MasterTop THN 2

Safety data sheet
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 19.11.2012 Version: 1.1
Product: MasterTop THN 2 also Cleaning Solvent NO.2
(ID no. 30423247/SDS_GEN_EU/EN)
Date of print 17.09.2015
1. Identification of the substance/mixture and of the company/undertaking

Product identifier
MasterTop THN 2 also Cleaning Solvent NO.2

Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Product for construction chemicals
Details of the supplier of the safety data sheet
Company:
BASF SE
67056 Ludwigshafen
GERMANY
Operating Division Construction Chemicals
Telephone: +49 621 60-74354

E-mail address: info.construction-chemicals@basf.com
Emergency telephone number
International emergency number:

Telephone: +49 180 2273-112
2. Hazards Identification
Label elements
According to Directive 67/548/EEC or 1999/45/EC
Directive 1999/45/EC ('Preparation Directive')
Hazard symbol(s)
Xn Harmful.
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R-phrase(s)
R10 Flammable.
R20/21 Harmful by inhalation and in contact with skin.
R38 Irritating to skin.
S-phrase(s)
S2 Keep out of the reach of children.
S36/37 Wear suitable protective clothing and gloves.
S46 If swallowed, seek medical advice immediately and show this container
or label.
S51 Use only in well-ventilated areas.
Hazard determining component(s) for labelling: XYLENE
Classification of the substance or mixture
According to Directive 67/548/EEC or 1999/45/EC
Possible Hazards:
Flammable.
Harmful by inhalation and in contact with skin.
Irritating to skin.
Other hazards
According to Regulation (EC) No 1272/2008 [CLP]
If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture.
3. Composition/Information on Ingredients
Mixtures
Chemical nature
Blend based on: organic, hydrocarbon solvent
Hazardous ingredients (GHS)

according to Regulation (EC) No. 1272/2008
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xylene
Content (W/W): >= 50 % - <= 100 Flam. Liq. 3
% Acute Tox. 4 (Inhalation - vapour)
CAS Number: 1330-20-7 Acute Tox. 4 (dermal)
EC-Number: 215-535-7 Skin Corr./Irrit. 2
INDEX-Number: 601-022-00-9 H315, H312, H332, H226
ethylbenzene
Content (W/W): >= 0 % - < 25 % Flam. Liq. 2
CAS Number: 100-41-4 Acute Tox. 4 (Inhalation - vapour)
REACH registration number: 01- Eye Dam./Irrit. 2
2119489370-35 STOT SE 3 (irr. to respiratory syst.)
INDEX-Number: 601-023-00-4 H319, H315, H332, H225, H335
toluene
Content (W/W): >= 0.1 % - < 1 % Asp. Tox. 1
CAS Number: 108-88-3 Flam. Liq. 2
REACH registration number: 01- Repr. 2 (unborn child)
2119471310-51 STOT SE 3 (drowsiness and dizziness)
INDEX-Number: 601-021-00-3 STOT RE (Central nervous system) 2
H315, H225, H304, H336, H361d, H373
Hazardous ingredients
according to Directive 1999/45/EC
xylene
Content (W/W): >= 50 % - <= 100 %
CAS Number: 1330-20-7
EC-Number: 215-535-7
INDEX-Number: 601-022-00-9
Hazard symbol(s): Xn
R-phrase(s): 10, 20/21, 38
ethylbenzene
Content (W/W): >= 0 % - < 25 %
REACH registration number: 01-2119489370-35
Hazard symbol(s): F, Xn
R-phrase(s): 11, 20
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toluene
Content (W/W): >= 0.1 % - < 1 %
REACH registration number: 01-2119471310-51
Hazard symbol(s): F, Xn
R-phrase(s): 11, 38, 48/20, 63, 65, 67
Repr. Cat. 3
For the classifications not written out in full in this section, including the indication of danger, the
hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.
4. First-Aid Measures
Description of first aid measures
First aid personnel should pay attention to their own safety. Remove contaminated clothing.
If inhaled:
Remove the affected individual into fresh air and keep the person calm. If breathing difficulties
develop, aid in breathing and seek immediate medical attention.
On skin contact:
Wash thoroughly with soap and water. Under no circumstances should organic solvent be used. If
irritation develops, seek medical attention.
On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an
eye specialist.
On ingestion:
Rinse mouth and then drink plenty of water. Do not induce vomiting due to aspiration hazard. Do not
induce vomiting unless told to by a poison control center or doctor.
Most important symptoms and effects, both acute and delayed

