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Extrusion Defects

Fundamentals & Solutions


for Optimum Finish
Columbus, Ohio – May 16-17, 2017
Jerome Fourmann

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 2

Defects framework – 6xxx series aluminum alloys


Common Extrusion Alloys

Soft Alloys 6360 “high performance”

6063 “general purpose”

Extrudability Properties
decrease increase 6063 “high strength” -T54, -T65

6005A

Medium Strength Alloys 6061 / 6351

6082

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 3

Defects framework – Acceptance level

Excellence

Fair

Basics

Surface critical
Roughness critical
Mill Finish
• PRINTER COPIER TUBE
• SUNROOF RAILS
• CRASH SYSTEM • COMPUTER
• SIDE TRIMS
• ABS HOUSING • MOBILE DEVICE CASE
• HEAT EXCHANGERS
• TRAILOR • LUGGAGE COVER
Roller aluminum tube
• HEAT & FLUID TRANSFER
images courtesy of • PLATFORM • DECORATIVE PARTS
Constellium • HEAT SINKS
• SUPERSTRUCTURE
• INDUSTRIAL
COMPONENT
• ENGINE PARTS
• ENGINE HOUSING

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 4

Defects classification in 6xxx aluminum extrusions


During Extrusion / Mill Finish After Extrusion - Metallurgical After Anodization

MgSi at
Coarse Atmos. Acid
Pick-up Blister grain
MgSi corrosion corrosion
boundary

Coarse
Speed Orange Alkali Rinse water
Tearing grain
Cracking peel corrosion corrosion
banding

Micro die Corrosion Corrosion Spacer Chloride


Die line
line pitting fingerprint marking contami.

Coloring
Corrosion
Die streak Snap mark Water stain Dull finish due to
fretting
MgSi

Front-end Back-end Spacer Excess White etch


Spangle
TW Coring marking lubricant bloom

Inclusion
Longit. Inclusion Inadequate Castle and
Hot spots extrusion
weld cast-in rinse moat
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 5

Defects occurring during extrusions / Mill Finish


During Extrusion / Mill Finish

Pick-up Blister

Speed
Tearing
Cracking

Micro die
Die line
line

Die streak Snap mark

Front-end Back-end
TW Coring

Longit.
Hot spots
weld
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 6

Pick-up
During Extrusion / Mill Finish

Pick-up Blister

Speed
Tearing
Cracking

Micro die
Die line
line

Die streak Snap mark

Front-end Back-end
TW Coring

Pick-up under paint layer


Longit.
Hot spots
weld
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 7

Pick-up – Topography tells it all: Cauliflower appearance

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Pick-up – Topography tells it all: Comet tail appearance

Normal surface appearance

Irregular surface appearance

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 9

Pick-up – Mechanisms

Extrusion direction
Coating of aluminum oxide on the
die bearing exit

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 10

Pick-up – Possible causes and prevention measures

• Exit temperature too high


– Optimize billet temperature “Stay in your 
lane!”

– Optimize extrusion speed

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 11

Pick-up – Possible causes and prevention measures

• Deterioration of die bearing condition


− Ensure correct re-nitriding to avoid premature wear of the bearing by flacking or cracking

− Correct die preheating to prevent excessive oxidation of the die bearing (no overheating)

− Die bearing too long or of incorrect contour, polishing, handling…

Pristine and fragile surface


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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 12

Pick-up – Possible causes and prevention measures

• Extrusion environment
Nitrogen shrouding reduces oxidation and
therefore pick-up

• Inferior billet quality


– Un-homogenized or inadequate
homogenization (95% or more
alpha Fe broken up)
– High Fe content: < 0.18%
– Inclusions: use quality billet
– Billet skin: limit the number
of billets

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 13

Not always pick-up! – foreign material

The Energy Dispersive X-Ray analysis (EDX) on the painted longitudinal section across the
defect revealed the presence of foreign material composed of Al, Mg, Ca, O. This is likely a
particle of clay, chalk or other pigment used to color the coating.

