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PREFACE
This book contains the Daily Practice Problems (DPPs) designed for the aspirants
separate booklets) from multiple topics to understand the application of concepts learned in
theory. Each DPP is kind of a timed test with marking scheme and prescribed time to be spent
on each problem. It is according to the latest pattern of JEE(Advanced) and serves as a great
tool for the students to simulate examination conditions at home. It enables a student to
practice time management while solving a problem which helps him/her to better prepare for
Every effort has been taken to keep this book error free, however any suggestions to improve
(i)
DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
DPP
DAILY PRACTICE PROBLEMS
CHEMISTRY
TARGET: JEE (Main + Advanced)
COURSE : VIJETA (01&02JPBH & 01&02JPABH)
Physical / Inorganic Chemistry DPPs (A1 to A20)
Organic Chemistry DPPs (A1 to A14)
INDEX
PHYSICAL / INORGANIC CHEMISTRY DPPS
(ii)
DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
NOTE:
Marked Questions may have for Revision Questions.
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(iii)
DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
4. lEihM~;rk xq.kkad (Z) ds lanHkZ esa fuEu esa ls dkSulk@dkSuls dFku lgh gS@gSa %
(A) U;wu nkc {ks=k esa] nkc esa o`f) ds lkFk Z ds eku esa izkjEHk esa deh gksrh gS] ;|fi H2 rFkk He xSl blds fy,
viokn gSaA
(B) ,d vkn'kZ xSl ds fy, Z, ,d ls vf/kd gksrk gSA
(C) ,d vukn'kZ xSl ds fy,] Z dk eku ,d ls vf/kd vFkok de gks ldrk gS rFkk ;g rki rFkk nkc ij fuHkZj
djrk gSA
(D) tc Z < 1 gS] rc vUrjvk.kfod vkd"kZ.k] vUrjvk.kfod izfrd"kZ.k ij izHkkoh gksrk gSA
5. ,d vkn'kZZ xSl dh fu;r ek=kk ds fy, rhu izØe AB, APB o AQB fd;s tkrs gSaA lgh fodYi pqfu;sA
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7. ,d foy;u dks Ag2CrO4 rFkk Ag2C2O4 nksuksa dks ?kksydj cuk;k tkrk gS tc rd fd nksuksa yo.kks a ds laxr lar`Irrk
izkIr u gks tk;sA
fn;k gS Ksp (Ag2C2O4) = 10–12, Ksp (Ag2CrO4) = 2×10–12
1
fn;k gS : 36 3 3.3
mijksDr nh x;h lwpuk ds laxr fuEu es ls dkSulk@dkSuls dFku lgh gS@gSa \
(A) vfUre foy;u esa [Ag+] rFkk [CrO24 ] Øe'k% 1.8×10–4 M rFkk 0.6×10–4 M gSA
(B) vfUre foy;u esa [Ag+] rFkk [CrO24 ] Øe'k% 0.9×10–4 M rFkk 0.6×10–4 M gSA
(C) vfUre foy;u esa [Ag+] rFkk [C2O24 ] Øe'k% 3.6×10–4 M rFkk 0.3×10–4 M gSA
(D) vfUre foy;u esa [Ag+] rFkk [C2O24 ] Øe'k% 1.8×10–4 M rFkk 0.3×10–4 M gSA
8. fuEu esa ls fdrus ijkWDlkbM iztkfr;ka j[krs gSa ?
(i) CO2 (ii) NO2 (iii) BaO2 (iv) PbO2 (v) KO2 (vi) Na2O2
(viii) MnO2 (viii) CrO5
9. pH = 8.65 dk cQj nsus ds fy, NH4Cl ds 0.2 M foy;u ds 0.3 M NH4OH feyk;k tkuk pkfg,A
fn;k gS% pkbNH OH = 4.75 rFkk izfry?kqxq.kd ( 0.6) = 0.25 .
4
10. 414 g H2O(s) ds H2O() esa :ikUrj.k ds fy, fuEu izØe ds fy, twy esa G dk fu/kkZj.k dhft,A
H2O(s) H2O()
(6 atm, 273 K) (6 atm, 273 K)
fn;k gS: H2O(s) dk ?kuRo = 0.92 g/cm3, H2O() dk ?kuRo = 1 g/cm3
viuk mÙkj 6 ls foHkkftr djus ds i'pkr~ nhft, (yhft, 1 atm L = 100 J)A
11. fuEu esa ls fdrus dFku lR; gS \
(a) BeO dh mHk;/kehZ çd`fr gSA (b) LiHCO3 Bksl voLFkk esa ugha ik;k tkrk gSA
(c) K2O2 çfrpqEcdh; gS ijUrq KO2 vuqpEq cdh; gSA
(d) lQsn QkWLQksjl] dkWfLVd lksMk ls fØ;k dj QkWLQhu xSl cukrk gSA
(e) AlCl3, NaOH ds vkf/kD; esa foys; gS rFkk lksfM;e esVk ,Y;qfeusV cukrk gSA
(f) futZyh; ikSVsf'k;e ukbVªsV dks ikSVsf'k;e /kkrq ds lkFk xeZ djus ij ikSVsf'k;e vkWDLkkbM vkSj ukbVªkstu xSl curh gSA
(g) fyfFk;e DyksjkbM ty esa vR;f/kd foys; gSA
(h) ty;ksftr eSXusf'k;e DyksjkbM dks 'kq"d gok esa xeZ djus ij futZyh; MgCl2 çkIr gksrk gSA
12. ,d fudk; ftlesa dh vkn'kZ xSl dh fuf'fpr ek=kk mifLFkr gS] ds fy, fuEufyf[kr dk feyku dhft,A
LrEHk I LrEHk II
(A) pfØ; izØe (Cyclic process) (p) H = 0 rFkk U = 0
(B) mRØe.kh; lerkih; izØe (Reversible isothermal process) (q) Q = –W
(C) mRØe.kh; :)ks "e iz Ø e (Reversible adiabatic process) (r) W = 0 rFkk Q = U
(D) levk;ruh izØe (Isochoric process) (s) Q = 0 rFkk dH = Vdp
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2. ,d vkn'kZ xSl dk ,d izkjfEHkd fuf'pr voLFkk ls lerkih; rFkk :)ks"e izlkj.k ds fy, lgh xzkQ gksxk&
lerkih; lerkih;
(A) L)ks"e (B) (C) L)ks"e (D) lerkih;
lerkih; L)ks"e L)ks"e
5. izØe H2O() (1 bar, 373 K) H2O(g) (1 bar, 373 K) ds fy,, Å"ekxfrdh ekiØeksa dk lgh lewg gSA
(A) G = 0, S = + ve (B) G = 0, S = – ve
(C) G = + ve, S = 0 (D) G = – ve, S = + ve
6. mRikn (x) rFkk (y) esa dsUnzh; ijek.kqvksa ds ladj.k dh voLFkk Øe'k% D;k gS \
(A) sp3 rFkk sp3d (B) sp2 rFkk sp3 (C) nksuksa esa sp3 (D) nksuksa esa sp3d
okLrfod xSl
8. P
vkn'kZ xSl
V
fuEu esa ls dkSulk dFku P-V oØ ds lUnHkZ esa xyr gS?
(A) mPp nkc {ks=k esa xSl /kukRed fopyu n'kkZrh gSA
(B) fuEu nkc {ks=k ij ekfir rFkk ifjdfyr vk;ru ,d nwljs ds fudV vkrs gSA
(C) mPp nkc {ks=k esa Z > 1 gksrk gS vr% xSl vkn'kZ xSl dh vis{kk de lEihM~; gksrh gSA
(D) fuEu nkc {ks=k esa Z < 1 gksrk gS vr% xSl vkn'kZ xSl dh vis{kk de lEihM~; gksrh gSA
9. fuEu esa ls dkSulk fp=k d.k ds laosx esa ifjorZu rFkk lacaf/kr Mh&czksXyh rjax nS/;Z dks iznf'kZr djrk gSA
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
10. ftad vkSj gkbMªksDyksfjd vEy dh fØ;k fuEu vfHkfØ;k ds vuqlkj gksrh gS %
Zn(s) + 2HCl(aq.) ZnCl2(aq.) + H2(g)
;fn HCl ds 0.52 eksy esa Zn ds 0.3 eksy dks feyk fn;k tk;s] rks H2 ds fdrus eksy cusxsa %
(A) 0.26 (B) 0.52 (C) 0.14 (D) 0.30
11. ijek.oh; la[;k c<+us ds lkFk {kkjh; e`nk /kkrqvksa ds fdl xq.kksa esa o`f) gksrh gS %
(A) vk;uu ÅtkZ (B) muds gkbMªksDlkWbM dh foys;rk
(C) muds lYQsV dh foys;rk (D) fo|qr _.kkRedrk
12. pH = 5.4 ds ,d foy;u esa gkbMªkstu vk;uksa dh lkanzrk ¼eksy@yhVj esa½ gksxh %
(A) 3.98 × 108 (B) 3.88 × 106 (C) 3.68 × 10–6 (D) 3.98 × 10–6
13. 109º 28' dk ca/k dks.k ik;k tkrk gS %
(A) NH3 (B) H2O (C) CH3+ (D) NH4+
14. ok"i izkoLFkk esa csUthu (PB0= 150 torr) rFkk VkWyqbZu (PT0 = 50 torr) dk eksy vuqikr D;k gS] ;fn fn, x, foy;u
dk ok"i nkc 120 torr gS ?
(A) 7 : 1 (B) 7 : 3 (C) 8 : 1 (D) 7 : 8
15. ,d nqcZy izksfVd vEy HA dk 0.20 eksyj foy;u 3.0 dh pH j[krk gSA vEy dk vk;uu fu;rkad gS&
(A) 5.0 × 10–7 (B) 2.0 × 10–7 (C) 5.0 × 10–6 (D) 5.0 × 10–3
16. 310 K ij 'kq) nzo A dk ok"inkc 40 mmHg gSA bl nzo dk] nzo B ds lkFk foy;u esa ok"i nkc 32 mmHg gSA
;fn foy;u jkmYV fu;e dk ikyu djrk gS rks foy;u esa A dh eksy fHkUu gS %
(A) 0.8 (B) 0.5 (C) 0.2 (D) 0.4
17. ty (B.P. = 100ºC) rFkk HCI (B.P. = 86ºC) dk fLFkjdokaFkh(azeotropic) feJ.k yxHkx 120ºC ij mcyrk gSA bl
feJ.k ds izekih vklou ds nkSjku fuEu dks izkIr djuk laEHko gS :
(A) 'kq) HCI dks (B) 'kq) H2O dks
(C) 'kq) H2O ds lkFk–lkFk 'kq) HCI dks (D) 'kq) H2O rFkk 'kq) HCI nksuks dksbZ ughaA
18. foy;u ds /kukRed fopyu ds fy, fuEu esa ls lgh dFku dkSulk gSA
(A) foyk;du esa eqDr ÅtkZ] vUrZfØ;k @ vUrjkf.od cyksa dks rksM+us esa iz;qDr ÅtkZ ls vf/kd gksrh gSA
(B) foys;&foyk;d vUrZfØ;k ¼interaction½ buds Loa; dh vUrZfØ;k ¼interaction½ dh rqyuk esa nqcZy gksrh gSA
(C) foy;u fuekZ.k ij vk;ru esa ladqpu gksrk gSA
(D) foy;u dk DoFkukad vuqekfur eku ls mPp gksxkA
19. nks nzOkksa ds ,d fLFkj DokFkh foy;u dk DoFkukad nksuksa nzoksa ls de gksxk tc %
(A) ;g jkmYV fu;e ls _.kkRed fopyu n'kkZrk gSA (B) ;g jkmYV fu;e ls dksbZ fopyu ugha n'kkZrk gSA
(C) ;g jkmYV fu;e ls /kukRed fopyu n'kkZrk gSA (D) ;g lar`IRk gSA
20. A rFkk B æo ds ,d vkn'kZ foy;u ds fy, tc xA = 0.2 gS rc foy;u ij dqy ok"i nkc 560 Vksj Fkk rFkk A dk
vkaf'kd nkc 80 Vksj FkkA ok"i dk la?kVu D;k gksxk] tc xA = 0.8 gS ?
1 8 3 9
(A) yA = (B) yA = (C) yB = (D) yB =
7 11 7 11
21. NO3– esa N ds pkjksa rjQ fdrus bysDVªkWu ca/k ;qXe ik;s tkrs gSa \
22. Mkbcksjsu lajpuk esa fjDr ladfjr d{kdksa dh la[;k crkb;s tks 3-dsUnz 2 bysDVªkWu ca/k vFkkZr~ cukuk ca/k (banana
bonds) fuekZ.k esa Hkkx ysrs gSaA
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24. ,d 10 M Na2S foy;u esa As2S3 dh foys;rk Kkr dhft;s \ ¼ekuk fd] /kuk;fud vFkok _.kk;fud Hkkx dk
–2
1
fdlh Hkh izdkj dk ty vi?kVu ugha gksrk gS½ ¼fn;k gS: As2S3 ds fy, Ksp = × 10–24) viuk mÙkj Y ds :i esa
625
nhft;s tgk¡ foys;rk (mol/L esa) = Y × 10–11.
25. fuEu vk¡dM+ks ls ,Fkkbyhu ds gkbMªkstuhdj.k dh Å"ek dk fu/kkZj.k dhft,&
cU/k cU/k ÅtkZ cU/k cU/k ÅtkZ
HH 104 k Cal CC 80 k Cal
CH 99 k Cal C=C 145 k Cal
4. ;fn leku nkc rFkk nks fHkUu rkieku ij ukbVªkstu o vkWDlhtu ds rms osx leku gks rc
(A) v.kqvksa dk vkSlr osx Hkh leku gksrk gSA
(B) ukbVªkstu rFkk vkWDlhtu dk ?kuRo (xzke/yhVj) Hkh leku gksrk gSA
(C) izR;sd xSl ds eksyksa dh la[;k cjkcj gksrh gSA
(D) v.kvksa dk lcls izkf;d osx (Vmp) Hkh leku gksrk gSA
5. 1 M Xywdksl (C6H12O6) dk foy;u (?kuRo = 1.18 g/ml) fuEu esa ls fdl foy;u ds lerqY; gSA
(A) % w/w = 18% (foy;u) (B) izfr yhVj foy;u esa 180 xzke foys;
(C) % w/v = 18% (foy;u) (D) 1 eksyy foy;u
6. ,d foy;u Cu2+ rFkk Cd2+ vk;u nksuksa esa 0.01M gSA foy;u esa 'ks"k cps Cd2+ dh lkUnzrk (M es) D;k gksxh tc
99.9% Cu2+ vk;u S2– ds ;ksx }kjk CuS ds :i esa vo{ksfir gksrk gS \
fn;k gS Ksp (CuS) = 8.7 × 10–36
Ksp (CdS) = 3.6 × 10–29
viuk mÙkj 100 ls xq.kk djds nhft,A
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
7. HCl rFkk CH3COOH dk ,d fuf'pr feJ.k izR;sd vEy esa 0.1 M gSA bl foy;u ds 20 ml dks 0.1M NaOH ds
lkFk mipkfjr fd;k tkrk gSA fdruh bdkbZ }kjk pH ifjorZu gksxk izkjEHk ls ml voLFkk rd tc HCl yxHkx
iw.kZr% mnklhuhÑr gksrk gS rFkk ,lhfVd vEy vuvfHkÑr jgrk gS\ ,lhfVd vEy ds fy, Ka = 2 x 105.
8. ;fn ,d nqcZy {kkj BOH ds 0.2 M foy;u dh pH 10.3 gS] rc mDr {kkj ds 20 mL foy;u esa feyk;s tkus okys
0.4 M HCl foy;u dk vk;ru (mL esa) Kkr dhft,] ftlls foy;u dh ifj.kkeh pH 7.3 ds cjkcj gks ldsA (yhft,
log 2 = 0.3)
9. 1 kg CaC2 j[kus okyk ,lhVhyhu ysEi fdrus ?kaVs rd dk;Z djsxkA ;fn 27ºC rki rFkk 1 atm nkc ij] 1 ?kaVs ds
fy, 60 yhVj ,lhVhyhu dh vko';drk gksrh gSA (viuk mÙkj fudVorhZ iw.kk±d esa fy[kksaA)
10. 10 yhVj ty esa 25ºC ij NaOH ds 10–2 eksy feyk;s tkrs gS] rc pH ifjorZu Kkr djks&
11. A rFkk B dk nzo ,d vkn'kZ foy;u cukrk gSA ,d fuf'pr rki ij] feJ.k A rFkk B dk dqy ok"i nkc 400 mm.
gSA ok"i voLFkk ds lkE; esa nzo feJ.k esa A dk eksy izHkkt 0.4 gSA ;fn blh rki ij 'kq) nzo ds fy, ok"i nkc
A dk vkaf'kd nkc
vuqikr (PA0/PB0) 1/6 gSA ok"i voLFkk esa gksxkA
10
12. fuEu dks lqesfyr dhft,&
LrEHk LrEHk
(A) 1 yhVj foy;u esa 120 xzke CH3COOH dfoy;u = 1.2 g / mL (p) M=2
(B) 1 yhVj foy;u esa 120 xzke Xyqdksl foys; (dfoy;u = 1.2 g/mL) (q) 10% Hkkj/Hkkj foy;u
(C) XNH2CONH2 = 1/31 (tyh; foy;u) (r) 12% Hkkj/vk;ru foy;u
(D) 19.6 % (Hkkj@vk;ru) H2SO4 foy;u (dfoy;u = 1.2 g/mL) (s) m = 1.85
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f=kd fcUnq
voLFkk vkjs[k ij og fcUnq] ftl ij inkFkZ dh rhu voLFkk,sa gS ;k rhuksa voLFkkvksa dk lgvfLrRo (coexist) gksrk gSA bu
fcUnqvksa ij lkE; dh js[kk,¡ ,d nwljs dks dkVrh gSA
ØkfUrd fcUnq
;g nzo rFkk xSl ds e/; dh voLFkk lhek gS] tks fujUrj vfuf'pr dky rd ugh gksrh gSA blds ctk; ;g voLFkk
vkjs[k ij ØkfUrd fcUnq ij lekIr gksrh gSA ;g bl rF; dks Li"V djrh gS fd vR;f/kd mPp rki rFkk nkc ij nzo rFkk
xSl vOkLFkk,sa vfoHksfnr gks tkrh gSA ;g vfrØkfUrd rjy (supercritical fluid) dgykrk gSA
laxyu (Xkyu) (;k fgeu) oØ (BD) – voLFkk vkjs[k ij og oØ] tks nzo rFkk Bksl voLFkkvksa ds e/; laØe.k dks iznf'kZr
djrk gSA
ok"ihdj.k (;k la?kuu) oØ (BC) – voLFkk vkjs[k ij og oØ] tks xSl rFkk nzo voLFkkvksa ds e/; laØe.k dks iznf'kZr
djrk gSA
Å/oZikru (;k fu{ksi.k] deposition) oØ (AB) – voLFkk vkjs[k ij og oØ] xSl rFkk Bksl voLFkkvksa ds e/; laØe.k dks
iznf'kZr djrk gSA
lkekU; xyukad rFkk DoFkukad 1 ok;qe.Myh; nkc ij ,d js[kk [khapus ij voLFkk vkjs[k ls izkIr gks ldrs gSA
CO2 ds mijksDr voLFkk vkjs[k dk iz;ksx djrs gq;s fuEu iz'uks ds mÙkj nhft;sA
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
13. voLFkk ifjorZu dk dkSulk izdkj izkIr gksxk] ;fn Bksl S dks lkekU; ifjfLFkfr;ksa ds vUrxZr [kqyk j[krs gS ?
(A) Å/oZikru (B) xyu (C) ok"ihdj.k (D) dksbZ ifjorZu ugh gksrk gSA
14. dkSulh ifjfLFkfr ds vUrxZr lkE; esa fudk; S dh leLr rhuksa voLFkk,sa izkIr gksrh gS ?
(A) T > 304.2 K rFkk P > 72.9 atm
(B) T = 216 K rFkk P = 5.2 atm
(C) T > 304.2 K
(D) P > 72.9 atm
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15. X1 fcUnq ij fudk; dk rki X4 fcUnq rd igqpusa ds fy, fu;r nkc ij c<+rk gSA fuEu esa ls dkSulk dFku fofHkUu
voLFkkvksa ij fudk; dh izkoLFkkvksa ds lUnHkZ es xyr gS \
(A) X1 fcUnq ij Bksl voLFkk dk vfLrRo gksrk gSA
(B) X2 fcUnq ij Bksl&nzo lkE; voLFkk dk vfLrRo gksrk gSA
(C) X3 fcUnq ij Bksl&nzo&xSl lkE; voLFkk dk vfLrRo gksrk gSA
(D) X4 fcUnq ij ok"i voLFkk dk vfLrRo gksrk gSA
16. ;fn nkc c<+krs gS] rks xSl S dk xyu rki gksxk &
(A) dksbZ ifjorZu ugh gksxk (B) c<+sxk
(C) ?kVsxk (D) dqN ugh dg ldrs
17. X5 fcUnq ij fudk; ds fy, D;k ?kfVRk gksrk gS] ;fn rki dks fu;r j[krs gq,s nkc dks /khjs&/khjs ifjofrZr djrs gS \
(A) mPp nkc ij fudk; nzo gksxkA (B) fuEu nkc ij fudk; nzo gksxkA
(C) fudk; leku voLFkk esa gksxkA (D) buesa ls dksbZ ugh
2. nks nzo X rFkk Y iw.kZr;k vfeJ.kh; gS ;fn X rFkk Y dk eksyj nzO;eku vuqikr 1 : 2 gS] rks vuqikr 2 : 3 esa cuk;k x;k
X rFkk Y ds feJ.k dk dqy ok"i nkc fuEu gksuk pkfg,A (PX0 = 400 torr, PY0 = 200 torr)
(A) 300 torr (B) 466.7 torr (C) 600 torr (D) 700 torr
3. 1 atm fu;r nkc ij nks vfeJ.kh; nzoksa ds ,d feJ.k dk DoFkukad %
(A) vf/kd ok"i'khy nzo ds lkekU; DoFkukad ds cjkcj gksrk gSA
(B) nks nzoksa ds lkekU; DoFkukadksa ds ek/; ds cjkcj gksrk gSA
(C) nksuksa nzoksa ds lkekU; DoFkukad esa ls fdlh ,d ls vf/kd gksrk gSA
(D) nksuksa nzoksa ds lkekU; DoFkukad esa ls fdlh ,d ls de gksrk gSA
4. U;wu nkc mifLFkfr ij ,d okLrfod xSl tks fd ok.MjokWy lehdj.k dk ikyu djrh gS ds fy,] fuEu esa ls dkSulk
oØ lgh gS\
M
5. Xywdkst (C6H12O6) dk og nzO;eku] tks blds tyh; foy;u ds 50 mL dks cukus ds fy, vko';d gS] fuEu gS %
9
(A) 10 xzke (B) 1 mg (C) 1 xzke (D) 100 mg
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8. KO2 dk mi;ksx vUrfj{k ok;q ;ku o iuMqCch esa vkWDlhtu flys.Mj es gksrk gS D;ksafd ;g
(A) CO2 vo'kksf"kr djrk gS o O2 ?kVd c<+rk gSA (B) ueh fu"dkflr djrk gSA
(C) CO2 vo'kksf"kr djrk gSA (D) O2 mRiUu djrk gSA
12. osusfM;e ijek.kq (Z = 23) esa v;qfXer bysDVªkWu ds fy, f}xa'kh DokaVe la[;k dk eku 'b' gS] rc (b) dk eku Kkr
dhft,A
(A) 6 (B) 2 (C) 3 (D) 1
(E) 'kwU;
13. 29Cu esa dsoy nks uksM j[kus okys iw.kZiwfjr d{kdksa dh la[;k gS &
(A) 5 (B) 9 (C) 3 (D) 7
14. fuEu esa ls dkSu mHk;/kehZ izÑfr n'kkZrk gS \
(A) Li2O (B) BeO (C) Cs2O (D) BaO
15. Si/P/S/Cl o vkWDlhtu ds e/; cU/k ;qDr ;kSfxdksa esa p d vU;ksU; fØ;k dk Øe gS &
(A) P > Si > Cl > S (B) Si < P < S < Cl (C) S < Cl < P < Si (D) Si > P > S > Cl
16. fuEu esas ls dkSulk dFku xyr gSa\
(A) HF > H2O > NH3 : H– ca/ku dh lkeF;Z
(B) F H....O O H....O F H....F : H– ca/ku dh lkeF;Z
(C) H2 O H2 Te H2 Se H2 S : DoFkukad
(D) HF H2 O NH3 : f}/kqzo vk?kw.kZ
17. esfFkyhulYQjVsVªk¶yksjkbM (CH2SF4) dh lajpuk esa] fdrus ijek.kq leku ry esa] mifLFkr gksrs gS \
18. ml pH dh x.kuk dhft,] ftl ij] 0.10 M Mg2+ vk;u j[kus okys ,d foy;u ls Mg(OH)2 dk vo{ksi.k çkjEHk gks
tkrk gSA Mg(OH)2 dk ksp = 1.0 × 10–11.
19. vkWDlsfyd vEy dh mnklhuhdj.k Å"ek – 25.4 Kcal mol–1 gS tc izcy {kkj NaOH dks iz;qDr fd;k tkrk gSA
rc izØe] H2C2O4 2H+ + C2O42– ds fy, ,UFkSYih ifjorZu Kkr djksaA
[izcy vEy dh izcy {kkj ds lkFk mnklhuhdj.k dh Å"ek = – 13.7 Kcal mol–1]
20. ,d 10 yhVj vk;ru okys fiLVu ;qDr ik=k esa ty ok"i ls lar`Ir gkbMªkstu xSl dks
fp=kkuqlkj j[kk tkrk gSA ik=k esa dqN ek=kk esa nzo ty Hkh mifLFkr gSA nzo ty ds
Åij] H2 dk vkaf'kd nkc] Hg dkWye ds 80 cm ds cjkcj gSA ;fn vc fiLVu dks
bl izdkj xfr djk;k tk;s fd ik=k dk vk;ru nqxquk gks tk,] rc ik=k es a nzo ty
ds Åij dqy nkc D;k gksxk \ (H2O dk i`"Bh; ruko = 20 cm of Hg) (H2O nzo ds
vk;ru dks ux.; yhft;s)
dqy nkc ¼ Hg ds lseh - esa)
(viuk mÙkj y ds :i esa nhft,] tgk¡ y = )
10
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21. ,d dkcZfud ;kSfxd esa Hkkjkuqlkj 44.44% dkcZu mifLFkr gSA ;fn ;kSfxd ds iz R;sd v.kq dk Hkkj 2.25 × 10–22 xzke
gS] rks dkcZfud ;kSfxd ds ,d v.kq esa mifLFkr C-ijek.kqvksa dh la[;k Kkr dhft;sA
(ii) fdlh ,d 'kq+) vo;o esa vU;ksU; fØ;k dh vis{kk (ii) fdlh ,d 'kq+) vo;o esa vU;ksU; fØ;k dh vis{kk
vUrjk vkf.od vU;ksU; fØ;k nqcZy gksrh gSA vUrjk vkf.od vU;ksU; fØ;k vf/kd gksrh gS
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
23. 55ºC, ij ,FksukWy ds fy, ok"i&nkc 168 mm gS o esfFky lkbDyksgSDlsu ds fy, ok"i&nkc 280 mm gSA bu nks
foy;uksa esa ftlesa ,FksukWy dk eksy&fHkUUk 0.68 gS o dqy ok"i nkc 376 mm gSA ;g foy;u fuEu ds lkFk blds
vo;oksa ls curk gSA
(A) Å"ek ds fu"dklu
(B) Å"ek ds vo'kks"k.k
(C) u rks Å"ek ds vo'kks"k.k vkSj uk gha Å"ek ds fu"dklu lsA
(D) nh xbZ tkudkjh ds vk/kkj ij buesa ls fdlh dks crk;k ugha tk ldrk gSA
24.
1 eksy A PA0 150mm o 2 eksy B PB0 240mm ds feJ.k dk dqy ok"i nkc 200 mm gSaA bl fLFkfr esa
(A) jkÅYV fu;e ls /kukRed fopyu gksrk gSA
(B) jkÅYV fu;e ls _.kkRed fopyu gksrk gSA
(C) jkÅYV fu;e ls dksbZ fopyu ugha gksrk gSA
(D) fopyu dks tk¡pus ds fy, A o B ds v.kqHkkjksa dh Hkh vko';drk gksrh gSA
25. ml feJ.k dks igpkfu, tks vukn'kZ foy;u ds /kukRed fopyu dks n'kkZrk gSA
(A) CH3COCH3 + CS2 (B) gSDlsu + gsIVsu
(C) DyksjkscsUthu + czksekscsUthu (D) ,lhVksu + DyksjksQkWeZ
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8. tc dsoy nzo voLFkk mifLFkr gS] rc nkcekih dk ikB~;kad gS \
(A) 499 (B) 399 (C) 299 (D) dksbZ ugha
9. cqycqyk fcUnq ij nkc ekih dk ikB~;kad gSA
(A) 500 (B) 600 (C) 700 (D) dksbZ ugha
10. tc dsoy ok"i voLFkk mifLFkr gS] rc nkcekih dk ikB~;kad fuEu gSA
(A) 501 (B) 457.14 (C) 425 (D) 525
11. ,d eksuksdkcksZfDlfyd vEy ds lksfM;e yo.k ds 0.01 M foy;u dh pH = 9 gSA vEy dk pKa ……… gksxkA
12. 500 xzke ty esa ,d f}yd oS|qr vi?kV~; ds 20 xzke (vkf.od Hkkj = 100) dks ?kksyk tkrk gSaA foy;u dk fgekad
0.74°C ; Kf = 1.86 K eksyjrk–1 gSA oS|qr vi?kV~; dk izfr'kr fo;kstu Kkr djksA
13. gkbMªkstu gSykbM ds xq.kèkeksZ esa fuEu izo`fÙk dk voyksdu dhft,&
1. vEyh; lkeF;Z : HF < HCl < HBr < HI 2. rkih; LFkkf;Ro : HF > HCl > HBr > HI
3. f}èkzqo vkèkw.kZ : HF < HCl < HBr < HI 4. vipk;d {kerk : HF > HCl > HBr > HI
lgh izo`fr dh la[;k Kkr djks A
14. feyku dhft,A
LrEHk I LrEHk II
(A) 0.1 M Al2(SO4)3 (p) mPpre DoFkukad dk foy;uA
(B) 0.1 M AlPO4 (q) okWUV gkWQ dkjd 1 ls vf/kdA
(C) 0.1 M ;wfj;k (r) U;wure ijklj.k nkc dk foy;uA
(D) 0.1 M MgCl2 (s) U;wure fgekad dk foy;uA
XA' o XB' ;gka ok"i izkoLFkk esa A o B ds eksy&fHkUu dks iznf'kZr djrs gSA
PTotal XB ' PB WB PB MB
PTotal XA ' PAº WA PA MA
ok"i ¼vklou½ esa vo;oksa dk nzO;eku] ok"inkc ds Øe'k% eksy nzO;eku ds lekuqikrh gksaxsA
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Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
15. 90ºC o 732 Vksj nkc ij ,d dkcZfud nzo o ty ds vfeJ.kh; nzo ds ,d feJ.k dks mckyk tkrk gSA vklou
dkcZfud nzo ds Hkkj dk 73% j[krk gSA dkcZfud nzo dk eksyj&nzO;eku ifjdfyr dhft, (90ºC ij ty dk
ok"inkc 526 Vksj gS)
(A) 168.2 xzke eksy–1 (B) 228.8 xzke eksy–1 (C) 122.2 xzke eksy–1 (D) 62.7 xzke eksy–1
16. tc 740.2 mm Hg, ds ,d cká nkc ij ty o DyksjkscsUthu ds ,d feJ.k dks vklfor fd;k tkrk gS] rks feJ.k
dks 90.3ºC ij mckyk x;k] ftl rkieku ij 'kq) ty dk ok"inkc 350.1 mmHg gSA vklou eas DyksjkcsUthu ds
Hkkj dk izfr'kr ifjdfyr dhft,A( v.kqHkkj 112).
(A) 0.71 (71%) (B) 0.48 (48%) (C) 0.25 (25%) (D) 0.86 (86%)
17. ,d vKkr ;kSfxd ty ds lkFk vfeJ.kh; gSA bldk Hkkih; vklou 98.0ºC ij gS o P = 737 Vksj]
Pº(H2O) = 707 Vksj gSA ;g vklou ty ds Hkkj dk 75% gSA vKkr dk v.kqHkkj ifjdfyr dhft,A
(A) M = 141.4 (B) M = 92.1 (C) M = 126.2 (D) M = 186.8
3. ,d xSl 'X' ds fuf'pr vk;ru dks ,d lw{e fNnz }kjk folfjr gksus esa yxk le; 2 feuV gSA leku ifjfLFkfr;kssa esa
vkWDlhtu xSl ds folj.k esa yxk le; 5.65 feuV gSA rc 'X' dk eksyj nzO;eku gSA .
