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IEEE ANTENNAS AND WIRELESS PROPAGATION LETTERS, VOL.

15, 2016 1569

Fabrication and Characterization of Graphene


Antenna for Low-Cost and Environmentally
Friendly RFID Tags
Mitra Akbari, Student Member, IEEE, M. Waqas A. Khan, Student Member, IEEE,
Masoumeh Hasani, Student Member, IEEE, Toni Björninen, Member, IEEE, Lauri Sydänheimo, Member, IEEE,
and Leena Ukkonen, Member, IEEE

Abstract—We present the fabrication and testing of graphene-


based dipole antennas on cardboard, which is a promising
low-cost, recyclable, and flexible substrate for future wireless
electronics. The letter presents the details of the manufacturing,
as well as results from the measurements and simulations. The
measured sheet resistance of graphene antenna is 1.9 sq.
Overall, a graphene-based planar dipole antenna with the length
of 143 mm achieved the measured total efficiency of 40% and
the realized gain of 2.18 dBi at 889 MHz. Moreover, a passive
ultra-high-frequency radio-frequency tag based on a graphene
dipole antenna on cardboard achieved the attainable read range
of more than 5 m at 950 MHz.
Index Terms—Doctor-blading technique, graphene-based
antenna, radio frequency identification (RFID).

I. INTRODUCTION

P RINTABLE electronics are known as one of the emerging


methods for fabrication of the electronic devices. It has
wide applications in the radio frequency identification (RFID),
environmental sensors, and wearable electronics [1]. Printed
techniques and their integration with carbon nanomaterials,
especially graphene, open new horizons in the future electronic Fig. 1. (a) Schematic image of the doctor-blade technique, (b) dipole antenna,
and telecommunication technology [2]. Graphene is a 2-D and (c) RFID tag.
nanomaterial with outstanding properties such as high charge
mobility cm V s , zero band-gap, high thermal antenna performance is achieved through rolling compression
conduction Wm K , high mechanical strength method. In order to form a binder-free graphene laminate with
(130 GPa), high surface area m g , and excellent low resistivity, compression was used. In [5], a graphene-based
biocompatibility [3], [4]. Due to these remarkable properties dipole antenna is presented for RFID application, but maximum
of graphene, it has great potential to provide high conductive range for tag interrogation is 2.04 m.
inks, which can be integrated with the flexible and transparent In this letter, we present a simple, fast and easy way to fabri-
substrates to produce chemically stable, mechanically flexible, cate graphene-based antennas for RFID applications by doctor-
and low-cost RF products [1]. blading method on the cardboard. First we fabricated graphene-
Recent works [1] and [5] demonstrate graphene-based based dipole antenna and measured its RF properties ( , an-
antennas for RFID application. In [1], good printable RFID tenna realized gain, antenna efficiency, and radiation pattern).
After verifying the performance of dipole antenna, we fabri-
Manuscript received September 30, 2015; accepted October 28, 2015. Date cated the tag antenna based on [6] design (the selected design
of publication November 09, 2015; date of current version June 02, 2016. This has input impedance same as of used RFID IC input impedance).
work was supported by the Academy of Finland, the Jane and Aatos Erkko Moreover, we present the simulated and measured key property
Foundation, and the Finnish Funding Agency for Technology and Innovation.
The authors are with the Department of Electronics and Communications En- (theoretical read range) of the tag.
gineering, Tampere University of Technology, 33720 Tampere, Finland (e-mail:
mitra.akbari@tut.fi; muhammad.khan@tut.fi; Masoumeh.hasani@tut.fi; II. FABRICATION PROCESS
toni.bjorninen@tut.fi; lauri.sydanheimo@tut.fi; leena.ukkonen@tut.fi).
We used doctor-blading technique for antennas fabrication.
Color versions of one or more of the figures in this letter are available online
at http://ieeexplore.ieee.org. Doctor-blading technique is a one-step and simple way to de-
Digital Object Identifier 10.1109/LAWP.2015.2498944 posit graphene-based ink. In this method, a constant amount of

1536-1225 © 2015 IEEE. Personal use is permitted, but republication/redistribution requires IEEE permission.
See http://www.ieee.org/publications_standards/publications/rights/index.html for more information.
1570 IEEE ANTENNAS AND WIRELESS PROPAGATION LETTERS, VOL. 15, 2016

Fig. 2. (a) 3-D profile of section “A” as mentioned in Fig. 1(c), which shows the height of printed graphene from the cardboard. (b) 2-D surface image, shows the
thickness variation from the average thickness (zero represents the average thickness). (c) Cross section of doctor-bladed graphene ink on the cardboard.

