CHEMISTRY

JEE MAIN SAMPLE PAPER

Chapter 07. Chemical and Ionic Equilibrium

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1. mole of a gas AB3 are introduced into a 1.0 dm3 vessel. It dissociate as:
2AB3(g) A2(g) + 3B2(g)
At equilibrium, 2 mole of A2 are found to be present. The equilibrium constant of the reaction
is:
(a) 2 mol2 L–2
(b) 3 mol2 L–2
(c) 27 mol2 L–2
(d) 36 mol2 L–2s

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 JEE Main Sample Paper – 07. Chemical and Ionic Equilibrium

2. At constant temperature, the equilibrium constant (kp) for the decomposition

reaction, N2O4 2NO2 is expressed by:

  
– 


Where, P = pressure, x = extent of decomposition, Which one of the following statements is

true?
(a) Kp increases with increase of P
(b) Kp increases with increase of x
(c) Kp increases with decrease of x
(d) Kp remains constant with change in p and x

3. Which graph will show equilibrium condition?

(a)

(b)

(c)

(d) None of these

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 JEE Main Sample Paper – 07. Chemical and Ionic Equilibrium

4. For the reaction, N2 + O2 2NO equilibrium constant Kc = 2. Degrees of dissociation of

N2 and O2 are:
 
(a)  
     
 
 
(b)  

      

(c) both are 
  

 
(d)  
     
  

5. Hydrolysis constant of two salts KA and KB of weak acids HA and HB are 10–8 and 10–6. If the
dissociation constant of third acid HC is 10–2. The order of acidic strength of three acids will be:

(a) HA > HB > HC (c) HC > HA > HB

(b) HB > HA > HC (d) HA = HB = HC

6. Consider the three solutions of 1M concentration.

I. Sodium acetate (CH3COONa)
II. Acetic acid + Sodium acetate
(CH3COOH + CH3COONa)
III. Acetic acid (CH3COOH)
The pH of these solutions will lie in the following sequence:
(a) 3 < 2 < 1
(b) 2 < 1 < 3
(c) 1 < 2 < 3
(d) 3 < 1 < 2

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 JEE Main Sample Paper – 07. Chemical and Ionic Equilibrium

7. Solubility of calcium phosphate (molecular mass, M) in water is W g per 100 mL at 25°C. Its
solubility product at 25°C will be approximately:
 
(a) 109 
  

(c) 105 
  


 
(b) 107   (d) 103  

8. In the following reaction:

HCO–3 + H2O CO2–3 + H3O+
which two substances are Bronsted bases?

(a) CO2–3 and H3O+ (c) HCO–3 and CO2–3

(b) HCO–3 and H3O+ (d) CO2–3 and H2O–

9. Which among the following represent the conjugate acid/base pairs?

(a) H3O+/H2O (c) H2CO–3/CO2–3

(b) H2SO4/SO2–4 (d) All are conjugate acid/base pairs

10. In gaseous reversible reaction,

N2(g) + O2(g) 2NO(g) + Heat
If pressure is increase, then the equilibrium constant would be:
(a) Unchanged
(b) Increased
(c) Decreased
(d) Sometimes increased, sometimes decreased

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 JEE Main Sample Paper – 07. Chemical and Ionic Equilibrium

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 JEE Main Sample Paper – 07. Chemical and Ionic Equilibrium

Answer Keys

Q1 Q2 Q3 Q4 Q5
(c) (d) (b) (c) (c)
Q6 Q7 Q8 Q9 Q10
(a) (b) (d) (a) (a)

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