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 14

Not always pick-up! – various inclusions


Al

O Fe

C Fe
Mg Si Cr Fe
Cr

0 1 2 3 4 5 6 7 8
Pleine échelle 768 cps Curseur : 10.094 (0 cps )

Example of tool steel particles

Al

Mg Cl
O Na Cl K K

0 1 2 3 4
Pleine échelle 731 cps Curseur : 10.094 (0 cps )

Example of carbon base lubricant

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 15

Not always pick-up! – polishing compound

Si Spectrum 2
Longitudinal polished
section.

The anodic film that Al

wets the particle O

indicates it laid on the K


C
S K
K
surface before the 0 1 2 3 4 5 6 7 8 9 10 11
Pleine échelle 501 cps Curseur : -0.042 (176 cps ) keV
anodizing process
Mainly silicon carbide and potassium particles compound particle
caused by buffing operations
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 16

Blister
During Extrusion / Mill Finish

Pick-up Blister

Speed
Tearing
Cracking

Micro die
Die line
line

Die streak Snap mark

Front-end Back-end
TW Coring

Longit.
Hot spots
weld
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 17

Blister

Blow hole

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 18

Blister – Possible causes and prevention measures

• Entrapment of air during billet upsetting


– Burp cycle not used
– Distortion of billet front surface
– Poor butt shearing
– Billet too long or 2 piece-billet
– Container liner worn out, misalignment
– Billet quality

• Entrapment of volatile liquid via back end of billet (minimum use of lubricants)
• Extrusion of billet skin
• Billet temperature too high (front-end should be hotter than back-end)
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 19

Blister – Possible causes and prevention measures

• Use burp cycle to release entrapped air


 Trapped air from upsetting too fast - Upset-By-Distance vs. Pressure
 Billet discards show presence of air?

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 20

Blister – Possible causes and prevention measures

• Incomplete Upset in the “die-end” of the Liner


 Check container liner condition, press alignment
 Sticky alloy, i.e. 3xxx

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 21

Speed cracking, tearing


During Extrusion / Mill Finish

Pick-up Blister

Speed
Tearing
Cracking

Micro die
Die line
line

Die streak Snap mark

Front-end Back-end
TW Coring

Longit.
Hot spots
weld
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 22

Speed cracking, tearing

Inner surface in hollow section

Delamination

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 23

Speed cracking, tearing – Causes and prevention measures


• Excessive die exit temperature
 Occurs near the alloy melting point
 Ultimate limit is speed cracking1400
750
700
1200 650

Temperature (oF)
SOLIDUS 600

Temperature (oC)
1000 550
Solid solution 500
800 450
400
350
600
300
SOLVUS 250
400 200
6360 6060 6063 6061
150
200 100
0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 24

Speed cracking, tearing – Causes and prevention measures

• Entrapment of billet skin in extrusions

• Check die design to ensure die cavity at least 20


mm away from container wall

• Check container alignment and liner condition (no


excessive wear)

• Clean container regularly to prevent build-up of


aluminium oxides

• Reduce container temperature to ensure billet to


container temp differential more than 50oF

• Increase butt length

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 25

Not always Speed cracking, tearing ! – Coring


Presence of transverse weld
(red arrows) and coring
(white arrows) associate with
the longitudinal weld (yellow
arrows)

Tearing is associated with coring

Caustic etched – White arrows


indicate the location of the
longitudinal welds

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 26

Not always Speed cracking, tearing ! – various inclusions

• Fragments (chips) of tool steel originated from die or cutting tool (scalping,
shear, dummy block…)

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 27

Speed cracking, tearing – Causes and prevention measures

• Excessive die exit temperature


 Should not exceed 1020ºF (Use IR probe)

• Entrapment of billet skin in extrusions


 container alignment, liner condition, container 45ºF-70ºF colder than billet, adequate front & back-
end scrap…

• Fragments (chips) of tool steel originating from die or cutting tool (if billet scalping is
used)
 Nitride layer, die condition, container liner, dummy block…