Symptoms: headache, sickness, dizziness, coughing, vomiting
Indication of any immediate medical attention and special treatment needed

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
5. Fire-Fighting Measures
Extinguishing media
Suitable extinguishing media:
dry powder, alcohol-resistant foam
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Unsuitable extinguishing media for safety reasons:
water jet
Special hazards arising from the substance or mixture

Carbon dioxide, carbon monoxide, harmful vapours, nitrogen oxides, fumes/smoke, carbon black
Advice for fire-fighters

Special protective equipment:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Containers may
rocket or explode in heat of fire. Keep containers cool by spraying with water if exposed to fire.
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent
systems. Contaminated extinguishing water must be disposed of in accordance with official
regulations.
6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures
Use personal protective clothing. Avoid prolonged inhalation. Avoid contact with the skin, eyes and
clothing. Avoid all sources of ignition: heat, sparks, open flame.
Environmental precautions
Prevent spread over a wide area (e.g. by containment or oil barriers). Contain contaminated
water/firefighting water. Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up

For large amounts: Pump off product.
For residues: Pick up with inert absorbent material (e.g. sand, earth etc.). Correctly dispose of
recovered product immediately.
Reference to other sections

Information regarding exposure controls/personal protection and disposal considerations can be
found in section 8 and 13.
7. Handling and Storage

Precautions for safe handling
Take precautionary measures against static discharges. Keep away from sources of ignition - No
smoking. Provide good room ventilation even at ground level (vapours are heavier than air).
Protection against fire and explosion:

Sources of ignition should be kept well clear. Take precautionary measures against static
discharges. Substance/product can form explosive mixture with air. Vapours are heavier than air and
may accumulate in low areas and travel a considerable distance up to the source of ignition.
Conditions for safe storage, including any incompatibilities

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Suitable materials for containers: Steel container, tin (tinplate)

Further information on storage conditions: Keep container tightly closed and in a well-ventilated
place. Keep away from heat. Avoid all sources of ignition: heat, sparks, open flame.
Specific end use(s)

For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be
observed.
8. Exposure Controls/Personal Protection

Control parameters
Components with occupational exposure limits
1330-20-7: xylene
TWA value 221 mg/m3 ; 50 ppm (OEL (EU))
indicative
STEL value 442 mg/m3 ; 100 ppm (OEL (EU))
indicative
Skin Designation (OEL (EU))
The substance can be absorbed through the skin.
100-41-4: ethylbenzene
indicative
indicative
108-88-3: toluene
indicative
indicative
Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Suitable respiratory protection for higher
concentrations or long-term effect: Gas filter for gases/vapours of organic compounds (boiling point
<65 °C, f.e. EN 14387 Type AX)
Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact
(Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to
EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other
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Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Tightly fitting safety goggles (splash goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen based on level of activity and exposure., Antistatic apron
General safety and hygiene measures

Avoid inhalation of dusts/mists/vapours. Avoid contact with the skin, eyes and clothing. Avoid
prolonged and/or repeated contact with the skin. Handle in accordance with good building materials
hygiene and safety practice. When using, do not eat, drink or smoke. Hands and/or face should be
washed before breaks and at the end of the shift. At the end of the shift the skin should be cleaned
and skin-care agents applied. Gloves must be inspected regularly and prior to each use. Replace if
necessary (e.g. pinhole leaks).
9. Physical and Chemical Properties