(A) 8 (B) 4 (C) 16 (D) 32
4. H–ijek.kq (Z = 1) ds fy, cksgj d{kk dh f=kT;k yxHkx 0.53 Å gSA rc izFke mRrsftr d{kk voLFkk ds fy, f=kT;k
gksxhA
(A) 0.13 Å (B) 1.06 Å (C) 4.77 Å (D) 2.12 Å
+
5. pH = 13 ds 1cc foy;u esa H vk;uksa dh la[;k D;k gS \
(A) 6.023 × 107 (B) 1 × 10–13 (C) 6.023 × 1013 (D) 1 × 1016
6. H = – 176 kJ, S = – 284.5 JK–1 gS rks fdl rki ij vfHkfØ;k Lor% gksxh&
(A) 380 K (B) 480 K (C) 580 k (D) 680 K
7. ,d 0.1 A dk lksfM;e ,flVsV dk foy;u cuk;k tkrk gSA ftldh Kh = 5.6 × 10–10 gSA lgh dFku gS&
(A) ty vi?kVu dh ek=kk 7.48 × 10–4 gSA (B) [OH–] = 7.48 × 10–5 gSA
(C) [OH–] = 7.48 × 10–6 M gSA (D) pH yxHkx 7 ds cjkcj gSA
8. ;fn 25ºC ij ¶yksjkbM vk;u ds fy, pKb dk eku 10 gS] rks bl rki ij ty esa gkbMªks¶yksfjd vEy dk vk;uu
fLFkjkad gksxk&
(A) 10–5 (B) 10–3 (C) 10–4 (D) 10–2
9. vfHkfØ;k Fe2O3(s) + 3CO(g) 3CO2(g) + 2 Fe() ds fy,] fuEu esa ls dkSulk lR; gS&
(A) Hº = Eº + 3RT (B) Hº = Eº + RT (C) Hº = Eº (D) Hº = Eº RT
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10. fuEu esa ls fdl izØe esa ,UVªkWih esa deh vkrh gS %
(A) Bksl dk nzo esa ifjorZu (B) ,d xSl dk izlkj
(C) fØLVy dk ty esa foys; gksuk (D) cgqyhdj.k (E) H2 dk leka'k fo[k.Mu
11. ,d rRo Z dh izFke rhu Øekxr vk;uu ÅtkZ;s Øe'k% 900, 1757 rFkk 14850 kJ mol–1 gSA rRo Z lEcfU/kr gS %
(A) oxZ-1 ls (B) oxZ-2 ls (C) oxZ-15 ls (D) oxZ-17 ls
12. (i) Br2 + 2NaOH [BaMk] NaBr + (X) + H2O
(ii) 2Br2 + 6NaOH [xeZ] NaBr + (Y) + H2O
X rFkk Y esa Br dk vkWDlhdj.k vad Øe'k% gS \
(A) +1, +7 (B) +1 , +5 (C) +4, +5 (D) +3, +5
13. fuEu esa ls fdldh mifLFkfr ds dkj.k] lksfM;e /kkrq dk nzo veksfu;k esa foy;u] çcy vipk;d gksrk gS %
(A) lksfM;e ijek.kq (B) lksfM;e gkbMªkbM (C) lksfM;e ,ekbM (D) foyk;fdr bysDVªkWu
14. lkj.kh-I dks lkj.kh-II ls lqesfyr dhft, rFkk fn;s gq;s dksM dk mi;ksx djrs gq, lgh mÙkj p;fur dhft,A
lkj.kh-I lkj.kh-II
A. (SiH3)3N 1. f=kdsUnzh; nks bysDVªkWu ca/k
B. BF3 2. sp3-ladj.k
C. SiO2 3. p–p ca/k
D. B2H6 4. p–d ca/k
A B C D A B C D
(A) 4 2 1 2 (B) 2 3 2 1
(C) 1 2 3 4 (D) 4 3 2 1
15. cksjsDl dk ,d tyh; foy;u gS %
(A) mnklhu (B) mHk;/kehZ (C) {kkjh; (D) vEyh;
gksrk gS rFkk fooZr [YbI6]4– vk;u j[krk gS tks tyh; foy;uksa esa fo;ksftr ugha gksrk gSA
f}yo.k foy;u esa lHkh O;fDrxr (individual) vk;uksa dk èkukRed ijh{k.k ns ldrs gSaA ijUrq] ladqy yo.k O;fDrxr vk;uksa
dk èkukRed ijh{k.k ugha ns ldrs gSA
f}yo.k rFkk ladqy yo.k ds eè; Hkze dks nwj djus ds fy,] ladqy vk;u ;k Hkkx dks xq: dks"Bd [ ] esa fy[krs gaSA
f}yo.k ds mnkgj.k: feujy MksyksekbV: CaMg(CO3)2;
eksj yo.k : (NH4)2SO4·FeSO4·6H2O
dkusZykbV : KCl.MgCl2·6H2O
iksVk'k ,ye : K2SO4·Al2(SO4)3·24H2O i.e. KAl(SO4)2·12H2O
,ye : f}yo.k dk lokZfèkd lkekU; mnkgj.k ,ye gSA ,ye~ f}d~ lYQsV yo.k gksrs gSaA ftudk lkekU; lw=k
AM(SO4)2·12H2O gS] tgk¡ A ,dd la;ksth èkuk;u tSls K ;k Na gS rFkk M, f=kla;ksth èkkrq èkuk;u tSls Al ;k Cr gSA
5. fu"dkflr xSl dh ijek.oh;rk D;k gksxh tc 'osr QkLQksjl dh dkfLVd lksMk ds lkFk fØ;k djkbZ tkrh gS \
6. v.kq lw=k NanAlnSi94O192 esa n dk eku gS %
7. vkorZ lkj.kh esa 18 oxZ (group) gSA fta+d (Zn) ds ,d leLFkkfud (isotope) ij U;wVªkWu (neutron) ls ceckjh
(bombardment) djus ij uhps fn[kkbZ x;h ukfHkdh; vfHkfØ;k (nuclear reaction) gksrh gS ftleas rRo X izkIr gksrk
gSA rRo X vkorZ lkj.kh ds fdl lewg esa gS\ 3064
Zn 10 n X 2 11 H
8. fuEu ds fy, IUPAC uke fyf[k,&
(a) Na2[Fe(CN)5NO] (b) [Ni(DMG)2] (c) NH4[Cr(SCN)4(NO)2] (NO is nitrosyl)
(d) [Pd(H2O)2 I2(ONO)2] (e) [Co(NH3)4 Cl(NCS)]+ (f) K4[FeO4]
(g) K2[Co(N3)4] (h) [Ni(PPh3)2Cl2] (i) [Cr(acac)3] (j) [Pt(C5H5N)4][PtCl4]
9. fuEu IUPAC ukeksa ds laxr izR;sd ds lajpuk lw=k dks fyf[k,&
(a) gSDlk,Dokvk;ju(II) DyksjkbM (b) iksVSf'k;eVsVªk¶yksjkbMksvtsZUVsV (III)
(c) isUVkDyksjkbMksVkbVusV(II) vk;u (d) VsªVk,EehuMkbDyksjkbMksdksckYV (III) DyksjkbM
(e) Mkblk;ukbMks-C-vtsZUVsV(I) vk;u (f) Mkb,EehuVsVªkDyksjkbMksfudysV(II) vk;u
(g) fVªl~ (,FkkbyhuMkb,ehu)dkWij (II) lYQsV (h) lksfM;eMkb,DokVsVªkgkbMªkWDlkbMks,Y;qfeusV (III)
(i) ,EehuDyksjkbMksfcl~(,FkkbyhuMkb,ehu~)Øksfe;e (III) lYQsV (j) iksVSf'k;eVsVªklk;ukbMks-C-ftadsV(II)
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(SO4)2
MkbZ-m-gkbMªksDlkbMksfcl(VªsVk,Dokvk;ju(III)) lYQsV
mnkgj.k:
(SO4)2
4+
NH3 NH3
H3N O2 NH3
12. Co Co
H3N N NH3
H3N H2 H3N
;fn nksuksa dksckYV vk;u +3 vkWDlhdj.k voLFkk j[krs gaS rks mDr ladqy esa lsrq fyxs.M gksxkA
(A) ,ekbM rFkk MkbZvkWDlhtu (B) ,ekbM rFkk ijkWDlkbM
(C) ,ekbM rFkk lqijkWDlkbM (D) ,ehu rFkk ijkWDlkbM
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13. ;fn nksuks dksckYV vk;u leku vkWDlhdj.k la[;k j[krs gaS rks [(NH3)5Co–NH2–Co(NH3)5](NO3)5 dk IUPAC uke
gS
(A) -,ehuksfcl(isUVk,EehudksckYV(III)) ukbVªsV (B) -,ekbMksfcl(isUVk,EehudksckYV(III)) ukbVªsV
(C) -,ekbMksfcl(isUVk,EehudksckYV(III)) isUVkukbVsªV (D) MkbZ--,ekbMksfcl(isUVk,EehudksckYV(III)) ukbVsªV
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+
10. fuEu esa ls fdldks ikuh esa ?kksyus ij [H ] vk;u dh lkUnzrk vf/kdre gksxhA ;fn lcds eksy cjkcj gks &
(A) LiOH (B) NaOH (C) KOH (D) RbOH
11. ,d DyksjkbM B.Ms ikuh es ?kqy tkrk gSA tc bls IysVhue ¼platinum½ ds rkj ij j[kdj cqUlsu Tokyk esa xeZ djrs
gS rks dksbZ jax izkIr ugh gksrk gSA og /kuk;u gS&
(A) Ca2+ (B) Mg2+ (C) Ba2+ (D) Pb2+
12. DoFkkukadekih (ebullioscopic) vuqekiu ds nkSjku dkSuls foyk;d dk mi;ksx djuk vPNk gSA
(A) mPp Kb (B) fuEu Kb (C) Kb = Kf (D) Kf < Kb
14. fuEu esa ls dkSu {kkjh; e`nk /kkrqvksa ds ty;ksftr vk;u dh f=kT;k ds ?kVrs gq, lgh Øe dks n'kkZrk gS%
(A) Be2+ (aq) > Mg2+ (aq) > Ca2+ (aq) > Sr2+ (aq) > Ba2+ (aq)
(B) Ba2+ (aq) > Sr2+ (aq) > Ca2+ (aq) > Mg2+ (aq) > Be2+ (aq)
(C) Be2+ (aq) > Mg2+ (aq) > Ca2+ (aq) > Ba2+ (aq) > Sr2+ (aq)
(D) Ba2+ (aq) > Sr2+ (aq) > Mg2+ (aq) > Ca2+ (aq) > Be2+ (aq)
15. fuEu ladqy ds uke rFkk lw=k ds ;qXeksa esa ls dkSulk ;qXe lgh ugha gS \
(A) VsVªk,EehudkWij(II) lYQsV............. [Cu(NH3)4]SO4
(B) MkbZ,EehuflYoj(I) DyksjkbM................ [Ag(NH3)2]Cl
(C) iksVsf'k;e gsDlklk;ukbMks-C-QsjsV(II) ............... K4[Fe(CN)6]
(D) iksVsf'k;e ,EehuisUVkDyksjkbMksIysfVusV (II) ................. K[Pt(NH3)Cl5]
16. fuEufyf[kr iztkfr;ksa] NF3, BF3, PF5 rFkk [SiF6]2– esa dsUnzh; ijek.kq ds ladj.k dk lgh Øe gS :
(A) sp2, sp3, sp3d2, sp3d (B) sp3, sp2, sp3d, sp3d2
(C) sp2, sp3, sp3d, sp3d2 (D) sp3, sp2, sp3d2, sp3d3
17. fuEu esa ls fdrus v.kq@vk;u f}narqd fyxs.M dh rjg O;ogkj dj ldrs gS \
CO32– NH2 – CH2 – COO– EDTA4– C2O42– SO42–
CH3COCHCOCH3– CH3C N SCN¯ DMG
18. P4 ds ,d v.kq dh] NaOH ds lkFk fo"kekuqikru vfHkfØ;k esa] NaOH ds fdrus v.kq vfHkd`r gksrs gS \ .............. .
19. vk/kqfud vkorZ lkj.kh ds pth oxZ ls lEcfU/kr ,d rRo dks Une çrhd ls çnf'kZr fd;k tkrk gS rFkk ,d rRo ftldh
bySDVªkWu xzg.k ,UFkSYih ¼eqDr ÅtkZ½ mPpre gSA bldk ijek.kq Øekad q gSA rc (q –p) dk eku Kkr dhft;s\
20. ,d cQj foy;u dks ,d nqcZy vEy HA (Ka = 10–6) ds lkFk blds yo.k NaA dks leku eksyj ek=kk esa feykdj
cuk;k tkrk gSA 180 ml cQj foy;u dks cukus ds fy, vEy o yo.k ds fdrus ehyheksy feykus pkfg;s\ ftlesa ;fn
bl cQj foy;u ds 1 L esa 0.1 eksy izcy vEy feykus ij pH esa bdkbZ ifjorZu gksrk gS ?
21. 300 K ij ,d [kqys ik=k esa fd;k x;k dk;Z dk ifjek.k (dSyksjh esa) ifjdfyr dhft,] tc 112 xzke vk;ju] ruq HCl
ds lkFk fØ;k djrk gSA (vius mÙkj dks 100 ls Hkkx nsdj iznf'kZr djsaA)
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
1. ,d ok.Mj oky xSl ds 1 eksy ds fy, tc a = 0 gS rks fuEu esa ls dkSulk vkjs[k lgh gS@gSa \
(T = fu;r) (T = fu;r) (P = fu;r) (P = fu;r)
P P T T
2. CCl4 o ,lhVksu ,d dkWij ik=k esa dejs ds rki ij ,d vu-vkn'kZ foy;u cukrs gSA bl izØe ds fy, lgh dFku gS@gSa %
(A) G /kukRed gksrk gSA (B) Sfudk; /kukRed gksrk gSA
(C) Sifjos'k < 0 (D) H > 0
H2O
Li + H2 A B+C
5.
(gas)
AlH3
D
(A) A vipk;d dh rjg dk;Z djrk gSA (B) C vuqpqEcdh; xSl gSA
(C) D ladqy ;kSfxd gSA (D) B {kkj gSA
B
6. ,d xSl iFk rFkk }kjk A ls C voLFkk esa ifjorZu ls lEcfU/kr gSA ;fn 5 C
N
P 2
iFk ds fy, U 2J gS rc iFk esa xSl }kjk vo'kksf"kr Å"ek (twy esaKkr m
3 A
dhft;sA
1 2 V(m3)
7. ladqyks [Fe(H2O)5(NO)]2+ rFkk [Fe(CN)5(NO)]2– esa vk;ju dh vkWDlhdj.k voLFkk;sa Øe'k% x rFkk y gSA rc
(x + y) cjkcj gS&
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
8. MkbZcksjsu veksfu;k ls vfHkfØ;k djds (A) ds ?kus 'osr /kwe nsrk gSA dejs ds rki ij (A) Bksl gSA nkc dh mifLFkrh
esa xeZ djus ij] ;g ngu'khy xSl eqDr djds nzo (B) mRikfnr djrk gS o vUrr% ,d lQsn Bksl (C) nsrk gSA (C)
ds v.kqlw=k esa dqy gkbMªkstu ijek.kqvksa dh la[;k gS&
9. tc 25ºC ij AB dsk ty esa ?kksydj lUr`Ir foy;u cuk;k tkrk gS rks DoFkukad esa mé;u 2 × 10–4 ºC gksrk gS rFkk
AB dk Ksp 4 × 10–x gSA rc x dk eku fu/kkZfjr dhft, (ekfu, = 1, eksyyrk eksyjrk
(fn;k gS Kb = 0.5 K/m.)
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
;g fp=k leku /kkrq fyxs.M la;kstu ds fy, prq"Qydh;] v"VQydh;] prq"ddks.kh; o oxZ leryh; T;kferh;ksa esa d-d{kdksa
ds fØLVy {ks=k foikVu dks n'kkZrk gSA
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
15. fuEu esa ls dkSulk lEcU/k lgh ugha gS ?
(A) o < t (B) o (9/4)t (C) sp > t (D) sp = 1.30
16. lgh dFku dk p;u dhft,A
(A) prq"Qydh; {ks=k esa z2 ,xy dh vis{kk mPp ÅtkZ j[krs gSaA
(B) oxZlery {ks=k esa foikVu] prq"Qydh; {ks=k esa foikVu ls de gksrk gSA
(C) oxZ lery {ks=k esa ikap d-d{kdksa dk] nks fHkUu ÅtkZ ryksa esa foikVu gksrk gSA
(D) v"V Qydh; {ks=k esa t2g d{kd] eg d{kdksa dh vis{kk fuEu ÅtkZ j[krs gSaA
17. oxZlery {ks=k esa dkSuls d-d{kd vf/kdre ÅtkZ j[krs gS?
(A) x2 – y2 (B) z2 (C) xy (D) yz
18. dk ifjek.k fuHkZj djrk gSA
(A) /kkrqvksa dh vkWDlhdj.k voLFkk ij (B) /kkrq dh izd`fr ij
(C) /kkrq dks ?ksjs gq, fyxs.Mksa dh la[;k ij (D) fyxs.M ds lkeF;Z ij
1. CsBr(s) ds foy;u dh ,UFkSYih 10 kJ mol1 gS ;fn Cs+ (g) rFkk Br– (g) dh ty;kstu ,UFkSYih Øe'k% 475 rFkk
655 kJ.mol gS] rc CsBr(s) dh tkyd ÅtkZ kJ.mol1 esa D;k gksuh pkfg;s \
(A) 1120 (B) 1130 (C) 1140 (D) 1150
2. vfHkfØ;k xVO + yFe2O3 FeO + V2O5 esa x o y ds eku Øe'k% fuEu gSA
(A) 1, 1 (B) 2, 3 (C) 3, 2 (D) buesa ls dksbZ ugh
3. 225 xzke ty esa NaCl dh fdruh ek=kk foys; dh tkuh pkfg, fd izkIr foy;u dk DoFkukad] 225 xzke ty esa 20
xzke Xywdkst (M – 180) rFkk 30 xzke lwØkst (M – 342) j[kus okys foy;u ds leku gksrk gS (Na – 23, Cl – 35.5)
(A) 5.8 (B) 11.6 (C) 12.3 (D) buesa ls dksbZ ugha
4. ,d lkE; vfHkfØ;k A(g) + B (g) C (g), H =+ ve ds fy,] rkieku esa o`f) fuEu esa ls fdldk dkj.k gksxkA
(A) Keq ds eku esa o`f) dkA
(B) Keq ds eku esa deh dkA
(C) Keq ds eku esa dksbZ ifjorZu ugha gksxkA
(D) Keq esa ifjorZu dk tks fd xq.kkRed :i ls ifjdfyr ugha fd;k tk ldrk gSaA
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
+
5. gkbMªkstu ijek.kq dh ykbeu Js.kh dh lcls NksVh rjaxnS/;Z 'x' gS] rc He ds ckej Js.kh dh lcls yEch rjaxnS/;Z gSA
9x 36x x 5x
(A) (B) (C) (D)
5 5 4 9
6. 4°C ij ikuh dk ?kuRo 1.0 × 103 kg m–3 gSA ikuh ds ,d v.kq }kjk ?ksjk x;k yxHkx vk;ru gS&
(A) 3.0 × 10–23 mL (B) 6.0 × 10–22 mL (C) 3.0 × 10–21 mL (D) 9.0 × 10–23 mL
7. He dk lEihM~;rk xq.kkad gS
(A) vk;ru ds lkFk js[kh; :i ls c<rk gqvkA (B) nkc ds lkFk js[kh; :i ls c<rk gqvkA
(C) 1 ds cjkcj (D) nkc ds lkFk js[kh; :i ls ?kVrk gqvkA
8. fuEu vfHkfØ;k lkE; ij nh x;h gS %
N2(g) + 3H2 (g) 2NH3 (g)
fu;r vk;ru ij blesa dqN vfØ; xSl feyk;h x;hA fuEu esa ls] mu rF;ksa dks crkb;s] tks dh çHkkfor gksaxs %
(A) NH3(g) vf/kd mRiUu gksrh gSA (B) NH3(g) de mRiUu gksrh gSA
(C) lkE; ij vfHkfØ;k o`f) dh ek=kk (degree of advancement of the reaction) çHkkfor ugha gksrh gSA
(D) vfHkfØ;k ds Kp esa o`f) gksrh gSA
9. ijek.kq esa izksVkWu] U;wVªkWu o bysDVªkWu mifLFkr gksrs gS ;fn U;wVªkWu dk nzO;eku mlds okLrfod eku dk vk/kk rFkk
bysDVªkWu dk nzO;eku mlds okLrfod eku dk nqxuk eku fy;k tk;s rks C612 dk ijek.kq Hkkj gksxkA
(A) nqxuk (B) 75% de (C) 25% de (D) mlds okLrfod eku dk vk/kk
10. fuEu esa ls dkSulk la;kstu ;ksxt (adduct) cukus ds fy, vf/kdre izo`fr j[krk gS \
(A) BF3 + NH3 (B) BCl3 + NH3 (C) BBr3 + NH3 (D) B3 + NH3
11. fuEu lHkh ladqy vk;u vuqpacq dh; ik, x, gSa &
P : [FeF6]3– ; Q : [CoF6]3– ; R : [V(H2O)6]3+ ; S : [Ti(H2O)6]3+
buds vuqpaqcdh; vk?kw.kksZ ¼dsoy pØ.k½ dk lgh Øe gS &
(A) P > Q > R > S (B) P < Q < R < S (C) P = Q = R = S (D) P > R > Q > S
3+
12. v"VQydh; {ks=k esa Cr ds fy;s fØLVy&{ks=k foikVu] I , H2O, NH3 , CN fyx.Mksa ds fy;s c<rk gS] bldk Øe gS
– –
(A) I– < H2O < NH3 < CN– (B) CN– < I– < H2O < NH3
(C) CN– < NH3 < H2O < I– (D) NH3 < H2O < I– < CN–
13. fuEu esa ls fdl foU;kl esa] fyxs.M dh izd`fÙk ij fuHkZj djrs gq,] vuqpqEcdRo o izfrpqEcdRo nksuksa dh lEHkkouk gksxh&
(A) d7 (B) d3 (C) d6 (D) d5
14. og ladqy] ftlds fy, vo'kks"k.k LisDVªe dks tkudj cgqr vklkuh ls fØLVy {ks=k foikVu dk ifjdyu fd;k tk
ldrk gSa] gksxk&
(A) [TiCl6]2– (B) [Fe(H2O)6]2+ (C) [Ti(CN)6]3– (D)[CoF6]3–
15. fuEu ladqyksa ds fy, CFSE (vkafdd eku) dk lgh Øe gS &
ladqy P Q R S
lw=k [CoF6]3– [Co(CN)6]3– [Co(NH3)6]3+ [Co(H2O)6]3+
(A) P > Q > R > S (B) Q > R > S > P (C) S > R > P > Q (D) R > Q > P > S
16. dFku-1 : pfØ; izØe (cyclic process) ds fy, U = 0
dFku-2 : tc ra=k esa ifjorZu (change of state) gksrk gS rc gh dk;Z rFkk Å"ek lkFkZdrk j[krs gSaA
(A) dFku&1 lR; gS] dFku&2 lR; gS; dFku&2, dFku&1 dk lgh Li"Vhdj.k gSA
(B) dFku&1 lR; gS] dFku&2 lR; gS; dFku&2, dFku&1 dk lgh Li"Vhdj.k ugha gSA
(C) dFku&1 lR; gS] dFku&2 vlR; gSA
(D) dFku&1 vlR; gS] dFku&2 lR; gSA
17. fo|qr HkV~h esa 2273-3273 K rki rd dSfYle vkWDlkbM dks dksd ds lkFk xeZ djus ij cus dSfYl;e ;kSfxd dk
jklk;fud lw=k gksxk
(A) Ca2C (B) CaC2 (C) CaCO3 (D) Ca(OH)2
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
18. ghjs rFkk Qqyjhu (C60) esa dkcZu ijek.kq dh ladfjr voLFkk,¡ Øe'k% gS
(A) sp3 o sp2 (B) sp2 o sp3 (C) sp3 o sp (D) nksuksa esa sp3
19. 0.21 g dkcZfud ;kSfxd ds ngu ij 0.308 g CO2 xSl izkIr gksrh gSA ;kSfxd esa dkcZu dh izfr'krrk gS
(A) 40% (B) 4% (C) 14.67% (D) 13.5%
20. vkf.od d{kd fl)kUr ds vuqlkj O2, O2 , O2– rFkk O2–
2 ds LFkkf;Ro dk lgh Øe gSA
21. lQsn QkWLQksjl (P4) v.kq esa fdrus P-P ,dy ca/k mifLFkr gSA
22. ,d milgla;ksth ladqy dh leUo; la[;k N% gS] bldk lw=k CoCl3.5NH3.H2O gSA fo|qr pkydrk ekiu ,d lw=kh;
bdkbZ esa rhu vk;uksa dh mifLFkfr bafxr djrh gSA ladqy ds ,d eksy dks AgNO3 ds lkFk mipkfjr djus ij AgCl
ds fdrus eksy vo{ksfir gksxsa \
23. ,d ra=k esa] tgk¡ E = – 15 kJ gS ,d fiLVu] 1.2 atm ds ckg~; nkc ds fo:) izlkfjr gksdj] 75 lt dk vk;ru esa
ifjorZu n'kkZrk gS bl ra=k ds fy, Å"ek esa ifjorZu dk ifjek.k D;k gS \ (1 lt atm = 100 J).
24. nks 'kq) nzoks A rFkk B dk ok"i nkc Øe'k% 5 rFkk 10 Vksj gS] rc 2 eksy A rFkk 3 eksy B ds lfEeJ.k ls izkIr foy;u
dk dqy nkc (Vksj) ifjdfyr dhft,A
25. vkDlhtu ds lUnHkZ esa A dk vkisf{kd ?kuRo 1/4 gSA xSl A ds ,d v.kq dk nzO;eku (amu esa) D;k gksxkA
DPP No. # A11 (REVISION DPP)
Total Marks : 61 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.9 (3 marks, 2 min.) [27, 18]
Multiple choice objective ('–1' negative marking) Q.10 to Q.12 (4 marks, 2 min.) [12, 06]
Comprehension ('–1' negative marking) Q.13 to Q.14 (3 marks, 2 min.) [06, 04]
Numerical value Questions ('0' negative marking) Q.15 to Q.18 (4 marks, 3 min.) [16, 12]
1. rhu foy;uksa A, B o C ds fy, ok"i nkc o rki ds chp oØ fn;s x;s gSaA tc
ok"i&nkc 1 atm ds cjkcj gks tkrk gS] rks ;g rkieku foy;u ds DoFkukad ds :i esa
tkuk tkrk gSA
lkUnzrk A, B o C dk lgh Øe fuEUk gS] ;fn A, B o C ds fy, i dk eku leku gksa %
(A) A > C > B (B) B > A > C
(C) C > A < B (D) C > A > B
2. 300 K ij nks 'kq) nzo X rFkk Y, tks ,d vkn'kZ foy;u cukrs gS ds ok"i nkc Øe'k% 200 rFkk 300 mm Hg gSA X
rFkk Y ds ,d nzo foy;u] ftlesa X dh eksy fHkUu 0.5 gS dks ,d fiLVu ;qDr can ik=k eas] fy;k x;k gS bl fiLVu
ij nkc ifjofrZr gks ldrk gS %
(A) dsoy ;fn foy;u ds Åij nkc 200 torr ls de gks] rHkh ok"i voLFkk vfLrRo esa gks ldrh gSA
(B) dsoy ;fn foy;u ds Åij nkc 300 torr ls de gks] rHkh ok"i voLFkk vfLrRo esa gks ldrh gSA
(C) dsoy ;fn foy;u ds Åij nkc 200 torr ls vf/kd gks] rHkh nzo voLFkk vfLrRo eas gSA
(D) dsoy ;fn foy;u ds Åij nkc 250 torr ds cjkcj vFkok de gks rHkh ok"i voLFkk vfLrRo esa gks ldrh gSA
3. nks nzoksa A(pº = 80 mm) o B(pº = 120 mm) ds foy;u dk ok"i nkc 100 mm ik;k x;k] tc xA = 0.4 gSA ifj.kke
n'kkZrk gS fd
(A) foy;u vkn'kZ O;ogkj iznf'kZr djrk gSA
(B) foy;u /kukRed fopyu n'kkZrk gSA
(C) foy;u _.kkRed fopyu n'kkZrk gSA
(D) foy;u fuEu lkanzrk ds fy, /kukRed rFkk mPp lkaUnzrk ds fy, _.kkRed fopyu n'kkZrk gSaA
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4. fuEu esa ls fdl feJ.k }kjk jkÅYV fu;e ls /kukRed fopyu dks n'kkZ;k tkrk gS :
(A) csUthu o VkWyqbu (B) CHCl3 o ,lhVksu (C) ,FksukWy o ty (D) HCl o ty
5. xUuk 'kdZjk ds ,d 10% w/w foy;u dk fuEu vfHkfØ;k ds vuqlkj vkaf'kd izfriu gksrk gSA
lqØksl + ty Xywdksl + ÝDVksl
foy;u dk DoFkukad 100.7°C gSA
'kdZjk ds fHkUu dk izfriu D;k gksrk gS \
Kb (H2O) = 1.8 K.kg/mol.
(A) 0.5 (B) 0.2 (C) 0.3 (D) 0.4
7. ,d vkn'kZ xSl ds 1 eksy dks ,d ok;qe.My ds fu;r ckâ; nkc ij 300K ls 400K rd xeZ fd;k x;k ;fn
Cv,m 21.686 103 T J / molK gS rc izØe ds fy, H gS %
(A) 3000 (B) 3035 (C) 3350 (D) 30350
9. dkWye-I dks dkWye-II ds lkFk lqesfyr dhft,] rFkk ladj.k ds izdkj ds lanHkZ esa uhps fn;s x;s dksM dk mi;ksx djrs
gq;s lgh mÙkj dk p;u dhft,A
dkWye- I dkWye- II
(ladqy) (ladj.k)
2–
(I) [Ni(CN)4] (p) dsp2 ladj.k
(II) [Cu(CN)4]3– (q) sp3 ladj.k
(III) [Co(C2O4)3]3– (r) sp3d2 ladj.k
(IV) [Fe(H2O)5NO]2+ (s) d2sp3 ladj.k
dksM %
(I) (II) (III) (IV) (I) (II) (III) (IV)
(A) q p r s (B) p q s r
(C) p q r s (D) q p s r
10. ,d vkn'kZ xSl ij fuEu esa fdl çØe esa] fudk; dh ,UVªkWih esa o`f) gksrh gS %
(A) mRØe.kh; lerkih çlkj (B) vuqRØe.kh; :)ks"eh; laihMu
(C) lerkih eqDr çlkj ¼fuokZr ds fo:)½ (D) mRØe.kh; :)ks"eh; çlkj
11. lEHkou dh ekud ,UFkSYih ds lanHkZ esa fuEu esa ls dkSulk dFku lgh gS \
(A) ;g lnSo _.kkRed gksrh gSA
(B) ekud voLFkk esa ,d eksy ;kSfxd ds fy, Kkr djrs gSA
(C) ekud voLFkk esa lHkh Lih'kht ds fy, 'kwU; gksrh gSA
(D) 'osr QkWLQksjl ds fy, 'kwU; gksrh gS] tks fd QkWLQksjl dk U;wure LFkk;h :i gSA
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
12. fuEu rU=k dk voyksdu dhft,&
rhu fHkUu tyh; foy;u] izR;sd dk vk;ru 100 ml ysrs gS rFkk fp=k esa fn[kk, vuqlkj lEidZ es j[krs gSaA
i;kZIr le; ds i'pkr~ (rki fu;r rFkk izcy oS|qr vi?kV~; dk 100% fo;kstu ekurs gq,)
100
(A) ;wfj;k foy;u dk vk;ru ml gksxkA
3
400
(B) AlCl3 foy;u dk vk;ru ml gksxkA
3
(C) KCl foy;u ds vk;ru es dksbZ ifjorZu ugha gksxkA
(D) KCl rFkk AlCl3 nksuks foy;uksa dk vk;ru c<+sxkA
vuqPNsn #
vkn'kZ xSl ds ,d izkn'kZ dks fuEu nks izØeksa esa iz;qDr fd;k tkrk gS %
izØe-I : 300 K rFkk 10 atm ij 4.4 xzke vkn'kZ xSl (v.kqHkkj = 44) dks 1 atm fu;r ckÐ; nkc ds fo:) lerkih;
:i ls izlkfjr fd;k tkrk gSA
izØe-II : vc 1 atm nkc ij izØe-1 ds i'pkr~ izkIr xSl izkn'kZ dks 10 atm fu;r ckÐ; nkc ds fo:) lerkih; :i
ls laihfM+r fd;k tkrk gSA 1 Latm = 100 J ysdj, fuEu iz'uksa ds mÙkj nhft, %
13. xSl }kjk izØe-I esa vo'kksf"kr Å"ek fuEu gS %
(A) 200.5 KJ (B) 212.5 J (C) 221.4 J (D) 242.4 J
14. fuEu esa ls dkSulk dFku xyr gS %
(A) izØe-I esa xSl }kjk fd;k x;k dk;Z] izØe-II esa ifjos'k }kjk fd;k x;k dk;Z dh rqyuk esa de gksrk gSA ¼ifjek.k ls½
(B) izØe-I esa xSl }kjk vo'kksf"kr Å"ek] izØe-II esa xSl }kjk eqDr dh xbZ Å"ek dh rqyuk esa de gksrh gSA ¼ifjek.k ls½
(C) xSl izkn'kZ ij izØe-I o II ds iw.kZ :i ls gksus ds i'pkr~ fudk; o ifjos'k nksuksa viuh okLrfod voLFkk esa iqu% vk
tkrs gSaA
(D) buesa ls dksbZ ugha
15. C – Cl ca/k (kJ/mol) dh ca/k ,UFksYih Kkr dhft,A fn;k x;k gS %
C2H6(g) + Cl2(g) C2H5 Cl(g) + HCl (g) H = –117 KJ/mol
Cl – Cl = 242 kJ/mol
C – H = 412 kJ/mol
H–Cl = 431 kJ/mol
viuk mÙkj 10 ls Hkkx nsdj nhft,A
B
(1.5Pa,2m )
–3
16. fp=k esa n'kkZ;s vuqlkj 1 mol vkn'kZ xSl mRØe.kh; izØe iznf'kZr djrh gSA izØe
A
P(pascal)
esa fd;s x;s dk;Z dh x.kuk (twy esa) dhft;s [ln 2 = 0.7] (1Pa,1m–3)
vius mÙkj dks 10 ls xq.kk djds nsA
1
(m –3)
V
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
17. fuEu esa ls fdruh vfHkfØ;k,¡ ;k izØe Å"ek{ksih gS@gSa \
(i) 2H(g) H2(g) (ii) C(ghjk) C(xzsQkbV) (iii) CH4 + O2 CO2 + H2O (iv)
C2H6 C2H4(g) + H2(g) (v) lei{k-2-C;wfVufoi{k-2-C;wfVu (vi) lQsn P yky P.
(vii) H2O() H2O(s) (viii) Na+(g) + aq Na+(aq)
(ix) NaOH + H2SO4 Na2SO4 + H2O (x) HNO3 + ty foy;u (xi) ,FksukWy + ty foy;u
18. ,d xSl 'X' 1.5 atm dqy nkc ij ty nzo ij lar`Ir ty ok"i ds lkFk 'X' dk
vkaf'kd nkc
mifLFkr gSA leku rki ij H2O dk ok"i nkc 0.5 atm gSA 10 eksy <+ky = 38 × 105 torr
H2O() esa fefyeksyksa ds inks esa xSl 'X' dh foys;rk D;k gS \
( nH2O nx )
H2O esa 'X' dk eksy fHkUu
DPP No. # A12 (JEE-ADVANCED)
Total Marks : 72 Max. Time : 44 min.
Multiple choice objective ('–1' negative marking) Q.1 to Q.6 (4 marks, 2 min.) [24, 12]
Numerical value Questions ('0' negative marking) Q.7 to Q.12 (4 marks, 3 min.) [24, 18]
Match the Following (no negative marking) Q.13 (8 marks, 6 min.) [08, 06]
ChemINFO: 4 Questions ('–1' negative marking) Q.14 to Q.17 (4 marks, 2 min.) [16, 08]
1. lgh dFku@dFkuksa dk p;u dhft,s&
(A) ge nkc dks iz;qDr dj ok"i dks ljyrk ls la?kfur dj ldrs gSA
(B) xSl dks nzohd`r djus ds fy, rkieku dks Tc ls de djuk pkfg, rFkk lkFk gh nkc Hkh iz;qDr djuk pkfg,A
(C) Tc ij] nzo rFkk ok"i voLFkk esa dksbZ foHksn ugha gksrk gS vr% nzo dk ?kuRo] ok"i ds ?kuRo ds yxHkx cjkcj jgrk gSA
(D) buesa ls dksbZ ugha
2. AOH rFkk BOH dk leeksyj foy;u rS;kj fd;k x;kA A rFkk B dk vk;uu foHko Øe'k% 5.1 rFkk 13.0eV gSA A rFkk
B dh fo|qr _.kkRedrk 0.9 rFkk 3.2 gSA bu vadks ds vk/kkj ij lR; dFku@dFkuksa dk p;u djsaA
(A) BOH dk ?kksy lksfM;e dkcksZusV ds lkFk cqncqnkgV iSnk djrk gSaA
(B) fQukW¶Fksyhu AOH ds ?kksy ds lkFk xqykch jax çnku djrk gSaA
(C) BOH dk ?kksy PH > 7 nsrk gSA
(D) NH4Cl AOH ds lkFk mipkfjr djus ij ;g veksfu;k fu"dkflr djrk gSA
3. gjs jax dk ladqy K2[Cr(CN)4(NH3)(NO)] vuqpcq dh; gS rFkk bldk vuqpqcdh; vk?kw.kZ ¼dsoy pØ.k½ 1.73 B.M. gSA
fuEu esa ls blds lanHkZ esa D;k lgh gS@gSaA
(A) bldk IUPAC uke iksVSf'k;e ,EehuVsVªklk;uksukbVªkslksfu;eØksesV () gSA
(B) Øksfe;e dh ladj.k voLFkk d2sp3 gSA
(C) ;g ca/ku leko;ork iznf'kZr dj ldrk gSA
(D) ;g T;kferh; leko;ork iznf'kZr ugha dj ldrk gSA
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6. fuEu esa ls fdldk vfLrRo ugha gS \
(A) SH6 (B) HFO4 (C) FeI3 (D) HClO3
7. 0.12 M, 50 ml nqcZy vEy foy;u dks 0.06 M, 50 ml NaOH ds lkFk vuqekfir djus ij izkIr foy;u dh pH Kkr
dhft,] nqcZy vEy dk fo;kstu fu;rkad 2 10–2 gSA viuk mÙkj 10 ls xq.kk djds nhft,A
8. 0.01 eksyy tyh; CH3COOH ds fgekad dk voueu 0.0198ºC gSA 1 eksyy ;wfj;k foy;u –1.8ºC ij terk gSA
eksyjrk dks eksyyrk ds cjkcj ekurs gq, CH3COOH foy;u dh pH gS&
9. fuEu esa ls fdrus dFku lgh gS@gSa \
(a) gsDlkdkcksZfuyØksfe;e(0) d2sp3 ladfjr vkSj izfrpqEcdh; gksrk gSA
(b) d6, fuEu pØ.k] v"VQydh; ladqy es v;qfXer bysDVªkWuksa dh la[;k 2 gSA
(c) [Ag(NH3)2]Cl vuqpEq cdRo ugh n'kkZrk gSA
(d) /kkrq vk;u dk fuEu vkos'k ?kuRo /kkrq vk;u ladqy ds LFkkf;Ro dks c<+krk gSA
(e) Qsjkslhu ,sjksesfVd ;kSfxd gSA
(f) Qsjkslhu es vk;ju dh vkWDlhdj.k voLFkk +3 gSA
(g) /kkrq dkcksZfuy [Mn(CO)6]+, [Cr(CO)6] dh vis{kk izcy C–O ca/k j[krk gSA
(h) ladqy [Co(CN)6]3–, ladqy [Co(H2O)6]3+ dh vis{kk o dk vf/kd eku j[krk gSA
(i) ,tkbM vk;u mHk;nUrqd fyxs.M gSA
(j) K2[PtCl6] dk IUPAC uke iksVsf'k;e gsDlkDyksjkbMksIysfVue(IV) gSA
10. mRiknksa [X] o [Y] esa mifLFkr lHkh S ijek.kqvksa ds O;fDrxr (individual) vkWDlhdj.k vadksa dk dqy ;ksx---------------- gSA
11. [Cr(NO3)3 (NH3)3] ds fy, f=kfoe leko;oh dh la[;k = x
K3[CoCl2(C2O4)2] ds fy, f=kfoe leko;oh dh la[;k = y
[CoBrCl(en)2] ds fy, f=kfoe leko;oh dh la[;k = z
x + y + z Kkr dhft,A
12. tc 'osr QkLQksjl (P4) dkfLVd lksM+k foy;u ds lkFk fØ;k dj PH3 o NaH2PO2 cukrk gSA tc vfHkfØ;k dks
lUrqfyr fd;k tkrk gS rks P4, dkfLVd lksM+k PH3 o NaH2PO2 ds jllehdj.kferh; xq.kkadksa dk ;ksx x gS] x Kkr
dhft,A
13. feyku dhft, %
dkWye-I dkWye-II
A. [Cr(NH3)6]3+ (p) d2sp3
B. [Co(en)3]3+ (q) CFSE = – 1.2 0
C. [Co(NO2)6]4– (r) vuqpEq cdh;
D. [Co(H2O)6]2+ (s) sp3d2
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lkr fØLVy ra=k
fØLVy ra=k v{kh; varjky v{kh; dks.k mnkgj.k ,dd~ dksf"Bdk ds izdkj
?kuh; a=b=c = = = 90° Cu, ZnS, KCl S,BCC,FCC
f}leyack{k a=b c = = = 90° Sn('osr fVu), SnO2,TiO2 S,BC
fo"keyack{k a b c = = = 90° jkWfEcd lYQj, CaCO3 S,BCC,FCC,ECC
,durk{k a b c = = 90°; 90° ,durk{k lYQj, PbCrO2 S,BCC
"kV~dks.kh; a=b c = = 90°; = 120° xzsQkbV, ZnO S
f=kleurk{k a=b=c = = 90° CaCO3(dsYlkbV), HgS(flusckj) S
f=kurk{k a b c 90° K2Cr2O7, CuSO4.5H2O S
c
?kuh; ; f}leyack{k c
; fo"keyack{k ; ,durk{k ;
b c
b c
b
a a a
b
a
c
c c
"kV~dks.kh; ; f=kleurk{k ; f=kurk{k
b
b
a a
b
a
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
14. ,d fn, x, fØLVy ds fy, tkyd çkpky a = 8.42 Å, b = 8.42 Å rFkk c = 9.80 Å gSA muds funsZ'kh; v{k ,d
nwljs ds vU;ksU; :i ls yEcor gSaA fØLVy fuEu gSA
(A) f}leyack{k (B) fo"keyack{k (C) ,durk{k (D) f=kdks.kh;
15. fØLVy foek a = b c ; = = 90º = 120º çnf'kZr djrh gSA
(A) f}leyack{k (B) "kV~dks.kh; ra=k (C) ,durk{k (D) fo"keyack{k
17. fups fn;s x;s ,dd dksf"Bdkvksa esa ls fdles a lokZf/kd leferrk gS \
(A) "kV~dks.kh; (B) fo"keyEck{k (C) ?kuh; (D) ,durk{k
a
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2. ladqy [PtCl2(NH3)(OH2)] ds lanHkZ esa fuEu esa ls dkSulk@dkSuls dFku lR; gS@gSaA [Pt dk ijek.kq Øekad = 78]
(A) blds lei{k o foi{k nks T;kferh; leko;oh gksaxsA (B) ;g ,d oxZ leryh; ladqy gSA
(C) ;g ,d izfrpqEcdh; ladqy gSA (D) ;g gkbMªsV leko;ork iznf'kZr dj ldrk gSA
4. ;kSfxd Na2IrCl6] VªkbZQsfuyQkWfLQu ds lkFk] MkbZ,fFkyhu Xykbdksy esa rFkk CO ds okrkoj.k esa vfHkd`r gksdj
[IrCl(CO)(PPh3)2] nsrk gSA ;g ;kSfxd *okWLdks ;kSfxd* ('Vaska's compound') dgykrk gSA
(Ir dk ijek.kq Øekad = 77 gSA)
fuEu esa ls dkSulk@dkSuls dFku lgh gS@gSa ?