• Foreign materials such as Al oxides and other materials


 Clean container to prevent build-up of Al oxides, increase butt length…

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 28

Die lines
During Extrusion / Mill Finish

Pick-up Blister

Speed
Tearing
Cracking

Micro die
Die line
line

Die streak Snap mark

Front-end Back-end
TW Coring

Longit.
Hot spots
weld
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 29

Die lines / Micro die lines / Streaks – Industry context


Common problem for extruders
Difficult to identify the root cause:
− Billet
− Extrusion process
− Finishing process
Streaking is revealed at last step of the process

• Many contributing factors from previous steps


• Evidence removed after anodizing

Need to understand why before we can know how

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 30

Die lines / Micro die lines / Streaks – Definitions


Die line: deep grove Micro die line: fine lines Streaks: bands of dark or light colors

A
Mounting media

Aluminum
Mounting media B
Aluminum

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 31

Die lines / Micro die lines – Mechanisms

Die line: deep grove

Micro die line: fine lines

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 32

Die lines – Possible causes and prevention measures


• Causes:
‒ Pitting in die bearing surface due to wash-out or spalling of the nitriding layer;
‒ Presence of large AlFeSi particles in the aluminium coating layer on die bearing
surface;
‒ Build-up of oxides in bearing relief region;
‒ Large inclusions in billet;

• Countermeasures:
‒ Remove die from press for cleaning and bearing polishing
‒ Improve die preparation, die preheating, die nitriding and re-nitriding practices;
‒ Prevent inflow of billet skin;
‒ Review and adjust extrusion conditions;
‒ Use high quality billet;

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 33

Micro die lines – Mechanisms

Microscopic top and


transverse views of a
“streaky” as-extruded
surface considered as die
lines

In streak Normal surface


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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 34

Micro die lines – Possible causes and prevention measures


• Causes:
‒ Deteriorated die bearing surface condition resulting from scratching by AlFeSi
particles in billet skin;
‒ Excessive build-up of an aluminium coating on the bearing surface due to high
deformation heating in the localised area;
‒ Improper design of bearing length, pocket or feeder plate opening;
‒ Billet quality: surface contamination, thick segregation zone, inadequate
homogenisation, high inclusion content;

• Countermeasures:
‒ Prevent inflow of billet skin;
‒ Improve die design, die correction and die maintenance;
‒ Use high quality billet;

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 35

Streaks – Mechanisms
TYPE II
Caused by die or
profile design

TYPE I
Caused by
contaminants

TYPE III
Caused by
extrusion process
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 36

Streaks – Mechanisms
Textural streak anodized
Surface topography 0.2µm
Variable grain size and attack

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 37

Streaks – Mechanisms

Non-uniform Metal Flow

Variation in Pressure and


Friction Force on Die Bearing

Difference in
Grain Orientation or Grain Size

Difference in Difference in Surface Morphology


Surface Roughness & Flatness after etching

Difference in Difference in
Light Reflection Light Reflection

Streaks on Mill Finish Product Streaks on Anodised Product

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 38

Streaks – Causes and prevention measures


• Always check die bearing first
‒ Bearing length:
 Correctly designed to ensure uniform metal flow

‒ Bearing shape:
 No rounded edge at entrance
 Square in respect to the die face

‒ Bearing surface condition


Pristine and fragile surface
 Flat and free of pits and damage

‒ Bearing blending – smooth and no shape steps

Bearing Bearing

 X
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 39

Streaks – Causes and prevention measures


• Balance metal flow
‒ Area with a screw:
 Reduce bearing length at the
tips of the screw, better from the die front side;
 If the flow in the screw area is still not fast enough, increase flow resistance of the
flat part of the profile (but ensure no steps in bearing);

‒ Area with an intersection:


 Check metal flow of the vertical branch during die trial (a) (b)
and adjust bearing length/angle accordingly;

‒ Area under a port


 Reduce web height and increase welding chamber size;
 Delay the flow under the port by using a pre-chamber or increasing
bearing length;

‒ Reduce speed and increase temperature


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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 40

Streaks – Causes and prevention measures


• Case studies: Streaked
100 69 region
86

Streak Zone 1 Zone 1 220

Zone 2

Web 
intersection Zone 3

Solution: not over-restrict the flow of the vertical part near the intersection

4 4
5 4 5 4
3 5
5 5 5< 3 5.5
5 .2 5 2
4 4 5 4
5 5 4

Original die design Modified die design

Solution: remove the groove on the mandrel to prevent “overfeeding”


