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DIVISIÓN DE INGENIERÍAS.
Students:
Group: Q25
What is a ceramic?
Ceramics compared to metals and plastics are hard, non-combustible and non-
oxidizing. This material can be used in high temperature environments. corrosive
and tribological. In these environments many ceramics exhibit good
electromagnetic, optical and mechanical properties. A fundamental feature for
ceramics is their ability to be manufactured in shapes with certain dimensions,
dictated by the use to be given to the material.
But once we start doing that, things can get confusing. For example, graphite (a
form or carbon allotropic) is considered a ceramic because it is not metallic and
inorganic, but (unlike most ceramics) it is soft, easily wears out and is a good
conductor of electricity. So, if I looked at only the properties of graphite, I wouldn't
consider it a pottery at all. Diamond (another form of carbon) is also a ceramic for
the same reason; Its properties may not be more different from those of graphite,
but they are similar to those of other ceramics. (Like modern ceramics, such as
tungsten carbide, diamond has long been used in cutting and drilling tools).
Properties of ceramic materials
The properties of ceramic materials, like their chemical compositions, vary greatly
due to differences in bonds, having a large amount of mechanical and physical
properties. The properties of ceramic materials are determined in four levels which
are atomic, atom, crystalline or amorphous ordering, microstructure and
macrostructure.
In general, ceramic materials are typically hard and fragile, with low toughness and
ductility. Ceramic materials usually behave as good electrical and thermal
insulators due to the absence of conductive electrons, they usually have relatively
high melting temperatures and, also, relatively high stability in most of the most
aggressive media due to the stability of their strong bonds. Because of these
properties ceramic materials are indispensable for many of the designs in
engineering.
High hardness
High elastic modulus
Low ductility
High dimensional stability
Good wear resistance
High resistance to corrosion and chemical attack
High weather resistance
High melting point
High working temperature
Low thermal expansion
Low to medium thermal conductivity
Good electrical insulation
Low to medium tensile strength
High compressive strength
Medium machinability
Opacity
Brittleness
Poor impact strength
Low thermal shock resistance
Tailoring the properties and structure of ceramic materials to their specific functions
in devices and equipment, and also the development of adequate processing
require a deep understanding of the relationships between composition and
properties. This book discusses the structure of crystalline and amorphous ceramic
phases, surfaces and interfaces. It also reviews the morphology of polycrystals,
multiphase materials (including composites), fibrous, and dispersed ceramic
systems.
Ceramic materials used for engineering applications can regularly be classified into
two groups: traditional ceramic materials and ceramic materials for specific
engineering use.
Traditional ceramic materials are usually made up of three basic components: clay,
silica (flint) and feldspar. Examples of traditional ceramics are bricks and shingles
used in the construction and electric porcelain industries for use in the electrical
industry.
Engineering ceramics, on the other hand, are typically composed of pure or almost
pure compounds such as aluminium oxide ( Al 2or3),siliconcarbide (SiC), and silicon
nitride(Si3N4). Examples of application of engineering ceramics in state-of-the-art
technology are silicon carbide in the high temperature areas of the gas engine
turbine, and aluminum oxide at the base of the support for the integrated circuits of
the chips in a thermal conduction module.
History (Timeline)
1500: Refractory ceramics are created, used to make steel, cement, etc.
1800: Electric bulb is created, also porcelain insulators.
1960: Insulators for 220 Kv, first applications of carbides and nitrides.
1970: Cellular ceramics for Diesel engine catalysts
Automotive Industry
In recent decades, great advances have been made in the industry, thanks in part
to the properties of these new materials. These properties in certain cases far
exceed that of traditional materials such as steel or alloys. They are obtained
thanks to the high purity of the base materials and meticulous manufacturing
process.
Automotive ceramics, advanced ceramic materials that are made into components
for automobiles. Examples include spark plug insulators, catalysts and catalyst
supports for emission control devices, and sensors of various kinds. This article
briefly describes two important automotive applications of modern advanced
ceramics—support structures for catalytic converter elements and various pressure
and heat sensors.
