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Material Safety Data Sheet

FLOMIN C-4132
MSDS number: DATE: 07/03 REV.: 0 5 Pages.

Section 1 : CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

1.1 Product Name....…………..................... XL-2062


Other Names ......................................... Thionocarbamate; Isopropyl Ethyl Thionocarbamate;
O-isopropyl N-ethyl thiocarbamate.

1.2 Supplier...................................….. SNF INC


PO Box 250
Riceboro, GA .
Information ..........................................…912-884-3366

1.3 Emergency Telephone No.....................


USA: Chemtrec: (800) 4249300

Section 2 : COMPOSITION/INFORMATION ON INGREDIENTS

2.1 Chemistry Ingredients :

Active Ingredients:
Thionocarbamate: CAS: 141-98-0 93-98%

Product contains Isopropyl alcohol (0-2%) (high flammable), and diethylurea (0-2%) (harmful if swallowed
or with skin contact).
2.2 Material Use: Flotation reagent (flotation collector).

Section 3 : HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
Caution: Flammable. Prolonged contact causes skin and mucous membranes irritation. Harmful
if swallowed.
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Section 3 : HAZARDS IDENTIFICATION (cont.)

3.1 Health Hazards (Acute and Chronic)


On prolonged contact causes severe irritation/burns to eyes and skin. Dangerous if swallowed. Vapors
may irritate respiratory tract.

3.2 Signs and Symptoms of Exposure


See 3.1.

3.3 Environmental Hazards


See 12.

Section 4 : FIRST AID MEASURES

4.1 EYES: Immediately flush eyes with plenty of water during 15 minutes. See physician immediately.

4.2 SKIN: Immediately flush skin with plenty of water while removing contaminated clothing and shoes.
See physician immediately.

4.3 SWALLOWED: Rinse mouth with water. Never give anything by mouth to an unconscious person.
Make the exposed person lie down and keep quiet. Get medical attention immediately, in case of large
quantities.
4.4 INHALATION: Keep victim away of contaminated atmosphere. Apply mouth to mouth respiration, if
necessary. Obtain medical assistance immediately.

Section 5 : FIRE-FIGHTING MEASURES

5.1 INFLAMMATION PROPERTIES:

FLASH POINT: 60 C.

5.2 FLAMMABLE LIMITS


NOT AVAILABLE

5.3 EXTINGUISHING MEDIA AND PROCEDURES: Dry chemical or carbon dioxide for small fires, water
spray or foam for large fire. Use water spray to keep fire-exposed containers cool. Approach fire from
upwind to avoid hazardous vapors and toxic decomposition products. Fight fire from protected location or
maximum possible distance. Avoid heavy hose streams. Dike area to prevent water runoff. Fireman
should wear self-contained breathing apparatus and protective clothing.

5.4 HAZARDOUS DECOMPOSITION OR BYPRODUCTS IN A FIRE: The essential breakdown


products are volatile, toxic, malodorous and inflammable compounds such as hydrogen sulfide, sulfur
dioxide, and nitrogen oxides.

5.5 UNUSUAL FIRE AND EXPLOSION HAZARDS.


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Section 6 : ACCIDENTAL RELEASE MEASURES
6.1 Personal Protection: Observe all protection and safety precautions when cleaning up spills, see 8.

6.2 STEPS TO BE TAKEN IN CASE OF SPILL: Spills should be contained and swept up by means of
an inert absorptive material such as hydrated lime, sawdust, Fuller´s earth or other absorbent clays.
Scoop into proper containers and arrange for removal by licensed contractor. Rinse area with strong
industrial detergent.
Section 7 : HANDLING AND STORAGE

7.1 PRECAUTIONS TO BE TAKEN IN HANDLING: See Personal Protection, Section 8. Use with good
ventilation. Close containers when not in use. Always open containers slowly to allow pressure release.

