20991294 0.96213867 0.5 39.1854535 0.98667958
11.4312222048311 0.04734573 0.85916942 0.6 46.8137575 0.99108012
18.0397138140251 0.02423094 0.77236152 0.7 54.4420616 0.99424746
26.9625809520302 0.01248695 0.65567125 0.8 62.0703656 0.99663629
38.5184935140502 0.00616028 0.50494366 0.9 69.6986696 0.99850222
52.9769182638527 0.00259021 0.31667186 1 77.3269737 1
78.1268677254779 0 0
 ÉTER ISOPROPILICO-ISOPROPANOL

TEMPERATURA 70°c Tsat éter

PRESION 101 Kpa Tsat isopropanol

CONSTANTE DE ANTONIE
A B C
ÉTER 6.222 1257.6 230.01
ISOPROPANOL 7.24316 1580.92 219.62

Xi Yi T
0 0
0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
1 1
68.1635005 Psat éter 101
82.1491731 Psat isopropanol 101

PT 101
Y 0.35