Sensors: In addition to the oxygen sensor used to monitor and control the air-fuel
ratio (see conductive ceramic), many other sensors are used in automobiles to
measure a number of variables, including temperature, pressure, speed and fuel
level. Many of these sensors are made of ceramic. For example, sensors to read
pressure in intake or exhaust manifolds may incorporate an alumina diaphragm
substrate in which thick film circuits are screen-printed. As the diaphragm deviates
due to pressure fluctuations, a change in capacitance is recorded. Dynamic
pressure sensors, for example, for combustion chamber pressures, are made of
piezoelectric ceramic, which generate a voltage when subjected to pressure.
Piezoelectric sensors can be quite small and have short response times. A variety
of position sensors-actuators and acceleration-deceleration sensors are made of
piezoelectric ceramic. Piezoelectric ceramic is described in the dielectric and
piezoelectric ceramic article condenser.
Ceramics also can be formed into the complex shapes of rotors and stators
employed in gas-turbine engines. Gas turbines have rotating rather than
reciprocating parts, and here the refractoriness of ceramics, their resistance to
corrosion and wear, and their light weight make for highly efficient high-
temperature operation. Turbine engines with ceramic parts or ceramic-coated
metal parts are currently in operation as auxiliary power sources. Automotive
ceramics are only one of several types of advanced structural ceramic. For a
survey of the issues involved in adapting ceramics for demanding structural
applications, see advanced structural ceramics. For a directory to all the articles
covering both traditional and advanced industrial ceramics, see Industrial
Ceramics: Outline of Coverage.
Methodology:
Ceramics in the automotive industry have great use and applications, the areas or
products where the application of ceramics stands out noticeably over the rest of
the materials, being indispensable in certain applications or as important
improvements in terms of performance or performance, are:
Piston Coating: Ceramics allow for greater efficiency, less wear, increase
component life and reduce material expansion.
Bearings: The use of ceramics allows very low friction rates (10 times better
for materials that do not use ceramics), allows to rotate at a higher number
of revolutions per minute, causes less expansion, prevents corrosion and
extends the life of the product.
Bodies: The bodies have evolved, are now lighter and stronger.
Ceramic processing.
1. Preparation of materials:
Most products are manufactured by particle agglomeration. The raw materials for
these products vary, depending on the propertiesrequeridas por la pieza de
cerámica Finished. Particles and other constituents such as binders and lubricants
can be mixed dry or wet. For ceramic products that do not need to have very
"critical" properties, mixing ingredients with water is a common practice. For other
ceramic materials, raw materials are dry lands with binders and other additives.
2. Forming techniques:
Pressing: The raw material can be pressed in a dry, plastic or wet state, inside a
die to form processed products.
Dry pressing: This method is frequently used for refractory products (high thermal
resistance materials) and electronic ceramic components. Dry pressing can be
defined as simultaneous uniaxial compaction and the formation of granulated
powders with small amounts of water and/or organic glues in a die. After cold
stamping, the particles are normally heated (sintered) so that the desired strength
and microstructural properties are achieved. Dry pressing is widely used because it
allows a wide variety of parts to be manufactured quickly with small uniformity and
tolerance.
Isostatic compaction: In this process the ceramic powder is loaded into a flexible
(usually rubber) airtight container (called a cartridge) that is inside a hydraulic fluid
chamber to which it is applied under pressure. The applied pressure force
compacts the powder evenly in all directions, taking the product the shape of the
flexible container. After pressing the isostatically cold part it has to pass through
the fire (sintering) to obtain the required microstructural properties.
Hot compression: In this process high density parts and optimized mechanical
properties are achieved by combining unidirectional pressure such as isostatic
pressure.
Extrusion: Simple cross sections and hollow shapes of ceramic materials in plastic
state through a funnel die. This process is commonly applicable in production.