(A) ladqy dk IUPAC uke] dkcksZfuyDyksjhMksfcl¼VªkbZQsfuyQkWfLQu½bZfjMh;e (I) gSA
(B) /kkrq vk;u dk ladj.k sp3 gSA
(C) ladqy dk pqEcdh; vk?kw.kZ ¼dsoy pØ.k½ 'kwU; gSA
(D) ladqy T;kferh; leko;ork ds lkFk&lkFk vk;uu leko;ork Hkh n'kkZrk gSA
5. Bkslks esa =kqfV;ksa ds lanHkZ esa dkSulk@dkSuls dFku lgh gS@ gSaA
(A) lkekU;r% 'kkSVdh =kqfV] /kuk;u rFkk _.kk;uksa ds vkdkj esa cgqr de vUrj ds dkj.k gksrh gSA
(B) 'kkSVdh =kqfV ds dkj.k Bkslksa ds ?kuRo esa deh vkrh gSA
(C) ;kSfxd ftuesa F-dsUnz mifLFkr gksrs gSa] og izfrpqEcdh; gksrs gaSA
(D) Ýsady =kqfV ,d izdkj dh LFkku ifjorZu (dislocation) =kqfV gSA
6. jkWd lkYV fØLVy ds fy,] fuEu esa ls dkSulk@dkSuls dFku lgh ugha gS@ gSaA
(A) ;fn 'kkWVdh =kqfV }kjk lHkh dk; dsUnzhr Na+ vk;uksa dks i`Fkd dj fn;k tk;s rc] ;kSfxd dk lw=k Na3Cl4 gksxkA
(B) ;fn ,dkUrfjr prq"Qydh; fjfDr;ksa esa] Na+ vk;u mifLFkr gks rc] ;kSfxd dk lw=k Na2Cl gksxkA
(C) ;fn lksfM;e ok"i dh mifLFkfr esa] tkyd ls dqN Cl– vk;uksa dks foLFkkfir dj fn;k tk;s rc] ;kSfxd dk jax
ifjofrZr gks tk;sxkA
(D) ;fn fØLVy esa vUrjvk;fud nwjh 4.2 Å gS] rc bdkbZ dksf"Bdk dh dksj yEckbZ 8.4 Å ds cjkcj gksxhA
8. N% (six) Si–O–Si cU/ku ;qDr flfydkWu R3Si–(OSiR2)n–SiR3 izkIr djus ds fy, R2SiCl2 dh x bdkbZ o R3SiCl dh
y bdkbZ yh tkrh gSA (x + y) dk eku gS&
9. ,d H ds leku Lih'kht dk izkn'kZ fdlh mÙksftr voLFkk 'A' esa gS rFkk 10.2 eV ÅtkZ dk ,d QksVkWu vo'kksf"kr djds
u;h voLFkk B esa tkrh gSA tc voLFkk 'B' ls bysDVªkWu izR;{k ;k vizR;{k :i ls (directly or indirectly) vk| voLFkk esa
ykSVdj vkrs gS rks fofHkUu rjaxnS/;Z ds 15 QksVkWu izsf{kr gksrs gS ftuesa ls dsoy 9 QksVkWu 10.2 eV ls vf/kd ÅtkZ
j[krs gSaA H ds leku Lih'kht dk ijek.kq Øekad Kkr djksA viuk mÙkj 7 ls xq.kk djus ds i'pkr~ nhft;sA
10. ,d :afMr prq"Qyd (truncated tetrahedron) esa mifLFkr "kV~Qyd o f=kdks.kh; Qyd dh la[;k dk ;ksx gS %
11. 0.1892 mol kg–1 KCN ;qDr ,d tyh; foy;u dk fgekad 0.70°C gSA Hg(CN)2 ds 0.09 eksy dks mijksDr foy;u
ds 1kg esa feykus ij foy;u dk fgekad –0.53°C ik;k x;kA Ekkukfd fuEu lehdj.k ds vuqlkj ladqy curk gS %
Hg(CN)2 X(CN) [Hg(CN)X 2 ] X
X Kkr dhft, (fn;k gS % ty dk Kf = 1.86K/molal):
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12. vkWxZu fcc O;oLFkk esa fØLVyhd`r gksrk gS rFkk Bksl rFkk nzo vkxZu ds ?kuRo Øe'k% 1.59 g cm– 3 rFkk 1.42 g
cm–3 gSa rks nzo Ar esa fjDr LFkku dk izfr'kr ¼yxHkx½ Kkr dhft,A
13. feyku dhft, %
dkWye I dkWye II
A. 74% ladqy {kerk ¼izfr'kr ?kuRo½ (p) ¶yksjkbV lajpuk esa /kuk;u dh leUo; la[;k
B. leUo; la[;k -8 (q) ?kuh; fufcM ladqyu
C. CaF2 esa Ca2+ vk;u (r) "kV~dks.kh; fufcM ladqyu
D. leUo; la[;k – 12 (s) dk; dsUnzh; ?kuh; ladqyu
Anion Cation
ZnS çdkj % ZnS esa /kuk;u o _.kk;u dh f=kT;k 0.40 gS tks bls vkd`fÙk dksa prq"Qydh; crkrh gSA çR;sd Zn2+ vk;u pkj
S2– vk;uksa }kjk prq"Qydh; :i ls f?kjk gksrk gS o çR;sd S2– vk;u pkj Zn2+ vk;uksa }kjk prq"Qydh; :i ls f?kjk gksrk
gSA vFkkZr ZnS dh leUo; la[;k 4 gSA bl çdkj ;g lajpuk 4 : 4 O;oLFkk j[krh gS] ;g /;ku nsus ;ksX; gS fd ftUd Cys.M
(ZnS) dh ccp ljapuk j[krk gSA tcfd oqVZtkbV (ZnS) hcp j[krk gSA vU; mnkgj.k CuCI, CuBr, CuI, o BeS gSA
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
14. ftUd Cys.M ljapuk esa ftUd vk;u ,dkUrfjr] prq"Qydh; fjfDr;ksa ls f?kjk gksrk gS o S2– vk;u ccp dsa :i esa
gksrk gSA Zn2+ o S2– vk;uksa dh f=kT;k Øe'k% 0.83 Å o 1.74 Å gaSA ZnS ,dd~ dksf"Bdk ds fy, dksj yEckbZ fuEu gSA
(A) 2.57 Å (B) 5.14 Å (C) 5.93 Å (D) 4.86 Å
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+
15. ;fn NaCl fØLVYk esa Na o Cl vk;uksa ds fy, nwjh ‘a’ pm gS] rks dksf"Bdk dh dksj yEckbZ D;k gS \
–
17. ftUd Cys.M ljapuk esa S2– ccp O;oLFkk o Zn2+ vk;u
(A) v"VQydh; O;oLFkk j[krs gSA (B) "kV~dks.kh; O;oLFkk j[krs gSA
(C) prq"Qydh; O;oLFkk j[krs gSA (D) dksbZ ugha j[krs gSA
3. vkWDlhtu dk Økafrd rki 154K rFkk Økafrd nkc 50 atm fn;k x;k gSA fuEu esa ls dkSuls dFku lR; gSa\
I. 154K rFkk 50 atm ij ,d cUn ik=k esa, vkWDlhtu dh Bksl] nzo rFkk xSl voLFkkvksa esa lkE;koLFkk gksxhA
II. vkWDlhtu xSl dks dejs ds rki ij nzfor fd;k tk ldrk gSA
III. ;g dgk tk ldrk gS fd veksfu;k dk ØkfUrd rki 154 K ls vf/kd gSA
(A) I lR; gS (B) II rFkk III lR; gS (C) III lR; gSA (D) I rFkk III lR; gSA
4. v.kq XF4 ds f}/kqzo vk?kw.kZ dk eku v'kwU; gS] rc X gS :
(A) Xe (B) Si (C) S (D) buesa dksbZ ugha
5. fuEu esa ls dkSUk NaOH ds lkFk vfHkfØ;k djds ,d xSl eqDr djrk gSA
(A) S8 (jksgfEcd lYQj) (B) Cl2
(C) P4 (lQsn QkLQksjl) (D) C (xzsQkbV)
6. ,d inkFkZ CO2 dks vo'kksf"kr djrk gS rFkk 'kh?kzrk ls ty ds lkFk vfHkfØ;k djrk gSA inkFkZ gS
(A) CaCO3 (B) CaO (C) H2SO4 (D) ZnO
7. 4 g X (ijek.oh; nzO;eku = 40), tks BCC O;oLFkk esa fØLVyhÑr gksrk gS] esa ,dd dksf"Bdkvksa dh dqy la[;k gS &
(NA = vkoksxknzks la[;k)&
0.1 NA
(A) 0.1 NA (B) 2 × 0.1 NA (C) (D) 2 × NA
2
8. BaCl2, NaCl ,oe~ Xywdksl ds leeksyj foy;ukas ds ijklj.k nkc dk Øe gSA
(A) Xywdksl > NaCl > BaCl2 (B) BaCl2 > NaCl > Xywdksl
(C) NaCl > BaCl2 > Xywdksl (D) NaCl > Xywdksl > BaCl2
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10. fuEu esa ls dkSulk ladqy lcls T;knk leko;oh j[krk gS \
(A) [Co(NH3)4Cl2] (B) [Ni (en)(NH3)4]2+ (C) [Ni(C2O4)en2]2– (D) [Cr(SCN)2(NH3)4]+
11. Cr rFkk Fe ds ijek.kq Øekad Øe'k% 24 o 26 gSaA bysDVªkWu ds çpØ.k ds lkFk dkSulk vuqpqEcdh; gS\
(A) [Cr(CO)6] (B) [Fe(CO)5] (C) [Fe(CN)6]4– (D) [Cr(NH3)6]3+
12. IUPAC ukedj.k ds vuqlkj] lksfM;e ukbVªksizwlkbM dk uke gS :
(A) lksfM;e ukbVªksQSfjlk;ukbM (B) lksfM;e ukbVªksQSjkslk;ukbM
(C) lksfM;e isUVklk;ukbMksukbVªkslksfu;eQSjsV (II) (D) lksfM;e isUVklk;uks ukbVªksflyQSjsV (III)
14. fuEu esa ls dkSulk ladqy mPpre vuqpEq cdh; O;ogkj çnf'kZr djrk gS \
tgk¡, gly = Xykblhu, en = ,fFkyhuMkbZ,ehu rFkk bpy = ckbZikbZjhfMy lewg)
(ijek.kq la[;k Ti = 22, V = 23, Fe = 26, Co = 27)
(A) [V(gly)2(OH)2(NH3)2]+ (B) [Fe(en)(bipy)(NH3)2]2+
(C) [Co(OX)2(OH)2]– (D) [Ti(NH3)6]3+
15. fuEu esa ls dkSulk ladqy vk;u n`'; izdk'k dks vo'kksf"kr ugha djrk gS \
(A) [Ni(CN)4]2– (B) [Cr(NH3)6]3+ (C) [Fe(H2O)6]2+ (D) [Ni(H2O)6]2+
16. fuEu esa ls dkSulk ladqy ;qXe izdkf'kd leko;ork n'kkZrk gS \
(A) lei{k-[Cr(C2O4)2Cl2]3–, lei{k-[Co(NH3)4Cl2] (B) [Co(en)3] Cl3 ,lei{k-[Co(en)2Cl2]Cl
(C) [PtCl(dien)Cl] , [NiCl2Br2]2– (D) [Co(NO3)3(NH3)3], lei{k-[Pt(en)2Cl2]
17. ;kSfxd [Ir(en)2(NH3)(NO2)]2+ ds fy, lHkh laHko leko;oh;ksa ¼lajpukRed rFkk f=kfoe leko;oh½ dh la[;k Kkr
djksA
18. Si2O5 n2n esa izfr SiO44 bdkbZ lkWf>r vkWDlhtu ijek.kqvksa dh dqy la[;k gS &
19. ;fn pH = 2 rFkk pH = 4 ds nks foy;uksa dks Øe'k% 1 : z ds vk;ru vuqikr esa fefJr fd;k x;k ifj.kkeh foy;u dk
pH = 2.75 ik;k x;kA rc z dk eku Kkr dhft;s \ (fn;k gS : log 1.75 = 0.25)
20. xSlh; H2, Cl2 rFkk HCl dh cU/k fo;kstu ÅtkZ Øe'k% 104, 58 rFkk 103 kcal mol–1 gSA HCl xSl ds fy, lEHkou dh
,UFkSYih ifjdfyr dhft,A
21. v"VQyd esa dksuksa dh la[;k fdruh gksxh\
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leku fn'kk esa f)/kzqo JO; o n`'; nksuksa
pqEcdh; {ks=k dh vuqifLFkfr esa Hkh lajsf[kr gksrs gSA
ykSgpqEcdh; Fe, Ni, CO, CrO2 esa CrO2 ç;qDr
LFkk;h pqEcdRo
gksrk gSA
;g gksrk gS tc leku o foijhr MnO, MnO2, Mn2O,
çfrykSgpqEcdh; lajs[k.k ds dkj.k tc f}/kzqo FeO, FeO2; NiO, -
vk?kw.kZ 'kwU; gksrk gSA Cr2O3, CoO, CO3O4
;g gksrk gS tc ifj.kkeh f}/kzqo FeO3O4 (Magnetite),
y?kqykSgpqEcdh; ferrites like MgFe2O4, -
vk?kw.kZ gksA ZnFe2O4
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
22. fuEu esa ls dkSulk fodYi lgh gSA
(A) O2 çfrpqEcdh; xq.k/keZ n'kkZrk gSA (B) S çfrpqEcdh; xq.k/keZ n'kkZrk gSA
(C) TiO2 çfrpqEcdh; xq.k/keZ n'kkZrk gSA (D) VO2 çfrpqEcdh; xq.k/keZ n'kkZrk gSA
1. 'kq) voLFkk esa 100 Vksj ok"i nkc j[kus okyk nzo A, 50 Vksj rFkk 25 Vksj ok"i nkc n'kkZrk gS] tc bldh fLFkj ek=kk
dks Øe'k% nzo B rFkk nzo C dh fuf'pr ek=kk esa ?kksyk x;kA A dk ok"i nkc D;k gksxk] tc nksuksa foy;uksa dks fefJr
fd;k tkrk gS\ (vkn'kZ feJ.k ekus)
(A) 37.5 Vksj (B) 75 Vksj (C) 12.5 Vksj (D) 33.3 Vksj (E) 25 Vksj
D B
D B
C C
Arrangement of atoms
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blds leku Qydks ds fdukjksa ds e/; fcUnqvksas dks tksM+ dj izkIr ,d ry ABCD ds ijek.kqvksa dh O;oLFkk fuEu
izdkj gS% ekuk p ladqyu n{krk gSA lgh fodYi dk p;u fdft;sA
22 11 11 11 3
(A) n = 1 , p = (B) n = 8 , p = (C) n = 8, p = (D) n = 1 , p =
21 2 21 14 28
4. ;fn PCl3 (g) rFkk PH3 (g) ds lEHkou dh Å"ek Øe'k% 140 rFkk 8 KJ eksy–1 gSa rFkk QkWLQksjl P4(s), Dyksjhu rFkk
gkbMªkstu ds ijek.oh;dj.k dh Å"ek Øe'k% 320, 120 rFkk 216 KJ eksy–1 gSa] rks fuEu esa ls dkSulk@dkSuls dFku
lgh gS@gSa\
(A) P–Cl dh ca/k ÅtkZ 63 KJ mol–1 gSA
(B) P–H dh ca/k ÅtkZ 210 KJ mol–1 gSA
(C) foyfxr xSlh; gkbMªkstu ijek.kq ds laHkou dh Å"ek 108 KJ mol–1 gSA
(D) foyfxr xSlh; Dyksjhu ijek.kq ds laHkou dh Å"ek 60 KJ mol–1 gSA
5. 1 atm ij ,d lhyc) ¶ykLd esa fufgr ,d eksy vkn'kZ xSl dks 27ºC ls 127ºC rd xeZ fd;k tkrk gSA
(fn;k gS : S(JK–1) = 10 + 12× 10–3 T, R = 0.082 atm L/mol K, 1 atm L = 101.3 J) lgh foDYi@fodYiksa dk
p;u dhft,&
(A) V = 12.3 L (B) vfUre nkc 4/3 atm gSA
(C) G = –589.34J (D) G = 322.5 J
vuqPNsn #
la;kstdrk ca/k fl)kUr esa] d{kdksa dk ladj.k ca/k fuekZ.k dk ,d egRoiw.kZ Hkkx gSA lad j.k esa **'kq)** ijekf.o;
d{kdksa dk lfEeJ.k vFkok js[kh; la;kstu bl izdkj gksrk gS fd ftlds }kjk u;s ladfjr d{kd curs gSa] tSls sp,
sp2, sp3, sp3d, sp3d2 bR;kfnA
vc fuEufyf[kr iz'uksa ds mÙkj nhft, %
6. fuEu esa ls dkSulk@dkSuls ijekf.o; d{kd f=kdks.kh; f}fijkfefM; ladj.k vFkkZr~ sp3d ladj.k esa Hkkx ysrs gS@gSa ?
(I) dZ2 (II) d (III) dxy (IV) pz
x2 –y2
7. fuEu esa ls dkSuls ijekf.o; d{kd [Pt(NH3)4]+2 ds lkFk&lkFk [Cr(CN)6]3– ds ladj.k esa Hkh Hkkx ysrs gSa \
(I) s (II) d (III) d (IV) px
x2 –y2 z2
(A) III, IV (B) I, III, IV (C) I,II,III, IV (D) I, II, IV
8. pKb1 = 5.2 o pKb2 = 16.7 ds N2H4 ,d f}izksfVd {kkj gSA N2H62+(Cl–)2 dk 0.1 M tyh; foy;u pH (yxHkx)
................. j[krk gSA (fudVre iw.kkZad dks pqfu;s)
2R
9. f=kT;k R ds N% leku xksyksa dks fp=k esa n'kkZ, vuqlkj fizTe ds izR;sd dksus ij O;ofLFkr
fd;k tkrk gSA bldk ladqyu izHkkt x gS] rc 10x gS &
2R
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2
10. 1 cm vuqizLr dkV {ks=kQy ;qDr ,d le:i ufydk dks ,d fljk v)ZikjxE; f>Yyh ls can gSaA ufydk esa] izfr
100 ml , 6 xzke Xywdksl ;qDr foy;u Hkjk tkrk gS rFkk ;g ufydk 27C ij 'kq) ty esa j[kh tkrh gSA tc lkE;
LFkkfor gksrk gS rc] ijklj.k nkc (ehVj esa) D;k gS (m)Zokgj dkWye dh izkIr ÅpkbZ ds :i esa ) Xywdksl foy;u dk
?kuRo 1 gm/ml gSA (fyft;s R = 0.08 L atm mol–1 k–1, Hg dk ?kuRo = 13.8 g/cc)
11. ladqy [CoL2Cl2]– ds fy, lEHko leko;oh;ksa dh la[;k (vlefer f}nUrqd fyxs. M L = H2NCH2CH2O–) gksxh&
12. ,d tyh; foy;u essa Øe'k% nqcZy vEy (HA) rFkk ;wfj;k Hkkj ds vuqlkj 6% rFkk 4% lfEefyr gSA ;fn fgekad esa
13.6
voueu ºC gSA ;fn HA dk Ka, x gS] rks 100x dk eku Hkfj;sA [Kf = 1.8 K-Kg/mole] (HA dk v.kqHkkj = 60,
3
dfoy;u = 1gm/ml). ekuk HA rFkk ;wfj;k ds e/; vfHkfØ;k ugha gksrh gSA
3. fuEu esa ls fdu v.kqvksa esa dsUnzh; ijek.kq esa v"V~d dk izlkj gksrk gS \
(A) PCl5 (B) SO4– – (C) NH3 (D) ClO3–
4. bySDVªkWu] izksVksu rFkk d.kksa ds fy, MhczksXyh rjaxnS/;Z dk xq.kkRed Øe e > P > gSa] ;fn&
(A) lHkh d.kksa ds fy, xfrt ÅtkZ leku gksa
(B) lHkh d.kksa ds fy, Rofjr foHkokUrj 'V' leku gksa ¼fojkeoLFkk ls½
(C) lHkh d.kksa ds fy, osx leku gksa ]
(D) mijksDr esa ls dksbZ ugha
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5. ,d yhVj ik=k esa ,d lkE; A(g) 2B(g) LFkkfir gSA lkE;koLFkk ij A ds eksYl rFkk B ds eksYl leku (çR;sd
ds 2 eksy) ik;s x;s gaSA vc fLFkj rki ij ;fn vfHkfØ;k ik=k dk vk;ru vk/kk dj nsa rFkk lkE;koLFkk iqu% LFkkfir
gksus nh tk;s rks fuEu esa ls dkSulk@dkSuls dFku lR; gSa ?
(A) ubZ lkE;koLFkk esa A rFkk B dh lkUnzrk Øe'k% 4.5 M rFkk 3 M gSaA
(B) vk;ru dks vk/kk djus ij lkE; vxz fn'kk esa foLFkkfir gksxkA
(C) vk;ru dks vk/kk djus ij lkE; i'p fn'kk esa foLFkkfir gksxkA
(D) vk;ru dks vk/kk djus ij lkE; fdlh Hkh fn'kk esa foLFkkfir ugha gksxk D;ksafd çkjfEHkd lkE; esa A rFkk B ds eksy
leku (çR;sd ds 2 eksy) gaSA
6. ,d ?kuh; dksf"Bdk esa A ijek.kq dksuks ij mifLFkr gS tcfd Qyd dsUnzks ls A ijek.kq yqIr gSA B ijek.kq dksj dsUnz
rFkk dk; dsUnz ij gSA C ijek.kq izR;sd lw{e ?ku (dksj yEckbZ a/2) ds dk; dsUnz ij mifLFkr gSA rc lgh
dFku@dFkuksa dk p;u dhft,& (a = dksj yEckbZ ?ku)
(A) ;kSfxd dk lw=k ABC2 gSA
(B) ;fn ,d dk; fod.kZ ds vuqfn'k lHkh ijek.kqvksa dks gVk nsrs gS] rks ifj.kkeh lajpuk esa A,B,C ijek.kq dk vuqikr
1 : 4 : 8 gSA
(C) ,d lw{e ?ku esa A,B,C ijek.kq (izHkkoh) dk vuqikr 1 : 4 : 8 gSA
(D) lw{e ?ku esa dsoy ik¡p dksus f?kjs gq, gSA
7. 0.01 eksyy tyh; CH3COOH foy;u ds fgekad dk voueu 0.02046° gSA ,d eksyy tyh; ;wfj;k foy;u
–1.86°C ij terk gSA ekuk fd eksyyrk eksyjrk ds cjkcj gS rc CH3COOH foy;u dh pH Kkr dhft;sA
8. fuEufyf[kr esa ls fdrus ;kSfxdksa @ feJ.kksa ds tyh; foy;u dh pH, foy;u dks ruq djus ij Hkh fu;r jgrh gS %
(1) NH4Cl
(2) Na2CO3
(3) Na2S rFkk HCl dk 1 : 2 eksyj vuqikr dk ,d feJ.k
(4) NaOH rFkk H3PO4 dk 5 : 2 eksyj vuqikr dk ,d feJ.k
(5) CH3COONa rFkk HCl dk 5 : 4 eksyj vuqikr dk ,d feJ.k
(6) NaH2PO4
(7) HCl rFkk NaHCO3 dk 2 : 1 eksyj vuqikr dk ,d feJ.k
(8) CH3COONH4
(9) NH4OH rFkk HCl dk 4 : 3 eksyj vuqikr dk ,d feJ.k
500
9. ,d vok"i'khy rFkk vuoS|qrvi?kV; foys; ds m tyh; foy;u dks ,d cUn ik=k es fy;k tkrk gSA lkE; ij
81
ik=k ds vUnj mifLFkr vkisf{kd vknzZrk izfr'kr ifjdfyr dhft,A
10. fuEu esa ls fdruh Lih'kht esa dsUnzh; ijek.kq nks ,dkdh bysDVªkWu ;qXe j[krk gS \
XeF4 XeF5– F2SeO2 XeF3+ XeOF4 ClOF3
ICl4– SCl2 OSF4
11. tfVy lw=k [Co(NH3)3(NO2)2Cl] ds fy, ;
dsUnzh; ijek.kq dh leUo; la[;k = a
dsUnzh; ijek.kq dk vkWDlhdj.k vad = b
T;kehfr; leko;oksa dh dqy la[;k ¼lHkh lajpukRed leko;oksa dks ysrs gq,½ = c
izdk'kh; leko;oksa dh dqy la[;k ¼lHkh lajpukRed leko;oksa dks ysrs gq,½ = d
fn;s x;s tfVy ds fy, (a + b - c+ d) dk eku gS&
12. fuEu v.kqvks ij fopkj dhft, : O2, Cl2, Li2, H2, B2, C2 rFkk N2
ekuk
a = (ca/k Øe = 1) j[kus okys v.kqvks dh la[;k b = (ca/k Øe = 2) j[kus okys v.kqvks dh la[;k
c = (ca/k Øe = 3) j[kus okys v.kqvks dh la[;k d = vuqpqEcdh; v.kqvks dh la[;k]
(a × b × c × d × 4.2) Kkr dhft,A
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13. feyku dhft,A
dkWye– I dkWye– II
(A) H+ (tyh;) (p) Hf0 = 0
(B) H (xSl) (q) Hf0 0
(C) H2 (xSl) (r) Gf0 = 0
(D) C (s, ghjk) (s) Hf0 > 0
ChemINFO ELECTROCHEMISTRY
Daily Self-Study Dosage for mastering Chemistry Topic: Galvanic Cell & Salt Bridge
og lSy ftls jsMkWDl vfHkfØ;k ls mRiUu jklk;fud ÅtkZ dks oS|qr ÅtkZ esa :ikUrfjr djus ds fy, iz;qDr fd;k tkrk gS ,d
oS|qr jklk;fud lSy ;k lkekU; jklk;fud lSy dgykrk gSA bUgsa Y;wxh XkSYosuh (1780) rFkk ,yslsUMªks oksYVk (1800) ds uke
ds i'pkRk~ xSYosfud lSy ;k oksYVsbZd lSy Hkh dgk tkrk gSA
;fn xsYosfud lSy esa bysDVªkWM vkUrfjd :i ls tqM+s gq, ugh gS rks izkjEHk esa lSy fo|qr ÅtkZ mRiUu djrk gSA bysDVªkWM le;
xqtjus ds lkFk&lkFk èkqzohd`r gksrk gS rFkk lSy dk;Z djuk can dj nsrk gSA lrr~ fo|qr ÅtkZ ds fy, bysDVªkWMksa dk vkUrfjd
:i ls tqM+k gksuk vko';d gksrk gSA
,d yo.k lsrq izk;% xsYosfud lSy ds bysDVªkWMksa dks tksMus ds fy, iz;qDr gksrk gSA ;g vklkuh ls cuk;k tk ldrk gS rFkk ,d
LoPN U ufydk esa tSy dk cuk gksrk gSA tSy dks KCl ds leku vfØ; fo|qr vi?kV~; okys ,d mcyrs gq, ty esa
vxkj&vxkj esa feykdj cuk;k tkrk gSA lkekU;r% KCl dks izkFkfedrk nh tkrh gS] D;ksa fd K+ rFkk Cl– dh vk;fud
pkydrk;sa izk;% leku gksrh gSA tSy fuEu fp=k esa n'kkZ;s vuqlkj ufydk esa bysDVªksMksa dks jksdrk gSA
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16. KNO3 dk lar`Ir foy;u yo.k lsrq cukus es iz;qDRk gksrk gS D;ksafd
(A) K dh xfr'khyrk NO3– dh rqyuk es vf/kd gksrh gSA
(B) NO3– dh xfr'khyrk Kdh rqyuk esa vf/kd gksrh gSA
(C) K rFkk NO3– dh xfr'khyrk yxHkx leku gksrh gSA
(D) KNO3 ty esa vf/kd foys;'khy gksrk gSA
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9. xSYosuhd lsy esa &
(A) jklk;fud vfHkfØ;k fo|qr ÅtkZ mRiUu djrh gS (B) fo|qr ÅtkZ jklk;fud vfHkfØ;k mRiUu djrh gS
(C) ,suksM+ ij vip;u gksrk gS (D) dSFkksM+ ij vkWDlhdj.k gksrk gS
10. dqN v)Z lsy vfHkfØ;kvksa ds fy, E° uhps fn;s x;s gSaA
Sn+4 + 2e– Sn2+ ; E° = 0.151 V
2Hg2+ + 2e– Hg2+2 ; E° = 0.92 V
PbO2 + 4H+ + 2e– Pb2+ + 2H2O ; E° = 1.45 V
fn;s x;s vkdMksa ds vk/kkj ij dkSulk dFku lgh gSA
(A) Sn4+ , Pb+4 dh rqyuk esa izcy vkWDlhdkjd gSA (B) Sn2+ , Hg22+ dh rqyuk esa izcy vipk;d gSA
(C) Hg2+ , Pb4+ dh rqyuk esa izcy vkWDlhdkjd gSA (D) Pb+2 , Sn2+ dh rqyuk esa izcy vipk;d gSA
Cr2O72 Fe3
11. bysDVªkWM A o B ls cus ,d lSy ds fy,] bysDVªkWM+ A : , Eºyky = + 1.33 V o bysDVªkWM+ B : ,
Cr 3 Fe2
Eºyky = 0.77 V gSA fuEu esa ls dkSulk okD; lgh ugh gS&
(A) tc la;ksftr fd;k tkrk gS] rks bysDVªkWu B ls A dh vksj ¼ckà; ifjiFk esa½ izokfgr gkssaxs A
(B) lsy dk ekud emf 0.56 V gksaxk A
(C) A /kukRed bysDVªkWM gksxkA
(D) buesa ls dksbZ ughaA
(B) E D / D2
= 'kwU; (298 K rki ij)
(C) ,d jsMkDl vfHkfØ;k gksrh gS ;fn vkWDlhdkjd ds SRP rFkk vipk;d ds SRP dk ;ksx ,d /kukRed ek=kk gS
(D) K2Cr2O7 (vEy)( KMnO4 (vEy) dh rqyuk esa izcyre vkWDlhdkjd gSA
[fn;k gS : EMnO /Mn2
= 1.51 V; E 2 – = 1.33 V]
–
4 Cr O 2 7 / Cr 3
13. leku rki ij Na2SO4 dk 0.004 M foy;u Xywdksl ds 0.010 M foy;u ds lkFk leijkljh gSA Na2SO4 dk
fdruk izfr'kr Hkkx fo;ksftr gksxk \
(A) 25% (B) 50% (C) 75% (D) 85%
14. KN3 ds 0.01 M foy;u esa eqDr HN3 dh lkUnzrk D;k gS ;fn Ka = 1.9 × 10–5 gSa %
(A) 2.3 mol/ML (B) 3.3 mol/ML (C) 4.3 mol/ML (D) 5.3 mol/ML
15. 0.01 eksyj MkbZDyksjksVsVªk,DokØksfe;e (III) DyksjkbM ds 100 mL foy;u esa AgNO3 dh vf/kdre ek=kk feykbZ xbZ gSA
AgCl ds vo{ksfir gksus okys eksyksa dh la[;k gksxh %
(A) 0.002 (B) 0.003 (C) 0.01 (D) 0.001
16. 1 kg nzO;eku dh ,d xsan] ftldh xfrt ÅtkZ 0.5 J gS] ds lkFk la;ksftr Mh czkWXyh rjax&nS/;Z fuEu gS %
(A) 6.626 10–34 m (B) 13.20 10–34m (C) 10.38 10–21 m (D) 6.626 10–34 Å
17. n`'; {ks=k esa vo'kksf"kr rjax}S/;Z ds fy, lgh Øe fuEu gS %
(A) [Ni(NO2)6]4– < [Ni(NH3)6]2+ < [Ni(H2O)6]2+ (B) [Ni(NO2)6]4– < [Ni(H2O)6]2+ < [Ni(NH3)6]2+
(C) [Ni(H2O)6]2+ < [Ni(NH3)6]2+ < [Ni(NO2)6]4+ (D) [Ni(NH3)6]2+ < [Ni(H2O)6]2+ < [Ni(NO2)6]4–
vuqPNsn #
fuEu vuqPNsn dks i<+dj rFkk iz'u 18 ls 20 rd ds mÙkj nhft,A ;g dsoy ,d lgh fodYi j[krs gSA
fofHkUu fudk;ksa ds eku vip;u foHko (SRP) dks ,d vfHkfØ;k dh Lorrk dks fu/kkZfjr djus esa iz;qDr fd;k tk
ldrk gS mnkgj.k ds fy, EZn 2 Zn = – 0.76V vr% Zn + 2H+ Zn2+ + H2 vfHkfØ;k ds fy, G° _.kkRed gS]
;g iz;ksfxd :i ls ik;k x;k gS fd tc (,d vkWDlhdkjd dk SRP– ,d vipk;d dk SRP) 1.7 V ls vf/kd gS]
rc ;g la;kstu foLQksfVr gks ldrs gSA ¼gkyk¡fd bls xfrdh dkjdks }kjk jksdk tk ldrk gS½
fuEu vk¡dM+kas ds vk/kkj ij iz'uksa ds mÙkj nhft,A
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vk¡dM+s : EAg /Ag = 0.80 V ; EN
2 /N3 ¯
= – 3.09 V
E = 1.23 V ;
ENa = – 2.71 V
ClO4¯ / ClO3 /Na
EFe3
/ Fe2
= 0.77 V ; EO2 / H2O2 = – 1.03 V
EH = 1.76 V ; EO 3 / O2
= 2.07 V
2O2 / H2O
EMnO /Mn2
= 1.54 V ; E = 1.33 V
–
4 Cr2O72 –
/ Cr 3
18. fuEu esa ls dkSulk vk;fud la;kstu foLQksVd inkFkZ ds fuekZ.k esa iz;qDr gksrs gS \
(A) lksfM;e vk;u rFkk ,tkbM vk;u (B) flYoj vk;u rFkk ijDyksjsV vk;u
