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ABSTRACT INTRODUCTION
Capillary pressure can be viewed as the pressure Capillary pressure techniques have been available to
required to drive a fluid through a pore throat and dis- the petroleum industry for over forty years but have been
place the pore wetting fluid, with greater pressure being used primarily in petroleum engineering. With the search
required as the pore throat becomes smaller. The size and for petroleum becoming more difficult, a review of exist-
distribution of pore throats within a host rock control its ing methods can provide the exploration and develop-
capillary pressure characteristics, which in turn control ment geologist with tools to improve the odds.
fluid behavior in the pore system. Mercury-injection cap- Mercury injection-capillary pressure data are
illary pressure curves, which measure capillarity, are obtained by injecting mercury into sample plugs to pro-
obtained by injecting mercury into sample plugs to pro- duce a plot of injection pressure vs. mercury saturation.
duce a plot of injection pressure vs. mercury saturation. The resulting capillary pressure curves are valuable aids
The resulting capillary pressure curves can provide quali- for exploration and development. In exploration pro-
tative assessments of reservoir rock using such calculated grams the data can be used to upgrade prospects or define
values as pore-throat sorting, reservoir grade, and oil areas for further exploratory efforts. Regional studies
columns required to obtain 50 and 15% oil saturations. can be constructed in much the same fashion as strati-
Regional capillary pressure maps of these calculated val- graphic studies and can be integrated into geological,
ues identify a north-south trend of favorable reservoir geophysical, and engineering programs. For field devel-
rock along the state line between Montana and North opment, capillary pressure data can be used to locate eco-
Dakota in the third porosity ("C") zone of the Ordovi- nomic oil-water contacts, calculate oil columns, or
cian Red River Formation. Oil migration and trapping determine if reservoir tilting is a function of hydrody-
can be significantly controlled by capillary pressure. At namics, capillary pressure, or both. Stratigraphic traps
Bell Creek field, in southeastern Montana, multiple oil- are significantly influenced by capillary pressure and
water contacts in Cretaceous Muddy Sandstone barrier understanding the concept of a capillary pressure release
sands can be explained vrith the concept of a capillary valve can help exploit these types of traps. With the
pressure release valve. Semi-permeable siltstones can increasing interest in enhanced recovery programs,
only trap finite columns with the excess oil being released capillary-pressure-derived relative permeabilities can
updip to migrate into other reservoir quality sand bodies. provide an inexpensive yet valuable source of data.
Oil columns can be estimated from capillary pressure If we understand how capillary pressure works within
data by determining the buoyancy force of the oil float- a reservoir or how it affects migration and entrapment,
ing on water and then converting from a mercury-air cap- we can learn and apply new information in our search for
illary system to an oil-water capillary system. Relative petroleum deposits. Capillary pressure data are neither
permeability data may also be calculated from capillary difficult nor prohibitively expensive to obtain and can
pressure data and can be used to estimate fractional yield answers that cannot be obtained in any other way.
water production at given water saturations. Tilted oil-
water contacts can result from hydrodynamics, capillary
pressure, or both, and capillary pressure data can help OBTAINING AND DISPLAYING
determine the type of tilting present. By understanding CAPILLARY PRESSURE DATA
capillarity, we can obtain better insight on the nature of
reservoir rock, oil accumulations, and permeability rela- Capillary pressure data are obtained by injecting mer-
tionships. cury, at increasing pressure levels, into sample plugs. The
plugs, normally the same ones used in routine core analy-
sis, are approximately 1 in. in diameter and 1 Vi in. long.
After a plug is thoroughly cleaned, its porosity is mea-
©Copyright 1987. The American Association of Petroleum Geologists. All
sured and it is placed within the sample chamber of the
rights reserved. capillary pressure apparatus (Figure 1). A strong vacuum
^ Manuscript received, April 27,1937; accepted, August 5,1987. reduces the pressure toward 0 atm, and the chamber is
^Consulting Geologist, 21S6 South Field Street, Lakewood, Colorado
80227. filled with mercury up to an index mark located in an
My thanks to B-1 Industries, Inc.; Core Analysis of Casper, Wyoming; and observation port immediately above the chamber. A
Cap-Strat, Inc., of Denver, Colorado; for contributing much of the data used in
this paper. A special thanks to Ken Bowen, President of B-1 industries, and
micrometer hand wheel, controlling the mercury reser-
Wes Bowen, President of Cap-Stral, Inc., for making this project possible. voir, is set to zero; pressure is then applied to the system.