3. Thermal treatments
Drying and removal of binders: The purpose of drying ceramics is to remove water
from the plastic ceramic body before being subjected to high temperatures.
Generally, water removal takes place at less than 100oC and can take as long as
24 hours. for a large piece of ceramic. Most organic binders can be removed from
ceramic pieces by heating in the range of 200 to 300oC, although some
hydrocarbon residues may require heating at higher temperatures.
Sintering: The process by which small particles of a material are held together by
diffusion are called sintering. In the manufacture of ceramics this heat treatment is
based on the transformation of a porous product into a compact and coherent one.
Sintering is widespreadly used to produce ceramic forms of, for example, alumina,
berilia, ferrite and titanates.
In the sintering process the coalescing particles by diffusion to the solid state at
very high temperatures, but below the melting point of the compound to be
sintered. In sintering, atomic diffusion takes place between the contact surfaces of
the particles so that they are chemically bonded.
Verification. Some ceramic products contain a vitreous phase. This vitreous phase
serves as a means of reaction so that diffusion can take place at a lower
temperature than in all other ceramic solid materials. During high-temperature
treatment of this type of ceramic solid material, a process called verification takes
place whereby the vitreous phase is liquefied and filled the pores of the material.
This liquid vitreous phase may also react with some of the remaining refractory
material solids. Under cooling, the liquid phase solidifies to form a vitreous matrix
that binds unmeltened particles.
In recent decades, great advances have been made in the automotive industry,
thanks in part to the properties offered by these new ceramic materials. These
properties, in some cases, far outweigh that of traditional materials such as steel
and alloys. These benefits are obtained by the high purity of the base materials
and the meticulous manufacturing processes.
The use of ceramic materials in the creation of motors allows them to improve their
efficiency with respect to the behavior at high temperatures. With the use of mixed
ceramic materials in internal combustion engines, their efficiency is increased,
although their current cost and their development still today make them unworkable
despite already being used in other industries.
Ceramic brake technology in vehicles has been gaining strength and relevance
today because of the great advantages of the uses of these technologies, such as
the low weight of the components that causes a now about 50% weight per wheel,
the high resistance it gives to wear of the brake discs extending the service life
approximately four times that of the convention metal discs, increases the
resistance to thermal shocks and greatly increases the friction rate of the disc, the
pickup by increasing operating temperatures. This is thanks to the C/SIC ceramic
compound which is a silicon carbide reinforced with carbon fiber, silicon carbide
has diamond-like properties and is characterized by a high hardness, which in turn
gives it very high resistance to abrasion wear and very good thermal stability.
On the part of the use of ceramics in automotive paints, these compounds have
presented a breakthrough for the creation of high durability protective layers that
are presented in a liquid and transparent state that is used in several layers. These
coatings when applied are transformed into a permanent shield of flexible glass,
being able to describe this type of paint as an additional transparent paint with a
greater hardness and with qualities of self-cleaning.
A few years ago, researchers found a way to reduce manufacturing costs and the
development time of electronic ceramics by applying electric fields at a rate of 60
Hertz. The result of subjecting ceramic materials (used for the manufacture of non-
metallic electronic components) to the exposure of electric fields to 60 Hertz levels,
was the decrease in manufacturing time, costs and size, the latter by 63% since
porosity was removed with only a temperature of 1,250 degrees Celsius and not to
1,500 degrees as regularly needed , provoked a totally positive reaction in the
manufacture of the ceramics itself. A breakthrough in reducing costs and making
the use of ceramics in the automotive industry more viable, as these electro-
ceramic materials are used for the creation of spark plugs.
Future prospects
Various technological and manufacturing industries are also involved with the
development of the automotive industry including mechanical and machine tool
manufacturing industries, glass and ceramic industries, electrical, electronics and
safety engineering, design and any other respective subsections for automotive
manufacture. Each is responsible for the development of individual components of
motorize vehicles such as the engine, power transmission, electric and electronic
components of the vehicle, the body, the designs etc.