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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 41

Streaks – Causes and prevention measures


Contaminants that build up in dead
metal zone
Feeder
Core /
Wall Billet #
mandrel
60
New metal

Feeder Old metal 59


58
Dead 57
Die
Rim of
body
Zone

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Die Face

Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 42

Streaks – Causes and prevention measures

Impact of bearing

• Bearing squareness, over polishing


• Cleanliness between runs
• Over-heated or soaked too long in the die oven
• Burrs, wash-out…

• Nitride case quality

• Anything that causes a build-up on the bearing


• Bearing change too abrupt, blending not smooth enough, matching to
section shape…
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 43

Streaks – Causes and prevention measures

Impact of billet

• Alloy 6061, 6005A, 6063, 6060, 6360


• Internal structure after homogenization
• Billet surface quality and external cleanliness

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 44

Streaks – Causes and prevention measures

Impact of extrusion practice

• Container too hot

• Press misalignment

• Excess skull build-up in container

NOT BAD
BAD But not perfect
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 45

Defects occurring after extrusions / Metallurgical


After Extrusion - Metallurgical

MgSi at
Coarse
grain
MgSi
boundary

Coarse
Orange
grain
peel
banding

Corrosion Corrosion
pitting fingerprint

Corrosion
Water stain
fretting

Spacer Excess
marking lubricant

Inclusion
Inclusion
extrusion
cast-in
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process

Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 46

MgSi
After Extrusion - Metallurgical

MgSi at
Coarse
grain
MgSi
boundary

Coarse
Orange
grain
peel
banding

Corrosion Corrosion
pitting fingerprint

Corrosion
Water stain
fretting

Spacer Excess
marking lubricant

MgSi image by High resolution transmission


Inclusion electronic microscope and atom-probe
Inclusion
extrusion
cast-in
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 47

MgSi - Where does MgSi formation take place?

How much Cooling quick Preheating Exit temperature


Temperature Mg & Si enough to prevent fast enough high enough to
available ? coarsening of MgSi? to prevent dissolve MgSi?
coarsening
Liquid of MgSi? Cooling quick
enough to prevent
Solid, coarsening of MgSi?
Mg & Si
dissolved
Natural ageing
Deformation long enough?
temperature
Artificial ageing
optimised?

Time
Casting Homogenization Ageing

Preheating

Extrusion
Cooling
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 48

MgSi - Aiming for the right condition!


Strength & properties of 6xxx extrusions
=
Large number of fine MgSi precipitates

Critical factor: temperature, temperature, temperature !


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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 49

MgSi – Coarse undissolved MgSi

Good sample Bad sample


Fine MgSi particles Coarse undissolved MgSi particles
Die exit temperature achieved Failure to achieve die exit
temperature

i.e. Low hardness: Presence of undissolved MgSi particles oriented in the extrusion direction
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 50

MgSi – Coarse undissolved MgSi


Recommended die exit temperatures:
6060, 6360, 6063, 6463 at 930oF minimum
6005A, 6061, 6082 at 950oF minimum

20m
0.001”

Undissolved MgSi in an Extrusion


Reasons include: - Extended billet preheat soak
- Failure to reach required die exit temperature
- Failure to reach required core temperature on heavy sections
- Low billet temperature
- Coarse homogenized structure
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 51

MgSi
After Extrusion - Metallurgical

MgSi at
Coarse
grain
MgSi
boundary

Coarse
Orange
grain
peel
banding

Corrosion Corrosion
pitting fingerprint

Corrosion
Water stain
fretting

Spacer Excess
marking lubricant 1 nm

MgSi image by High resolution transmission


Inclusion electronic microscope and atom-probe
Inclusion
extrusion
cast-in
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process

Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 52

MgSi precipitation at the grain boundaries

i.e. Low Properties: i.e. Good Properties:


Precipitates concentrated at grain No precipitates at grain boundaries and good
boundaries and more MgSi out of Solution distribution overall