Information on basic physical and chemical properties
Form: liquid
Colour: colourless
Odour: product specific
pH value:
neutral to slightly alkaline
Boiling point: 135 - 145 °C
Flash point: approx. 27 - 30 °C
Information applies to the solvent.
Flammability: Flammable.
Ignition temperature: approx. 500 °C
Information applies to the solvent.
Vapour pressure:
not determined
Density: approx. 0.90 g/cm3
(25 °C)
Solubility in water: immiscible
(20 °C)
Thermal decomposition: Vapours may form explosive mixture with air. No decomposition if
stored and handled as prescribed/indicated.
Explosion hazard: not explosive
Other information
Miscibility with water:

(20 °C)
not soluble
Hygroscopy: Non-hygroscopic
Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.
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10. Stability and Reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals: Corrosive effects to metal are not anticipated.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions

Reacts with strong oxidizing agents. Reacts with strong acids.
Conditions to avoid
See MSDS section 7 - Handling and storage.
Incompatible materials
Substances to avoid:
strong oxidizing agents
Hazardous decomposition products
No hazardous decomposition products if stored and handled as prescribed/indicated.
11. Toxicological Information

Information on toxicological effects
Acute toxicity
Assessment of acute toxicity:

Of moderate toxicity after short-term skin contact.
Experimental/calculated data:
LD50 rat (oral): > 2,000 mg/kg
Irritation
Assessment of irritating effects:

Eye contact causes irritation. Skin contact causes irritation.
Respiratory/Skin sensitization
Assessment of sensitization:
There is no evidence of a skin-sensitizing potential.
Germ cell mutagenicity

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Assessment of mutagenicity:
The substance was not mutagenic in studies with mammals.
Carcinogenicity
Assessment of carcinogenicity:
Not expected to be carcinogenic (based on composition).
Reproductive toxicity
Assessment of reproduction toxicity:

Not expected to cause reproductive toxicity (based on composition).
Developmental toxicity
Assessment of teratogenicity:
The potential to cause toxicity to development cannot be excluded when given in high doses.
Specific target organ toxicity (single exposure)
Assessment of STOT single:

Causes temporary irritation of the respiratory tract.
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Assessment of repeated dose toxicity:

Repeated exposure may affect certain organs.
Aspiration hazard
May also damage the lung at swallowing (aspiration hazard).
Other relevant toxicity information
The product has not been tested. The statement has been derived from the properties of the
individual components.
12. Ecological Information

Toxicity
Assessment of aquatic toxicity:

Acutely toxic for aquatic organisms. The inhibition of the degradation activity of activated sludge is
not anticipated when introduced to biological treatment plants in appropriate low concentrations.
Persistence and degradability
Assessment biodegradation and elimination (H2O):

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The product is partially biodegradable. Significant residues will remain. The product has not been
tested. The statement has been derived from the properties of the individual components.
Bioaccumulative potential
Assessment bioaccumulation potential:

Does not significantly accumulate in organisms.
Mobility in soil (and other compartments if available)
Assessment transport between environmental compartments:

The substance will slowly evaporate into the atmosphere from the water surface.
Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of
groundwater is not expected.
Results of PBT and vPvB assessment
The product does not fulfill the criteria for PBT (Persistent/bioaccumulative/toxic) and vPvB (very
persistent/very bioaccumulative).
Additional information
Other ecotoxicological advice:

Do not discharge product into the environment without control. The product has not been tested. The
statements on ecotoxicology have been derived from the properties of the individual components.
13. Disposal Considerations
Waste treatment methods
Observe national and local legal requirements.

The waste code in accordance with the European waste catalog (EWC) must be specified in
cooperation with disposal agency/manufacturer/authorities.
Residues should be disposed of in the same manner as the substance/product.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for
recycling after being thoroughly cleaned.
14. Transport Information
Land transport
ADR
UN number UN1307
UN proper shipping name: XYLENES
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Transport hazard class(es): 3
Packing group: III
Environmental hazards: no
Special precautions for Tunnel code: D/E
user:
RID
UN number UN1307
Packing group: III
Special precautions for None known
user:
Inland waterway transport

ADN
UN number UN1307
Packing group: III
user:
Transport in inland Not evaluated
waterway vessel:
Sea transport
IMDG
UN number: UN 1307
Packing group: III
Marine pollutant: NO
user:
Air transport
IATA/ICAO
UN number: UN 1307
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Packing group: III
Environmental hazards: No Mark as dangerous for the environment is needed
user:
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated
15. Regulatory Information

