CHAPTER PRACTICE PROBLEMS (CHEMISTRY) FIITJE

E
AMINES
Q.1. Write the major products when the following compounds are treated with aqueous alkaline
Br2.
(a) (b) H2N NH2
NH2
O O

H3C O

Q.2. Write the major organic products when the following compounds are heated
(a) CH3 (b) Ph CH3
+ +
N N
CH3 CH3 OH
CH3 CH3 OH
H3C

Q.3. Write the products in the following sequence:

H3C

NaNO2 HCl N2 , Cl H2O
NH2   ?   ?   ? ?
0 C
H3C

Complete the following equations:

Q.4. H3C
CH3 AgOH
N CH3 H3C  ?   ?  ?
H3C I

Q.5. H3C
SOCl2 NaCN LiAlH4
  ?  ?  ?
OH
Q.6. CH3CH2CH2CH2Cl  ? 
4
? NaCN LiAIH

Q.7. KOHaq. Cr2O7 / H 2 

NH
CH3CH2CH2Cl   ?   ?  3
H / Ni
?
2

Q.8. Br2 / CCl4

CH2  CH2  NaCN
?  LiAlH4
?  ?

Q.9. Complete the following equation and give the:

O
NaN3 N2 H2O
  ?   ?   ? 
 CO
?
2

Cl
Identify the bracketed compounds on the following reactions:
PBr3 n  C3H7 COCl NH3
Q.10. n-C3H7 COOH 
LiAlH4
[A]  [B] (i) Li
(ii) CuI

[C]  [D] 
H2 / Ni
[E]


CH3NH2 CH3Br H3 O
Q.11. C6H5 SO2Cl  [A] 
NaOH
[B]  [C]  [D]  [E]

Q.12.
NH2 
excess of Ag2 O
[A]  [B] 
heat
[C]  (CH3 )3 N
CH I 3 H O 2

ICES House, 29 – A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 26515949, 26569493, Fax:011-26513942.
CHAPTER PRACTICE PROBLEMS (CHEMISTRY) FIITJE
E
Q.13. O

 
NK 
Br(CH2 )2 COO
[A] 
(i) OH
[B]
(ii) H

O
Q.14.
NH2 
NaNO2
[A]  [B]  [C]
HCl

Give steps involved in the following conversions.

Q.15. Propene into allylamine

Q.16. n-Butanol to n-hexylamine

Q.17.
H3C NO 2 H2N NO 2

Q.18.
CH3
NH2

Q.19. Write the products of the following reactions:

(a)

H
O  RNH2 

?

(b)

H
O  R2NH 

?

Q.20. Give the following conversions:

O NH2

(i) CH3 – NH2 to CH3CH2NH2 (ii)

to

NH2 OH

(iii) (iv) CH3 – COOH to CH3 – NH2

to



ICES House, 29 – A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 26515949, 26569493, Fax:011-26513942.