TABLE I
FABRICATED SAMPLES PROPERTIES

ink is spread on the rigid or flexible substrates [see Fig. 1(a)].


The wet layer thickness is mainly adjusted by the size of gap be-
tween the blade and the substrate, and it depends on the printing Fig. 3. Measured [dB] of dipole antenna.
speed and flow behavior. Furthermore, blade specifications such
as shape, substance, and edge profile play an important role on
the fabrication process. The other effective operating param- The thickness of the printed samples was measured by Al-
eters on the film formation are surface temperatures, surface icona optical profilometer (a highly flexible optical 3-D mea-
energy of the substrate, surface tension, and viscosity of the surement system). According to Fig. 2(a), the thickness of the
ink [7]–[9]. coated graphene for RFID tag varies mostly between 30–60 m,
A high-viscosity graphene screen ink (Vor-ink X103) was although some peaks with 120 m thickness can be seen in
spread with a doctor blade across the mechanical mask on the Fig. 2(a), which is a result of ink agglomeration. The average
substrate. The printing speed and gap width between a blade thickness is 38 m for RFID tag antenna, and 42 m for dipole
and the substrate were adjusted to 14 mm/s and zero, respec- antenna. Furthermore, the printed surface has uneven structure,
tively. Hence, the final wet thickness is close to the mechanical which is probably a result of the porous surface of cardboard
mask’s thickness. Manually doctor-bladed samples were dried [see Fig. 2(b)]. According to the rough and relatively porous
for 4 min at . The fabrication process is schematically nature of cardboard, the ink penetrated approximately 30 m
shown in Fig. 1(a). into the cardboard [see Fig. 2(c)].
Fig. 1(b) and (c) shows the fabricated dipole antenna and
RFID tag. The cardboard has relative permittivity, loss tangent, III. RF MEASUREMENTS OF FABRICATED SAMPLES
and thickness of 1.8, 0.015, and 560 m, respectively [10]. A After fabrication, we measured the fabricated dipole and
dipole antenna is designed with 70 mm length of one arm with RFID tag antennas. For dipole antenna, we measured the ,
3 mm width. Gap between the arms is 3 mm. We followed the radiation pattern, realized gain, and efficiency. To check the
RFID tag antenna dimensions as explained in [6]. RFID antenna performance, we attached the NXP UCODE
In Table I, thickness ( ), sheet resistance ( ), conductivity G2iL series RFID IC with conductive epoxy.
( ), and resistivity ( ) of fabricated samples are mentioned. The Fig. 3 shows the measured values for dipole antenna.
4-point sheet resistance was measured by Thales software and has minimum values of 15.5 dB at 876 MHz. The an-
Zennium device equipped with a special head of four probes. tenna shows a broadband behavior. The antenna has 165 MHz
According to the head, there is a limitation to measure sheet re- (800–965 MHz) of 10 dB bandwidth. Fig. 4 shows the
sistance of narrow patterns like the dipole antenna. As a result, measured total efficiency and realized gain of the dipole an-
we are able to measure sheet resistance of the RFID tag antenna tenna. The antenna has a maximum 40% total efficiency and
only. However, manufacturing of both dipole and RFID tag an- 2.18 dBi realized gain at 889 MHz. Lower value of total
tennas is the same, so we can say that the dipole antenna has efficiencies for antennas is due to lower radiation efficiency (as
also the same sheet resistance as that of the RFID tag antenna. matching efficiency of antennas is reasonably good) because
AKBARI et al.: GRAPHENE ANTENNA FOR LOW-COST AND ENVIRONMENTALLY FRIENDLY RFID TAGS 1571

Fig. 6. Measured and simulated theoretical read range [m] of RFID tag.

Fig. 4. Measured total antenna efficiency [%] and realized gain of dipole
antenna.