Therefore the physical, mechanical and chemical properties of the materials are
the key components to their exploitation as primary components which meet the
technical requirements of automotive industry. High-quality ceramic based
materials on the other hand are considered to be the major constituents of various
components integrated and formed todays’ motor-powered vehicles. In fact, the
ceramic materials have wide range of industrial applications and are considered as
the key engineering materials.
Integrated components for motorized vehicles are individually installed for specific
purpose thus each component has particular property which could be reliable and
efficient all through the long term operation. Hence, research and testing prior to
utilization of certain component focused on distinct property such as mechanical
strength, dimensional stability, thermal and electrical property, chemical inertness,
long term durability, dielectric property, and other key properties before a certain
component is to be considered.
Today, the use of ceramic materials in automotive industry has become common
and widespread all over the world. Such utilization and integration include its
application to transducers and sensors such as fuel talk ultrasonic level sensors.
Utilizing specifically the piezo-electric properties of PZT (or lead zirconia titanate)
ceramic materials made it an ideal component for transducers and sensors.
Moreover, ceramic’s resistance to abrasion through long cycles make the materials
more reliable in this matter. Like for example, “the key advantage of using alumina
plates in such valve assemblies are that the valves are typically used for more than
20 million cycles.” Therefore, ceramic based materials have been used as primary
constituents to major automotive components and their physical and chemical
properties are made them an attractive option to such industry.
Conclusions
We can conclude that ceramic materials in the automotive industry have been of
great help to this has been developed in large numbers over the last few years,
since much of the parts that make up an automobile are made from ceramics.
Thanks to all the virtues of these compounds, their future projection is abysmalally
large, represented to a more ecological and economical form by the expense of
fuels, if they come to develop processes and products with affordable prices for the
general public, in addition to offering products more resistant to time and other
conditions that are presented as an adversity in the other materials currently used
for the manufacture of automobiles.
The good characteristics and qualities they offer to ceramics have caused it to
surpass other materials traditionally used in this field and today large automotive
companies prefer to make their parts of this material. A notable example in which
ceramics have surpassed another material is in the case of metal, since ceramics
far exceed it in aspects such as its resistance to corrosion, its low electrical
conductivity, its more efficient stamina to the use for which they are designed, a
wide margin of resistance to different temperatures, among other characteristics
that make ceramics a winning bet in the future , and together is the fact that
research follows to improve ceramics that only promise to have a product of better
properties for the automotive industry.
In a not too distant time we will see how most automotive industries will prefer to
make parts and components for their ceramic-based cars, since these by their
good characteristics are more convenient and efficient in what the industry is
looking for. There are currently many companies that conduct research to make
this material more cost-effective and affordable for its more extensive in automobile
manufacturing. With all that is exposed be seen as ceramics represent an
imminent improvement for the industry only hindered by the high prices involved in
its use, but it is not crazy to say that in some years its use will be widespread to be
able to have products of higher quality, durability and with a great ecological
involvement for the world. Ceramic materials are of vital importance at the moment
in the automotive industry and will be more important in the future. We only have to
see which ceramic technologies we are about to be amazed by the near future.
References
Akira Okada. (2008). Ceramic technologies for automotive industry: Current status
and perspectives. Monday, May 4, 2020, of ScienceDirect Website:
https://www.sciencedirect.com/science/article/abs/pii/S0921510708005734
AZO Materials. (2020). How will the Technical Ceramics Industry Develop?.
Monday, May 4, 2020, of AZO Materials Website:
https://www.azom.com/article.aspx?ArticleID=19129
Ummen Sabu. (2015). Ceramic Technologies for Automotive Applications.
Monday, May 4, 2020, of SlideShare Website:
https://es.slideshare.net/ummen6097/ceramic-technologies-for-automotive-
applications