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 53

MgSi precipitation at the grain boundaries

Reasons include: - Inadequate press quenching


- Premature ageing on run out
table (soft spots)

MgSi out of Solution and at


the grain boundary

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 54

MgSi
After Extrusion - Metallurgical

MgSi at
Coarse
grain
MgSi
boundary

Coarse
Orange
grain
peel
banding

Corrosion Corrosion
pitting fingerprint

Corrosion
Water stain
fretting

Spacer Excess
marking lubricant

Inclusion
Inclusion
extrusion
cast-in
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 55

Coarse grain banding (PCG) - Crack

Appearance of the cracked area

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 56

Coarse grain banding (PCG) - Crack

Bad part
Appearance of the PCG area

Good part
uniform grain

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 57

Coarse grain banding (PCG) – Causes and prevention measures


• Objective: Produce a fully Rx structure or a completely un-Rx structure

• Die conditions
– Bearing length and choke angle influence the PCG thickness in quenched profiles
– Extrusion speeds with acceptable PCG thickness can be several times higher with
long choked bearings and in addition the onset of speed cracking can be delayed.

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 58

MgSi
After Extrusion - Metallurgical

MgSi at
Coarse
grain
MgSi
boundary

Coarse
Orange
grain
peel
banding

Corrosion Corrosion
pitting fingerprint

Corrosion
Water stain
fretting

Spacer Excess
marking lubricant

Inclusion
Inclusion
extrusion
cast-in
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 59

MgSi precipitates at the grain boundaries: Orange Peel

Orange peel surface Normal surface

Mg2Si precipitate more Mg2Si precipitate less visible.


visible. 43 HRFW 56 HRFW
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 60

Orange peel – Causes and prevention measures


Possible causes:
• Alloys metallurgy
– Alloys suitable to bending condition: not subject to coarse grain outer-band

• Extrusion conditions
– Slow billet preheating
– Exit temperature not high enough to dissolve MgSi
– Exit temperature too high favours re-crystallized outer-band
– Insufficient press quenching and avoid delay into the quench box
– Over stretching
– Ensure billet to container temperature differential more than 50oF

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 61

Defects occurring after anodization


After Anodization

Atmos. Acid
corrosion corrosion

Alkali Rinse water


corrosion corrosion

Spacer Chloride
marking contami.

Coloring
Dull finish due to
MgSi

White etch
Spangle
bloom

Inadequate Castle and


rinse moat
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 62

Spacer mark
After Anodization

Atmos. Acid
corrosion corrosion

Alkali Rinse water


corrosion corrosion

Spacer Chloride
marking contami.

Coloring
Dull finish due to
MgSi

White etch
Spangle
bloom

Inadequate Castle and


rinse moat
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 63

Spacer mark
Also known as hot spots, dull spots, or black spotting.
• Typically visible after anodization
• Cool and reheat section creates the environment for a rapid precipitation of MgSi

Heavy density of MgSi


precipitates in the defect

Low density of MgSi


precipitates away from the
defect

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 64

Dull finish
After Anodization

Atmos. Acid
corrosion corrosion

Alkali Rinse water


corrosion corrosion

Spacer Chloride
marking contami.

Coloring
Dull finish due to
MgSi

White etch
Spangle
bloom

Inadequate Castle and


rinse moat
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 65

Dullness Appearance

“Good” Surface Dull Surface

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 66

Dullness Appearance

Desirable Sample – less precipitates at Dull Sample – note precipitates at grain


grain boundaries and overall boundaries

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 67

Dullness Appearance

Desirable Sample – less precipitates at Dull Sample – note precipitates at grain


grain boundaries and overall boundaries

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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 68

Color finish
After Anodization

Atmos. Acid
corrosion corrosion

Alkali Rinse water


corrosion corrosion

Spacer Chloride
marking contami.