1196
Jeffrey B. Jennings 1197
irreducible Saturation, %
Pressure gauge 0 20 40 60 80 100
2000 0.05
K Irreducible
Saturation, S^\
1000 0.10
High-pressure hose
Vacuum gauge
To
-=* vacuum
pump
3
(A
Supply (A
pressure a>
Sample Chamber a
(internal view) 100
containing rock sample _^ Observation
windows
Handwheel
micrometer
idial l\4etering Mercury
plunger 1 reservoir
Measuring
screw
used on well cuttings or chips, but they tend to provide OIL COLUMN
inaccurate results due to the large surface-area to volume
ratio. Percussion sidewall plugs can sometimes be used,
but often contain induced fractures that produce errone-
ous capillary pressure measurements. Sidewall plugs,
Top of Trap
n 80%
L
100% water level, it is not 100% water saturated. Oil sat-
urations are commonly in the range of 5 to 10%, with sig-
nificantly higher saturations possible. A better term for \
this point might be the displacement or threshold pres-
sure level.
The free-water level is typically the point of zero capil- 20% 20% 20%
lary pressure with oil globules moving freely within large,
open pores. The interval between the free-water level and 0.5md lOmd 350 md
the 100% water level (displacement pressure level) is fur-
ther defined as being 100% water saturated and is not
considered to be part of the oil column. I disagree with PORE-THROAT SORTING
this definition and prefer to place the base of the oil
column at the free-water level. The interval between the 1.2 4.2 1.2
100% water level and the free-water level then defines the
height an oil globule must reach before vertical migration
can occur. In the absence of a trap, the globule will RESERVOIR GRADE
migrate without producing significant oil saturations.
When a trap does exist, the displacement pressure can be 28 21 5
exceeded and significant oil saturations may start to
form. OIL COLUMN 50% SATURATION
A great deal of confusion can exist when the term "oil-
water contact" is used. The most common usage refers to 170ft 60ft 6ft
either the economic oil-water contact or the productive
oil-water contact, as these two points can be determined
from log analysis or drill-stem tests. For applying capil- OIL COLUMN 75% SATURATION
lary pressure data, the free-water level represents the only
oil-water contact that is not rock dependent and thus 210ft 130ft 8ft
identifies the absolute bottom of the oil column.
Canada Canada
Dakota
0 30 Ordovician Red River Ordovician Red River
i_ _i Pore-Throat Sorting Reservoir Grade
miles miles
C.l. = 0.25units C.I. = 10 units
Figure 6—Contour map of pore-throat sorting from third Figure 7—Contour map of reservoir grade from third porosity
porosity ("C") zone of the Ordovician Red River Formation. A ("C") Zone of the Ordovician Red River Formation. A fairway
fairway of favorable reservoir rock lies inside the 1.50 units of favorable reservoir rock lies Inside the 20 units contour.
contour.
erwise, oil columns could be calculated to reflect a more an 80% dolomite content, dolomitization becomes
appropriate oil saturation. The contours on the map thus destructive, reducing porosity and permeability. By cor-
represent the minimum oil columns or trap closures relating capillary pressure data with stratigraphy, we can
required before marginal oil production can be expected. measure the effects of dolomitization and identify a fair-
The oil column required for a 75% oil saturation (Fig- way exhibiting the best reservoir potential. Note that a
ure 9) provides an estimate of the minimum trap closure number of dry holes are present within the favorable fair-
(structural or stratigraphic) required to obtain a 75% oil way trend. The quality of the rock in these wells was
saturation. The same oil column cutoffs for good, fair, good, but unfortunately either a trap was not present or
and marginal rock were used as in the 50% oil saturation petroleum never migrated into these areas.