(C) flYoj vk;u rFkk ,tkbM vk;u (D) mijksDr lHkh
19. H2O2 ds mRizsjdh; fo?kVu ds fy, fuEu esa ls dkSulk vk;u mi;qDr gksxk \
(A) Fe3+ (B) Fe2+ (C) nksuksa (D) buesa ls dksbZ ugha
1. okLrfod xSl ds fy, voLFkk lehdj.k nh x;h gS tgk¡ A rFkk B fu;rkad gSA P : nkc rFkk V : eksyj vk;ru
A 2B 1
PV = RT – Økafrd fcUnq ij Kkr dhft,A
V V2 Z
(A) 3 (B) 2 (C) 1 (D) buesa ls dksbZ ugha
2. tc ft;ksykbV] tks fd lksfM;e ,Y;qfefu;e lhfydsV gS dks dBksj ty ds lkFk mipkfjr djrs gS rc lksfM;e
vk;uks dk fofue; dkSuls vk;uks ls gksrk gSA
(A) H+ vk;u (B) Ca2+ vk;u (C) SO42– vk;u (D) Mg2+ vk;u
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3. Na dk nzo veksfu;k esa vR;Ur 'kq) ruq foy;u %
(A) uhyk jax n'kkZrk gSA (B) oS|qr pkydrk iznf'kZr djrk gSA
(C) lksfM;e ,ekbM cukrk gSA (D) gkbMªkstu xSl mRiUu djrk gSA
4. dqN v)Z lsy vfHkfØ;kvksa ds ekud vip;u foHko uhps fn, gSa &
PbO2 + 4H+ + 2e– Pb2+ + 2H2O Eº = 1.455 V
MnO4– + 8H+ + 5e– Mn2+ + 4H2O Eº = 1.51 V
Ce4+ + e– Ce3+ Eº = 1.61 V
+
H2O2 + 2H + 2e– 2H2O Eº = 1.71 V
lgh dFku dks pqfu;s &
(A) Ce+4, Pb2+ dks PbO2 esa vkWDlhd`r djsxk (B) MnO-4 , Pb2+ dks PbO2 esa vkWDlhd`r djsxk
(C) H2O2, Mn+2 dks MnO-4 esa vkWDlhd`r djsxk (D) PbO2, Mn+2 dks MnO- esa vkWDlhd`r djsxk
4
5. fuEu esa ls dkSuls dkjd oS|qr la;kstdrk dk leFkZu ugha djrs gSa \
(A) vk;u ij fuEu vkos'k (B) vk;u ij mPp vkos'k
(C) cM+k /kuk;u rFkk NksVk _.kk;u (D) NksVk /kuk;u rFkk cM+k _.kk;u
6. ,d gkbMªkstu leku Lih'kht esa izFke cksj d{kk ls f}rh; d{kk esa mRrstu ds fy, 40.8 eV dh ÅtkZ vko';d gSA
rc fuEu esa ls dkSulk@dkSuls dFku lgh gS@gSa %
(A) H- leku Lih'kht dk ijek.kq Øekad 2 gSA (B) H-leku Lih'kht dh vk;uu ÅtkZ 122.4 eV gSA
st
(C) 1 d{kk esa bysDVªkWu dh xfrt ÅtkZ 54.4 eV gSA (D) f}rh; d{kk dh ÅtkZ –13.6 eV gSA
10 m
7. xSl (P) rFkk (Q) Øe'k% gks ldrh gS&
(ijek.oh; nzO;eku% N = 14, B = 10.7, H = 1, O = 16,
Br = 80, As = 75) xSl (P) xSl (Q)
(A) H2, N2 (B) B2H6, NH3 M n`'; oy; dk izFke
(C) B2H6, AsH3 (D) NH3, HBr ¼e/; fcUnq½ izdVhdj.k(appearance)
9. ,d Li"V% fØLVyh; Bksl ds fy, (CP)m = aT3 gS tgk¡ a ] ,d fu;rkad gS ;fn 10K ij] (CP)m dk eku 0.375 J/K-
mol gS rc] 20K ij eksyj ,UVªksih dk eku (J/K-mol esa) Kkr dhft;sA
10. ,d nqcZy vEy HA ds 0.1 M foy;u dks 0.05 N NaOH foy;u ds fo:) vuqekfir fd;k tkrk gSA vEy ds 1/4th
rFkk 3/4th Lrj ij mnklhuhdj.k ds fy, pH dh x.kuk dhft,A fn;k gS fd 0.1 M HA foy;u dh pH 3 gSA
pH1 pH2
viuk mÙkj ds :i esa nsaA
2
11. vko`fÙk esa n'kkZ;s vuqlkj Nk;kafdr ryksa dh vksj fcc tkyd Hkkx dk voyksdu
dhft;sA vkÑfr esa bl izdkj dk ry n'kkZ;k x;k gSA ry DBF esa ijek.kqvksa dh
la[;k nhft;s tks /kkfRod fcc tkyd ds fcUnq ij ,d ijek.kq ds lkFk uhps lEidZ esa
j[ks x;s gSaA
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12. x.kuk dhft;ss (a) ,d ,dy{kkjh; vEy ds fy, Ka dk eku] ftlds 0.10 M foy;u dh pH 4.5 gSA
(b) ,d ,dyvEyh; {kkj ds fy, Kb dk eku] ftlds 0.10 M foy;u dh pH 9.7 gSA
viuk mÙkj 2Kb / Ka ds :i esa nhft;sA
13. feyku dhft,A
dkWye-I dkWye-II
(A) 74% ladqy {kerk ¼izfr'kr ?kuRo½ (p) ¶yksjkbV lajpuk esa /kuk;u dh leUo; la[;k
(B) leUo; la[;k-8 (q) ?kuh; fufcM ladqyu
(C) CaF2 esa Ca2+ vk;u (r) "kV~dks.kh; fufcM ladqyu
(D) leUo; la[;k – 12 (s) dk; dsUnzh; ?kuh; ladqyu
ChemINFO ELECTROCHEMISTRY
Daily Self-Study Dosage for mastering Chemistry Topic: lhlk
lapk;d lSy (lhlk&vEy cSVjh)
dkjksa esa iz;qDr lhlk lapk;d cSVjh dks loZizFke xSLVu IykUV }kjk foKku dh ÝSap vdsMeh }kjk 1860 esa iznf'kZr fd;k x;kA
blesa ukS lSy lekukUrj ry esa gksrs gSa rFkk ;g vk'p;Ztud :i ls vf/kd /kkjk igqapkus esa l{ke gksrk gSA lSy dks ¶ysuy] tks
10% H2SO4 foy;u esa Mwch gqbZ gS] dh ijrksa }kjk i`Fkd ysM ;k lhlk dh IysVksa ls cuk;k x;kA vis{kkd`r :i ls fudk; vc
lhlk&vEy cSVjh dgykrk gSA
lhlk lapk;d lSy esa LikWUth ysM ls Hkjh gqbZ ysM fxzM gksrh gS] tks ,uksM ds :i esa dk;Z djrh gS rFkk ysM vkWDlkbM ls
ladqfyr ysM fxzM dSFkksM ds :i esa dk;Z djrh gSA bl izdkj ds bysDVªkWM ;qXeksa dh la[;k (lkekU;r% N%) dks lY¶;wfjd vEy
foy;u (20%) esa Mwcksrs gSa] tks fo|qr vi?kV~; ds leku dk;Z djrh gS rFkk ;g vfØ; o fNfnzr Hkkxks }kjk i`Fkd gksrs gSaA
tc cSVjh dks fujkosf'kr djrs gSa rks PbO2 , PbSO4 esa vipf;r gksrk gSA tc bls vkosf'kr djrs gSa rks vfHkfØ;k O;qRØe gksrh
gSA v)Z vfHkfØ;k ds fy, ekud bysDVªkWM foHko 1.682 V gSA lSy vfHkfØ;k,a fuEu izdkj gS %
,uksM ij : Pb(s) + SO42– (aq) PbSO4(s) + 2e–
dSFkksM ij : PbO2(s) + 4H+ (aq) + SO42– (aq) + 2e– PbSO4(s) + 2H2O(I)
lEiw.kZ vfHkfØ;k: Pb(s) + PbO2(s) + 2H2SO4 (aq) 2PbSO4(s) + 2H2O(I)
lSy vfHkfØ;k n'kkZrh gS fd fo|qr vi?kV~; H2SO4 dk vfHkfØ;k ds nkSjku miHkksx gksrk gS vr% vfHkfØ;k lEiUu gksrh gS]
H2SO4 dh lkUnzrk ?kVrh gSA H2SO4 dh lkUnzrk fuf'pr Lohd`r Lrj rd de gksrh gSA cSVjh dks fujkos'ku vfHkfØ;k ds
O;qRØe }kjk iqu% vkosf'kr djus dh vko';drk gksrh gSA blds fy, lSy foHko ls mPp ckáre foHko iz;qDr fd;k tkrk gSA
ckn esa lSy ,d oS|qr vi?kV~; lSy ds leku lapkfyr gksrk gS rFkk bysDVªkWM ij fu{ksfir PbSO4 fuEu vfHkfØ;kvksa }kjk Pb
rFkk PbO2 eas cnyrk gS :
,uksM ij : PbSO4(s) + 2H2O(I) PbO2(s) + 4H+ (aq) + SO42– (aq) + 2e–
dSFkksM ij : PbSO4(s) + 2e– Pb(s) + SO42–(aq)
lEiw.kZ vfHkfØ;k: 2PbSO4(s) + 2H2O(I) Pb(s) + PbO2(s) + 4H+ (aq) + 2SO42–(aq)
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
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14.ysM vEy cSVjh ds vkos'ku ds nkSjku dSFkksM+ vfHkfØ;k esa gksrk gSA
(A) PbSO4 dk fuekZ.k (B) Pb2+ dk Pb es vip;u
(C) PbO2 dk fuekZ.k (D) ,uksM ij Pb dk fu{ksi.k
16. lhlk lapk;d cSVjh ds iqu% vkos'ku ds nkSjku ,uksM+ ij fuEUk esa ls dkSulh vfHkfØ;k gksrh gSA
(A) Pb + SO42– PbSO4 + 2e– (B) Pb + PbO2 + H2SO4 2PbSO4 + 2H2O
(C) PbSO4 + 2e– Pb + SO42– (D) PbSO4 + 2H2O PbO2 + 4H+ + SO42– + 2e–
17. tc lhlk lapk;d lsy fujkosf'kr gksrk gS%&
(A) SO2 eqDr gksrh gSA (B) ysM curk gSA
(C) ysM lYQsV iz;qDRk gksrk gSA (D) lY¶;wfjd vEy iz;qDRk gksrk gSA
3. ,d izcy {kkj }kjk ,d izcy vEy dh mnklhuhdj.k dh Å"ek dk eku fuEu esa ls fdlds H ds cjkcj gS %
(A) H+ + OH– = H2O (B) H2O + H+ = H3O+
(C) 2H2 + O2 = 2H2O (D) CH3COOH + NaOH = CH3COONa + H2O
4. fuEu esa ls dkSulk lEcU/k lgh gSA ¼tgk¡ fn;s x;s izrhd budk lkekU; vFkZ j[krs gSa ½
T2 T
(A) a C (B) b C (C) A rFkk B nksuksa (D) buesa ls dksbZ ugha
PC PC
14. 75% 'kq) Xywdkst (C6H12O6) dk og nzO;eku] tks blds M/9 tyh; foy;u ds 50 mL dks cukus ds fy, vko';d
gS] fuEu gS&
4
(A) 4 g (B) 1 mg (C) 1 g g (D)
3
15. lhft;e dk ijek.kq nzO;eku 133 u gS rFkk Dyksjhu dk ijek.kq nzO;eku 35.5 u gSA 16.85 g CsCl esa mifLFkr ,dd
dksf"Bdk dh la[;k fdruh gS \
(A) 6.023 × 1022 (B) 1.204 × 1022 (C) 6.023 × 1021 (D) 1.204 × 1023
16. ljy J`a[kyk cgqyd dk fuekZ.k fuEu }kjk fd;k tkrk gS %
(A) (CH3)3 SiCl dk ty&vi?kVu rRki'’pkr~ la?kuu cgqydhdj.k
(B) (CH3)2 SiCl2 dk ty&vi?kVu rRki'’pkr~ la?kuu cgqydhdj.k
(C) (CH3) SiCl3 dk ty&vi?kVu rRki'’pkr~ la?kuu cgqydhdj.k
(D) (CH3)4 Si dk ty&vi?kVu rRi’pkr~ la?kuu cgqydhdj.k
17. ekuk fd ath dks'k esa d{kdksa dh dqy la[;k 16 gS rFkk osusfM;e ijek.kq (Z = 23) esa v;qfXer bysDVªkWu ds fy, f}xa'kh
DokaVe la[;k dk eku ‘b’ gS rc (a + b) ds ;ksx dk eku Kkr dhft,A
(A) 4 (B) 5 (C) 6 (D) 3
18. P4S3 ds ,d v.kq esa mifLFkr P-P ca/kks rFkk P-S cU/kksa dh la[;k dk ;ksx Kkr dhft, \
19. [Pt(NH3)2Cl2(H2O)2]2+ ds fdrus T;kferh leko;oh lEHko gS \
20. N% dk; dsUnzh; ?kuh; bdkbZ lSyksa ls ijek.kqvksa dks ysdj Qyd dsUnzh; lajpuk cuk;h x;hA çkIr Qyd dsUnzh;
bdkbZ lSyksa dh la[;k Kkr dhft,A
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24
21. 10 yhVj vk;ru ds ik=k esa mifLFkr ,d xSl ds 6 × 10 d.kksa ftlesa izR;sd d.k dk nzO;eku 3 × 10–22 gm gS]
}kjk yxk;s x;s nkc dh x.kuk dhft;s \ oxZ ek/; ewy osx (rms speed) 105 mm sec–1 gSA
22. 25ºC ij] fuEu lsy ds ,uksMhd Hkkx esa foy;u dh pH, x gSaA tc Elsy – Eºlsy = 0.0591 V gSA Pt(H2) (1 atm) |
pH = x | | Ni2+ (1 M) | NiA x dk eku Kkr dhft;sA
ChemINFO ELECTROCHEMISTRY
Daily Self-Study Dosage for mastering Chemistry Topic: Fuel Cell
ijaijkxr (Conventionally) ÅtkZ thok'eh; bZa/ku ds ngu }kjk izkIr gksrh gSA oS|qr ÅtkZ es :ikUrj.k vusd inks esa gksrk gS
rFkk ;gk¡ izR;sd in ij ÅtkZ dh gkfu gksrh gSA izØe dh n{krk yxHkx 40% gksrh gSA ;gk¡ bZa/ku dh jklk;fud ÅtkZ dks lh/ks
mRizsjdh; lfØ;r jsMkWDl vfHkfØ;kvksa }kjk oS|qr ÅtkZ ess :ikUrfjr djus ds fy, Hkh vusd rjhds gksrs gSA bl izdkj dh
;qfDRk;k¡ bZa/ku lSy dgykrh gSA vU; 'kCnks esa bZa/ku lsy XksYosfud lSy gksrs gS] ftuesa oS|qr ÅtkZ bZa/ku dh jsMkWDl vfHkfØ;kvksa
ls lh/ks O;qRiUu gksrh gSA
b±èku lSy dk izn'kZu gS % b±èku | bysDVªkWM | oS|qr vi?kV~; | bysDVªkWM | vkWDlhdkjh
lEiw.kZ lSy vfHkfØ;k : b±èku + vkWDlhdkjh vkWDlhdj.k mRikn + vip;u mRikn
gkbMªkstu&vkWDlhtu bZa/ku lSy
;g bZ/kau lSy gkbMªkstu rFkk vkWDlhtu dks tksM+dj fo/kqr] Å"ek rFkk ty mRiUu djrs gSA ;g jklk;fud ÅtkZ dks fo/kqr
ÅtkZ esa cnyrs gS rFkk bl izdkj cSVjh ds rqY; gks ldrs gSA dsoy vUrj ;g gS fd vf/kd yEcs le; rd gkbMªkstu izokfgr
djus ij ;g fujUrj fujkosf'kr gq, fcuk fo/kqr mRiUu djrk gSA
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23. H2 – O2 bZ/ku lsy es] dSFkksM ij vfHkfØ;k gksrh gS%&
(A) 2H2 + O2 2H2O (l) (B) H O H H2O
(C) O2 + 2H2O + 4e– 4OH– (D) He– 1/2 H2
24. bZ/ku lsy dh Å"ekxfrdh; {kerk fuEu }kjk nh tkrh gSA
H nFE nFE
(A) (B) (C) (D) nEF–
G G H
25. bZ/ku lsy dh lsy vfHkfØ;k gS %&
(A) 2H2O(l) 2H2 (g) + O2(g) (B) 2H2(g) + O2(g) 2H2O(l)
(C) CH4(g) + O2(g) CO2(g) + H2O (l) (D) C(s) + O2(g) CO2(g)
3. Lih'kht ds fn;s x;s ;qXeks esa ls prq"Qydh; rFkk vuqpqEcdh; bdkbZ gS@gSa&
(A) [MnO4]2–,[NiCl4]2– (B) [MnBr4]2–, [CoCl4]2–
(C) [CrO2F2], [Cr2O7]2– (D) [Ni(CO)4], [Ni(dmg)2]
4. vf/kdrj vk;fud ;kSfxd dk gksrk gS %
(A) mPp xyukad rFkk fuEu DoFkukad
(B) mPp xyukad rFkk vfn'kkRed cU/k
(C) /kzqoh; foyk;d esa mPp foys;rk rFkk v/kqoh; foyk;d esa fuEu foys;rk
(D) f=kfofe; fØLVyh; lajpuk rFkk xfyr voLFkk esa oS|qr dk vPNk pkyd gSA
5. gkbMªkstu ijek.kq ds 1s d{kd ds fy, f=kT;h; rjax Qyu fuEu izdkj n'kkZ;k tkrk gS &
3/2
1 1 –r / ao
R(r) = e (tgk¡ ao = 0.529 Å)
ao
r = ao ij bysDVªkWu ds ik;s tkus dk f=kT;h; izkf;drk ?kuRo rFkk ukfHkd ij bysDVªkWu ds ik;s tkus ds f=kT;h;
izkf;drk ?kuRo dk vuqikr (xe–y) ds :i es n'kkZ;k tkrk gSA
(x + y)3 dk eku ifjdfyr dhft,A
6. 300 K rFkk 20 atm ij ,d xSl dk lEihM~;rk dkjd 0.8 gSA bu ifjfLFkfr;ksa esa] xSl ds 8 mmol }kjk ?ksjs x;s
vk;ru dh x.kuk dhft,A (yhft, R = 1/12 L atm K–1 mol–1)
7. oS|qr :i ls fu{ksfir flYoj dh eksVkbZ Kkr dhft, ;fn i`"B lrg {ks=kQy] ftl ij fu{ksi.k gqvk gS] 100 cm2 ik;k
x;k gS rFkk 0.2 A dh fo|qr /kkjk 1 ?k.Vs ds fy, izokfgr dh tkrh gS o dSFkksM dh n{krk 80% gSA
Ag dk ?kuRo = 10 g/cc (Ag = 108).
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
8. fn;s x;s js[kkfp=k esa oS|qr vi?kV~; lsy ,d tyh; 1 M dkWij (II) lYQsV foy;u dk 1
yhVj j[krk gSaA ;fn lsy ds }kjk bysDVªkWu ds 0.4 eksy izokfgr fd;s x;s rks vkos'k ds
izokfgr gksus ds ckn dkWij vk;u dh eksyj lkUnzrk D;k gksxhA
9. ,d dkcZfud ;kSfxd dk 4×10–2 M tyh; foy;u] 1.5 ×10–2 M NaCl (iw.kZ vk;uu) ds tyh; foy;u ls lEkijkljh
gSA ;fn ;kSfxd f}ydhd`r gksrk gS vkSj mldh dksfV gS rFkk okUV gkWQ dkjd i gSaA (8i + 2 ) dk eku Kkr djsaA
iSysfM;e iUuh 76 cm Hg
10. foHkktu dks gVkus ds i'pkr~ nksuksa Hkq tkvksa ij Hg Lrj (cm esa) esa
D;k vUrj gksxk \ 76 cm Hg
uksV : dsoy gkbMªkstu iSysfM;e iUuh ls xqtj ldrh gSA
(esuksehVj dk vk;ru ux.; ekfu,];g i;kZIr yEch gS rFkk dksbZ foHkktu
vfHkfØ;k ugha gksrh gSA ½
76 cm Hg
11. fuEu ;kSfxdksa esa ls ,sls ;kSfxdksa dh dqy la[;k Kkr dhft,] tgk¡ d x2 y2 d{kd ladj.k esa Hkkx ugha ysxkA
(1) [Pt(NH3)Cl (H2O)Br] (2) SF4 (3) [Cu(NH3)4]2+ (4) XeO3F2
(5) XeO2F2 (6) [Co(en)3]3+ (7) [Ni(CO)4] (8) POCl3
(9) PCl5 (10) XeO64–
12. nks chdj A rFkk B esa fp=k esa n'kkZ, vuqlkj Øe'k% 0.1 M rFkk 0.01 M lkanzrk ds AgNO3 foy;u mifLFkr gSA
izR;sd chdj esa vc 'kq) flYoj bysDVªkWM dks j[kk tkrk gSA vc NH3 dks chdj A vkSj B esa NH3 dh lkUnzrk Øe'k%
0.1 M rFkk 0.2 M gksus rd izR;sd chdj esa feyk;k tkrk gSA ;fn vc nksuksa chdj xSYosfud lSy O;oLFkk esa tksM+s tkrs
gSa] rks 298 K ij ifj.kkeh lSy dk EMF (feyhoksYV es) Kkr dhft,A viuk mÙkj 16 ls Hkkx yxkus ds i'pkr~
RT
nhft,A [iz;ksx djs log10 2 = 0.3, 298 K ij (2.303) = 0.06 V] fn;k gS : E ºAg / Ag = 0.8 Volt
F
Ag Ag
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
ChemINFO ELECTROCHEMISTRY
Daily Self-Study Dosage for mastering Chemistry Topic: la{kkj.k
vk/kqfud vkS|ksfxd leqnk;ksa esa ,d eq[; leL;k la{kkj.k (Corrosion) gSA ;g crkrk gS fd okf"kZd mRiUu yxHkx 30-40%
vk;ju rFkk LVhy tax yxs vk;ju inkFkksZ dks gVkus ds fy, iz;qDr gksrs gSaA la{kkj.k ?kj ds vUnj rFkk ckgj lHkh midj.kksa eas]
lM+dksa ij] leqnzksa ij] ikniksa esa rFkk ok;oh; ifg;ksa esa iz;qDr gksrk gSA la{kkj.k] /kkrq vFkok blds ok;qe.My ds lkFk feJ /kkrq
dh ,d Lor% eUn jklk;fud vU;ksU; fØ;k gS] blds ifj.kkeLo:i vkWDlkbM] ty;ksftr vkWDlkbM] dkcksZusV] lYQkbM] lYQsV
bR;kfn ds leku blds ,d ;kSfxd dk fuekZ.k gksrk gSA
la{kkj.k dks buds ok;qe.My ds lkFk jklk;fud vU;ksU; fØ;k }kjk inkFkksZ ds voufr (deterioration) ds :i esa ifjHkkf"kr dj
ldrs gSaA inkFkksZa dk la{kkj.k ok;qe.My }kjk /kkrq ij fo|qr jklk;fud okrkoj.k }kjk vFkok izR;{k jklk;fud vkØe.k }kjk
izkIr gksrk gSA la{kkj.k dk lokZf/kd ikfjokfjd mnkgj.k ok;qe.Myh; ifjfLFkfr;ksa eas [kqyk NksM+us ij vk;ju dk tax yxuk gSA
2Fe(s) + 3/2 O2 (g) + xH2O(I) Fe2O3· xH2O(s)
(tax dk jklk;fud laxBu)
vk;ju dk tax yxuk ,d tfVy jklk;fud vfHkfØ;k gS ftlesa vkWDlhtu rFkk ueh (fp=k ns[ksa) nksuksa gksrs gSaA vk;ju ij 'kq)
ty esa tax ugha yxrk gS D;ksafd ;g vkWDlhtu eq Dr gksrk gS rFkk bl ij ueh dh vuqifLFkfr eas 'kq) vkWDlhtu esa tax ugha
yxrk gSA ;g crkrk gS fd laa{kkj.k izØe ,d oS|qr jklk;fud izd`fr dk gksrk gSA /kkrq dh ,d lrg ij vk;ju ty dh
mifLFkfr eas vkWDlhd`r gksrk gS rFkk Fe2+ ds :i esa foy;u esa izos'k djrk gS rFkk ;g /kkrq lrg dh ,uksfMd fLFkfr gSA ,uksM
ij gksus okyh vfHkfØ;k gS&
bysDVªkWu tks fu"dkflr gksrs gS] tc vk;ju vkWDlhd`r gksrk gS] rc ;g bysDVªkWu dqN ,sls vU; LFkku ij /kkrq ds }kjk xfr'khy
gksrs gSa] tgk¡ vk;ju dks vkWDlhtu esa [kqyk NksMrs gSaA ;g /kkrq lrg dk dSFkksfMd {ks=k gS] tgk¡ vip;u gksrk gS ,oa vkWDlhtu
vipf;r gksdj gkbMªkWDlkbM vk;u nsrh gSA dSFkksM ij gksus okyh vfHkfØ;k gS %
1/2O2(aq) + H2O(I) + 2e– 2OH– (aq)
vk;ju (II) vk;u rc curs gSa tc ;g ,uksfMd {ks=k ij ty ds }kjk /khjs&/khjs folfjr gksrs gS rFkk vUr esa gkbMªkWDlkbM vk;uksa
ds lEidZ eas vkrs gSaA blds dkj.k Fe(OH)2 dk vo{ksi curk gS] tks vf/kd vklkuh ls O2 }kjk vkWDlhd`r gksdj Fe(OH)3
nsrk gSA ;g gkbMªkWDlkbM rsth ls ty fu"dkflr djrk gSA okLro esa iw.kZ futZyhdj.k vkWDlkbM nsrk gSA
2Fe(OH)3 Fe2O3 + 3H2O
tc Fe(OH)3 dk vkaf'kd futZyhdj.k izkIr gksrk gS rks tax curk gSA ;g ,slk laxBu curk gS ftleas gkbMªkWDlkbM rFkk
vkWDlkbM] Fe2O3 ds e/; ;g izkIr gksrk gS rFkk ;g izk;% ty;ksftr vkWDlkbM ds :i eas gksrk gS] blds lw=k dks lkekU;r%
Fe2O3· xH2O ds :i eas iznf'kZr djrs gSaA
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
14. ykSgs ij tax yxuk ,d gS%&
(A) fo?kVu (decompostion) izØe (B) izdk'kjklk;fud izØe
(C) fo|qr jklk;fud izØe (D) vip;u izØe
15. ykSgs ij tax yxus es fuEUk es ls dkSulh lsy vfHkfØ;k dSFkksM ij gksrh gS \
(A) Fe2+ | Fe (B) O2 | H2O (C) Fe3+ | F2+ (D) Fe | Fe3+
16. fuEu es ls dkSulk dFku ykSgs ij tax yxus ds lUnHkZ es lgh gS@gSa \
(A) ;g ue ok;q es gksrk gSA (B) ;g CO2 ds okrkoj.k es cUn gks tkrk gSA
(C) ;g Fe (III) vkWDlkbM cukrk gSA (D) ;g ,d fo|qrjlk;fud izØe gSA
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
(A) fLFkfr leko;oh (B) Jà[kyk leko;oh (C) letkr (D) T;kferh; leko;oh
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
13. fuEu esa ls fdl ;kSfxd esa izR;sd f}ca/k ij lei{k foU;kl gS \
(A) (B)
(C) (D)
(A) (1Z, 2Z, 3E) gsIVk-1,3,5-VªkbbZu (B) (2E, 4Z, 6Z) gsIVk-2,4,6-VªkbbZu
(C) (3Z, 5E) gsIVk-1,3,5-VªkbbZu (D) (2E, 4Z) gsIVk-2,4,6-VªkbbZu
(A) (B)
(C) (D)
(A) (B)
(C) (D)
19. fLVychu (PhCH=CHPh) nks foofje leko;oh :i (X) vkSj (Y) esa jgrk gS vkSj ik;k x;k fd (X), (Y) ls vfèkd
ty esa foys; gS rks fuEu esa ls lgh dFku gSA
(A) X foi{k leko;oh gS (B) X dk LFkkf;Ro > Y dk LFkkf;Ro
(C) X dk xyukad < Y dk xyukad (D) X dk DoFkukad < Y dk DoFkukad
22. tc lkbDyksizksisuksu rFkk 2-C;wVsuksu NH2OH ds vkf/kD; ds lkFk vfHkfØ;k djrs gSa] rks fdrus vkWfDle izkIr gksrs gS %
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
23. fuEu esa ls dkSu T;kferh; leko;ork iznf'kZr ugha djrk gS \
H CH3
(v) CH3 (vi) (vii) (viii)
HO CH3
24. uhps fn;s x;s ;kSfxd esa fdrus f=kfoedsUnz ¼T;kferh; dsUæ½ mifLFkr gS \
CH2=CH–CH=CH–CH= N H
1. fuEu esa ls dkSuls fodYi esa lHkh ;kSfxd T;kferh; leko;ork iznf'kZr djrs gSA
Cl
(A) , (B) , C2FClBrI
Br
(C) , Ph2N2 (D) CH3–CH=N–OH, H2C=CH–CH=CH–CN
3. ;kSfxdksa ds fuEu esa ls dkSuls ;qXe esa lgh ladsr fn;k x;k gS \
(A) (B)
(C) (D)
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
4. fuEu esa ls dkSuls ;kSfxd dk Z foU;kl gksxk?
(A) (B)
(C) (D)
5. fuEu ;kSfxdksa ds ;qXeksa ds fy, iznf'kZr xq.k/keZ esa dkSulk Øe xyr gSA
¼foi{k½ ¼lei{k½
vuqNsn # 1
fuEu ;kSfxd dk izs{k.k dhft,A
CH3–CH=CH
O O CH3
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
9. dqy fdrus bZukWfyd :i ¼f=kfoe leko;oh lfgr½ C;wVsukWu ds fy, lEHko gSa \
(A) 1 (B) 2 (C) 3 (D) 4
10. fuEu esa ls fdrus v.kq ;k ;kSfxdksa es T;kferh; leko;ork lEHko gS \
Cl
NH Br
(1) (2) (3) (4)
NH
Me
NH
(5) (6) (7) (8) MeS
NH
(9) (10)
11. VsVªkDyksjks lkbDyks C;wVsu ds dqy fdrus fLFkfr leko;oh T;kferh; leko;ork n'kkZrs gSA
O3/Zn NH2–OH
12. isUVk-1,3-MkbbZu dkcksZfuy ;kSfxdks dh vkWfDleks dh
dqy la[;k vkf/kD; dqy la[;k
[X] [Y]
viuk mÙkj X Y ds :i es nhft,&
13. dkWye-I dks dkWye-II ls lqesfyr dhft, %
dkWye I dkWye II
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
4. fuEu esa ls dkSu U;wure v.kq Hkkj ;qDr gkbMªksdkcZu tks fd fdjSy gSA
(A) 3-esfFkygsDlsu (B) 2, 4-MkbesfFkyisUVsu
(C) 2, 2-MkbesfFkyisUVsu (D) 3, 3-MkbesfFkyisUVsu
NH2
11. uhps fn;s x;s ;kSfxd esa nksuksa fdjSy dkcZu ijek.kqvksa dk lgh R/S vfHkfoU;kl gS %
14. dkSuls fodYi esa fn;s x;s lewgksa ,oa ijek.kqvksa ds f=kfoe vfHkfoU;kl lajpuk P ls fHkUu gSA
Cl
P = H3C H
D
CH3 CH3 Cl
D CH3
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
19. fn;s x;s ;kSfxd esa fdrus fdjSy ijek.kq mifLFkr gS \
20. uhps fn;s x;s ;kSfxd esa fdrus fdjSy dsUnz mifLFkr gS %
Ph
HO
D OH
21. uhps fn;s x;s ;kSfxd esa fdrus fdjSy dsUnz mifLFkr gS %
Ha
uksV : fuEu ;kSfxd rFkk CH3–C–CH–C–CH3 Hkh vEyh; gkbMªkstu j[krs gSaA
O Ha O
1
lkekU; vfHkfØ;k : Z– + Na + H2
2
1 1
(a) R COOH
Na
R COONa H2 (b) PhOH
Na
PhONa H2
2 2
1 1
(c) R—C CH + Na R—C C–Na+ + H2 (d) R—SO3H + Na R—SO3–Na+ + H2
2 2
1
(e) R —CH2—O —CH3 + Na No reaction. (f) HCl NaCl H2
Na
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
24. fuEu esa ls dkSulk ;kSfxd lksfM;e /kkrq ds lkFk vfHkfØ;k ds Ik'pkr~ H2 xSl eqDr ugha djsxk ?
(A) CH3–S–H (B) CH3–CHO (C) CH3–CH2–CCH (D) CH3–C–CH2–C–CH3
O O
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
25. fuEu esa ls dkSulk ;kSfxd lksfM;e /kkrq ds lkFk vfHkfØ;k ds Ik'pkr~ H2 xSl eqDr ugha djsxk ?
