Solubility-Of Acid Gases in TEG-Solution

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Solubility of Acid Gases in TEG Solution

In gas dehydration service, triethylene glycol (TEG) will absorb limited quantities of BTEX (benz
ethylbenzene, and xylene) and acid gases such as carbon dioxide (CO2) and hydrogen sulfide (
gas. Predicted absorption levels for acid gases can be as high as about 10 SCF/gallon (75 SCM
solution and depends on temperature, pressure, acid gas concentration in the vapor phase and
concentration. Figure 18.16 in reference [1] shows the solubility of H2S in TEG at various H2S p
pressures. This is true absorption that takes place in the absorber and corresponds to typical ac
data. Figure 18.17 also in reference [1] shows solubility of CO2 in a 96.5 weight percent TEG so
2 absorption of acid gases increases with TEG purity. The solution of acid gases in TEG solution
and enhances corrosion. In addition, one of the main issues is dealing with the H2S that comes
regenerator. This is a problem if vented (bad smell & poisonous) and can be a significant source
(SO2) if burned.
In the June 2011 tip of the month (TOTM), we presented diagrams for quick estimation of absorption of BTE
dehydration systems using the experimental vapor-liquid equilibrium data. The objective of this TOTM is to r
similar diagrams covering wide ranges of operating conditions. First we demonstrate the accuracy of a rece
proposed by Mamrosh et al. [2] against Gas Processors Association experimental data and then reproduce
recommended diagrams for approximate and quick estimation of acid gas absorption in TEG solution.
Mamrosh-Fisher-Matthews Solubility Model:
Recently, Mamrosh et al. [2] presented the following correlation based on the experimental data to estimate
CO2 and H2S in TEG solution.
The values of the A, B, C, D, and E parameters are given in Table 1. For details of the calculation procedure
calculation refer to reference [2].
Accuracy of Mamrosh-Fisher-Matthews Solubility Model:
The accuracy of the Mamrosh et al. [2] model was evaluated against the experimental data of Gas Processo
Research Reports RR 183 [3] and RR 189 [4] for CO2 and H2S solubility in TEG solution, respectively. The s
our evaluation results is shown in Table 2.
http://www.jmcampbell.com/tip-of-the-month/2012/06/solubility-of-acid-gases-in-teg... 22.04.2014
It should be noted that for three cases of experimental data of H2S in TEG/H2O system, the absolute percen
were abnormally high (128, 260, and 319 %); therefore, they were eliminated from our analysis. Considering
analysis shown in Table 2, the proposed model by Mamrosh et al. [2] has good accuracy for estimating solu
gases in TEG/H2O solution. All experimental data reported in GPA RR 183 and RR 189 were collected at eq
consideration in the proposed model is given to the rate at which processes reach equilibrium.
Figures 1 and 2 present a graphical comparison of the calculated CO2 and H2S solubility (mole fraction of ac
liquid phase) with the experimental data of GPA RR 183 and GPA RR 189 for CO2 and H2S, respectively. O
accuracy is observed for both systems in these two figures. The ranges of data are the same as those show
Figure 1. Accuracy of the proposed model by Mamrosh et al. [2] for estimating CO2 solubility in TEG solutio
RR 183 experimental data [3]
Figure 2. Accuracy of the proposed model by Mamrosh et al. [2] for estimating H2S solubility in TEG solutio
RR 189 experimental data [4]
In Figures 3 through and 8 we have reproduced the CO2 and H2S solubility (on volumetric basis of SCF/gall
solution or SCM/m3 of TEG solution) for pressures of 1000 and 500 (6897 and 3448 kPa) representing conta
and 50 psia (345 kPa) representing the flash separator in a typical TEG dehydration unit. In each of these d
solubility is presented as a function of temperature, acid gas mole % in the gas phase, and H2O weight % in
based on the model proposed by Mamrosh et al. [2]. These figures are reproduced in the field or Engineerin
SI (International) systems of units. They can be quickly used to estimate acid gas absorption by TEG solutio
Figures A1 through A6 in Appendix A present solubility of acid gases in terms mole fraction instead of volum
Conclusions:
We have performed an independent evaluation of a recently developed model by Mamrosh et al. [2] for estim
gas absorption by TEG solution while dehydrating natural gas. Our evaluation was based on the experimen
data reported in the GPA RR 183 [3] and GPA RR 189 [4]. All experimental data reported in GPA RR 183 a
were collected at equilibrium. No consideration in the proposed model is given to the rate at which processe
equilibrium.
The analysis of Figures 1 and 2 and Table 2 indicates, that even though the Mamrosh et al. [2] model is sim
to use, it is relatively accurate for estimation purposes. It also covers a wide range of operating conditions. B
model we have reproduced Figures 3 through 8 in the field and SI systems of units that can be used to estim
absorption of CO2 and H2S in TEG solution during gas dehydration. The analysis of Figures 3 through 8 also
