sistema benceno-tolueno

datos
A=Benceno p-eb.= 80.13 C 635.9 R deltaT= 154.9 graficar 29 puntos
B=tolueno p-eb.= 166.18C 790.8 R paso= 7.745
7.745
714.2
pv=pc.exp(A1-(A2/(Tb+A3)))

Pc(psia) A1 A2 A3 Xa=(Pt-Pvb)/(Pva-Pvb)
Benceno 714.2 5.658375 5307.813 379.456
Tolueno 587.8 5.944251 5836.287 374.745 Ya=((Xa*Pva)/Pt)
P=1 atm=14.696 psia

Ti(F) Pva(psia) Pvb(psia) Xa Ya

176.18 14.53933686235 5.62388877893 1 1
178 14.99993332285 5.82351786074 0.96687886 0.98687524
180 15.5192959765 6.049475063551 0.91306108 0.96421238
182 16.05274793673 6.282481115766 0.86113502 0.94063578
184 16.60055322926 6.522696783043 0.81101604 0.91612105
186 17.16297804858 6.770284878192 0.7626238 0.8906434
188 17.74029072856 7.025410254119 0.71588197 0.86417762
190 18.33276171259 7.288239796223 0.67071805 0.83669803
192 18.94066352328 7.558942414275 0.62706312 0.80817853
194 19.56427073164 7.837689033768 0.58485168 0.77859258
196 20.20385992593 8.124652586752 0.54402141 0.7479132
198 20.85970968005 8.420008002162 0.50451306 0.71611296
200 21.53210052147 8.72393219564 0.46627025 0.68316398
202 22.22131489888 9.036604058864 0.42923929 0.64903793
204 22.92763714941 9.358204448382 0.3933691 0.61370604
206 23.65135346549 9.688916173972 0.35861102 0.57713908
208 24.39275186138 10.02892398652 0.32491868 0.53930735
210 25.15212213943 10.37841456544 0.29224793 0.5001807
212 25.92975585592 10.73757650561 0.26055666 0.45972854
214 26.7259462867 11.10660030392 0.22980474 0.41791978
216 27.54098839253 11.48567834526 0.19995389 0.3747229
218 28.37517878412 11.87500488821 0.1709676 0.33010589
220 29.22881568697 12.2747760502 0.14281104 0.2840363
222 30.10219890591 12.68518979228 0.11545095 0.23648118
224 30.99562978952 13.10644590349 0.0888556 0.18740713
226 31.9094111942 13.53874598485 0.06299467 0.13678027
228 32.8438474482 13.98229343285 0.03783922 0.08456626
230 33.79924431538 14.43729342272 0.0133616 0.03073026
231.08 34.32398212592 14.68782816416 0 0
a=(Pt-Pvb)/(Pva-Pvb)

a=((Xa*Pva)/Pt)

digrama benceno-tolueno
1.2

0.8

0.6
Ya

0.4

0.2

0
0 0.2 0.4 0.6 0.8 1 1.2
Xa
sistema ciclohexano-heptano
datos
A=ciclohexano
B=heptano

pv=pc.exp(A1-(A2/(Tb+A3)))

Pc(psia) A1 A2 A3 Xa=(Pt-Pvb)/(Pva-Pvb)
ciclohexano 591.5 5.473055 5030.253 371.2755
heptano 396.9 5.98627 5278.902 359.5259 Ya=((Xa*Pva)/Pt)
P=1 atm=14.696 psia

Ti(F) Pva(psia) Pvb(psia) Xa Ya

176.18 14.40093520768 8.296632505153 1 1
178 14.84612046806 8.578118146151 0.97604971 0.98602011
180 15.34766385587 8.896159189366 0.89899041 0.93885429
182 15.86234013087 9.223511271975 0.82431538 0.88973673
184 16.39038086944 9.5603661223 0.75192135 0.8386144
186 16.93201919703 9.90691735813 0.68171007 0.78543331
188 17.48748975766 10.26336046714 0.61358807 0.73013848
190 18.05702868319 10.62989278684 0.54746638 0.67267394
192 18.64087356223 11.00671348399 0.4832603 0.61298273
194 19.23926340892 11.39402353365 0.42088917 0.55100691
196 19.85243863134 11.79202569769 0.36027612 0.48668751
198 20.48064099972 12.20092450293 0.30134794 0.41996454
200 21.12411361452 12.62092621879 0.24403482 0.35077703
202 21.78310087419 13.05223883464 0.1882702 0.27906293
204 22.45784844277 13.49507203659 0.13399062 0.20475919
206 23.14860321739 13.94963718403 0.08113551 0.1278017
208 23.85561329553 14.41614728578 0.02964709 0.04812531
210 24.57912794214 14.89481697576 -0.0205298 -0.03433619
212 25.31939755668 15.38586248849 -0.06944783 -0.11965006
214 26.07667363996 15.88950163408 -0.11715731 -0.20788465
216 26.85120876098 16.40595377304 -0.16370627 -0.29910937
218 27.64325652353 16.93543979069 -0.20914065 -0.39339472
220 28.45307153287 17.47818207128 -0.25350434 -0.49081226
222 29.2809093622 18.03440447186 -0.29683929 -0.59143469
224 30.12702651919 18.60433229586 -0.33918563 -0.69533577
226 30.99168041237 19.18819226636 -0.38058176 -0.80259038
228 31.87512931754 19.78621249921 -0.4210644 -0.91327451
230 32.77763234416 20.39862247578 -0.46066871 -1.02746526
231.08 33.27299815037 20.73538832381 0 0
a=(Pt-Pvb)/(Pva-Pvb)

a=((Xa*Pva)/Pt)

diagrama ciclo hexano- heptano

1.5

0.5

0
-0.6 -0.4 -0.2 0 0.2 0.4 0.6 0.8 1 1.2
-0.5

-1

-1.5

Ya