CH2 —COOH
CH2 —O — H CH2 —O — H CH2 —S — CH3
CH — O — H
(A) (B) (C) CH2 — CHO (D)
CH2 O —CH3 CH2 — NH2
CH2 — S — H
2. fuEu esa ls dkSu nksgjh&eqM+h gq;h (two-fold) v{k lefefr dk v{k j[krk gS\
(A) ,Fkkbyhu (B) lkbDyksizksisu (C) lkbDyksC;wVsu (D) csUthu
(A) blesa lefefr dsUnz mifLFkr gSA (B) blesa lefefr C3 v{k mifLFkr gSA
(C) blesa lefefr ry mifLFkr gSA (D) blesa lefefr C2 v{k mifLFkr gSA
(A) (B)
(C) (D)
vuqNsn #
,d vlar`Ir ;kSfxd X (C5H10O) ds pkj f=kfoe leko;oh lEHko gSA Y, (X dk lajpukRed leko;oh) uk rks vlar`Ir
gS vkSj uk gh f=kfoe leko;ork n'kkZ ldrk gSA X o Y esa leku fØ;kRed lewg ik;k tkrk gSA rhljk leko;oh
(Z), X dk fLFkfr leko;oh gS rFkk dsoy nks f=kfoe leko;oh j[krk gSA
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
6. fuEu esa ls ;kSfxd Z ugha gks ldrk gS\
(A) CH2=CH– CH –CH2 CH3 (B) H2C = CH–CH2– CH –CH3
| |
OH OH
CH3
|
(C) CH3–CH=CH–CH2–CH2–OH (D) H2C=C–CH–CH3
|
OH
7. Y gks ldrk gS %
CH2OH
|
(A) (B) (C) (D) (B) rFkk (C) nksuksa
|
O OH
8. CH4 es mifLFkr ry lefefr dh dqy la[;k gS&
9. fuEu esa ls fdl ;kSfxd esa lefefr dk dsUnz ugha ik;k tkrk gS %
H
11. BF3 esa lefefr dh aC2 v{k X gS rFkk lefefr dh C3 v{k Y gSA viuk mÙkj X + Y ds :i esa nhft,A
12. fuEu dks lqesfyr dhft,A
dkWye-I dkWye -II
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
H F & F Cl
Br H
(A) izfrfcEc:iksa leko;oh (B) foofje:ih leko;oh
(C) le:I (D) dksbZ lEc/k ugh
CH3
H Cl
(A) (B) (C) (D) mijksDr lHkh
Cl H
CH3
8. fuEu esa ls dkSulk felks ;kSfxd ugha gS %
COOH
CH3 CH3 H OH
H Cl H Cl HO H CHO
(A) H OH (B) HO H (C) HO H (D) H OH
H Cl H Cl H OH
CH3 CH 3 COOH CH3
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
9. fuEu esa ls dkSulk ;kSfxd 2- esfFky C;wVsuksbd vEy ds jslsfed feJ.k ds izdkf'kd fo;kstu ds fy, mi;qDr gS :
(A) 2-C;wVsukWy (B) 1-izksisukWy
(C) 2-izksisukWy (D) lkbDyksC;wVsu dkcksZfDlfyd vEy
10. ,d ;kSfxd dk [] = 40.3º gS ftls iksyjs hehVj iz;ksx ls nf{k.kkorZ fn'kk esa Kkr fd;k x;k gSA vr% bldh lajpuk
gksxhA
(A) (B)
. (C) (D)
(A) + 45° (B) 0° (C) –45° (D) dqN dgk ugha tk ldrkA
12. ;fn }kjk mRiUu izdkf'kd ?kw.kZu +36º gS rks }kjk mRiUu izdkf'kd ?kw.kZu gksxk&
14. uhps fn;s x;s ;kSfxd (I) rFkk (II) ds e/; laca/k gS %
CH3 CH3
HO — C — H H — C — OH
HO — C — H H — C — OH
H — C — OH H — C — CH3
CH3 OH
(I) (II)
(A) izfrcEc:ih leko;oh (B) foofje:ih leko;oh
(C) le:ih ;k leku (D) lajpukRed leko;oh
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
Br Br
C C
15. & H
H CH2Cl C2H5
C2H5 Cl
mijksDr ;kSfxdks dk ;qXe fuEu esa ls fdl izdkj lEcfU/kr gSa\
(A) izfrfcEc :ih leko;oh (B) foofje :ih leko;oh
(C) ltkrh; (D) le:i ;kSfxd
19. C;wVsu-2,3-MkbvkWy ds fy;s laHkkfor f=kfoe izdkf'kd lfØ; leko;fo;ksa dh la[;k fuEu esa ls gksxh \
20. fn;s x;s ;kSfxd ds T;kfefr leko;oh;ksa dh la[;k D;k gksxhA
,LVj dk ijh{k.k
,LVj e/kqj xa/k ¼Qyksa tSlh½ okys nzo gksrs gSaA
tc budh vfHkfØ;k NaOH rFkk fQukWY¶FkSyhu ds lkFk djkrs gSa rks xeZ djus ij xqykch jax foyqIr gks tkrk gSA
RCOOR’ + NaOH + fQukWY¶FkSyhu (xqykch jax) RCOOH + R’OH (jaxghu foy;u)
ukbVªks lewg ds fy, ijh{k.k ¼eqyhdu&ckdZj ijh{k.k½
ukbVªks,sYdsu ,oe~ ukbVªkscsUthu dks Zn o veksfu;e DyksjkbM ls vipf;r djus ds ckn VkWysu vfHkdeZd ls
mipkfjr djus ij dkyk vo{ksi izkIr gksrk gSA bls eqyhdu ijh{k.k dgrs gSA
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
AgNO3 NH4 OH
(b) + Zn + NH4Cl
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
22. ,d dkcZfud ;kSfxd X (C4H8O2), NaOH vkSj fQukW¶Fkyhu ds lkFk /kukRed ijh{k.k nsr k X dh lajpuk gksxhA
(A) CH3 CH2 CH2 C OH (B) CH3 C C CH3
|| || ||
O O O
(C) CH3 C O C2H5 (D) CH3 C OCH3
|| ||
O O
23. dkSulk ;kSfxd lkUnz NaOH ds lkFk NH3 dh xa/k nsrk gSA
(A) CH3 CH2 C NH2 (B) CH3 C CH2 NH2
|| ||
O O
24. ,d ;kSfxd tks ftad pw.kZ ,oa veksfu;e DyksjkbM ds lkFk xeZ fd;k tkrk gS izkIr vfHkfØ;k feJ.k dks VkWysu
vfHkdeZd esa Nkuus ij jtr niZ.k curk gSA ;g fØ;k fuEu esa ls fdl lewg dh mifLFkfr n'kkZrh gSaA
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
5. 2,3-MkbesfFky C;wVsu dk lokZf/kd LFkk;h la:i.k leko;oh gS %
Me
Me H
(A) (B) (C) (D) lHkh dk LFkk;hRo leku gS
H Me
Me
6. vkblksisUVsu dk og la:i.k ftlesa vf/kdre ,sBu ruko (torsional) vkSj okUMjoky fod`fr gS%
(A) ;fn ‘X’, H gS rc ‘Y’, CH3 gksxk (B) ;fn ‘X’, H gS rc ‘Y’, Cl gksxk
(C) ;fn ‘X’, H gS rc ‘Y’, C2H5 gksxk (D) ;fn ‘X’, Cl gS rc ‘Y’, CH3 gksxk
H H H H
H H
(A) la:i.k izfrfcEc :ih (B) la:i.k foofje :ih
(C) T;kferh; leko;oh (D) letkr
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
13. uhps n'kkZ;h x;h lajpukvksa esa dkSu U;wure fLFkfrt ÅtkZ j[krk gS\
14. lfDlfud vEy dk {kkjh; ekè;e esa lcls vfèkd LFkk;h la:i.k gksxk%
(A) (B)
(C) (D)
H H
H
21. fn;s x;s ;kSfxd ds dqy fdrus f=kfoeleko;oh lEHko gS %
CH3–CH=CH–CH=CH–CH=CH–CH3
22. (P)
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
S
||
(b) CH3CH2NH2 + S = C=S HgCl2
CH3CH2–N=C=S + HgS + 2HCl
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
23. fuEu esa ls dkSu NaNO2 / HCl ds lkFk N2 xSl nsrk gSA
(A) CH3–CH2–NH–CH3 (B) CH3–CH2–CH2–NH2
(C) Ph–NH2 (D) (CH3CH2)3N
24. fglacxZ çØe ç;qDr djrs gS %
(A) çkFkfed ,ehu ds la'ys"k.k ds fy, (B) f}rh;d ,ehu ds la'ys"k.k ds fy,
(C) r`rh;d ,ehu ds la'ys"k.k ds fy, (D) ,ehu feJ.k ds i`FkDdj.k ds fy,
25. fuEu esa ls dkSulh ,ehu fglacxZ vfHkdeZd (Hinsberg's reagent) ls vfHkfØ;k ugha djrk gSA
(A) CH3CH2NH2 (B) Ph–NH2 (C) (CH3CH2)2NH (D) Ph–CH2–NH2
3.
I II III
mijksDr ;kSfxdks esa lgh lEc/ak gSA
(A) I rFkk II fLFkfr leko;oh gSA (B) I rFkk II Jà[kyk leko;oh gSA
(C) II rFkk III e/;ko;oh gSA (D) II rFkk III le:i gSA
4.
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
5. fuEu esa dkSuls la:i.kks dk f}/kzqo vk/kq.kZ v'kqU;
7. fuEu esa ls dkSulk ;kSfxd tyh; foy;u esa j[kus ij jslsehd`r gksxk\
CH3 Me
| |
(A) CH3–CH2–CHO (B) Ph C C CH3 (C) Ph C C CH3 (D) Ph CH CH2 C CH3
| || | || | ||
H O Et O D O
OD / D2O vkf/kD;
9.
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
5. fuEu esa ls dkSulk vPNs ukfHkdLusfg ds lkFk&lkFk vPNk fu"d"khZ lewg Hkh gS %
(A) NH2 (B) OH (C) I (D) CH3–O
9. v/kqzoh; foyk;d gS %
(A) ,FksukWy (B) ,lhVksu (C) DMF (D) CS2
10. fuEu esa ls dkSulk ,d bysDVªkWuLusgh gS\
(A) H2O (B) NH3 (C) CH3OH (D) AlCl3
11. fuEu esa ls dkSulk ,d bysDVªkWuLusgh ugha gS \
(A) PCl5 (B) SO3 (C) Ph–OH (D) HCHO
12. dkSulk nqcZy fu"dklu lewg gS\
(A) OH (B) SH (C) OPh (D) CH3COO
13. fuEu esa ls dkSulh iztkfr mHk;/kehZ ukfHkdLusgh gS \
(A) C6H5O– (B) NO3– (C) HSO3– (D) NH3
14. fuEu esa ls dkSulk lcls vPNk fu"dklu lewg gS \
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
15. fn;s x, fu"dklu lewgksa dh fu"dklu ;ksX;rk dk ?kVrk gqvk lgh Øe gS \
(A) IV > III > II > I (B) III > IV > II > I (C) II > IV > III > I (D) IV > II > III > I
+ OH + Cl¯
NO2 NO2
(A) ,d ;ksxkRed vfHkfØ;k (B) ,d ukfHkdLusgh izfrLFkkiu vfHkfØ;k
(C) ,d bysDVªkWuLusgh izfrLFkkiu vfHkfØ;k (D) ,d eqDrewyd izfrLFkkiu vfHkfØ;k
H2 O
CH OH
3
(C) (D)
H
20. fn;s x;s lajpukRed lw=k esa dqy f=kfoe leko;oh;ksa dh la[;k gSA
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
1. fuEu esa ls dkSulk ;kSfxd bysDVªkWuLusgh izfrLFkkiu vfHkfØ;k ds izfr lokZf/kd fØ;k'khy gS\
CHO OCH3 Cl
5. fuEu esa ls dkSuls ;kSfxd esa vkFkksZ&iSjk fuZns'kh o folfØ;.kdkjh lewg mifLFkr gS&
6. fuEu esa ls dkSulk ;kSfxd ,d fo'ks"k bysDVªkWuLusgh ds izfr vfèkdre izfr'kr iSjk mRikn nsrk gSA
F Cl Br I
ICl / ZnCl
7.
2
mRikn( mijksDr vfHkfØ;k dk mRikn gS%
Cl Cl I I
9. fuEu vfHkfØ;kvksa esa ls fdlesa izkFkfed leLFkkfud izHkko izsf{kr gksrk gS&
(A) Dyksjhfudj.k (B) ukbVªhdj.k
(C) esfFkfydj.k (D) lYQksfudj.k
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
10. lYQksfudj.k vfHkfØ;k ds fy, xyr dFku gS&
(A) lYQksfudj.k ds fy, lkUæ H2SO4 mfpr gSA
(B) folYQksfudj.k ds fy, ruq H2SO4 mfpr gSA
(C) ;g ,d vuqRØe.kh; vfHkfØ;k gSA
(D) fuEu rki lYQksfudj.k ds fy, mfpr gS rFkk mPp rki folYQksfudj.k ds fy, mfpr gSA
11. mRizsjd futZyh; AlCl3 dh mifLFkfr esa fuEu esa ls fdldh fØ;k }kjk ,fFkycsUthu (PhEt) curk gS?
(A) CH3–CH2OH + C6H6 (B) CH3–CH=CH2 + C6H6
(C) C2H5Cl + C6H6 (D) CH3–CH3 + C6H6
12. csUthu dh lY¶;wfjd vEy dh mifLFkfr esa vkblksC;wVhu ds lkFk fØ;k ij curk gS%
(A) vkblksC;qfVy csUthu (B) r`rh;d-C;qfVy csUthu
(C) n-C;qfVy csUthu (D) vfHkfØ;k ugha
13. fuEu esa ls dkSulk dkcZfud DyksjkbM csUthu vkSj AICI3 ds lkFk xeZ djus ij ÝhMy&Øk¶V ,fYdyhdj.k vfHkfØ;k
ugha nsxkA
(A) CH3)3CCI (B) CH2=CHCH2CI (C) CH3CH2CI (D) CH2=CHCl
14. tc csUthu dh fØ;k HNO3/H2SO4 ds lkFk dh tkrh gS rc e/;orhZ D;k gksxk&
mRikn Y gS %
(A) p-Dyksjks ukbVªkscsUthu (B) m-Dyksjks ukVªkscsUthu
(C) o-Dyksjks ukbVªkscsUthu (D) o,p-MkbZDyksjks ukbVªkscsUthu
16.
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
18. fuEu esa ls fdrus ukWu&,sjksesfVd ;kSfxd gS\
(i) (ii) (iii) (iv)
(ix)
(ix)
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry ,sjksesfVd ik'oZ J`a[kyk dk vkWDlhdj.k
,sjksesfVd ik'oZ Jà[kyk dk vkWDlhdj.k
izcy vkWDlhdkjd inkFkZ tSls KMnO4/H/ ;k K2Cr2O7/H/ csfUtfyd dkcZu dks –COOH lewg esa vkWDlhd`r dj nsrs gSa
;fn v.kq esa csfUtfyd gkbMªkstu ijek.kq ;k vlar`Irrk mifLFkr gksrh gSA
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
lkekU;r vfHkfØ;k,sa:
COOH
KMnO / H KMnO / H
4
4
CH3
COOH CH3 C CH3
KMnO / H KMnO / H
4
4
dksbZ
vfHkfØ;k ugha gksxh
uksV :- r`rh; C;wVhy (CH3)3C– vkWDlhdkjh vfHkdeZd }kjk vkWDlhd`r ugha gksrk gSA
KMnO / H
4
KMnO / H
Ex.1 Ex.2
4
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
CH2–CH3
KMnO / H
22.
4
mRikn ; mRikn gksxk :
23. fuEu esa ls dkSulk vfHkdeZd csfUty ,YdksgkWy dks csUtksbd vEy esa ifjofrZr djus ds fy, mi;qDr gSS \
(A) K2Cr2O7/H+ / (B) KMnO4/H+ / (B) m–CPBA (D) (A) rFkk (B) nksuksa
KMnO / H
4
KMnO / H
25.
4
mRikn ; mRikn gksxk :
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
1.
Cl / FeCl
2
3
+
(A) gSykstu dk –I izHkko (B) gSykstu dk +I izHkko (C) gSykstu dk +M izHkko (D) gSykstu dk –M izHkko
3. fuEu esa ls fdlesa fÝMy ØkW¶V ,lhyhdj.k vfHkfØ;k izsf{kr ugha gksrh gS@gSa \
4. fuEu esa ls fdlesa bysDVªkWu Lusgh ,sjksesfVd izfrLFkkiu vfHkfØ;k cka;h vksj dh Qsfuy oy; ij gksxhA
(A) (B)
(C) (D)
5. fuEu esa ls dkSulh bysDVªkWu Lusgh izfrLFkkiu vfHkfØ;k esa lgh mRikn n'kkZ;k x;k gSA
Br / FeBr
(A) 2
3
Br / FeBr
(B) 2
3
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
Br / FeBr
(C) 2
3
Br / FeBr
(D) 2
3
vuqNsn #
COCl AlCl Zn-Hg/HCl
3
6. + (X) [Y]
COCl
Y gS %
OH
(A) COOH (B) (C) OH (D)
8. fuEu esa ls dkSulh vfHkfØ;k esa 1–Dyksjks–3–,fFky csUthu fufeZr gksrk gSA
Cl / AlCl Zn Hg/HCl
(A)
2 3
Cl /AlCl Zn Hg/HCl
(B)
2 3
Cl /AlCl
(C)
2 3
Cl /Fe
(D)
2
CMe3
(C) (r) bysDVªkWu Lusgh izfrLFkkiu vfHkfØ;k ds fy, cSathu ls de fØ;k'khy gSA
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry Oxidation
,ydhuks o ,Ydkbuksa dk flu gkbMªksDlhyhdj.k
lkekU; vfHkfØ;k :
H.A. H.A.
—CC—
H.A.
mnk-
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
(A) (B) HO OH
OH
(C) (D)
HO OH OH
14.
vfHkdeZd x gksxk %
(A) 1% {kkjh; KMnO4 (cs;j vfHkdeZd) (B) OsO4 /NaHSO3
(C) ij vEy /H3O+ (D) (A) ,oe~ (B) nksuksa
cs;j vfHkd eZd
15. CH3–CC–CH3 mRikn( mRikn gksxk %
or OsO4 / NaHSO3
(A) (B)
Br Br Br
1.
2
2.
2
3.
2
Fe Fe Fe
Br Br Br
4.
2
5.
2
6.
2
Fe Fe Fe
Br Br Br
7.
2
8.
2
9.
2
Fe Fe Fe
Br Br Br
10.
2
11.
2
12.
2
Fe Fe Fe
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
Br Br Br
13.
2
14.
2
15.
2
Fe Fe Fe
Br Br Br
16.
2
17.
2
18.
2
Fe Fe Fe
Br Br Br
19.
2
20.
2
21.
2
Fe Fe Fe
3
2
Br Br Br
22.
2
23.
2
24.
2
Fe Fe N 1 Fe
Br2
25.
26.
2
Br
Fe
Br Br
27.
2
28.
2
Fe Fe
2
Br Br
1
29. 2
30. 2
Fe Fe
NH
1. 3 2. 3 3. 3 4. 2 5. 2
6. 2 7. 4 8. 1 9. 3 10. 3
11. 1 12. 1 13. 3 14. 1 15. 3
16. 2 17. 2 18. 1 19. 1 20. 1
21. 5 22. 3 23. 3 24. 2 25. 2
26. 3 27. 3 28. 1 29. 1 30. 3
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
HClO4
(B)
NaH
(C)
K( èkkrq) K( èkkrq)
(C) (D)
4. fn;s x;s ;kSfxd dh Dyksjhuhdj.k vfHkfØ;k dh nj dks izHkkfor djus okyk fuEu ls dkSu lk lewg izfrLFkkih X ds
fy;s mi;qDr gksxk\
CO, HCl
5. (Y) mRikn gksxk
AlCl3
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
6. fuEu esa ls dkSu lk ;kSfxd ukfHkd Lusgh ,sjkseSfVd izfrLFkkiu vfHkfØ;k vR;f/kd rhoz xfr ls nsrk gS \
H O /
3
mRikn
(A) (B)
(C) (D)
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
RONa /
13.
(A) CCl4 esa (B) ruq NaOH esa (C) ruq HCl esa (D) ruq HCl esa
15. lkUnz HNO3 vkSj lkUnz H2SO4 ds ,d feJ.k dk mi;ksx dj csUthu ls ukbVªkscsUthu cukrs gSA feJ.k esa ukbfVªd
vEy ds :i esa dk;Z djrk gS %
(A) mRizsjd (B) vipk;d (C) vEy (D) {kkj
NaOH
16. + C2H5I X, X gS %
(1 eq.)
(A) C6H5OC2H5 (B) C2H5OC2H5 (C) C2H5OH (D) C6H5I
17. fdruh VkWyqbZMhu] NaNO2/HCl ds lkFk vfHkfØ;k ds i'pkr H3PO2 ds lkFk mipkfjr gksus ij VkWyqbZu nsrh gS \
NO2
Sn/HCl NaNO H O,
18.
2
2
mRikn Z
HCl 05C
19. ;fn esVk fØlkWy czksehu ty ds lkFk fØ;k djrk gS rks fdrus czksehu ijek.kq csUthu oy; ij tqM+s gq, gSA
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry ,Ydhuksa dk ,s.Vh gkbMªksfDlyhdj.k
,Ydhuksa dk ,UVh gkbMªkWfDlyhdj.k
ijkWDlh vEy dh lkekU; lajpuk ¼lw=k½ (RCO3H) gksrk gSA ;g eq[; :i ls vLFkk;h gksrs gS rFkk vklkuh
ls uotkr O ns nsrs gSA vr% ;g vkWDlhdkjd inkFkZ dh Hkk¡fr dk;Z djrs gSA ;g ,Ydhu dks ,ikWDlkbM esa ifjofrZr dj
nsrs gSA RCO3H dk la;kstu blds ckn bldk tyvi?kVu [RCO3H(H3O+)] djus ij ;g vkxs ,ikWDlkbM dks ,UVh
gkbMªkWDlhyhdj.k esa rksMrk gSA
lkekU; vfHkfØ;k :
Peroxyacid H O
3
1. ;g ,UVh (anti) ;ksx gSA nksuksa OH lewg ikbZ&caèk dh foifjr fn'kk ls ;ksx djsxsaA
2. ,jksesfVd oy; ds f}cU/k bu vfHkdeZdks ls fØ;k ugh djrs gSA
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
OH
(i) ijkWD lh vEy
Ex.1
(ii) H3O OH
lkbDyksgsDlhu foi{k&lkbDyksgsDlsu
1,2-Mkbvksy
bues ls dksbZ Hkh ij vEy gks ldrk gSA
CO H
– 3
(a) = m-CPBA ¼esVkDyksjks ijcsUtkWbd vEy½
–
Cl
(b) CH3CO3H = PAA (ij,flfVd vEy)
(c) PhCO3H = PBA ¼ijcsUtkWbd vEy½
(d) CF3CO3H = TFPAA (VªkbZ¶yksjks ij,flfVd vEy½
Ex.2
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
22. gS&
OH OH OH H
(A) (B) (C) (D) 50% B vkSj 50% C
H H H HO
ijkWD lh vEy
23. CH2 = CH2 X , X gS&
OH O
| CH2 — CH2
(A) CH2 — CH2 (B) | | (C) (D)
| OH OH
OH
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
1. fuEu esa ls fdl vfHkfØ;k esa cuus okys mRikn lgh fn,s x;s gS \
OH
OH
Br Br
Br /H O
(A)
2 2
Br
O O
C–O C–O
Br (1 mol)/Fe
(B)
2
Br
OH OH
Dilute ruq HNO , 20ºC O2N NO2
3
(C)
NO2
OH O–C2H5
(C H ) SO NaOH /
(D) 25
2
4
2. fuEu nh xbZ vfHkfØ;k esa fuEu esa ls dkSuls mRIkkn curs gSA
O / heat
H3O / heat
Ph3C – H 2
D
N = N – Ar
ArN
+ H
2
(B)
HO HO
SO3H
H / H O
(C)
2
+ H2SO4
OH ONa
CO / NaOH
COONa
(D)
2
vuqNsn #
I
II
III
Iv
v vI
(X) ¼nnZ fuokjd½
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
6. in-VI esa vfHkdeZd rFkk mRikn (X) Øe'k% gksxsaA
7. tkbyhu ds fdrus ,sjkseSfVd MkbZ,tksfu;e DyksjkbM dks H3PO2 ds }kjk esVk&tkbyhu esa ifjofrZr dj ldrs gS \
H PO ,
3 2
(m-tkbyhu)
8. fuEu ;kSfxd Br2/H2O ds vkf/kD; esa mipkfjr fd;k tkrk gS] rks mu fLFkfr;ksa dh dqy la[;k Kkr djks] tgk¡
czksehuhdj.k vklkuh ls gksrk gSA
Cl
|
9. Dyksjy +
Conc.H2SO4
PmRikn
mRikn dhVuk'kh gS rFkk eysfj;k fu;U=k.k ds fy, f}rh; fo'o ;q) esa iz;qDr gqvk FkkA dhVuk'kh ds ,d v.kq esa
Dyksjhu ijek.kqvksa dh la[;k gS&
10. lwph I ¼vfHkdkjd½ dks lwph II ¼mRikn½ ls lqesfyr dhft, rFkk lwfp;ksa ds uhps fn;s x;s dksM dk iz;ksx djds lgh
mRrj pqfu;s :
lwph I lwph II
OH
CH2OH
(P) (1) Br / CS (1)
22
OH
( 2) (CH3 )2 SO 4 / OH
NH2 OCH3
OCH3 OH
OH OH
(1) CHCl / O H
(R) 3
(3)
( 2) H2O
(3 ) NaBH 2
OH
Br OCH 3
(1) Br / Fe
(S)
2
(4)
( 2) Mg / Ether
(3 ) O2
( 4 ) H2O Br
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
dksM :
P Q R S P Q R S
(A) 4 2 3 1 (B) 3 1 4 2
(C) 4 2 1 3 (D) 2 4 1 3
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry Topic: C = C/CC dk vkWDlhdkjh fo[k.Mu
KMnO4 rFkk K2Cr2O7 izcyre vkWDlhdkjd vfHkdeZd gksrs gSaA ;s C=C ;k CC dks iw.kZ:i ls rksM+rs gS rFkk C=C ;k CC
dh lajpuk ds vkèkkj ij vkWDlhd`r mRikn tSls vEy rFkk dhVksu cukrs gSA vkWDlhdkjh vfHkdeZd (O.A) }kjk C=C ;k CC
dk vkWDlhdkjh fo[k.Mu fuEu vkWDlhdkjh inkFkZ }kjk gksrk gSA
(a) KMnO4 (b) K2Cr2O7 or CrO3/H (c) O3/H2O ;k O3/H2O2
lkekU; vfHkfØ;k %
O.A. O.A.
O.A. O.A.
+ CO2+ H2O 2RCOOH
O.A.
+ CO2 + H2O
mnkgj.k %
O.A. O.A.
+ H2O
O.A. O.A.
+ CO2+ H2O 2CH3COOH
O.A.
+ CO2+H2O
uksV % 1. ,Ydhu o ,YdkbZu tks =CH2 ;k C–H j[krs gS tks vkWDlhdkjh vfHkdeZd KMnO4 rFkk K2Cr2O7 ;k CrO3/H+
ds }kjk CO2 ds :i esa ,d vkWDlhdkjh mRikn nsrs gSA
O.A.
2. HCOOH (QkfeZd vEy) ;k H2C2O4 (vkDtsfyd vEy) CO2H2O
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
K Cr O
11. 2 2
7
P ; mRikn gS :
OH
(A) (B) (C) (D) O
OH
O
KMnO / H
13. A 4
CH3COOH + CH3CH2COOH. ,YdkbZu 'A' gks ldrh gS%
(A) CH3–CH=CH–CH3 (B) CH3–CC–CH3
(C) CH3–CH=CH–CH2–CH3 (D) CH3–CC–CH2–CH3
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
+
14. fuEu esa ls dkSulh ,Ydhu KMnO4 / K2Cr2O7 /H ds lkFk vfHkfØ;k djds vkWDlhdkjh mRikn ds :i esa CO2 nsrh
gSA
(A) CH3–CH=CH–CH3 (B) CH3–CH=CH2
(C) (D)
Br
Br OH
Br NO2
NaHS Br /KOH
(A)
(B)
2
Cl / Fe 4 HNO H SO ,
KCN NH HS NaNO / HCl
2
(A)
2 3 2 4
(a) (b) (c) (d) H2O/ (e)
.
HNO H SO
2 Sn / HCl (i) Cl / Fe Cl / Fe KCN
(C)
3 2 4
2
(a ) (ii) NaOH/ (c ) ( d) (e) H3O
(b)
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
4. vfHkfØ;k esa izkIr gksus okys mRikn ds fo"k; esa fuEu esa ls dkSulk fodYi lgh gS
KI
(A) X (B) Z =
(C) Y (D) Y =
5. ,sjkseSfVd ;kSfxdksa esa MkbZ,tks;qXeu vfHkfØ;k ,d bysDVªkWuLusgh izfrLFkkiu vfHkfØ;k gksrh gSA fuEu esa ls dkSulh
vfHkfØ;k esa oy; izfrLFkkiu MkbZ,tks;qXeu vfHkfØ;k ds fy, vf/kd mi;qDr gS \
(A) + (B) +
(C) + (D) +
vuqPNsn # (Q.6 ls 8)
NH2
+ CuCN H O
HNO 3 Fe / H NaNO
X 2 3
'Z'
HCl
+
CH3 Y CH3
+
Fe / H NaNO CuBr
W 2
' V '
HBr
6. ;kSfxd 'V' gS
CH3 CH3 CH3 CH2Br
Br
(A) (B) (C) (D)
Br
Br
8. ;kSfxd 'Z' gS
CH3 CH3 CH3 CH3
COOH CN
(A) (B) (C) (D)
COOH CN
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
12. lwph I (vfHkfØ;k) dks lwph II (mRikn) ds lkFk lqesfyr dhft, rFkk lwphc) fd;s x;s dksM ds vk/kkj ij lgh mÙkj
dkSulk gSA
lwph-I lwph-II
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry cs;j&foyxj vkWDlhdj.k
ijkWDlh vEy dh lkekU; lajpuk (RCO3H) gksrh gSA ;g vkisf{kd :i ls vLFkk;h gksrs gS rFkk vklkuh ls
uotkr O ns nsrs gSA vr% ;g vkWDlhdkjd inkFkZ dh rjg dk;Z djrs gSA ;g dhVksu dks ,LVj esa ifjofrZr dj nsrs gSA
lkekU; vfHkfØ;k,sa :
O. A.
O. A.
Cl
(b) CH3CO3H = PAA (ij&,sflfVd vEy)
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
m-CPBA
mnk--1: CH3—C—CH3 CH 3—C—O—CH 3
O O
mnk--2:
mnk--3:
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
13. fuEufyf[kr vfHkfØ;k ds fy, dkSulk vfHkdeZd ç;qDr fd;k tkuk pkfg,A
14. fuEUkfyf[kr vfHkfØ;k ds fy, dkSulk vfHkdeZd ç;qDr fd;k tkrk gSA
vfHkdeZd
(A) KMnO4 / H+ (B) K2Cr2O7 / H+
(C) m-Dyksjks ijcsUktksbd vEy (m-CPBA) (D) CrO3 / H+
15. nh xbZ vfHkfØ;k ds fy,] fuEu es ls dkSulk eq[; mRikn çkIr gksxk \
16. nh xbZ vfHkfØ;k ds fy,] fuEu es ls dkSulk eq[; mRikn çkIr gksxk \
(C) (D)
2. fuEu esa ls dkSulk@dkSuls dkcksZfuy ;kSfxd mi;qDr fxzU;kj vfHkdeZd ds lkFk fØ;k djus ij 2-QsfuyC;wVsu-2-vkWy
cuk ldrk@ldrs gSA
(A) CH3–CO–CH2–CH3 (B) Ph–CO–CH3
(C) Ph–CO–CH2–CH3 (D) mijksDr lHkh
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
3. fuEu esa ls dkSu&dkSu lgh gSa \
H O/ H
(A) CH3–CH2MgBr + HCHO CH3–CH2–CHO
2
DO
(B) CH3–CH2–CHO + LiAlH4 CH3–CH2–CHD–OH
2
HO
(C) CH3–CH2–CHO + NaBD4 CH3–CH2–CHD–OH
2
H SO
(D) CH3–CH2–CHO + NaCN
2 4
4. ,lhVsfYMgkbM dh gkbMªkstu lk;ukbM ds lkFk vfHkfØ;k ds i'pkr~ ty vi?kVu }kjk ,d ;kSfxd curk gS , tks
n'kkZrk gS
(A) izdkf'kd leko;ork (B) T;kferh; leko;ork
(C) e/;ko;ork (D) pyko;ork
5. fuEu esa ls dkSUklk fxzU;kj vfHkØed ds lkFk vfHkfØ;k ugh djrk gSA
6. fuEu esa ls ;kSfxdksa dk dkSulk ;qXe SN2 Th vfHkfØ;k ugh n'kkZ ldrk gS\
(A) CH3COOH & CH3COCl (B) CH3COOCOCH3 & CH3COOCH3
(C) CH3COOCH3 & CH3COCH3 (D) CH3COOH & C2H5COOC2H5
9.
(X)
;kSfxd X, SN2 Th vfHkfØ;k ds izfr lokZf/kd fØ;k'khy gksrk gS] tc P gS&
(A) –CH3 (B) –Br (C) –OCH3 (D) –NO2
10. ; Z ugha gks ldrk gS&
H O
11. 2 A + B
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
12. fuEu esa ls dkSulk vEy ,LVjhdj.k vfHkfØ;k ds izfr lokZf/kd fØ;k'khy gS \
(A) Me–COOH (B) n-PrCOOH (C) Me3CCOOH (D) Et3CCOOH
13. CH3COOH ds lkFk ,LVjhdj.k dh nj lokZfèkd gksxhA
H SO
+ 2
4
15. ;fn isUVsu-2-vksu dk NaBH4 dh mifLFkfr esa vip;u ds ckn D2O }kjk ty vi?kVu ls izkIr mRikn gksxk:
(A) CH3–CH(OD)CH2CH2CH3 (B) CH3CD(OH)CH2CH2H3
(C) CH3CH(OH)CH2CH2CH3 (D) CH3CD(OD)CH2CH2CH3
16. izksisukWu dks fuEu esa ls fdlds lkFk xeZ djus ij curk gS\
(A) CH3MgI rFkk D2O (B) LiAlH4 rFkk D3O+ (C) LiAlD4 rFkk H3O+ (D) NaBH4 rFkk D3O+
(A) (B)
(C) (D)
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
21. 6-czkseks-2-gsDlsuksu dks THF dh mifLFkfr es eSfXuf'k;e ds lkFk fØ;k djkus ij X ,d eq[; mRikn ds :i es curk
gSA
22. dqN vfHkfØ;kvksa ds vadu fuEu izdkj fn;s x;s gS vfHkfØ;k dk dkSulk vad SN2Th vfHkfØ;k gS\
(1) CH3COOH + NaOH CH3COONa + H2O
(2) CH3COOH + SOCl2CH3COCl + SO2 + HCl
AlC·KOH
(3)
23. + + HCl
vfHkfØ;k izdkj ds vadu fuEu izdkj fn;s x;s gSA dkSulk vad mijksDr vfHkfØ;k ds fy, fn;k x;k gS \
(1) SN2Th vfHkfØ;k (2) ukfHkdLusgh ;ksxkRed vfHkfØ;k
(3) ;ksxkRed vfHkfØ;k (4) foyksiu vfHkfØ;k
24. ,LVj A
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
ANSWERS KEY
8. 3 9. 5 10. –3 11. 6
DPP No. # A2
DPP No. # A3
6. 01 7. 02 8. 5 9. 6 10. 4
DPP No. # A4
DPP No. # A5
DPP No. # A6
DPP No. # A7
4. 4 5. 4 6. 2 7. 7
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
DPP No. # A8
DPP No. # A9
6. 6 7. 3 8. 00 9. 8 10. 5
15. 34 16. 6 17. 09 (i, ii, iii, v, vi, vii, viii, ix, x) 18. 2
7. 20 8. 03 9. 05 10. 2 11. 8
7. 02 8. 07 9. 21 10. 8 11. 2
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
7. 3 8. 5 9. 90 10. 5 11. 1
ORGANIC CHEMISTRY
DPP No. # A1
DPP No. # A2
13. (A) (q, r, s); (B) (q, r); (C) (q, r, s); (D) (s)
DPP No. # A3
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
DPP No. # A4
8. 6 9. 4 10. 6 11. 4
DPP No. # A5
DPP No. # A6
DPP No. # A7
DPP No. # A8
21. 3 22. 8 23. 4 24. 6 25. 5
DPP No. # A9
9. 4 10. 9 12. (A – q , s) ; (B – p, q) ; (C – q) ; (D – p, r)
7. 3 8. 7 9. 5
9. 4 10. 4 11. 1
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
PREFACE
This book contains the Daily Practice Problems (DPPs) designed for the aspirants
separate booklets) from multiple topics to understand the application of concepts learned in
theory. Each DPP is kind of a timed test with marking scheme and prescribed time to be spent
on each problem. It is according to the latest pattern of JEE(Advanced) and serves as a great
tool for the students to simulate examination conditions at home. It enables a student to
practice time management while solving a problem which helps him/her to better prepare for
Every effort has been taken to keep this book error free, however any suggestions to improve
(i)
DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
DPP
DAILY PRACTICE PROBLEMS
CHEMISTRY
TARGET: JEE (Main + Advanced)
COURSE : VIJETA (01&02JPB & 03&04JPAB)
Physical / Inorganic Chemistry DPPs (A1 to A20)
Organic Chemistry DPPs (A1 to A14)
INDEX
PHYSICAL / INORGANIC CHEMISTRY DPPS
S. No. Particulars Page No.
1. DPP No. A1 01 – 03
2. DPP No. A2 03 – 05
3. DPP No. A3 06 – 09
4. DPP No. A4 09 – 11
5. DPP No. A5 11 – 14
6. DPP No. A6 14 – 16
7. DPP No. A7 16 – 18
8. DPP No. A8 18 – 21
9. DPP No. A9 21 – 23
10. DPP No. A10 23 – 24
11. DPP No. A11 25 – 27
12. DPP No. A12 27 – 29
13. DPP No. A13 29 – 32
14. DPP No. A14 32 – 34
15. DPP No. A15 34 – 36
16. DPP No. A16 36 – 38
17. DPP No. A17 39 – 41
18. DPP No. A18 41 – 43
19. DPP No. A19 44 – 46
20. DPP No. A20 47 – 49
(ii)
DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
1. DPP No. A1 50 – 52
2. DPP No. A2 52 – 54
3. DPP No. A3 54 – 57
4. DPP No. A4 58 – 59
5. DPP No. A5 60 – 63
6. DPP No. A6 63 – 66
7. DPP No. A7 66 – 69
8. DPP No. A8 69 – 71
9. DPP No. A9 71 – 74
ANSWER KEY 93 – 97
NOTE:
Marked Questions may have for Revision Questions.
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(iii)
DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
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7. A solution is made by dissolving both Ag2CrO4 and Ag2C2O4 until saturation is reached with respect to
both the salts.
Given Ksp (Ag2C2O4) = 10–12
Ksp (Ag2CrO4) = 2 × 10–12
1
Given : 36 3 3.3
Which of the following statement(s) is/are correct with respect to above given information?
(A) In the final solution [Ag+] and [CrO24 ] are 1.8×10–4 M and 0.6 × 10–4 M respectively.
(B) In the final solution [Ag+] and [CrO24 ] are 0.9×10–4 M and 0.6 × 10–4 M respectively.
(C) In the final solution [Ag+] and [C2O24 ] are 3.6×10–4 M and 0.3 × 10–4 M respectively.
(D) In the final solution [Ag+] and [C2O24 ] are 1.8×10–4 M and 0.3 × 10–4 M respectively.
10. Determine G in Joule for the following process for conversion 414 g of H2O(s) to H2O()
H2O(s) H2O()
(6 atm, 273 K) (6 atm, 273 K)
Given : density of H2O(s) = 0.92 g/cm 3, density of H2O() = 1 g/cm3
Give your answer after dividing it by 6 (Take 1 atm L = 100 J)
11. How many of the following statements are correct ?
(a) BeO is amphoteric in nature.
(b) LiHCO3 is not found in solid state.
(c) K2O2 is diamagnetic but KO2 is paramagnetic.
(d) White phosphorous react with castic soda and gives phosphine gas.
(e) AlCl3 is soluble in excess of NaOH and form sodium meta aluminate.
(f) Anhydrous potassium nitrate on heating with potassium metal gives potassium oxide and nitrogen
gas.
(g) Lithium chloride is highly soluble in water.