map. A 75% oil saturation represents the level of satura- Other than identifying an area possessing favorable
tion that should yield good economic recoveries of oil. reservoir rock, what other capillary pressure applications
The contoured fairways are narrower than in the 50% oil are available to the explorationist? Geophysical pros-
saturation map because of the higher minimum oil satu- pecting is popular in the WiUiston basin, and a direct
ration, which reflects the higher reservoir quality of the application of oil column heights can be used. If a partic-
rock. ular area of interest requires a minimum of 100 ft (30.4
The data delineate a north-south-trending fairway; m) of trap closure to obtain a 50% oil saturation, then the
when compared to a lithology map by Foster (1972), res- seismic data need only be tuned to detect structures of
ervoir quality appears to be associated with dolomitiza- this magnitude. This tuning can eliminate costly repro-
tion. The best reservoir rock possesses a dolomite content cessing and can provide constraints for analyzing seismic
ranging from 40 to 80%. This range may be evidence for data or when acquiring new data.
enhanced porosity and permeability as a function of opti- Ranking prospects is valuable. The explorationist
mum dolomitization. Dolomite within the Red River commonly generates a number of prospects of which
Formation is a result of secondary processes (Foster, only a few can be drilled. Regional capillary pressure
1972), and workers have long recognized that primary maps can be used to help select the best prospects for first
limestone porosity and permeability can be enhanced by consideration. Other uses might be in developing more
dolomitization (Levorsen, 1954, p. 126-128). Evidence accurate effective porosity maps or, in the case of strati-
from capillary pressure data would also infer that beyond graphic traps, mapping displacement pressure oil
1202 Capillary Pressure Techniques
Canada Canada
\ N. Dakota N. Dakota
Ordovician Red River Ordovician Red River
Oil Column Oil Colunr\n
for for
50% Oil Saturation 75% Oil Saturation
C.I. = 5 0 ' C.I. = 50"
Figure 8—Contour map of oil columnrequiredfor a SOVo oii Figure 9—Contour map of oil column required for a 75% oU
saturation in third porosity ("C") Zone of the Ordovician Red saturation in the third porosity ("C") Zone of the Ordovician
River Formation. A fairway of favorable reservoir rock lies Red River Formation. A fairway of favorahlereservoirrock
inside the 100-ft contour. lies inside the 100-ft contour.
columns to determine the downdip limit of oil accumula- in the trapping rock builds up oil saturation in the down-
tions. dip reservoir rock. If the resulting oil column is large
enough, an economic oil accumulation can occur. A pos-
sible model for this type of trapping is Bell Creek oil field
in southeastern Montana.
OIL MIGRATION AND ENTRAPMENT AT
BELL CREEK OIL FIELD Berg et al (1985) describe the trapping mechanism at
Bell Creek as being controlled by both hydrodynamic
flow and capillary pressure with hydrodynamics provid-
Oil migration and entrapment can be controlled by the ing the largest contribution. Of the 500 ft (152.4 m) of
capillary pressure characteristics of the conduit and seal- total oil column, 429 ft (130.7 m) could be accounted for
ing rocks. For purposes of applying capillary pressure from hydrodynamic flow and 71 ft (21.6 m) from capil-
techniques, oil is viewed as migrating in the form of glob- lary pressure trapping. They further state that long-range
ules. As oil is generated from a source rock, it accumu- migration was needed to provide oil for Bell Creek and
lates as small globules. These globules coalesce and that this was most easily accomplished under hydrostatic
enlarge until enough buoyancy force is developed to initi- conditions. Oil entrapment was then timed with the start
ate migration. The process is analogous to filling a sub- of hydrodynamic flow in the late Pliocene when the Cre-
merged balloon with air. The larger the balloon becomes, taceous Muddy Sandstone was uplifted and exposed
the greater is its upward force. The size that a globule along the western and southwestern flanks of the Black
must obtain before migrating (expressed in terms of feet Hills. Although hydrodynamics provides a plausible
of vertical oil column) is controlled by the displacement trapping mechanism, data I have collected suggest an
pressure of the rock in conjunction with the density dif- alternative explanation using capillary pressure as the
ferential between the oil and formation water. When the major trapping mechanism at Bell Creek.