Safety, health and environmental regulations/legislation specific for the substance or
mixture
If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.
16. Other Information
Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases,
and the hazard statements, if mentioned in section 2 or 3:
Xn Harmful.
F Highly flammable.
10 Flammable.
20/21 Harmful by inhalation and in contact with skin.
38 Irritating to skin.
11 Highly flammable.
20 Harmful by inhalation.
48/20 Harmful: Danger of serious damage to health by prolonged exposure
through inhalation.
63 Possible risk of harm to the unborn child.
65 Harmful: may cause lung damage if swallowed.
67 Vapours may cause drowsiness and dizziness.
Flam. Liq. Flammable liquid
Acute Tox. Acute toxicity
Skin Corr./Irrit. Skin corrosion/irritation
Eye Dam./Irrit. Serious eye damage/eye irritation
STOT SE Specific target organ toxicity — single exposure
Asp. Tox. Aspiration hazard
Repr. Reproductive toxicity
STOT RE Specific target organ toxicity — repeated exposure
Repr. Cat. 3 Reprotoxic substances (fertility or development) Category 3: Substances
which cause concern for humans owing to possible developmental toxic
effects or substances which cause concern for human fertility.
H315 Causes skin irritation.
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H312 Harmful in contact with skin.
H332 Harmful if inhaled.
H226 Flammable liquid and vapour.
H319 Causes serious eye irritation.
H225 Highly flammable liquid and vapour.
H335 May cause respiratory irritation.
H304 May be fatal if swallowed and enters airways.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs (Central nervous system) through
prolonged or repeated exposure.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility
of the recipient of the product to ensure any proprietary rights and existing laws and legislation are
observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.

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Safety data sheet

1. Identification of the substance/mixture and of the company/undertaking

MasterTop THN 2 also Cleaning Solvent NO.2

Relevant identified uses: Product for construction chemicals

Details of the supplier of the safety data sheet

Telephone: +49 621 60-74354

Emergency telephone number

International emergency number:

According to Directive 67/548/EEC or 1999/45/EC

Directive 1999/45/EC ('Preparation Directive')

Hazard determining component(s) for labelling: XYLENE

Classification of the substance or mixture

According to Directive 67/548/EEC or 1999/45/EC

According to Regulation (EC) No 1272/2008 [CLP]

Blend based on: organic, hydrocarbon solvent

Hazardous ingredients (GHS)

On contact with eyes:

Most important symptoms and effects, both acute and delayed

Indication of any immediate medical attention and special treatment needed

Special hazards arising from the substance or mixture

Advice for fire-fighters

6. Accidental Release Measures

Methods and material for containment and cleaning up

Reference to other sections

7. Handling and Storage

Protection against fire and explosion:

Conditions for safe storage, including any incompatibilities

Suitable materials for containers: Steel container, tin (tinplate)

Specific end use(s)

8. Exposure Controls/Personal Protection

Components with occupational exposure limits

General safety and hygiene measures

9. Physical and Chemical Properties

Miscibility with water:

Corrosion to metals: Corrosive effects to metal are not anticipated.

Possibility of hazardous reactions

Hazardous decomposition products

No hazardous decomposition products if stored and handled as prescribed/indicated.

11. Toxicological Information

Assessment of acute toxicity:

Assessment of irritating effects:

Germ cell mutagenicity

Assessment of reproduction toxicity:

Specific target organ toxicity (single exposure)

Assessment of STOT single:

Assessment of repeated dose toxicity:

May also damage the lung at swallowing (aspiration hazard).

Other relevant toxicity information

12. Ecological Information

Assessment of aquatic toxicity:

Persistence and degradability

Assessment biodegradation and elimination (H2O):

Assessment bioaccumulation potential:

Mobility in soil (and other compartments if available)

Assessment transport between environmental compartments:

Results of PBT and vPvB assessment

Other ecotoxicological advice:

13. Disposal Considerations

Waste treatment methods

Observe national and local legal requirements.

14. Transport Information

Inland waterway transport

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code