(h) Hydrated magnesium chloride on heating in dry air gives anhydrous MgCl 2.
12. Match the following for a system involving fixed amount of ideal gas.
Column I Column II
(A) Cyclic process (p) H = 0 & U = 0
(B) Reversible isothermal process (q) Q = –W
(C) Reversible adiabatic process (r) W = 0 and Q = U
(D) Isochoric process (s) Q = 0 and dH = Vdp
15. The henry’s law constant s for H2 O2 and CO2 in water are 1282 L atm/mol, 769.2 Latm/ mol, 29.41 L
atm/ Mol respectively which of these gas has highest concentration in a sample of water at 25 0C when
pressure over water is 1 atm.
(A) H2 (B) O2 (C) CO2 (D) None of these
16. The Henry’s law constant for the solubility of N2 gas in water at 298 K is 2.0 × 105 atm. The mole
fraction of N2 in air is 0.8. The no. of moles of N2 from air dissolved in 5 moles of water of 298 K and 3
atm pressure is:
(A) 2 × 10–5 (B) 6 × 10–5 (C) 9 × 10–4 (D) 9 × 10–5
17. Select correct statements :
(A) Gases which have high value of van der Waals constant ‘a’ are easily liquefied
(B) Easily liquefiable gases are water soluble
(C) Ions forming gases in a solvent are soluble in that solvent
(D) Under same conditions, NH3 has low solubility than that of CO2 .
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2. The correct figure representing isothermal and adiabatic expansions of an ideal gas from a particular
initial state is :
5. For the process H2O() (1 bar, 373 K) H2O(g) (1 bar, 373 K), the correct set of thermodynamic
parameters is:
(A) G = 0, S = + ve (B) G = 0, S = – ve
(C) G = + ve, S = 0 (D) G = – ve, S = + ve
6. XeF6 + SiO2 XeO3 (x) + SiF4 (y)
The hybridisation states of central atoms in the products (x) and (y) are respectively :
(A) sp3 and sp3d (B) sp2 and sp3 (C) both sp3 (D) both sp3d
7. Which of the following salts undergoes anionic hydrolysis?
(A) CuSO4 (B) NH4Cl (C) FeCl3 (D) Na2CO3
Real gas
8. P Ideal gas
V
Which of following statement is incorrect regarding above P-V curve ?
(A) At higher pressure region gas shows positive deviation.
(B) At low pressure region measured and calculated volumes approach each other.
(C) In high pressure region Z > 1 hence gas is less compressible than ideal gas.
(D) In low pressure region Z < 1 hence gas is less compressible than ideal gas.
9. Which of the following figures represents the variation of particle momentum and associated de-Broglie
wavelength.
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10. Zinc and hydrochloric acid react according to the reaction :
Zn(s) + 2HCl(aq.) ZnCl2(aq.) + H2(g)
If 0.3 mole of Zn are added to hydrochloric acid containing 0.52 mole HCl, how many moles of H 2 are
produced:
(A) 0.26 (B) 0.52 (C) 0.14 (D) 0.30
11. Property of the alkaline earth metals that increases with their atomic number is :
(A) ionisation energy (B) solubility of their hydroxides
(C) solubility of their sulphates (D) electronegativity
12. Hydrogen ion concentration in mol/L in a solution of pH = 5.4 will be:
(A) 3.98 × 108 (B) 3.88 × 106 (C) 3.68 × 10–6 (D) 3.98 × 10–6
13. Bond angle of 109º 28' is found in:
(A) NH3 (B) H2O (C) CH3+ (D) NH4+
14. What is the mole ratio of benzene (PB0=
150 torr) and toluene (PT0 = 50 torr) in vapour phase if the
given solution has a vapour pressure of 120 torr?
(A) 7 : 1 (B) 7 : 3 (C) 8 : 1 (D) 7 : 8
15. A 0.20 molar solution of a weak monoprotic acid, HA, has a pH of 3.0. The ionization constant of the
acid is :
(A) 5.0 × 10–7 (B) 2.0 × 10–7 (C) 5.0 × 10–6 (D) 5.0 × 10–3
16. The vapour pressure of a pure liquid A is 40 mmHg at 310 K. The vapour pressure of this liquid in a
solution with liquid B is 32 mmHg. Mole fraction of A in the solution, if it obeys Raoult’s law is:
(A) 0.8 (B) 0.5 (C) 0.2 (D) 0.4
17. The azeotropic mixture of water (B.P. = 100ºC) and HCI (B.P. = 86ºC) boils at about 120ºC During
fractional distillation of this mixture it is possible to obtain:
(A) pure HCI (B) pure H2O
(C) pure H2O as well as pure HCI (D) neither pure H2O nor HCI
18. Which is the correct statement for positive deviation of solution.
(A) The energy released in solvation exceeds the energy used in breaking up interactions/
intermolecular forces.
(B) Solute-solvent interaction is weaker than their own interactions.
(C) Volume would contract during formation of solution.
(D) Boiling point of solution will be higher than expected.
19. An azeotropic solution of two liquids has boiling point lower than that of either of the liquids when it
(A) Shows a negative deviation from Raoult's law
(B) Shows no deviation from Raoult's law
(C) Shows positive deviation from Raoult's law
(D) Is saturated
20. For an ideal solution of A and B liquid, when x A = 0.2, total vapor pressure over solution was 560 torr
and partial pressure of A was 80 torr. What will be the composition of vapor when x A = 0.8 ?
1 8 3 9
(A) yA = (B) yA = (C) yB = (D) yB =
7 11 7 11
21. How many bond pairs of electrons are around N in NO3– ?
22. The number of vacant hybrid orbitals which participate in the formation of 3-centre 2 electron bonds i.e.,
banana bonds in diborane structure is :
23. The pH of 0.1 M RCOOH (Ka = 10–5) aqueous solution is :
24. Find the solubility of As2S3 in a10–2M Na2S solution assuming no hydrolysis of cationic or anionic part.
1
Given: Ksp for As2S3 = × 10–24. Report your answer as Y where : solubility (in mol/L) = Y × 10–11.
625
25. Determine the heat of hydrogenation of ethylene from the following data .
Bond Bond energy Bond Bond energy
HH 104 k Cal CC 80 k Cal
CH 99 k Cal C=C 145 k Cal
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7. A certain mixture of HCl and CH3COOH is 0.1 M in each of the acids. 20 ml of this solution is titrated
against 0.1M NaOH. By how many units does the pH change from the start to the stage when the HCl
is almost completely neutralised and acetic acid remains unreacted ? Ka for acetic acid = 2 x 105.
8. If the pH of a 0.2 M solution of a weak base BOH is 10.3, then find the volume of 0.4 M HCl solution (in
mL) to be added to 20 mL of above base solution to make the pH of the resulting solution equal to 7.3.
(Take log 2 = 0.3)
9. Calculate the number of hours of service that can be derived from an acetylene lamp containing 1 kg
CaC2 if 60 liter acetylene gas at 1 atm & 27°C is needed for 1 hour. (Report your answer in nearst
integer)
10. 10–2 mole of NaOH was added to 10 litre of water at 25ºC, calculate the pH change.
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11. Liquids A and B form an ideal solution. At a certain temperature the total vapour pressure of a mixture
of A and B is 400 mm. The mole fraction of A in the liquid mixture in equilibrium with the vapour phase
is 0.4. If the vapour pressure ratio (PA0/PB0) for the pure liquids at this temperature is 1/6, what is the
Partial pressure of A
10 in the vapour phase?
12. Match the following :
Column Column
(A) 120 g CH3COOH in 1 Ltr solution dsol = 1.2 g / mL (p) M = 2
(B) 120 g glucose dissolved in 1 Ltr solution (dsol = 1.2 g/mL) (q) 10% w/w solution
(C) XNH2CONH2 = 1/31 (aquous solution) (r) 12% w/v solution
(D) 19.6 % (w/v) H2SO4 solution (dsolution = 1.2 g/mL) (s) m = 1.85
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Critical point
The phase boundary between liquid and gas does not continue indefinitely. Instead, it terminates at critical
point on the phase diagram This reflects the fact that, at extremely high temperatures and pressures, the
liquid and gaseous phases become indistinguishable,[2] in what is known as a supercritical fluid.
Fusion(melting) (or freezing) curve(BD) – the curve on a phase diagram which represents the transition
between liquid and solid states
Vaporization (or condensation) curve(BC) – the curve on a phase diagram which represents the
transition between gaseous and liquid states
Sublimation (or deposition) curve (AB) – the curve on a phase diagram which represents the transition
between gaseous and solid states
Normal melting and boiling points can be found from the phase diagram by drawing a line across at 1
atmosphere pressure.
Give the answer of following question by using above phase diagram of CO2.
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
13. What kind of phase change will take place if solid S is kept in the open under normal condition?
(A) Sublimation (B) Melting
(C) Evaporation (D) No change
14. Under which condition, are all the three phases of the system S in equilibrium?
(A) T > 304.2k and P > 72.9 atm (B) T = 216 K and P = 5.2 atm
(C) T > 304.2 K (D) P > 72.9 atm
15. Temperature of the system at X1 is increased at constant pressure to reach X4. Which of the following is
incorrect about the phases of the system at different state.
(A) At X1 solid phase exists.
(B) At X2 solid liquid equilibrium phase exists
(C) At X3 solid-liquid gas equilibrium phase exists.
(D) At X4 vapour phase exists.
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16. If the pressure is increased, the melting temperature of solid S will
(A) Not change (B) Increase (C) Decrease (D) Can’t say
17. What happens to the system at X5 if pressure is changed slowly keeping temperature constant?
(A) At a higher pressure, the system will become liquid
(B) At a lower pressure, the system will become liquid.
(C) The system will be in the same phase
(D) None of these
M
5. The mass of Glucose (C6H12O6) required to prepare 50 mL of its aqueous solution is:
9
(A) 10 g (B) 1 mg (C) 1 g (D) 100 mg
6. For the redox reaction MnO4– + C2O42– + H+ Mn2+ + CO2 + H2O, the correct whole number
stoichiometric coefficients of MnO4–, C2O42– and H+ are respectively :
(A) 2, 5, 16 (B) 5, 2, 8 (C) 2, 5, 8 (D) 5, 2, 16
7. Densities of two gases (having same molar mass) are in the ratio 1 : 2 and their temperatures are in the
ratio 2 : 1, then the ratio of their respective pressure is :
(A) 1 : 1 (B) 1 : 2 (C) 2 : 1 (D) 2 : 3
8. KO2 is used in oxygen cylinder in space air craft and submarines because it
(A) absorbs CO2 and increase O2 content (B) eliminates moisture
(C) absorbs CO2 (D) Produce O2
9. When borax is dissolved in water :
(A) B(OH)3 is formed only (B) [B(OH)4]– is formed only
(C) both B(OH)3 and [B(OH)4]– are formed (D) [B3O3(OH)4]– is formed only
10. Which statement is incorrect –
(A) Ozone (O3) is a planar molecule. (B) Dioxygen (O2) is a diamagnetic species.
(C) Bond order of N2 is greater than N
2 . (D) C2–2 is more stable than C2.
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11. Which of the following salts is least soluble in water ?
(A) CaF2 : Ksp = 3.9 × 10–11 (B) PbCl2 : Ksp = 1.6 × 10–5
(C) AgCl : Ksp = 1.8 × 10 –10
(D) AgIO3 : Ksp = 3.1 × 10–8
(E) All are equally soluble.
12. Value of azimuthal quantum number for the unpaired electron in vanadium atom (Z = 23) be 'b', then
find the value of (b).
(A) 6 (B) 2 (C) 3 (D) 1
(E) zero
13. The number of completely filled orbitals in 29Cu which have only two nodes is :
(A) 5 (B) 9 (C) 3 (D) 7
15. The order of p d interaction in the compounds containing bond between Si/P/S/Cl and oxygen is in
the order.
(A) P > Si > Cl > S (B) Si < P < S < Cl (C) S < Cl < P < Si (D) Si > P > S > Cl
17. How many maximum number of atoms lie in the same plane in the sructure of
methylenesulphurtetrafluoride (CH2SF4) ?
18. Calculate the pH at which Mg(OH)2 begins to precipitate from a solution containing 0.10 M Mg2+ ions.
ksp for Mg(OH)2 = 1.0 × 10–11.
19. Heat of neutralization of oxalic acid is – 25.4 Kcal mol–1 using strong base, NaOH. Then, find the
enthalpy change for the given process:
H2C2O4 2H+ + C2O42–
[Take heat of neutralization of strong acid with strong base = – 13.7 Kcal mol–1]
20. Hydrogen gas saturated with water vapour is confined under a piston in a container with confined
volume 10 litres as shown. The container also contains some liquid water. The partial pressure of H 2
over liquid water is 80 cm of Hg column. If now the piston is moved such that confined volume is
doubled, then find final total pressure over water liquid in the container. (aq. tension = 20 cm of Hg
column)
Total pressure in cm of Hg
(Neglect volume of liquid H2O). (Report your answer as y, where y = )
10
21. An organic compound contains 44.44% carbon by mass. If each molecule of the compound weighs
2.25 × 10–22 g, find the number of C-atoms present in one molecule of organic compound.
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Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
22. Identify the mixture that shows negative deviation solutions.
(A) Benzene + (CH3)2CO (B) (CH3)2CO+ C6H5NH2
(C) CHCl3 + C6H6 (D) (CH3)2CO + CS2
23. At 55ºC, ethanol has a vapour pressure of 168 mm, and the vapour pressure of methyl cyclohexane is
280 mm. A solution of the two in which the mole fraction of ethanol is 0.68, has a total vapour pressure
of 376 mm. This solution is formed from its components with
(A) The evolution of heat
(B) The absorption of heat.
(C) Neither absorption nor evolution of heat
(D) Nothing can be predicted on the basis of given information
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1. The pH at the equivalence point of titration of 10 mL, 0.1 M weak base BOH with 0.1 M HCl is 5. Find
the pKb of BOH : (log 2 = 0.30)
(A) 6.3 (B) 5.3 (C) 4.3 (D) 7.3
(E) none of these
2. 1L of a buffer solution contains one mole of (CH3COO)2Ca and one mole of CH3COOH. Which of the
following statement is correct ? (pKa = 4.7) (log 2 = 0.30)
(A) pH = 9 (B) pOH = 9 (C) pH = 4.4 (D) pOH = 8.6
(E) pH = 14
3. Which of the following statements are correct
(A) It is not possible to compress a gas at a temperature below T C
(B) At a temperature below TC, the molecules are close enough for the attractive forces to act, and
condensation occurs
(C) No condensation takes place above TC
(D) The kinetic energy of the gas molecule is higher above TC, so is considered as super critical fluid.
4. Which is wrong statement about (SiH3)3N is
(A) (SiH3)3N is planar.
(B) (SiH3)3N is linear.
(C) in (SiH3)3N lone pair is present on N doesnot undergo back bonding.
(D) there are 9 sigma bond in the above molecule.
5. An ideal gas at initial pressure Pi and volume Vi undergoes reversible expansion to the same volume Vf
either isothermally or adiabatically. Which of the following statement(s) is (are) correct ?
Where the symbols have their usual meaning.
(A) |Pf (adiabatic) < Pf (isothermal)| (B) |W(adiabatic)| < |W(isothermal)|
(C) |Tf (adiabatic) < Tf (isothermal)| (D) |q(adiabatic)| < |q(isothermal)|
6. For the depression of freezing point experiment involving non-volatile solute. The correct statement(s)
is/are:
(A) Vapour pressure of pure solvent is more than that of solution
(B) Vapour pressure of pure solvent is less than that of solution
(C) Only solute molecules solidify at the freezing point
(D) Only solvent molecules solidify at the freezing point
7. In which of the following pairs of solutions will the values of the van't Hoff factor be the same?
(A) 0.05 M K4 [Fe(CN)6] and 0.10 M FeSO4.
(B) 0.10 M K4[Fe(CN)6] and 0.05 M FeSO4.(NH4)2SO4. 6H2O.
(C) 0.20 M NaCl and 0.10 M BaCl2
(D) 0.05 M FeSO4.(NH4)2SO4.6H2O and 0.02 M KCl . MgCl2 . 6H2O
Comperhension #
The pressure of two pure liquid A and B which form an ideal solutions are 400 mm Hg and 800 mm Hg
respectively at temperature T. A liquid containing 3 : 1 molar composition pressure can be varied. The
solutions is slowly vaporized at temperature T by decreasing the applied pressure starting with a
pressure of 760 mm Hg. A pressure gauge (in mm) Hg is connected which given the reading of
pressure applied.
8. The reading of pressure Gauge at which only liquid phase exists.
(A) 499 (B) 399 (C) 299 (D) None
10. The reading of pressure Gauge at which only vapour phase exists is:
(A) 501 (B) 457.14 (C) 425 (D) 525
11. The pH of a 0.01 M solution of the sodium salt of a monocarboxylic acid is 9. The pKa of the acid will be
………
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12. 20 g of a binary electrolyte (molecular weight = 100) are dissolved in 500 g of water. The freezing point
of the solution is – 0.74°C; Kf = 1.86 K moIality–1, Calculate percentage degree of dissociation of
electrolyte.
13. Consider the following trends in properties of hydrogen halides :
1. Acidic strength : HF < HCl < HBr < HI 2. Thermal stability : HF > HCl > HBr > HI
3. Dipole moment : HF < HCl < HBr < HI 4. Reducing power : HF > HCl > HBr > HI
Find number of correct trends.
14. Match the Column.
Column I Column II
(A) 0.1 M Al2(SO4)3 (p) Solution with highest boiling point
(B) 0.1 M AlPO4 (q) Van't Hoff factor is greater than 1.
(C) 0.1 M urea. (r) Solution with lowest osmotic pressure.
(D) 0.1 M MgCl2 (s) Solution with lowest freezing point.
XA' and XB' represents the mole fraction of A and B in the vapour phase.
PTotal XB ' PB WB PB MB
PTotal XA ' PAº WA PA MA
The masses of the constituents in the vapour (distillate) will be proportional to their respective molar mass of
vapour pressure.
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
15. A mixture of immiscible liquids of an organic liquid and water boils at 90ºC and 732 torr pressure. The
distillate contains 73% by weight of the organic liquid. Calcualte the molar mass of the organic liquid
(vapour pressure of water at 90ºC is 526 torr.)
(A) 168.2 g mol–1 (B) 228.8 g mol–1 (C) 122.2 g mol–1 (D) 62.7 g mol–1
16. When a mixture of water and chlorobenzene (mutually immiscible) is distilled at an external pressure of
740.2 mm Hg, the mixture is found to boil at 90.3ºC, at which temperature the vapor pressure of pure
water is 350.1 mmHg. Calculate the per cent by weight of chlorobenzene in the disillate. (Molecular
weight is 112).
(A) 0.71 (71%) (B) 0.48 (48%) (C) 0.25 (25%) (D) 0.86 (86%)
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17. An unknown compound is immiscible with water. It is steam distilled at 98.00C and P = 737 torr, Pº
(H2O) = 707 torr at 98.0ºC. This distillate was 75% by weight water. Calculate the molecular weight of
the unknown.
(A) M = 141.4 (B) M = 92.1 (C) M = 126.2 (D) M = 186.8
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14. Match List-I with List-II and select the correct answer using the codes given below the lists:
List-I List-II
A. (SiH3)3N 1. 3 centre-2 electron bond
B. BF3 2. sp3-hybridization
C. SiO2 3. p–p bond
D. B2H6 4. p–d bond
A B C D A B C D
(A) 4 2 1 2 (B) 2 3 2 1
(C) 1 2 3 4 (D) 4 3 2 1
15. An aqueous solution of borax is:
(A) Neutral (B) Amphoteric (C) Basic (D) Acidic
16. The oxide which is not a reducing agent is :
(A) CO2 (B) CO (C) SO2 (D) Both (A) & (C)
17. The dipole moment of HBr is 7.95 debye and the intermolecular separation is 1.94 × 10–10 m. Find the
% ionic character in HBr molecule.
18. Calculate % degree of dissociation of 0.5 M NH3 at 25°C in a solution of pH = 12
19. The chemical reaction : A P (Hº = 2.8 kJ) is spontaneous only above 400 K. Find least value of Sº
of the reaction (in J/K).
20. Calculate the weight of residue obtained when CaCO3 is strongly heated and 5.6 litre CO2 is produced
at N.T.P.
21. What is the maximum number of species among the following which are isoelectronic with N2?
CN–, Si, NO–, CO, O22+, C22–, C2H4, CH3+, MgH2
Alums :
Most common examples of double salts include alums. Alums are double sulphate salts, with the general
formula AM(SO4)2·12H2O, where A is a monovalent cation such as K or Na and M is a trivalent metal cation
such as Al or Cr.
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Examples of Alums:
Soda alum: NaAl(SO4)2·12H2O, Ammonium alum: NH4Al(SO4)2·12H2O, Chrome alum: KCr(SO4)2·12H2O
Uses of Alums:
i. as a blood coagulant (usually used after shaving)
ii. as an deodorant due to its antiperspirant and antibacterial properties.
iii. Alum is used to clarify water by hastening sedimentation through the
process of flocculation (sticking together of small suspended particles).
Small, undesirable particles in water stick together (through the use of
electric charge imparted by the alum) forming larger particles which settle
down and can be easily removed. (You will learn more about this point in
Surface Chemistry).
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
22. Which of the following is a double salt?
(A) Al2(SO4)3 (B) NaOH
(C) Na2SO4.Al2(SO4)3.24H2O (D) [Cr(H2O)6]Cl3
23. 1 mole of Carnallite will give how many moles of ions in aqueous solution?
(A) 2 (B) 4 (C) 5 (D) 6
24. Aqueous solution of potash alum will give positive test of which of the following ions?
(A) K+ (B) Al3+ (C) SO42– (D) all of these
25. Aqueous solution of K3[Fe(CN)6] will give positive test of which of the following ions?
(A) K+ (B) Fe2+ (C) Fe3+ (D) CN–
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8. Write IUPAC names of the following
(a) Na2[Fe(CN)5NO] (b) [Ni(DMG)2] (c) NH4[Cr(SCN)4(NO)2] (NO is nitrosyl)
(d) [Pd(H2O)2 I2(ONO)2] (e) [Co(NH3)4 Cl(NCS)]+ (f) K4[FeO4]
(g) K2[Co(N3)4] (h) [Ni(PPh3)2Cl2] (i) [Cr(acac)3] (j) [Pt(C5H5N)4][PtCl4]
9. Write the structural formula corresponding to each of the following IUPAC names :
(a) hexaaquairon (II) chloride (b) potassium tetrafluoridoargentate (III)
(c) pentachloridotitanate (II) ion (d) tetraamminedichloridocobalt (III) chloride
(e) dicyanido-C-argentate (I) ion (f) diamminetetrachloridonickelate (II) ion
(g) tris(ethylenediamine)copper(II) sulphate (h) sodium diaquatetrahydroxidoaluminate (III)
(i) amminechloridobis(ethylene diamine)chromium(III) sulphate
(j) potassium tetracyanido-C-zincate (II)
10. Match the ligands listed in column–I with the characteristic(s)/type of ligands listed in column–II.
Column-I Column-II
A. Acetyl acetonato (p) Resonance stabilization
B. Oxalato (q) Monoanion
C. Dimethyl glyoximato (r) Chelating ligand
D. Nitrito (s) Ambidentate ligand
(t) Monodentate
NOTE : For resonance stabilization consider the ligands as only free ions.
Tetraaquacobalt(III)––amido––hydroxidotetramminechromium(III) sulphate
Rule 2: When the molecule is symmetrical a more compact name can be given by listing the bridging ligands first:
5
3 1 3
(NH3 )5 Cr OH – Cr (NH3 )5 Cl5
–hydroxidobis(pentaamminechromium(III)) chloride
OR
we could also use Rule 1 to write the name of one side of the bridge then the name of bridging complex
and then the name of the other side of the bridge, like
pentaamminechromium(III)––hydroxidopentaamminechromium(III) chloride
Rule 3: If there are two or more bridging groups of the same kind, this is indicated by di––, tri–– etc.
(SO4)2
di––hydroxidobis(tetraaquairon(III)) sulphate
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Example:
(SO4)2
–amido––hydroxidobis(bis(ethylenediammine)cobalt(III)) sulphate
OR
bis(ethylenediammine)cobalt(III)––amido––hydroxidobis(ethylenediammine)cobalt(III) sulphate
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
11. What is the correct name of
4+
NH3 NH3
H3N O2 NH3
12. Co Co
H3N N NH3
H3N H2 H3N
The bridging ligands in the above complex, if both cobalt ions are in+3 oxidation state, are:
(A) Amide and dioxygen (B) Amide and peroxide
(C) Amide and superoxide (D) Amine and peroxide
13. What is the IUPAC name of [(NH3)5Co–NH2–Co(NH3)5](NO3)5 if both cobalt ions have the same
oxidation number.
(A) –aminobis(pentaaminecobalt(III))nitrate
(B) –amidobis(pentaamminecobalt(III))nitrate
(C) –amidobis(pentaamminecobalt(III))pentanitrate
(D) di-–amidobis(pentaamminecobalt(III))nitrate
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3. In the reaction CS2 () + 3O2 (g) CO2 (g) + 2SO2 (g) H = 265 kcal. The enthalpies of formation of
CO2 and SO2 are both negative and are in the ratio 4 : 3. The enthalpy of formation of CS2 is
+26kcal/mol. Calculate the enthalpy of formation of SO2.
(A) – 90 kcal/mol (B) – 52 kcal/mol (C) – 78 kcal/mol (D) – 71.7 kcal/mol
4. For the reaction at 25°C, X2O4() 2XO2(g); H = 2.1 Kcal and S = 20 cal K–1.
The reaction would be :
(A) spontaneous (B) non-spontaneous (C) at equilibrium (D) unpredictable
5. Which of the following statement is false ?
(A) Two different solutions of sucrose of same molality prepared in different solvents will have the same
depression in freezing point.
(B) The osmotic pressure of a solution is given by the equation = CRT (where C is the molarity of the
solution).
(C) Decreasing order of osmotic pressure for 0.01 M aqueous solutions of barium chloride, potassium
chloride, acetic acid and sucrose is BaCl 2 > KCl > CH3COOH > sucrose
(D) According to Raoult’s law, the vapour pressure exerted by a volatile component of a solution is
directly proportional to its mole fraction in the solution.
6. The species C2
(A) Has one bond and one bond (B) Has both bond
(C) Has both bonds (D) Does not exist
7. An acid solution of pH = 6 is diluted 1000 times, the pH of the final solution becomes.
(A) 6.99 (B) 6 (C) 3 (D) 9
8. Which of the following has highest electron affinity?
(A) Li+ (B) Na+ (C) F– (D) Cl–
9. A pre-weighed vessel was filled with oxygen at NTP and weighed. It was then evacuated, filled with
SO3 at the same temperature and pressure and again weighed. The weight of oxygen will be–
(A) Same as that of SO3 (B) 4 times that of SO3
(C) 0.4 times that of SO3 (D) 0.25 times that of SO3
10. Which will give maximum [H+] ion concentration by dissolving equal moles in water
(A) LiOH (B) NaOH (C) KOH (D) RbOH
11. A chloride dissolves appreciably in cold water. When placed on a platinum wire in Bunsen flame, no
distinctive colour is noticed. The cation is–
(A) Ca2+ (B) Mg2+ (C) Ba2+ (D) Pb2+
12. The solvent which is better to be used during ebullioscopic, measurement has–
(A) High Kb (B) Low Kb (C) Kb = Kf (D) Kf < Kb
13. Standard molar enthalpy of formation of CO2 is equal to -
(A) zero
(B) the standard molar enthalpy of combustion of gaseous carbon
(C) the sum of standard molar enthalpies of CO & O2
(D) the standard molar enthalpy of combustion of C(s)
14. Arrange the alkalline earth metals in decreasing order of size of their hydrated ion :
(A) Be2+ (aq) > Mg2+ (aq) > Ca2+ (aq) > Sr2+ (aq) > Ba2+ (aq)
(B) Ba2+ (aq) > Sr2+ (aq) > Ca2+ (aq) > Mg2+ (aq) > Be2+ (aq)
(C) Be2+ (aq) > Mg2+ (aq) > Ca2+ (aq) > Ba2+ (aq) > Sr2+ (aq)
(D) Ba2+ (aq) > Sr2+ (aq) > Mg2+ (aq) > Ca2+ (aq) > Be2+ (aq)
15. Which of the following pairs of name and formula of complexes, is not correct?
(A) Tetraamminecopper(II) sulphate............. [Cu(NH3)4]SO4
(B) Diamminesilver(I) chloride ................ [Ag(NH3)2]Cl
(C) Potassium hexacyanido-C-ferrate(II) ............... K4[Fe(CN) 6]
(D) Potassium amminepentachloridoplatinate(II) ................. K[Pt(NH3)Cl5]
16. The correct order of hybridisation of the central atom in the following species NF3, BF3, PF5 and [SiF6]2–is:
(A) sp2, sp3, sp3d2, sp3d (B) sp3, sp2, sp3d, sp3d2
2 3 3 3 2
(C) sp , sp , sp d, sp d (D) sp3, sp2, sp3d2, sp3d3
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17. How many of the following molecules / ions may act as a bidentate ligand ?
CO32– NH2 – CH2 – COO– EDTA4– C2O42– SO42–
CH3COCHCOCH3 –
CH3C N SCN¯ DMG
18. In the disproportionation reaction of NaOH with one molecule of P4, number of molecules of NaOH
reacting are .............. .
19. The element respresented by the symbol Une belong to pth group of moden periodic table. Also the
element having highest value of electron gain enthalpy (released energy) has atomic number q. Find
the value of (q –p).
20. A buffer solution is made by mixing a weak acid HA (Ka = 10–6) with its salt NaA in equal molar amounts.
What should be the millimoles of acid or salt that should be added to make 180 ml of buffer solution in
which if 0.1 mole of strong acid are added into 1 L of this buffer solution then change in pH is unity ?
21. Calculate the magnitude of work done (in cal.) an open vessel at 300 K, when 112 g iron reacts with dil.
HCl. (Report your answer after division with 100)
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23. Select the correct option for the rosy red complex obtained in the detection of Ni 2+.
(A) Coordination number of Ni is 4 (B) The complex is square planar
(C) Chelating ligand is present in the complex (D) All of the above are correct
24. Which of the following complexes is not blue?
(A) Co[Hg(SCN)4] (B) Fe4[Fe(CN)6]3 (C) [Cu(NH3)4]SO4 (D) [Fe(H2O)5(SCN)]2+
25. Which of the following precipitates are yellow?
(A) K3[Co(NO2)6 (B) (NH4)2[PtCl6] (C) K2[PtCl6] (D) [Fe(H2O)5(NO+)]SO4
P P T T
2. CCl4 and acetone form a non-ideal solution at room temperature in a copper container. For this
process, the true statement(s) is (are) :
(A) G is positive (B) Ssystem is positive (C) Ssurroundings < 0 (D) H > 0
3. Which of the following statement(s) is/are true.
(A) Chelation effect is maximum for five and six membered rings.
(B) Chelating ligands are at least bidentate ligand.
(C) As the number of rings in a complex increase stability of complex (Chelate) also increases.
(D) Azide ion (N3–) has two N as donor atoms and behaves as a chelating ligand.
4. It is an experiment fact that :
DMG + Ni()salt + NH4OH Red ppt.
Which of the following is/are true about this red ppt :
(A) It is a non–ionic complex (B) It involves intra molecular H–bonding
(C) Ni() is sp3 hybridised (D) It is a diamagnetic complex
H2O
5. Li + H2 A B+C
(gas)
AlH3
D
(A) A can act as reducing agent (B) C is a paramagnetic gas
(C) D is a complex compound (D) B is a base.
B
5 C
A real gas is subjected to change in state from A to C by path and N
P 2
6. , if U for path is 2J then find the heat absorbed by gas in path m
(in joule 3 A
1 2 V(m3)
7. Oxidation states of iron in the complexes [Fe(H2O)5(NO)]2+ and [Fe(CN)5(NO)]2– are x and y
respectively. Then (x + y) is equal to :
8. Diborane reacts with ammonia to produce dense white fumes of (A). (A) is solid at room temperature.
On heating under pressure, it releases a combustible gas to produce a liquid (B) and finally a white
coloured solid (C). The total number of hydrogen atoms in molecular formula of (C) is:
9. If elevation in boiling point when AB is dissolved in water to make saturated solution at 25°C is
2 × 10–4 ºC and Ksp of AB is 4 × 10–x then determine the value of x. (Assume = 1, Molality Molarity
(Given Kb = 0.5 K/m.)
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10. How many of the following are bidentate ligand?
Oxalate, Glycinate, Hydrazine, Cyanide, Acetylacetonate, Diethylenetriamine, dmg, Ammonia,
Sulphate, Water.
11. An ideal monoatomic gas initially in state 1 with pressure P 1 = 20 atm and volume V1 = 1500 cm3. It is
then taken to state 2 with pressure P2 = 1.5 P1 and volume V2 = 2V1. Find the change in internal energy
in this process in KJ. (Take 1 atm lit 100 J)
12. How many of the following are diamagnetic ?
(a) K4[Fe(CN)6] (b) Na3[Co(ox)3] (c) [Pt(NH3)3Cl] Br (d) [Fe(H2O)6]2+
(e) [Zn(NH3)4] Cl2 (f) [MnO4]2– (g) Li[AlH4] (h) [V(H2O)6]2+
13. In how many of the following molecules/ions, the number of electrons in molecular orbital (both &
*) are more than or equal to 9. (In ground state)
(a) N2 (b) N2 (c) Be2 (d) B 2 (e) B2 (f) C22
(g) C2 (h) H2 (i) Li2 (j) O 2 (k) F2
14. Match the column :
Column I Column II
A. O2, O2+, O2– (p) Diamagnetic
B. O22–, C2 ,C22– (q) Same bond order
C. N2 ,CO, NO+ (r) Paramagnetic
D. He2, Be2, B22+ (s) Isoelectronic
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
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15. Which of the following relations is not correct?
(A) o < t (B) o (9/4)t (C) sp > t (D) sp = 1.30
16. Select the correct statement?
(A) In tetrahedral field z2 lies higher in energy than xy
(B) Splitting in square planar field is less than that in tetrahedral field
(C) In square planar field five d-orbitals are split into 2 different energy levels.
(D) In octahedral field t2g orbital lie lower in energy than eg orbitals
17. Which d-orbital has the highest energy in square planar field?]
(A) x2 – y2 (B) z2 (C) xy (D) yz
18. Magnitude of depends on
(A) the metal’s oxidation state (B) nature of the metal
(C) number of ligands surrounding the metal (D) strength of ligand
1. Enthalpy of solution of CsBr(s) is 10 kJ.mol1. If the enthalpies of hydration of Cs+(g) and Br(g) are
475 and 655 kJ.mol, what should be the lattice energy of CsBr(s) in kJ.mol 1 ?
(A) 1120 (B) 1130 (C) 1140 (D) 1150
2. In the reaction, xVO + yFe2O3 FeO + V2O5. What is the value of x and y respectively?
(A) 1, 1 (B) 2, 3 (C) 3, 2 (D) None of these
3. How many grams of NaCl must be dissolved in 225 g of water to yield a solution having the same
boiling point as that containing 20 g glucose (M – 180) and 30 g sucrose (M – 342) in 225 g of water?
(Na – 23, Cl – 35.5)
(A) 5.8 (B) 11.6 (C) 12.3 (D) None of these
4. For an equilibrium reaction A(g) + B (g) C (g), H =+ ve
an increase in temperature would cause
(A) an increase in the value of Keq (B) a decrease in the value of Keq
(C) no change in the value of Keq.
(D) a change in Keq which cannot be qualitatively predicted.
5. If the shortest wavelength of H atom in Lyman series is x. Then longest wavelength in Balmer series of
He+ is :
9x 36x x 5x
(A) (B) (C) (D)
5 5 4 9
6. The density of water at 4°C is 1.0 × 103 kg m–3. The volume occupied by one molecule of water is
approximately.
(A) 3.0 × 10–23 mL (B) 6.0 × 10–22 mL (C) 3.0 × 10–21 mL (D) 9.0 × 10–23 mL
7. The compressibility factor of He is:
(A) Linearly increasing with volume (B) Linearly increasing with pressure
(C) Equal to 1 (D) Linearly decreasing with pressure
8. Given the following reaction at equilibrium
N2(g) + 3H2 (g) 2NH3 (g)
Some inert gas is added at constant volume. Predict which of the following facts will be affected ?
(A) More of NH3(g) is produced.
(B) Less of NH3(g) is produced
(C) No affect on the degree of advancement of the reaction at equilibrium.
(D) Kp of the reaction is increased.
9. It is known that atoms contain protons, neutrons and electrons. If the mass of neutron is assumed tobe
half of its original value whereas that of electron is assumed to be twice of this original value. The
atomic mass of C612 will be :
(A) Twice (B) 75% less (C) 25% less (D) one-half of its
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10. Which of the following combination has maximum tendency to form adduct?