displacement pressure oil column is obtained, the globule Oil migration and entrapment as a function of capil-
will migrate until it encounters a trap or loses enough oil lary pressure can explain pure stratigraphic trapping
along the way to reduce its buoyancy force below the dis- involving updip permeability pinch-outs. The degree of
placement pressure. In stratigraphic traps involving per- permeability reduction does not have to be significant,
meability pinch-outs, the capillary displacement pressure for even reservoir quality sands may form effective barri-
Jeffrey B. Jennings 1203
R53E R54E
Valve
Lagoon
Facies
Cross Section A A'
Capillary Pressure Curves Bell Creek Field
Powder River Co., Montana
CALCULATING HEIGHT OF AN OIL COLUMN facial tension of oil to water (dynes/cm), and d^/^ =
ABOVE FREE-WATER LEVEL contact angle of oil to water.
All of the variables except the interfacial tension of oil
One of the more useful applications of capillary pres- to water are known, and an accurate measurement of
sure data is to calculate the height of an oil column for interfacial tension is critical to calculating an oil column
any given oil saturation above the free-water level. This is height. A disparity in values seems to exist in the litera-
accomplished by first using a number of nomographs to ture, giving the impression of a large degree of inaccu-
find the density gradients of the formation water and oil. racy or disagreement. Published values by Livingston
The difference in these density gradients defines a buoy- (1938), Hocott (1939), and Hjelmeland and Larrondo
ancy force that constitutes the driving mechanism for oil (1986) provide a range of 13 to 36 dynes/cm. Schowalter
to migrate into the reservoir rock. The second element (1979) suggests that oil-water interfacial tensions should
needed is the injection pressure from a capillary pressure be measured, but if such data are not available, 21 dynes/
curve at a given mercury saturation (i.e., oil saturation). cm (average value for 34 Texas oil reservoirs as measured
Calculating the oil column is then a process of converting by Livingston, 1938) can be used with the values adjusted
the injection pressure value from a mercury-air system to downward with increasing pressure and temperature.
an oil-water system and dividing this number by the pre- Berg (1975) applied values in the 30 to 35 dynes/cm range
viously calculated buoyancy force. The resulting number for medium-gravity oils. Both Hocott (1939), with oils
represents the feet of vertical oil column needed to from three Texas fields, and Hjelmeland and Larrondo
achieve the oil saturation. Following is a simplified equa- (1986), using oils from an Alberta, Canada, limestone
tion, modified from D. A. Smith (1966), for calculating reservoir, were in agreement, with average values ranging
feet of oil column above the free-water level: from 25 to 33 dynes/cm. They raised the possibility of
experimental errors caused by a skin forming on the oil
surface during lab measurements. This skin effect appar-
H = ently increases with time and substantially reduces the
(W„ - W„) (CF) measured interfacial tension by as much as 50%, depend-
ing upon pressure, temperature, and the presence of aer-
where H = height of oil column (ft), P^ = capillary pres- obic conditions. Furthermore, Hjelmeland and
sure (psi) at a given mercury saturation, W„ = density Larrondo (1986) measured about an 8 dynes/cm increase
gradient of the formation water (psi/ft), W^ = density in the interfacial tension of stock-tank oils as compared
gradient of the oil (psi/ft), and CF = conversion factor to live reservoir oils.
