Experimental Determination

H
Hans Science
Company
Solubility determination is achieved with
thorough difficulties. Difficulty in establishing that the

Solubility
system is in equilibrium at the chosen temperature is
one of the factors that greatly affects the experimental
determination of solubility. This is because both
precipitation and dissolution reactions may be slow.
The methods fall broadly into categories: static and
dynamic.
Static Methods
A mixture is brought to equilibrium and the
concentration of a species in the solution phase is
determined by chemical analysis. This requires
Equilibri
um
separation of the solid and solution phases.
Dynamic Methods

H
Science Company Submitted by: Hans Laurence
Sayson
Mail:
hanssciencecompany@gmail.commailto:jft
.company@gmail.com
FB: H Science Company
Address: Poblacion, Bien Unido, Bohol,
Philippines
Date of Publication: March 11, 2020
 Solubility Equilibrium Dissolution with Dissociation
Definition
A type of dynamic equilibrium that exists when a In dissolution with dissociation, ionic compounds
chemical compound in the solid state is in chemical normally dissociate into their constituent ions when
equilibrium with a solution of that compound. The they dissolve in water. Solubility products are often
solid may dissolve unchanged, with dissociation of expressed in logarithmic form. For hydroxides,
with chmical reaction with another constituent of the solubility products are often modified form using
solvents, such as acid or alkali. There are main types hydrogen ion concentration in place of hydroxide ion
of solubility equilibrium: (1) Simple dissolution, (2) concentration. Common-ion Effect is the effect of

Simple Dissolution Dissolution with Ionization

Simple dissolution is a dissolution of an organic
solid that can be described as an equilibrium between
the substance in its solid and dissolved forms. An
equilibrium expression can be written as:
In
Reaction
dissolution with ionization reaction is the
mosrt complex among the types wherein typical
reaction with dissolution involves a weak base,

Kº = Products dissolving in an acidic aqueous solution.

Reactants B(s) + (H+) (aq) = (BH+) (aq)
Where Kº is called the thermodynamic solubility This reaction is very important for
constant. When Kº is divided by y (activity coefficient), pharmaceutical products. Dissolution of weak acids in
the solubility constant Kѕ is obtained. The solubility
constant is a true constant only if the activity alkaline media is similarly important. For example,
coefficient is not affected by the presence of any other when a concentrated solution of ammonia is added to