Coloring
Dull finish due to
MgSi

White etch
Spangle
bloom

Inadequate Castle and


rinse moat
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34
Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 69

Color finish

bad High MgSi precipitates concentration in


the “bad” dark sample

good
Low MgSi precipitates concentration in
the “good” light sample

AA6063 Dark Light


Si 0.42 0.43
Fe 0.22 0.21
Cu 0.027 0.001
The anodic layer: Mn 0.064 0.032
• light sample: 16-18 µm thick Mg 0.47 0.50
• dark sample: 20-22 µm thick Cr 0.017 0.000
Ni 0.006 0.002
Zn 0.009 0.002
Ti 0.015 0.005
© 2017 Rio Tinto. All rights reserved.

Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 70

Color finish – Mechanisms pits & grooves during etching

Increased Fe content promotes matt finish


© 2017 Rio Tinto. All rights reserved.

35
Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 71

Color finish – Mechanisms pits & grooves during etching

Caustic etching is microstructure sensitive

© 2017 Rio Tinto. All rights reserved.

Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 72

Color finish – Mechanisms pits & grooves during etching


40 Caustic etching is microstructure sensitive

20 film
30
Anodised Gloss 60°

Pilot Caustic etch 180s Acid Etch. Insensitive to microstructure


20

Commercial
10 Caustic -10

180s Acid + 40s NaOH. Attack microstructure


Acid Etch
0
AA6063 Hi Cu Lo Fe Hi Zn AA6360
Alloy

Acid etching minimizes sensitivity of alloy composition


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36
Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 73

Dull and Color Appearance – Mechanisms

Dull / Color appearance

Diffusion of reflected light

Pits - Dissolution of Pits & grooves formed during alkaline etching Grooves - Dissolution of
aluminium matrix MgSi precipitates in grain
surrounding AlFeSi boundary
intermetallic particles
Pits in grain interior Grooves in grain boundaries
Grain
Fe intermetallic MgSi MgSi Grain size
orientation

Alloy Homo whole process Profile Die

Whole process
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Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 74

Dull and Color Appearance – Causes and prevention measures


Possible causes:
• Over-ageing
– Ageing conditions not optimised: can occur on purposely over-aged products
– Poor control of ageing oven: conduct yearly oven survey
• Extrusion conditions that lead to MgSi coarsening
– Slow billet preheating
– Exit temperature not high enough to dissolve MgSi
– Insufficient press quenching
• Poor billet quality
– High Fe content in alloy (i.e. secondary billet): < 0.18%
– Billet not or not adequately homogenized
– Slow post-homo cooling rate

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37
Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 75

Spangle
After Anodization

Atmos. Acid
corrosion corrosion

Alkali Rinse water


corrosion corrosion

Spacer Chloride
marking contami.

Coloring
Dull finish due to
MgSi

White etch
Spangle
bloom

Inadequate Castle and


rinse moat
© 2017 Rio Tinto. All rights reserved.

Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 76

Spangle – “grainy” or “galvanized” surface


SEM - varying level of attack
Normal surface
after caustic etch
preferential grain attack

Irregular surface
Anodic layer thickness 6μm

SEM - Step
Spangle surface
Coarse grain size

Irregular surface
Anodic layer thickness 14μm

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38
Extrusion Defects: Fundamentals & Solutions AEC – Finishing Workshop 2017 77

Spangle – Causes and prevention measures


• Metal composition
– Presence of zinc as a contaminant in the alloy: Zn below 0.025%
• Extrusion - Metallurgy
– Hollow more prone than solids because of their generally coarser grain size.
– Coarse grain structure in the extrusion: composition, extrusion process
• Etching and anodizing conditions
– Presence of free zinc as a contaminant in the caustic etch solution: Zn below 6ppm
– Long life vs. recovery process: Crystallizers do not remove Zn along with the
aluminum in recovery process and no additive as the filters can clog by the precipitate.
Long-life etch the additive (usually sodium sulfide) precipitates the zinc (as zinc
sulfide) and is skimmed off the top.
– Appropriate level of caustic soda: 50-60 g/l achieve the same etching as 100 g/l.
– High-speed or high etching temperature: 125-135 ˚F and extend time if needed

© 2017 Rio Tinto. All rights reserved.

Extrusion Defects
Fundamentals & Solutions
for Optimum Finish
Columbus, Ohio – May 16-17, 2017
Jerome Fourmann

© 2017 Rio Tinto. All rights reserved

39

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