needed to convert from a mercury-air system to an oil- To resolve the conflict of which interfacial tension val-
water system. ue(s) to use, capillary pressure data were acquired from
Densities for oil and formation water are easily calcu- established fields with well-defined oil columns. With
lated by knowing the water salinity, API gravity, gas-oil this data, estimates of interfacial tension could be made
ratio, formation pressure, and formation temperature. A by solving CF for the interfacial tension of oil to water
number of nomographs diagramed by Schowalter (1979) (T„, J . This technique was applied to fields in the Willis-
can be used to calculate the respective densities in psi/ft. ton and Powder River basins and in a variety of forma-
These values are then substituted into the equation along tions comprised of the Ordovician Red River,
with the applicable conversion factor to calculate the oil Mississippian Madison, Permian-Pennsylvanian Minne-
column. lusa, and Cretaceous Muddy. Depths ranged from 3,500
The conversion factor (CF) is determined from an to 10,000 ft (1,066.8 to 3,048.0 m), with corresponding
interfacial tension of mercury to air of 480 dynes/cm and increases in temperature and pressure. The resulting cal-
a contact angle of 40°. For a water-wet reservoir, the culations yielded a range of interfacial tension values
interfacial tension of oil to water is variable but the con- from 26 to 30 dynes/cm, giving an average of 28 dynes/
tact angle is assumed to be 0°. Calculating an oil column cm. This correlates to a CF of approximately 13, with an
with this technique infers the wetting fluid will always be expected error of ± 10% for the calculated oil columns.
water. Although oil-wet reservoirs exist, these reservoirs These data indicate a stable range of variability in line
were probably water wet at the time of entrapment and with the lab results obtained by Hocott (1939) and
the oil columns should have stabilized before the oil Hjelmeland and Larrondo (1986).
became the wetting agent. In addition, oil column calcu- Ideally, to obtain the most accurate oil column calcula-
lations are only best estimates due to the complex nature tions, interfacial tension should be measured for each oil-
of oil reservoirs and uncertainties in the true interfacial water system being investigated. Unfortunately this type
tensions and contact angles of oil-water systems. The fol- of data can be difficult to acquire and great care must be
lowing equation, from Purcell (1949), is used to calculate exercised to arrive at usable numbers reflecting the true
the conversion factor: interfacial tension. Hjelmeland and Larrondo (1986)
suggest that live reservoir oils and the oil-drop method be
(THJ (COS <?HJ _ (480) (0.766)
used to obtain the most accurate data. In place of lab
CF measurements, acceptable interfacial tension numbers
(T„,„ (cos e^,J (T„/J(1.0)
are available by applying capillary pressure data to
known fields. When measured data are not available, an
where THJ = interfacial tension of mercury to air (dynes/ interfacial tension of 28 dynes/cm should yield reason-
cm), ^Hg = contact angle of mercury to air, T„/„ = inter- able oil column calculations.
Jeffrey B. Jennings 1205
1
J function = ^ vST^ = ^ V ^ , F„ =
1 + (K„/K J (U„/U„)
(T„,) (cos e„,) "^368
where P,, = capillary pressure (psi),THg = interfacial ten- where F^ = the fractional water production at a given
sion of mercury (dynes/cm), Cos ^Hg = contact angle of water saturation, K^, = relative permeability of the oil,
mercury, K = measured permeability (millidarcys), and 4> K„ = relative permeability of the water, U„ = viscosity
= measured porosity (%). of the formation water, and Uo = viscosity of the oil at
Obviously, calculating relative permeability data by reservoir conditions.
hand can be laborious but the equations can be pro-
grammed into a computer to turn out printed data within
a few minutes (Ikble 1). The relative permeability calcu- CAPILLARY-PRESSURE-TILTED
lations detailed in this paper were for the oil and water OII^WATER CONTACTS
phases but the gas phase can be determined in a similar
manner. Equations for the gas phase and oil and water Tilted oil-water contacts are often found in petroleum
phases are discussed by Fatt and Dykstra (1951), Burdine reservoirs and are usually attributed to hydrodynamic
(1953), Corey et al (1956), Amyx et al (1960, p. 195-199), flow of formation fluids. Another form of tilting can be
C. R. Smith (1966), Land (1968), and Standing (1974). created by capillary pressure effects. Arps (1964) dis-
The value of relative permeability curves to geologic cussed the possibility of tihed oil-water contacts as the
applications may, at first, seem to be limited, but these result of lateral changes in porosity and permeability
Jeffrey B. Jennings 1207
SUMMARY