at the same conditions, the solubility of H2S is almost 5 times greater than that of CO2. In addition, it can be
the absorption of acid gases increase as:
• Pressure increases
• Temperature decreases
• Acid gas concentration in gas phase increases
• TEG concentration in liquid phase increases
• TEG solution circulation rate increases
To learn more about similar cases and how to minimize operational problems, we suggest attending our G4
(Process/Facility Fundamentals), G4 (Gas Conditioning and Processing), PF81 (CO2 Surface Facilitie
(Oil Production and Processing Facilities) courses.
John M. Campbell Consulting (JMCC) offers consulting expertise on this subject and many others. For more
about the services JMCC provides, visit our website at www.jmcampbellconsulting.com, or email your co
to consulting@jmcampbell.com.
By: Dr. Mahmood Moshfeghian
Figure 3 (FPS). Estimated solubility CO2 in TEG solution at 1000 psia as a function of temperature, CO2 m
phase and water weight %
Figure 3 (SI). Estimated solubility CO2 in TEG solution at 6897 kPa as a function of temperature, CO2 mo
Figure 4 (FPS). Estimated solubility H2S in TEG solution at 1000 psia as a function of temperature, H2S mo
Figure 4 (SI). Estimated solubility H2S in TEG solution at 6897 kPa as a function of temperature, H2S mol
Figure 5 (FPS). Estimated solubility CO2 in TEG solution at 500 psia as a function of temperature, CO2 mo
Figure 5 (SI). Estimated solubility CO2 in TEG solution at 3448 kPa psia as a function of temperature, CO
vapor phase and water weight %
Figure 6 (FPS). Estimated solubility H2S in TEG solution at 500 psia as a function of temperature, H2S mo
Figure 6 (SI). Estimated solubility H2S in TEG solution at 3448 kPa as a function of temperature, H2S mol
Figure 7 (FPS). Estimated solubility CO2 in TEG solution at 50 psia as a function of temperature, CO2 mo
Figure 7 (SI). Estimated solubility CO2 in TEG solution at 345 kPa psia as a function of temperature, CO2 m
Figure 8 (FPS). Estimated solubility H2S in TEG solution at 50 psia as a function of temperature, H2S mol
Figure 8 (SI). Estimated solubility H2S in TEG solution at 345 kPa as a function of temperature, H2S mole
Reference:
1. Campbell, J. M. “Gas conditioning and processing, Volume 2: The Equipment Modules,” John M. Ca
Company, Norman, Oklahoma, USA, 2001.
2. Mamrosh, D., Fisher, K. and J. Matthews, “Preparing solubility data for use by the gas processing in
Updating Key Resources,” Presented at 91st Gas Processors Association National Convention, New
Louisiana, USA, April 15-18, 2012.
3. Davis, P.M., et al.; “The Impact of Sulfur Species on Glycol Dehydration – A Study of the Solubility o
Gases and Gas Mixtures in Glycol Solutions at Elevated Pressures and Temperatures, Revised RR
Phase I: CO2/CH4/EG/TEG;” GPA Research Report, RR-183; Gas Processors Association., Tulsa O
USA, 2002.
4. Marriott, R.A., et al.; “The impact of Sulfur Species on Glycol Dehydration – A Study of the Solubility
Gases and Gas Mixtures in Glycol Solutions at Elevated Pressures and Temperatures, VLE Data for
H2S/CH4/EG/H2O System and the H2S/CH4/TEG/H2O System,” GPA Research Report, RR-189; Ga
Association., Tulsa Oklahoma, USA, 2005.
Appendix A
Additional solubility Diagrams
Figure A1. Estimated solubility CO2 in TEG solution at 1000 psia [6897 kPa] as a function of temperature, C
Figure A2. Estimated solubility H2S in TEG solution at 1000 psia [6897 kPa] as a function of temperature, H
Figure A3. Estimated solubility CO2 in TEG solution at 500 psia [3448 kPa] as a function of temperature, C
Figure A4. Estimated solubility H2S in TEG solution at 500 psia [3448 kPa] as a function of temperature, H
Figure A5. Estimated solubility CO2 in TEG solution at 50 psia [345 kPa] as a function of temperature, CO
Figure A6. Estimated solubility H2S in TEG solution at 50 psia [345 kPa] as a function of temperature, H2
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Posted on June 1, 2012 at 12:04 pm
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Written by Dr. Mahmood Moshfeghian
Dr. Mahmood Moshfeghian is an instructor and consultant with John M Campbell and Company (JMC). He
most of Campbell Tips of the Month and develops technical software for JMC. He has 35 years teaching exp
universities (Oklahoma State University, University of Shiraz, University of Sydney and University of Qatar)
oil and gas industries. Dr. Moshfeghian joined JMC in 1990 as a part time consultant and then as full time
instructor/consultant in 2005. Previous to joining JMC, Dr. Moshfeghian was a Senior Research Scientist at
Institute for Scientific Research and Professor of Chemical Engineering at Shiraz University. Dr. Moshfeghia
member of AIChE and has published numerous technical papers on thermodynamic properties, and Proces
Dr. Moshfeghian has presented invited papers in international conferences. He holds a B.S., an M.S. and a
Chemical Engineering, all from Oklahoma State University.
View all posts by: Dr. Mahmood Moshfeghian
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5 Responses to “Solubility of Acid Gases in TEG Solution”

