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June 2010
GCE
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Summer 2010
Publications Code US023632
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© Edexcel Ltd 2010
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Section A (multiple choice)
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Question Correct Answer Mark
Number
12 A 1
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Section B
Just “not
accurate”
“Titration 1 is
a control
experiment”
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IN (d)(i) to (d)(v), IGNORE UNITS EVEN IF INCORRECT AND
ALLOW ANSWER IN EACH CASE WHETHER BY TE OR MARK SCHEME ANSWER, REGARDLESS OF
ANY WORKING SHOWN
Question Acceptable Answers Reject Mark
Number
OR
OR
OR
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Question Acceptable Answers Reject Mark
Number
OR
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Question Acceptable Answers Reject Mark
Number
Improvement: Use of
Use a pipette / burette to measure acid volumetric
(solution) (1) flask for initial
measurement
of volume of
vinegar
solution
Reason:
Pipette / burette more accurate (than a “more
measuring cylinder) (1) reliable”
OR
Improvement: swirl (the
Shake / invert the volumetric flask flask)
(thoroughly) (1)
Reason:
To ensure a uniform concentration (1) to ensure
“fully
dissolved”
OR
Improvement:
Rinse out measuring cylinder (and transfer just “rinse out
washings to the volumetric flask) (1) apparatus”
Reason:
To ensure all the acid is transferred (to the
volumetric flask) (1)
OR
Improvement:
Use a (teat) pipette to make up to the mark (in
volumetric flask) (1)
Reason:
To ensure volume of solution accurately Any suggested
measured (1) improvements
relating to the
titration part
of this
experiment
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Question Acceptable Answers Reject Mark
Number
• overshoots/misses end-point
• water left in burette / pipette “water left in
• air lock below tap in burette / air in conical flask”
pipette
• burette not vertical just
• alkali not at stated concentration “measurements
• leaking tap may be
• not reading meniscus at eye-level inaccurate”
• funnel left in top of burette
“there could be
• not reading level against a white
uncertainty
background
with other
• not reading meniscus correctly equipment”
• washing pipette between titres
• washing the flask with the solution that “contamination
will go in it of the vinegar”
• not swirling flask / mixture
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Question Acceptable Answers Mark
Number
H3C H
20 (a)(i) H3C H 3
H C C H
H C C H
H (1) for carbocation
H
(1) for arrow
Br (:) Br
H3C H
H C C H
Br H
1st mark:
• top arrow must start from the double bond / close to the
double bond and not from either of the C atoms of the
C=C bond
• top arrow can end on, or close to, the H in HBr
• lower arrow must start from the bond and not the H
atom in HBr
REJECT full charges on the HBr
2nd mark:
the carbocation must have a full + and not ∂+
3rd mark:
• the bromide ion must have a full — and not ∂—
•
the lone pair need not be shown on the Br—
• arrow from bromide ion can start anywhere on the Br–— or
from the minus sign or the lone pair (if shown) on Br— and
can go to the C or the + sign on the intermediate
20(a)(ii) H3C H 1
H C C H
OR
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Question Acceptable Answers Reject Mark
Number
20(b)(iii) BOTH 1
B / CH3CH2CH(OH)CH3 / butan-2-ol
AND
H H O H
Structural /
H C C C C H skeletal
formula
H H H
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Question Acceptable Answers Reject Mark
Number
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Question Acceptable Answers Reject Mark
Number
Reason:
Exothermic (in forward direction) (1)
Second mark:
(cooling the gases would make) the rate (too)
slow /rate is faster if the temperature is high Cooling the
(so the gases are not cooled) gases
(1) decreases the
yield (of
products) /an
incorrect Le
Chatelier
argument
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Question Acceptable Answers Reject Mark
Number
Reason:
Shifts / moves in the direction of fewer (moles “.... fewer
of gas) molecules atoms”
NOTE:
ACCEPT multiples
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Question Acceptable Answers Reject Mark
Number
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SECTION C
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Question Acceptable Answers Reject Mark
Number
ALLOW
“To enable the mixture to dissolve”
(0) if
contradictory
observation
given, eg
“cream
precipitate
and fizzing”
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Question Acceptable Answers Reject Mark
Number
Structural formula:
CH3CH2OH or C2H5OH (1) C2H6O
Allow displayed formula
ALLOW brackets around the OH
2nd mark:
Shape of profile with one ‘hump’ (1)
3rd mark:
Activation energy / “Ea” correctly shown with a Double-
single-headed arrow to the peak (or close to headed arrow
it) (1) showing Ea
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Question Acceptable Answers Reject Mark
Number
22(c)(i) Chlorofluorocarbon 1
air-
conditioning
frying pans
detergents
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Question Acceptable Answers Reject Mark
Number
OR
2O3 → 3O2
2nd mark:
(chlorine free radical acts as a) catalyst (1)
Last 3 marks:
any three from:
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Question Acceptable Answers Reject Mark
Number
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Order Code US023632 Summer 2010
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