Fig. 7. Measured E-plane and H-plane realized gain radiation pattern at


950 MHz of RFID tag antenna.

Fig. 5. Measured E-plane and H-plane realized gain radiation pattern at


876 MHz of dipole antenna. measured threshold power, which is the minimum transmitted
power from transmitting antenna required to activate the tag,
and is forward loss, which can be described as wireless
of low conductivity of graphene material. Fig. 5 shows the link loss between the carrier generator’s output port and input
measured E-plane and H-plane realized gain radiation patterns. port of the isotropic antenna when placed at the measured tag’s
Based on plot, radiation patterns are measured at 876 MHz. location. The forward loss is calculated during calibration of
Both plane radiation patterns are close to ideal dipole antenna measurement equipment using a reference tag before the mea-
radiation patterns. surement of the actual tag.
After attaching the RFID IC with tag antenna, we measured Fig. 6 shows the simulated and measured theoretical read
the theoretical read range of RFID tag in the UHF frequency range [m] of the RFID tag. Simulation is done based on mea-
range of 800–1000 MHz. Theoretical read range is the max- sured parameters (sheet resistance and thickness) in Table I.
imum distance between the reader antenna and tag in free space We did the simulation ANSYS HFSS ver. 15 by assigning
(without any reflection from external environment) through conductivity value to the conductor as presented in Table I.
which the tag IC can be activated. We used the RFID measure- The tag IC is modeled by using a resistor (2.85 k ) and a
ment system of [11], in which the query command response capacitor (0.19 pF) in parallel configuration, which results in
from the tag in the ISO 18000-6C communication standard an impedance of -j at 940 MHz [13]. Fig. 7 shows the
is monitored. The system is calibrated through the provided measured E-plane and H-plane realized gain radiation patterns
reference tag from the manufacturer. We swept the transmission of the RFID tag antenna at 950 MHz. Measured radiation
power and the transmission frequency of the carrier. After patterns are calculated from [13]
measuring the threshold power to make the tag response valid,
we calculated the theoretical read range [12]

(1) where is the minimum power required for the IC to ac-


tivate, which is 18 dBm. Simulated theoretical read range is
where is wavelength of transmitted carrier and is equiv- calculated based on [14]. The tag has more than 5 m of mea-
alent maximum isotropic radiated power. We have followed the sured theoretical read range, and the tag antenna has more than
European RFID emission regulation: W. is 7 dBi of realized gain. Tag dimensions are originally designed
1572 IEEE ANTENNAS AND WIRELESS PROPAGATION LETTERS, VOL. 15, 2016

for 940 MHz [6] on stretchable silver-coated fabric. According [3] M. Akbari, L. Sydanheimo, J. Juuti, J. Vuorinen, and L. Ukkonen,
to the measurement plot (Fig. 6), the tag has a constant read “Characterization of graphene-based inkjet printed samples on flexible
substrate for wireless sensing applications,” in Proc. IEEE RFID-TA,
range after 940 MHz, which may be due to the reason that this 2014, pp. 135–139.
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behavior). By tuning the feeding gap of the tag antenna, max- tion of graphene oxide,” J. Amer. Chem. Soc., vol. 133, no. 43, pp.
17315–17321, 2011.
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in Proc. IEEE MTT-S IMS, May 17–22, 2015, pp. 1–3.
[6] T. Björninen, J. Virkki, L. Sydänheimo, and L. Ukkonen, “Impact of
recurrent stretching on the performance of electro-textile UHF RFID
IV. CONCLUSION tags,” in Proc. Electron. Syst.-Integr. Technol. Conf., Helsinki, Finland,
Sep. 16–18, 2014, p. 5.
The proposed graphene tag on cardboard is cost-effective [7] A. Berni, M. Mennig, and H. Schmidt, “Dotor blade,” in Sol-Gel
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and eco-friendly with excellent processability. It has strong po- Springer, 2004, pp. 89–92.
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parcel transportation. The fabricated RFID tag has theoretical “Comparison of large scale coating techniques for organic and hybrid
films in polymer based solar cells,” Chem. Eng. Process. Process
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measured 2.18 dBi realized gain and 40% total efficiency. The [9] M. Hoesel, “Large-scale roll-to-roll fabrication of organic solar cells
performance of RFID can be further improved by tuning tag an- for energy production,” Ph.D. dissertation, Department of Chemistry,
Technical University of Denmark, Kgs. Lyngby, Denmark, Dec. 2013.
tenna parameters like input feed gap and length and width of tag [10] H. Saghlatoon, L. Sydanheimo, L. Ukkonen, and M. Tentzeris, “Opti-
antenna. Our future step is to optimize the tag antenna parame- mization of inkjet printing of patch antennas on low-cost fibrous sub-
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