1. Abdelrahman says:
June 3, 2012 at 10:37 am
very good study , thanks very much , however i think there is a typo error in the conclusion as follow
As per the presented graphs we can conclude that the absorption of acid gases increase as tempera
not increase, please verify and correct this typo error in the conclusion part of this study if needed
again thanks alot for TOTM we are really so interested on it
Reply
2. admin says:
June 4, 2012 at 2:18 pm
Thanks for your comment, Abdelrahman. This typo has been corrected.
Reply
3. Charanjit Jootla says:
June 10, 2012 at 2:56 am
Very informative and comphrensive. Do we have similar figures for low pressures at the Regenerato
the pressure is close to atmospheric and the temperature is around 370 deg F ?
This is to determine how much of H2S / CO2 will be in the lean TEG solution AFTER Regenerator st
how much of H2S / CO2 is “unavoidable” in the lean TEG solution.
Also, solubility data at the Regenerator conditions will help in doing a rough mass balance of the H2S
which comes out with the rich TEG, how much leaves via the Flash Drum / Regenerator and how mu
“recycled” back to the Contactor via the lean TEG stream.
Reply
4. vamsi.krishnaprasad says:
June 15, 2012 at 1:55 am
good one
Reply
5. R Hussain says:
June 25, 2012 at 1:02 am
Very informative article, thanks. – R Hussain
Reply
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Solubility of Acid Gases in TEG Solution | Campbell Tip of the Month Seite 1 von 14

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Solubility of Acid Gases in TEG Solution

Mamrosh-Fisher-Matthews Solubility Model:

Accuracy of Mamrosh-Fisher-Matthews Solubility Model:

By: Dr. Mahmood Moshfeghian

Did you enjoy this post? Do you have a question?

Posted on June 1, 2012 at 12:04 pm

Categories: Gas Processing, Process Facilities

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Written by Dr. Mahmood Moshfeghian

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5 Responses to “Solubility of Acid Gases in TEG Solution”

Very informative article, thanks. – R Hussain

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