(A) BF3 + NH3 (B) BCl3 + NH3 (C) BBr3 + NH3 (D) B3 + NH3
11. All the following complex ions are found to be paramagnetic :
P : [FeF6]3– ; Q : [CoF6]3– ; R : [V(H2O)6]3+ ; S : [Ti(H2O)6]3+
The correct order of their paramagnetic moment (spin only) is :
(A) P > Q > R > S (B) P < Q < R < S (C) P = Q = R = S (D) P > R > Q > S
12. The crystal field-splitting for Cr3+ ion in octahedral field increases for ligands I–, H2O, NH3 , CN– and the
order is :
(A) I– < H2O < NH3 < CN– (B) CN– < I– < H2O < NH3
(C) CN < NH3 < H2O < I
– –
(D) NH3 < H2O < I– < CN–
13. In which of the following configurations will there be the possibility of both para and diamagnestism,
depending on the nature of the ligands?
(A) d7 (B) d3 (C) d6 (D) d5
14. The complex for which the calculation of crystal field splitting can be most easily done, by knowing its
absorption spectrum, will be:
(A) [TiCl6]2– (B) [Fe(H2O)6]2+ (C) [Ti(CN)6]3– (D)[CoF6]3–
15. The correct order for the CFSE (numerical value) for the following complexes is:
Complex P Q R S
Formula [CoF6]3– [Co(CN)6]3– [Co(NH3)6]3+ [Co(H2O)6]3+
(A) P > Q > R > S (B) Q > R > S > P (C) S > R > P > Q (D) R > Q > P > S
16. Statement-1 : For cyclic process U = 0
Statement-2 : Work & heat are significant only when the system undergoes a change.
(A) Statement-1 is True, statement-2 is True; statement-2 is a correct explanation for statement-1.
(B) Statement-1 is True, statement-2 is True; statement-2 is NOT a correct explanation for statement-1
(C) Statement-1 is True, statement-2 is False
(D) Statement-1 is False, statement-2 is True
17. The chemical formula of the compound of calcium obtained by heating calcium oxide with coke in
electric furnace up to 2273-3273 K temperature will be
(A) Ca2C (B) CaC2 (C) CaCO3 (D) Ca(OH)2
18. The hybridised states of carbon atoms in diamond and fullerene (C60) respectively are
(A) sp3 and sp2 (B) sp2 and sp3 (C) sp3 and sp (D) sp3 in both
19. 0.308 g CO2 is obtained on the combustion of 0.21 g organic compound. The percentage of carbon in
the compound is
(A) 40% (B) 4% (C) 14.67% (D) 13.5%
20. The correct order of stability of O2, O2 , O2– and O2–
2 according to Molecular Orbital theory is
21. How many P-P single bonds are present in white phosphrus (P4) molecule ?
22. A six co-ordinate complex has the formula CoCl 3.5NH3 .H2O. Electrical conductance measurements
indicate the presence of three ions in one formula unit. How many moles of AgCl will be percipitated
with AgNO3 solution with one mole of complex ?
23. In a system, where E = – 15 kJ, a piston expanded against a external pressure of 1.2 atm giving a
change in volume of 75 lt. What was the magnitude of change in heat energy of this system (in kJ) ?
(Take 1 lt atm = 100 J).
24. The vapour pressure of two pure liquids A and B are 5 and 10 torr respectively then calculate the total
pressure of the solution (in torr) obtained by mixing 2 moles of A and 3 moles of B.
25. The relative density of a gas A with respect to oxygen gas is 1/4. What would be the mass (in amu) of
one molecule of the Gas A.
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9. Match Column-I with Column-II and select the correct answer with respect to hybridisation using the
codes given below :
Column - I Column - II
(Complex) (Hybridisation)
(I) [Ni(CN)4]2– (p) dsp2 hybridisation
3–
(II) [Cu(CN)4] (q) sp3 hybridisation
(III) [Co(C2O4)3]3– (r) sp3d2 hybridisation
(IV) [Fe(H2O)5NO]2+ (s) d2sp3 hybridisation
Codes :
(I) (II) (III) (IV) (I) (II) (III) (IV)
(A) q p r s (B) p q s r
(C) p q r s (D) q p s r
10. In which of the following processes on an ideal gas, there occurs an increase in entropy of the system :
(A) Reversible Isothermal expansion.
(B) Irreversible adiabatic compression.
(C) Isothermal free expansion (against vacuum)
(D) Reversible adiabatic expansion.
11. Which of the following is correct for standard enthalpy of formation?
(A) It is always negative.
(B) It is found for one mole of compound in standard state.
(C) It is zero for all species in standard state.
(D) It is zero for white phorphrous, which is least stable form of phosphorous.
12. Consider the following system :
Three different aqueous solution each having volume 100 ml are taken and kept in contact as shown.
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14. Which of the following statements is false :
(A) Work done by the gas in process-I is less than the work done by surroundings in process-II
(magnitude wise).
(B) Heat absorbed by the gas in process-I is less than the heat released by the gas in process-II
(magnitude wise).
(C) Both system and surroundings are restored back to their original state after process-I and II have
been performed on gas sample.
(D) None of these
15. Find the bond enthalpy of C – Cl bond (kJ/mol),given that
C2H6(g) + Cl2(g) C2H5Cl(g) + HCl (g) H = –117 KJ/mol
Cl – Cl = 242 kJ/mol
C – H = 412 kJ/mol
H–Cl = 431 kJ/mol
Given your answer by dividing it by 10.
16. 1 mole of an ideal gas is subjected to a reversible process as shown in the figure.
B
(1.5Pa,2m )
–3
A
P(pascal)
(1Pa,1m–3)
1
(m –3)
V
Calculate the work done (in joule) in the process. [ln 2 = 0.7]
Report your answer after multipling with 10.
17. How many of the following reactions or processes is/are exothermic ?
(i) 2H(g) H2(g) (ii) C(diamond) C(graphite) (iii) CH4 + O2 CO2 + H2O
(iv) C2H6 C2H4(g) + H2(g) (v) cis-2-butene trans-2-butene (vi) white P red P.
(vii) H2O() H2O(s) (viii) Na+(g) + aq Na+(aq) (ix) NaOH+H2SO4Na2SO4+H2O
(x) HNO3 + water Solution. (xi) ethanol + water Solution.
A gas 'X' is present with saturated water vapour over water Partial
pressure
liquid at total pressure of 1.5 atm. Vapour pressure of H2O at of 'X' Slope = 38 × 105 torr
18. same temperature is 0.5 atm. What is the solubility of gas 'X' in
terms of millimoles in 10 mole H2O() ? ( nH2O nx )
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2. Equimolar solution of AOH and BOH are prepared. The I.P. of A and B are 5.1 and 13.0eV respectively.
The E.N. of A and B are 0.9 and 3.2 respectively. Reviewing the data pick out the correct statement(s).
(A) Solution of BOH will give effervescence with sodium carbonate.
(B) Phenolphthalein will give pink colour with AOH solution.
(C) BOH solution will show a PH > 7.
(D) Treatment of NH4Cl with AOH will lead to liberation of ammonia.
3. The green coloured complex K2[Cr(CN)4(NH3)(NO)] is paramagnetic and its paramagnetic moment
(spin only) is 1.73 B.M. Which of the following is/are correct about it :
(A) Its IUPAC name is Potassium amminetetracyanonitrosoniumchromate ()
(B) Hybridisation state of chromium is d2sp3
(C) It can show linkage isomerism
(D) It cannot show geometrical isomerism
4. Which are correct statements ?
(A) [Ag(NH3)2]+ is linear with sp hybridised Ag+ ion.
(B) NiCl42–, VO43– and MnO4– have tetrahedral geometry
(C) [Cu(NH3)4]2+, [Pt(NH3)4]2+ and [Ni(CN)4]2– have dsp2 hybridisation of the metal ion
(D) Fe(CO)5 have bipyramidal structure with dsp3 hybridised iron.
5. Which of the following statements is/are correct :
(A) Among NaF & NaBF4, NaF is relatively less soluble in water.
(B) Larger negative value of lattice enthalpy is a favourable condition for formation of ionic bond.
(C) In general, ionic compounds do not conduct electricity in solid state.
(D) The water solubility of alkalline earth metal carbonates increases on moving down the group.
6. Which of the following do not exist?
(A) SH6 (B) HFO4 (C) FeI3 (D) HClO3
7. Find pH of solution obtained by titrating 0.12 M, 50 ml solution of weak acid with 0.06 M, 50 ml NaOH.
The dissociation constant of weak acid is 2 10–2. Give your answer by multiplying with 10.
8. Depression of freezing point of 0.01 molal aqueous CH3COOH is 0.0198ºC. 1 molal urea solution
freezes at –1.8ºC. Assuming molarity is equal to molality, pH of CH3COOH solution is :
9. How many of the following statement(s) is/are correct ?
(a) Hexacarbonylchromium(0) is d2sp3 hybridised and diamagnetic.
(b) The number of unpaired electron in d6, low spin, octahedral complex is 2.
(c) [Ag(NH3)2]Cl does not show paramagnetism.
(d) Lower charge density of metal ion increases the stability of metal ion complex.
(e) Ferrocene is an aromatic compound.
(f) Oxidation state of iron in ferrocene is +3.
(g) Metal carbonyl [Mn(CO)6]+ has stronger C–O bond than [Cr(CO)6].
(h) Complex [Co(CN)6]3– has larger value of o than the complex [Co(H2O)6]3+.
(i) Azide ion is an ambidentate ligand.
(j) IUPAC name of K2[PtCl6] is Potassium hexachloridoplatinum(IV).
10. NaOH + S [X] + [Y] + H2O
Total sum of individual oxidation number of all S atoms present in product [X] & [Y] is .............
11. Number of stereo isomers of [Cr(NO3)3 (NH3)3] = x
Number of stereo isomers of K3[CoCl2(C2O4)2] = y
Number of stereo isomers of [CoBrCl(en)2] = z
find x + y + z :
12. When white phosphorus (P4) reacts with caustic soda solution PH3 & NaH2PO2 are obtained. When
reaction is balanced x is the sum of stochiometric coefficients of P4, caustic soda, PH3 & NaH2PO2, find x.
13. Match the following
Column I Column II
A. [Cr(NH3)6]3+ (p) d2sp3
B. [Co(en)3]3+ (q) CFSE = – 1.2 0
C. [Co(NO2)6]4– (r) Paramagnetic
D. [Co(H2O)6]2+ (s) sp3d2
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c
Cubic ; Tetragonal c
; Orthorhombic ; Monoclinic ;
b c
b c
b
a a a
b
a
c
c c
Hexagonal ; Rhombohedral ; Triclinic
b
b
a a
b
a
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
14. The lattice parameters of a given crystals are a = 8.42 Å, b = 8.42 Å and c = 9.80 Å. There coordinate
axes are mutually perpendicular to each other. The crystal is:
(A) Tetragonal (B) Ortho rhombic (C) Monoclinic (D) Trigonal
15. The crystal dimensions a = b c; = = 900 = 1200 represents.
(A) Tetragonal (B) Hexagonal system (C) Monoclinic (D) Orthorhombic system
16. Which of the following unit cells has least symmetry ?
(A) Tetragonal (B) Monoclinic (C) Triclinic (D) Cubic
17. Among the unit cells given below, which has highest symmetry?
(A) Hexagonal (B) Orthorhombic (C) Cubic (D) Monoclinic
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
1. Look at the AB solid structure and use it to calculate r+ / r– .
A+ -
M N B
.
K . L
a
(A) 0.155 (B) 0.225 (C) 0.414 (D) 0.732
2. Which of the following is/are true about the complex [PtCl 2(NH3)(OH2)];[Atomic no. of Pt = 78]
(A) It will have two geometrical isomeric forms, cis and trans
(B) It is a square planar complex
(C) It is a diamagnetic complex (D) It can show hydrate isomerism
3. Which is/are correct statement (s)?
(A) [Co(en)3] [Cr(CN)6] will display coordination isomerism.
(B) [Mn(CO)5(SCN)] will display linkage isomerism.
(C) [Co(NH3)5(NO3)]SO4 will display ionisation isomerism
(D) None is correct.
4. The compound Na2IrCl6 reacts with triphenylphosphine in diethyleneglycol in an atmosphere of CO to
give [IrCl(CO)(PPh3)2], known as 'Vaska's compound'. (Atomic number of Ir = 77)
Which of the following statements is /are correct?
(A) The IUPAC name of the complex is carbonylchloridobis(triphenylphosphine)iridium(I).
(B) The hybridisation of the metal ion is sp3 .
(C) The magnetic moment (spin only) of the complex is zero.
(D) The complex shows geometrical as well as ionization isomerism.
5. The correct statement(s) regarding defects solids is (are)
(A) Schottky defect is usually favoured by small difference in the sizes of cation and anion.
(B) Schottky defect lowers the density of solids.
(C) Compounds having F-centres are diamagnetic.
(D) Frenkel defect is a dislocation defect.
6. Which of the following is/are incorrect for Rock salt crystal :
(A) If all Na+ ions occupied at body centre are removed according to schottky defect then formula of
resulting ionic compound would be Na3Cl4.
(B) If Na+ ions would be present in alternate tetrahedral voids then formula would be Na2Cl.
(C) If some Cl– get displaced from the lattice in the presence of Na vapours then colour of compound
will change.
(D) If interionic distance in crystal is 4.2 Å then edge length of unit cell becomes equal to 8.4 Å.
7. Consider the following arrangement :
x
If O2 and N2 are assumed to behave ideally, then on removing partition X (smoothly), how many of the
following are expected to be correct for this process ?
(i) Ssys < 0 (ii) Ssurr < 0 (iii) Suniv > 0 (iv) U > 0
(v) H > 0 (vi) G < 0
8. To get the silicone R3Si–(OSiR2)n–SiR3 having six Si–O–Si linkage x unit of R2SiCl2 and y unit of R3SiCl
is taken. Value of (x + y) is:
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9. A sample of H-like species is in some excited state 'A' and on absorbing a photon of energy 10.2 eV
gets promoted to a new state B. When the electrons from state 'B' return back to ground state directly
or indirectly, photons of 15 different wave lengths are observed in which only 9 photon have energy
greater than 10.2 eV. Determine atomic number of H-like species. Give your answer after multiplying by 7.
10. The sum of number of hexagonal and triangular faces that are present in a truncated tetrahedron is :
11. The freezing point of an aqueous solution of KCN containing 0.1892 mol kg–1 was 0.70°C. On adding
0.09 mol of Hg(CN)2 in 1kg of above solution the freezing point of solution was –0.53°C. Assuming that
complex is formed according to the equation. Hg(CN)2 X(CN) [Hg(CN)X 2 ] X
find X (given Kf of water = 1.86K/molal):
12. Argon crystallizes in fcc arrangement, and the density of solid and liquid Ar is 1.59 g cm – 3 and 1.42 g
cm–3 respectively find the approximate percentage of empty space in liquid Ar.
13. Match the following :
Column I Column II
A. 74% occupancy of space (p) Coordination No. of cation in fluorite structure
B. Coordination No -8 (q) Cubic close packing
C. Ca2+ ion in CaF2 (r) Hexagonal close packing
D. Coordination No. – 12 (s) body centred cubic packing.
Anion Cation
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ZnS Type
In ZnS the radius of cation to anion is 0.40 which suggests it to be tetrahedral in shape. Each Zn2+ ion is
tetrahedrally surrounded by four S2– ions and each S2– is tetrahedrally surrounded by four Zn2+ ions. i.e.,
coordination no. of ZnS. is 4.
Thus this structure is termed as 4:4 arrangement it should be noted that zinc blend (ZnS) has ccp structure
while wurtzuite (ZnS) has hcp structure. Other example are CuCI, CuBr, CuI, and BeS.
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
14. In the zinc blende structure, zinc ions occupy alternate tetrahedral voids and S2– ions exist as ccp. The
radii of Zn2+ and S2– ions are 0.83 Å and 1.74 Å respectively. The edge length of the ZnS unit cell is
(A) 2.57 Å (B) 5.14 Å (C) 5.93 Å (D) 4.86 Å
15. If the distance between Na+ and Cl – ions in NaCl crystal is ‘a’ pm, what is the length of the cell edge?
a a
(A) 2a (B) (C) 4a (D)
2 4
16. Which of the following statement is incorrect about rock salt type structure?
(A) It has FCC arrangement of Na+
(B) Na+ & Cl– ions have co-ordination number of 6 : 6.
(C) A unit cell of NaCl consists of four NaCl units
(D) All halides of alkali metals have rock salt type structure.
17. In the zinc blende structure S2– adopt ccp arragement and Zn2+ occupy.
(A) Octahedral sites (B) Hexagonal sites (C) Tetrahedral sites (D) None of these
2. For a real gas with very large value of molar volume, which of the following equation can most suitably
be applied:
a Pb a
(A) Z = 1 – (B) PVm = RT (C) Z = 1 + (D) PVm – RT =
VmRT RT Vm
3. Given that the critical temperature of oxygen is 154K and its critical pressure is 50 atm, which of the
following statements is are true :
I. In a closed container at 154K and 50 atm, the solid, liquid, and gaseous phase of oxygen are in
equilibrium.
II. Oxygen gas can be liquefied at room temperature.
III. It can be reasoned that ammonia has a critical temperature above 154 K.
(A) I is true (B) II and III are true (C) III is true (D) I and III are true
4. Molecule XF4 has non-zero value of dipole moment. Then X is
(A) Xe (B) Si (C) S (D) none of these
5. Which of the following reacts with NaOH to liberate a gas?
(A) S8 (rhombic sulphur) (B) Cl2
(C) P4 (white phosphorus) (D) C (graphite)
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6. A substance absorbs CO2 and violently reacts with water. The substance is :
(A) CaCO3 (B) CaO (C) H2SO4 (D) ZnO
7. Total number of unit cells in 4 g of X (atomic mass = 40), which crystallises in BCC pattern is (N A =
Avogadro's number):
0.1 NA
(A) 0.1 NA (B) 2 × 0.1 NA (C) (D) 2 × NA
2
8. The osmotic pressure of equimolar solutions of BaCl 2, NaCl and glucose will be in the order
(A) glucose > NaCl > BaCl2 (B) BaCl2 > NaCl > glucose
(C) NaCl > BaCl2 > glucose (D) NaCl > glucose > BaCl2
9. Which of the following will exhibit maximum ionic conductivity?
(A) K4[Fe(CN)6] (B) [Co(NH3)6]Cl3 (C) [Cu(NH3)4]Cl2 (D) [Ni(CO)4]
10. Which of the following will give maximum number of isomers ?
(A) [Co(NH3)4Cl2] (B) [Ni (en)(NH3)4]2+ (C) [Ni(C2O4)en2]2– (D) [Cr(SCN)2(NH3)4]+
11. Atomic number of Cr and Fe are respectively 24 and 26, which of the following is paramagnetic with the
spin of electron?
(A) [Cr(CO)6] (B) [Fe(CO)5] (C) [Fe(CN)6]4– (D) [Cr(NH3)6]3+
12. According to IUPAC nomenclature, sodium nitroprusside is named as :
(A) Sodium nitroferricyanide (B) Sodium nitroferrocyanide
(C) Sodium pentacyanidonitrosoniumferratae(II) (D) Sodium pentacyano nitrosylferrate (III)
13. Which of the following coordination compounds would exhibit optical isomerism?
(A) Pentaamminenitrocobalt (III) iodide
(B) Diamminedichloroplatinum (II)
(C) Trans-dicyanobis (ethylenediamine chromium (III) chloride)
(D) Tris-(ethylenediamine) cobalt (III) bromide
14. Which of the following complexes exhibits the highest paramagnetic behaviour?
Where, gly = glycine, en = ethylenediamine and bipy = bipyridyl moities)
(At no Ti = 22, V = 23, Fe = 26, Co = 27)
(A) [V(gly)2(OH)2(NH3)2]+ (B) [Fe(en)(bipy)(NH3)2]2+
(C) [Co(OX)2(OH)2] –
(D) [Ti(NH3)6]3+
15. Which of the following complex ions is not expected to absorb visible light ?
(A) [Ni(CN)4]2– (B) [Cr(NH3)6]3+ (C) [Fe(H2O)6]2+ (D) [Ni(H2O)6]2+
16. In which of the following pairs, both the complexes show optical isomerism ?
(A) cis-[Cr(C2O4)2Cl2]3– , cis-[Co(NH3)4Cl2] (B) [Co(en)3] Cl3 ,cis-[Co(en)2Cl2]Cl
(C) [PtCl(dien)Cl] , [NiCl2Br2]2– (D) [Co(NO3)3(NH3)3], cis-[Pt(en)2Cl2]
17. Calculate total number of possible isomers (structrural and stereoisomers) of the compound
[Ir(en)2(NH3)(NO2)]2+
19. If two solutions of pH = 2 and pH = 4 be mixed respectively in volume ratio 1 : z, the pH of the resulting
solution was found to be 2.75. Find the value of z. (Given : log 1.75 = 0.25)
20. The bond dissociation energy of gaseous H2, Cl2 and HCl are 104, 58 and 103 kcal mol –1 respectively.
Calculate the enthalpy of formation for HCl gas.
21. How many corners are there in octahedron ?
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MnO, MnO2,
This arises when the dipole
Mn2O, FeO, FeO2;
Antiferromagnetic alignment is zero due to equal -
NiO, Cr2O3, CoO,
and opposite alignment.
CO3O4
FeO3O4
(Magnetite),
This arises when there is net
Ferrimagnetic ferrites like -
dipole moment.
MgFe2O4,
ZnFe2O4
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
22. Which of the following is correct option
(A) O2 is show diamagnetic properties. (B) S is show diamagnetic properties.
(C) TiO2 show diamagnetic properties. (D) VO2 show diamagnetic properties.
23. Which is the following is correctly match
(A) Diamagnetic (B) Paramagnetic
(C) Ferromagnetic (D) Antiferromagnetic
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
1. Liquid A having vapour pressure of 100 torr in pure state exhibited vapour pressures of 50 torr and 25
torr when its fixed amount was dissolved in certain amounts of liquid B and liquid C respectively. What
will be the vapour pressure of A when both the solutions are mixed? (Assume ideal mixtures)
(A) 37.5 torr (B) 75 torr (C) 12.5 torr (D*) 33.3 torr
(E) 25 torr
2. Consider a cube containing n unit cells of a cubic system.
A
A
D B
D B
C C
Arrangement of atoms
A plane ABCD obtained by joining the mid points of the edges on one of the its identical faces had
atoms arranged as shown. Let p be the packing fraction. Choose the correct option :
22 11 11 11 3
(A) n = 1 , p = (B*) n = 8 , p = (C) n = 8, p = (D) n = 1 , p =
21 2 21 14 28
4. If heat of formation of PCl3 (g) and PH3 (g) are 140 and 8 KJ mol–1 respectively and heat of atomization
of phosphorous P4(s), chlorine and hydrogen are 320, 120 & 216 KJ mol –1 respectively then, find which
of the following is/are correct statement(s).
(A) The bond energy of P–Cl is 63 KJ mol–1
(B) The bond energy of P–H is 210 KJ mol–1
(C*) Heat of formation of isolated gaseous hydrogen atom is 108 KJ mol –1
(D*) Heat of formation of isolated gaseous chlorine atom is 60 KJ mol –1
5. One mole of an ideal gas contained in a sealed flask at 1 atm is heated from 27ºC to 127ºC. (Given :
S(JK–1) = 10 + 12× 10–3 T, R = 0.082 atm L/mol K, 1 atm L = 101.3 J). Select correct option(s):
(A) V = 12.3 L (B*) Final pressure is 4/3 atm
(C*) G = –589.34J (D) G = 322.5 J
Comprehension #
In the valence bond theory, hybridisation of orbitals is an integral part of bond formation. Hybridisation
consists of mixings or linear combination of the "pure" atomic orbitals in such a way as to form new
hybrid orbitals such as sp, sp2, sp3, sp3d, sp3d2 etc.
Now answer the following questions:
6. Which of the following atomic orbital(s) participates in trigonal bipyramidal hybridisation i.e. sp 3d
hybridisation?
(I) dZ2 (II) d 2 2 (III) dxy (IV) pz
x –y
(A) II, IV (B) III, IV (C*) I, IV (D) Only II
7. Which of the following atomic orbitals participitates in hybridisation in [Pt(NH 3)4]+2 as well as in
[Cr(CN)6]3–?
(I) s (II) d 2 2 (III) d 2 (IV) px
x –y z
(A) III, IV (B) I, III, IV (C) I,II,III, IV (D*) I, II, IV
8. N2H4 is a diprotic base with pKb1 = 5.2, pKb2 = 16.7, 0.1 M aq. solution of N2H62+(Cl–)2 has pH closest to
................. (choose the nearest integer).
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
9. Six identical spheres of radius R are arranged at each corner of prism as shown in the figure. Its
packing fraction is x, then 10x is :
2R
2R
10. A tube of uniform cross sectional area 1 cm 2 is closed at one end with semi permeable membrane. A
solution having 6 g glucose per 100 ml is placed inside the tube and dipped in pure water at 27C.
When the equilibrium is established, what will be the osmotic pressure, height developed in vertical
column (in meters). Density of glucose solution is 1 gm/ml. (Take R = 0.08 L atm mol –1 k–1, density of
Hg = 13.8 g/cc)
11. Total number of geometric isomers possible for the complex [CoL2Cl2]– (unsymmetrical bidentate ligand
L = H2NCH2CH2O–) is:
12. An aqueous solution contains 6% and 4% by weight weak acid (HA) and urea respectively. Depression
13.6
in freezing point of solution is ºC. If Ka of HA is x, then fill the value of 100x. [Kf = 1.8 K-Kg/mole]
3
(Molecular weight of HA = 60, dsolution = 1gm/ml). Assume no reaction between HA and urea.
15. Equal volume of 0.2 M CH3COOH is mixed with 0.2 M NaOH solution then determine pH of resulting
solution? Write your answer after multiplying by 9. [Ka(CH3COOH) = 10–5]
16. A 0.25 molal aqueous solution of Co(NH3)4Cl3 freezes at –0.93ºC. Calculate the number of
stereoisomers for this coordination compound. Molal depression constant for H2O is 1.86 K/molal.
(Assume complete dissociation of the coordination compound into its ions)
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3. In which of the following molecules central atom involve expansion of octet?
(A) PCl5 (B) SO4– – (C) NH3 (D) ClO3–
4. The qualitative order of Debroglie wavelength for electron, proton and particle is e > P > if
(A) If kinetic energy is same for all particles
(B) If the accelerating potential difference 'V' is same for all the particles (from rest)
(C) If velocities are same for all particles
(D) None of the above
5. An equilibrium A(g) 2B(g) has been established in a one litre container. At equilibrium, moles of A
and moles of B are found to be equal (2 moles each). Now, if the volume of reaction vessel is halved
keeping the temperature constant and the equilibrium is allowed to restablish, then which of the
following statements is/are true ?
(A) The concentrations of A and B at new equilibrium are 4.5 M and 3 M respectively.
(B) The equilibrium can be said to be shifted in forward direction upon reducing the volume to half.
(C) The equilibrium can be said to be shifted in backward direction upon reducing the volume to half.
(D) The equilibrium will not shift in any direction upon reducing the volume to half as moles of A and B
at initial equilibrium are equal (2 each.)
6. In a cubic cell atoms A are present at corners while A atoms are missing from face centers. B atoms
are at edge centers and body center. C atoms are present at the body center of each small cube (edge
length a/2).Then select the correct statement(s) : (a = edge length cube)
(A) Formula of compound is ABC2
(B) If all the atoms along one of the body diagonal are removed then ratio of atoms A,B,C is 1 : 4 : 8 in
resultant structure
(C) Ratio of A, B, C atoms (effectively) in a small cube is 1 : 4 : 8
(D) In small cube only five corners are occupied
7. Depression of freezing point of 0.01 molal aqueous CH3COOH solution is 0.02046°. 1 molal aqueous
urea solution freezes at –1.86°C. Assuming molality to be equal to molarity, calculate pH of CH3COOH
solution.
8. For aqueous solution of how many of the following compounds / mixtures, does the pH remains constant
even upon dilution:
(1) NH4Cl (2) Na2CO3
(3) A 1 : 2 molar ratio mixture of Na2S and HCl. (4) A 5 : 2 molar ratio mixture of NaOH and H3PO4.
(5) A 5 : 4 molar ratio mixture of CH3COONa and HCl.
(6) NaH2PO4 (7) A 2 : 1 molar ratio mixture of HCl and NaHCO3.
(8) CH3COONH4 (9) A 4 : 3 molar ratio mixture of NH4OH and HCl.
500
9. An aqueous m solution of a non-volatile and non-electrolyte solute is taken in a closed container.
81
Calculate percentage relative humidity present inside the container at equilibrium.
10. In how many following species, the central atoms have two lone pairs of electrons ?
XeF4 XeF5– F2SeO2 XeF3+ XeOF4 ClOF3
ICl4–
SCl2 OSF4
11. For the Complex formula [Co(NH3)3(NO2)2Cl] :
The coordination number of central atom = a
The oxidation number of central atom = b
Total number of geometrical isomres (considering all structural isomers) = c
Total number of optical isomres (considering all structural isomers) = d
The value of (a + b - c+ d) for given complex is :
12. Consider the following molecules: O2, Cl2, Li2, H2, B2, C2 and N2
Let a = number of molecules having (bond order = 1)
b = number of molecules having (bond order = 2)
c = number of molecules having (bond order = 3)
d = number of paramagnetic molecules.
Find the value of (a × b × c × d × 4.2).
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13. Match the column
Column – I Column – II
(A) H+ (aq) (p) Hf0 = 0
(B) H (gas) (q) Hf0 0
(C) H2 (gas) (r) Gf0 = 0
(D) C (s, diamond) (s) Hf0 > 0
ChemINFO ELECTROCHEMISTRY
Daily Self-Study Dosage for mastering Chemistry Topic: Galvanic Cell & Salt Bridge
A device used to convert chemical energy produced in a redox reaction into electrical energy is called an
electrochemical cell or simply chemical cell. These are also called galvanic cells or voltaic cells, after the name
of Luigi Galvani (1780) and Alessandro Volta (1800).
If the electrodes in a galvanic cell are not connected internally, initially the cell generates electrical energy. The
electrodes get polarized with passage of time and the cell stops working. For continuous of electrical energy,
the electrodes need to be internally connected.
A salt bridge is usually used to connect the electrodes of a galvanic cell. It is easy to construct and
consists of a gell drawn into a clean U-tube. The gel is formed by adding agar-agar into boiling water containing
a inert electrolyte like KCl. Generally, KCl is preferred because the ionic conductances of K+ and Cl– are almost
the same. The gel holds the electrolyte in the tube as shown in below Fig.
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Cr2O72 0
11. For the cell prepared from electrode A and B, electrode A : , Ered = +1.33 V and electrode B:
3
Cr
3
Fe 0
, Ered = 0.77 V, which of the following statement is not correct?
2
Fe
(A) The electrons will flow from B to A (in the outer circuit) when connections are made.
(B) The standard emf of the cell will be 0.56 V.
(C) A will be positive electrode.
(D) None of the above.
12. Which statement about standard reduction potentials is correct
(A) EH
/H
= Zero at all temperature
2
(B) ED
/D2
= zero at 298 K
(C) A redox reaction is feasible if sum of SRP of oxidant and that of reductant is a positive quantity
(D) K2Cr2O7 (acid) is stronger oxidising agent than KMnO4 (acid)
[Given : EMnO –
/Mn2
= 1.51 V ; E 2 – 3 = 1.33 V]
4 Cr2O7 / Cr
13. A 0.004 M solution of Na2SO4 is isotonic with 0.010 M solution of glucose at same temperature. The
apparent percentage dissociation of Na2SO4 is -
(A) 25% (B) 50% (C) 75% (D) 85%
14. The concentration of free HN3 in a 0.01 M solution of KN3 if Ka = 1.9 × 10–5 is
(A) 2.3 mol/ML (B) 3.3 mol/ML (C) 4.3 mol/ML (D) 5.3 mol/ML
15. An excess of AgNO3 is added to 100 mL of a 0.01M solution of dichlorotetraaquachromium (III)
chloride. The number of moles of AgCl precipitated would be :
(A) 0.002 (B) 0.003 (C) 0.01 (D) 0.001
16. The de Broglie wavelength associated with a ball of mass 1 kg having kinetic energy 0.5 J is :
(A) 6.626 10–34 m (B) 13.20 10–34m (C) 10.38 10–21 m (D) 6.626 10–34 Å
17. The correct order for the wavelength of absorption in the visible region is :
(A) [Ni(NO2)6]4– < [Ni(NH3)6]2+ < [Ni(H2O)6]2+ (B) [Ni(NO2)6]4– < [Ni(H2O)6]2+ < [Ni(NH3)6]2+
2+ 2+ 4+
(C) [Ni(H2O)6] < [Ni(NH3)6] < [Ni(NO2)6] (D) [Ni(NH3)6]2+ < [Ni(H2O)6]2+ < [Ni(NO2)6]4–
Comprehension #
(Read the following passage and answer the questions numbered 18 to 20. They have only one
correct option)
Standard reduction potentials (SRP) for different systems can be used to decide the spontaneity of a
reaction e.g. EZn 2 Zn = – 0.76V, hence for the reaction Zn + 2H+ Zn2+ + H2, G° is negative. It has
been found experimentally that if (SRP of an oxidant – SRP of a reductant) is more than 1.7V, then
their combination may lead to explosion (though it may be prevented by kinetic factors).
Now go through the following data and answer the questions.
Data : EAg /Ag = 0.80 V ; EN /N ¯ = – 3.09 V
2 3
E ¯ = 1.23 V ;
ENa = – 2.71 V
ClO4 / ClO3 /Na
EFe3
/ Fe2
= 0.77 V ; EO2 / H2O2 = – 1.03 V
EH 2O2 / H2O
= 1.76 V ; EO 3 / O2
= 2.07 V
EMnO /Mn2
= 1.54 V ; E = 1.33 V
–
4 Cr2O72 –
/ Cr 3
18. Which of the following ionic combinations may lead to the formation of explosive substance.
(A) Sodium ion and azide ion (B) Silver ion and perchlorate ion
(C) Silver ion and azide ion (D) All the above
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19. Which of the following ions will be capable of causing catalytic decomposition of H2O2.
(A) Fe3+ (B) Fe2+ (C) both (D) None of these
20. Which is correct about the reaction between H2O2 and O3
(A) It is a case of mutual reduction
(B) O3 will oxidise H2O2 into O2
(C) It is not a redox reaction
(D) H2O2 being a stronger oxidising agent will decompose ozone into oxygen
21. The bond order of the underlined species; NOHSO4 is :
22. Specify the most stable complex among the following complexes. (Report your answer as 1 or 2 or 3).
1. [Fe(NH3)6]3+ , 2. [Fe(en)3]3+ , 3. [Fe(dien)2]2+
23. If the de-Broglie wavelength of electron in pth orbit of He+ ion is 11.66 Å, find the value of p. Given
radius of Ist orbit of H-atom is 0.53 Å.
a b c d
24. Find the value of , where a = coordination number in BCC structure; b = coordination
8 6 2 1
number of simple cubical structure; c = effective number of particles in BCC unit cell and d = effective
number of particles in simple cubical unit cell.
25. The density of a gas filled in an electric lamp is 0.75 kg/m 3. When lamp is switched on, the pressure in it
increases from 4 Pa to 25 Pa, then what is increase in urms in m/sec.
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6. An energy of 40.8 eV is required to excite a Hydrogen-like species from 1st Bohr orbit to second. Which
is/are correct statement(s) :
(A) Atomic number of H-like species is 2.
(B) Ionisation energy of H-like species is 122.4 eV.
(C) Kinetic energy of electron in 1st orbit is 54.4 eV.
(D) Energy of second orbit is –13.6 eV.
10 m
9. For a perfectly crystalline solid, (CP)m = aT3, where a is a constant. If (CP)m at 10K is 0.375 J/K-mol,
then find the value of molar entropy at 20K (in J/K-mol).
10. 0.1 M solution of a weak acid HA is titrated against 0.05 N NaOH solution. Calculate pH at 1/4th and
3/4th neutralization of acid. Given that the pH of 0.1 M HA solution is 3.
pH1 pH2
Report your answer as .
2
11. Consider an fcc lattice sectioned along the shaded plane shown in figure.
One such plane is shown in figure. Give the number of atoms in plane
DBF which are in direct contact with an atom placed at point C of metallic
fcc lattice.
12. Calculate (a) Ka for a monobasic acid whose 0.10 M solution has pH of 4.5.
(b) Kb for a monoacidic base whose 0.10 M solution has a pH of 9.7.
Report your answer as 2Kb / Ka.
ChemINFO ELECTROCHEMISTRY
Daily Self-Study Dosage for mastering Chemistry Topic: Lead Storage Batterty (Lead-Acid Battery)
The lead storage battery used in cars was first demonstrated to the French Academy of Sciences by Gaston
plante in 1860. It contained nine cells in parallel and was able to deliver extraordinarily large currents. The cells
were constructed from lead plates separated by layers of flannel that were immersed in a 10% H2SO4 solution.