7.2 PRECAUTIONS TO BE TAKEN IN STORING: Store away from open flames or excessive heat.

Section 8 : EXPOSURE CONTROL/PERSONAL PROTECTION

8.1 RESPIRATORY PROTECTION: Avoid inhalation of vapors.

PROTECTIVE GLOVES: Wear chemical resistant gloves, such as barrier laminated, butyl rubber,
nitrile rubber or viton.

EYE PROTECTION: Wear safety glasses, goggles or facial protection. Don’t use contact glasses.

OTHER PROTECTION: Wear protective clothing.

8.2 WORK/HYGIENIC PRACTICES: Before removing gloves, wash them with soap and water. Always
wash hands, face and arms with soap and water before smoking, eating or drinking. After work, take off
all work clothes and shoes. Shower, using soap an water. Wear only clean clothes when leaving job. Do
not wear contaminated clothing/protective equipment.

Section 9 : PHYSICAL AND CHEMICAL PROPERTIES

9.1 PHYSICAL STATE: Liquid, yellowish to light brown


9.2 ODOR: -
9.3 MELTING/FREEZING POINT: -4 C
9.4 BOILING POINT: approx. 217 C
9.5 SPECIFIC GRAVITY: 0.99 g/ml at 20 C.
9.6 SOLUBILITY IN WATER: Insoluble
9.7 pH: -
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Section 10 : STABILITY AND REACTIVITY

10.1 THERMAL DECOMPOSITION: Stable at ambient temperatures.

10.2 HAZARDOUS DECOMPOSITION OR BYPRODUCTS: See 5.2.

10.3 MATERIAL TO AVOID: Strongly oxidant media. Product is corrosive to copper and brass.

Section 11 : TOXICOLOGICAL INFORMATION

11.1 HEALTH HAZARDS………………………………….. See 3.1.

11.2 ROUTE(S) OF ENTRY -Ingestion LD50, oral, rat: 500-2000 mg/kg


-Skin -
-Inhalation -

11.3 IRRITANCY OF MATERIAL:…………………………Causes severe irritation/burns to eyes and


skin

Section 12 : ECOLOGICAL INFORMATION

The product is biodegradable.


Biodegradability thionocarbamate: 30-70% (OECD Test 302 B).

Section 13 : DISPOSAL CONSIDERATIONS

13.1 WASTE DISPOSAL METHOD: Spill and waste disposal procedures in conformity with state and
local regulations must be followed. Do not contaminate water, food or feed by storage or disposal.

13.2 CONTAINED DISPOSAL: Triple rinse (or equivalent). Then offer recycling or reconditioning, or
puncture and dispose of in a sanitary landfill. However, procedures in conformity with state and local
regulations must be followed.
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Section 14 : TRANSPORT INFORMATION

14.1 Proper shipping name: Flammable liquid, N.O.S. (Thionocarbamate).

14.2 UN Number: 1993

14.3 Class: 3

14.4 Packaging Group: III

14.5 Primary hazard: Flammable

14.6 Subsidiary risk -

14.7 Marine pollutant (P/PP) Marine Pollutant.


(IMDG-Code)

Section 15 : REGULATORY INFORMATION

15.1 IN THE EU:


Contains…. O-Isopropyl N-ethyl thionocarbamate.
R-phrases…. R22: Harmful if swallowed
S-phrases…..S26-28-37/39: In case of eyes contact, rinse immediately with plenty of water and
seek medical advice. After contact with skin, wash immediately with plenty of water and soap.
Wear suitable gloves and eye/face protection.

15.2 THRESHOLD LIMIT VALUE: Not established.

Section 16 : OTHER INFORMATION

The buyer assumes all risk in connection with the use of the material. SNF assumes no responsibility or liability in
connection with the information supplied on this sheet or for any damage or injury caused by the material if
reasonable safety procedures are not followed as stipulated. SNF assumes no responsibility for injury or damage
caused by abnormal use of the material even if reasonable safety procedures are followed. The information
contained in this sheet is developed from what are believed to be accurate and reliable sources and is based on the
best opinions and authoritative facts, available at the time of issue.