As might be expected, the system soon became known as the
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Lead-acid battery
Lead storage cell consists of lead grid filled with spongy lead which acts as the anode and a lead grid packed
with lead oxide that acts as the cathode. A number of (generally six) such electrode pairs are dipped in
sulphuric acid solution (20%) which acts as the electrolyte and these are separated by inert and porous
partitions. When the battery discharges, PbO2 is reduced to PbSO4 . When it is charged, the reaction is
reversed. The standard electrode potential for the half-reaction is 1.682 V. The cell reactions are as follows:
At the anode: Pb(s) + SO42– (aq) PbSO4(s) + 2e–
At the cathode: PbO2(s) + 4H+ (aq) + SO42– (aq) + 2e– PbSO4(s) + 2H2O(I)
Overall reaction: Pb(s) + PbO2(s) + 2H2SO4 (aq) 2PbSO4(s) + 2H2O(I)
The cell reaction shows that the electrolyte H2SO4 is consumed during the reaction, so as the reaction
proceeds, the concentration of H2SO4 decreases. Once the concentration of H2SO4 has fallen to a certain
permissible level, the battery needs to be recharged by reversing the discharge reaction. For this, an external
potential higher than the cell potential is applied. The cell then operates like an electrolyte cell and the PbSO 4
deposited on the electrodes is reverted to Pb and PbO2 by the following reactions:
At the anode: PbSO4(s) + 2H2O(I) PbO2(s) + 4H+ (aq) + SO42– (aq) + 2e–
At the cathode: PbSO4(s) + 2e– Pb(s) + SO42–(aq)
Overall reaction: 2PbSO4(s) + 2H2O(I) Pb(s) + PbO2(s) + 4H+ (aq) + 2SO42–(aq)
The cell reactions show that the concentration of H2SO4 increases during recharging of the cell. The potential
developed by each electrode pair is about 2V and higher potential can be obtained by connecting a number of
electrode pairs in series. These batteries find extensive use as automobile batteries, besides being used for
electrical supply in trains, hospitals, etc.
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
14.Th cathode reaction during the charging of a lead-acid battery leads to the
(A) Formation of PbSO4 (B) Reduction of Pb2+ to Pb
(C) Formation of PbO2 (D) Deposition of Pb at the anode
15. In a lead storage battery
(A) Pb is oxidized to PbSO4 at the anode
(B) PbO2 is reduced to PbSO4 at the cathode
(C) Both electrodes are immersed in the same aqueous solution of H2SO4
(D) All the above are true
16. Which of the following reactions occurs at the anode during the recharging of lead storage battery ?
(A) Pb + SO42– PbSO4 + 2e– (B) Pb + PbO2 + H2SO4 2PbSO4 + 2H2O
(C) PbSO4 + 2e– Pb + SO42– (D) PbSO4 + 2H2O PbO2 + 4H+ + SO42– + 2e–
17. When a lead storage battery is discharged,
(A) SO2 is evolved (B) Lead is formed
(C) Lead sulphate is consumed (D) Sulphuric acid is consumed
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4. Which of the following relations hold good (where symbols have their usual meaning) :
T2 T
(A) a C (B) b C (C) A and B both (D) None of these
PC PC
7. In which of the following cases, vapour pressure is more as compared to I. (Consider all solutes to be
non-volatile solutes).
I = 0.2 m solution of C12H22O11.
II = Mixture of 1011.6 g, 0.2 molal acetone and 1012 g, 0.2 molal urea.
III = Solution of 0.2 mol NaOH in 1 Kg water.
IV = Solution of 0.2 mol NaCl in 3 Kg water.
(A) II (B) III (C) IV (D) None
8. Which of the following is paramagnetic in nature?
II
(A) K 4 [F e(CN)5 (O2 )] (B) Na 4 [Fe(CN)5 (NOS)]
3
(C) [Co(H2O)6 ] (D) (A) & (C)
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11. Which of the following is not a function of salt bridge in an electrochemical cell ?
(A) To maintain electrical neutrality of the solution
(B) To complete the circuit so that current can flow.
(C) To supply ions to cathodic and anodic compartment.
(D) To increase cell voltage
12. What is the concentration of nitrate ions if equal volumes of 0.1 M AgNO 3 and 0.1 M NaCl are mixed
together:
(A) 0.1 M (B) 0.2 M (C) 0.05 M (D) 0.25 M
13. From the figure representing enthalpy change of various transitions as indicated,
a substance has maximum enthalpy when present in -
(A) solid state (B) liquid state
(C) gaseous state (D) equal in all states
14. The mass of 75% pure Glucose (C6H12O6) required to prepare 50 mL of its M/9 aqueous solution is :
4
(A) 4 g (B) 1 mg (C) 1 g (D) g
3
15. Atomic mass of Cesium is 133 u and atomic mass of Chlorine is 35.5 u. How many unit cell are present
in 16.85 g of CsCl ?
(A) 6.023 × 1022 (B) 1.204 × 1022 (C) 6.023 × 1021 (D) 1.204 × 1023
ChemINFO ELECTROCHEMISTRY
Daily Self-Study Dosage for mastering Chemistry Topic: Fuel Cell
Conventionally energy is obtained by the combustion of the fossil fuel. The conversion into electrical energy
involves a number of steps and there is loss of energy at every step. The efficiency of the process is around
40%. There is also a viable way of converting the chemical energy of fuel directly into elecrtical energy through
catalytically activated redox reactions. Such devices are called fuel cells. In other words, fuel cells are galvanic
cells in which the electrical energy is directly derived from the redox reactions of the fuel.
The representation of the fuel cell is Fuel | Electrode | Electrolyte | Electrode | Oxidant
Overall cell reaction: Fuel + Oxidant Oxidation product + Reduction product
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Hydrogen–Oxygen Fuel Cell
This fuel cell combines hydrogen and oxygen to produce electricity, heat and water. It converts chemical energy
to electrical energy and thus can be compared to a battery. the only difference being that as long as hydrogen
is upplied, it continues to produce electricity without being discharged.
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3. The tetrahedral and paramagnetic unit amongs given pair of species is/are:
(A) [MnO4]2–,[NiCl4]2– (B) [MnBr4]2–, [CoCl4]2–
2–
(C) [CrO2F2], [Cr2O7] (D) [Ni(CO)4], [Ni(dmg)2]
6. At 300 K and 20 atm, the compression factor of a gas is 0.8. Calculate the volume occupied by 8 mmol
1
of the gas under these conditions ? (Take R = L atm K–1 mol–1)
12
7. Find the thickness of the electro deposited silver if the surface area over which deposition occurred was
100 cm2 and a current of 0.2 A flowed for 1hr with the cathodic efficiency of 80%. Density of
Ag = 10 g/cc (Ag = 108).
Copper (II) sulphate solution. If 0.4 mole of electrons are passed through the
cell, the molar concentration of copper ion after passage of the charge will be :
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9. 4×10 M aqueous solution of an organic compound is isotonic with 1.5 ×10–2 M aqueous solution of
–2
NaCl (complete ionisation). The compound gets dimerised with degree of dimerisation and Van't Hoff
factor i. Find the value of (8i + 2 ).
reaction is occuring.) 76 cm of Hg
11. Find the total number of compounds amongs the following, where d orbital will not take part in
x2 y2
hybridization.
(1) [Pt(NH3)Cl (H2O)Br] (2) SF4 (3) [Cu(NH3)4]2+ (4) XeO3F2
(5) XeO2F2 (6) [Co(en)3]3+ (7) [Ni(CO)4] (8) POCl3
(9) PCl5 (10) XeO64–
12. Two beaker A and B contains AgNO3 solutions of concentrations 0.1 M and 0.01 M respectively as
shown in figure. Pure silver electrodes are now placed in each beaker. Now NH3 is added in each
beaker till conc. of NH3 in beaker A and B become 0.1 M and 0.2 M respectively. If two beakers are
now connected in Galvanic cell arrangement, find the EMF (in millivolt) of the resulting cell at 298 K.
Give your answer after dividing by 16.
RT
[Use log10 2 = 0.3, (2.303) = 0.06 V at 298 K] Given : E ºAg / Ag = 0.8 Volt
F
Ag Ag
ChemINFO ELECTROCHEMISTRY
Daily Self-Study Dosage for mastering Chemistry Topic: Corrosion
Corrosion is one of the most significant problems faced by advanced industrial societies. It is estimated that
about 30-40% of iron and steel produced annually is used just to replace the rusted iron materials. Corrosion
toches all appliances used inside and outside home, on the road,on the sea, in plants and in aerospace
vehicles. corrosion is a spontaneous slow chemical interaction of metal or alloy with its environment, resulting in
the formation of one of its compounds such as oxide, hydrated oxide, carbonate, sulphide, sulphate, etc.
Corrosion can be defined as the deterioration of materials by chemical interaction with their environmnet.
Corrosion of metals occurs either by direct chemical attack or by electrochemical attack on the metal by the
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corrosive environment. The most familiar example of corrosion is rusting of iron exposed to the atmospheric
3
conditions. 2Fe(s) + O2 (g) + xH2O(I) Fe2O3 · xH2O(s)
2
(Chemical composition of rust)
The rusting of iron is a complex chemical reaction that involves both oxygen and moisture (see Fig.). Iron does
not rust in pure water that is oxygen free, and it does not rust in pure oxygen in the absence of moisture. This
suggests that the corrosion process is electrochemical in nature. At one place on the surface, iron becomes
oxidized in the presence of water and enters solution as Fe2+ and this is the anodic location of the metal
surface. Reaction taking place at the anode is
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(C) (D)
(A) (1Z, 2Z, 3E) Hepta-1,3,5-triene (B) (2E, 4Z, 6Z) Hepta-2,4,6-triene
(C) (3Z, 5E) Hepta-1,3,5-triene (D) (2E, 4Z) Hepta-2,4,6-triene
15. Which of the following has geometrical isomer.
(A) (B)
(C) (D)
(A) (B)
(C) (D)
H
I. II. III. IV.
O O O
(A) I and IV (B) II and IV (C) III and IV (D) II only
21. How many structural isomers of C3H5Cl will show geometrical isomerism?
22. How many oximes obtained when cyclopropanone and 2-Butanone react with excess of NH2OH:
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
23. How many of following can show geometrical isomerism?
H CH3
(v) CH3 (vi) (vii) (viii)
HO CH3
24. How many stereocenters (Geometrical centre) are present in given species -
CH2=CH–CH=CH–CH= N H
25. How many positional isomers of Decene can show geometrical isomerism.
3. For which of the following pairs of compounds are the CORRECT notations given.
(A) (B)
(C) (D)
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
4. Which of the following compound has Z configuration?
(A) (B)
(C) (D)
5. The incorrect order with respect to the properties mentioned for the following pair of compounds is:
(A) < (Stability)
Comprehension # 1
Observe the following compound :
CH3–CH=CH
O O CH3
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
9. How many total enolic forms (including stereoisomers) are possible for butanone.
(A) 1 (B) 2 (C) 3 (D) 4
10. Geometrical isomerism is possible in how many of the following molecules/compounds.
Cl
NH Br
(1) (2) (3) (4)
NH
Me
NH
(5) (6) (7) (8) MeS
NH
(9) (10)
11. Total number of position isomers of tetrachlorocyclobutane which can shows geometrical isomerism
are:
O3/Zn NH2–OH
12. Penta-1,3-diene Total no. of carbonyl excess Total no. of
compounds oximes
[X] [Y]
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
4. Which of the following is the lowest molecular weight hydrocarbon which is chiral?
(A) 3-Methylhexane (B) 2, 4-Dimethylpentane
(C) 2, 2-Dimethylpentane (D) 3, 3-Dimethylpentane
5. Which of the following molecule has 2 chiral carbon atoms :
CH3 H H
C2H5
NH2
8. Which of the following does not represent D-Lactic acid:
11. Identify the R/S configuration of both chiral carbon atoms in given molecule:
P = H3C H
D
CH3 CH3 Cl
D CH3
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
19. How many chiral atoms are present in given species.
D OH
21. Number of chiral centres in given molecule are :
Ha
Note : The following compound are also have acidic hydrogen and CH3–C–CH–C–CH3
O Ha O
1
General reaction : Z– + Na + H2
2
1 1
(a) R COOH
Na
R COONa H2 (b) PhOH
Na
PhONa H2
2 2
1 1
(c) R—C CH + Na R—C C–Na+ + H2 (d) R—SO3H + Na R—SO3–Na+ + H2
2 2
1
(e) R —CH2—O —CH3 + Na No reaction. (f) HCl
Na
NaCl H2
2
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
22. Which of the following compound has Acidic hydrogen.
(A) CH3–CH3 (B) CH3–N–CH2–CH3 (C) CH3–COOH (D) CH3–O–CH3
CH3
23. Which of the following compound liberates H2 gas after reaction with Na metal.
24. Which of the following compound does not liberates H2 gas after reaction with Na – metal.
(A) CH3–S–H (B) CH3–CHO (C) CH3–CH2–CCH (D) CH3–C–CH2–C–CH3
O O
25. Which of the following compound does not liberates H2 gas after reaction with Na – metal.
CH2 —COOH
CH2 —O — H CH2 —O — H CH2 —S — CH3
CH — O — H
(A) (B) (C) CH2 — CHO (D)
CH2 O —CH3 CH2 — NH2
CH2 — S — H
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
(A) (B)
(C) (D)
Comprehension #
An unsaturated compound X (C5H10O) exists as four stereoisomers. Y, (structural isomer of X) is
neither unsaturated nor shows any stereoisomerism. X and Y have same functional group. The third
isomer (Z) is a positional isomer of X, and has only two stereoisomers.
6. The compound Z cannot be ?
(A) CH2 = CH– CH –CH2 CH3 (B) H2C = CH–CH2– CH –CH3
| |
OH OH
CH3
|
(C) CH3 – CH = CH–CH2–CH2–OH (D) H2C=C–CH–CH3
|
OH
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
7. Y can be :
CH2OH
|
(A) (B) (C) (D) (B) and (C) both
O |
OH
8. Total number of plane of symmetry present in CH4.
9. How many of following centre of symmetry is present.
H
C
(i) (ii) (iii) H3C (iv) BeCl2(linear)
D
T
Cl
CH3
H H H Cl Cl
(v) (vi) H (vii) (viii)
H Br
Cl Cl Cl
10. How many of following have plane of symmetry.
H CH3
H CH3 H H H Br D
CH3 H C
(i) (ii) (iii) (iv) H
CH3
CH3 H CH3 Br Br
11. In BF3 C2 axis of symmetry are X and C3 axis of symmetry are Y. Report your answer as X + Y.
12. Matching the column :
Column-I Column-II
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
H F & F Cl
Br H
(A) Enantiomers (B) Diastereomers (C) Identical (D) No relation
2. Relation between maleic acid and fumaric acid is :
(A) Identical (B) Enantiomer (C) Diastereomer (D) Chain isomer
3. Relation between given compounds is :
COOH COOH
H OH and H OH
H OH HO H
COOH COOH
(A) Enantiomer (B) Diastereomer (C) Identical (D) Geometrical isomer
4. D-Lactic acid and L-Lactic acid are :
(A) Homologous (B) Conformer (C) Enantiomer (D) Diastereomer
5. Meso compound is :
CH3
CH3 Cl CH3
H Cl
(A) (B) (C) H Cl (D)
C2H5 H Cl
H
6. Which of the following can be meso compound :
(A) CH 3–CH–CH–CH 3 (B) CH3–CH–CD–CH3 (C) CH3–CH–CH–CH3 (D) CH3–CH–CH–CH3
Cl Br OH OH CH3 Cl Cl Cl
7. Identify the Chiral compound :
CH3
H Cl
(A) (B) (C) (D) All of these
Cl H
CH3
8. Which of the following is not a meso compound :
COOH
CH3 CH3 H OH
H Cl H Cl HO H CHO
(A) H OH (B) HO H (C) HO H (D) H OH
H Cl H Cl H OH
CH3 CH 3 COOH CH3
9. Which of the following compound is suitable for optical resolution of racemic mixture of 2- methyl
butanoic acid :
(A) 2-Butanol (B) 1-Propanol
(C) 2-Propanol (D) Cyclobutane carboxylic acid
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
10. A compound was having [] = 40.3º in polarimeter experiment in clockwise direction what can be the
structure is:
(A) (B)
(C) (D)
12. If the optical rotation produced by is +36º, then the optical rotation produced by
will be:
14. Relation between (I) and (II) (whose configuration in given below is):
CH3 CH3
HO — C — H H — C — OH
HO — C — H H — C — OH
H — C — OH H — C — CH3
CH3 OH
(I) (II)
(A) Enantiomers (B) Diastereomers
(C) Identical or homomers (D) Constitutional isomers
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
D D
C C
15. & H
H CH2COOH C2H5
C2H5 COOH
The above pair has relation
(A) Enantiomers (B) Diastereomers (C) Homologous (D) Identical
16. Meso compound is :
19. Total number of optically active stereoisomers possible for butane-2,3-diol is:
20. How many geometrical isomers are possible for given compound?
Test of Ester
Esters are sweet (fruity) smelling liquids.
When react with NaOH & Phenophthalein then pink colour will disappear on heating.
RCOOR’ + NaOH + Phenophthalein (Pink) RCOOH + R’OH (Colourless solution)
Test of Nitro group : (Mulliken- Barker’s Test)
Nitroalkane & nitrobenzene give black ppt on reduction with Zn and ammonium chloride followed by
treating with Tollen’s reagent. This is also said to be Mulliken’s test.
(a) R–NO2 R–NHOH Ag
AgNO3 NH4 OH
(b) + Zn + NH4Cl
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
22. An oragnic compound X (C4H8O2) gives positive test with NaOH and Phenopthalein. Structure of X will
be:
(A) CH3 CH2 CH2 C OH (B) CH3 C C CH3
|| || ||
O O O
(C) CH3 C O C2H5 (D) CH3 C OCH3
|| ||
O O
23. Which of the following compound will give smell of NH3 with conc. NaOH.
(A) CH3 CH2 C NH2 (B) CH3 C CH2 NH2
|| ||
O O
24. A compound is heated with zinc dust and ammonium chloride followed by addition of the Tollen's
reagent. Formation of silver mirror indicates the presence of following group
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
6. The conformation of isopentane having maximum torsional and maximum Vander Waal strain is:
H H H H
H H
(A) Conformational enantiomer (B) Conformational diasteromer
(C) Geometrical isomer (D) Homologous
11. Three membered cyclic compounds are highly reactive because of:
(A) High degree of torsional strain (B) High degree of angle strain
(C)High degree of steric strain (D) All of these
13. Among the structure shown below, which has lowest potential energy?
14. Most stable conformation of succinic acid in basic medium will be:
(A) (B)
(C) (D)
H H
H
21. Find total number of stereoisomers for given molecule -
CH3–CH=CH–CH=CH–CH=CH–CH3
22. (P)
The no. of geometrical isomers is X and optical isomers is Y. Value of (X + Y)
|
|| S
(b) CH3CH2NH2 + S=C=S HgCl2
CH3CH2–N=C=S + HgS + 2HCl
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
23. Which of the following liberate N2 gas with NaNO2 / HCl
(A) CH3–CH2–NH–CH3 (B) CH3–CH2–CH2–NH2
(C) Ph–NH2 (D) (CH3CH2)3N
3.
I II III
Correct relation between above compounds:
(A) I & II are position isomers (B) I & II are chain isomers
(C) II & III are metamers (D) II & III are identical
4.
Comprehension #
The carbonyl compounds which have alpha asymmetric carbon (C) atom and have –H hydrogen
atom, racemise due to tautomerisation on keeping in aqueous solution.
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
7. Which of the following compounds will racemise on keeping in aqueous solution
CH3 Me
| |
(A) CH3–CH2–CHO (B) Ph C C CH3 (C) Ph C C CH3 (D) Ph CH CH2 C CH3
| || | || | ||
H O Et O D O
9.
10. For the given compound X, the total number of optically active stereoisomers is …….
OH OH
12. How many total enolic forms (including stereoisomers) are possible for .
13. Match the column:
Column-I Column-II
(C) (r) Keq is greater than one when compound undergo flip.
(D) (s) Keq is less than one when compound undergo flip.
15. Identify correct order of leaving group ability for given leaving groups?
+ OH + Cl¯
NO2 NO2
(A) An addition reaction (B) A nucleophilic substitution reaction
(C) An electrophilic substitution reaction (D) A free radical substitution reaction
19. Which of the following reaction is an example of Acid-base reaction.
(A) CH2– CH2 Zn
CH2=CH2 + ZnBr2 (B) CH3COOH + NaNH2 CH2COONa + NH3
Br Br
H2 O
CH OH
3
(C) (D)
H
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
22. Total number of stereoisomers of CH3 – CH – CH – CH CH – CH3 is :
| |
Br Cl
6. Which of the following compound gives maximum % of para product with a particular electrophile?
F Cl Br I
ICl / ZnCl
7.
2
product; Product is :
Cl Cl I I
16.
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
18. How many of following are non-aromatic compound.
Br / Fe
2
(1 eq.)
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry Aromatic side chain oxidation
Aromatic side chain oxidation
Strong oxidising agents like KMnO4/H/ or K2Cr2O7/H/, oxidises benzylic carbon to – COOH group if
benzylic hydrogen or unsaturation is present.
General Reaction
COOH
KMnO / H KMnO / H
4
4
COOH CH3
CH3 C CH3
KMnO / H
4
KMnO / H
4
No reaction
Note : Tertiary butyl (CH3)3C– will not oxidise by oxidising reagent
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
KMnO / H
4
KMnO / H
Ex.1 Ex.2
4
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
CH2–CH3
KMnO 4 / H
22. Product ; Product will be:
23. Which of the following reagent is suitable for the conversion of benzyl alcohol to benzoic acid?
(A) K2Cr2O7/H+ / (B) KMnO4/H+ / (B) m–CPBA (D) (A) and (B) both
24. Which of the following is oxidation product of given reaction.
KMnO / H
4
KMnO 4 / H
25. Product; Product is:
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
1.
2. Which factor is responsible for the regioselective nature of the following reaction.
Cl / FeCl
2
3
+
4. In which of following electrophilic aromatic substitution reaction takes place on left hand side phenyl
ring.
(A) (B)
(C) (D)
5. Which of the following electophilic substitution reaction represent correct product.
Br / FeBr
(A) 2
3
Br / FeBr
(B) 2
3
Br / FeBr
(C) 2
3
Br / FeBr
(D) 2
3
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
Comprehension #
Friedel Craft's Acylation: Acylation of benzene may be brought about with acid chlorides or
anhydrides in presence of Lewis acids.
Step-1 : Formation of an acylium ion.
:O:
|| ..
+ - -
R – C – Cl
.. – AlCl3 AlCl4 +
complex
Step-2 : Electrophilicattack.
O
O ||
|| C
C+ R
| + H
R H
sigma complex
O
|| .. -
C :Cl
.. – AlCl3
R
+ H
H
sigma complex
OH
(A) COOH (B) (C) OH (D)
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
8. Which step is used to produce 1–Chloro–3–ethylbenzene.
Cl /AlCl Zn Hg / HCl
(B)
2 3
Cl /AlCl
(C)
2 3
Cl /Fe
(D)
2
Br / Fe HNO / H SO
2
3 2 4
(1 eq.) (1 eq.)
11. Match List I (Group when attached to phenyl ring) with List II (Effect shown) and select the correct
answer using the code given below the lists:
List I List II
(P) –Cl (1) + m & + I
(Q) (2) + m &– I
–O
(R) –CH2–CH3 (3) only – I
(S) – N H3 (4) +I & Hyperconjugation
Codes:
P Q R S P Q R S
(A) 1 3 2 4 (B) 3 4 2 1
(C) 4 2 3 1 (D) 2 1 4 3
12. Match the column-I with column-II:
Column-I Column-II
CMe3
(C) (r) Less reactive than benzene for electrophilic subsitution reactions.
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry Oxidation
Syn hydroxylation of Alkenes and Alkynes
General Reactions :
H.A. H.A.
—CC—
H.A.
Ex.
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
(A) (B) HO OH
OH
(C) (D)
HO OH OH
14.
(A) (B)
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
Br Br Br
1.
2
2.
2
3.
2
Fe Fe Fe
Br Br Br
4.
2
5.
2
6.
2
Fe Fe Fe
Br Br Br
7.
2
8.
2
9.
2
Fe Fe Fe
Br Br Br
10.
2
11.
2
12.
2
Fe Fe Fe
Br Br Br
13.
2
14.
2
15.
2
Fe Fe Fe
Br Br Br
16.
2
17.
2
18.
2
Fe Fe Fe
Br Br Br
19.
2
20.
2
21.
2
Fe Fe Fe
3
2
Br Br Br
22.
2
23.
2
24.
2
Fe Fe N 1 Fe
Br2
25.
26.
2
Br
Fe
Br Br
27.
2
28.
2
Fe Fe
2
Br Br
1
29. 2
30. 2
Fe Fe
NH
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
1. 3 2. 3 3. 3 4. 2 5. 2
6. 2 7. 4 8. 1 9. 3 10. 3
11. 1 12. 1 13. 3 14. 1 15. 3
16. 2 17. 2 18. 1 19. 1 20. 1
21. 5 22. 3 23. 3 24. 2 25. 2
26. 3 27. 3 28. 1 29. 1 30. 3
NaH
(B)
HClO4
(C)
4. Which is the most likely group for substituent 'X' based on the relative rate factors for chlorination in the
given compound.
CO, HCl
5. (Y) Product will be:
AlCl3
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
6. Which one of the following undergoes nucleophilic aromatic substitution at the fastest rate?
H O /
3
Products
(A) (B)
(C) (D)
RONa /
13.
(A) in CCl4 (B) in dil NaOH (C) in dil HCl (D) in dil HCl
15. Nitrobenzen can be prepared from benzene by using a mixture of conc. HNO3 and conc. H2SO4. In the
mixture, nitric acid acts as a/an.
(A) Catalyst (B) Reducing agent (C) Acid (D) Base
NaOH
16. + C2H5I X , X is:
(1 eq.)
(A) C6H5OC2H5 (B) C2H5OC2H5 (C) C2H5OH (D) C6H5I
17. How many toluidines on reaction with NaNO2/HCl followed by H3PO2 treatment gives Toluene.
NO2
Sn/HCl
NaNO2 H O,
18.
2
Product Z
HCl 05C
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry Syn hydroxylation of Alkenes and Alkynes
Anti hydroxylation of Alkenes
Peroxy acid have general structure as (RCO3H). They are relatively unstable and easily gives
nascent O hence, acting as oxidant. It converts alkene into epoxides. A combination of RCO 3H followed by
hydrolysis [RCO3H(H3O+)] further breaks epoxide to anti hydroxylation product.
General Reaction :
Peroxyacid H O
3
Note : 1. It is anti addition. Both OH groups add on the opposite side of pi-bond.
2. Double bond of aromatic ring cannot react with these reagents.
OH
(i) Peroxy acid
(ii) H3O OH
Ex.1
Trans-cyclohexane-1,2-diol
(a) = m-CPBA (Metachloro perbenzoic acid) (b) CH3CO3H = PAA (Peracetic acid)
–
Cl
(c) PhCO3H = PBA (Per benzoic acid) (d) CF3CO3H = TFPAA (Trifluoro peracetic acid).
Ex.2
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
m-CPBA
22. x , x is
OH OH OH H
(A) (B) (C) (D) 50% B and 50% C
H H H HO
Peroxyacid
23. CH2 = CH2 X, X is:
OH O
| CH2 — CH2
(A) CH2 — CH2 (B) | | (C) (D)
| OH OH
OH
(1) Peroxyacid
24. P; Product is:
( 2) H3O
Br
O O
C–O C–O
Br (1 mol)/Fe
(B)
2
Br
OH OH
Dilute HNO3, 20ºC O2N NO2
(C)
NO2
OH O–C2H5
(C H ) SO NaOH /
(D) 25
2
4
Comprehension #
I
II
III
Iv
v vI
(X) (Pain killer)
7. How many aromatic diazonium chlorides of xylene can be reduced to meta-xylene by H3PO2?
H PO ,
3 2
(m-Xylene)
8. The following compound is treated with excess of Br2/H2O. Find the total number of positions, where
bromination will occur significantly:
Cl
|
Conc.H2SO4
9. Chloral + Product
Product is insecticide and was used in II world war to control malaria.The number of chlorine atoms in
one molecule of insecticide is –
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
10. Match List I (Reactants) with List II (Products) and select the correct answer using the code given below
the lists:
List I List II
OH
CH2OH
(P) (1) Br2 / CS2 (1)
OH
( 2) (CH3 )2 SO 4 / OH
NH2 OCH3
OCH3 OH
OH OH
(1) CHCl / O H
(R) 3
(3)
( 2) H2O
(3 ) NaBH 2
OH
Br OCH 3
(1) Br / Fe
(S)
2
(4)
( 2) Mg / Ether
(3 ) O2
( 4 ) H2O Br
Codes:
P Q R S P Q R S
(A) 4 2 3 1 (B) 3 1 4 2
(C) 4 2 1 3 (D) 2 4 1 3
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry Topic: Oxidative cleavage of C=C/CC
KMnO4 and K2Cr2O7 are amongst the strongest oxidising agent. They completely rupture the C=C or CC and
form oxidised products as Acids and ketones depending on structure of C=C and CC. Observe the following
oxidative cleavage of C=C and CC by oxidising agents (O.A) as
(a) KMnO4 (b) K2Cr2O7 or CrO3/H (c) O3/H2O or O3/H2O2
General Reactions:
O.A. O.A.
O.A. O.A.
+ CO2+ H2O 2RCOOH
O.A.
+ CO2 + H2O
Examples :
O.A. O.A.
+ H2O
O.A. O.A.
+ CO2+ H2O 2CH3COOH
O.A.
+ CO2+H2O
Note : 1. Alkene & alkyne having = CH2 & C–H will give CO2 as one of the oxidation product by oxidising
agent KMnO4 and K2Cr2O4 or CrO3/H+.
O.A.
2. HCOOH (Formic Acid) or H2C2O4 (Oxalic Acid) CO2 + H2O.
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
K Cr O
11. 2 2
7
P ; Products is:
OH
(A) (B) (C) (D) O
OH
O
KMnO 4 / H
13. A CH3COOH + CH3CH2COOH. The Alkyne 'A' can be:
(A) CH3–CH=CH–CH3 (B) CH3–CC–CH3
(C) CH3–CH=CH–CH2–CH3 (D) CH3–CC–CH2–CH3
14. From which of the following alkene, CO2 is one of the oxidation product by KMnO4/K2Cr2O7 /H . +
(C) (D)
Br
OH CH3–C–Cl / Pyridine
O Br water dil H SO /
(B) 2
2
4
Br OH
1 eq. NaOH Sn / HCl NaNO / H SO
CuBr / HBr
(C)
(D)
2 2 4
Br NO2
NaHS Br /KOH
(A)
(B)
2
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
HNO 2 H SO
Sn / HCl (i) Cl / Fe Cl / Fe KCN
(C)
3 2 4
2
(a ) (ii) NaOH/ (c ) ( d) (e) H3O
(b)
H O / heat ( X) / OH ( dilute )
(X)
NaNO 2 / HCl 2
(Y) (Z)
(0 5C)
KI
(A) X (B) Z =
(C) Y (D) Y =
5. Diazocoupling reaction in aromatic compounds is an electrophilic substitution reaction. In which of the
following reaction the ring subsitution is most suitable for diazocoupling reaction?
(A) + (B) +
(C) + (D) +
+ CuCN H O
HNO 3 Fe / H NaNO
X 2 3
'Z'
HCl
+
CH3 Y CH3
+
Fe / H NaNO CuBr
W 2
' V '
HBr
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
6. Compound 'V' is:
CH3 CH3 CH3 CH2Br
Br
(A) (B) (C) (D)
Br
Br
7. Compound 'X' and 'Y' are:
(A) Metamers (B) Chain isomers (C) Position isomers (D) Functional isomers
8. Compound 'Z' is:
CH3 CH3 CH3 CH3
COOH CN
(A) (B) (C) (D)
COOH CN
(i) Conc .HNO3 Conc .H2SO 4
(ii) Sn / HCl
9. Proudct
(iii) Br2 / H2O
(iv ) NaNO2 HCl (0 5C)
( v ) Cu2Br2 HBr
What is the number of halogen atoms in final product ?
10. A mixture of 1° amides (benzenoid) having molecular formula (C8H9NO) reacted with Br2/NaOH. The
number of 1° amines products formed will be:
11. How many Five member ring present in A.
NH2
Aq.NaNO
2
A
HCl (0C)
NH2
12. Match list I (reaction) with II (products) and then select the correct answer from the codes given below
the lists:
List-I List-II
(P) Phenol + NaOH + CH3 (1) Phenolphthalein
(Q) Phenol + NaOH +CHCI3 (2) Salicylic acid
(R) Phenol + Phthalic anhydride + conc. H2SO4 (3) Anisole
(S) Phenol + CO2 + NaOH (4) Salicylaldehyde
Codes:
P Q R S P Q R S
(A) 1 2 3 4 (B) 4 3 2 1
(C) 3 4 1 2 (D) 4 3 1 2
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry Baeyer–Villiger oxidation
Peroxy acid have general structure as (RCO3H). They are relatively unstable and easily gives
nascent O hence, acting as oxidant. It converts ketone into ester.
General reactions :
O. A. O. A.
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
Migratory aptitude : –H > –Ph > –Et > –Me
O.A. = Oxidizing agent. Peroxy acids as an oxidizing agent may be one of these
CO H
– 3
(a) = m-CPBA (Metachloro perbenzoic acid)
–
Cl
(b) CH3CO3H = PAA (Peracetic acid)
m-CPBA
Ex-1: CH3—C—CH3 CH 3—C—O—CH 3 Ex-2:
O O
Ex-3:
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
13. Which reagent is used for the following reaction?
Reagent
16. Which of the following is the main product obtained by the given reaction:
Peroxy
acid
(C) (D)
HO
(C) CH3–CH2–CHO + NaBD4 CH3–CH2–CHD–OH
2
H SO
(D) CH3–CH2–CHO + NaCN
2 4
4. Reaction of acetaldehyde with HCN followed by hydrolysis gives a compound which shows
(A) Optical isomerism (B) Geometrical isomerism
(C) Metamerism (D) Tautomerism
5. Which of the following can not react with Grignard reagent?
6. Which of the following pair of compounds can not show SN2Th reaction:
(A) CH3COOH & CH3COCl (B) CH3COOCOCH3 & CH3COOCH3
(C) CH3COOCH3 & CH3COCH3 (D) CH3COOH & C2H5COOC2H5
9.
(X)
Compound X is most reactive towards SN2 Th reaction when P is:
(A) –CH3 (B) –Br (C) –OCH3 (D) –NO2
10. ; Z can not be:
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
12. Which of the following acid is most reactive toward esterification reaction?
(A) Me–COOH (B) n-PrCOOH (C) Me3CCOOH (D) Et3CCOOH
H SO
+ 2
4
15. If pentan-2-one is reduced with NaBH4 followed by hydrolysis with D2O, the product will be:
(A) CH3–CH(OD)CH2CH2CH3 (B) CH3CD(OH)CH2CH2H3
(C) CH3CH(OH)CH2CH2CH3 (D) CH3CD(OD)CH2CH2CH3
(A) CH3MgI then D2O (B) LiAlH4 then D3O+ (C) LiAlD4 then H3O+ (D) NaBH4 then D3O+
18. Which one of the following is least reactive for hydrolysis reaction?
(A) (B)
(C) (D)
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
20. The reaction,
O O
– –
R–C + Nu R–C +X
X Nu
is fastest when X is :
(A) Cl (B) Br (C) I (D) F
21. 6-Bromo-2-hexanone is treated with magnesium in presence of THF produce X as major product.
How many carbon atoms present in the ring of product 'X'.
22. Numbering of some reactions are given as following. Which number of the reaction is SN2Th Reaction.
(1) CH3COOH + NaOH CH3COONa + H2O
(2) CH3COOH + SOCl2CH3COCl + SO2 + HCl
AlC·KOH
(3)
23. + + HCl
Numbering of type of reaction are given as following which number is given for above reaction
(1) SN2Th reaction (2) Nucleophilic addtition reaction
(3) Addition reaction (4) Elimination Reaction
24. Ester A
25. How many grignard reagent required to react 1 mole of acetyl chloride.
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
ANSWERS KEY
DPP No. # A1
8. 3 9. 5 10. –3 11. 6
DPP No. # A2
DPP No. # A3
6. 01 7. 02 8. 5 9. 6 10. 4
DPP No. # A4
DPP No. # A5
DPP No. # A6
DPP No. # A7
4. 4 5. 4 6. 2 7. 7
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
DPP No. # A8
DPP No. # A9
6. 6 7. 3 8. 00 9. 8 10. 5
15. 34 16. 6 17. 09 (i, ii, iii, v, vi, vii, viii, ix, x) 18. 2
7. 20 8. 03 9. 05 10. 2 11. 8
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
7. 02 8. 07 9. 21 10. 8 11. 2
7. 3 8. 5 9. 90 10. 5 11. 1
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
ORGANIC CHEMISTRY
DPP No. # A1
DPP No. # A2
13. (A) (q, r, s); (B) (q, r); (C) (q, r, s); (D) (s)
DPP No. # A3
DPP No. # A4
8. 6 9. 4 10. 6 11. 4
DPP No. # A5
DPP No. # A6
DPP No. # A7
DPP No. # A8
21. 3 22. 8 23. 4 24. 6 25. 5
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DPPs BOOKLET-1 | VIJETA (01&02JPB & 03&04JPAB) |
DPP No. # A9
9. 4 10. 9 12. (A – q , s) ; (B – p, q) ; (C – q) ; (D – p, r)
7. 3 8. 7 9. 5
9. 4 10. 4 11. 1
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